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1
= v
and has units of m3/kg.
Chapter 1:
Fluids and their Properties
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
7
4.2 Viscosity
The viscosity of a fluid is similar in concept to the modulus of rigidity of a solid, in that it links the
deformation of a right angle in a fluid to the shear stress applied to it. The major difference
between them is that a solid deforms by a fixed amount set by the shear stress applied, whereas
a fluid continually deforms. Thus, in a fluid, the shear stress is proportional to the strain rate, not
the strain. The constant of proportionality is the dynamic viscosity, usually abbreviated to the
viscosity.
Figure 4: Fluid Element
The rectangle shown in Figure 4 is a two-dimensional element of fluid moving parallel to the x-
axis. The velocity at y is u and at y + y is u + u. The rectangle deforms to the shape shown in
time t.
The shear strain, the deformation to the right angle, , can be determined from
( ) ( ) ( )
y
t u x t u u x
A
A + A A + +
= A tan
If the angle of deformation is small, and the limit is taken as y and t tend to zero, the strain
rate is given by
dy
du
dt
d
= =
Thus the shear stress, , is given by
dy
du
t =
where is the viscosity. Shear stress is a force per unit area and has units of N/m
2
. The SI unit of
viscosity is Ns/m
2
or Pas. This is Newtons law of viscosity. If the viscosity is independent of
Chapter 1:
Fluids and their Properties
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
8
velocity gradient the fluid is Newtonian, otherwise it is non-Newtonian. Water, oil and air are
Newtonian. The viscosity of a Newtonian fluid can vary with temperature and to a lesser extent
pressure. These variations can be accounted for by using interpolating equations. Liquids and
gases behave differently.
In general, liquid viscosity decreases with increasing temperature while gas viscosities increase
with increasing temperature. In many fluid mechanic applications, the ratio of the dynamic
viscosity to the density is required. This ratio is referred to as the kinematic viscosity and has
units of m
2
/s. Many non-Newtonian fluids can be characterised by an equation of the form
n
dy
du
B A
|
|
.
|
\
|
+ = t
where A, B and n are constants. Fluids described in this way have an apparent viscosity given by
1
|
|
.
|
\
|
=
n
dy
du
B
There are several subsets to these fluids (Figure 5), the most commonly occurring ones being
the power law fluids where A is zero, B is the consistency index and n is the flow behavioural
index. Power law fluids with a flow behavioural index less than one are call shear thinning, or
pseudo-plastic, fluids because the apparent viscosity decreases with increasing strain rate. Fluids
with the index greater than one are shear thickening, or dilatant, fluids because the apparent
viscosity increases with increasing strain rate. A polymer solution is a typical shear thinning fluid
and quicksand is an example of shear thickening fluid. The constant A is a threshold shear stress,
below which, the fluid acts as a solid. Strictly speaking this doesnt meet the definition of a fluid,
see section 3 (b). When A is not zero and n is one, the fluid is known as a Bingham plastic fluid,
of which sewage sludge is a common example. Finally, it is worth noting that some non-
Newtonian fluids have an apparent viscosity that varies with time. If the apparent viscosity
increases with time, the fluid is rheopectic. If it decreases with time it is thixotropic.
Figure 5: Newtonian and Non-Newtonian Fluids
Chapter 1:
Fluids and their Properties
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
9
4.3 Surface Tension and Contact Angle
In the bulk of a liquid, a molecule is, on average, held in equilibrium by the other molecules
surrounding it. As you near a free surface there are insufficient molecules to achieve this. This
causes a line tension at the surface. This line tension is known as the surface tension, . Surface
tension varies with temperature. Surface tension forces can only be significant when a free
surface is present, such as in a two-phase flow.
Figure 6: Contact Angle
N E
A similar phenomenon occurs when a liquid, solid and gas come together simultaneously. The
interactions between the liquid and solid molecules give rise to a contact angle as shown in
Figure 6. The contact angle is a property of the fluid relative to that solid material.
4.4 Properties of Perfect Gases
For any gas, the thermodynamic state is fully specified if any two properties are known. Typical
properties are pressure, temperature, specific volume, entropy and enthalpy. Gas equations of
state relate any property to up to any other two. A simple model of a gas, derived from the
kinetic theory of gases, is the perfect gas law, section 4.1. A perfect gas is one where:
(a) The volume occupied by the gas molecules is negligible in comparison to the volume
occupied by the gas.
(b) The forces of attraction between the gas molecules are negligible.
(c) Molecular collisions are perfectly elastic.
(d) The average kinetic energy of the molecules is proportional to the absolute temperature
of the gas.
Real gases approximate to ideal gases reasonably well when they are removed from their wet
fields. Gases like air can normally be treated as perfect. A gas will have energy by virtue of its
temperature. For a perfect gas the internal energy, i, is proportional to its absolute temperature,
thus
T C i
V
=
where C
v
is the specific heat at constant volume. For air the specific heat at constant volume is
718 J/kgK.
Chapter 1:
Fluids and their Properties
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
Fluid Mechanics
10
There are two types of fluid systems, open systems and closed systems. An example of a closed
system is a piston cylinder arrangement, where a gas is trapped between the piston and the
cylinder. An example of an open system is a pipe flow, where fluid enters the system and
subsequently departs from it. When a fluid has to cross a boundary, work has to be done to get
it to cross it. This work, or flow energy, frequently appears in fluid mechanic calculations as an
add-on to the internal energy.
The sum of these is referred to as the enthalpy, h. For a perfect gas the enthalpy is proportional
to the absolute temperature, thus
T C h
P
=
where C
p
is the specific heat at constant pressure. For air the specific heat at constant pressure is
1005 J/kgK. The relationships for internal energy and enthalpy and the perfect gas law implicitly
relate specific heats to the gas constant thus
R C C
V P
=
In gas dynamic calculations, the ratio of these specific heats frequently occurs. For a perfect gas
this ratio is known as the isentropic index, , i.e.
=
V
P
C
C
For air the isentropic index is 1.4 and is dimensionless.
4.5 Properties of Perfect Liquids
A perfect liquid is one that is incompressible. For a perfect liquid there is no difference between
the specific heat at constant pressure and the specific heat at constant volume and is simply
referred to as the specific heat capacity, C
l
. Real liquid are, to some extent compressible,
although the effect is usually negligible. For calculation purposes the specific heat at constant
pressure is used. This varies slightly with temperature and can be found from an interpolating
equation of the form
bT a C
P
+ =
Liquid properties do not vary much with pressure. The saturated liquid line values can therefore
normally be used, i.e. if the liquid is at T
2
, Figure 3, the saturated liquid properties can be used
whether it is saturated or subcooled.