ELGHZIZAL’s Documents Scribd

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@  

 50ml   G = f(c)   

 
     

C0 =0,1mol.l-1: &$
% S0     !" #   $
%  
 %
C1= 10m.mol.l-1 $
%  (  
+ ,    & *(
V0 ( ) (1
. #
- &. $(/  0  
 (2  

"  (3
2  
! 
3
+  

"
$
%
"4 3.  (4
3  

( 
5 *( 

. "
6
7- 8 
(5  

 %    9 ) #- 5 :  74, 8 9  

Ga = 293 mS : "9 
 - &. 
 
. 
(  9 6 - $
%  
 
. 9 %
. (15
6 <    
3%   :  *(
0 % (25
Ga’ = 1,89 mS "9   
0 200 - : (6 
-  C’a $
%   

 (16
. : 
 Ca - $
% ( (26
+
−3
-1
λΚ = 7,35.10 (Sm.mol ) λCl- = 7,63.10-3(Sm.mol-1) : 3" (7
L  S 
 σ   
G  " 3 ! "9 (17
Ca’ $
% λι 

, 

= σ 9 9 (27 
5 
* Ga’ Ca’ λCl- λΚ+ = S/L   (37
* !9  Ga = 293 mS # - $
%   %
. (8
.  9 6(
!  09-)

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1

ELGHZIZAL’s Documents Scribd 

 

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% 7  
#    V0 =1L + .  

( "4  3?  #
- %  


+  %
) S0   3 .m0 = 1,195 g @  M = 101g.mol-1 

: 3 ( 3?  


S4 A S0  -  
$
% * (

-  
$
%   9 " (2
5,42.10 S. : 

- "9 5( &$
% + # 3B     
(3  
. $
% (   9 9 
 %
.   
%  
#   " 
. S5   C(4 
9 6   
 % " 
 ? <     
 % $
%
-5

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2

ELGHZIZAL’s Documents Scribd  


@ @Z‫א
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C0 .V0 = C1 .V1
C .V
10 −2 .50.10 −3
V0 = 1 1 =
= 5.10 −3 L = 5mL
−1
C0
10

) : 
! 0 
% D : : 
  (1
(2

G = a.C : 
! F % 
C $
% E " * G    

(3
( 2, 8 − 0, 5 ) .10−3 2, 3
a=
=
= 0, 2875S .mol −1 .L .
-  (  a
8
(10 − 2 ) .10−3 
A ) #
,  "-? 
9     
%  *(
 &. $(/ (4
0 ( = ( L  S 
G = ) 
  9 D? (   

  !G
(5
−3
−2.
−1
#!  10 ;10 mol.l  $
% 3?  .  
! ( 3?  
 G
(15

. [ 0, 25mS ; 2, 8mS ]  -? 

&. 9  

3 < ( F ( Ga = 293 mS 5 ? -  
. - $
%   

 -  7 3% - :  *(
< 
- B G 3% (25 
% 0 100 : 
 7 A )H
( : 
) $
% 7 G = a.C : ! *
0 100   % : 
*(
A 2,93mS ) Ga/100 5 - 
:(   Ga’ = 1,89 mS ( 0200 : (6
:  ‫(  ا‬16

C a = 6,8.10-3mol.l-1  

0 n : * : 
!9 * (26
C
Ca n = a ⇔ Ca = n.Cn
n
Ca = 1,36mol.l −1 = 1,36.103 mol.m −3

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3

ELGHZIZAL’s Documents Scribd

(7
( 1) G = σ .

S
L

:  
(17
:  
(27

(2) σ

(

)

= λK + + λCl − Ca '  σ = ∑ λi [ X i ]
i =1

: S/L  
 (1) 3? (2) 8 
(37
-8

-1

S/L = 9,28.10 m

G 'a
S
=
I.# :  L
λK + + λCl − .C 'a

(

) 

( @? C  G  

!9 5D #% A (1) ! , 
! < 
" %
= (37
Ga = 293 mS # +  E  <"
= )   
( 3?  
5- 
" 

W  ‫א
א‬ 
E1 


(2

( &!9 "" D ) C = 4,5.10-4 mol.L-1 (   (3  

#   .     9 9 " ,  .  %
= (4 

B   
" 
  
 E
= . : D 
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4

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