liT -2014-PAT -A-LOT -TEST-I-CPM(I)-13

FIITJEE PAT TEST

(CTY 1214 A LOT Batch)
liT - JEE 2014
ANSWERS
SECTION - I (Chemistry)
PART-A
1.
5.
9.
13.

8
8
A
A,C

2.
6.
10.
14.

A
0

A,C,O

3.
7.
11.
15.

A
A
A,C
A,8

4.
12.

8
8
A,C

4.

8.

PART-C
1.
5.

4
6

2.

3.

SECTION - II (Physics)
PART-A
1.
5.
9.
13.

8
C
8
8,C

2.
6.
10.
14.

A
C
C
A,C

1.
5.

3
3

2.

3.
7.
11.
15.

A
C
A,8,C,O
8,C

4.
12.

C
C
A,C,O

4.

A
A
C,O
A,8,O

4.
8.
12.

C
C
C,O

4.

8.

PART-C
3.

SECTION - III (Mathematics)

PART-A
1.
5.
9.
13.

A
A
C
A,8,C

2.
6.
10.
14.

8
8
8
A,8

3.

7.
11.
15.

PART-C
1.
5.

FIITJEE

6
4

2.

3.

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HINTS & SOLUTIONS

Section - I (Chemistry)
PART-A

1.

Sol.

Kp =Kc(RTtn
2

:.1.3 x 10-

~n=2-3=-1

= Kc (0.0821

x 1000t

Kc = 1.067
2.

2HI(g)~H2

(g)+I2

Sol.

I-a
(~ Pr
K =---

3.

Sol.

(NH4\

)2
fj(

=>~=2
I-a

=> a=

P:

(l_a)2

(g)

'\j"'"p

2JK;

1+2JK;
(g) + CO2 (g)

C03 (s)~2NH3
2P

+ H20(g)
P

Total Pressure = 4P = 0.42

P = 0.105

Kp =(2P)2 xPxP
Kp

Sol.

2HI ~

H2 + 12

I
I - .22

0
.11

K
5.

= 4.86 x 10-4 atm44.

0
.11

=[HJ[IJ=0.IIXO.II=0.OI99
c
[HIt
(0.78)2

B
S8 (g)

Sol.

4S2

(g)

Initially

At equilibrium

(1- .30)

4x0.30

Kp

(p;,

0.70 atm

(1.2f
=-( P ,) =-( 0.70
-) =2.96

1.2 atm

atm

s,

6.
Sol.
7.
Sol.

A
Those reaction which have more value of K proceeds towards completion.
A
For the given equilibrium

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2AB2 (g)
Initially

al2

At equilibrium

L:n

~2AB(g)+B2(g)

(I-a)

= 1 +-a
2

a
a is small compared to unity, so 1- a =:: 1 and 1 + -

Since,

=::

2
3

. K

8.

Pa
2

=_T_

PCI 5 ---"
..-Sol.

(I-a)

Use the relation

a
neqw . = 1 + a

(vapour density) initial

nequilibrium

(vapour density) equilibrium

=---

ninitial

104.16 1+a
--=-71
1

a =46.7%
9.

Sol.

K =
p

(pso,
(

)2(
)
p.~o, Po,

Now, Kp =

(0_.3_3~1)_2
_=
(0.662)2(0.101)

=__

(pso,
(p )(p )
so,

Then Po
10.

Sol.

2.5

a,

1
1
== 0.4 atm
Kp
2.5

=:: -

+ B

Initially

At equilibrium

(1- .8) (1- .8)

'K

.. c

~C+D

.8

.8

_[C][D]=0.8xO.8=16
[A][B]
0.2xO.2

11.

A, C

Sol.

The degree of dissociation cannot be calculated from the vapour density data when the number of
moles remain unchanged before and after reaching equilibrium.
A, C

12.
Sol.
13.

Pressure does not disturb equilibrium state because b.n =

forward and backward reaction equally.
A,C

Sol.

':Kp =Kc(RTt'

14.

A, C, D
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K p = ( PH,O

Sol.

':Kp=KC(RT)Z

':~n=2

K = [H 0J
C

15.

A, B

Sol.

Doubling the volume would reduce the pressure and shift the equilibrium in the direction where there
is more number of moles of gases.

1.

Sol.

e(s)+e02(g)~2eO(g)

PART-C

- ( P;o

r -~-

--(p'co, ) -I -

2.

Sol.

According to Le-chatlier's principle, when the temperature is increased, the equilibrium shifts in the
direction of the endothermic reaction. When the pressure is increased, the equilibrium shifts in the
direction of less number of moles. The removal of a reactant and addition of product shift the
equlibbrium in the backward direction.
1

3.

A
Sol.

K
c

[e][D]
[A][B]

=(2/V)2
(2/V)2

~e+D

Initial moles

At equilibrium

(4 -2)

(4 -2)

=1

4.

Sol.

.,' The unit of K

5.

Hence ~n = 2
6

c is molz [2,

N204
Sol.

+B

Initially

(g)

2NOz

(1- 0.2)

At equilibrium

(g)

2 x 0.2

Total moles
1.2
Now PV=nRT

P x I x R x 300
I
P =6 atm

= 1.2 x R x 1500

Section - III (Mathematics)

1.

Sol.

If a, b>O, then x

a,y,z,b

in G.P.

= A.M.

=> x = --a+b .... (1)

2

b)1/3

=> b = ~ = ar =>r = ( -;;

b )1/3

~ = Y = ar = a ( -;;
FIITJEE

of a and b

= (a

b)

113

,~

= z = a/ = a

( b )Z13
-;;

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= ( ab
And

2)113

3
3
2
2
. This => y +z =a b+ab =ab(a+b) ...(2)

XYz=( a;b)(a2bt3.(ab2t3

=(a+b)ab=!(/+/),
2 .
2
2.

Sol.

Given

by (2)

=>/+/

xyz

=2

x,y,z in G.P. and so / = xz

1 , 1+ logy
1 , 1+ logz
1
in H.P. => 1+ logz.1 + logy, 1+ logz in AP. => logx, logy, logz in
1+ logx
AP.

=> 210gy = logx + logz => /

3.

Sol.

222
1.3 +2.5 +3.7 + ...

= xz,

which is true

Series formed by first factors is

1+ 2 + 3 + ...1n = n. Series formed by second factors is

2 2
3 +5 +i +...1" =[3+(n-I)2J
=(2n+lr,
Sn = I,ln = I,n.(2n + 1)2 = I,n( 4n + 4n + 1) = 4I,n3 + 4I,n2 + I,n
2

=4[~(n + 1)]2 + in(n + 1)(2n + 1)+ ~(n+ 1) =

262
This
4.
Sol.

=> S 20 = (20x 21)2 +3.x

20x 21 x 41 + lOx 21 = 188090
3

a,a
,a 3 ,...,a n are in H.P.
I
2
This

=> ~,~,~,
.... ,_1 are in AP. with common difference
aJ a2 a3
an

=d

1 1
1
1
1
1
a-a
a -a
:. d=---=---=
...
or d=_I __ 2 = 2
3
a2 aI a3 a2
an an-I
aa
a
a
I 2
23
=>daa
=a
-a
,daa
=a
-a,
....,daa
=a
-a
2
2
I 2
1
2 3
3
n n-I n-I n
Adding, d(aa +a a +....+a a )=a -a
....(1)
1 2
2 3
" n-I
1
n
Also

= n-I

-I-a

anan-I

n. This =>

a -a

T =-=-+(n-l)d=>
n an aI

Put this in (1),

_I_n =(n-I)d
aa
n I

a1a2 +a2a3 +...+anan_1=(n-l)a a

n

5.

Sol.

x + y + z = 15...(1),9,x,y,z,a
S"

=~(a+l)

in AP. with common dif. = d

gives

5
9+(x+ y +z) +a =-(9+a)
2

=> 2(9 + 15 +a) = 5(9+a)

=> a = 1. same result is obtained with the second result.

6.

Sol.

3 3
3
1 1 +i
1 +i+33
-+--+----+
1
1+3
1+3+5

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T =

I' +2' +3' + ...+n'

1+3+S+

[i(n+l)r

..... nterms

= (n+I)'

~[2+2(n-I)J

8 n ='l.:.Tn => 48n = 'l.:.(n+1)2 ='l.:.n2+2'l.:.n+n

n
n
=>48n =6'(n+l)(2n+l)+2'2(n+l)+n
= ~(n+ 1)[2n + 7] +n
6

If n = 168
,

16

7.

Sol.

Let the numbers be

a+ar+a/

+.!i = 446
4

= 16x17x39
6x 4

=14

a,ar,ar

...(1)

(a + 1),( ar + 1),( ar
2(ar+I)=a+a/

-I) are in A.P.

.... (2)

Solving (1) and (2)

We get the answer 8.
8.

Sol.

8 = 1+ 2 +3 + .... +n =~(n+ 1)
2

8+669=(n-8r

By assumption,

or

~(n+I)+669=n2+64-I6n

or,

n2-33n-I2IO=0

or

(n - SS) ( n + 22) = 0 .'. n = S5 .

n

55(56)

Total number of balls = -( n + 1) =

9.
Sol.

-1540

150,146, I42, ....,a = I50,d = -4.

Suppose 150 workers complete work in n days

1 worker does In one day --th part of the work.

I50n

Under condition II, workers complete the work in

=( n ;8)[

2x I50+(n +8-1)(

Total workers. --

ISOn

(n + 8) days.

Total workers

-4)J = (n+8)(136-2n)

= 1 => (n + 8)(136 - 2n) = I50n

2
=> (n+ 8)( 68- n) = 7Sn => n + ISn-544

=0

(n + 32) ( n - 17) = 0 => n = 17 => n + 8 = 17 + 8 = 25 days.

10.

Sol.

6.6.6 ....n terms = 6+6.10+6.10 +6.10

6.(JOn

-1) =~(10n

JO-I
Similarly

+ ...n terms = 6[1+10+102

+103 + ..... mtermsJ

-1)

8.8.8.8 ....n terms

= %( JOn -1)

-I)r

+~(IOn -1)

Given sum
FIITJEE

[%(IO

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=~[(lOn -If +2(lOn _1)]=~(102n -1)11.

Sol.

x,x

+ 2, / + 10 in G.P.

=:>( /

+2

f =x.( /

+ 10) =:>/

+ 2, /

+4+4/

=/

lOx

=:>4x -10x+4=0=:>x=2,x,x2

C,O

+ 10 = 2,6,18 if x = 2 ... (1) and .!.,2,!!

2 4 8

if

x =.!.

...(2)

Next term of (1) is 18x 3 = 54

Next term of (2)

. 81

IS

-x-

12.

C,O

Sol.

.
H
4
By assumption, - =-

729
16

5(2ab)
a+b

r;- 4"ab

=:> 5H = 4G =:>

=:>

=-

5J;;E = 2 ( a + b) =:> 5 = 2 ( K + ~),

K = (~

(a)I/2
-

1
=:>2K2 -5K+2=0=:>K=2,-.lfK=2,then
2

13.
Sol.

where

=2 or-=-.

.
Thls=:>a:b=4:1

or 1 : 4
A, B,C
Last term of nth row
= 1+ 2 +3 + ... +

n = -n(n
2

I)

As terms in the nth row forms an A.P. with common difference 1.

First term = last term 1=lastterm

a = first
Sum =

term =

(n-l)(1)

=~(n2 -n+2)

-(n+l)
2

~(n2 - n + 2)

-(a+l)
2

=:> Sum =

=~n[~(n2

-n+2)+~(n2

+n)]

=~n(n2 +1)
14.

A,B

Sol.

We have S=--=
1-1/3

1/3

(A) Thus, (0.25yog,(S) = (0.5)210g,(1/2)

= (0.5(IOg,(2) = (0.5f2
(B) (0.008)=(0.2)2

,=C~J

= 4,

= 53

g
(0.008yo s(S)= (0.008tOgs2 =(5-3tOgS2 =(5)3108,2

=i =8
15.

A, B, 0
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Sol.

(a_b)2 +(b-C)2 +(c_a)2

1.
Sol.

+(a_l)2

+(b-ll

+(c_l)2

=0

PART-C
Given SZn = 3Sn in AP.

= 3~[2a+(n-l)dJ

:::)2n[ 2a+ (2n -l)dJ

:::)2a = ( n + I) d
:::) S3n = 3n[2a+(3n-l)dJ+~[2a+(n-l)dJ
Sn

=3.(4nd)=6
2nd
2.
Sol.

6
Given

al,aZ,.....,aIO in AP.

hi' hz, ...,hlo in H.P

... (1)

al =hl =2 ...(2) alo =hlo =3

...(3) a4h7 =?

a10 = aI + (10 -1) d :::)3 = 2 + 9d U d = !

9
3

a =a +3d=2+-=-.
4
I
93
_I =~+(IO-l)d
h10

Now(1)

1 1
hhh

:::)-,-,I

:::)~=!+9d

hI

hI = 2"I + (7 - I) d = 2"I + 6 ( - 54I)

l

arelnAP.

:::)d = __1
I

7
= 18

54

:::)\

18
=7

h =~.~=6
4

3.
Sol.

3 7

6
Four numbers are a, b, c, d.
According to problem, a, b, c in AP. with

a = 6 and b,c,d in G.P. with common ration = -1

2

b b
b b
:. b,c,d = b,-,-z = b,-,2 2
2 4
:. a,b,c,d = 6,b,~,~
242

(1). Now 6, b, ~ in AP.

:::)2b = 6 + ~:::) b = 4. Again b,~,~ in G.P. :::) (~)Z

2
24
2
4.

Which is true. Put b

2

Sol.

x,y,z

= b.~

= 4 in (1), we find a, b, c, d = 6,4,2,1.

are In H.P. :::) Y

= --,2xz

Now

x+z

log(x

+ z) + log(x+z -2y) = log(x+ z)+ log [ x+ z --- 4XZ]

= log(x + z) + log

r-

x+z

z ); = log(x + z) + 2log(x - z )-log(x + z)

x+z

= 2log(x -z)
5.

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