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CHEMISTRY
COOH
P2 O 5 / ∆
3. CH3 CH2 COONH4 → ?
(1) CH3 CH2 CN (2) CH3 CH2 CONH2 (3) CH3 CH2 NH2 (4) CH3 CH2 CH2 CN
Sol: Ans [1]
CH 3 CH3 CH 3
NaNO 2 X
4. HCl . ‘X’ is
Br Br Br
+ –
NH 2 N2 Cl
7. [Co(NH3 )3 Cl]Cl2 in aqueous solution will give how many numbers of ion
(1) 2 (2) 3 (3) 4 (4) 7
Sol: Ans [2]
C C
(1) –(CH3 CH–CH2 )n – (2) C C C C (3) both (1) & (2) (4) none of these
n
13. | ψ2 | = 0 represents
(1) probability of finding electron minimum
(2) probability of finding electron maximum
(3) probability of finding electron maximum along x-axis
(4) nodal point
Sol: Ans [4]
14. For a particular reaction unit of rate constant k = l2 mol–2 sec–1 , overall order of this reaction will be
(1) 1 (2) 2 (3) 3 (4) 4
Sol: Ans [3]
18. 0.5 g mixture of NaHCO3 and Na2 CO3 titrated with HCl. The change of colour of indicator appears
at pH 9 and at pH 5, the reaction corresponding pH 9 will be as
(1) CO3 2– + HCO3 – → 2CO2 + H2 O + 3e
(2) HCO3 – + H+ → H2 O + CO2
(3) CO3 2– + 2H+ → H2 CO3
(4) CO3 2– + H+ → HCO3 –
Sol: Ans [4]
24. Radius of Ag is 144 pm it crystalises in f.c.c. (c.c.p.). What is the density of Ag in g/cc?
(1) 11 (2) 16 (3) 6 (4) 21
Sol: Ans [1]
26. 238
U captures neutron and emit 2 successive β-particles, the product is
239 239 238 239
(1) Pu (2) U (3) Th (4) Np
Sol: Ans [1]
d d d d d d
(3) − [N 2O 5 ] = [NO 2 ] = 2 [O 2 ] (4) [N 2 O5 ] = [NO 2 ] = [O2 ]
dt dt dt dt dt dt
Sol: Ans [2]
32. A + B → AB(fast),
AB + B → C + D(Slow)
Rate law expression for this reaction will be as
(1) rate = k[A][B]2 (2) rate = k[A]2 [B] (3) rate = k[A][B] (4) rate = k[A]3 [B]
Sol: Ans [1]
33. Absolute vapour pressure of dichloroethane and dichloropropane are 183 mm of Hg and 123 mm of
Hg respectively. When they are mixed in the molar ratio of 2 : 1. Vapour pressure of the solution
made will be
(1) 163 mm of Hg (2) 162.5 mm of Hg (3) 164 mm of Hg (4) 165 mm of Hg
Sol: Ans [1]
Me
34. IUPAC name of C C C C C C is
eth OH
35. Which one has different type of linkage between the two monosaccharides?
(1) Sucrose (2) Lactose (3) Maltose (4) Amylose
Sol: Ans [3]
37. 1 g CaCO3 decomposes by 11% as the given chemical reaction in a 5 litre vessel at 27ºC
CaCO3 → CaO + CO2 ,
what will be its Kp
(1) 0.054 atm (2) 0.54 atm (3) 5.4 atm (4) None of these
Sol: Ans [1]
38. 25 g sample of a compound MCl4 liberates 0.5 mole of Cl2 . Molecular weight will be
(1) 10 (2) 100 (3) 1000 (4) 110
Sol: Ans [2]
39. Solubility of BaSO 4 in water is X g/ltr, if solubility product constant for BaSO 4 is Ksp then relation
between X and Ksp will be (At. wt. of Ba = 137, S = 32, O = 16)
40. For the reaction N2 + 3H2 2NH3 + energy, increase of temperature will result into
(1) increase of NH3 (2) increase of N2 (3) decrease of N2 (4) decrease of H2
Sol: Ans [2]
bacd