Professional Documents
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Starch modification
Martin Kozich
Elasticity, cohesion
Adhesiveness adhesion/cohesion Binding water Flocculation Starch for sensoric properties
63. Starch Convention Martin Kozich
30%
52%
18%
Martin Kozich
Chemically modified starches are used, because they provide functional attributes in food applications that native starches normally cannot provide
Raw material: maize, potato, wheat, tapioca, rice, Type of modification: ether, ester, cross-linking,.. Degree of modification
18th of April 2012 63. Starch Convention Martin Kozich
E - NUMBER E 1404 E 1410 / E 1412 E 1413 E 1414 E 1420 E 1422 E 1440 E 1442 E 1450 / E 1452 E 1451
18th of April 2012
CHEMICALLY MODIFIED STARCH Oxidised starch Monostarch phosphate / distarch phosphate Phosphated distarch phosphate Acetylated distarch phosphate Acetylated starch Acetylated distarch adipate Hydroxy propyl starch Hydroxy propyl distarch phosphate Starch sodium octenyl succinate / Al-type Acetylated oxidised starch
63. Starch Convention Martin Kozich
Derivatisation
Increase of binding water, swelling power and viscosity
Repression of retrogradation
Increase of freeze-thaw-stability Increase of baking stability
Martin Kozich
For example: Acetylated distarch adipate (E 1422) Hydroxy propyl distarch phosphate (E 1442)
18th of April 2012 63. Starch Convention Martin Kozich
Corrugated board Lamination, tissue, book-binding Remoistable adhesives Paper bags Wallpaper glue, glues for posters
Textile market
Tile cement, plaster, stucco Shotcrete, self compacting concrete Emulsion paints, renders
18th of April 2012 63. Starch Convention Martin Kozich
Paper industry
Wet end
Textile market
Sizing
Adhesives
Paper bags
Construction sector
Tile cement
Martin Kozich
Modification
Rate 21%
Application
cationic (amphoteric)
usually enzymatic, oxidised oxidised, dextrins; enzymatic native; cross-linked
Surface
64%
Coating Spray
18th of April 2012
12% 3%
Increase of hydrogen bonds between fibers Increase of filler retention due to ionic character Protective colloid for ASA emulsification Increase of dry substance in the press section of the paper machine
63. Starch Convention Martin Kozich
Retention aid
Sizing
Drainage
18th of April 2012
Martin Kozich
Bottom gluing
18th of April 2012 63. Starch Convention Martin Kozich
Martin Kozich
no splashing
high splashing
Martin Kozich
Sizing of fiber
Martin Kozich
ox potato starch
Martin Kozich
Martin Kozich
thickening effect in dry mortar! Why chem. modified starch? - The behaviour of starch is strongly dosage-dependent: it acts as a thickener when the incorporated dosage is up to 0.2% of weight. The thickening effect takes place because starch is adsorbed onto inorganic particles acting as a flocculant to make a network, as confirmed by zeta-potential and particle size distribution results. J.I.lvarez et al. Carbohyr. Polym. 80, 222 (2010)
A. Glatthor, Schleibinger Rheologie-Kolloquium Regensburg, 2005
Aqueous viscosity
18th of April 2012 63. Starch Convention
Slump flow
Martin Kozich
Typ B
63. Starch Convention Martin Kozich
Martin Kozich