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The UltraFast module can easily be programmed and controlled either through the local GC keyboard or data system. When required, the column can rapidly be changed by simply replacing the full module. Installation is performed just as it is for any conventional column, and no further specific set-up or optimization is necessary. For any analysis, you simply select the most appropriate stationary phase and temperature program. The rest is the same as using your standard gas chromatograph, with the exception of having results delivered at a remarkable speed!
Peak compression
1400 1200 Heating rate (C/min) 1000 800 600 400 200 0 Conventional GC Ultra Fast TRACE GC Ultra
100 150
10
20
30 sec
A large variety of UltraFast TRACE GC column phases opens up this innovative technology to all major applications in the Chemical, Petrochemical, Environmental and Flavors and Fragrances industries. The list below provides the available columns, standard and non-standard, with the dimensions and a short description of their use.
Capillary column
Transfer lines
12,5 cm ~ 8 cm (3 )
Cable connection
Any existing column in our TRACE GC column range can be custom-prepared for UltraFast use upon request!
Phase UFC-1 UFC-1 UFC-1 UFC-1 UFC-1 UFC-1 (Metal) UFC-1 UFC-1 UFC-1 UFC-1 UFC-5 UFC-5 UFC-5 UFC-5 UFC-5 UFC-5 (Amine) UFC-1701 UFC-WAX UFC-WAX UFC-264 UFC-200 UFC-200 UFC-23 UFC-23 UFC-23 UFC-PlotQ ID (mm) 0.1 0.32 0.32 0.32 0.32 0.32 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.18 0.1 0.1 0.1 0.1 0.18 0.18 0.18 0.18 0.15 0.25 Film Thickness (m) 0.1 3 0.1 0.1 0.25 0.25 0.1 0.2 0.4 0.2 0.4 0.4 0.1 0.1 0.4 0.1 0.1 0.2 0.1 0.5 0.4 0.2 0.2 0.2 0.15 3 Length (m) 5 10 2.5 5 5 5 10 2.5 5 5 2.5 5 5 10 10 10 5 5 5 10 10 15 10 15 10 10 Use General ASTM D-3710 ASTM D-2887 Extended ASTM D-2887 ISO 9377-2 ISO 9377-2 General General General General General General General General Volatiles Amine General FAMEs, Essential Oils FAMEs, Essential Oils Volatiles Alcohols/Ketones Alcohols/Ketones FAMEs FAMEs FAMEs Gas analysis Part Number UFMC00001010401 UFMC00002070414 UFMC00000070401 UFMC00001070401 UFMC00001070404 UFMC00001070904 UFMC00002010701 UFMC00000010403 UFMC00001010606 UFMC00001010703 UFMC00100000000 UFMC00200000000 UFMC00300000000 UFMC00002010601 UFMC00002010006 UFMC00002031001 UFMC00400000000 UFMC00001010503 UFMC00001010501 UFMC00002010207 UFMC00002030306 UFMC00003030303 UFMC00002030603 UFMC00003030603 UFMC00002020802 UFMC00002060614
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c h r o m a t o g r a p h y
Operating conditions
C14 C16
Column: UFC-1, 5 m, 0.32 mm id, 0.1 m film thickness T.Prog: 40 C (6 s), 3 C/s, 370 C (6 s)
C18
C9
2 min
2.0 min 0 10 20
30 min
30 min
10 min
5 6 7 8
11 13 14 15 16 17 18 19
Olens Analysis
1.5 min
0.5* 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 99.5**
115 151 176 201 224 243 259 275 289 302 312 321 332 343 354 365 378 391 407 428 475
112 151 175 200 223 243 259 276 291 300 312 321 331 340 352 365 375 389 405 427 475
112 151 175 198 222 242 258 276 289 300 311 320 331 340 352 366 376 388 405 425 475
0.5
1 n-Propane 2 Methylpropane 3 n-Butane 4 2-Methylbutane 5 n-Pentane 6 2-Methylpentane 7 n-Hexane 8 2,4-Dimethylpentane 9 n-Heptane 10 Toluene
Column: UFC-WAX, 5 m x 0.1 mm, 0.2um FT Temp. prog: 50 C (30 s), 2 C /s, 230 C (20 s) Sample: Stirene with 10-500 ppm of impurities Injection: 0.2 uL split 400: 1
9 11 7 10 12 13 8
50 60
C5 1
Carrier gas: H2
2 5 3 1 4 6
0.0 2.5 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5
20
14
70 80
40
60
80
100 sec
10
20
30
40 times (s)
Concentration (ppm) Ultrafast GC Conventional GC 223 258 1 n-alkanes 411 400 2 Ethylbenzene 180 162 3 m-Xylene 145 131 4 p-Xylene 277 274 5 Cumene 114 116 6 o-Xylene 506 479 7 n-propylbenzene 97 103 8 Methyl ethyl benzene n.a. n.a. 9 Stirene 376 (ISTD) 376 (ISTD) 10 Cycloesanone 371 380 11 -Methyl stirene 29 29 12 Methyl vinil benzene 94 13 Phenyl acetilene 103 7 14 -Methyl stirene 6 Component
Environmental Applications
ISO 9377-2 in 2 Minutes
ISO 9377-2 Hydrocarbons analysis in water and soils
Ultra Fast GC: 2 min 800 600 400 200 0 0 20 40 60 80 100 120 sec 0 200 400 600 Concentration (mg/L) R 20.9999
Soil extract (50 mg/L total hydrocarbon) C10 C40 Splitless injection
2250 mV
C10
C40
2 min
Total hydrocarbons
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
1.8
Column: UFC-5, 5 m, 0.32 mm i.d., 0.25 m f.t. Temp. prog.: 40 oC (20 sec), 3.3 o C/sec, 350 oC (30 sec) Splitless time: 20 sec Carrier gas: He
2.0 min
Conventional: 35 min.
2 3 5 9 4 8 67 1011 12
Area (counts x 10 6 )
High linearity from 5 to 500 mg/L nC40/nC20 area ratio > 0.9 (required 0.8) RSD % on group peak absolute area: 0.8 %
2 3 4 5 89 1 6 7 10 1112 UltraFast: 35 seconds UFC-1701, 5 m x 0.1 mm, 0.1 m f.t. 40 o C to 200 oC at 5 oC/s He at 1 mL/min 1 L (split 100:1) 0 5 10 15 20 25 30 35 time (s)
0 5 10 15 20 25 30 35
time (min)
3 4 2
5 6 78
125 9 11 12 13 127 129 139 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 141 143
10
15 14
16
20
40
60
80 Time (s)
100
120
140
160
Naphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo(a)anthracene Chrysene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3,-c,d)pyrene Dibenzo(a,h)anthracene Benzo(g,h,l)perylene
UFM: UFM-WAX, 5 m x 0.1 mm i.d., 0.1 m T Program: 40 C (6 s) to 250 C (20 s) at 1.7 C/s Carrier: Hydrogen at 1 ml/min CF mode Injection: 1 l (10 ng/l), split ratio of 1:100 1 2 3 4 6 8 7 10 9
16 14 15
1.7
1.8
1.9
2.3
2.4 min
12 13 11
2.5 min
0 10 20 30 time (min) 40 50 60
0.5
1.0
1.5
2.0
2.5 min
1 2 3 4 5 6 7 8 9 10
Butyric (C4:0) Caproic (C6:0) Caprylic (C8:0) Capric (C10:0) Undecanoic (C11:0) Lauric (C12:0) Tridecanoic (C13:0) Myristic (C14:0) Myristoleic (C14:1) Pentadecanoic (C15:1)
11 12 13 14 15 16 17 18 19 20
cis-10-Pentadecenoic (C15:1) Palmitic (C16:0) Palmitoleic (C16:1) Heptadecanoic (C17:0) cis-10-Heptadecenoic (C17:1) Stearic (C18:0) Oleic (C18:1n9c) Elaidic (C18:1n9t) Linoleic (C18:2n6c) Linolelaidic (C18:2n6t)
21 22 23 24 25 26 27 28 29 30
g-Linolenic (C18:3n6) a-Linolenic (C18:3n3) Arachidic (C20:0) cis-11-Eicosenoic (C20:1) cis-11,14-Eicosadienoic (C20:2) cis-8,11,14-Eicosatrienoic (C20:3n6) Heneicosanoic (C21:0) cis-11,14,17-Eicosatrienoic (C20:3n3) Arachidonic (C20:4n6) cis-5,8,11,14,17-Eicosapentaenoic (C20:5n3)
31 32 33 34 35 36 37
Behenic (C22:0) Erucic (C22:1n9) cis-13,16-Docosadienoic (C22:2) Tricosanoic (C23:0) Lignoceric (C24:0) cis-4,7,10,13,16,19-Docosahexaenoic (C22:6n3) Nervonic (C24:1)
OLIVE OIL
UFM: 1 6 5 7
UFC-WAX, 5 m x 0.1 mm i.d., 0.2 m T Prog.: 150 C (10 s) to 250 C (12 s) at 1.7 C/s Carrier: Helium at 1 mL/min CF mode Injection: 1 L, split ratio of 1:300
2 8 3 4 0 0.5 9 10 11 1 12 13 14
1.5 min
BUTTER
c16:0
c18:0
c18:1
BEEF
Food Packages
Essential Oils
6 9 12 5 1 2 7 34 8 5 10 15 10 11 14 17 16 20 13 14 12 15 25 30 13 15
Conventional GC 35 minutes
UFM: UFC-WAX, 5m, 0.1 mm i.d., 0.1 m f.t. T prog: 50 to 250 oC at 500 oC/min Carrier: Hydrogen Injection: 1 L, split ratio of 1:300 1 -pinene 2 -pinene 3 Sabinene 4 Myrcene 5 p-cymene 6 Limonene 7 1,8 cineole 8 -terpinene 9 Menthone 10 Menthofurane 11 i-menthone 12 Methyl acetate 13 Neomenthol 14 -cariophyllene 15 Menthol 16 Pulegone 17 Germacrene D 18 Viridilflorol
Area % Conv. GC
0.94 1.41 0.64 0.39 0.58 2.47 6.07 0.94 14.21 2.44 2.57 5.74 5.95 2.39 47.49 2.54 2.64 0.58
Ultra Fast GC
0.96 1.37 0.62 0.35 0.56 2.58 6.19 1.02 14.18 2.56 2.59 5.69 5.88 2.34 47.26 2.58 2.69 0.56
Component
Ethanol Acetone Ethyl Acetate
Amount (mg/m2)
0.1 0.4 0.1
18 35 min
1 min
2 1 3
150 oC/min
16 17
18 35 40 45 50 55 60 65 70 sec
0.2
0.4
0.6
0.8
1.0 min
15 30