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22010/2011
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22010/2011
Pyrite (FeS2) !
Pyrite is the most common sulfide mineral and occurs associated with hydrothermal ore deposits and in coal derived from marine deposits.
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Pyrite/FeOOH Stability !
(species in italics are aqueous complexes)
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TITLE Generate Acid mine water vi REACTION! SOLUTION 1 PURE WATER! pH 7.0! temp 25.0! EQUILIBRIUM_PHASES 1 !! !Pyrite 0.0 0.1! !Goethite 0.0 0.0! REACTION 1! O2 1.0! 0.5 moles in 100 steps!
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Precipitation of FeOOH !
Iron(III) (hydr)oxides precipitate out from solution when pH > 3.
Goethite ("-FeOOH)
Schwertmannite (Fe8O8(OH)6SO4)
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Pyrite+K-Feldpar !
Dissolution of K-Felspar buffers pH to high values.
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!8.10
At pH 2.0 in air-saturated conditions [O2] = 10-3.6 mol/ kg, t1/2 = 16 years for 0.05m2/g.
4Fe2+(aq) + O2 + 4H+ ! 4Fe3+(aq) + 4H2O Thiobacillus ferrooxidans is acidophillic, autotropic and fixes its carbon from atmospheric CO2.
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At pH 2.0 with [Fe]tot = 10-2 and [Fe2+]/[Fe3+] = 0.01, t1/2 = 150 days for 0.05m2/g.
(c) FeS2(aq) + 14Fe3+(aq) + 8H2O ! 15Fe2+(aq) + 2SO42-(aq) + 16H+(aq) Fast, autocatalytic mechanism
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Summary !
"Acid Mine Drainage results from the oxidation of pyrite. "Geochemical modelling can be used to test if a rock is suseptible to AMD "Geochemical modelling can also be used to test the effect of active remediation strategies.
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