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j
1
~. AA~\ jJ~
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Â.? ~~ 1 .r' t,;,;,
~

! ty.$.\ f it~
t J-lo'.,I.\
Jil\ e~"...J1
(J:aW 03) J.#I ŒA
: i"~1 J.J..l;I.- 1
0.5
C1I3 COOH(I) + C 2 H 5 0H(l) = CH3COOC2 H5(1) + H 2 0(I)
. 1c 1 no no 0 0
0.75
J. c 1 n -x
0
no -x X X
n o -xf no - xI xf xf
ùc 1 1

0.25
.Xma;x = no = lmol ~J no - xrnax 0: X max i! t.:l..ü....\
0.25 ; 0.25 ................n' = 1 n ~\ ~'il o~La ~ ~ .;JI 4.V."J1- 2

1
1 0.5

1
t
n'(mol) :ù~I~.)
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i
i
08 -;
0.7
n' ­ f(t)
0.5

0.1
t(heure)
0"o .
150 )J
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t = 3h .llc Jc,l9::J1 ~? ~ ~~-4

t = 3h .llc W'lWI ~ ~

0.5
.~ = ~n' = (3,5 5,9).0,1 = 0,16 _ 0.046nwl.h- 1
~t 6-2,5 3,5
ÙA yI t::' ~WJ:j •

?~·1
û (.$",
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••••••••• X
f
:.::: O.67mol w~l ~ . rJi:ill ~4:J\ ~I ybS
0.25
Tf = = 0,67 = 67%
x max 1
0.25
........................... ("\.:j J#- J~\ : <: t.:i..û...w';ll

(~l1.i 03) :~-un ù:!;4l) .

. . .'iI~
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4..b1.:....J\ Jb.J\
di
E Ri + L - + 1'$
dt
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dt
L di + R'i R'=R+r p.,.:
0.5 E
,.... , ... , - =
di +-z
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L dt L

0.25 di 0 C}i I..jJl&. r.,sA) Jiu ~~ ~."JI ~ ~bll ?~l .) -2

dt - ­
0.25
.E = (R + 1')1 0
=? lu = E/R +r ~ .Jy:JI 'ilJ...t 'iI)~ ..)~l ­

i = A(l- e~t/T) -3
di
dt
= AT e -llr •T .J A ÙA JSj ~ yJl ô.)~\ J4--:\
4.VWI . . ·--.IL
~~..,........

A
+R-+ -r (A - A e -t / T ) ~ E
"-~-
T . L L
~e-I/r + A(R + r) + A(R + r) e-I!r == E
T L L L
e~l/r(A _ (R -:.r)A) + A(R2 _:1 E
T L L L

01 0.5
fi
................... ,............. -
T
(R+r),A
= -~--
L
=? T
L
= -_.
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0.5 ................................ AC R + r) = E =? A E
L L R+r

---4----1-----­ C1s1J
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~)I ~~ ~ Une y;J\ ô.J~ ~tuwl -y

di . 1/ E R + 1'11 T l' -I! T
Une = L- +n =p - .e + .E(l e )
0.5 dt R + l' t R + l'
0.5 ................. = E e :/ + l'
.E(l - e-I/r)
'

R +r
~\Jl\ rl.b1l1 ~ UHf: y;J1 A.4 y~ Î-4
r E
U 1. = n --E
R+r 10 = R + r

0.25 ~=lV
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0.5 .~)l~.;b ~ ~4~\ yjill Î':'(~ ù~ ~~.J-y

0.25

------ ----- ------- ---- tes)

(.bW 03) ~ tJ: ;.43\

0.25
0.25 ~ fi ~ _______ ~<.S.,ïll JlW~ .\bej ~
va:?hW"#Ml
Px nwx
0.25 ""' -p = m.a- --.., -P '1 (Y
L., +~
R"1 ~
F = m.a : 4 'i ~ ._ Il -: 1 • \ '~\I 'i 1 l
~~ ~WUI "'o.I~1.a.AJ

0.5 -F = m.a
~kx = m d2 x =;:} d2 x k : ~..rJ1 .J..?A ~ .b~;H.l
0.25
dt ~+-x
m
0 ­

:~~ ~jll 4..bla..J\ (----=!t­

x = XI".x cos(wut +:p) : ~l Ù"I ~ ~ ~L.J\ ~1lJ1 ~~i ~

Wo Ik lORad/8
Vm
27r 27r 27r 7r
0.25 Wu -
T0 --,> T
0
-=- -8
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0.75
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0.25 :p = 0 <= cos:p = 1<= x = xm., O.îJ.c.

0.25
x 4J~t....Jl

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~l ~l9.J.l1
2

d x
de
+a dx +),x = 0:
dt
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~
4J.J1.&.J1 ü\,s; \j\
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/2
: ~1.S:b..';1\ é~ ~ ~ ut9li
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ut:. ~ ~,~ . ~.J'\ ...r- (8) ~..F" u.".....
'(1&\ , ~LS: lj\• (1
'"""""t'". uLS:~"i1
'1'(-;:<L.

0.25 .é.lA~ ~ "'bol (8) ~. ,(', ~ uLS:~'Vf I ~LS: \j\, (2

... ' ~~J'\ ...r- ..F" u."..... •
0.25
',-?JY'l rl1:r..i 4Jb. .} (s) ùfo éy:l- û\,s;1.S:b..'j\ ü\,s; IjJ (3

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\
1 fi

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0.25

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~ t(s)

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(~W 04) ~I)l ,;: >431

: (ai, ôZ) ~ li fill 4.llbc fi y. ~ y:.. ~I.J..) -1

~
L,;
F = m.a~:.(..)-l~
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~
.\.::JI uJ-l
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-:. .. L~..
~
P = m.a_'1
J m.g
- = m.a -""t
'* 9 = a
• ...j- .....

0.25 az = ~g = ete. f'\.l;.Jj4;;~ ~ ~y:.. : oz .Jp..J1 ~ .b~y~

0.25
ac = 0 - ~ ~ ~y:.. : OX .J~\ > .bti....'i4
1.5
a, -g

0.25 x 2 Vz = ~gt + VO: =-gt + Vo sina (1)

Z = -1 gt 2 + 110 sm
•
cd + ho
2

0.25 x 2 1 j~l:V~ cos a (2)

x C~ VO cosat

:Z, y~-2

t = _x_~ 4.ll (2) ÙA : ) ......JI 4.l..)~ ..)~\

Vo cos a

z 1 - c - - : - - x2 + tga.x + h0
0.5 2 a
01 0.25
l 9 2
Zc
2
2
tIo cos
2
a
Xc + tga.x, + ho :~(1)ÙA

z ==
(
4.9 (4.5)2 + 0.75 x 4..5 + 2.l
64 x 0.63
0.25
-~2.46 + 3_37 + 2.1 C':' 3m

:~.lll\ Jy..aJ ÙAJ ..)~I -3

0.25 4.5
- - '-- = = 0.81s
'/Jo cos a 8 cos 37
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: vz , y~
?I,e = '/Jo cos LV
0.25 =8cos;37 = 6.3gm.s~l: v" y~
1.5
v" = R+ 11,,2 = 7.11m.s- 1
: V,. y~
0.25
0.25 sin{3 = ~s..: {3 y~
'Ii,

0.25 {3 = 26° ~J

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0.5 (J:aW 04) (.)oi'o4W1 ÙOI~I

0.5 (~I J~I) wy~1 J.lC. ~ 226 1
(!i.J.ll1 J~I) w\..ijjJyll J.lC. ~ 88
: :l!Jla.J1 -2
0.5
Z 86,A = 222
0.5 ;x 2;Rn
0.25 x 2 4 .2. x 10 JO S ... ~ .
..........J tin = ln 2 -3
À
0.25
~\~';l 4..:.:}l~1 .l..lc ~ &J ,:?JJy.Ql1 û-oy\ ~ ..;-lI ~ (i -4
M 1\r -At
m = -.JVo.e N = rn ,N : 4.V\..,J\
0.25 NI M A

0.25

0.25
m = f(t) Ù~I

0.5

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(12lli 03) (,!'H 8431 ù: ~

~\ JyJl j,:Sfi\ y b -1
1.5 2H2021aQ) 2H2 0(11 + 02(9)

V 10
n( = -g = -- = 0.446mol
0, V 22.4
n 0.446 ,
0.5 Co = - = - - = 0.446molr
, II 1
.. ., .., .......... Cl"
1/0) = 2C,O)
.•
= 0, 893molr 1

0.5 ................... .lJ~1

"" ~ : u.-.l\ .,1\
......, ,~
~._--.

-1,..,.1

cy =C2V~ :l~ ~\ ~I .
0.5
......................0, 893,Vl = 0,1.0.1 =} v: Il mL
:4..:c 4-.J':i 1 ô.~.Ié·j \ 4.l.}la..o ~\:jS- i - 2
2 x (MnO,- + + 5e- = Mn
H
+ 4H,o)
5 x (H,(J, 0, +-2H+ +2c-)

0.5
0.5 ......... , .. ,2MnO,- + 5H,o, + 611+ 2Mn 2+ + 502 + 8H,o

• t.F'1 îu;J
. \ ~
A_" 1\
lf"'-" '. .< .~.11 . ~\
\ . - 1\ ..J::"'.r C -1,..,.1
.
:)!I.S.::J\ ~

M,,(; 1
n, x 2

5CYE ClV: X 2

0.5 ",,,.,,,,,,,,,0, 95.10- morC

3 l

01 2V,
oy
0.5 ~\fo ;J .. 0 0,86mol,L-
l
~.J C,l~ = CYo: ~~\
v,

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(.blQj 03) :JiJl ÛoI..A

0.25

0.25

(-) Al
0.25 x 2
~I~I

0.25 (J.,-Jl CJG..) f'~\ LS~ ~ ~ILS~ ÙA J\;JI ~ ùfo

.~û\..iJ~I~J

:0i J9'0'111
I ~JL....JI -3
0.25 x 2 [AI(s) = AI:q+ +3e-" .................... (I)

.................... .... ·1;3Ag(:., + 3e~ = 3Ag(s)'··· .. ··· .... ···(II)

!1t = 300min J')L:.. J.,-J! ~.;JI j:.~~1 ~ yk-4

1 =..!L ..u...aJ q I.!1t
Ôt
0.25 x 2
q 40xl0~;1 x300x60 720C ç.~~1 ~

f'b J~l ),-:uc~ : f'~1 JJ~ -5

A les)

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~<: f'Ji:l.I!
le 0 no(Al)
o o
h: x no x n~ 3x x 3x
0<: :Ifmx no X nmx
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: (Llt) ~.l.J1 J)Li. X rJi:j,1I ~ (i

wUJ.;Al':I\ .)~ z J ~I x ~ q = z ,x.F 'Û4J ,7,;
z .F

0.25 4J,j\..jj.J\

x 720 ~~ 0,002.5
3 x 96500 289500
= 2 5 x 1 0 ., 4 mol

.(' ~I c.S.,YwIA 4.tS ~ ùL..ai:J\ '-:J~ ('-:J

b.m(AI) = ml - m

0.25 ~ :...;
0.25
m = nlvI ~J n = m
M
tfi.l
Llm(All == noM (no x)M
=(71,0 no + x)M = xM
=25 x 10'4 x 27 = 67,5 x 10-;' 9

(.b1,ij 3) v-ü!! 6:A

0.75 ....I.jjS.y ~ F ~ (Giove-A) ~1.l..o.l\ yill ~yJ ~\.J.ll\ ~ -1
0.25
~
"I.::J\ .~ •• '1j -:' .. L~..
L)-l.J:-l U,JJ ~ ~
~ -.11
t..r .J
..II
ë?' Y""' l\h'
~
~\ ~ .~II
~ yu

J ~ ..1\j ~..ShJ ·W~ I.j.fiJA~\ ~I ù~ J :~

0.25x2
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(* ~p. W~ ~\~) ,~I ya. ~)'11

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'1:J\, U. , ~
(.j~
-:. .. L";-2
""
6fext=ma
-;---' ~.
"Ü4.J mg=ma~ '.
0.25
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0.75 : ('WI i..-li::J\

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-:. .. L,,; .

M(1')~s)
F ~= :m(S),g = G (RI' +- W
0.25x2
~ Men -2
a, = 9 = G - = 0, 44m,s
, (Rr + h) 2

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3,98 X 1014
0.25 x 2 v=
30x 1O()
v = 3,64 x 103 m/ s
z,hl-, Z, .)-,J ~ j Y' : .)-,..ùl Ù;lyû-A
0.25 x 2 I(Rr +hyl
T 21f 1 5,16 X 10 4 S
V G.M(T)
14,33h

0.25 x 2
Epp = aj ~1.Sl1 ~L6lJ 4.)-4 ~_fil F ~

ET = ~(700)X(3,64XI03l +700.0,44x23,6xlO G

=46,36.10l:' 72,68 X 10 8 :::::: 119.10~ J

(.l:!\.i.j 04) :~I U; ~\

(1) ~)I ~ ~..lJ411

0.25
-1

+
r UC=UAB

0.25 PE

(q) ~ UR -' Uc ùC- ~I - y

.......... " ..... ............ U c --il..

C

0.25
............................. U (R) = R i = R. d: ~t)
01 0.25

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: ~\.i::Jl
~
~t....J\ ....
Jb.J1

U. 1H U!JIJ = U AD

q Rdq-E ... ,.
-+
e .--
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"""""'J

0.5 dg 1 E
........................ -+-q=­
dt R.e R

'-S"I~I~)I'
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. r..r J

a J A Ù4 JS. J~ - ~
0.25
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l _e
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Re Re R
0.75 •.Ct'.C

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e.."'(A a - A) E - ­A
-
Re R RC
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' =1 , q= 0 .:U..aJ [J (: = 0 0}9 t=O W
E
0.25 Aa - 4..l.oJ
R
0.25 1 Ct' _1_ J A = CE 4..l.oJ E -~ = 0 4..l.oJ e- n ' = 0 ü19 t = 00 W
RC R RC '

q(t) = C.E(l- e Re)

[Je 5V (~IJ ("tJ:..j) ~l 4.:~ Jk. -J

0.5 0.25
....}4;..J.
'J li:J\ 4..l.oJ ~~.. ti&J\­

0.25 .............................. .U c E 5V , UR =0
:ti&J1 ~ C~\ -..J,

E .!CU 2 4..l.o C 2.E

2 max J U1
nHnc
0.25 3
10 X 10-
0.25 .................................C = = 4 X 10-4
25
6
=400 X 10- F = 400MF
:(61fil o)J) (2) ~."ll ~ ~J41I-2
0.5 0.25x2
........................... ~J Co~'\ 1::.\ .1
(.,.l:'\.JJ\ r.r ~I t.)LI -\
• -: ,~<' 1 • " '

._ _ _ _ _ _ _ (160 J________
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:~.)li.J\ - y
0.25 x 2
T1 R.C 470 x 400 x lO-ü
=0,188 S

Tl (R + R).C '''' 2RC

..····..•···....·....······..····..··..·....·......12 21ï

(..hW 03) :~I)I ~I

:4J.lL....J\ ~t6. -}
0.25
•••••••.••••••••••.•••••••• 84
210
Po -7
206
811 Pb + 4
2 He
0.25 .......................................... (tY) JA (~l) .).lL...:J1 ~I

(No) ~l.fl:ï\ Â..)yYI .l~ ~ -2

0.25
.......................................N" .r;; x Nt = 2,87 x 10](; ôly
N
ln ,; = I(t): w4:J\ ~.)-3

: ~)\ -1
0.25

-ln(-)
No lem --> 0.2
N lem -> 40 jours

0.8+--------7f

0.2

o tCi)
o 160 240

tl -' (.~) ~~l-Y

2

: u. W\
~.
4J.lb

0.25
ln: = at .............. ( 1) ~~ :'.J4c
v

N!.! \ •.. 1
- = e 1.J:l""-l
No
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~4-'11~
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0.25 -ln: o
= +Àt .............. (2) ~.;hi o.)~

0.80 - 0 _ ~.- 11 Il
À = a = tan a =
160 - 0
~ 4...,Q,JI..JQ.,QJU
. . .

0.25 .............. .............. A 5,1 0-:1 J·-1

\ =

In2 0,693 .
............................... t 1 = - = -3 = 138.6Jours
0.25 2 ,\ 5xlO
~ ~\~_,._~,I '.,,\\1\. jl\-~
100 ~ '--:---""'" f'..,YU UA .
->.t
N (t) = N oe <Ü..a.J

c - AI ... ~ _
m (1) m ..........J

Jl'(, À1 1 -Àt
100 = Jl'().e- <Ü..a.J -=e
0.5 100
0.25 x2 l .
In - = -Àt 'Üoo.J In100 = )..t
100
<Û..o t = ln 100 4,6 4600
.J À 5 x 10- 3 5

t 921,03jours 2,51ans
(.blil 04) : ~W\ ~\
0.5 0.25x2 . 4..J-\"~\a."I~,_I\. -.~ - ~\ ~~..>:U'W
l.lk. ~.J ,.1\ ~ --1
~ ~.)~t ~ UA.J U ~

~ J~ u.:o};l1 (.JI.J.J j ~yo. f'Lol I~

:~tJ\.c.J.~ ~-2
0.5

1.25
~-~ X,

--W;~W/////M
F . _______ x ~

L F,," = mû <Ü..a.J P + R+ T = mû
0.25
d2 x
-kx=m­
de :..b~'i~

d2 x k
................... ::::}--2 +-x = 0

0.5 dt m
x = x lllftX cos (w t 0
+ ln) 't"
1. L ~tJ\ ~)\
~... •
. ~tij
lJA ... ~..bLt...a

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:Ùt+.J1 Ù4 -3
0.25
"", ...............................T" 0,2,5 x 4 = 18 ~ljJl ')3.ll\
27l' 2 Rad. ~I·tl .·_.~11
0.25 ... , ........................ , .... w
o y= 7l'S'
o
~JJ ~

Ivruax I=wx 0 lTldX

7r
Vmax 10
Wo 27r
1
" .. "xm <1' = 20 O,O.5m = 5em
0.5
v om x u.'ij t 0 W :~~I..:....J\
s
0.25
:4..;k:. 3 1) = oRad

0.25 ,X(t) = 5 X 10-2 cos(27rt) .... (m).

~'
~,~I 4!\..b 'î
U ûUi\'C
-4
E = Ee + }t'pp Ep€
1 2 1
-mv + -Kx­ ?

2 2
1 2
- mwoX max SIn
2 . 2(
Wo
t 19) lKx max
2 cos 2( W" t
2
2

0.25 x 2 ......... E = 1 KX~lax = este

2

0.25 ~(20) x 25 x 10-4

=25 X 10.3 j 25mJ

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16 Ù'" 14~
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),75 .:;.flt-ll ~~I Jc,li::J1 ~..)Lt..o ~bS 1

:t~Y.U J ·ù . f'
0.25
(Jvln~~..; +8~:1) +5e- Mn~,,~) +~ql) ......... (1)

.~. ....'.,1 1 1 "

.b~ l 'i..J'f'
0.25 (802 HO
2 (1)
= 804,,,,-
2
4H+((1.'1) + 2e-) ........ (2)

: ~ ~4YI 4.b1.a.Jl
0.25 2MnO-4,,,,,, + 5802 + 2H 0(1),,,., 2
= 2Mn~a+q) + 580:- + 4H(~ ) '''i' UJ

'ii "''''9;,11
. . :,
'-I~
_.,::. A..J\.lJ : '.ilts.::J1
JII .J~........r G~..l.:...
.J
,"te..
~
~I ~
., ...

- 2
1.25 0.25
(~j.Jl) ~li::J1 k."ll ~ ~I

(~~~.,;:w. .1:..J~) Lt..o J)lc tllJl ~ ,j9ts.::J\ ~ - 3

n O (S02 n O (Mn0 4 ) <Ü..a.J
0.25 5 2
CY <Ü..a-,
2 ·5
.5CI Y E .5 x 2 x 10-<
).5 J):...J\ jfi. Y} C 2V 2 x 50 x
............... .):!k..J1 =lO,2 mo l,rJ
0.25

. (j"j).lJl ç.\~\ ~ ~1jl.J1 sq jW ~\ JyJI jfojJ\ ~-4

0.25 t
.75 •..••..•.•• C = - =? t = C.M
M
0.25 •••••••••• M(Nu,) 32 + 32 64gmor
1

0.25 ........ t C.M = 10-2 X 64 = 0,64g1- 1

...,ts.J1 )#ojlll

:1YI-'.J.w\ ç.\ ~1 ~ ~~ -5
rJ';:':";
(soJ ÙA 0) 64 ( g) +­ S 0 2 J.;b..o ÙA ft 1 JS
<$';:':";
ç.1~1 ÙA2 0 m ;\ +­ S 0 2 J."h.J1 ÙA ft 1

16 &-15
[ 164)
 http://forum.physianet.com

0.25x2 1 lxO.64 J
······ .. ·· .. · ...... ··m(SO)
2 0,032g = 32xl0 fl9
20
:~ ~W\ 4...J:w.l1 ..bJy:;, ~
0.25 (4...J:w.l\ ..bJy:;, ~) 250/l.g.m;l

'----------.----- (165 J­ 16 w.-16