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ANSWERS, HINTS & SOLUTIONS

CRT-I(Set-I)

PAPER -2


ANSWERS KEY
PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1.
A B D
2.
D A B
3.
A C A
4.
C A C
5.
A D B
6.
C A B
7.
A D A
8.
C B B
9.
C B C
10.
B C A
11.
D C A
12.
D D B
13.
A C A
14.
A D C
15.
B B A
16.
C D D
17.
C D A
18.
C B C
19.
A B A
1.
(A) (p, q, r, s)
(B) (p, q, r, s, t)
(C) (q, r)
(D) (q, r, s, t)
A q
B r
C q, r, t
D p, s, t
(A) (p)
(B) (q), (r)
(C) (p)
(D) (q), (r)
2.
(A) (r)
(B) (p)
(C) (q)
(D) (q)
A q, s
B p, q, r, s
C p, r, s
D r
(A) (r)
(B) (s)
(C) (s)
(D) (q)
3.
(A) (s)
(B) (s)
(C) (t)
(D) (s)
A (r)
B (p)
C (s)
D(q, t)
(A) (p)
(B) (r)
(C) (q)
(D) (s)
A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

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2
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4
3

i
n

T
o
p

1
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0
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7
5

i
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T
o
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2
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1
5
9

i
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T
o
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5
0
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R
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3
5
4
2


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2

AITS-CRT(Set-I)-Paper-2-PCM(S)-JEE(Adv)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
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P Ph hy ys si ic cs s PART I


SECTION A

1. V = Es ;
E =
2
2sm
qt


2
2
2s m
V
qt
= = 11.375 Volt

2. Static friction depends on tendency.

3.
A
L
g
4
v

=



B
3L
g
4
v =



B A
v 3v =

4. When impulse of external force is zero.

5
'
sin30 sin60
=



' 3 =
' ' cos30 vcos30 =
cos60 (v ' ') cos60 (2v) v = + = =
= v/ =
40 3
400
0.1 3
= rad/s




30
120

v


6. for x<0
It will oscillate like SHM
Time period
1
m
T
k
=
For x>0
It will perform periodic motion under constant force

2 2
2E
T 2
mg
=
Hence time period
1 2
T T T = +

2
m 2E
T 2
k mg
= +

7.
2
0
0
mv
ev B
R
=

0
mv
B
eR
=
AITS-CRT(Set-I)-Paper-2-PCM(S)-JEE(Adv)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 16, Ph: 46106000, 26515949, Fax: 26513942.
3

2 2
a R b R + =

2 2
b a
R
2b

=

0
2 2
2bmv
B
(b a )e
=



8. Here the total time is given T
Time spent m the region is ( 2 ) +
Hence total time spent

2
T
2
+ | |
=
|
\ .



2 +
2

9. Torque of Internal force is always zero. All other quantities will vary.


17.
B E
F F =
0
I 2k
9 u q
2 r r
| | | |
=
| |

\ . \ .


0 0
I
u

=


If the current a half then to maintain the force
velocity should be increased by two times.

18. If we increase the radius by the times then there is
no need to change m velocity

0
q
2 r

0
qu I
2 r


u

19. If this case the only force is magnetic force

2
0
quI u
m
R 2 r



0
2 rum
R
qI


SECTION - B
1. Adiabatic dQ = 0
Isochoric dW = 0
Isothermal dT = 0 dU = 0

C Ch he em mi is st tr ry y PART II


SECTION A
1.
OH
NH
2
3
CH COOH +
O
-
NH
2
3
OH
||
CH CH OH
O
NH
2
OH
C H
3
OH
-H
2
O
O
N H
2
O
C H
3
N
H
O
OH
CH
3
2
H O

N
O
CH
3
AITS-CRT(Set-I)-Paper-2-PCM(S)-JEE(Adv)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
4
2.

O
O
CH
3
O
H
O
CH
3
O
OH

2
CO

CH
3
O
CH
3
CH
3
O
O
C H
3
O

3.
CN

O
Ph H
O
-
Ph H
CN
CN

C
OH
Ph
CN
H
Ph
O
CN
Ph
OH H
O
-
Ph

CN
Ph
O
-
H
OH
Ph
Ph
O
OH
Ph


4.
3
PhCHO 2NH +
2
3H O +
Ph
N
N
Ph
Ph
3
Hydrobenzamide
As there in no asymmetric carbon in hydrobenzamide, it is optically inactive

5. The rate equation of 3
rd
order reaction is

3
dx
k(a x)
dt
=
As it is cubical equation, the above graph is cubical parabola

6. Na
2
Al
2
SiO
3
. xH
2
O + Ca
2+
CaAl
2
SiO
3
. xH
2
O + 2Na
+


7. The dissociation equilibrium is

2 4 2
2 N O NO
Moles at t = 0 1 0
Moles at eqm. 1 x 2x

( )
( )
2
2 4
2
'
2
'
4
.... i
1
n
NO
p
N O
P
x P
k
P x n

(
| |

= =
|

\ .

1 2 1 n x x x = + = +
On putting values in eqn. (i), we get x = 70.7%
For 50% dissociation x = 0.5
From (i)
P = 780 mm Hg

10. Spontaneous change must have +ve sign for
total.
S

17.
NH
2
H
2
SO
4
/ HNO
3
NH
3
NO
2
NH
3
NO
2
AITS-CRT(Set-I)-Paper-2-PCM(S)-JEE(Adv)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 16, Ph: 46106000, 26515949, Fax: 26513942.
5
18.
NH
2
Br
Br
Br
NaNO
2
/ HCl
N
2
Cl
Br
Br
Br
H
3
PO
2
Br Br
Br

SECTION - B

3. The reaction at high temperature in the blast furnace is

2 2 2 2
2CuFeS O Cu S 2FeS SO + + +


M Ma at th he em ma at ti ic cs s PART III


SECTION A

1. Put x [x] = y
The equation becomes f(y) = (a 2)y
2
+ 2y + a
2
= 0 .. (1)
Here 0 y < 1
Since the given equation has exactly one solution in (2, 3), so equation (1) has exactly one root in
(0, 1).
So, f(0) . f(1) < 0 a
2
(a 2 + 2 + a
2
) < 0 a
2
(a + a
2
) < 0
a
3
(1 + a) < 0 a (1, 0)
If a = 2, 2y + 4 y = 2 (not possible)

2. I =
2
2
2 1
dx
x x x
1 1
1
x
x
| |
+
|
\ .
| |
+ +
|
\ .

put 1 +
1 1
x
x
+ = t;
2
1 1
dx dt
x 2x x
(
+ =
(


= 2
2
dt 2
t
t
=

+ c I =
2x
x x 1 + +
+ c.

3. ( )
( )
3x 3x
d
g x e 3e
dx

> ( )
( )
3x 3x
d
g x e e 0
dx

+ > (g(x) + 1)e
3x
is increasing function
Now (g(x) + 1) e
-3x
> (g(0) + 1) x > 0
(g(x) + 1) > 0 g(x) + x is an increasing function.

4.
2
2 2
2 2
x y xcos ysin
p p
a b
| |
= +
|
\ .

2 2
2 2
2 2 2 2
1 cos 1 sin
x y ........ 0
a p b p
| | | |

+ + =
| |
| |
\ . \ .

These lines are perpendicular

2 2
2 2 2 2
1 cos 1 sin
0
a p b p

=
( )
2 2
2 2
2 2
b a 1 ab
p
p
ab b a

= =

.

5. Since |z 6| = |z 8|
z is locus of perpendicular bisector of points joining (6, 0) and (8, 0) If z = x + iy x = 7

AITS-CRT(Set-I)-Paper-2-PCM(S)-JEE(Adv)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
6
6. Tangent at x = to the curve f (x) = |cos x| will be
parallel to xaxis and cuts the curve f (x) = cos
1

(cos x) at B and C.
AD = ( 1)
Area of ABC = ( 1)
2



/2
3/2
2
1
21
B
A
C
y
x

1
D
45
0
45
0

7. Suppose = 2cosx 2 sinx 7 + + = ( ) 2sin x 7 + + 2 7 2 7 + +
m =
1

m
1 1
, ,
2 7 2 7
| ( |

| (
+ \ .
.

8. (x cot y + ln cos x) dy + (ln sin y y tan x) dx = 0
x cot y dy + ln sin y dx + ln cos x dy y tan x dx = 0
( ) ( ) d xlnsiny d ylncosx 0 + =


x ln sin y + y ln cos x = ln k
or (sin y)
x
(cos x)
y
= c
9. Given equation 2x
2
+ 2mx + m + 1 = 0
D = 4m
2
8(m + 1) 0
m
2
2m 2 0
(m 1)
2
3 0 m = 3, 4, 5, 6, 7, 8, 9, 10.
Also, number of ways of choosing m is 10.
Required probability =
4
5
.

11.
2 2 2 2 2
a b c d a b c d
4 4
+ + + + + + | |

|
\ .

( )
2 2
16 e
8 e
16 4


64 + e
2
16e 64 4e
2

5e
2
16e 0
0 e
16
5
.

1416. f(x) f(x) 0 in [a, c] and 0 in [c, b]
f(c) = 2 and f(x) f(x) 0 in (a, c) (c, b)
f(a), f(b) 0.
f(a) f(b) f(c)
0 0

3
2

0 1

3
2

0
2

3
2

1 1

3
2

1
2

3
2

2 2

3
2


AITS-CRT(Set-I)-Paper-2-PCM(S)-JEE(Adv)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 16, Ph: 46106000, 26515949, Fax: 26513942.
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17. If P is inside the triangle and area of PAB = area of PBC
BP must be the median. Similarly, AP must be the median.
Hence P is the centroid. If ABC > ACB, then AB > AC and PB > PC
perimeter of PAB > perimeter of PAC
ABC = ACB. Similarly, other angles are equal and the triangle must be equilateral.

1819. If P lies outside the triangle assuming A and B lie on the opposite sides of PC. Hence A, C lie on
the same side of PB. Since area PBC = area PBA
A and C must be the same distance from PB so AC is parallel to PB and PA is parallel to BC. So
PACB is a parallelogram and PC = AB
ACB = 90 and parallelogram is a rectangle.

SECTION - B

1. Since f(g(x)) is a one-one function
f(g(x
1
)) f(g(x
2
)) whenever x
1
x
2

g(x
1
) g(x
2
) whenever x
1
x
2

g(x) is one-one.
If f(x) is not one-one then f(x) = y is satisfied by x = x
1
, x
2

f(x
1
) = f(x
2
) = y also if g(x) is onto then
let ( )
1 1
g x x = and ( )
2 2
g x x =
( ) ( ) ( ) ( )
1 2
f g f g x x =
f(g(x)) cant be one-one.

2. (A)
x
tanx
2 4

+ =
from graph, the equation has 3 solutions in [, ].
(B)
1 2 1 2
sin | x 1| cos | 2x 5 |
2


+ = |x
2
1| = |2x
2
5|
x
2
= 2 x = 2 (Two solutions)
(C) x
4

2 2
x
2x sin 1 0
2

+ =
2
2 2 4
x x
x sin 1 sin 0
2 2
| |
+ =
|
\ .

x = (2n + 1), n I and x
2
=
2
x
sin 1
2

=
x = 1 is the solution.
(D) Let y = x
2
+ 2x + 2 sec
2
x + tan
2
x
y = (x + 1)
2
+ (2 sec
2
x 1) + tan
2
x > 0 no solution.

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