Sol Aits 2013 FT I Jeea Paper 1

AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/13
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1

ANSWERS, HINTS & SOLUTIONS
FULL TEST I
(Paper-1)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
C A D
2.
C A A
3.
A B B
4.
C C A
5.
D B D
6.
C C B
7.
A D B
8.
A C B
9.
C, D
A, C, D
A, C
10.
A, C
A, C
A, B
11.
A, C
A, B, C
B, C, D
12.
A, B, C, D
A, B
A, C
13.
A B B
14.
A A C
15.
C B D
16.
B D B
17.
D A B
18.
A D A
1.
(A) (s)
(B) (p)
(C) (p)
(D) (q, r)
(A) (p, r, t)
(B) (q)
(C) (r, s)
(D) (r, s)
(A) (p, q, r, s)
(B) (p)
(C) (q, s)
(D) (p, r)
2.
(A) (r)
(B) (q)
(C) (q)
(D) (s)
(A) (p, q, s)
(B) (p, s)
(C) (r, s)
(D) (q, t)
(A) (s)
(B) (t)
(C) (q)
(D) (s)
A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

FIITJEE JEE(Advanced)-2013
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5

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2
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1
2


2
P Ph hy ys si ic cs s PART I

SECTION A

1. E
2
=
2 2 2
R L C R
V (V V ) V 0 + = +

As, E = V
R

V
R
= V = 220 V
I =
E 220
2.2
R 100
= = amp

3. Equivalent circuit can be drawn as
Equivalent capacitance =
79
C
30
.

C
2C
C C
8/3C
C C
C
C
C
C
C
C
2C
C
C
C C
2/3C
2C
2C
C
19C/11

4. This is simply discharging of a capacitor.

t / CR
0
q Q e
= where C = 4
0
r

5. When the circuit will reach to steady state the inductor will given zero resistance. Hence the entire
current will only pass through it.
6. X =
H 2H 3H
2 2
+
=

8. Here V 1/r
r distance between Sun and Planet.

9.
2 2
(y h) x h + + = A

2 2
dy x dx
0
dt dt
x h
+ =
+

2 2
dy x dx
dt dt
x h
=
+

A
dy 3
v
dt 5
=

y
x=3cm
h
=
4
c
m
A
B
h = 3 m
h

=

4

m

B A
3
| u | v
5
= (i)

2 2
2
A
2 2 2
d y h
v
3
dt (x h )
2
=
+

2
B A
3
16
a v
(5)
=

3

2
B A
16
a v
125
= (ii)

10. Mg T = Ma (i)
T = ma (ii)
Solving (i) and (ii)

Mg
a
(M m)
=
+

FBD of man
Mg N = Ma

Mmg
N
(M m)
=
+

N
a
Mg
11.
2 m
T 3.14
qB
= = s.

4
C Ch he em mi is st tr ry y PART II

SECTION A

1.
Et
( )
3
1 O
O
H
O
Et
( )
( )
2 4
4
2 Ag O/NH OH
2 NaBH
H
+
O
O
Et
O
OH
OH
Et

2.
C
O
C
O
O
5
PCl
C
C
O
O
Cl
Cl
4
LiAlH
CH
2
OH
COO
PCC
CH
2
OH
CH
2
OH
CHO
CHO
OH

3.
C
C
C
C
C
H OH
H OH
O H H
H OH
H
CH
2
OH
O
1
2
3
4
5
6
and
C
C
C
C
C
O H H
H OH
O H H
H OH
H
CH
2
OH
O
1
2
3
4
5
6

Cyclic forms of diastereomers that differ
only in the configuration of C1, are known
as anomers.
The configuration differ only at carbon no. 1.

4. For equimolar solutions, n
1
= n
2

1
x 0.5 and 0.5 =

o
B B B
P x P 0.5 160 80 mm = = =

o
T T T
P x P 0.5 60 30 mm = = =

Total
P 80 30 110 mm = + =
Mole fraction of toluene in vapour phase =
T
Total
P 30
0.27
P 110
= =

5. Entropy is a state function, i.e. the change entropy depends upon the initial and final states of the
system and not on how that change is brought about.


5
7.
o
0.6
o
0.4
d orbitals in symmetrical
field of ligands
4
high spin d configuration
in an octahedral field
CFSE = 3(- 0.4)
o
+ 0.6
o
= - 1.2
o
+ 0.6
o
= -0.6
o

8. Given
( )
13
sp
AgBr
K 5 10
=

3 3
KBr AgNO AgBr KNO + +
Given, [AgNO
3
] = 0.05 M

3
Ag NO 0.05M
+
( ( = =

( )
sp
Ag Br K AgBr
+
( ( =

13
0.05 Br 5 10

( =

13
11
5 10
Br 1 10 M
0.05
( = =

| |
11
Br KBr 1 10 M

( = =

11 9
wt. of KBr 1 10 120 1.20 10 gm/ litre

= =
10.
Br Br
H
H
Plane of symmetry

11. (A) ( ) ( )
( )
2
anh.ZnCl
2 2 conc.HCl
Ph CH OH Ph CH Cl Zn OH Cl immediate
white turbidity
+

( ) ( )
Lucas reagent
3 2 3 2
CH CH OH CH CH Cl Zn OH Cl slow +
(B) ( ) ( )
( )
Lucas
2 2 reagent
Ph CH OH PhCH Cl Zn OH Cl immediate
White turbidity
+

Lucas
reagent
Ph OH No reaction under normal condition
(C) ( ) ( ) ( ) ( )
( )
Lucas
3 3 reagent 2 2
CH CH OH CH CH Cl Zn OH Cl Moderate rate
White turbidity
+

( ) ( )
( )
Lucas
3 2 2 2 3 2 2 2 reagent
CH CH CH CH OH CH CH CH CH Cl Zn OH Cl Slow
White turbidity
+


6
12.
2 3 2 2
H S O H O S O + + +

3 4 2
PbS 4O PbSO 4O + +

2 3 3
3SO O 3SO +

2 3 4 2
3SnCl 6HCl O 3SnCl 3H O + + +

13.
2 2
Zn Fe Fe Zn
+ +
+ +

o
eq
0.0591
E E logK
n
=
Given, E = 0.2905

o
0.0591 0.01
0.2905 E log
2 0.001
=
0.02905 + 0.0295 log10
= 0.2905 + 0.0295
= 0.32

o
eq
0.0591
E logK
2
=

eq
0.0591
0.32 logK
2
=

0.32
0.0295
eq
K 10 =

14. For 1 mole of O
2

2 2
2
2
O 2O i.e. 3O
3

| |

|
\ .

Or
4
3
mol of Al to change into Al
+3
ions.
n = 4
Thus, G nEF =

G 827000
E 2.14 volt
nF 4 96500
+
= = =

15.
o
cell eq eq
0.059 1.1 2
E logK 37.2881 logK
2 0.059
= = =

37
eq
K 1.9 10 =

16. Copper sulphate when reacts with hypophosphorus acid, gets reduced to cuprous hydride.

4 3 2 2 2 2 3 4 2 4
4CuSO 3H PO 6H O 2Cu H 3H PO 4H SO + + + +

17.
( ) ( )
( ) ( ) ( )
4 2 2 2 3
2 2
3Ba OH 2P 6H O 3Ba H PO 2PH
J L K
+ + +

( )
( ) ( ) ( )
2 2 2 4 4 3 2
2
Ba H PO H SO BaSO 2H PO
L N M
gives apple
green colour in
the flame
+ +


7
18. H
4
P
2
O
7
(pyrophosphoric acid) is a tetrabasic acid, i.e. 4-hydroxyl groups are present. It is
prepared by removing one water molecule from two molecules of orthophosphoric acid. Each
phosphorus atom lies in same tetrahedral environment, so called isopolyacid.

+ O H P
O
OH
OH
P
O
OH
OH O H
2
H O
O H P
O
OH
P
O
OH
OH O

SECTION-B

1. (A)
C H
3
CH
Br
COOH
( )
( )
1 OH
2 H
+
C H
3
CH
OH
COOH
(B)
C H
3
CH
Br
CH
2
COOH
( )
( )
1 OH
2 H
+
C H
3
CH CH COOH

(C)
H
2
C
Br
CH
2
CH
2
C
O
OH
OH
H
2
C
Br
CH
2
CH
2
C
O
O
O
C
O
(D)
H
2
C
Br
CH
2
CH
2
CH
2
C OH
O
OH
O
C
O
Reactions A, C, and D show S
N
2 reactions.

2. In case of (A), compound given in (A) exchanges H with D and becomes racemic.
In case (B), compound in (B) reacts through a carbocation and gives racemic mixture.
In case of (C), no bond attached to the stereocentre breaks in reaction of (C), so retention.
In case of (D), compound in (D) gives Hoffmann elimination and it is an example of anti-
elimination. Product does not have any stereogenic centre.

( ) d, form A C H
3
D
C
2
H
5
OH ( ) Reaction B gives

C H
3
D
C
2
H
5
COOH ( ) Reaction C gives

( ) Reaction D gives
C H
3
CH
3
( ) No stereocentre


8

M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. We must have f(a
2
+ 2a + 5) > f(a + 11)
a
2
+ 2a + 5 < a + 11
a (3, 2)
a can take values 2, 1, 0, 1

2. ABC is equilateral
a = b = c

3. AC
2
= AB
2
+ BC
2
.. (1)
BD
2
= BC
2
+ CD
2
.. (2)
CA
2
= CD
2
+ DA
2
.. (3)
DB
2
= DA
2
+ AB
2
.. (4)
Equation (1) + (3) and (2) + (4) gives AC = BD
So, equation (1) and (2) give AB = CD and equation (2) and (3) give BC = AD
So s CBD and ADB are congruent CBD = ADB = 90 ABD
CBD + ABD = CBA DB lies in the plane of ABC, so the points are coplanar

4. Let a d = 3t; then bc = (d + zt)(d + t) = d
2
+ 3td + 2t
2

Also
a 3t
1
d d
= + , so
2 2
3t
hk d 1 d t 3td bc
d
(
= + = + <
(

bc > hk

5. Clearly P (1, 2)
Equation of tangent at P is 4x(1) + y(2) = 8
A (2, 0) and B (0, 4)
Similarly normal at P is 2x 4y = 6
A'( 3, 0) and
3
B' 0,
2
| |
|
\ .

B
P
A
B
A
Area
0 4 1
1 5
BPB' 1 2 1
2 4
3
0 1
2
= = and Area APA' 5 =
Ratio = 4

6. As sin x + sin y cos cos x x R
Let x
2
= sin y 1 sin y = 1
1 + sin x cos cos x
cos cos x sin x 1

2
cos 1 1 + = cos = 0 sin y + cos = 1 + 0 = 1


9
7.
1 1
0 0
sinx x 2
I dx dx
3
x x
= < =

2
I
3
< and
1 1
1/ 2
0 0
cosx
J x dx 2
x

= < =

J < 2

8. Equation of tangent
2
x t y 2ct + = T (2ct, 0) and T
2c
0,
t
| |
|
\ .

Equation of normal
( )
3 4
t x ty c t 1 = ;
3
1
N c t , 0
t
( | |

| (
\ .
;
3
1
N 0, c t
t
( | |

|
(
\ .

3
c
NT ct;
t
= +
3
c
N' T' ct
t
= +

3
1 c c
ct
2 t
t
= +
( )
4
2 4
1 2t
c 1 t
=
+
and
3
1 c
' ct ct
2 t
= +

( )
2 4
1 2
'
c 1 t
=
+

2
1 1 2
'
c
+ =

9. We have
2 2 2
2sin cos x 2sin sin2x
2 2
| | | |
=
| |
\ . \ .

cos
2
x = sin 2x cos x(cos x 2 sin x) = 0
1 2 tan x = 0 as cos x 0
tan x =
1
2
and cos 2x =
3
5

10. Clearly, the point lies on 7x y = 5
Also, centre of the circle must lie on the bisectors of the
lines
x + y + 13 = 0 and 7x y 5 = 0 given by

x y 13 7x y 5
2 50
+ +
= x 3y = 35 and 3x + y + 15 = 0
Let (h, k) be the centre of the circle, then h 3k = 35 ..
(1)
C(h, k)
A
B
x + y + 13 = 0
7x y 5 = 0
P(1, 12)
and 3h + k = 15 .. (2)
Clearly CB is perpendicular BP
k 2
7 1
h 1
h + 7k 15 = 0 .. (3)
On solving, we get centres as C
1
(29 2) and C
2
(6, 3)

2
1
r 800 = and
2
1
r 50 = smaller circle has radius = 50
Therefore area of quadrilateral ACBP =
1
2 50 200
2
(

(

sq. units

11. Let
2
f(x) ax bx c = + + and f(1) = a + b + c < 0 f(x) < 0 for all x R f(2) < 0 4a 2b + c <
0
Again f(3) + f(2) < 0 13a + 5b + 2c < 0
Also f(5) < 0 25a 5b + c < 0 5b 25a c > 0


10
12.
( )
( )
2
(x x) x 0 ; x 0
f(x)
x x x 2x ; x 0
= <
=

+ =

f is continuous and differentiable
Again
0 ; x 0
f '(x)
4x ; x 0
<
=

f(x) is continuous but not differentiable at x = 0

13. Taking B as origin, BC as xaxis and A as (h, k) and
C(4, 0)
We have D (2, 0) and E
h 4 k
,
2 2
+ | |
|
\ .

K
2
+ (h + 4)(h 2) = 0 .. (1)
Also AC = 3 (h 4)
2
+ k
2
= 9 .. (2)
And area =
1
4 K 2K
2
=
y
E
B (0, 0)
A(h, k)
C(4, 0) D
x
Solving (1) and (2), we get
3
h
2
= and
11
K
2
=
ABC = 11

14. Let AD be angle bisector
AB BD
AC DC
= c = 2b
Now b + c > a b + c > 6 b + 2b > 6 b > 2
Again
2 2
2
b 4b 6
1
4b
+
< b < 6 b (2, 6) and consequently c (4, 12)

15.
BE 3
EC 4
= , take BE = 3K and EC = 4K
A must be (3K, 6)
Now equation of line BA is
6
y x
3K
=
Ky 2x = 0
Since perpendicular from c on AB = 7
y
E
B
A(3K, 6)
C(7K, 0) E
x
y
x

2
0 14K
7
K 4
=
+

2
4
K
3
=
Now
( ) ( )
2 2
2
c 6 0 3K 0 = + = 36 + 9K
2
= 36 + 12
c 48 4 3 = =

1618. Let
1
0
12 yf(y)dy a =
and ( )
1
2
0
20 y f(y) dy 4 b + =

2
f(x) ax bx = + f(y) = ay
2
+ by
( ) ( )
1 1
2 2 2 2
0 0
f(x) 12x y ay by dy 20x y ay by dy 4x = + + + +

=
2
a b a b
12x 20x 4x
4 3 5 4
| | (
+ + + +
|
(
\ .

a = 3a + 4b a = 2b .. (1)
and 4a + 5b + 4 = b a + b = 1 .. (2)
a = 2, b = 1

2
f(x) 2x x = +

11
SECTION B

1. Clearly we have
2 ; x [ 2, 1)
f(x) 1 ; x [ 1, 0)
x ; x [0, 2]

and g(x) = sec x; x R (2x + 1)

2

We have
( )
2 ; sec x [ 2, 1)
fog x 1 ; sec x [ 1, 0)
secx ; secx [0, 2]

( )
{ }
4 2 2 4
2 ; x , , ,
3 3 3 3
fog x 1 ; x ,
secx ; x ,
3 3
( (

( (

= =

(

Limit of fog exist at x = , , 1, points of discontinuity of fog are , and points of
differentiability of fog are
5
1,
6

Again
{ }
{ }
sec( 2) ; x [ 2, 1)
2
g(f(x)) sec( 1) ; x [ 1, 0)
secx ; x [0, 2]
2

Limit of g(f(x)) does not exist at x = 1

2. (A) Let E
i
; i = 1, 2, 3, 4 represents the events that the bag contains I white balls: Clearly
( )
i
1
P E
4
= . Let W be the event that the ball drawn is white then,

( )
( )
i
i
W 1 1 2 3 4 5
P W P E P
E 4 4 4 4 4 8
| | | |
= = + + + =
|
|
\ .
\ .

Now
( ) ( )
4 4 4
P E P W/ E E 1/ 4 2 p
P
W P(W) 5/ 8 5 15
| |
= = = =
|
\ .
p = 6
(B) Required number of ways
= ( ) ( ) ( )
12 12 2 2 12 3 3 12 12 12
1 2 1 2 3 1 2 12 1 2
C C C 2 C C C 2 C ..... C C 2 C + + + + + + +
=
( ) ( )
12 12 12 12 12 2 12 3 12 12
1 2 3 2 2 2 3 2 2 2
C 2 C 3 C ..... 12 C 2 C C C C ..... C C + + + + + + + +
=
12 12
12 10 11 10
r r 2
r 1 r 2
r C 12 C 12 2 12 11 2
= =
+ = +

= 13 2
10
12 = 13 2
10
m m = 12
(C)
5x 5y 5z x y z
5
2 x 2 y 2 z 2 x 2 y 2 z
(
+ + = + +
(

=
x 2 2 y 2 2 z 2 2 1 1 1
5 5 3 2
2 x 2 y 2 z 2 x 2 y 2 z
( + + + ( (
+ + = + + +
( ( (

Now apply A.M H.M on 2 x, 2 y and 2 z

12

2 x 2 y 2 z 3
1 1 1
3
2 x 2 y 2 z
+ +

+ +

1 1 1 9
2 x 2 y 2 z 5
+ +

Hence
5x 5y 5z 9
5 3 2 3
2 x 2 y 2 z 5
(
+ + + =
(

Least value = 3
(D) ( )
n 12
2
12 11 2 11 2
K K 1 K 1
K 1 K 1
22!
12 K C C 12 C 12
11! 11!

= =
= =

=
12
21 19 17.....3
12 2 6
11!

p = 6

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AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/13

and g(x) = sec x; x R (2x + 1)

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