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D
[1]
2.
B
[1]
3.
D
[1]
4.
B
[1]
5.
A
[1]
6.
B
[1]
7.
D
[1]
8.
(a)
(i)
(ii)
(iii)
IB Questionbank Chemistry
(b)
greater;
fewer intermolecular bonds/forces to break / vaporization is
endothermic / gaseous fuel has greater enthalpy than liquid fuel / OWTTE;
M2 cannot be scored if M1 is incorrect.
2
[7]
9.
D
[1]
10.
D
[1]
11.
D
[1]
12.
A
[1]
13.
D
[1]
14.
C
[1]
15.
B
[1]
16.
D
[1]
IB Questionbank Chemistry
17.
A
[1]
18.
A
[1]
19.
(a)
(i)
Copper:
0 to +2 / increases by 2 / +2 / 2+;
Allow zero/nought for 0.
Nitrogen:
+5 to +4 / decreases by 1 / 1 / 1;
Penalize missing + sign or incorrect notation such as 2+, 2+
or II, once only.
(ii)
(b)
0.100 0.0285;
2.85 103 (mol);
Award [2] for correct final answer.
(ii)
(iii)
0.181
100 =
0.456
39.7 %
44.2 39.7
100 =
44.2
10/10.2 %;
Allow 11.3 % i.e. percentage obtained in (iv) is used to
divide instead of 44.2 %.
(i)
(iv)
(v)
IB Questionbank Chemistry
(c)
Brass has:
delocalized electrons / sea of mobile electrons / sea of electrons
free to move;
No mark for just mobile electrons.
1
[10]
20.
B
[1]
21.
B
[1]
22.
A
[1]
23.
D
[1]
24.
(a)
n(HCl)(= 0.200 mol dm3 0.02720 dm3) = 0.00544 / 5.44 103 (mol);
(b)
(c)
(d)
IB Questionbank Chemistry
(e)
n(CaCO3) = ( 2 n(HCl)) =
1
2
0.00306;
0.153
100
=
0
.
188
= 81.4 % / 81.5 %
%CaCO3
Accept answers in the range 79.8 to 81.5 %.
Award [3] for correct final answer.
(g)
1
[11]
25.
C
[1]
26.
D
[1]
27.
D
[1]
28.
B
[1]
29.
C
[1]
IB Questionbank Chemistry
30.
C
[1]
31.
(a)
81.7
18.3
nC = 12.01 = 6.80 and nH = 1.01 = 18.1;
ratio of 1: 2.67 /1: 2.7;
C3H8;
No penalty for using 12 and 1.
(b)
C3H8;
(c)
(i)
Br2 /bromine;
UV/ultraviolet light;
Accept hf/hv/sunlight.
(ii)
(d)
Initiation:
Br2 2Br;
Propagation:
Br + RCH3 HBr + RCH2;
RCH2 + Br2 RCH2Br + Br;
Termination: [1 max]
Br + Br Br2;
RCH2 + Br RCH2Br;
RCH2 + RCH2 RCH2CH2R;
Award [1] for any termination step.
Accept radical with or without throughout.
Do not penalize the use of an incorrect alkane in the mechanism.
(e)
(i)
IB Questionbank Chemistry
4 max
(ii)
3
[16]
32.
C
[1]
33.
D
[1]
34.
A
[1]
35.
C
[1]
36.
C
[1]
IB Questionbank Chemistry
37.
B
[1]
38.
B
[1]
39.
(a)
(b)
(c)
ester;
1013.0
amount of oil = 885.6 = 1.144 mol;
200.0
amount of methanol = 32.05 = 6.240 mol;
since three mol of methanol react with one mol of vegetable oil the
amount of excess methanol = 6.204 (3 1.144) = 2.808 mol;
(i)
rate of the forward reaction is equal to the rate of the reverse reaction /
forward and reverse reactions occur and the concentrations of the
reactants and products do not change / OWTTE;
[glycerol] [biodiesel] 3
(ii)
(iii)
(iv)
(d)
3
Kc = [ vegetable oil] [methanol] ;
IB Questionbank Chemistry
(e)
(f)
1
[14]
40.
(a)
(b)
(i)
Fe2+ Fe3+ + e;
(ii)
(iii)
(i)
11.6
amount of MnO4 = 1000 0.0200 = 2.32 104 mol;
(ii)
(iii)
[7]
41.
D
[1]
42.
C
[1]
IB Questionbank Chemistry
43.
B
[1]
44.
D
[1]
45.
(a)
(b)
(i)
Mr(C7H6O3) = 138.13;
3.15
=
138
.
13
(iii)
(iv)
(v)
Mr(C9H8O4) = 180.17;
m = (180.17 2.28 102 =) 4.11(g);
Accept range 4.104.14
Award [2] for the correct final answer.
2.50
(percentage yield = 4.11 100 =) 60.8 %;
Accept 6061 %.
3;
0.02
(percentage uncertainty = 2.50 100 =) 0.80 %;
Allow 0.8 %
1
[11]
IB Questionbank Chemistry
10
46.
C
20.2
12.01
= 1.68
1.68
0.814 = 2
N
11.4
14.01
= 0.814
0.814
0.814 = 1
O
65.9
16.00
= 4.12
4.12
0.814 = 5
H
2.50
1.01
= 2.48
;
2.48
0.814 = 3 ;
C2NO5H3;
No penalty for use of 12, 1 and/or 14.
Award [1 max] if the empirical formula is correct, but no working shown.
3
[3]
47.
C
[1]
48.
B
[1]
49.
D
[1]
50.
D
[1]
51.
C
[1]
52.
(a)
(b)
Award [1 max] for correct balanced equation but with electrons shown.
Ignore state symbols.
Fe2+/ iron(II);
Do not accept iron.
IB Questionbank Chemistry
11
(c)
(d)
(e)
2
[9]
53.
C
[1]
54.
D
[1]
55.
B
[1]
56.
C
[1]
57.
C
[1]
58.
C
[1]
IB Questionbank Chemistry
12
59.
(a)
2
Penalize incorrect units.
(c)
0.200 mol;
1
Use ECF from (a).
(d)
(e)
60.
CC
N:;
3
[3]
IB Questionbank Chemistry
13