Professional Documents
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STUDENT NAME:
CHRYSOULA SFYNIA
DISSERTATION TITLE:
I confirm that I have read and understood the guidelines on plagiarism, that I understand the meaning of plagiarism and that I may be penalised for submitting work that has been plagiarised.
I declare that all material presented in the accompanying work is entirely my own work except where explicitly and individually indicated and that all sources used in its preparation and all quotations are clearly cited.
Should this statement prove to be untrue, I recognise the right of the Board of Examiners to recommend what action should be taken in line with UCLs regulations.
Signature:
Date: 06/09/2013
EXECUTIVE SUMMARY
Arup and University College Londons (UCL), Civil, Environmental and Geomatic Engineering Department, have launched a joint project for the design configuration of urban water reuse networks. This master thesis is part of the venture Water Reuse Networks Project and of the ongoing research in the field with regards to wastewater treatment options for reuse and their costs. The present study Urban Wastewater Reuse treatment technologies and costs involves a detailed review of the current trends and reuse applications with emphasis on possible efficient scenarios. The project is concerned how increasing pressures on the water environment necessitate the implementation of sustainable water management practices and regimes. It is argued that this can be achieved through the design, the application and the optimal operation of water reuse infrastructure and management of both supply and demand. Wastewater reuse can be a tool of rational management of water resources. The reasoning of the appropriate reuse of treated municipal or industrial wastewater has intrinsic benefits associated with saving water resources and producing
environmental and economic benefits. However, the reuse of wastewater requires a comprehensive and rational planning, taking into account possible risks and limitations. This study summarizes the current trends concerning urban wastewater reuse focusing in the case of greywater reclamation. In addition, it outlines the objectives and scope of the collaborative project. Overall, the report consists of 7 Chapters, a glossary, an appendix and the appropriate referencing.
The study reviews the following main issues (Chapter 4-6): Legislation of urban wastewater reuse Available technologies for greywater treatment for reuse Costs for these treatment schemes
Chapter 7 introduces the reader to the planning of water reuse networks. This Chapter analyses four different possible greywater treatment scenarios that can be implemented and have proved to be effective. These scenarios have been formed after extensive research in literature, case studies and communication with wastewater treatment specialists. Finally, another significant component of this project is the discussion parts at the end of each of the core chapters that illustrate briefly the main findings and comment on the outcomes.
ACKNOWLEDGEMENTS
First and foremost, I would like to thank my supervisor Dr. Luiza Cintra Campos for giving me the opportunity to carry out this project as my master thesis together with her invaluable guidance and support throughout the whole period. Her great experience and professionalism inspired me to progress in my research and further explore my capabilities. Secondly, I am also thankful to Eleni Georgiou for her contribution and feedback review for this thesis. Special thanks to ARUP and the WReN group for all the confidence, advice and flexibility I was given, which ensured the smooth completion of the first part of the collaborative project. I would also like to thank the wastewater treatment companies that kindly provided technical and financial information of their technologies. Last but not least, I would like to thank the family we created in London for all the unconditional and endless support and help during my studies.
TABLE OF CONTENTS
EXECUTIVE SUMMARY ................................................................................................. 1 ACKNOWLEDGEMENTS ................................................................................................ 3 1. INTRODUCTION .................................................................................................... 9 1.1 1.2 2. 3. Water Scarcity & Urbanization................................................................... 10 Water Use around the World ..................................................................... 12
AIMS & OBJECTIVES .......................................................................................... 16 BACKGROUND RESEARCH.................................................................................. 17 3.1 3.2 3.3 3.4 3.5 Water Reclamation & Reuse A Sustainable Solution .............................. 18 Challenges of Water & Wastewater Reuse................................................ 19 Advantages of Water Reuse ..................................................................... 21 Types of Water Reuse Applications .......................................................... 22 Case Studies............................................................................................. 24
4.
WASTEWATER REUSE FRAMEWORK ................................................................... 28 4.1 4.2 4.3 Regulations by International Organizations ............................................... 29 Regulations by the State of California ....................................................... 38 Regulations by Other Countries ................................................................ 40
5.
WASTEWATER TREATMENT FOR REUSE .............................................................. 44 5.1 5.2 5.3 Wastewater for Reuse Greywater .......................................................... 46 Greywater Treatment Stages .................................................................... 50 Discussion................................................................................................. 71
6.
WATER REUSE & COSTS .................................................................................... 72 6.1 6.2 6.3 Capital Costs............................................................................................. 73 Operation & Maintenance Costs................................................................ 82 Discussion................................................................................................. 86
7.
SETTING UP WATER REUSE NETWORKS ............................................................. 87 7.1 7.2 Treatment Scenarios ................................................................................. 91 Discussion............................................................................................... 100
8.
LIST OF FIGURES
Figure 1.1: The Percent of Population with access to improved Water Sources (%) ............. 10 Figure 1.2: The Percent of Population with access to improved Sanitation (%) ..................... 11 Figure 1.3: Map of Worlds Water Stress in 1995 and in 2020 ................................................ 11 Figure 1.5: Water Use by Sector in European Countries ........................................................ 13 Figure 1.6: Agricultural water withdrawal as a percent of total withdrawal (%) ....................... 14 Figure 1.7: Industrial water withdrawal as a percent of total withdrawal (%) .......................... 14 Figure 1.8: Municipal water withdrawal as a percent of total withdrawal (%) .......................... 15 Figure 3.1: Water Reuse Applications .................................................................................... 22 Figure 3.2: Water Reuse Projects in Europe (Size & Application) ......................................... 27 Figure 4.1: Californias Warning Sign for Recycled Water ...................................................... 39 Figure 5.1: Treatment Technologies for Any Type of Reuse ................................................. 45 Figure 5.2: Sources of Household Wastewater ...................................................................... 46 Figure 5.3: Greywater Categories ........................................................................................... 47 Figure 5.4: Typical Flow Diagram of Basic System Coarse Filtration ................................. 53 Figure 5.5: Typical Flow Diagram of Basic System Sedimentation..................................... 54 Figure 5.6: Typical Flow Diagram of Physical System Sand Filter ...................................... 55 Figure 5.7: Typical Flow Diagram of Physical System Membranes .................................... 57 Figure 5.8: Typical Flow Diagram of Chemical System Coagulation .................................. 58 Figure 5.9: Typical Flow Diagram of Chemical System Photobioreactor ............................ 60 Figure 5.10: Typical Flow Diagram of Biological System SBR ............................................ 62 Figure 5.11: Typical Flow Diagram of Biological System MBR ........................................... 64 Figure 5.12: Typical Flow Diagram of Biological System RBC ........................................... 66 Figure 5.13: Typical Flow Diagram of Extensive Systems Constructed Wetlands ............... 70 Figure 6.1: Typical Water & Drainage Pipelines ..................................................................... 80 Figure 6.2: Typical Pumping Station....................................................................................... 81 Figure 6.3: Breakdown of Running costs of a Wastewater Treatment Plant ......................... 82 Figure 7.1: Water Network Configuration ............................................................................... 89 Figure 7.2: Summary of Treatment Scenarios for Greywater Reclamation ............................ 90 Figure 7.3: Flow Diagram of Scenario 1- Constructed Wetland ............................................. 92 Figure 7.4: Flow Diagram of Scenario 2- RBC ....................................................................... 94 Figure 7.5: Flow Diagram of Scenario 3- SBR ........................................................................ 96 Figure 7.6: Flow Diagram of Scenario 4- MBR ........................................................................ 98 Figure 7.7: Diagram of Scenarios Costs per Equivalent Population ..................................... 101
LIST OF TABLES
Table 3.1: Categories of Reclamation and Reused Water ...................................................... 23 Table 3.2: Worldwide Wastewater Reuse Projects in chronological order from 1912-1989 ... 24 Table 4.1: Directive Limits for Monitoring Parameters in Agriculture and Aquaculture ........... 31 Table 4.2: Health-based Targets & Helminth Reduction Targets from WHO.......................... 32 Table 4.3: Health Based Targets for Water Reuse by WHO ................................................... 33 Table 4.4: Suggested Guidelines for Urban & Agricultural Reuse .......................................... 35 Table 4.6: Suggested Guidelines for Indirect Potable Reuse ................................................. 37 Table 4.7: Californias Title 22 Pathogen Limits ...................................................................... 39 Table 4.8: Water Reuse Practices & Criteria in European Countries...................................... 41 Table 4.9: Existing Water Reuse Criteria in European Countries ........................................... 41 Table 4.10: Existing Water Reuse Criteria in the UK .............................................................. 42 Table 4.11: Reuse Criteria in Japan ........................................................................................ 43 Table 5.1: Average Greywater Yield & Demand ..................................................................... 48 Table 5.2: Summary of Greywater Characteristics .................................................................. 49 Table 5.3: Removal of various components using Membranes .............................................. 56 Table 6.1: Cost of Basic Systems............................................................................................ 74 Table 6.2: Cost of Physical Systems ....................................................................................... 75 Table 6.3: Cost of Chemical Systems ..................................................................................... 76 Table 6.4: Cost of Biological Systems ..................................................................................... 77 Table 6.5: Cost of Extensive Systems ..................................................................................... 78 Table 6.6: Unit Cost of Water Distribution &Transmission Pipelines ...................................... 80 Table 6.7: Unit Cost of Water Transmission Pumping Station ................................................ 81 Table 6.8: Cost of Microbiological Monitoring Analysis ........................................................... 84 Table 6.9: Cost of Physicochemical Monitoring Analysis ........................................................ 85 Table 7.1: Summarized table for Scenario 1 ........................................................................... 93 Table 7.2: Summarized table for Scenario 2 ........................................................................... 95 Table 7.3: Summarized table for Scenario 3 ........................................................................... 97 Table 7.4: Summarized table for Scenario 4 ........................................................................... 99
GLOSSARY
CFU DIY EU FAO FC GAC HRT MF NF OECD RO TC TDS TSS UF UN UNDESA UV WCED WHO Colony Forming Unit Do It Yourself European Union Food and Agriculture Organisation Faecal Coliforms Granular Activated Carbon Hydraulic Retention Time Microfiltration Nanofiltration Organisation for Economic Co-operation and Development Reverse Osmosis Total Coliforms Total Dissolved Solids Total Suspended Solids Ultrafiltration United Nations United Nations/Department of Economic and Social Affairs Ultraviolet World Commission on Environment and Development World Health Organisation
1. INTRODUCTION
Water has a significant importance in the creation, preservation and the development of life in our planet and human civilization. On July 2010, through Resolution 64/292, the United Nations recognized the human right to water and sanitation and acknowledged that clean drinking water and sanitation are essential to the realization of all human rights (UNDESA, 2010). Large quantities of fresh water are needed daily in many parts of the world for domestic, agricultural, industrial use (Eltawil, 2009). Regarding the current situation, almost a quarter of the worlds population suffers from inadequate fresh water supply (Fiorenza, 2003). Because of the impending global population growth (especially in developing countries), the situation is expected to become even worse in the next two decades (Eltawil, 2009). The current water crisis is not subjected only to scarcity, but also to difficulties in accessibility and unequal distribution. According to the latest statistical information from the WHO/UNICEF Joint Monitoring Program for Water Supply and Sanitation (JMP), released in 2013, 36% per cent of the of the worlds population, approximately 2.5 million people lack access to proper sanitation amenities and 768 million people still consume unsafe drinking water. This dire situation results in thousands of
deaths and leads to impoverishment and diminished opportunities for thousands more (WHO, 2013). Furthermore, the pollution and uncontrolled exploitation of groundwater aquifers and surface waters for anthropogenic activities have led to a reduction of both quantity and quality of the available natural water resources (WHO, 2013).
FIGURE 1.1: THE PERCENT OF POPULATION WITH ACCESS TO IMPROVED WATER SOURCES (%) (FAO, 2012)
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FIGURE 1.2: THE PERCENT OF POPULATION WITH ACCESS TO IMPROVED SANITATION (%) (FAO, 2012)
According to estimates, in 2025, when the Earth's population will be approaching or it will have exceeded 10 billion people, one in three inhabitants of the planet, - 3.5 billion people- will live in water scarcity conditions or will be directly threatened by it. This trend is being illustrated in Figure 1.3, which shows the freshwater scarcity of 1995 and that of 2025.
FIGURE 1.3: MAP OF WORLDS WATER STRESS IN 1995 AND IN 2025 (WMO, 1996)
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In addition, water is projected to become a cause of conflicts in neighbouring countries, since about 40% of Earth's inhabitants live in more than 200 transnational river basins, from which they share water resources (Eltawil, 2009). According to all the above statistics and owing to the foreseen growth of the worlds population (especially in the developing countries), the problem is expected to become more and more critical over the next two decades (Eltawil, 2009), bringing water shortage to the top of the international agenda.
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Worldwide, it is estimated that 70% of fresh water is consumed for irrigation needs (FAO, 2012), but in countries like India, Mexico, Iran and Greece the figure is even higher (FAO, 2013). In Japan, agriculture does not contribute significantly to the economy of the country but the amount of water needed for agricultural use is vast as all of its crops are based on irrigation. The different allocation of water use which characterizes the U.S., Poland, UK and Germanys irrigation policies not only indicates greater water consumption by the industry, but also that the agriculture is depended on the rainfalls.
In industrially developed countries, such as England and Germany, the largest percentage of disposable water is being distributed into the industry (Figure 1.5). Conversely, in countries where the developed agriculture is based on irrigated crops, more water goes to agriculture. A visual impression is provided in the following maps (Figure 1.6, 1.7) where it is shown the amount of water withdrawn by the agricultural and the industrial sector, respectively.
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FIGURE 1.6: AGRICULTURAL WATER WITHDRAWAL AS A PERCENT OF TOTAL WITHDRAWAL (%) (FAO, 2012)
FIGURE 1.7: INDUSTRIAL WATER WITHDRAWAL AS A PERCENT OF TOTAL WITHDRAWAL (%) (FAO, 2012)
Generally, the consumption of water for domestic use is proportional to the living standards of a country. Higher living standards and higher income per person implies higher consumption of water (larger homes, better conditions of cleanliness and hygiene, lifestyle change, etc.). However, this is not the rule, as in modern countries
14
where the state and the communities have realised the importance of saving water resources, serious efforts have been made to reduce the use of household level. This also follows from the calculations of FAO, which states that the U.S. consumes far more water for domestic uses (210 m3/person per year), whereas the United Kingdom is an exception and consumes 35 m3/person per year (FAO, 2013). A map of the municipal water withdrawal globally is displayed below in Figure 1.8.
FIGURE 1.8: MUNICIPAL WATER WITHDRAWAL AS A PERCENT OF TOTAL WITHDRAWAL (%) (FAO, 2012)
According to Shiklomanov (1999), the three main sectors mentioned that consume water will become more demanding in the near future. Specifically, the percentage of irrigated surfaces is projected to increase by one third in 2010 and by 50% by 2025, while water for industrial and domestic use is growing at twice the rate of the population growth. The water consumption is observed that since 1900 has sevenfold in total, as the water demand doubles every 20 years (Shiklomanov, 1999). Under these circumstances, an increased trend towards the reclamation and reuse of wastewater is observed around the world as a means to reduce current or future water scarcity. 15
The objectives have been accomplished with the following: Collection and recording of the existing water reuse framework Understanding of the wastewaters nature (quality and quantity) Determination of water reuse applications and final recipients Evaluation of existing wastewater treatment systems Calculation of the wastewater treatment costs (literature and companies)
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3. BACKGROUND RESEARCH
The continuous population growth, pollution and the continuing deterioration of both surface and groundwater aquifers, the unequal distribution of water resources and periodic droughts have necessitated the exploration and development of new water sources (Metcalf & Eddy, 1991). In industrialized countries the problems associated with ensuring water supply and disposal of urban and industrial waste have been intensified. In contrast, in developing countries and especially in arid or semi-arid regions, there is a need for affordable technology in order to increase the exploitable quantities of water, along with the protection of the environment and the natural resources.
It is estimated that the use of "marginal" water could decisively contribute to the sustainable use of water resources through the implementation of integrated water resources management plans, where the recycled water will be considered an essential component for increasing the availability and control of pollution (Angelakis et al., 2002).
In the path for water sustainability, a key concern of the international community is finding alternative water sources. In this direction, the practice of reclaiming and reusing municipal waters wins more territory and is the objective of several academic projects. Thus, the necessity for establishing criteria for wastewater recycling and reuse has been widely recognised in many countries of the world. Development of criteria to minimize the microbial health risks associated with wastewater recycling and reuse should take into account other water related exposures such as through the food-chain, drinking water and contact with water in recreational areas.
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In this context, reclaimed and reusable water promotes an alternative reliable water source. Reusing treated wastewater basically compresses the hydrological cycle from an uncontrolled global scale to a controlled local scale (Durham et al., 2005).
Water reclamation and reuse: Definitions (Durham et al., 2005) Reclaimed water: Wastewater that has been treated to meet specific water quality standars with the intention to be used for a series of purposes. Water Reuse: The use of appropriately treated wastewater. Non-potable reuse (NPR): The use of reclaimed water for purposes other than drinking water (e.g. irrigation). Direct potable reuse (DPR): The use of reclaimed water directly into drinking water after advanced treatment. Greywater: Used water discharged from homes, business, industry, and agricultural facilities.
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An important issue is the need for the establishment of a legislative framework that enhances water and wastewater reuse. This framework should take into consideration all risks that may arise (health and environment), including microbiological and physicochemical quality parameters and proposing strategies for motivation and public acceptance. Public health protection
The reclaimed and treated water should not pose any risk to public health. So in this direction, regulations set limits on the amount of pathogenic microorganisms. Also special emphasis should be given to the frequent monitoring of the water quality reused. Finally, some guidelines suggest protective measures to be in place for the safety of the public that may be exposed directly or indirectly with the treated water (see Chapter 4). Environmental cost
The reuse of wastewater should be done with respect to the natural environment. The protection of ecosystems, the flora and fauna, the avoidance of further degradation of the natural resources are main targets. The calculation of the environmental footprint and the potential impact would be very useful at a preliminary level.
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Economic factors
The economic factor is one of the most important challenges in the issues of water and wastewater reuse. Financing such projects is possibly the main obstacle for the wider use of treated water. However, researchers are working on new technologies that may reduce the capital, the operation and the maintenance costs. Public acceptance & opinion
The authorities responsible for the distribution of reclaimed water (local communities, councils, organizations) should not only make sure of the safety of the provided water but also need to build trust and credibility with the public. This can be achieved with water reuse campaigns, educational programs or further motives. Aesthetics
In some cases and also for aesthetic reasons, reusable water should be colourless and odourless (e.g. for irrigation in gardens or parks, recreation areas). Also, attention should be given in harmonising the treatment process, chosen for the wastewater treatment, with the landscape and the environment.
20
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Water reuse can be direct or indirect. In recent years it has attracted more and more interest in the indirect reuse field even for indirect potable use (Leverenz et al., 2011). In the first case, water is reclaimed from wastewater transported from the treatment units for irrigation of agricultural land and recreational areas without the mediation of natural water sources or other aquatic formations. In the second case, indirect water reuse happens after the reclaimed water is mixed with surface or underground water resources that can be used as drinking water sources (Leverenz et al., 2011).
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The improvements in technology for wastewater and drinking water treatment have ensured that a range of new and emerging challenges from both microbial and chemical contaminants are met. Hence, the indirect recycling developed in many parts of the world for many years is demonstrated to be safe (UKWIR 2004). Table 3.1 summarizes the fields for reclaimed water use and the applications that treated water can have in these fields.
TABLE 3.1: CATEGORIES OF RECLAMATION AND REUSED WATER (USEPA, 2004) Categories Agricultural use Irrigation of food crops Characteristics
Other type of irrigation livestock, plant nurseries, lawn Irrigation in areas open to the public: parks, schools, fountains, fire protection, cooling, toilet cleaning
Irrigation in areas with limited access: golf courts, cemeteries, motorways Restricted use fishing, boating
cooling, boiler feed, process water maintain / increase watercourses flow, strengthening natural wetlands, aquaculture, enrichment of underground aquifers garden irrigation, car washing, toilet flushing, cooling Direct
Drinking use Indirect mixing with surface or underground drinking water sources
23
24
1969
10,000
1970
1975
10,000
1976
200,000
1977
500,000
1977
150,000
1984
1985 1987
City of El Paso, Texas, USA Monterey Regional Water Pollution Control Agency Monterey Wastewater, California, USA
38,000 5,500
1989
120,000
1989
The reclamation and reuse of wastewater seems to be a rapidly growing practice mainly in arid and semi-arid regions. Similar projects of increased number and extent are being programmed and implemented each year in several countries, particularly in the U.S., Australia, Israel, Japan, the countries of the Maghreb and South Africa (Paranichianakis et al., 2009).
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Because of its wealthy water resources and the existing differences between the member countries, the EU has not particularly dealt so far with reclamation and reuse water. However, the recent drought in Spain, Greece and other countries has posed serious questions for the crucial issue of water recycling. The most experienced country in reclamation and reuse of municipal wastewater is the U.S.A. In the 70s, 216 million cubic meters of treated wastewater were annually used (Asano & Tchompanoglous, 1991), while today this quantity has reached 555715 million cubic meters, which are distributed in more than 4,800 applications. Israel has a similar experience (Fine et al., 2006), where it is estimated that 20% of the needs are covered today with the use of reused wastewater. Moreover, Spain uses recycled water for four types of uses: watering golf courses, irrigation of crops, enhance aquifer of coastal areas to prevent the inflow of seawater and flow increase of rivers in order to protect riverside ecosystems (Castro, 2010). In Italy today treated wastewater is used to irrigate about 4000 hectares, whereas in Southern Italy the irrigation areas that use untreated wastewater is undefined (Barbagallo, 2001). Belgium is another example of water recycle for industrial purposes, as 38% (expected 60% in near future) of the wastewater is used in industrial operations. In the UK, treatment and recycling of waste water is limited. The recycled water is used mainly to maintain river levels and protect their ecosystems. It is also used to irrigate golf courses, parks and wash cars. Figure 3.2 shows the geographic distribution of recorded water reuse projects in conjunction with their capacity and reuse in applications. It is observed that the majority of these projects are large scale (> 5106 m3/s) with applications in agriculture.
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FIGURE 3.2: WATER REUSE PROJECTS IN EUROPE (SIZE & APPLICATION) (Bixio, 2006)
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In 1973, World Health Organization proposed the first criteria and treatment methods for various water reuse applications. The criteria established for the crop irrigation, have been characterised as particularly severe (100 FC/100 ml for unrestricted irrigation) and were based on the philosophy of zero risk (WHO, 1973). In 1989 the organization reviewed the directive and issued a new set of criteria, mainly of microbiological quality that emphasized on the type of irrigated crops. Irrigation is separated into two categories with the following limits (WHO, 1989): Unrestricted (crop irrigation, garden and recreational areas watering) 200 FC/100 ml
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Restricted (irrigation of crops not eaten raw). 1 helminth egg per litter In addition, the WHO directive takes in account, for the first time, the methods of wastewater treatment, the irrigation system and the exposed human groups. So, it recommends additional specific precautions such as using special clothing, high levels of hygiene, careful cooking, special washing facilities, control of human exposure, promoting of sanitation (WHO, 1989). In 2006, the Organization issued the third edition of the directives for safe wastewater reuse that replaced the previous two editions (Table 4.1). The main purpose of the new Directive is to protect the health of people that may come directly or indirectly in contact with the treated water. In this direction, WHO developed further information on issues relating with: Diseases of the population that contacts with the reclaimed wastewater Risk Analysis Risk managing strategies (quantification of safety measures) Chemical compounds in wastewater, whose acceptable limits are summarized in Appendix F. Strategies for the implementation of the Directives The current water quality parameter limits are described in Table 4.1 together with the proposed application.
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TABLE 4.1: DIRECTIVE LIMITS FOR MONITORING PARAMETERS FOR WASTEWATER REUSE IN AGRICULTURE AND AQUACULTURE (WHO, 2006). Activity / Exposure Agriculture Unrestricted irrigation Root crops Leaf crops Drip irrigation, high-growing crops Restricted irrigation Labour-intensive, high-contact agriculture Highly mechanized agriculture Septic tank Aquaculture Produce consumers Pond Wastewater Excreta Workers, Local communities Pond Wastewater Excreta 10 10 10
3 4 5
Water Quality Parameters E.coli per 100 ml Helminth eggs per litre
10 10 10
3 4 5
10 10 10
4 5 6
10 10 10
4 5 6
For the establishment of the appropriate legislation to protect public health, experts have defined specific levels of protection according to the type of exposure (health based targets). These levels are based on the fact that any disease that results from the use of reclaimed wastewater should not cause a "loss" greater than 10-6 DALYs (Disability - Adjusted Life Years) per person per year, as shown in Table 4.2 (WHO, 2006).
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TABLE 4.2: HEALTH-BASED TARGETS & HELMINTH REDUCTION TARGETS FROM WHO Irrigation type Unrestricted Restricted Target for viral, bacterial & protozoan pathogens 10 DALY per person per year 10 DALY per person per year 10 DALY per person per year Localized (e.g. drip irrigation)
-6 -6 -6
Microbial reduction target for helminth eggs 1 per litre 1 per litre Low-growing crops 1 per litre High-growing crops No recommendation
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Finally, WHO proposes a series of measures to protect consumers, workers, their families and local communities, as presented in Table 4.3.
TABLE 4.3: HEALTH BASED TARGETS FOR WATER REUSE BY WHO (WHO, 2006) Exposed group Health-based targets Quality parameters E.coli/100 ml Viable trematode/l - Wastewater treatment Consumers, workers & local communities Excreta-related diseases 10 DALY per person per year
-6
Hazard
10 (consumers) 3 10 (contact)
-Excreta treatment Not detected -Health & hygiene promotion -Chemotherapy & immunization -Produce restrictions -Waste application timing
Excreta-related diseases
-6
Consumers
Foodborne trematodes
10
-Depuration Not detected -Food handling -Produce washing/disinfection -Cooking foods -Access control
Chemicals
Excreta-related diseases
10 DALY per person per year Absence of skin disease Absence of schistosomiasis 10 (contact)
3
-6
-Use of protective equipment -Disease vector control No viable schistosome eggs -Intermediate host control -Access to clean drinking water & sanitation -Redusing vector contact
Schistosomiasis
Vector-borne diseases
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The US EPA issued its first directive on the reuse of municipal wastewater in 1980. The Directive was revised in 1992 and recently in 2004 in order to include more information and the advanced technologies (US EPA, 2004). US EPA revised Guidelines for Water Reuse published in 2004 contains updated information on water use and water reuse practices in the United States (USEPA, 2004). The revised guidelines propose treatment processes, safety distances, monitoring frequencies and define the limits of water quality parameters for each intended use of the output (Tables 4.4-4.6). Faecal coliforms (FC) are adopted as indicators to assess the microbiological quality of the treated wastewater and concentration limits for BOD and turbidity are also set. Furthermore a minimum level of disinfection for all purposes is recommended to avoid effects from accidental contact. Generally, for the majority of the applications the expected turbidity, TSS and pH are 2 NTU, 30 and 6-9, respectively, whereas BOD values vary due to the sensitivity
of each recipient (Tables 4.4, 4.5). As shown in Table 4.6 emphasis is given on the categories related to indirect potable reuse taking into account the findings of recent research studies which suggest groundwater recharge and surface water augmentation with treated wastewater. As expected, these standards are very strict with no detected coliforms, low turbidity ( 2 NTU) and mean pH values (6.5-8.5).
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TABLE 4.4: SUGGESTED GUIDELINES FOR URBAN & AGRICULTURAL REUSE (USEPA, 2012)
Treatment
Setback Distances
Unrestricted
(4)
pH=6.0-9.0 (7) 10mg/l BOD (8) 2 NTU (9,10) No detectable faecal coliform/100ml (11) 1mg/l Cl2 residual (min) pH=6.0-9.0 (7) 30mg/l BOD 30mg/l TSS (9,13,14) 200 faecal coliform/100ml (11) 1mg/l Cl2 residual (min)
pH weekly BOD weekly Turbidity continuous Faecal coliform daily Cl2 residual continuous pH weekly BOD weekly TSS daily Faecal coliform daily Cl2 residual continuous
50 ft (15 m) to potable water supply wells; increase to 100 ft (30 m) when located in (18) porous media 300 ft (90 m) to potable water supply wells 100 ft (30 m) to areas accessible to the public (if spray irrigation)
Restricted
(4)
Agricultural Reuse
pH=6.0-9.0 (7) 10mg/l BOD (8) 2 NTU (9,10) No detectable faecal coliform/100ml (11) 1mg/l Cl2 residual (min) pH=6.0-9.0 (7) 30mg/l BOD 30mg/l TSS (9,13,14) 200 faecal coliform/100ml (11) 1mg/l Cl2 residual (min) pH weekly BOD weekly Turbidity continuous Faecal coliform daily Cl2 residual continuous pH weekly BOD weekly TSS daily Faecal coliform daily Cl2 residual continuous 50 ft (15 m) to potable water supply wells; increase to 100 ft (30 m) when located in (18) porous media 300 ft (90 m) to potable water supply wells 100 ft (30 m) to areas accessible to the public (if spray irrigation)
Food Crops
(4)
(4)
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Treatment
Setback Distances
Unrestricted
Restricted
Secondary Disinfection
pH=6.0-9.0 10mg/l BOD 2 NTU No detectable faecal coliform/100ml 1mg/l Cl2 residual (min) 30mg/l BOD 30mg/l TSS 200 faecal coliform/100ml 1mg/l Cl2 residual (min) Variable, but not to exceed: 30mg/l BOD 30mg/l TSS 200 faecal coliform/100ml 1mg/l Cl2 residual (min) pH=6.0-9.0 30mg/l BOD 30mg/l TSS 200 faecal coliform/100ml 1mg/l Cl2 residual (min) Variable, depends on recirculation ratio: pH=6.0-9.0 30mg/l BOD 30mg/l TSS 200 faecal coliform/100ml 1mg/l Cl2 residual (min)
500 ft (150 m) to potable water supply wells (min) if bottom not sealed.
500 ft (150 m) to potable water supply wells (min) if bottom not sealed.
Environmental Reuse
Variable Secondary and disinfection(min) BOD weekly SS daily Faecal coliform daily Cl2 residual continuous
Environmental Reuse
Industrial Reuse
Secondary
Once-through Cooling
pH weekly BOD weekly TSS daily Faecal coliform daily Cl2 residual continuous
300 ft (90 m) to areas accessible to the public. May be reduced if high level of disinfection is provided.
Site specific
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TABLE 4.6: SUGGESTED GUIDELINES FOR INDIRECT POTABLE REUSE (USEPA, 2012) Reuse Category & Description Indirect Potable Reuse
Treatment
Setback Distances
Includes, but not limited to, the following: No detectable total coliform/100ml pH=6.5-8.5 1mg/l Cl2 residual (min) pH=6.5-8.5 2 NTU 2 mg/l TOC of wastewater origin Meet drinking water standards after percolation through vandose zone
Includes, but not limited to, the following: pH daily Total coliform daily Cl2 residual continuous Drinking water standards quarterly Other depends on constituent TOC weekly Turbidity continuous Monitoring is not required for viruses and parasites: their removal rates are prescribed by treatment requirements Includes, but not limited to, the following: pH daily Total coliform daily Cl2 residual continuous Drinking water standards quarterly Other depends on constituent TOC weekly Turbidity continuous Monitoring is not required for viruses and parasites: their removal rates are prescribed by treatment requirements
Distance to nearest potable water extraction well that provides a minimum of 2 months retention time to the underground.
Includes, but not limited to, the following: No detectable total coliform/100ml pH=6.5-8.5 1mg/l Cl2 residual (min) pH=6.5-8.5 2 NTU 2 mg/l TOC(7) of wastewater origin Meet drinking water standards Includes, but not limited to, the following: No detectable total coliform/100ml pH=6.5-8.5 1mg/l Cl2 residual (min) pH=6.5-8.5 2 NTU 2 mg/l TOC(7) of wastewater origin Meet drinking water standards
Distance to nearest potable water extraction well that provides a minimum of 2 months retention time to the underground.
Site specific based on providing 2 months retention time between introduction of reclaimed water into a raw water supply reservoir and the intake to potable water treatment plant.
37
38
Water Quality Disinfected Tertiary recycled water Disinfected Secondary 2.2 recycled water Disinfected Secondary 23 recycled water Direct beneficial Use (no disinfection)
Total Coliform [MPN] < 2.2 per 100 ml 2.2 -23 per 100 ml < 23 per 100 ml -
Other space control measures include the reduction of runoffs while using recycled water, the protection of recreational places of human contact, the placement of warning signs like: "Recycled waterNon potable" and others.
The state of California has also established criteria of the enrichment of underground aquifers (directly and indirectly) with treated wastewater since 1974, which were recently revised. More details on the allowable uses for recycled water according to the State of California can be found in Appendix G.
FIGURE 4.1: CALIFORNIAS WARNING SIGN FOR RECYCLED WATER (State of California, 2003)
39
40
TABLE 4.8: WATER REUSE PRACTICES & CRITERIA IN EUROPEAN COUNTRIES (Angelakis et al., 2002) Unlimited Urban Country Albania Belgium Croatia Cyprus France Greece Italy Malta Monaco Spain UK
1: 1
use
TABLE 4.9: EXISTING WATER REUSE CRITERIA IN EUROPEAN COUNTRIES (Bixio et al., 2006) Country Type of Criteria Aquafin proposal to the Government (2003) Provisional Standards Art. 24 dcret 94/469 3 1994 Circulaire DGS/SD1.D./91/n51 Decree of Environmental Ministry 185/2003 Guidelines Law 29/1985, BOE n.189, 08/08/85 Royal Decree 2473/1985 Guidelines Notes
Belgium Cyprus
Based on Australian EPA Guidelines TC < 50/100 ml in 80% of the cases on a monthly basis and < 100/100 ml always Based on WHO standards Based on WHO standards and Title 22, respectively Based on Californias Title 22
France Italy Regional authorities: Sicily, Emilia Romagna & Puglia Spain Regional authorities: Andaluca, Balearic & Catalonia
41
In the UK, British Standards has published BS8525-1: 2010 for greywater systems. These recently published standards provide tables with the water quality requirements for reuse purposes and include guidelines for the designing, the implementation and the maintenance of greywater treatment systems. Table 4.10 describes these water quality requirements.
TABLE 4.10: EXISTING WATER REUSE CRITERIA IN THE UK (BSi, 2010) Parameter Escherichia coli /100 ml Intestinal enterococci/ 100 ml Legionella pneumophila / 100 ml Total coliform / 100 ml Spray application Not detected Not detected 10 10 Non-spray application 250 100 N/A 1000
Since 1984, the Environmental Policy Agency of the State New South Wales (NSW) has established a council to develop guidelines and promote the reclamation and reuse of treated wastewater. Recent studies estimate that in the area of Sidney approximately 1.3 Mm3/d are being treated of which 0.031 Mm3/d are being reused (NSW, 2008).
42
The initial Australian EPA guidelines provided criteria for three categories of reuse of secondary treated water after disinfection for agricultural and industrial use, with the following quality criteria: i. ii. iii. Category A: < 300 cfu/100 mL FC, after 30 days storage Category B: <750 cfu/100 mL FC , after 20 days storage Category C: <2.000 cfu/100 mL FC, after 10 days storage
A couple of years later, the same organization established criteria for urban and unlimited use of wastewater effluents, with the following qualitative characteristics: FC <1/100 mL, TC <10/100 mL, viruses <5/50 L, parasites <1/50 L (NSW, 2008). Japan
In Japan, unlike other countries in arid or semi-arid areas, the main categories in wastewater reuse are based on the enhancement of the environment, toilet cleaning, industrial use and snow production (Nagasawa, 2009). The quality requirements seem to be strict (Table 4.11) as they are the same for all reuse purposes (Jefferson et al., 1999).
TABLE 4.11: REUSE CRITERIA IN JAPAN (Jefferson et al., 1999)
BOD5 [mg/l] 10
Turbidity [NTU] 5
pH 6-9
43
44
The purpose of wastewater treatment is to return the water in nature with acceptable quality characteristics that are compatible with the desired uses, in order to protect public health and natural ecosystems, preserve the environment and avoid depletion of water resources, which despite their apparent abundance, are not inexhaustible in front of the growing human population and multiple needs (Metcalf & Eddy, 1991). The following figure (5.1) demonstrates that wastewater reclamation technologies have progressed to such an extent, that the produced treated water can be of higher quality than that of drinking water .
FIGURE 5.1: TREATMENT TECHNOLOGIES FOR ANY TYPE OF REUSE (USEPA, 2012)
45
46
In addition, greywater is divided in two categories according to its load, as high load greywater needs a different type of treatment than low load greywater. Figure 5.3, describes the two types of greywater loading.
Specifically, greywater corresponds to up to 70% of the total domestic consumed water (44% in the UK) but contains only 30% of the organic fraction and 9-20% of the nutrients (Pidou et al., 2007). However, greywater has several other characteristics, considering the quantity and quality, which are described further in the following section (5.1.1).
47
TABLE 5.1: AVERAGE GREYWATER YIELD & DEMAND (BSi, 2010) Occupancy Yield [litres] WC 1person 2 people 4 people 8 people 10 people 15 people 20 people 30 people 50 people 100 people 150 people 200 people 500 people 1000 people 10000 people 50 100 200 400 500 750 1,000 1,500 2,500 5,000 7,500 10,000 25,000 50,000 500,000 25 50 100 200 250 375 500 750 1,250 2,500 3,750 50,000 12,500 25,000 250,000 Demand Laundry 15 30 60 120 150 225 300 450 750 1,500 2,250 3,000 7,500 15,000 150,000 Other uses 10 20 40 80 100 150 200 300 500 1,000 1,500 2,000 5,000 10,000 100,000
1
48
As far as greywater quality is concerned, the main polluting parameters are: Suspended Solids (TSS) - Organic load (COD, BOD5) - Nitrogen and Phosphorus compounds - Dissolved solids (DS) and the microbes (coliforms, bacteria, viruses, protozoa). Table 5.2, summarizes the physicochemical characteristics of greywater, as found in literature (Metcalf & Eddy, 1991).
TABLE 5.2: SUMMARY OF GREYWATER CHARACTERISTICS (Metcalf & Eddy, 1991) Parameters Units Value
pH Conductivity Turbidity TSS Raw COD Filtered DO BOD5 NT PT Anionic Surfactant E.Coli Fecal Enterococci
C/cm NTU mg/L mg/L mg/L mg/L mg/L mgN/L mgP/L mg/L LSS CFU/100 mL CFU/100 mL
6.4 - 8.1 82 - 1845 0 - 240 48 - 435 100 795 82 472 0 176.9 50 539 3.8 17 0.1- 2 9 86 0 2.5110 0 2.5110
7 5
49
Pre-treatment in which materials, such as cloths, gravels, sand particles, small pieces of wood or plastic, oil, grease, etc. are being removed because they usually cause damage to the mechanical equipment and problems in the maintenance/operation of the system.
Primary treatment in which part of the suspended solids and organic substances are being removed.
Secondary treatment in which the biodegradable organic substances, the suspended solids and the nutrients (nitrogen and phosphorus) are being removed with the use of biological and chemical processes. Noted that disinfection is also included in the standard definition of conventional secondary treatment.
Tertiary treatment in which the remaining suspended solids from the secondary treatment are being removed, typically using filtration means.
Advanced treatment for the removal of suspended and dissolved substances of the waste those remain after the usual biological treatment when this is required in various applications of water reuse.
50
Research on greywater treatment and reuse has been observed in literature since 1970 (Hall et al., 1974; Hypes et al., 1975; Arika et al., 1977). The primary technologies investigated were physical based treatment schemes, such as coarse filtration and membranes, usually followed by disinfection. These technologies were implemented and tested years later, initially in single houses (Brewer et al., 2000). Between 1990-2000 more advanced biological treatment options were studied for greywater treatment, such as rotating biological contactors (Nolde, 1999), biological aerated filters (Surendran and Wheatley, 1998) and aerated bio-reactors (Shin et al., 1998; Brewer et al., 2000). Later researches have suggested the use of more complex technologies like membrane bioreactors (MBRs) (Friedler, 2005; Liu et al., 2005) and in lieu of these expensive options, natural treatment systems such as constructed wetlands (Shrestha et al., 2001; Dallas et al., 2004; Gross et al., 2007). As far as chemical based greywater treatment options are concerned, only three are mentioned in literature; conventional coagulation (Sostar-Turk, 2005), electrocoagulation (Lin et al., 2005) and photocatalysis (Parsons et al., 2000). The choice of the appropriate treatment highly depends on the reuse application and the influent flow rate. Overall greywater treatment systems can be categorised according to their treatment type as follows (Pidou, 2007): Basic systems (coarse filtration, sedimentation and disinfection) Physical systems (sand filter, adsorption and membranes) Biological systems (biological aerated filter, rotating biological contractor and membrane bioreactor) Chemical systems (conventional coagulation, electro-coagulation and advanced oxidation methods) Extensive systems (ponds and reed beds)
51
In the extensive systems physical, chemical and biological processes take place. The main distinction is that treatment in extensive systems flows naturally, thus in slow velocities, whereas in conventional systems treatment is being done rapidly, because of the imposed artificial conditions.
52
The purpose of coarse filtration is the removal of the sizeable materials or particles that greywater may contain (sand, pieces of wood, plastic, branches, rags, etc.), in order to eliminate the suspended solids. However, it provides only a restricted treatment in terms of organics and solids (Pidou, 2007). Nevertheless, it is a simple filtration system which can be easily installed in households by anyone with even limited DIY skills.
FIGURE 5.4: TYPICAL FLOW DIAGRAM OF BASIC SYSTEM COARSE FILTRATION (Pidou, 2007)
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Sedimentation
The aim of sedimentation is to separate the substances that float and the ones that precipitate from greywater (Metcalf and Eddy, 1991). It is a physical separation process of the suspended particles based on gravity, of which the specific weight is greater than that of water (d>100 m and C>50 mg/L). The widespread implementation of sedimentation systems is due to the simplicity of the method, despite the complications often occurred in sedimentation tanks, and the low energy consumption.
FIGURE 5.5: TYPICAL FLOW DIAGRAM OF BASIC SYSTEM SEDIMENTATION (Pidou, 2007)
54
Sand filters are used for the removal of suspended particles, turbidity and bacteria from greywater. The basic principle of filtration through a bed of sand (and in some cases a combination of sand and anthracite) is already adopted by nature (Darakas, 2010). Sand filters usually offer high speeds of filtering and can have an increased lifetime when properly maintained through frequent backwashing. Thus, their implementation has low operation and maintenance costs (Pidou, 2007). However, when used alone sand filters offer coarse filtration, which means weak treatment levels, so they are often combined with disinfection (Hypes et al., 1975). Hypes et al. (1975) reported good removal of total coliforms but inadequate removal of suspended solis and turbidity. The addition of an adsorption technique, like activated carbon, interestingly may not provide considerable improvement to the results (Pidou et al., 2007). A typical flow diagram of a sand filter system is illustrated in Figure 5.6 below.
FIGURE 5.6: TYPICAL FLOW DIAGRAM OF PHYSICAL SYSTEM SAND FILTER (Pidou, 2007)
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Membranes
The application of membranes in advanced water and wastewater treatment is a new and promising technology in that it is increasingly attracting interest from environmental researchers. The main disadvantage of this technology is the high cost and energy consumption. Despite this, literature shows surprisingly positive results (Tsonis, 2004), concerning the efficiency of the method (Table 5.3):
TABLE 5.3: REMOVAL OF VARIOUS COMPONENTS USING MEMBRANES (Tsonis, 2004) Parameters MF UF NF RO
Biodegradable Organic Compounds TDS TSS Heavy Metals Hardness Nitric ions Synthetic Organic Compounds Priority Organic Compounds Bacteria Protozoa, Helminth eggs Viruses
Membranes are usually made of cellulose acetate (rayon) or proprietary polymers such as polyamides (Judd and Jefferson, 2003). Each membrane presents best performance values in a certain range of temperature, pH and qualitative characteristics of the liquid, which requires experimental data for the selection. In Figure 5.7, a flow diagram of a typical membrane physical treatment is illustrated, where MF, UF, NF or RO membranes can be implemented.
56
FIGURE 5.7: TYPICAL FLOW DIAGRAM OF PHYSICAL SYSTEM MEMBRANES (Pidou, 2007)
The main advantages of using membrane technologies for greywater treatment are the excellent removal capacity of dissolved and suspended solids and the good removal of organic compounds. On the other hand, limitations in membrane implementation include the high operation and maintenance costs, which are mainly due to the large energy consumption needed to achieve the required overpressure, the demands for regular replacement or cleaning of the membranes and the disposal of the produced concentrate (Sostar-Turk, 2005; Pidou, 2007).
57
Chemical coagulation in wastewater treatment is the process in which flocculants of the suspended matter are created in colloidal dimensions. This process is necessary in order to allow the precipitation of these substances which precipitate with a very slow pace because of their small size (10-3 m 1 m). Therefore the flocculants generated during the process, which are larger and denser, facilitate and accelerate sedimentation alongside easing filtration (Gregory, 2013). Sostar- Turk (2005), proposes coagulation coupled with a sand filter and activated carbon for the treatment of high load greywater, with impressive results in the removal of suspended solids (100%) and satisfying removal of COD and BOD, 93% and 95% respectively. These results can be found in more detail in the summarised tables in Appendix C.
FIGURE 5.8: TYPICAL FLOW DIAGRAM OF CHEMICAL SYSTEM COAGULATION (Darakas, 2010)
58
The electrochemical flocculation or electro coagulation is an advanced and efficient electrochemical technology for removal of organic and inorganic contaminants from wastewaters (Lin et al., 2005). This method differs from the conventional chemical coagulation in the fact that the coagulants (Al(OH)3, Fe(OH)3 and Mg(OH)2) are not added into the wastewater but are being generated in situ due to electro dialysis of the anodes of Al, Fe or Mg (Tsonis, 2004). This method has been tested for low load greywater in Taiwan by Lin at al. (2005), showing good levels of treatment. Photocatalysis
Photocatalysis (PCD) is an advanced oxidation method which is becoming increasingly important in wastewater treatment especially in cases when greywater contains small quantities of refractory organic substances (Mills et al., 1997). This method is based in the ability of the UV light to extract constantly electrons from TiO2 and create pairs of holes (h+) and electrons (e) that with the combination of water create hydroxyl radicals (OH-). Hydroxyl radicals are one of the most powerful oxidants, which react and degrade all harmful organic compounds in greywater (Tsonis, 2004). This technique can be applied in special photobioreactors installed in greywater treatment plants. A detailed flow diagram is illustrated in Figure 4.8. Parsons (2004) tested the efficiency of a bench scale system that used photobiorector (TiO2/UV) that showed interesting findings which can be found in Appendix C.
59
FIGURE 5.9: TYPICAL FLOW DIAGRAM OF CHEMICAL SYSTEM PHOTOBIOREACTOR (Parsons, 2004)
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sedimentation, and screening) in order to meet the quality demands (Pidou, 2007). Pidou et al. (2007) in their publication, state that biological systems are the type of treatment most commonly seen in big scale treatment projects. In fact, these schemes have been reported to treat greywater generated in multi-storey buildings (Nolde, 1999) and student accommodation (Brewer, 2000). This Section demonstrates the three most applied systems, as these seem to be very promising and differ significantly among them.
61
This system, which can also be applied to large settlements, is particularly attractive in the case of small settlements, because of its simplicity and its ability to respond very well to flow and pollutant load frequent fluctuations (MEECC, 2012). The system is characterised by the high level of organic load removal, which can exceed 95% (Shin et al., 1998). One of the main features of the system is the combination, in a common reservoir, of activated sludge bioreactor functions and these of secondary sedimentation. An SBR has three basic alternating operating phases (2, 3, and 4) as demonstrated in Figure 5.10. The main difference with a conventional activated sludge system lies in the fact that in the SBR reactor the distinction of biochemical reactions and sedimentation is not spatial but temporal (Darakas, 2010).
FIGURE 5.10: TYPICAL FLOW DIAGRAM OF BIOLOGICAL SYSTEM SBR (MEECC, 2012)
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The main advantages of this system are (Shin et al., 1998; Darakas, 2010): Good removal of organic load expressed as BOD5. Satisfactory removal of nitrogen and phosphorus. Small area requirement. Relative simplicity of the system. Absence of sedimentation tanks, pipes for handling wastewater and pump stations. Minimum staff requirement, because operation phase is easily automated. Sludge bulking problems are almost nonexistent, and in any case can be easily controlled. The main disadvantages of an SBR are: High construction and operation costs (generally lower than conventional activated sludge and extended aeration systems). High energy consumption. Advanced electrical equipment and automation systems. Construction of equalization tank.
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Membrane Bioreactors is a relatively recent development in the field of wastewater treatment. This method is essentially a combination of the classical and widespread method of activated sludge with filtration (MF or UF), thus eliminating the use of sedimentation tank as a means of final effluent clarifier and sludge condenser (MEECC, 2012). Specifically, the novelty of the method lies in the use of special new technology membrane films which are submerged in the stream and through which the influent is moving (Darakas, 2010). The flow diagram of the bioreactor is presented below in Figure 5.11. The high concentration of biomass in the bioreactor, results in the accomplishment of full decomposition of the organic matter (small amount of excess sludge) and nitrification within 3 hours. The method can be an autonomous process, after a simple pretreatment, as literature provides very promising results about the efficiency of the system.
FIGURE 5.11: TYPICAL FLOW DIAGRAM OF BIOLOGICAL SYSTEM MBR (MEECC, 2012)
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MRB presents the following advantages (MEECC, 2012): High outflow quality (removal of organic load expressed as BOD5 > 95%). Presents no problems of sludge sedimentation Reduced volume system requirements Works perfectly even as a decentralized wastewater treatment system with great flexibility depending on the population served Needs limited but skilled personnel It can fit perfectly with the natural environment Causes minimal disturbance
Among the major drawbacks of MBR are (MEECC, 2012): High fixed costs of membranes High operating costs (due to the need of regular membrane replacement) Limited application (relatively modern technology) Require delicate screening upstream of the membranes to avoid fouling problems Requires an equalization tank
65
Rotating biological contactor is a system that combines many of the advantages of traditional activated sludge systems (small area requirement) and these of biological filters (simplicity of operation, low operational costs). The rotation of the biological discs provides effective ventilation and sufficient contact with the effluent and biomass so as to achieve high organic load removal and in some cases nitrification (Darakas, 2010).
FIGURE 5.12: TYPICAL FLOW DIAGRAM OF BIOLOGICAL SYSTEM RBC (MEECC, 2012)
An RBC has the following advantages: High removal of organic load Small area requirement Simplicity of operation Low operating cost Easy biomass and effluent separation Stability of both hydraulic and organic load fluctuations System flexibility Denitrification potential using appropriate devices
66
The main disadvantages of RBCs are: May encounter operational problems, mainly in the support and rotating mechanism of the filters Require to be combined with sedimentation tanks Odour problems
Appendix D includes a detailed table with the performance data of the biological based systems found in literature.
67
These systems are usually soils flooded with an amount of shallow water (<0.6 m), in which specific flora is being cultivated for treatment reasons. There is a variety of plants that may be used for this process in reed beds such as Phragmites australis (Shrestha et al., 2001), Coix lacryma-jobi (Dallas et al., 2004) and many other hydrophilic species. The vegetation is the substrate for the bacteria growth that assists in filtering and adsorbing the components of waste, transports the oxygen in the water mass and reduces the growth of algae by controlling the amount of solar radiation (Darakas, 2010). Both artificial and natural wetlands are used for greywater treatment. Reed beds are a simple and effective solution for small treatment units, to serve even until 2,000 inhabitants, when the required output has low organic load (BOD5 <5mg / l) and solids (TSS <10mg /l).
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The advantages of reed beds are summarised below (Tsonis, 2004): Low construction, operation and maintenance costs Resistance in hydraulic and pollution load fluctuations Easy to customise it with the surrounding ecosystem and aesthetics of the area Enhances green technology
Some disadvantages include: Low nitrogen and phosphorus removal. Odour and insect problems. Large areas requirement Strong dependence on climatic factors Inability to treat greywater with high organic load.
Ponds
The most common natural scheme for greywater treatment systems are the systems of artificial ponds (Gross et al., 2007). It is usually earthen basins used for the treatment of municipal sewage and rarely for industrial wastewater. Ponds are classified depending on the frequency of evacuation they undergo. Despite this
classification, they are divided in categories according to their depth and biological processes (Tsonis, 2004). So, ponds may be aerobic, anaerobic or aerated.
The advantages of artificial ponds are (Tsonis, 2004): The low manufacturing and operation costs. The possibility to adjust the effluent flow rate. The stability in the fluctuations of the organic load, due to dilution.
69
The disadvantages of ponds are: Requirement for large areas. Possible odours (especially where anaerobic decomposition takes place). The high concentration of suspended solids in the effluent (due to high concentrations of algae) (Gross et al., 2007). Strong dependence on climatic factors.
A typical flow diagram of constructed wetlands is shown in Figure 5.13 and a detailed table with the literature findings on the performance of these systems in included in Appendix E.
FIGURE 5.13: TYPICAL FLOW DIAGRAM OF EXTENSIVE SYSTEMSCONSTRUCTED WETLANDS (Pidou, 2007)
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5.3 DISCUSSION
The literature review indicates that sand filters and simple technologies have been shown to attain a limited treatment of the greywater, whereas membranes have been reported to provide great elimination of the solids but could not deal with the organic fraction efficiently. On the other hand, extensive and biological schemes can accomplish a reliable general treatment of greywater with a significant removal of the organics. However, the most proficient by and large performances were reported within the schemes that combined different approaches to guarantee efficient treatment of all the fractions. Finally, all the above technologies cannot be completely evaluated without an investigation of their economic feasibility, which can be found in the next chapter.
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otherwise the decision maker should, in the context of sustainable development, select technical solutions that meet the environmental and social constraints, have lower energy requirements and minimum cost. As part of the effort to achieve the environmental and social goals, the engineer can choose between a variety of technological schemes, as analysed in Chapter 5. The range, however of this choice is restricted, by several factors, of which the most important is cost. The aim of this Chapter was to provide a comparative evaluation of the total costs (construction, operation and maintenance) of some of the most important greywater treatment systems, suitable for a range of units (from domestic to municipal) and costs of wastewater treatment plant that may implement these technologies. The findings of this Chapter followed a long term literature research and communication with wastewater treatment companies and specialists. This Chapter can be useful for the preliminary assessment of these systems, but also constitute the basis for estimates and other options.
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The first five elements generally correspond to 85% of the total capital expenditures (Andreadakis et al., 1992). However, the structure costs together with the building and insulation costs are not included in this study as the study focuses on the treatment costs.
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Basic systems
Basic systems are marketed and promoted as being simple to use with low operational costs (Pidou et al. 2007). Usually these systems are coupled with disinfection in order to provide a satisfactory treatment level. For this reason there is no economical data for individual basic systems. However, there are three case studies that provide costs (Table 6.1) for complete treatment systems that include coarse filtration or sedimentation (Brewer et al. 2000; Hills et al., 2001; March et al., 2004).
Location
1
Structure
System
Filtration + Disinfection Coarse filtration + Disinfection Screening +
UK
House
UK
Houses
28 m /day
Spain
Hotel
Sedimentation + Disinfection
38 hours
11,500
0.50/m3
From literature, only the system located in Spain was observed to be cost effective as it had savings of 0.75/m3 and a payback period of 14 years (Pidou, 2007).
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technologies in the case of greywater reclamation, as they provide an excellent treatment level. The economical data concerning these systems was provided from wastewater treatment companies in the UK and from one case study, summarised in Table 6.2.
TABLE 6.2: COST OF PHYSICAL SYSTEMS
Location
UK
1 2
Structure
Houses Houses
System
Sand filter Activated carbon filter Membrane plant
Slovenia
Slovenia
Houses
UF/RO
200 m /day
When comparing the costs of the above schemes, the filters coupled with activated carbon seem to be cost effective and with high pollutants removal rates, at the same time (Sostar-Turk, 2005). However, membrane plants are a more sustainable option, because only 25% of effluent water ends in the environment and about 75% is recycled ((Sostar-Turk, 2005). This means that larger amounts of water are recycled annually, thus more money is being saved. Nevertheless, site specific scenarios should be studied because even though the percentage of the recycled water may be high the membranes cost is still 50% higher than that of GAC.
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Chemical systems
As far as the chemical systems are concerned, there are some costs data in literature (Table 6.3) from already tested wastewater treatment plants, yet evidence of photobioreactor costs is not available.
TABLE 6.3: COST OF CHEMICAL SYSTEMS
Location
Slovenia
1
System
Coagulation + Sand filter + GAC Electro-coagulation + Disinfection
Taiwan
28 m /day
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Biological systems
The biological schemes that can be implemented for greywater reclamation are usually coupled with other treatment schemes and an although expensive option can also be effective (Pidou et al., 2007). A summary of the cost data for biological systems can be found in Table 6.4.
Location
Structure
System
Screening +
Capital Costs
O&M Costs
UK
Student hall
1720
128 /year
UK
Student hall
0.65 m /day
30,000
611/year
Australia
House
N/A
3
N/A 17-20/year
Germany
Houses
0.6m day
UK
Houses
125 m /day
> 20/m3
UK
Houses
Membrane bioreactor
(Al flocs on substrate)
35/m2
4,000 m /day
3
17-21/m3
UK
Houses
Membrane bioreactor
(polypropylene membrane)
30-40/m2
3,750 m /day
3
12/m3 160-260/year
USA
House
SBR
N/A
5500 -7700
1: Surendran et al., 1998, 2: Brewer et al., 2000, 3: Pidou et al., 2007, 4: Nolde, 2005, 5: Visvanathan et al., 2000, 6: Obropta, 2005
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Extensive systems
Apart from being considered as sustainable technologies, extensive or natural systems are also regarded as low cost options for greywater recycle. In fact,
literature has provided some interesting data concerning the costs of constructed wetlands, compiled in Table 6.5. In addition, further cost data are shown in the following table, for modular reed beds, gathered from a wastewater treatment company that specializes in natural treatment systems.
TABLE 6.5: COST OF EXTENSIVE SYSTEMS
Location
1
Structure
System
2 Reed beds + Pond Sedimentation + Reed bed 3 Ponds + Sand filter Vertical flow reed beds Horizontal flow reed bed
Costa Rica
2
3 Houses
Nepal
House
3
Sweden
Student hall
Ireland
Ireland
1: Dallas et al., 2004, 2: Shrestha et al., 2001, 3: Gunther, 2000, 4: Herr Ltd., 2013
The only economic constraint of constructed wetlands is the cost of the substrate media which may be 50% of the total construction costs, thus raising significantly the budget for small scale treatment plants (USEPA, 1999).
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TABLE 6.6: UNIT COST OF WATER DISTRIBUTION &TRANSMISSION PIPELINES (COSTwater, 2013)
Frost areas / m
143.2 140.6 152.8 165.0 210.0 254.3 284.5 314.0 319.8 373.7 539.4 745.6 800.2 1103.3 1116.1 1251.0 1326.7 1819.3
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TABLE 6.7: UNIT COST OF WATER TRANSMISSION PUMPING STATION (COSTwater, 2013)
/ m3/d
77.1 60.4 43.7 34.0 26.3 19.3 14.8
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The personnel needed of each treatment plant depend on its size and complexity. The replacement costs apply to those design elements that have shorter lifetime than the planned period and should therefore be replaced sooner (e.g. membranes). Replacement cost is the same as the original cost of the items (Metcalf and Eddy, 1995).
10% 18% 9% Water discharge fee Electric fee Chemical fee Sludge transport and disposal 18% 26% Administration cost Maintenance & Replacement cost 6% Staff cost
13%
FIGURE 6.3: BREAKDOWN OF RUNNING COSTS OF A W ASTEWATER TREATMENT PLANT (adapted from COSTwater, 2013)
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Generally, the energy requirements of reclaimed water treatment may vary from 0.4 to 1.53 kWh/m3 (or 1.4 to 5.5 MJ/m3) (NRC, 2012).
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TABLE 6.8: COST OF MICROBIOLOGICAL MONITORING ANALYSIS (adapted from Salgot et al., 2006)
Parameter
Legionella E.coli and similar Enterococci (Salmonela) Nematode eggs Taenia Giardia and Cryptosporidium Bacteriophage Enterovirus
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TABLE 6.9: COST OF PHYSICOCHEMICAL MONITORING ANALYSIS (adapted from Salgot et al., 2006)
Parameter
Indicators
Monitoring frequency1
pH, EC, Turbidity, TSS COD, BOD, DO, AOX Total N, NH4+-N, Total-P NO3-, SO42+, CN-, F-, ClCl2 (if chlorination) Disinfection products As, Cd, Cr, Hg, Pb, B, Al, Ba, Be, Co, Cu, Fe, Li, Mn, Mo, Ni, Se, Sn, Th, V, Zn Surfactants Mineral oil Pesticides EDTA
(Heavy) metals
Organic micropollutants
1: Frequency: 5 years)
(permanently-weekly),
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6.3 DISCUSSION
The cost information provided in this Chapter is an initial level of details and can be useful for basic financial evaluations, as it does not include building construction and water disposal system costs. However, demonstrates cost trends concerning the capital, the operational and the maintenance costs. Primarily, energy requirements of the plant seem to determine the operating expenses. As far as the treatment schemes are concerned, they show many economical variations. In brief, it is observed that natural processes (e.g. reed beds) that do not require mechanical equipment and large amounts of energy are generally the most economical option. Whereas advanced treatment schemes (e.g. MRB) have high capital and operational costs. Gratziou (2005) used mathematical modelling in order to rank the cost of some schemes according to the equivalent population as shown in Table 6.10.
TABLE 6.10: RANKING OF TREATMENT SCHEMES ACCORDING TO THEIR COST (Gratziou, 2005)
In any case the overall and the running costs of greywater treatment plants depend on of the type and capacity of the unit thus is difficult to evaluate their costeffectiveness.
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The composition and origin of wastewater (domestic, commercial, industrial) should be determined. In the case of greywater, it can be characterised as low or high load greywater. In addition, the quantity (flow) of the produced greywater will determine the area footprint of the treatment facility and the selection of treatment processes that need to be employed. Desired quality performance
This is determined by the final recipients of the reclaimed water, which may have quality requirements for specific reuse applications, always in accordance to the legislation. Legislation
The regulatory determinants and discharge standards for the quality of treated effluents in accordance with the regional and national standards and guidelines that must be met for the end use of the reclaimed wastewater.
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Economic factors
Economic affordability of the various treatment processes used in wastewater reclamation should be taken into consideration, with the analysis of the capital, operational and maintenance costs. Environmental conditions
These may include the land availability, geography and climate. Location
The availability of local skills for design, construction as well as operation and maintenance may dictate the technical acceptability of the various treatment options. Unlike in developed and industrialised countries, capital is scarcely found in poor and developing countries and therefore, available treatment options tend to be less automated and energy intensive. Furthermore, setting up water reuse networks requires not only the understanding of the network connections, but also the correlation between the suggested treatment schemes in the processing stages. Figures 7.1 and 7.2 were designed in order to ease this understanding and are the basis of Treatment Scenarios (Section 7.1).
88
These diagrams illustrate the user configuration of the network with water transfer between the supplier and the recipients. In details, Figure 7.1a, is the central supply core, in which a group of suppliers deliver their outputs after treatment to other users. On the other hand, Figure 7.1b represents a network of individual users, in which the supplier is also the user after recirculation. Finally, the third diagram, Figure 7.1c, illustrates the demand relationship of one to many and many to one.
Figure 7.2 shows the summarised figures of all the suggested greywater treatment schemes (Chapter 5) organised in the relevant treatment stages in order to support the design of the networks treatment scenarios.
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FIGURE 7.2: SUMMARY OF TREATMENT SCENARIOS FOR GREYWATER RECLAMATION (adapted from Tilley et al., 2008)
90
7.1
TREATMENT SCENARIOS
This section aims to investigate four (4) potential scenarios for greywater treatment, which have been selected after extensive research in order to meet both the legislative and the economic standards. In the first part, four flow diagrams, one for each scenario describe the stages of the treatment processes selected. The second part presents the relevant summarizing tables for the quality performance and cost effectiveness of these scenarios. The flow diagrams include solid lines that illustrate the core treatment stages and dashed lines that describe the optional steps. The corresponding tables on the other hand incorporate three main subjects; systems performance, legislative criteria and costs.
Scenario 1 - Constructed wetland system, combines a natural treatment system with primary sedimentation (basic system), leading the effluent into UV disinfection before storage or distribution. Scenario 2 Rotating Biological Contactors system employs two sedimentation processes before and after the RBC, with a final disinfection stage. Scenario 3 Sequencing Batch Reactor system includes a pre-treatment stage with a sieve filter and then introduces the effluent in the SBR system and the UV disinfection tank. Scenario 4 Membrane Bioreactor system, unlike all the above systems is a one stage treatment that may need only disinfection.
91
92
System Performance < 17 mg/l < 13 mg/l < 50 mg/l < 10 NTU < 102 CFU /100 ml < 102 CFU/100 ml
System Costs
93
94
Scenario 2 RBC
Quality Parameters BOD5 TSS COD Turbidity Faecal Coliforms Legislative criteria < 10 mg/l < 30 mg/l N/A < 10 NTU < 250 CFU /100ml
1
Systems Performance < 8 mg/l < 13 mg/l < 40 mg/l < 2 NTU > 1 CFU /100 ml
Systems Costs
1,625,000
95
96
Scenario 3 SBR
Parameters Legislative criteria
1
Systems Performance
Systems Costs [] 61,100 89,050 220,350 263,250 263,250 366,600 474,500 760,500
1: (BSi, 2010; USEPA, 2012) , 2: (Pidou, 2007) 3: (EPA, 1999; COSTwater, 2013)
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98
Scenario 4 MBR
Quality Parameters Legislative criteria
1
Systems Performance
BOD5 TSS COD Turbidity Faecal Coliform Total Nitrogen NH3 Phosphorus
< 10 mg/l < 30 mg/l N/A < 10 NTU < 250 CFU /100ml N/A N/A N/A
< 2.0 mg/l < 2.0 mg/l < 45 mg/l < 1 NTU < 2.2 CFU/100 ml < 10.0 mg/l < 1.0 mg/l < 1.0 mg/l
25 LMH (l/m /hour) 36 360 3600 36000 40,131 114,660 401,310 1,146,600 5,000,000-6,032,000 36,800,000-40,300,000
1: (BSi, 2010; USEPA, 2012) , 2: (Pidou, 2007; Nalco, 2013) 3: (COSTwater, 2013)
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7.2
DISCUSSION
The above Treatment Scenarios constitute four possible greywater treatment systems which were selected after extensive literature research and personal communication with wastewater treatment companies. However, Figure 7.2 can be used to form other possible scenarios, as part of supplementary future studies in the field. From the findings analysis, it is shown that all the selected systems comply with the standards, concerning the quality parameters. This means that they accomplish very good removal levels of the organic load and solids found in greywater. It is worth noting that for the performance evaluation, the strictest legislative limits were chosen, in order to show the performance for demanding applications (BSi, 2010; USEPA, 2012). From the analysis of the systems costs, it is observed that these vary according to the capacity and scale of the treatment system, with the most expensive choice this of Membrane bioreactor, following the Rotating biological contactor, the Sequencing batch reactor and the Constructed wetland. Furthermore, Gratziou (2005) has developed a mathematical model that calculated the cost of treatment systems according to the equivalent population. Figure 7.7 illustrates the results for our scenarios and it is shown that increased systems capacities correspond to lower costs per m3 of wastewater per capita. This means that large scale reuse projects may be more cost effective than these of domestic scale.
100
9000.0
8000.0
7000.0
6000.0
Constructed wetland
5000.0
RBC
4000.0
3000.0
SBR
2000.0
MBR
1000.0
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102
reason that the advantages, disadvantages and limitations of each option had different weighting and degree of importance in each individual reuse project. For these reasons it was considered appropriate that this work should focus on the registration of the legislation, the treatment options and their costs, aiming that a review of the reuse trends will provide ideas for further advances. This study covered the fields and objectives set in the beginning of the project, regarding greywater treatment systems and costs. However, there are still many fields that could be investigated in urban water reuse networks. Some suggestions of further research are as follows: Conduct the same technical and economical research for commercial or industrial wastewater for urban reuse applications. Investigate the case of reusing reclaimed waters for indirect or even direct potable use. Research the technical and economical feasibility of other Treatment Scenarios.
Finally, the problem of adequacy, quality and management of water resources needs to be perceived from local as well as international perspectives. It is a complex issue with various social and economical dimensions and conflicting views. The issue of water intersects the relationship between society, nature and ecological balance, the relationship of production and economy, the relationship of society with political and social values, thus water is and should be considered as a collective good.
The world has enough for everyone's need, but not enough for everyone's greed.
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APPENDIX
APPENDIX A: Data of Basic Systems APPENDIX B: Data of Physical Systems APPENDIX C: Data of Chemical Systems APPENDIX D: Data of Biological Systems APPENDIX E: Data of Extensive Systems APPENDIX F: WHO Regulation - Maximum permissible concentration for chemical compounds APPENDIX G: California Title 22 - Allowable uses for Recycled water
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APPENDIX F: WHO Regulation - Maximum permissible concentration for toxic chemical compounds (WHO, 2006)
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