You are on page 1of 12

Scientific Journal of Frontier Chemical Development

SJFCD

1*211
1. 266100
2. 100012


10%>97%
>84%pH
99%99.9%
pH5.55.5V58%

Heavy Metals Recovery from Electroplating Sludge by Multi-Steps of


Electrodepositing and Precipitating
Changsheng Peng 1*, Qingbao Gu 2, Panpan Li 1, Ruijie Jin 1
1 The Key Lab of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao, 266100
2 Chinese Research Academy of Environmental Sciences, Beijing, 100012

Abstract: A combined processes of acid-leaching, electrodepositing and ammonium jarosite precipitating was developed to recover
heavy metals from an electroplating sludge. More than 97% of copper, nickel, chromium, and 84% of iron were extracted from the
sludge with 10% H2SO4 leaching. More than 99% of copper was recovered from the leaching solution with electrodepositing process.
The left solution after copper recovery was then treated with ammonium jarosite precipitating process, about 99.9% of chromium and
iron could be deposited as chromium ferrite in this process. Finally, the left solution was treated with electrodepositing process again
for nickel recovery, and about 58% of nickel could be recovered in this process under the condition of pH 5.5 and voltage 5.5V.

Key words: Electroplating sludge, heavy metal recovery, acid-leaching, electrodepositing, ammonium jarosite precipitating.

[1]7

The project was supported by the Ministry of Education Science and technology innovation engineering major cultivation project (708060;)
the Excellent Young Teachers Program of MOE (200804231036); The Special fund Project forScientific Research of Environment Protection
Public Welfare Industry (200809095)
708060200804231036
200809095

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
-9-

Scientific Journal of Frontier Chemical Development

SJFCD

[2]

/
[3-5]

1
1.1
CuNiCrFe
1(a)2mm
1(b)pH84.3%pH
10:19.310:14250 s / cm

(a)

(b)

1 (a)

(b)

200 X D8ADVANCE
2 HF-HClO4-HNO3
M6 THERMO 1
2
Magalhaes [6]

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 10 -

Scientific Journal of Frontier Chemical Development

SJFCD

[cuoh.txt] 10.0000 249.97


500

450

Intensity(Counts)

400

350

300

250

200

150
20

30

40

50

60

70

2-Theta(
2 XRD

Cu

Ni

Cr

Fe

mg/kg

114133

99967

13820

12730

1CuNi114g/kg100g/kg
[7]HW17-

1.2

30%
pH pHS-3DDDS-307
pH M6 THERMO

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 11 -

Scientific Journal of Frontier Chemical Development

SJFCD

1.3
3

pH

pH

2
2.1
12

M (OH )2 H 2 SO4( aq ) MSO4 2 H 2O

2M (OH )3 3H 2 SO4( aq ) M 2 ( SO4 )3 6 H 2O

98%

Vml 100nM (OH )2 /1.84 Vml 150nM (OH )3 /1.84

n
1Cu2+ Ni 2+Cr3+Fe 3+n31kg
98%242ml
2g
50ml250.50.54000rps7
25ml
44

C
100%
C0

CmgC0mg

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 12 -

Scientific Journal of Frontier Chemical Development

SJFCD

120

120
(b)

100

100

80

80
(%)

(%)

(a)

60
Cu

60

Cu

40

Ni

40

Ni

20

Cr

20

Cr
Fe

Fe
0

0
0

10

15

20

25

30

H2SO4 (V%)

10

11

12

H2SO4 (mL)

4 a10mLb10%

4(a)10%
30%
10%4(b)10%
10mlCuNiCr95%Fe80%0.882ml
1g5ml 10%0.5h
2

Cu

Ni

Cr

Fe

95.21

96.57

90.88

85.94

g/L

21.734

19.308

2.512

2.188

2.2
400mL5
3.5cm0.5h
1h2h1.5mLpHpH

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 13 -

Scientific Journal of Frontier Chemical Development

SJFCD

1- 2- 3-4- 5- 6-
5

2.2.1 pH
2.0V2.2V2.5V2.7V3.0V2pH20.3
6

100

100
(a)

U=2.0V
U=2.2V
U=2.5V
U=2.7V
U=3.0V

90

80

80

70

70
(%)

(%)

90

60

60
50

50

U=2.0V

40

U=2.2V

30

U=2.5V

20

U=2.7V

20

U=3.0V

10

10

(b)

40
30

0
0

10

12

(h)

10

12

(h)

6 (a) pH0.3

(b) pH2

6
U=2.0VU=2.2V
30%50%2.5V1290%2.5V12
99%
4(a)4(b)pH12
pH

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 14 -

Scientific Journal of Frontier Chemical Development

SJFCD

2.2.2
pH0.32.7V3.5cm
78

100

(%)

80
60
40

20
0
0

10

12

(h)
7

72.7V

8000

(a)

6000

(mg/L)

(mg/L)

8000

4000

Ni
Cr
Fe

2000

(b)

6000

4000

Ni
Cr
Fe

2000

0
0

6
8
(h)

10

12

6
8
(h)

10

12

8 (a)(b)

8
8apH

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 15 -

Scientific Journal of Frontier Chemical Development

SJFCD

8b

2.2.3
64
9 pH
2 2.0V pH 0.3
pH pH
pH pH
pH

(a)

(b)

U=2.0V

U=2.5V

U=2.7V

U=3.0V

9 pH (a) pH=0.3, (b) pH=2

2.3

550mL100mL
pH3.03.23.53.84.02
50mL1mol/L
pH1.6953h150r/min

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 16 -

Scientific Journal of Frontier Chemical Development

SJFCD

[9]10
10(a)1mL
0.11mLNaOH pH 4 83% 64.46mg/L
25%14% 15% 10(b)
50mL 1mL 99% 10%
50mL 1mL
99%

100

100
(b)

80
60

(%)

(%)

(a)

Ni
Cr
Fe

40
20
0

80
60

Ni
Cr
Fe

40
20
0

2.0

2.5

3.0

3.5

4.0 4.5

5.0

5.5

6.0

NaOH (mL)

0.5

1.5

2.5

(mL)

10 (a) (b)

2.4

60
pH11

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 17 -

Scientific Journal of Frontier Chemical Development

SJFCD

11 pH (a) pH, (b) , (c)

11(a) pH pH=3.64pH=4.6 pH=5.5400mL 8g


1
1 pH
pH Ni 2+ OH- pH

pH pH 3.644.655.5
31%38% 42%
5V 5V 5.5V
pH 5.5400mL 8g 11(b)
11(a)
5.5V 48%
5V 6%
pH pH
[10]
5.5V pH 5.5 400mL 0g8g12g
11(c) pH H+
57%

3
(1) 100 2 10ml10%
0.5h 95%
(2) 3.5cm 2.7V pH 0.3
8h 95%

(3) pH pH 3.644.655.5
31%38% 42%5.5V

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 18 -

Scientific Journal of Frontier Chemical Development

SJFCD

48% 5V 6%
(4)
pH pH

9.3-0.3
pH 0.3-0.26
pH 0.26-1.6
pH 5.5-2

pH

(g/kg)

Cu

Cr

Fe

Ni

114.1

99.9

13.8

12.7

111.7

97.6

13.4

10.7

(%)

97.9

97.7

97.1

84.3

(mg/L)

Cu

Cr

Fe

Ni

21734

3240

2188

19308

37.9

2512

1835

18792

5.0

0.2

15510

6493

(%)

99.9

99.8

99.9

58.1

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 19 -

Scientific Journal of Frontier Chemical Development

SJFCD

[1]

, , ., , 2002, 21(2): 40-43.

[2]

, , ., , 1995, 15(5): 21-22.

[3]

, , . , , 2004, 33(2): 45-47.

[4]

. , , 2006, 35(1): 7-8.

[5]

, , . , , 2001, 7: 25-28.

[6]

Magalhaes J M, Silva J E, Castro F P. Physical and chemical characterization of metal finishing industrial wastes, Journal of
Environmental Management, 2005, 75(2): 157-166.

[7]

, , 2008.

[8]

, pH , F-HZ-DZ-TR-0026.

[9]

Sefton.Process for the precipitation of iron as jarosite[P], USA, 4193970, 1980.

[10] . , [], : , 2002.

1972-

Emailcspeng@ouc.edu.cn

SJFCD Vol.1 No.1 Dec. 2011 pp.9-20 www.sjfcd.org 2011 American V-King Scientific Publishing, LTD
- 20 -

You might also like