Solubility Equilibrium Exam

Name:______________________________ Part A: Multiple Choice Value: 50 marks Suggested Time: 60 minutes INSTRU TI!NS: 8or each 'uestion9 select the best answer an& recor& %our choice on the 1es*onse 8orm *ro4i&e&. :sing an "B *encil9 com*letel% fill in the circle that has the letter corres*on&ing to %our answer. 1. Which of the following forms a molecular solution in water? A. SrSO4 B. Na3PO4 . !"1#O! $. N"4 "3 OO #. Which of the following is necessar% to form a saturate& solution at e'uili(rium? A. e)cess solute B. an ionic solute . solute of low solu(ilit% $. trial ion *ro&uct is less than +s* 3. ,he net ionic e'uation that &escri(es a saturate& solution of Ag# rO4 is A. Ag# rO4-s. Ag# rO4-a'. B. Ag# rO4-s. #Ag/-a'. / rO4#0-a'. . Ag# rO4-s. #Ag/-a'. / r!/-a'. / 4O#0-a'. / $. #Ag -a'. / rO4#0-a'. / #"#O-l. #AgO"-s. / "# rO4-a'. 4. Which of the following com*oun&s has the lowest solu(ilit%? A. SrS B. a l# . 1(# O3 $. 2n-O".# 3. Which of the following will form a *reci*itate when e'ual 4olumes of 5.# 6 solutions are com(ine&? A. "7 an& Na# O3 B. SrS an& N"4O" . Ba l# an& uSO4 $. 6g-NO3.# an& + l

!. ,he solute AgBr is least solu(le in A. "#O B. 1.5 6 8eBr3 . 1.5 6 aBr# $. 1.5 6 AgNO3 ;. ,he magnesium an& calcium ions in har& water can (e remo4e& (% the a&&ition of A. Na7 B. NaNO3 . Na# O3 $. Na#SO4 <. ,he solu(ilit% of an AB# t%*e salt is #.3 ) 150! 6. ,he salt is A. P(Br# B. 8e-O".# . u-7O3.# $. 6g-O".# =. Which of the following saturate& solutions will ha4e the lowest >P(#/?? A. P(7# B. P( l# . P(-7O3.# $. P(-NO3.# 15. Which of the following units coul& (e use& to &escri(e solu(ilit%? A. g @ s B. g @ A .6@A $. mol @ s 11. onsi&er the following anions: Anion 15.5 mA of 5.#5 6 l0 15.5 mA of 5.#5 6 O"0 15.5 mA of 5.#5 6 SO3#0

7. 77. 777.

When 15.5 mA of 5.#5 6 P(-NO3.# are a&&e& to each of the a(o4e9 *reci*itates form in A. 7 an& 77 onl%. B. 7 an& 777 onl%. . 77 an& 777 onl%. $. 79 77 an& 777.

1#. When e'ual 4olumes of 5.#5 6 uSO4 an& 5. #5 6 Ai#S are com(ine&9 the com*lete ionic e'uation is A. u#/-a'. / S#0-a'. uS-s. B. uSO4-a'. / Ai#S-a'. uS-s. / Ai#SO4-a'. . u#/-a'. / SO4#0-a'. / #Ai/-a'. / S#0-a'. Ai#SO4-a'. / uS-s. $. u#/-a'. / SO4#0-a'. / #Ai/-a'. / S#0-a'. #Ai/-a'. / SO4#0-a'. / uS-s. 13. ,he +s* e)*ression for a saturate& solution of Ag# O3 is A. +s* B >Ag#/?> O3#0? B. +s* B >Ag/?#> O3#0? . +s* B >#Ag/?> O3#0? $. +s* B >#Ag/?#> O3#0? 14. ,he solu(ilit% of 8e8# is <.4 ) 1503 6. ,he +s* 4alue is A. 3.= ) 150; B. #.4 ) 150! . ;.1 ) 1503 $. <.4 ) 1503 13. 7f the ,rial 7on Pro&uct for AgBrO3 is calculate& to (e 1.5 150;9 then A. a *reci*itate forms (ecause the ,rial 7on Pro&uct C +s* B. a *reci*itate forms (ecause the ,rial 7on Pro&uct D +s* . no *reci*itate forms (ecause the ,rial 7on Pro&uct C +s* $. no *reci*itate forms (ecause the ,rial 7on Pro&uct D +s* 1!. ,he least solu(le salt in water is A. aS B. aSO4 . a #O4 $. a-NO3.# 1;. A saturate& solution of Na l contains 3!.3 g of solute in 5.155 A of solution. ,he solu(ilit% of the com*oun& is A. 5.5!# 6 B. 1.!5 6 . 3.!3 6 $. !.#4 6 1<. alculate the >Ai/? in #55.5 ml of 1.3 6 Ai#SO4. A. 5.35 6 B. 5.!5 6 . 1.3 6 $. 3.5 6

1=. When e'ual 4olumes of 5.#5 6 1( l an& 5.#5 6 SrS are com(ine&9 A. no *reci*itate forms. B. a *reci*itate of 1(#S onl% forms. . a *reci*itate of Sr l# onl% forms. $. *reci*itates of (oth 1(#S an& Sr l# form. #5. A solution contains (oth Ag/ an& 6g#/ ions. $uring selecti4e *reci*itation9 these ions are remo4e& one at a time (% a&&ing A. 70 followe& (% O"0 B. O"0 followe& (% S#0 . SO4#0 followe& (% l0 $. NO30 followe& (% PO430 #1. ,he +s* e)*ression for a saturate& solution of 6g-O".# is A. +s* B >6g#/?>O"0?# @ >6g-O".#? B. +s* B >6g#/?>O"0?# . +s* B >6g#/?>O"0? $. +s* B >6g#/?>#O"0?# ##. onsi&er the following saturate& solutions: uSO4 BaSO4 aSO4 ,he or&er of cation concentration9 from highest to lowest9 is A. >Ba#/? C > a#/? C > u#/? B. > a#/? C > u#/? C >Ba#/? . > u#/? C > a#/? C >Ba#/? $. > u#/? C >Ba#/? C > a#/? #3. When 1.5 ) 1503 moles of u l#-s. are a&&e& to 1.5 A of 1.5 ) 1503 7O309 the A. ,rial +s* C +s* an& a *reci*itate forms. B. ,rial +s* D +s* an& a *reci*itate forms. . ,rial +s* C +s* an& no *reci*itate forms. $. ,rial +s* D +s* an& no *reci*itate forms. #4. Which of the following *ro&uces a molecular solution when &issol4e& in water? A. 1( lO B. "3O" . N"4S N $. Na "3 OO

#3. onsi&er the solu(ilit% e'uili(rium: a O3-s. a#/-a'. /

O3#0-a'.

An a&&itional *iece of soli& a O3 is a&&e& to the e'uili(rium a(o4e. ,he rate of &issol4ing an& rate of cr%stalliEation ha4e Rate o" #issol$ing increase& increase& not change& not change& Rate o" rystalli%ation increase& not change& increase& not change&

A. B. . $.

#!. At #5 9 which of the following com*oun&s woul& &issol4e to form a saturate& solution with the greatest >P(#/?? A. P(7# B. P( l# . P(Br# $. P(-7O3.# #;. When e'ual 4olumes of 5.#5 6 2nSO4 an& 5.#5 6 Sr-O".# are com(ine&9 A. no *reci*itate forms. B. a *reci*itate of onl% SrSO4 forms. . a *reci*itate of onl% 2n-O".# forms. $. *reci*itates of (oth SrSO4 an& 2n-O".# form. #<. ,he solu(ilit% of SnS is 3.# ) 1503 6. ,he 4alue of +s* is A. 1.5 ) 1503 B. 3.# ) 1503 . !.4 ) 1503 $. 3.; ) 150# #=. Sil4er chlori&e9 Ag l9 woul& (e least solu(le in A. 1.5 6 " l B. 1.5 6 NaNO3 . 1.5 6 2n l# $. 1.5 6 AgNO3 35. ,he solu(ilit% of Sr8# is A. 4.3 ) 150= 6 B. !.! ) 1503 6 . 1.5 ) 1503 6 $. 1.! ) 1503 6

31. A solution contains two cations9 each ha4ing a concentration of 5.#5 6. When an e'ual 4olume of 5.#5 6 O"0 is a&&e&9 these cations are remo4e& from the solution (% *reci*itation. ,hese ions are A. Ba#/ an& +/ B. Sr#/ an& Na/ . 6g#/ an& Sr#/ $. 6g#/ an& a#/ 3#. ,he solu(ilit% of 6n-7O3.# is 4.< ) 1503 6. What is the 4alue of +s*? A. 1.1 ) 150; B. 4.4 ) 150; . ;.1 ) 150! $. 1.1 ) 1501 33. ,he ma)imum >SO4#0? that can e)ist in 1.5 ) 1503 6 a-NO3.# without a *reci*itate forming is A. ;.1 ) 1503 6 B. 1.5 ) 1503 6 . <.4 ) 1503 6 $. ;.1 ) 150# 6 34. At a certain tem*erature9 ;.5 ) 1504 mol 6gSO4 is *resent in 155.5 mA of solution. ,he concentration of the 6g#/ in this solution is A. ;.5 ) 1503 6 B. ;.5 ) 1504 6 . ;.5 ) 1503 6 $. ;.5 ) 150! 6 33. When e'ual 4olumes of 5.#5 6 SrBr# an& 5.#5 6 AgNO3 are com(ine&9 A. no *reci*itate forms. B. a *reci*itate of onl% AgBr forms. . a *reci*itate of onl% Sr-NO3.# forms. $. *reci*itates of (oth AgBr an& Sr-NO3.# form. 3!. onsi&er the following solu(ilit% e'uili(rium: P( l#-s. P(#/-a'. + # l0-a'. A stu&ent a&&s Na l-s. to a saturate& solution of P( l#. When e'uili(rium is reesta(lishe&9 how ha4e the concentrations change& from the original e'uili(rium? A. >P(#/? an& > l0? (oth increase&. B. >P(#/? an& > l0? (oth &ecrease&. . >P(#/? &ecrease& an& > l0? (oth increase&. $. >P(#/? increase& an& > l0? (oth &ecrease&.

3;. Soli& Ag# rO4 is a&&e& to water to form a saturate& solution. ,he +s* 4alue can (e calculate& (% A. +s* B > rO4#0? B. +s* B > rO4#0?3 . +s* B > rO4#0?3 @ # $. +s* = 4> rO4#0?3 3<. onsi&er the following solu(ilit% e'uili(rium: BaSO3-s. Ba#/-a'. / SO3#0-a'. Which of the following will result in an increase of >Ba#/?? A. a&&ing water B. a&&ing BaS-s. . a&&ing BaSO3-s. $. a&&ing Na#SO3-s. 3=. When e'ual 4olumes of 5.#5 6 a-NO3.# an& 5. #5 6 Na#SO4 are com(ine&9 A. a *reci*itate forms (ecause ,rial 7on Pro&uct C +s* B. a *reci*itate forms (ecause ,rial 7on Pro&uct D +s* . no *reci*itate forms (ecause ,rial 7on Pro&uct C +s* $. no *reci*itate forms (ecause ,rial 7on Pro&uct D +s* 45. Soli& NaBrO3 is a&&e& to a 5.515 6 Ag/ solution. What is the >BrO30? when a *reci*itate first forms? A. #.< ) 150= 6 B. 3.3 ) 150; 6 . 3.3 ) 1503 6 $. 1.5 ) 150# 6 41. Which of the following will &issol4e in water to *ro&uce a molecular solution? A. a l# B. NaO" . "3O" $. Sr-O".# 4#. 7n a solu(ilit% e'uili(rium9 the A. rate of &issol4ing e'uals the rate of cr%stalliEation. B. neither &issol4ing nor cr%stalliEation are occurring. . concentration of solute an& sol4ent are alwa%s e'ual. $. mass of &issol4e& solute is greater than the mass of the solution. 43. Which of the following solutions woul& ha4e >8e3/? B 5.5#5 6? A. 5.45 A of 5.535 6 8e-NO3.3 B. 5.<5 A of 5.5#5 6 8e#-SO4.3 . 5.35 A of 5.545 6 8e !"3O; $. 5.35 A of 5.515 6 8e#- #O4.3

44. Which of the following su(stances has the lowest solu(ilit%? A. BaS B. uS . 8eS $. 2nS 43. ,he com*lete ionic e'uation for the reaction (etween 6gS an& Sr-O".# is A. 6gS-a'. / Sr-O".#-a'. 6g-O".#-s. / SrS-s. B. 6gS-a'. / Sr-O".#-a'. 6g-O".#-s. / SrS-a'. . 6g#/-a'. / S#0-a'. / Sr#/-a'. / #O"0-a'. 6g#/-a'. / #O"0-a'. / SrS-s. $. 6g#/-a'. / S#0-a'. / Sr#/-a'. / #O"0-a'. 6g#/-a'. / #O"0-a'. / SrS-s. 4!. onsi&er the following e'uili(rium: 8e-O".#-s. 8e#/-a'. / #O"0-a'. Which of the following will cause the e'uili(rium to shift to the right? A. a&&ing +O" B. a&&ing Na#S . a&&ing 8e-O".# $. a&&ing 8e-NO3.# 4;. onsi&er the following e)*eriment:

,he unFnown solution coul& contain A. 5.#5 6 O"0 B. 5.#5 6 NO30 . 5.#5 6 PO430 $. 5.#5 6 SO4#0

4<. A com*oun& has a solu(ilit% of ;.1 ) 1503 6 at #3 G . ,he com*oun& is A. uS B. AgBr . a O3 $. aSO4 4=. onsi&er the following 5.15 mA solutions:

H'ual moles of AgNO3 are a&&e& to each solution. 7t is o(ser4e& that a *reci*itate forms in all (ut one solution. Which solution &oes not form a *reci*itate? A. l0 B. Br0 . 7O30 $. BrO30 35. Which of the following coul& &issol4e a *reci*itate of a #O4 in a saturate& solution of a #O4? A. NaO" B. a #O4 . "# #O4 $. a-NO3.# 31. A famous hristmas stor% written (% $r. Seuss is A. "ow the Irinch Stole hristmas B. "ow the Irinch Stole SantaJs Wife . "ow the Irinch 8orgot to Aea4e the ,oilet Seat $own $. "ow the Irinch Stole Oscar 6e%erJs Weiner

T&is is t&e end o" t&e multi'le()&oi)e se)tion*

Part B: Written Response Value: +, marks Suggested Time: -0 minutes INSTRU TI!NS: Kou will (e e)*ecte& to communicate %our Fnowle&ge an& un&erstan&ing of chemical *rinci*les in a clear an& logical manner. Kour ste*s an& assum*tions lea&ing to a solution must (e written in the s*aces (elow the 'uestions. Answers must inclu&e units where a**ro*riate an& (e gi4en to the correct num(er of significant figures. 1or questions in$ol$ing )al)ulation2 "ull marks 3ill N!T be gi$en "or 'ro$iding only an ans3er* 1. a. Write the com*lete ionic e'uation for the reaction (etween NaBrO3 an& AgNO3. ./ mark0

(. What is the ma)imum >NaBrO3? that can e)ist in e'uili(rium with #.5 6 AgNO3? .+ marks0

#. A 155.5 mA sam*le of 5. !55 6 a-NO3.# is &ilute& (% a&&ing 455.5mA of water. alculate the concentration of ions in the resulting solution. .+ marks0

3. 7n an e)*eriment to &etermine the solu(ilit% of (arium fluori&e9 355. 5 mA of the saturate& solution was heate& in an e4a*orating &ish to remo4e the water. ,he e4a*orating &ish an& resi&ue were heate& two more times9 to ensure all the water ha& (een &ri4en off. 7. 77. 777. 7L. L. Lolume of saturate& solution of Ba8# 6ass of e4a*orating &ish 6ass of e4a*orating &ish an& Ba8# after heating 6ass of e4a*orating &ish an& Ba8# after secon& heating 6ass of e4a*orating &ish an& Ba8# after thir& heating 355.5 mA ;#.345 g ;3.355 g ;#.<33 g ;#.<## g

:sing the &ata a(o4e9 calculate the +s* for Ba8#. .- marks0

4. A ma)imum of 5.!5 g P(-NO3.# can (e a&&e& to 1.3 A of NaBr-a'. without forming a *reci*itate. alculate the >NaBr?. .- marks0

3. At #3 M 9 will a *reci*itate form when #3.5 mA of 5.515 6 P(-NO3.# is com(ine& with ;3.5 mA of 5.515 mA of 6 Na7? Su**ort %our answer with calculations. .4 marks0

!. Write the net ionic e'uation re*resenting the reaction that occurs when 35.5 mA of 5.#5 6 2nSO4 an& 35.5 mA of 5.#5 6 BaS are com(ine&. .+ marks0

;. When 1.55 g of 6g O3 is a&&e& to #.5 A of water9 some9 (ut not all9 will &issol4e to form a saturate& solution. alculate the mass of soli& that remains un&issol4e&. .- marks0

<.

onsi&er the following:

a. Which two soli& sam*les coul& (e a&&e& to the aS solution in or&er to remo4e first one ion an& then the other from the solution. 7n&icate the or&er in which to a&& them. .+ marks0 8irst a&&: ,hen a&&: (. Write the net ionic e'uation for one of the *reci*itation reactions in *art a.. ./ mark0

=.

onsi&er the following saturate& solutions at #5 :

:sing calculations9 i&entif% the solution with the greater >Ag/?. .5 marks0

Part C: Bonus Question 1. a. onnect the &ots on the following &iagram. ./ mark0

(. What is this a &iagram of?