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13

th
VXY (Date: 22-01-2012) Review Test-6
PAPER-2
Code-A
ANSWER KEY
PHYSICS
SECTION-2
PART-A
Q.1 D
Q.2 C
Q.3 B
Q.4 B
Q.5 D
Q.6 A
Q.7 B
Q.8 B
Q.9 B
Q.10 A
Q.11 C
Q.12 C
Q.13 B
Q.14 C
Q.15 A
Q.16 A
PART-B
Q.1 (A) S
(B) S
(C) Q
PART-C
Q.1 0002
Q.2 0006
Q.3 2375
Q.4 0006
MATHS
SECTION-1
PART-A
Q.1 A
Q.2 B
Q.3 D
Q.4 B
Q.5 A
Q.6 B
Q.7 C
Q.8 A
Q.9 A
Q.10 B
Q.11 D
Q.12 D
Q.13 C
Q.14 C
Q.15 B
Q.16 D
PART-B
Q.1 (A) R
(B) S
(C) Q
PART-C
Q.1 0002
Q.2 0075
Q.3 0021
Q.4 0439
CHEMISTRY
SECTION-3
PART-A
Q.1 D
Q.2 A
Q.3 B
Q.4 C
Q.5 C
Q.6 D
Q.7 C
Q.8 C
ONLY V-GROUP :
Q.9 D
Q.10 B
Q.11 D
ONLY XY-GROUP :
Q.9 B
Q.10 A
Q.11 D
Q.12 B
Q.13 D
Q.14 C
Q.15 D
Q.16 D
PART-B
Q.1 (A) Q,R
(B) R
(C) R,S
PART-C
Q.1 0810
Q.2 0004
Q.3 9306
Q.4 3421
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. Put tan x = t sec
2
x dx = dt. So I = dx
1 x tan 3
3 x tan
12
0
2
2
}
t

= dt
) t 1 )( 1 t 3 (
3 t
3 2
0
2 2
2
}

+

= dt
1 t 3
2
t 1
1
3 2
0
2 2 }

|
.
|

\
|

+
=
} }

|
.
|

\
|

+
3 2
0
2
2
3 2
0
2
3
1
t
dt
3
2
t 1
dt
=
12
t
+
3
1
ln
|
|
.
|

\
|


3 2
1 3
]
Q.2
[Sol. We must have f(p) < 0, where f(x) = 2x
2
2(2p + 1)x + p(p + 1)
p
x-axis
x = | x = o So, f(p) < 0 p
2
+ p > 0 p > 0 or p < 1. ]
Q.3
[Sol. If y = ax
3
+ bx
2
+ cx + d has only one critical point on R, so
dx
dy
= 0 has both roots real and equal.
Put
dx
dy
= 0 3ax
2
+ 2bx + c = 0. So, D = 0 4b
2
12ac = 0 b
2
= 3ac
Given, ac = 2 b
2
= 6
| b | =
6
. Ans.]
Q.4
[Sol. Given, 1 + x
2
+ 2x sin (cos
1
y) = 0
As x = 0 will not satisfy it, so x +
x
1
= 2 sin (cos
1
y).
As, cos
1
y e [0, t], so 0 s sin (cos
1
y) s 1.
So, above equation is possible when x = 1 and y = 0.
Only one ordered pair (1, 0) is possible. ]
Q.5
[Sol. Use L'Hospital rule, we have
}
>

x
a
t
a x
) 0 a ( dt t sin e t
a x
1
Lim |
.
|

\
|
form
0
0
=
x 2
1
x sin e x Lim
x
a x
=
a sin e
2
1
a
. Ans.]
Q.6
[Sol. G G G G G G | R | R | R | R | R |
6
C
2
gaps for G G and G G
& selection of 2 more gaps from the remaining 4 in
4
C
2
ways for G and G.
Total ways =
6
C
2

4
C
2
=
! 2 ! 2
! 4

! 4 ! 2
! 6
=
! 2 ! 2 ! 2
! 6
=
8
720
= 90. Ans.]
MATHEMATICS
Code-A Page # 2
Q.7
[Sol. As, trace A = (x 2) + (x
2
x + 3) + (x 7) = x
2
+ x 6
Given, trace A = 0 x
2
+ x 6 = 0 = (x + 3) (x 2)
x = 3 or 2. Ans.]
Q.8
[Sol. Given, C
1
(3, 2) and r
1
= 12 4 9 + + = 5
Also, C
2
(2, 3) and r
2
= 12 9 4 + + = 5
Also, C
1
C
2
= 1 1+ = 2
As, | r
1
r
2
| < C
1
C
2
< r
1
+ r
2
S
1
and S
2
intersect each other at two distinct points S
1
and S
2
have 2 direct common tangents.
Also, (C
1
C
2
)
2
=
2
2
2
1
r r +
S
1
and S
2
are not orthogonal circles.
Also, equation of radical axis of S
1
and S
2
is S
1
S
2
= 0 i.e. x y = 0.
As, S
1
(1, 2) < 0 and S
2
(1, 2) > 0 (1, 2) lies inside S
1
but outside S
2
.]
Q.9, 10, 11
[Sol. Any tangent to 1
4
y
25
x
2 2
= + , is
y = mx
4 25
2
+
.........(1)
If above line in equation (1) is also tangent to x
2
+ y
2
= 16, so
4
m 1
4 m 25 ) 0 ( m 0
2
2
=
+
+
25 m
2
+ 4 = 16(1 + m
2
) 9m
2
= 12
m
2
=
3
4
or m =
3
2
.
On putting m =
3
2
in equation (1), we get
T
1
:
0 7 4 y 3 x 2 = + +
.........(i)
T
2
:
0 7 4 y 3 x 2 = +
.........(ii)
T
3
:
0 7 4 y 3 x 2 = + +
........(iii)
T
4
:
0 7 4 y 3 x 2 = +
........(iv)
MATHEMATICS
Code-A Page # 3
(i) The equation of common tangent between C
1
and C
2
having negative gradient in the first quadrant is
7 4 y 3 x 2 = +
.
So, x-intercept =
7 2
(A) is correct.
(ii) As quadrilateral formed by common tangents
between C
1
and C
2
is a rhombus, so area of rhombus
=
( )
|
|
.
|

\
|
=
3
7 8
7 4
2
1
d d
2
1
2 1
O(0,0)
(2 7, 0)
(2 7, 0)
|
|
.
|

\
|
3
7 4
, 0
|
|
.
|

\
|

3
7 4
, 0
x
y
=
3
3
112
3
7 16
=

(B) is correct. Ans.


(iii) Director circle of C
1
is x
2
+ y
2
= 32. So, any point on it is
( ) u u sin 2 4 , cos 2 4
.
Also, auxiliary circle of C
2
, is x
2
+ y
2
= 25.
So, equation of chord of contact, is
( ) ( ) u + u sin 2 4 y cos 2 4 x
= 25 ..........(1)
Let, mid point of chord of contact be (h, k). So, also equation of chord of contact is
hx + ky = h
2
+ k
2
[Using T = S
1
] ..........(2)
As, equation (1) and equation (2) represents same line, so on comparing, we get
h
cos 2 4 u
=
k
sin 2 4 u
=
2 2
k h
25
+
cos u =
( )
2 2
k h 2 4
h 25
+
, sin u =
( )
2 2
k h 2 4
k 25
+
Now, on squaring and adding, we get
( ) ( )
1
k h 32
k 625
k h 32
h 625
2
2 2
2
2
2 2
2
=
+
+
+
625 (h
2
+ k
2
) = 32(h
2
+ k
2
)
2
h
2
+ k
2
=
32
625
Locus of (h, k) is x
2
+ y
2
=
32
625
(D) is correct. Ans.]
Q.12, 13, 14
[Sol. We have,
( )

>
s s +
< +
=
0 x , x
0 x 1 ), 1 x (
1 x , 1 x
) x ( F
and

>
< <
s < +
s < +
=
2 x , x 2
2 x 1 , 2 x
1 x 0 , 1 x
0 x , 1 x
) x ( G
Now, H(x) = F(x) + G(x) =
( )

> = +
< < = +
s < + = + +
s s = + +
< < = + +
2 x , 2 x 2 x
2 x 1 , 2 x 2 ) 2 x ( x
1 x 0 , 1 x 2 ) 1 x ( x
0 x 1 , 2 1 x ) 1 x (
1 x , x 2 1 x 1 x
MATHEMATICS
Code-A Page # 4
y
(0,3) (1,3)
(2,2)
y=2
(0,2)
y=2
(1,2)
y = 2x
(2,4)
1 2 1 2
x
y=2x+1
A
1
A
2
A
3
A
4
y=2x2
(0,1)
O
(0,4)
(i) From above graph, the function H(x) has local maximum at x = 1 (D) is correct.
(ii) From above graph, the function H(x) is discontinuous at two points viz. x = 0
and x = 1 (C) is correct.
(iii)
}

2
2
dx ) x ( H = AA
1
+ A
2
+ A
3
+ A
4
=
2
1
(4 + 2) 1 + ( ) 2 1 +
( ) 1 3 1
2
1
+
+
|
.
|

\
|
2 1
2
1
= 3 + 2 + 2 + 1 = 8. Ans.]
Q.15
[Sol. We have, f(x) = (x
2
+ x 2) (x
2
+ 2x 3), x e R
or f(x) = (x + 2) (x 1)
2
(x + 3)
S-1 is correct because f(1

) > f(1) < f (1


+
) .
S-2 is correct as f(x) has a repeated root at x = 1.
But S-2 is not correct explanation of S-1 as f '(c) = 0 does not imply that f has an extrema at x = c. ]
e.g., f(x) = (x 1)
3
is differentiable x e R and f '(1) = 0 but f(x) does not have extrema at x = 1.
(B) is correct.
Q.16
[Sol. For two non-zero vectors to be perpendicular, their dot product must be zero.
i.e.,
( ) ( ) ( ) ( ) C B A A C C B B A

+ + |
.
|

\
|
+ +
= 3 | | C B A

= 0
Statement-1 is false.
Obviously, Statement-2 is true.
(D) is correct.]
MATHEMATICS
Code-A Page # 5
PART-B
Q.1
Sol.
(A) Equation of given tangent to y
2
= 8x, is y = x + 2 ... (1)
So, equation of any line perpendicular to it is
y = x + c. If this line is tangent to y
2
= 8x, so
x=-2
y
y=x+2
90
0
(-2, 0)
x
c =
m
a
gives c =
1
2

c = 2.
Equation of other tangent is y = x 2 ... (2)
Now, on solving (1) and (2), we get M(2, 0).
So distance of M(2, 0) from
N(1, 2
2
) =
2 2
) 2 2 0 ( ) 1 2 ( + + =
9 8 1 = +
= 3 Ans.
(B) The equation of ellipse x
2
+ 2y
2
= 6 ... (1)
or 1
3
y
6
x
2 2
= +
Differentiate (1) on both sides with respect to x, we get
(0, 0)
(x, y)
x
y
x
+
y
=
7
2x + 4y
dx
dy
= 0
dx
dy
=
y 2
x
= 1. (Given)
(As, slope of line x + y 7 = 0 is 1)
x = 2y ... (2)
Solving (1) and (2), we get
4y
2
+ 2y
2
= 6 y = 1
So, points are (2, 1) and (2, 1).
But, the point lies in first quadrant. So, P(2, 1).
Also, Distance between P(2, 1) and Q(2, 1) =
16 ) 1 1 ( ) 2 2 (
2 2
= + +
= 4. Ans.
(C) The co-ordinates of P are
|
|
.
|

\
|
2
3 3
,
2
5
.
Also, e =
25
9
1
=
5
4
.
So, co-ordinates of foci are S(4, 0) and S'(4, 0) and SS' = 8.
y
x
S'(-4, 0)
8
S(4, 0)
I
(x , y )
1 1
|
|
.
|

\
|
2
3 3
,
2
5
P
7 3
Also, SP = a ex
1
= 5
|
.
|

\
|
5
4

|
.
|

\
|
2
5
= 5 2 = 3.
and S'P = a + ex
1
= 5
|
.
|

\
|
5
4

|
.
|

\
|
2
5
= 5 + 2 = 7
The co-ordinates of incentre I(x
1
, y
1
) are
x
1
= 2
8 3 7
2
5
8 ) 4 ( 3 ) 4 7 (
=
+ +
|
.
|

\
|
+ +
and y
1
=
3
2
8 3 7
2
3 3
8 ) 0 3 ( ) 0 7 (
=
+ +
|
|
.
|

\
|
+ +
MATHEMATICS
Code-A Page # 6
I
|
.
|

\
|
3
2
, 2
.
Now, distance from I |
.
|

\
|
3
2
, 2 from |
.
|

\
|
3
2
, 0 =
2
2
3
2
3
2
) 0 2 ( |
.
|

\
|
+ = 2 4 = . Ans.
PART-C
Q.1
Sol. Given, f(x) =
|
.
|

\
|
t
x 2
cost (x + 3) +
2
1
t
sin t (x +3) = |
.
|

\
|
t
2 x
cost x
2
1
t
sin t x
Now, f '(x) =
|
.
|

\
|
t
2 x
(t sin tx) +
t
1
cost x
2
1
t
(t cos t x)
f '(x) = (2 x) sin (tx)
+
0 1 2 3 4
+
x-axis
Clearly, x = 1 is the point of local maximum. Also, x = 3 is the point of local minimum.
Note : x = 2 is inflection point of function. ]
Q.2
[Sol. Line AB :
( ) k

2 i

3 k

r + + + =

As, P(3 + 1, 2, + 1) which lies on x + y + z = 6


2 + 2 = 6 = 2
Hence P is (7, 4, 3)
Now, line of intersection of the planes x + y + z = 1 and x + z = 0
is parallel to vector =
1 0 1
1 1 1
k

=
) 1 0 ( k

) 1 1 ( j

) 1 ( i

+
=
k


=
k

0 i

+
Now, the line is
1
z
0
1 y
1
x

=
= t (say)
k

) t 3 ( j

5 i

) 7 t ( N P + + =
P(7, 4, 3)
N(t, 1, t)

( ) V N P

= 0 1(t 7) + 0 + 3 + t = 0 2t = 4 t = 2
So, N (2, 1, 2)

5 j

5 i

5 N P + =
Hence,
75 N P =
= d d = 75 Ans.]
MATHEMATICS
Code-A Page # 7
Q.3
[Sol. Let x = 5 and y = 100.
Now, x, A
1
, A
2
, A
3
, ........., A
n
, y are in A.P. ......(1)
and x, H
1
, H
2
, H
2
, H
3
, ...., H
n
, y are in H.P. .......(2)
Given that, P = A
r 1
and Q = H
r 1
From (1), y = x + (n + 1) d d =
1 n
x y
+

P = A
r 1
= r
th
term = x + (r 1) d = x + (r 1)
|
.
|

\
|
+

1 n
x y

( ) ( )
) 1 n ( x
x y 1 r
1
x
P
+

+ =
..........(3)
Now, from (2),
y
1
,
H
1
, ,.........
H
1
,
H
1
,
x
1
n 2 1
are in A.P..

y
1
= (n + 2)
th
term =
x
1
+ (n + 1) d' d' =
|
|
|
|
.
|

\
|
+

1 n
x
1
y
1

1 r
H
1
Q
1

=
= r
th
term =
( ) ' d 1 r
x
1
+
= ( )
|
|
|
|
.
|

\
|
+

+
1 n
x
1
y
1
1 r
x
1
( )
( )
( ) 1 n x
y x
1 r
x
y
Q
y
+

+ = ... (4)
Hence, |
.
|

\
|
+
Q
y
x
P
= 1 +
x
y
(independent of n and r)
[Put x = 5 and y = 100]
Here, |
.
|

\
|
+
Q
100
5
P
= 1 +
5
100
= 21. Ans.
Objective approach: Take P as first arithmetic mean of 5 and 100 i.e. P =
2
105
.
Hence
5
P
=
2
21
and Q as first harmonic mean of 5 and 100 hence Q =
105
100 5 2
Hence
Q
100
=
2
1 2
|
.
|

\
|
+
Q
100
5
P
= 21 Ans.]
MATHEMATICS
Code-A Page # 8
Q.4
[Sol. Clearly, A =
p 2 1
3 1 2
1 1 1
= 1 (p 6) 1(2p 3) + 1 (4 1) (Expanding along R
1
)
A = p
Case-I : If p = 0, then system of equations has unique solution.
Case-II: If p = 0, put z = k, we get x + y = 4 k and 2x + y = 6 3k
On solving, we get
x = 2 2k, y = 2 + k
Now, substituting these values of x, y and z in equation x + 2y + p z = q, we get
(2 2k) + 2 (2 + k) + p k = q 6 + 0k = q i.e, q = 6
Thus for q = 6, there is no solution and for q = 6, there are infinite solution.
Hence, for unique solution p = 0, q e R L = 20 21 = 420
for no solution we must have p = 0, q = 6 M = 1 20 = 20
for infinite solution p = 0 and q = 6 N = 1 1 = 1
L + M N = 420 + 20 1 = 440 1 = 439. Ans.
Alternatively: x + y + z = 4 ... (1)
2x + y + 3z = 6 ... (2)
x + 2y + pz = q ... (3)
Solving (1) and (2) x = 2 2z and y = 2 + z
Put in equation (3), we get
pz = q 6
Hence, for unique solution p = 0, q e R L = 20 21 = 420
for no solution we must have p = 0, q = 6 M = 1 20 = 20
for infinite solution p = 0 and q = 6 N = 1 1 = 1
L + M N = 420 + 20 1 = 439 Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol.
20
1
+
20
1
+
15
1
=
60
4 6 +
= 6O ]
Q.4
[Sol. p =
s
A
] cos v [
dt
dm
u
=
u
u
sec A
cos Av
2
= v
2
cos
2
u ]
Q.11
[Sol. t = NiAB
Ie = NqAB
Io = Cu
2
2
e
=
I 2
C
2
u
e =
I
C
u
NABQ = I
u
I
C
Q = Ku ]
PART-C
Q.1
[Sol. di =
T
dq
=
t
e
2
dq
=
t
e t o
2
dx x 2
}
dB =
}

x 2
di
0
B =
2

0
}
e o
R
0
x
dx x
=
2
R
0
e o
]
Q.2
[Sol. i
2
=
2
R r +
c
=
4 1
5
+
= 1A
Pd = i
2
R
2
= 4V
Pd. A = 2V
Q = 3 2 = 6 C ]
PHYSICS
Code-A Page # 2
Q.3
[Sol. A
1
v
1
= A
2
v
2
10 5 = 5 v
2
v
2
= 10 m/s
pg
p
1
+
g 2
v
2
1
=
pg
v
2
+
g 2
v
2
2
4
1
10
p
+
20
25
=
4
5
10
10 2
+
20
100
4
1
10
p
= 25 1.25 = 23.75
p
1
= 2375 10
2
Pa ]
Q.4
[Sol. e
1
=
3
1200
= 20
e
2
=
27
1200
=
3
20
e
1
t = (2x + 1)
2
t
e
2
t = (2m + 1)
2
t

1
3
=
1 m 2
1 n 2
+
+
2n + 1 = 3
e
1
t =
2
3t
t =
80
6t
]
CHEMISTRY
Code-A Page # 1
PART-A
Q.2
[Sol.
P O
P
O
P
O
O
O O
O O
P
O
O
P O
P
O
P
O
O O
P
:
:
:
:
O
pt dt present NO t- bond
6 POP linkages 6 POP linkages
P = sp
3
hybridised P = sp
3
hybridised
= 4 o = 3 o + 1 lp ]
Q.3
[Sol. During intramolecular cannizaro more reaction CHO is oxidised and less reactive in reduced.]
Q.4
[Sol. N
2
+ 1/2 O
2
N = N = O
100 = 100 )] 600 BE ( ) 250 950 [(
N N
+ +

200 = 1200 BE
N=N
600
BE
N=N
= 400 kJmol
1
]
Q.6
[Sol. t
1/2
=
. avg
k
2 ln
=
) 2 (ln 2
2 ln
20 = 10 min
A

B
1x x/2
A

C
1x x/2
(1 x) 60 =
2
x
40 + 80
x = 0.5
Time in which reaction will be optically inactive = 10 min. ]
CHEMISTRY
Code-A Page # 2
Q.7
[Sol. LAH can rduce
NH C
| |
O
into CH
2
NH and C = O into CH
2
While SHB can not reduce
NH C R
| |
O
, it reduce C = O , CHO and
Cl C
| |
O

into alcohol. ]
Q.8
[Sol. (A) E
cell
= 2 / 1
H
] P [
] H [
log
1
059 . 0
2
+
2
H
P

|
( E
cell

|
)
(B) its a fact
(C) for spontaneous process AH = ve and AS = +ve
(D) From structure
O S O O S O
O
O
O
O
+6 +6
]
ONLY V-GROUP :
Paragraph for question nos. 9 to 11
[Sol.(9)
NH Cl + K Cr O + conc. H SO
4 2 2 7 2 4
Salt solid
NaOH
(E)
HCl
White fumes
(A)
(B)
Orange red fumes
NaOH
(C)
yellow solution
CH COOH
3
(CH COO) Pb
3 2
(D)
yellow ppt
gas
NaCl + NH + H O
3 2
NH Cl
4
CrO Cl
2 2
Na CrO
2 4
PbCrO
4
CHEMISTRY
Code-A Page # 3
(10)
O
Cr
Cl
O
Cl
O
Cr
O

O
O

d s hybridisation
3
BaCl
2
+ CrO
4
2

colour Yellow
BaCrO
4
(11) NH
4
Cl + AgNO
3

ppt White
AgCl


+ O H NH
2 3 [Ag(NH
3
)
2
]Cl

3
HNO
AgCl
+
Z = [Ag(NH
3
)
2
]
+
Cl

C.N. = 2 , hybridisation = sp ]
ONLY XY-GROUP :
Paragraph for question nos. 9 to 11
(9) In polling process impurity of metal oxide i reduced
3Cu
2
O + CH
4
6Cu + CO
2
+ 2H
2
O
(10) In Bessemerisation Cu
2
O is reduced by Cu
2
S
2Cu
2
O + Cu
2
S 6Cu + SO
2
]
Paragraph for question nos. 12 to 14
[Sol.
C=N
C=N
C=N
OH
OH
2
Ph
Ph
Ph
H
H
H
H
+
(i) LAH
(i) MeMgX
(ii) H /H O
+
2
CHCl /OH
3
(ii) H O
2
(A) (B) (D)
(C)

PhC NH
PhC N
H O
2
PhCH NH
2 2
PhCH NC
2
PhCCH
3
O
Note : PhCN czn be prepared. By heating
O
| |
NH C Ph
2
into Ph CN in presence of P
2
O
5
(Dehydrating agent)
2
NH C Ph
| |
O


O H
O P
2
5 2

Ph CN ]
CHEMISTRY
Code-A Page # 4
Q.15
[Sol.

+
>
Na / Na
H / O H
E E
2 2
]
Q.16
[Sol. Resonating structure with complete octet is more stable. ]
PART-B
Q.1
[Sol. (A)
Zn / O H ) ii (
O ) i (
2
3

O +
O
H
(B)
Zn / O H ) ii (
O ) i (
2
3

O
(C)
H
Zn / O H ) ii (
O ) i (
2
3

O C CH
|
H
3
= +
O
]
PART-C
Q.1
[Sol. Equal volume of AgNO
3
(0.2M) and KCN (1M) are mixed
[Ag
+
] = 0.1 M [CN

] = 0.5 M
Ag
+
+ 2CN

Ag(CN)
2

...(i)
Initial conc. 0.1 0.5 0
at eq
m
. conc. 10
6
0.3 0.1
k
1
=
2 6
) 3 . 0 ( 10
1 . 0

Similarly equal volume of Zn(NO


3
)
2
(0.2M) and KCN(1M) are mixed.
[Zn
+2
] = 0.1 M [CN

] = 0.5 M
Zn
+2
+ 4CN

Zn(CN)
4
2
...(ii)
Initial conc. 0.1 0.5 0
at eq
m
.conc. 10
12
0.1 0.1
k
2
=
4 12
) 1 . 0 ( 10
1 . 0

2[Ag(CN)
4
]

(aq) + Zn
+2
(aq) [Zn(CN)
4
]
2
(aq) + 2Ag
+
(aq)
K
c
= 2
1
2
k
k
(By reaction (i) and (ii)
CHEMISTRY
Code-A Page # 5
=
4 6
2
12 4
) 3 . 0 ( 10
) 1 . 0 (
10 ) 1 . 0 (
1 . 0

= 810 ]
Q.2
[Sol.
spin
= 2.8 BM
so unpaired electron = 2
Li
2
+
B
2
/C
2
+2
B
2

C
2
N
2
O
2

N
2
2
/O
2
unpaired e

1 2 1 0 0 1 2
Ans. 4 ]
Q.3
[Sol.(a) K
sp
= [Mg
2+
][OH

]
2
[OH

]
2
= 10
10
[OH

] = 10
5
[H
+
] = 10
9
pH = 9
(b) AH AG = PdV + VdP
AH AG = VdP
= 1 [70 40]
= 30 bar hit = 3000 J = 3 kJ
(c) For zero order t
1/2
o a
(d) Pb U
206
82
236
92

8 'o' and 6 '|' particule are emitted.]
Q.4
[Sol.
O
OH
OH
H
C
C

OH
(Phenol salt with Na, NaOH)
(Carboxylic acid form salt
with Na, NaOH, NaHCO )
3
(Alcohol form salt with Na)
(
F
o
r
m

s
a
l
t

w
i
t
h

N
a
)
]

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