Conferina Naional a Societii Geologice a Romniei, Ploieti, 18 Decembrie 2013

POSTER

THE X-RAY DIFFRACTION STUDY OF THE STIBNITE CRYSTAL STRUCTURE

GHEORGHE-ADRIAN BRANOIU1, BOGDAN STANCIU1

1

Universitatea Petrol-Gaze din Ploiesti, a!"ltatea In#ineria Petrol"l"i si Gazelor, De$arta%ent"l GPI&, B-d"l B"!"resti nr' (), !od $ostal 1**+,*, gbranoiu@yahoo.com
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Universitatea Petrol-Gaze din Ploiesti, a!"ltatea In#ineria Petrol"l"i si Gazelor, S$e!ializarea Geolo#ia Res"rselor Petroliere, nox_pater@yahoo.com

Key words: Rietve d !et"od# str$%t$re re&i'e!e't# Her() ore de*osit# Neo+e'e vo %)'ites# ,$t)i -o$'t)i's T.e !r/stal str"!t"re o0 t.e sti1nite sa%$le 0ro% Her2a 34ara%"res !o"nt/, nort.ern Ro%ania5 6as re0ined "sin# 7-Ra/ $o6der di00ra!tion data and t.e Rietveld %et.od' T.e st"died sa%$le 30i#"re 15 !o%es 0ro% t.e !olle!tion o0 %ineralo#/ la1orator/ o0 Petrole"%-Gas Universit/ o0 Ploiesti, and 6as !olle!ted 0ro% t.e vein 1* Salan o0 Her2a ore de$osit'

i#"re 1' Sti1nite sa%$le 0ro% Her2a ore de$osit' ro% #eolo#i!al $oint o0 vie6 t.e Her2a $eri%eter 1elon#s to t.e Neo#ene vol!anites zone o0 Eastern Car$at.ians, lo!all/ 1ein# sit"ated in t.e G"tai 4o"ntains' T.e Her2a ore de$osit is lo!ated 1et6een C.i"z1aia 8alle/ and iriza 8alle/, a1o"t 9:% N; o0 Baia S$rie to6n' In t.e Her2a zone are :no6n sedi%entar/ tertiar/ and Neo#ene %a#%ati! 0or%ations' T.e sedi%entar/ 0or%ations 1elon# to t.e Eo!ene, Sar%atian and Pannonian' T.e Neo#ene %a#%atites are re$resented 1/ vol!ani! $rod"!ts and 1/ intr"sive 1odies' T.e vol!ani! $rod"!ts are re$resented 1/ lava 0lo6s and s"1ordinatel/, $/ro!lasti! ro!:s' T.e v"l!anites are re$resented 1/ $/ro<ene and ="artz andesites 3Da%ian, -**(5'

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Conferina Naional a Societii Geologice a Romniei, Ploieti, 18 Decembrie 2013

T.is ore de$osit re$resented 1/ ./drot.er%al veins oriented NE-S;, is lo!ated in andesiti! er"$tions 0ro% t.e Neo#ene $eriod' T.e $ol/%etalli! %ineralized veins !ontains a 6ide variet/ o0 %etalli! %inerals> s$.alerite, #alena, $/rite, $/rr.otite, sti1nite, !.al!o$/rite, arseno$/rite, 2a%esonite, tetra.edrite, se%se/ite, and non%etalli! %inerals> ="artz, siderite, an:erite, !al!ite, #/$s"%, 1ar/te and vivianite' T.e ./drot.er%al veins s.o6 di00erent t/$es o0 str"!t"res> %assive, r"1anate, 1re!!iated and !on!entri! 3Po$es!", 1)?+5' T.e sti1nite !r/stals s.a$ed li:e slender $ris%s t.ere are o0ten striated and or $arallel lines on !r/stal s"r0a!e or !leava#e 0a!es' ;.ere one t6in $lane 1ends t.e !r/stal one dire!tion and anot.er t6in $lane 1ends it in t.e ot.er dire!tion' T.e ="alit/ o0 t.e sti1nite sa%$le 6as #ood, t.is 1ein# !o%$osed onl/ o0 sti1nite !r/stals' Sti1nite is t.e %ost !o%%on and 6ides$read anti%on/ %inerals, and is one o0 t.e end ter%s o0 t.e sti1nite-1is%"t.inite iso%or$. series, !r/stallized in t.e ort.or.o%1i! s/ste%' T.e sti1nite str"!t"re !onsists o0 @S1AS+Bn !.ains $arallel to t.e c a<is' Ea!. anti%on/ ato% 6it.in a !.ain is !oordinated 1/ 0ive s"l0"r ato%s 0or%in# a s="are $/ra%id 3S!avni!ar, 1)+*5' T.e sa%$le 6as #ro"nd in an a#ate %ortar 6it. $estle to $arti!le size s%aller t.an a1o"t -*C%' 7-ra/ $o6der di00ra!tion data 6ere %eas"red at -ADC "sin# an a"to%ated Br":er D, Advan!e E-E di00ra!to%eter, 6it. C"FG radiation 3H I 1,9AJK A*:8K A*%A5, a L/n<E/e solid-state Si dete!tor and Bra##-Brentano #eo%etr/' FM radiation 6as eli%inated 1/ a Ni 0ilter' Pri%ar/ and se!ondar/ Soller slits 6ere -'9D' A 0i<ed a$ert"re and diver#en!e slit o0 *'+%%, a *'+%% antidiver#en!e slit and *'1%% 6idt. dete!tor slit 6ere "sed' 7-ra/ di00ra!tion data 6ere o1tained "sin# *'1D -E ste$s 0ro% 1*D to +*D -E !o"ntin# 0or 1* s $er ste$'

i#"re -' (D vie6 o0 t.e sti1nite !r/stal str"!t"res res"lted 0ro% Rietveld re0ine%ent' T.e Rietveld re0ine%ents 6ere !arried o"t "sin# t.e !o%$"ter $ro#ra% Di00ra!$l"s TOPAS A'1 3Br":er-A7S G%1H5' or t.e 0it o0 t.e $ea:s .as 1een "sed $se"do-8oi#t $ro0ile 0"n!tion' Rietveld re0ine%ent "sin# 7-Ra/ $o6der di00ra!tion data o0 sti1nite sa%$le in t.e s$a!e #ro"$ Pnma 3No'+-5 3Ha.n, -**95> aI11'(*?J, bI(',((J, cI11'-1?J, ZIA, !r/ size LI1+*n%, !r/ densit/ 3#N!%O(5IA'+A, 3--si#%aI*'*1+5, R6$I)'+,, Re<$I,'1(, R$I1*'*1, !on0ir% t.e 1asi! sti1nite str"!t"re' Ta1le 1> Ato%i! $ositional $ara%eters 0or t.e sti1nite str"!t"re res"lted 0ro% Rietveld re0ine%ent' Ato! S11 S1S1 SS( N* A A A A A . *'A?(,? *'(A((9 *'-,+A) *'9A+,1 *'(?--9 y *'-9*** *'?9*** *'-9*** *'?9*** *'?9*** / *'(1+)+ *'*(*A( *'-1?() *'1A1-+ *'A99?? O%% 1 1 1 1 1 Be0 1'A?1, 1'9,+1'+*+1 1'+,A* 1'(A?+ 1-si+!) *'*19A *'*+?A *'*(+? *'*199 *'*(1+

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Conferina Naional a Societii Geologice a Romniei, Ploieti, 18 Decembrie 2013

T.e 0i#"res o0 %erit 3Po"n#, 1))+K Pe!.ars:/ and &avali2, -**)5 6ere> #oodness-o0-0it GO I1'1), Q-I1'A1 and t.e D"r1in-;atson statisti! dI-'1+' T.e ato%i! $ositional $ara%eters 0or t.e sti1nite str"!t"re res"lted 0ro% t.e Rietveld re0ine%ents are $resented in t.e ta1le 1' T.e $a$er $rovides a ne6 set o0 t.e "nit !ell $ara%eters and 0ra!tional !oordinates t.at de0ine t.e sti1nite str"!t"re' Re&ere'%es Br":er A7S G%1H Farlsr".e, -**,' TOPAS AT"torial' Da%ian G.', -**(' T.e #enesis o0 t.e 1ase %etal ore de$osit 0ro% Her2a, St"dia Univ' Ba1eR-Bol/ai, Geolo#ie, 7L8III, 1, ,)' Ha.n T.', -**9' International Ta1les 0or Cr/stallo#ra$./, 8ol"%e A, 9t. Edition, S$a!e Gro"$ S/%%etr/' 3IUCr Series5' S$rin#er' Nea%" G'4', Ri H'R', Son# H', Branoi" G.'A, -*11, T.e re0ine%ent o0 t.e 0l"orite str"!t"re 0ro% Her2a 3Ro%ania5, St"dents:T #eolo#i!:T :on0eren!e -*11, Univerzita Farlova v Praze, PUVrodovWde!:T 0a:"lta, Pra.a' Pe!.ars:/ 8'F', &avali2 P'P', -**)' "nda%entals o0 Po6der Di00ra!tion and Str"!t"ral C.ara!terization o0 4aterials, Se!ond Edition, S$rin#er' Po$es!" G.', 1)+A' O1servatii as"$ra !atorva as$e!te %or0olo#i!e ale "nor !ristale din za!a%ant"l Her2a 3Baia 4are5' Analele Universitatii B"!"resti, Seria Geolo#ie-Geo#ra0ie, To%e 7III, nr' 1, $' )(-1*9' S!avni!ar S', 1)+*' T.e !r/stal str"!t"re o0 sti1nite' A redeter%ination o0 ato%i! $ositions' &eits!.ri0t 0Xr Fristallo#ra$.ie, 11A, ,9-)?' Po"n# R'A', 1))+' T.e Rietveld 4et.od, O<0ord Universit/ Press 3Great Britain5, -), $$'

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