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SJFCD
1*211
1. 266100
2. 100012
10%>97%
>84%pH
99%99.9%
pH5.55.5V58%
Abstract: A combined processes of acid-leaching, electrodepositing and ammonium jarosite precipitating was developed to recover
heavy metals from an electroplating sludge. More than 97% of copper, nickel, chromium, and 84% of iron were extracted from the
sludge with 10% H2SO4 leaching. More than 99% of copper was recovered from the leaching solution with electrodepositing process.
The left solution after copper recovery was then treated with ammonium jarosite precipitating process, about 99.9% of chromium and
iron could be deposited as chromium ferrite in this process. Finally, the left solution was treated with electrodepositing process again
for nickel recovery, and about 58% of nickel could be recovered in this process under the condition of pH 5.5 and voltage 5.5V.
Key words: Electroplating sludge, heavy metal recovery, acid-leaching, electrodepositing, ammonium jarosite precipitating.
[1]7
The project was supported by the Ministry of Education Science and technology innovation engineering major cultivation project (708060;)
the Excellent Young Teachers Program of MOE (200804231036); The Special fund Project forScientific Research of Environment Protection
Public Welfare Industry (200809095)
708060200804231036
200809095
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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SJFCD
[2]
/
[3-5]
1
1.1
CuNiCrFe
1(a)2mm
1(b)pH84.3%pH
10:19.310:14250 s / cm
(a)
(b)
1 (a)
(b)
200 X D8ADVANCE
2 HF-HClO4-HNO3
M6 THERMO 1
2
Magalhaes [6]
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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450
Intensity(Counts)
400
350
300
250
200
150
20
30
40
50
60
70
2-Theta(
2 XRD
Cu
Ni
Cr
Fe
mg/kg
114133
99967
13820
12730
1CuNi114g/kg100g/kg
[7]HW17-
1.2
30%
pH pHS-3DDDS-307
pH M6 THERMO
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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1.3
3
pH
pH
2
2.1
12
98%
n
1Cu2+ Ni 2+Cr3+Fe 3+n31kg
98%242ml
2g
50ml250.50.54000rps7
25ml
44
C
100%
C0
CmgC0mg
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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SJFCD
120
120
(b)
100
100
80
80
(%)
(%)
(a)
60
Cu
60
Cu
40
Ni
40
Ni
20
Cr
20
Cr
Fe
Fe
0
0
0
10
15
20
25
30
H2SO4 (V%)
10
11
12
H2SO4 (mL)
4 a10mLb10%
4(a)10%
30%
10%4(b)10%
10mlCuNiCr95%Fe80%0.882ml
1g5ml 10%0.5h
2
Cu
Ni
Cr
Fe
95.21
96.57
90.88
85.94
g/L
21.734
19.308
2.512
2.188
2.2
400mL5
3.5cm0.5h
1h2h1.5mLpHpH
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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1- 2- 3-4- 5- 6-
5
2.2.1 pH
2.0V2.2V2.5V2.7V3.0V2pH20.3
6
100
100
(a)
U=2.0V
U=2.2V
U=2.5V
U=2.7V
U=3.0V
90
80
80
70
70
(%)
(%)
90
60
60
50
50
U=2.0V
40
U=2.2V
30
U=2.5V
20
U=2.7V
20
U=3.0V
10
10
(b)
40
30
0
0
10
12
(h)
10
12
(h)
6 (a) pH0.3
(b) pH2
6
U=2.0VU=2.2V
30%50%2.5V1290%2.5V12
99%
4(a)4(b)pH12
pH
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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2.2.2
pH0.32.7V3.5cm
78
100
(%)
80
60
40
20
0
0
10
12
(h)
7
72.7V
8000
(a)
6000
(mg/L)
(mg/L)
8000
4000
Ni
Cr
Fe
2000
(b)
6000
4000
Ni
Cr
Fe
2000
0
0
6
8
(h)
10
12
6
8
(h)
10
12
8 (a)(b)
8
8apH
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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8b
2.2.3
64
9 pH
2 2.0V pH 0.3
pH pH
pH pH
pH
(a)
(b)
U=2.0V
U=2.5V
U=2.7V
U=3.0V
2.3
550mL100mL
pH3.03.23.53.84.02
50mL1mol/L
pH1.6953h150r/min
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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[9]10
10(a)1mL
0.11mLNaOH pH 4 83% 64.46mg/L
25%14% 15% 10(b)
50mL 1mL 99% 10%
50mL 1mL
99%
100
100
(b)
80
60
(%)
(%)
(a)
Ni
Cr
Fe
40
20
0
80
60
Ni
Cr
Fe
40
20
0
2.0
2.5
3.0
3.5
4.0 4.5
5.0
5.5
6.0
NaOH (mL)
0.5
1.5
2.5
(mL)
10 (a) (b)
2.4
60
pH11
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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pH pH 3.644.655.5
31%38% 42%
5V 5V 5.5V
pH 5.5400mL 8g 11(b)
11(a)
5.5V 48%
5V 6%
pH pH
[10]
5.5V pH 5.5 400mL 0g8g12g
11(c) pH H+
57%
3
(1) 100 2 10ml10%
0.5h 95%
(2) 3.5cm 2.7V pH 0.3
8h 95%
(3) pH pH 3.644.655.5
31%38% 42%5.5V
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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48% 5V 6%
(4)
pH pH
9.3-0.3
pH 0.3-0.26
pH 0.26-1.6
pH 5.5-2
pH
(g/kg)
Cu
Cr
Fe
Ni
114.1
99.9
13.8
12.7
111.7
97.6
13.4
10.7
(%)
97.9
97.7
97.1
84.3
(mg/L)
Cu
Cr
Fe
Ni
21734
3240
2188
19308
37.9
2512
1835
18792
5.0
0.2
15510
6493
(%)
99.9
99.8
99.9
58.1
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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SJFCD
[1]
[2]
[3]
[4]
[5]
, , . , , 2001, 7: 25-28.
[6]
Magalhaes J M, Silva J E, Castro F P. Physical and chemical characterization of metal finishing industrial wastes, Journal of
Environmental Management, 2005, 75(2): 157-166.
[7]
, , 2008.
[8]
, pH , F-HZ-DZ-TR-0026.
[9]
1972-
Emailcspeng@ouc.edu.cn
SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
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