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The reaction proceeds through the Cu2+/Cu+ couple 2Fe3+ + 3H2O Î Fe2O3 + 6H+ (9)
as for arsenopyrite at a temperature of 90-95oC in +
2H + SO42- + CaCO3 Î CaSO4 + H2O + CO2 (10)
the same liquor used for arsenopyrite oxidation
according to the following reaction: Limestone addition is controlled to maintain a stable
solution and to precipitate excess iron.
FeS2 + 14Cu 2+
+ 8H2O Î2SO42- + Fe 2+ +
+ 16H +
14Cu+ (8) Process Flowsheet
The Cu+ and Fe2+ are oxidised by air or oxygen (if The IGP flowsheet for the treatment of mixed
required) sparging according to reactions 2 and 4 arsenopyrite/pyrite gold concentrates is presented in
with the ferric and sulphate formed being Figure 1.
precipitated as hematite and anhydrite by the
addition of limestone to a pH of approximately 1-
1.5 according to the following reactions:
Limestone Water
Gold Concentrate
Leach
SINGLE-STAGE S Residue
LEACH L
Air
Copper Recovery
Plus pH9 Copper
Precipitation pH9
Recovery
Precipitation
Figure 1: IGP simplified flowsheet for the treatment of mixed arsenopyrite/pyrite gold concentrates
Arsenopyrite plus Pyrite plus Carbon (Double conditions. Further, the optimal conditions for
Refractory) pyrite roasting differ from those for arsenopyrite,
necessitating a two-stage roasting process.
The impact of naturally occurring carbon in the
processing of gold concentrates is largely a function The use of the IGP prior to roasting can selectively
of its grade and activity. At the lower range of leach arsenic and sulphur to simplify subsequent
carbon content, organic additives may be used to roasting, which in this instance becomes a simpler
inhibit gold adsorption. In these instances, the single-stage process. Further, the removal of arsenic
oxidation of the arsenopyrite and pyrite is as and sulphur reduces the duty for off-gas cleaning
described previously. from roaster operations as As2O3 and SO2 are
greatly reduced. The impact is thus one of
When the content of carbon becomes significant,
significantly reduced capital and operating costs in
the effectiveness of inhibition is greatly reduced as
the roasting step.
“preg-robbing” of the gold by the naturally
occurring carbon increases. In this instance, the The IGP in the case of a double-refractory
destruction of the carbon by roasting is the main concentrate consists of the five process steps of
treatment option that is practiced. This can be a arsenic leach, pyrite leach, arsenic precipitation,
relatively complex process, as gold extraction from carbon oxidation by roasting and gold leaching as
the resulting calcine is affected by the roasting shown in Figure 2.
3
Intec Gold Process (IGP)
Gold Concentrate
Limestone
Lime
Air
Limestone
Arsenopyrite
Leach Carbon Column
FeAsO4 Bleed
Precipitation Circuit
Thickener
Air Contaminant
By-Products
As2O3
Pyrite (Zn,Pb, Ni, Cd,
Leach Mn, Mg)
H2O L
S
H2O
L
S
Air Recycle Ferric
Wash Water Limestone Arsenate
Fuel
Residue
Air
Gold
Leach
Gold Dore
L
S
Carbon Column Leach Residue
4
Intec Gold Process (IGP)
3. Concentrate Grind Size Gold loading onto the carbon is typically 2-5% w/w
due to the relatively high gold concentrations in
Concentrates are typically received in the size range
such solutions (typically 10-100mg/l), which are a
of 80% passing 70-100 microns. Tests have
consequence of the typical high gold grade of the
indicated that reaction kinetics are significantly
concentrate. The gold is recovered by conventional
enhanced when concentrates are reground to a finer
elution or by burning of the carbon, with the choice
size that is dependent on the characteristics of each
depending on the economics of the individual
individual concentrate.
situation.
Where arsenopyrite is the sole gold-bearing mineral,
The IGP’s ability to dispose of by-products such as
a size of 80% passing 30-40 microns has proven
arsenic and sulphur in a responsible manner is of
adequate to achieve good gold extraction and an
similar environmental importance. Roasting creates
acceptable leach retention time.
toxic arsenic trioxide (As2O3), which must be
Where gold is locked in pyrite, the grind size will carefully stored and eventually disposed of at
principally depend on the reactivity of the pyrite, considerable expense. In contrast, the IGP creates
which as previously explained, can vary greatly. crystalline ferric arsenate (FeAsO4.2H2O) in its
For a highly active pyrite, the grind employed for most stable form, similar to the naturally occurring
arsenopyrite is used, but more refractory pyrite mineral scorodite.
examples require finer grinding. This may extend
The presence of impurities in the feed concentrate
to an ultra-fine grind in the most refractory cases.
(such as Cd, Mn, Mg, etc.) has no detrimental effect
4. Environmental Advantages of the IGP on either the leaching or arsenic precipitation
In addition to optimising project economics, the operations. Nevertheless, a method for the
gold industry’s worldwide focus on the management of impurities is required. This is
development of improved processing techniques for achieved via precipitation from a bleed of the
refractory gold deposits has also been driven by the regenerated cupric solution with the purified brine
need for more environmentally acceptable returned to the process. It is important to note that
processing routes. the IGP does not generate any liquid effluents or
gaseous emissions and that all impurities are
Conventional processes treat the entire concentrate produced as solid by-products.
feedstock with cyanide such that the final residue
(after gold extraction) is contaminated with the Limestone is added to the bleed to adjust the pH to
cyanide leachant. Thus the residues suffer from 3.5, precipitating residual iron and copper, which
numerous inherent risks – both real and perceived – are removed by filtration and recycled to the leach.
associated with cyanide usage and disposal and Impurities, such as Cd, Mn and Mg, are then
some projects have been vetoed for this reason. removed via slaked lime addition at pH 9 to form
Cyanide is invariably disposed of into open-air insoluble oxides that are recovered by filtration for
tailings dams from whence it is lost, either ideally disposal.
by natural decay or by unwanted leakage. In oxidising arsenopyrite and pyrite, the IGP
Alternatively, it is expensively destroyed by produces elemental sulphur and anhydrite
chemical oxidants such as hypochlorites. On the respectively. These are stable residues compared
other hand, the IGP leach residue contains only with the sulphate residues produced by pressure
minor residual chlorides and is essentially the same oxidation and the even less stable sulphate residues
as the residue from the Intec Copper demonstration produced by bacterial oxidation.
plant that passed under EPA test procedures in New
5. Materials of Construction
South Wales as being suitable for disposal in a
landfill. The IGP unit operations are virtually the same as
those of the Intec Copper Process that has been
The IGP therefore has a major advantage over all
operated at a 1tpd demonstration-plant scale for
other refractory gold processes in that it is
approximately 1 year. The same materials of
unnecessary to include a secondary cyanide leach to
construction as were proven in that plant will be
recover gold from pre-treated materials; rather the
utilized for the IGP.
gold is recovered directly onto conventional carbon
from the primary leach solution. Retention time for These materials include conventional fibreglass-
gold adsorption is 10-15 minutes, which is similar reinforced plastics (FRP) for tanks and piping and
to conventional practice for cyanide systems. conventional plastics for pumps.
5
Intec Gold Process (IGP)
20
18
16 Enquiries should be directed to:
US$ million
14
Mr A John Moyes
12 Technical Director
10 Intec Ltd
8 Gordon Chiu Building J01
6 Department of Chemical Engineering
4
Maze Crescent
University of Sydney NSW 2006
2
Australia
0
IGP BiOx POx Telephone: +612-9351-6741
Facsimile: +612-9351-7180
Figure 3: Comparative capital expenditure for Email: john@intec.com.au
50,000tpa of gold concentrate Website: www.intec.com.au