1.

For the adsorption of a gas on a solid the plot of log (a / m) versus log P is linear with the slope equal to (A) n (B) 1/n (C) k (D) log k 2. Which is a absorbed maximum by activated charcoal? (A) CO2 (B) N2 (C) O2 (D) C12 3. Which of the following is less than zero during adsorption? (A) S (B) G (C) H (D) All. 4. Which of the following statement is not correct? (A) Absorption energy for a chemical adsorption is lower than that of physical adsorplion (B) Physical adsorption is due to van der Waals forces (C) Physical adsorption decreases at high temperature and low pressure (D) Physical adsorption is reversible. 5. According to Langmuir adsorption, the amount of gas adsorbed at very high pressures (A) goes on increasing with pressure (B) goes on decreasing with pressure (C) increases fIrst and decreases later with pressure (D) reaches a constant limiting value 6. Which of the following is true about chemical adsorption? (A) Exothermic (B) Irreversible (C) Takes place at a high temperature (D) All the above are correct. 7. The volumes of gases H2 CH4' CO2 and NH3 absorbed by charcoal at 298 K are in the decreasing order (A) H2. CH4 CO2 NH3 (B) CH4 CO2, NH3. H2 (C) CO2 NH3 H2 CH4 (D) NH3 CO2 CH4 H2 8. A catalyst is substance which (A) increases the equilibrium concentration of the product (B) shortens the time to reach equilibrium (C) changes the equilibrium constant of the reaction (D) supplies energy to the reaction. 9.A catalyst increases the rate of a chemical reaction by (A) increasing the activation energy (B) decreasing the activation energy (C) reacting with the reactants (D) reacting with products. 10. Which one of the following statements is not true? (A) The action of the catalyst is specific (B) A small amount of catalyst is sufficient (C) The catalyst does not alter the equilibrium (D) The catalyst initiates a reaction 11. The phenomenon when the composition of the activated complex includes a substance which does not take part stoichiometrically in the chemical process, but changes the kinetic properties of the system is called (A) chemical equilibrium (B) catalysis (C) osmosis (D) none of these. 12. Which one of the following is a shape selective catalyst? (A) Cr2O6 (B) Cr2O3 , (D) Al2O3 (D) ZSM - 5. 13. A catalyst in the finely divided state is more efficient because in the state (A) It has larger activation energy (B) It has larger surface area. (C) It can react with one of the reactant more efficiently (D) Particle-molecule contact becomes easier. 14. Which of the following catalyst is sensitive to temperature changes? (A) Fe (B) Pt (C) Ni (D) Enzyme. 15. Which of the following characteristics is the most important factor in giving rise to peculiar properties of colloids? (A) Large size (B) High ratio of electrical charge to mass (C) High ratio of surface area to the volume (D) Small size