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S BLOCK ELEMENTS 1. The number of nucleons in D2 molecule (A) 6 (B) 5 2. The mass of tritium oxide is (A) 18 amu (B) 20 amu (C) 4 (C) 22 amu (D) 3 (D) 24 amu

3. When same amount of Zn is treated separately with excess of H 2SO4 and excess of NaOH solution, the ratio of hydrogen gas produced is (A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) 9 : 4 4. The oxide that gives hydrogen peroxide (H 2O2 ) on the treatment with a dilute acid (H 2SO4 ) is [Pb. PMT 1999] (A) MnO2 (B) PbO2 (C) Na2O2 (D) TiO2 5. What is the product of the reaction of H 2O2 with Cl 2 [Rajasthan PET 2003] O (A) 2 + HOCl (B) HCl + O2 (C) H 2O + HCl 6. In lab H 2O2 is prepared by (A) Cold H 2SO4 + BaO2 (C) Conc. H 2SO4 + Na2O2 7. Hydrogen cant reduce the (A) Hot CuO (B) Fe2O3 (B) HCl + BaO2 (D) H 2 + O2 (C) Hot SnO2 (D) Hot Al2O3

(D) HCl + H 2

8. The total number of protons, electrons and neutrons in all three isotopes of hydrogen is (A) 7 (B) 8 (C) 9 (D) 10 9. Decomposition of H2O2 is prevented by (A) NaOH (B) MnO2 (C) Acetanilide (D) Oxalic acid

10. Which one of the following illustrates the structure of hydrogen peroxide?

H
(A) HOOH (B)

O 90 90 O H

94 O
(C)

H 45
(D)

H 97

O 97 O H

45 O

From Q11 to Q14, given Table and paragraph is given for different isotopes of Hydrogen. Chemically heavy water is deuterium oxide (D2O) . It was discovered by Urey. It has been finding use in nuclear reactors as a moderator because it slows down the fast moving neutrons and therefore, helps in controlling the nuclear fission process. Generally heavier isotopes form stronger bond.

Some physical constants of H2O and D2O.

Boiling point (K) Dielectric Constant Ordinary water H2O 373.2 82 Heavy water D2O 374.4 80.5

11. Out of the following, which one is more stable?

H3C C H3C
+

CD3 CH3

(I)
CD3

D3 C

(II)

(A) I 12. Heavy water freeze at (A) 0oC

(B) II (B) 3.8oC

(C) Both are equally stable (C) 3.8oC (C) 7 and 6.85 (C) same in both

(D) cant say (D) 273.15oC (D) 6.85 and 7 (D) depend on temperature

13. The pH of D2O and H2O at 298 K respectively (A) 7 and 7 (B) 7.35 and 7 14. The solubility of NaCl is (A) larger in D2O (B) larger in H2O

From Q15 to Q19, paragraph is given for different type of Hydrides. When hydrogen combine with other elements, hydride are formed. Depending upon the properties of these hydride, these are three main type of hydride, ionic hydride, molecular hydride or covalent hydride and metallic or interstitial hydrides. If E is the symbol of an element then hydride can be expressed as EH x (e.g., MgH2) or EmHn (e.g., B2H6). Ionic hydrides are stoichiometric compounds of dihydrogen formed with most of the s-block elements which are highly electropositive incharacter. Dihydrogen forms molecular compounds with most of the p-block elements. Most familiar examples are CH 4, NH3, H2O and HF. For convenience hydrogen compounds of nonmetals have also been considered as hydrides. Being covalent, they are volatile compounds.Metallic hydrideThese are formed by many d-block and f-block elements. These

hydrides conduct heat and electricity though not as efficiently as their parent metals do. Unlike saline hydrides, they are almost always nonstoichiometric, being deficient in hydrogen.
( A) , A will be 15. In the reaction CaH 2 + H 2O (A) Ca(OH)2 + H2O2 (B) CaO + H2

(C) CaO + H2O2 (C) Fe (C) BaH2

(D) Ca(OH)2 + H2 (D) Sb (D) SrH2

16. Out of the following which dont form hydride? (A) Ti (B) Be 17. Most covalent among the following hydride (A) BeH2 (B) CaH2

18. Which out of the following does not decompose into its constituent elements on heating? (A) LiH (B) NaH (C) KH (D) CsH 19. If La forming ccp structure and only 30% of tetrahedral voids is occupies by dihydrogen, then hydride is (A) LaH3 (B) LaH1.33 (C) LaH2.1 (D) LaH1.2 20. If 10 lits of water consist 120 mg of MgSO4, then degree of hardness is (A) 12 ppm (B) 120 ppm (C) 10 ppm (D) 100 ppm 21. The molarity of 20 Volumes H2O2 solution is (A) 3.57 (B) 2.5 22. (C) 1.79 (D) 2.0

Identify the correct statement : (a) Gypsum contains a lower percentage of calcium than plaster of Paris. (b) Gypsum is obtained by heating Plaster of Paris. (c) Plaster of Paris can be obtained by hydration of gypsum. (d) Plaster of Paris is obtained by partial oxidation of gypsum.

23. Alkaline earth metals have a tendency to form the complexes, for example Chlorophyll is the complex of Magnesium, Out of the following, which one has highest tendency to form the complex? (A) Be (B) Ba (C) Mg (D) Sr 24. The compound insoluble in acetic acid is (A) Calcium oxide (C) Calcium hydroxide (B) Calcium carbonate (D) Calcium oxalate (D) Ca(ClO3)2 (D) Calcium

25. Bleaching action of bleaching powder is due to the formation of (A) CaCl2 (B) CaSO4 (C) HOCl 26. For which element crimson colour is obtained in flame test? (A) Sodium (B) Barium (C) Strontium

27. Product on strong heating of K[IBrCl](s) are (A) KBr & ICl (B) KCl & IBr (C) KI & BrCl (D) None of these 28. A substance which gives brick red flame and breaks down on heating giving oxygen and brown gas is: (A) Calcium carbonate (B) Barium Oxlates (C) Calcium nitrates (D) Magnesium carbonates 29. Beryllium forms basic Beryllium acetate (CH 3COO)6Be4O. The number of CH3COO ions linked with each Be atoms are (A) 2 (B) 3 (C) 4 (D) 6

30. Lattice energies of BeF2, MgF2, CaCl2 and BaCl2 are 2906, 2610, 2459 and 2367 kJ/mol respectively. Hydration energies of Be2+, Mg2+, Ca2+, Ba2+, F and Cl are 2494, 1921, 1577, 1305, 457 and 395 kJ/mol respectively. Then which of the compound will be most soluble in water? (A) BeF2 (B) MgF2 (C) CaCl2 (D) BaCl2

From Q31 to Q35, read the given comprehension for S-block and answer the following Questions The trends in properties of alkali metal salts can be explained by using Fajans rule. It is associated with the incorporation of covalent character in ionic bond. It states that smaller cations form more covalent compound and relative covalent and ionic character explain the solubility, thermal stability, hydrolysis and other properties of these salts. Some exception are also there and are be explained by change in lattice energy. 31. Out of the following, which one is correct order of ionic character of following? (A) SrSO4 < CaSO4 < MgSO4 < BeSO4 (B) BeSO4 < MgSO4 < CaSO4 < SrSO4 (C) CaSO4 < BeSO4 < MgSO4 < SrSO4 (D) MgSO4 < BeSO4 < CaSO4 < SrSO4 32. Which oxide is not attacked by water? (A) BaO (B) SrO 33. Which salt does not show hydrolysis at all? (A) Mg(NO3)2 (B) Be(NO3)2 34. Which hydroxide is amphoteric? (A) Be(OH)2 (B) Mg(OH)2 (C) MgO (C) Ca(NO3)2 (C) Ca(OH)2 (D) BeO (D) Ba(NO3)2 (D) Ba(OH)2

35. Among the nitrates of alkali metals which one can be decomposed to its oxide at 500 o C? (A) NaNO3 (B) KNO3 (C) LiNO3 (D) All of these From Q36 to Q40, ONE o MORE than one may be correct. 36. The bicarbonate, which in not exist in solid state? (A) KHCO3 (B) LiHCO3 (C) Ca(HCO3)2 (D) NH4HCO3

37. Out of the following which does not react with atmospheric Nitrogen to form its nitride? (A) Li (B) Na (C) Mg (D) K 38. Out of the following, which do not give characteristic colour with flame? (A) Na (B) Mg (C) Be (D) Ca

39. Which of the following metal carbonate will decompose on heating? (A) K2CO3 (B) Na2CO3 (C) MgCO3 (D) (NH4)2CO3 40. At 0K, hydrogen contains mainly para hydrogen which is more stable, at the temperature of liquefaction of air, the ratio of ortho and para hydrogen is 1:1 and at the room temperature, the ratio of ortho to para hydrogen is 3:1. Then find out the correct statement.

(A) Molar heat capacity of Ortho hydrogen is greater than Para hydrogen. (B) Ortho hydrogen consist parallel spin. (C) Both hydrogen consist similar chemical properties. (D) Pure ortho hydrogen cannot be obtained. NAME: ________________________________________________ DATE: ____________________ 1. 2. 3. 4. 5. 6. 7. 8.
A A A A A A A A B B B B B B B B C C C C C C C C D D D D D D D D

9. 10. 11. 12. 13. 14. 15. 16.

A A A A A A A A

B B B B B B B B

C C C C C C C C

D D D D D D D D

17. 18. 19. 20. 21. 22. 23. 24.

A A A A A A A A

B B B B B B B B

C C C C C C C C

D D D D D D D D

25. 26. 27. 28. 29. 30. 31. 32.

A A A A A A A A

B B B B B B B B

C C C C C C C C

D D D D D D D D

33. 34. 35. 36. 37. 38. 39. 40.

A A A A A A A A

B B B B B B B B

C C C C C C C C

D D D D D D D D