Professional Documents
Culture Documents
Hansen et al.
[54] FROTHERS DEMONSTRATING ENHANCED
RECOVERY OF COARSE PARTICLES IN FROTH FLOATATION
[75] Inventors: Robert D. Hansen; Roger W. Bergman; Richard R. Klimpel, all of Midland, Mich.
[73] Assignee:
[57]
ABSTRACT
prises subjecting the raw coal or mineral ore in the form of an aqueous pulp, to a ?oatation process in the pres
ence of a ?oatation collector, and a ?otating amount of
Jun. 4, 1934
a ?oatation frother which comprises the reaction prod uct of an alitphatic C6 alcohol and between about 1 and
568/618; 568/622
[58] Field Of Search .............. .. 568/622, 618; 209/166,
209/167; 252/61
15 Claims, N0 Drawings
4,582,596
inability of many commercial froth ?otation processes to recover large particles of valuable minerals. Many of the frothers described hereinbefore demonstrate an inability to recover ef?ciently the coarse particles in a froth ?otation process. What are needed are mining
This invention relates to novel froth ?otation frothers which demonstrate enhanced recovery of coarse parti cles in froth ?otation. Froth ?otation is a commonly employed process for
concentrating minerals from ores. In a ?otation process, the ore is crushed and wet ground to obtain a pulp. A
values to adhere to the bubbles formed during this aera mineral values are recovered. tion step. The adherence of the mineral values is selec The process of this invention is a process in which the tively accomplished so that the portion of the ore not recovery of coarse particles of the desired mineral val containing mineral values does not adhere to the bub bles. The mineral-bearing froth is collected and further 25 ues is surprisingly higher than processes heretofore known. The particular frothers used in this invention processed to obtain the desired minerals. That portion
of the ore which is not carried over with the froth,
presence of a ?otation collector, and a ?otating amount of a ?otation frother which comprises the reaction product of an aliphatic C6 alcohol and between about 1 and 5 moles of propylene oxide, butylene oxide or mix tures thereof, under conditions such that the coal or
usually identi?ed as ?otation tailings, is usually not further processed for extraction of mineral values there from. The froth ?otation process is applicable to ores containing metallic and nonmetallic mineral values.
In ?otation processes, it is desirable to recover as
particles while maintaining ef?cient recoveries of me dium and ?ne particle sizes of mineral values.
DETAILED DESCRIPTION OF THE INVENTION
much mineral values as possible from the ore while effecting the recovery in a selective manner, that is, without carrying over undesirable portions of the ore in the froth. While a large number of compounds have foam or
The process of this invention results in an improved and ef?cient process for the recovery of coal and min eral values with enhanced recovery of the coarse parti
cles of the coal and mineral values. Critical to the en
hanced recovery of such coarse particles is the choice of the frother to be used. The frother which gives such enhanced recovery of the coarse particles is the reaction
40 product of a C6 alcohol and between about 1 and 5
monohydroxylated compounds such as C54; alcohols, pine oils, cresols and C1_4alkyl ethers of polypropylene glycols as well as dihydroxylates such as polypropylene glycols. The frothers most widely used in froth ?otation operations are compounds containing a nonpolar, wa ter-repellant group and a single, polar, water-avid group such as hydroxyl (OH). Typical of this class of frothers are mixed amyl alcohols, methylisobutyl carbi
moles of propylene oxide, butylene oxide or mixtures thereof. The C6 alcohol can be any alicyclic straightor branched-chain alcohol. Examples of such alcohols
thyl)butanol), l-methyl pentanol, 2-methyl pentanol, 3-methyl pentanol, 4-methyl pentanol, l-(l,2-dimethyl)
butanol, 1-(l-ethyl-)butanol, l-(2-ethyl)butanol, l-(l
ethyl-2-methyl)propanol, l-(l,l,2-trimethyl)propanol, l-( l , l -dimethyl)butanol, 50 l-( l ,2,2-trimethyl)propanol,
alkyl ethers of polypropylene glycol, especially the methyl ether and the polypropylene glycols of
140-2100 molecular weight and particularly those in the 200-500 range. In addition, certain alkoxyalkanes, e.g.,
triethoxybutane, are used as frothers in the ?otation of
certain ores.
about 1 and 5 moles of the described propylene oxide, butylene oxide, or mixtures thereof. Preferably, the
since commercial operations often handle as much as 60 frothers are the reaction product of a C6 alcohol and
tons of minerals daily. Obviously then, any frother which promotes improved mineral recovery, even though small, is very desirable and can be advantageous in commercial flotation operations.
uct of a C6 alcohol and about 2 moles of propylene oxide, butylene oxide, or mixtures thereof. The pre
ferred alkylene oxide is propylene oxide. Preferred frothers of this invention correspond gen
erally to the formula
4,582,596
trated by froth ?otation using the process of this inven tion include copper-bearing ores, such as cuprite
ethyl; and n is an integer of between about 1 and 5 inclusive; with the proviso that one R2 in each unit must be methyl or ethyl, and with the further proviso that - 0 hematite and magnetite; chromium-containing ores, when one R2 in a unit is ethyl, the other R2 must be such as chromite (FeOCrgOg); iron- and titanium-con hydrogen. R2 is preferably hydrogen or methyl. Prefer taining ores, such as ilmenite; magnesium- and alumi ably, n is an integer of between about 1 and 3 inclusive, num-containing ores, such as spinel; iron-chromium with about 2 being most preferred. In the embodiment containing ores, such as chromite; titanium-containing wherein propylene oxide is the alkylene oxide used, in 5 ores, such as rutile; manganese-containing ores, such as each repeating unit of the hereinbefore described for pyrolusite; tin-containing ores, such as cassiterite; and mula, one R2 must be methyl while the other R2 must be uranium-containing ores, such as uraninite; and urani hydrogen. um-bearing ores such as, for example, pitchblende The frothers of this invention can be prepared by (U2O5(U3O3)) and gummite (UO3nH2O). Other metal contacting the C6 alcohol with the appropriate molar values for which this process is useful include gold amount of propylene oxide, butylene oxide or mixtures bearing ores, such as sylvanite (AuAgTeg) and calaver thereof, in the presence of an alkali catalyst such as an ite (AuTe); platinum- and palladium-bearing ores, such alkali metal hydroxide, an amine, or boron tri?uoride. as sperrylite (PtAsz); and silver-bearing ores, such as Generally, between about 0.5 and 1 percent of the total hessite (AgTez). weight of the reactants of the catalyst can be used. In 25 In a preferred embodiment of this invention, coal or general, temperatures of up to 150 C. and pressures of sul?de-containing ores are recovered. In a more pre
up to 100 psi can be used for the reaction. In that em
azurite (Cu3(OH)2(CO3)2), atacamite (Cu2Cl(OH)3), chrysocolla (CuSiO3); aluminum-bearing ores, such as corundum; zinc-containing ores, such as zincite (ZnO), and smithsonite (ZnCOg); iron-containing ores, such as
ferred embodiment of this invention, coal, copper sul ?de, nickel sul?de, lead sul?de, zinc sul?de or molybde
num sul?de are recovered. In an even more preferred embodiment, coal or copper sul?de values are recov-'
ef?cient flotation of large particle sizes of the coal and coal contains both the valuable coal and what is known 35 mineral values to be recovered. For the purposes of this invention, coarse particle size in reference to coal refers in the art as gangue. Gangue refers herein to those mate to a particle size of 500 microns or greater (+35 mesh). rials which are of no value and need to be separated For the purpose of this invention, coarse particle size in from the coal. A metal ore refers herein to the metal as reference to metal values means a particle size of 250 it is taken out of the ground and includes the metal microns or greater (60+mesh). Not only do the frothers values in admixture with the gangue. This process can of this invention ef?ciently ?oat coarse particle size be used to recover metal oxides, metal sul?des and coal and metal values, but they also ef?ciently ?oat the other metal values. medium and ?ne size coal and metal value particles. The Sul?de ores for which these compounds are useful use of the frothers of this invention results in an increase include copper su1?de-, zinc sul?de-, molybdenum sul ?de-, cobalt sul?de-, nickel sul?de-, lead sul?de-, ar 45 of 2 percent or greater in recovery of the coarse parti
senic sul?de-, silver sul?de-, chromium sul?de-, gold sul?de-, platinum sul?de- and uranium sul?de-contain
ing ores. Examples of sul?de ores from which metal sul?des may be concentrated by froth ?otation using the process of this invention include copper-bearing ores such as, for example, covellite (CuS), chalcocite
duct of propanol and propylene oxide as the frother. Preferably, an increased recovery of 10 percent, and most preferably an increased recovery of 20 percent is
achieved. '
(CuZS), chalcopyrite (CUFCSz), valleriite (CuzFe4S7 or Cu3Fe4S7), bornite (Cu5FeS4), cubanite (Cu2SFe4S5), enargite (Cu3(As1Sb)S4), tetrahedrite (Cu3SbS2), ten
nantite (Cu12As4S13), brochantite (Cu4(OH)6SO4), ant lerite (Cu3SO4(OH)4), famatinite (Cu3(SbAs)S4), and
bournonite (PbCuSbS3); lead-bearing ores such as, for
The amount of the frother used for froth ?otation depends upon the type of ore used, the grade of ore, the size of the ore particles and the particular frother used. Generally, that amount which separates the desired coal
or metal values from the raw coal or metal ore is suit
able. Preferably between about 0.005 and 0.5 lb/ton (0.0025 and 0.25 kg/metric ton) can be used. Most pref erably, between about 0.01 and 0.2 lb/ton (0.005 and 0.1 example, galena (PbS); antimony-bearing ores such as, kg/metric ton) are used. The froth ?otation process of for example, stibnite (Sb253); zinc-bearing ores such as, for example, sphalerite (ZnS); silver-bearing ores such 60 this invention, usually requires the use of collectors. Any collector well-known in the art, which results in as, for example, stephanite (Ag5SbS4), and argentite the recovery of the desired coal or metal value is suit (AggS); chromium-bearing ores such as, for example, able. Further, in the process of this invention it is con daubreelite (FeSCrS3); and platinum- and palladium templated that the frothers of this invention can be used bearing ores such as, for example, cooperite (Pt(AsS)2).
copper oxide-, aluminum oxide-, iron oxide-, iron tita~ nium oxide-, magnesium aluminum oxide-, iron chro mium oxide-, titanium oxide-, manganese oxide-, tin
Oxide ores for which this process is useful include 65 in mixtures with other frothers known in the art. Collectors useful in this invention include any collec tors known in the art which give recovery of the de
4,582,596
invention include alkyl monothiocarbonates, alkyl dithi ocarbonates, alkyl trithiocarbonates, dialkyl dithiocar
bamates, alkyl thionocarbamates, dialkyl thioureas, monoalkyl dithiophosphates, dialkyl and diaryl dithio
crusher and then screened through a 25 mesh sieve. The coarse portion is passed through a hammer mill. The two streams are combined, blended, and then split suc
blade mechanized froth removal paddle that revolves at primary amines, secondary amines, tertiary amines, 10 rpm. The pulp level is maintained by means of a quaternary ammonium salts, alkyl pyridinium salts, constant level device that introduces water as the pulp guanidine, and alkyl propylene diamines. Collectors 5 level falls. useful in froth ?otation of coal such as kerosene, diesel The 200-g sample of coal is conditioned in 2800 cc of oil, fuel oil and the like may be used in this invention. deionized water for 6 minutes with the agitator revolv Furthermore, blends of such known collectors can be ing at 900 rpm. The pH is measured at this time, and used in this invention also. typically is 5.1. After the 6-minute conditioning period, In the process of this invention, the frothers described the collector is added (Soltrol puri?ed kerosene); hereinbefore can be used in admixture with other well after a one-minute conditioning period, the frother is known frothers. Examples of such frothers include C54;
pylene glycols, dihydroxylates of polypropylene gly cols, glycols, fatty acids, soaps, alkylaryl sulfonates, and
the like. Furthermore, blends of such frothers may also
be used. All frothers which are suitable for bene?ciation of mineral ores and coal by froth ?otation can be used in this invention.
25
the air is started at 9 liters/minute and the paddle is energized. The frother is collected after 3 paddle revo
SPECIFIC EMBODIMENTS
ties in a cut, the sample is split with a rif?e splitter until Unless otherwise indicated, all parts and percentages are by weight. 35 a small enough sample is available for an ash determina In the following examples, the performance of the tion. The weight versus time is then calculated for the frothing processes described is shown by giving the rate clean coal as well as the ash for each ?otation run. The
constant of ?otation and the amount of recovery at
1
wherein: )1 is the amount of mineral recovered at time t, k is the rate constant for the rate of recovery and R,o is the calculated amount of the mineral which would be
recovered at in?nite time. The amount recovered at
perimentally determined recovery associated with 4 minutes of ?otation. The experimental error in R-4 minutes is $0.015. In Tables I, II and III, MIBC refers to methyl isobu
tyl carbinol, MIBC-ZPO refers to the reaction product of methyl isobutyl carbinol and two equivalents of 45 propylene oxide, and MIBC-BPO refers to the reaction
various times is determined experimentally and the se ries of values are substituted into the equation to obtain the R,(, and k. The above formula is explained in Klim
pel Selection of Chemical Reagents for Flotation, Chapter 45, pp. 907-934, Mineral Processing Plant De
lents of propylene oxide. DF-200 refers herein to DOWFROTH 200 (Trademark of The Dow Chemi cal Company) which is a methyl ether of propylene glycol with an average molecular weight of 200. DE 400 refers herein to DOWFROTH @400 (Trademark of The Dow Chemical Company) which is a polypro pylene glycol with an average molecular weight of about 400. DF-10l2 refers to DOWFROTH l0l2
55
Froth Flotation of Coal lents of propylene oxide. TPGME-lPO refers to the The frothers of this invention, along with several 60 reaction product of tripropylene glycol methyl ether and one equivalent of propylene oxide. TEB refers to known frothers are used to ?oat coal using 0.2 lb/ton of triethoxybutane. Phenol-4P0 refers to the reaction frother and 1 lb/ton of the collector Soltrol.
Experimental Procedure:
oxide. Heptanol-2PO refers to the reaction product of The major coal tested is a bituminous Pittsburgh Seam coal which is slightly oxidized, which is a good 65 heptanol and two equivalents of propylene oxide. Pen tanol-ZPO refers to the reaction product of pentanol test coal for reagent evaluation and comparisons, as it
exhibits very typical (average) coal ?otation character istics. The coal, as received, is passed through a jaw
4,582,596
two equivalents of propylene oxide. Hexanol-lPO-IEO is the reaction product of hexane], one equivalent of propylene oxide and one equivalent of ethylene oxide.
8
EXAMPLE 2
Flotation of Coal MIBC-2P0 with MIBC is a blend of MIBC-2P0 and A series of froth ?otation experiments on coal using MIBC. Z-Ethylhexyl a1cohol~2PO and 2-ethy1hexy1 5 the novel frothers of this invention and other known alcohol-3P0 refers to the reaction product of Z-ethyl frothers is run using the same procedure as described in hexyl alcohol and 2 and 3 equivalents of propylene Example 1, with the exception that the collector con oxide, respectively. Hexanol-ZPO refers herein to the centration is 2 lb/ton (1.0 kg/metric ton). The results reaction product of hexane] and 2 equivalents of propy are compiled in Table II. The experimental error in R-4
lane oxide 10 minutes is i0.015.
TABLE I
Total
Frother
MIBC-2P0
Portion
A B C A B C A B C A B C A B C A B C A B C A B C A
K
11.3 6.2 1.8 15.5 9.5 1.6 20.6 14.0 1.5 8.9 5.0 1.8 11.1 7.3 1.5 15.6 8.9 1.8 14.2 7.3 1.9 10.1 5.9 1.7 6.4
R
0.80 0.24 3.3 0.77 0.19 4.1 0.48 0.11 4.4 0.46 0.10 4.6 0.73 0.23 3.2
K
21.4 21.5 1.0 40.0 20.8 1.9 35.4 34.9 1.0 12.6 7.8 1.6 22.0 11.6 1.9
+352 R
0.38 0.040 9.5 0.33 0.026 12.7 0.25 0.030 8.3 0.12 0.017 12.0 0.27 0.028 9.6
R-4 min
0.373
35 X 1703 K R
13.3 10.0 1.3 22.2 17.6 1.3 40.0 29.7 2.2 16.3 9.8 1.7 14.5 13.4 1.1
_ i704 R
1.00 0.41 2.4 0.97 0.38 2.6 0.75 0.16 4.7 0.85 0.23 3.7 0.99 0.40 2.5
MIBC-3P0 (crude)
0.325
MIBCl
0.255
DF-200l
0.130
DF-400l
0.270
0.81 8.3 0.22 3.9 3.7 2.1 0.77 9.7 0.18 5.9 4.3 1.6 0.41 10.2 0.092 9 3 4.5 1.1 0.33 62 0.055 3 9 6.0 1.6 0.71 78 0.23 4.7 3.1 1.7
DF-1012l
IPA-2P0I (crude)
TPGME-IPOI
TEBl
B
Ct'esylicl acid
Phenol-4PO1
C A B C A B
C
3.4
1.9 3.5 1.0 3.5 9.4 5.8
1.6
0.74 0.19 3.9 0.71 0.21 3.4 0.63 0.17 3.8 0.46 0.10 4.5 0.14 0.081 1.7 0.62 0.17 3.6
28.8 20.7 2.0 28.2 12.0 2.4 17.0 10.1 1.7 13.6 8.0 1.7 1.0 3.6 0.3 17.3 9.6 1.8
0.28 0.024 11.3 0.25 0.026 9.6 0.19 0.013 14.6 0.083 0.0085 9.8 0.047 0.014 3.4 0.14 0.018 7.8
0.274
0.254
0.184
0.0847
0.0355
0.145
23.0 17.8 1.3 19.7 12.2 1.6 14.4 12.2 1.2 10.2 6.1 1.7 1.9 0.7 2.7 12.9 10.1
1.3
0.74 0.17 4.4 0.68 0.18 3.8 0.56 0.13 4.3 0.31 0.053 5.8 0.077 0.066 1.2 0.55 0.13 4.1
99 5.5 1.8 96 5.3 1.8 7.2 4.13 1.7 4.6 2.7 1.7 4.7 1.3 3.6 6.8 4.0
1.7
0.97 0.38 2.6 0.99 0.38 2.6 0.97 0.39 2.5 0.91 0.27 3.4 0.34 0.13 2.6 0.95 0.34 2.8
A : Clean coal ?oated B = Gangue ?oated C : Ratio of clean coal to gangue ?oated
1Not an embodiment of the invention ZParticles recovered with a size of greater than 35 mesh 3Particles recovered with a size of between 35 and 170 mesh articles recovered with a size of less than 170 mesh
TABLE II
Total +35 35 X 170 170
Frother
MIBC-2P0
Portion
A 13 C A
B
K
8.7 4.5 1.9 5.7
4.7
R
0.88 0.25 3.5 0.70
0.14
K
10.9 5.3 2.1 12.4
8.2
R
0.55 0.072 7.9 0.29
0.035
R4 min
0.526
K
9.6 7.1 1.4 14.0
8.7
R
0.89 0.22 4.1 0.51
0.11
K
7.8 3.5 2.2 5.0
3.7
R
1.00 0.45 2.2 0.88
0.23
MIBCI
0.295 0.158
0.491
0.392
1315-200l
DF-4001
DF-1O121
C A B
C
Heptanol-ZPOl
l-Penta-
nOI'ZPOI
A B C A B C A B C A B C
10.9 7.1 1.5 9.3 5.7 1.6 6.3 6.1 1.0 6.8 6.0 1.1
0.87 0.25 3.5 0.86 0.22 3.9 0.91 0.24 3.8 0.93 0.28 3.3
19.2 29.5 0.7 12.6 11.2 1.1 10.0 12.0 0.8 11.7 13.9 0.8
0.50 0.042 11.9 0.41 0.037 11.1 0.48 0.033 14.5 0.52 0.038 13.7
0.454
0.504
13.7 11.6 1.2 11.0 8.4 1.3 6.6 7.6 0.9 7.4 8.3 0.9
0.88 0.24 3.6 0.90 0.20 4.6 0.92 0.25 3.7 0.93 0.28 3.3
8.0 4.6 1.7 7.4 4.0 1.8 54 4.4 1.2 6.1 3.9 1.6
1.00 0.42 2.4 1.00 0.43 2.3 1.00 0.40 2.5 1.00 0.49 2.0
9
TABLE II-continued
Total Frother Portion K R K +35 R R-4 min
4,582,596
35 X 170 K R 170 R
10
Cyclohexano1-2POl
Hexanol
A B
C A
6.0 5.0
1.2 9.9
0.86
0.19 4.5 0.54
39.2 4.1
9.6 26.7
0.31 0.091
3.4 0.26
0.306
0.256
HexanollPO-lEO
B C A B
C
0.475
4.6 3.3
1.4 5.3
EXAMPLE 3
A bituminous Pittsburgh Seam coal, non-oxidized is The rod mill is then rotated at 60 rpm for a total of 360 exposed to froth ?otation conditions identical to those revolutions. The ground slurry is transferred to a 1500 described in Example 1. The results are compiled in 20 ml cell of an Agitair Flotation machine. The ?oat cell is Table III. agitated at 1150 rpm and the pH is adjusted to the de TABLE III
Frother Portion T0131 K R K +35 R R-4 min 35 X 170 K R K _170 R
MIBC-ZPO (015111160)
Hexanol-ZPO
A 13
c A B
6.8 4.7
1.4 7.9 7.4 1.1 4.5
4.2
1.00 0.30
6.9 7.2
0.64 0.049
13.1 0.60 0.054
0.600
0.588
7.0 5.9
1.2 8.6 8.2 1.0 4.2
5.3
1.00 0.51
2.0 1.00 0.45 2.2 1.00
0.46
c
MIBC-ZPO
4 with MIBC
A
13
3.3 1.0 0.94 11.7 0.26 11.0 3.6 1.1 0.93 6.4
0.25 6.9
11.1
0.47
0.031
0.433
0.24 3.0
MIBC-ZPO (crude)
Isopropan61-27Po1-2
c A 13 c A B c
3.7 0.9 1.00 6.9 0.23 7.7 3.6 0.9 0.92 10.1 0.27 3.6 3.4 2.3
0.510
0.509
Hepta1161-21301
l-Penta1161-21301
A 13
c A B c A B c A B c A B c
Cyclohexanol-2PO1
MIBC 13112001
DF-4001
2-ethyl~ llCXyl 81001161-21101 Z-ethylhexyl alcohOl-3PO1
A B c A 13 c A B c
6.3 6.1 1.0 6.3 6.0 1.1 6.0 5.0 1.2 7.3 11.3 0.6 6.3 6.5 1.0 6.3 5.5 1.1 6.3 6.2 1.0 5.5 4.5 1.2
0.24 3.3 0.93 0.28 3.3 0.86 0.19 4.5 0.61 0.12 5.1 0.78 0.15 5.2
0.43
0.033 14.5 0.52 0.038 13.7 0.31 0.091 3.4 0.23 0.031 9.0 0.33 0.033 11.5
0.454
0.504
6.6
7.6 0.9 7.4 8.3 0.9 6.9 7.6 0.9 3.9 15.8 0.6 7.4 9.4 0.8
0.306
0.232 0.363
0.94 9.6 0.27 11.1 3.5 0.9 0.90 10.0 0.23 11.5 3.9 0.9 0.90 8.8 0.21 8.7 4.3 1.0
0.518
0.453
0.424
0.92 0.25 3.7 0.93 0.23 3.3 0.85 0.17 5.0 0.58 0.10 5.3 0.75 0.14 5.4 0.95 0.27 3.5 0.92 0.23 4.0 0.91 0.21 4.3
5.4 4.4 1.2 6.1 3.9 1.6 4.6 3.3 1.4 4.5 5.7 0.3 4.6 4.1 1.1 5.9 3.5 1.7 5.4 4.3 1.3 4.6 3.4 1.4
1.00
0.40 2.5 1.00 0.49 2.0 1.00 0.32 3.1 0.77 0.17 4.5 0.95 0.26 3.7
1Not an embodiment of this invention 2lsopropanol 2.7190 - Has the composition of l IPA with an average of 2.7 propylene units per molecule with no molecules with l propylene oxide unit present.
EXAMPLE 4
The collector, potassium amyl xanthate, is added to the ?oat cell (0.004 kg/metric ton), followed by a con
ditioning time of one minute, at which time the frother
11
4,582,596
12
is added (0.058 kg/metric ton). After an additional one minute conditioning time, the air to the ?oat cell is
turned on at a rate of 4.5 liters per minute and the auto
3. The process of claim 1 wherein coal, copper sul ?de, nickel sul?de, lead sul?de, zinc sul?de or molybde
num sul?de values are recovered.
matic froth removal paddle is started. Timed cuts of the froth were taken at intervals of 0.5, 1.5, 3.0, 5.0 and 8.0 minutes. The froth samples are dried overnight in an oven, along with the ?otation tailings. The dried sam ples are weighed, divided into suitable samples for anal
4. The process of claim 1 wherein coal or metal sul ?de values are recovered. 5. The process of claim 4 wherein the frother corre
ysis, pulverized to insure suitable ?neness, and dissolved in acid for analysis. The samples are analyzed using a DC Plasma Spectrograph. The weights of recovered froth and tailings samples and the analyses are used in a
computer program to calculate metal and gangue re covery, and the R and K parameters. The results are
with the proviso that one R2 in each unit must be methyl or ethyl, and with the further proviso that when one R2 20 in a unit is ethyl, the other R2 must be hydrogen. MIBC~2PO 9.3 0.198 26.4 0.706 18.4 0.904 6. The process of claim 5 wherein n is an integer of l DF-l0121 17.9 0.110 32.2 0.692 28.5 0.802 DF-ZOOl 6.31 0.158 16.9 0.694 12.8 0.852 to 3, inclusive. 7. The process of claim 6 wherein n is the integer 2. DF : Dowfroth ]Not an embodiment of this invention 8. The process of claim 5 wherein the frother is a 25 reaction product of a C6 alcohol and propylene oxide. What is claimed is: 9. The process of claim 8 wherein the C6 alcohol is 1. A process for recovering coal or metal values from hexanol or methylisobutyl carbinol. raw coal or metal ore which comprises subjecting the 10. The process of claim 9 wherein n is the integer 2. raw coal or metal ore in the form of an aqueous pulp, to 11. The process of claim 9 wherein a ?otating amount a ?otation process in the presence of a ?otation collec of frother is between about 0.005 and 0.5 lb/ton. tor for coal or metal values and a ?otating amount of a 12. The process of claim 11 wherein a ?otating ?otation frother which comprises the reaction product amount of frother is between about 0.01 and 0.2 lb/ton. of a monohydroxy aliphatic C6 alcohol and between 13. The process of claim 5 wherein coal values are about 1 and 5 moles of propylene oxide, butylene oxide recovered. 14. The process of claim 13 wherein the C6 alcohol is or mixtures thereof, under conditions such that the coal 35
60 mesh
R
Combined
Frother
2. The process of claim 1 wherein coal, metal oxide or metal sul?de values are recovered.
40
45
55
60
65