Professional Documents
Culture Documents
NEWS
Graphene gets ready
for the big time
Physicists are talking about how to make practical
use of a former laboratory curiosity.
PITTSBURGH, PENNSYLVANIA has properties that make it alluring for certain
Physicists are in the grips of graphene applications. Electrical charge can fly through
madness. At last week’s American Physical the sheets at high velocities, up to four times
Society meeting in Pittsburgh, Pennsylvania, those in silicon. Large thin layers of graph-
they packed conference rooms to hear about ene would be both flexible and transparent.
the atom-thick sheets of honeycombed car- Graphene ribbons might act as transistors,
bon. Talks on graphene transistors, chemical even though bulk graphene does not. And
sensors, electrodes, scales and frequency gen- because graphene is so thin, even the slight-
erators could all be heard, with participants est brush from neighbouring atoms can alter
from industry, notably IBM, in many of the its mechanical and electrical properties. “It
sessions. has been a fascinating material,” says Marcus
The ultra-thin carbon sheets have turned Freitag of IBM’s T. J. Watson Research Center
the normally staid community into “a herd in Yorktown Heights, New York.
of rhinos”, says Andre Geim, a physicist at the
University of Manchester, UK. And, he adds, Silicon transplant?
“this year, I feel more like applications are what’s To turn graphene applications into reality,
driving the field.” the material must first be synthesized in large
Not everyone is sanguine about graphene’s quantities. Until now, it has often been grown
chances for going commercial. Graphene has on substrates of silicon carbide, a costly mate-
several problems, notably a lack of an obvi- rial that is available in only limited quantities
ous ‘band gap’, a break in electron energy from suppliers. But at last week’s meeting, sev-
levels that would allow it to be easily used as eral new techniques were on display, includ-
a transistor, says Kenneth Shepard, an elec- ing a way to grow graphene through chemical
trical engineer at Columbia University in vapour deposition, a process widely used in
New York. “There are a lot of problems with the electronics industry. In one session, Byung
this stuff,” he warns, fearing that starry-eyed Hee Hong of Sungkyunkwan University in
researchers may overhype this South Korea reported using the Sheet happens: graphene could have potential
latest material. “There have been technique to grow films up to uses in solar cells or flexible displays.
But others argue that graphene great advances in 10 centimetres in diameter — a
is much more promising than its figure he soon hopes to double. frequencies allow for more bandwidth, and
A. WEE, NATL UNIV. SINGAPORE/H. HUANG ET AL. ACS NANO 2, 2513–2518 (2008)
predecessor, carbon nanotubes. making large-scale “There have been great advances that means graphene could pave the way for
Nanotubes, essentially rolls of graphene.” in making large-scale graphene,” broadband satellite communication. In early
graphene, have been difficult to Freitag says. experiments on display at the conference, Han
control and integrate into existing electronics, While some researchers work on making Wang, one of Palacios’s graduate students, pre-
says Tomás Palacios, an electrical engineer at more graphene, others hunt for ways to use it. sented data up to one megahertz (106 Hz), but
the Massachusetts Institute of Technology in The most immediate application would be as Palacios is bullish: “We should be able to have
Cambridge. Graphene’s uniformity and flat- a simple electrode. Although transparent elec- competitive devices just a few months from
ness make it easier to combine with current trodes using materials such as indium tin oxide now,” he says.
silicon technology, and many researchers who are already commercially available, graphene’s Whether graphene can replace silicon as the
once worked on nanotubes are now focusing flexibility would give it an edge in solar cells basic unit of the electronics industry is another
instead on graphene. The shift was evident at and displays, says Philip Kim, a physicist at question; its lack of a band gap is a formidable
this year’s meeting: there were 16 sessions on Columbia University. problem. The most obvious solution is to cut
nanotubes, whereas graphene had 28. Graphene also shows promise for broad- the material into ribbons, which have discrete
Work on graphene — discovered by Geim band communications, in part because elec- energy levels. But, as several groups showed in
and his colleagues almost 5 years ago (K. S. trical charge can move so quickly through it. Pittsburgh, cutting the sheets creates a jagged
Novoselov et al. Science 306, 666–669; 2004) Graphene transmitters and receivers should be edge of dangling chemical bonds that can pick
— heated up quickly as researchers realized able to operate at frequencies on a scale of hun- up unwanted contaminants. Xinran Wang of
that the material’s two-dimensionality caused dreds of gigahertz (109 Hz) or even terahertz Stanford University in California reported
it to show unusual quantum behaviours (see (1012 Hz), far better than silicon, which oper- some success in using ammonia and other
Nature 438, 201–204; 2005). But graphene also ates at several gigahertz, says Palacios. Higher compounds to dope the edges of the graphene
390
© 2009 Macmillan Publishers Limited. All rights reserved
NATURE|Vol 458|26 March 2009 NEWS
391
© 2009 Macmillan Publishers Limited. All rights reserved