RULES FOR CLASSIFICATION OF

NEWBUILDINGS
SPECIAL EQUIPMENT AND SYSTEMS ADDITIONAL CLASS

6+,36

PART 6 CHAPTER 6

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JANUARY 1998

CONTENTS
Sec. 1 Sec. 2 Sec. 3 App. A

PAGE

General Requirements ................................................................................................................ 5 Arrangements for Centralised Operation and Surveillance........................................................ 6 Information System .................................................................................................................... 8 Compatibility Guide ................................................................................................................... 9

DET NORSKE VERITAS

Veritasveien 1, N-1322 Hvik, Norway Tel.: +47 67 57 99 00 Fax: +47 67 57 99 11

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The present edition of the Rules includes additions and amendments decided by the Board as of January 1998, and supersedes the January 1991 edition of the same chapter. The Rule changes come into force on 1st of July 1998. This chapter is valid until superseded by a revised chapter. Supplements will not be issued except for an updated list of minor amendments and corrections presented in the introduction booklet. The introduction booklet is normally revised in January and July each year. Revised chapters will be forwarded to all subscribers to the Rules. Buyers of reprints are advised to check the updated list of Rule chapters printed in Pt.0 Ch.1 Sec.1 to ensure that the chapter is current. eral above. The latest amendments are described under Main changes below. They are incorporated in the present version and enter into force on 1 July 2002. A complete list of the current amendments and corrections is found in Pt.0 Ch.1 Sec.3.

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6HF *HQHUDO 5HTXLUHPHQWV In item B101 further requirements have been included concerning the submission of plans and particulars.

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This chapter has been amended since its latest issue in print, see GenIn addition to the above stated rule amendments, some detected errors have been corrected, and some clarifications have been made in the existing rule wording.

Comments to the rules may be sent by e-mail to UXOHV#GQYFRP For subscription orders or information about subscription terms, please use GLVWULEXWLRQ#GQYFRP Comprehensive information about DNV and the Societys services is found at the Web site http://www.dnv.com Det Norske Veritas Computer Typesetting (FM+SGML) by Det Norske Veritas Printed in Norway by GCS AS.

If any person suffers loss or damage which is proved to have been caused by any negligent act or omission of Det Norske Veritas, then Det Norske Veritas shall pay compensation to such person for his proved direct loss or damage. However, the compensation shall not exceed an amount equal to ten times the fee charged for the service in question, provided that the maximum compensation shall never exceed USD 2 million. In this provision "Det Norske Veritas" shall mean the Foundation Det Norske Veritas as well as all its subsidiaries, directors, officers, employees, agents and any other acting on behalf of Det Norske Veritas.

Rules for Ships, January 1998 Pt.6 Ch.6 Contents Page 3

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A 100 A 200 B 100 Application........................................................................5 Class notation....................................................................5 Plans and particulars .........................................................5

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C C C C 100 200 300 400

General..............................................................................6 Alarm and remote reading ................................................6 Emergency stop/shut down arrangements ........................6 Cargo tanks secondary ullaging system............................6

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A 100 A 200 A 300 Information retrieval and presentation..............................8 Extent of information........................................................8 Verification of loading conditions. ...................................8

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A 100 A 200 B B B B Extent of remote control and surveillance ........................6 Cargo control room ...........................................................6 General ..............................................................................6 Cargo tank cleaning ..........................................................6 Cargo tank gasfreeing .......................................................6 Segregation of piping systems ..........................................6

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A 100 A 200 B 100 Definition of hazardous reaction.......................................9 Chart format ......................................................................9 Procedure. .........................................................................9

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100 200 300 400

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DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 Contents Page 4

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 Sec.1 Page 5

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$  $SSOLFDWLRQ  The Rules in this chapter apply to cargo handling systems, cargo related systems and ballast systems in the cargo area arranged for centralised operation and surveillance.  The Rules in this chapter are applicable to vessels assigned one of the following class notations: 7DQNHU IRU &KHPLFDOV 7DQNHU IRU 2LO 3URGXFWV 7DQNHU IRU 2LO $  &ODVV QRWDWLRQ  Vessels having their cargo systems and ballast systems built and equipped, surveyed and tested in accordance with the requirements of this chapter, may be given the additional class notation &&2.

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%  3ODQV DQG SDUWLFXODUV  The following plans and particulars are to be submitted for approval: arrangement of control room schematic diagrams showing arrangements for segregation of piping systems for various cargo loading and operational modes functional description of remotely controlled operations and monitoring systems operational procedures including emergency procedures description of the information systems, including user interface, logic diagrams, extent of available information, procedure for updating stored information and as applicable, interface to other instrumentation.

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 Sec.2 Page 6

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$  ([WHQW RI UHPRWH FRQWURO DQG VXUYHLOODQFH  All main operations related to cargo loading and discharging, ballasting and de-ballasting are to be arranged for centralised operation from a cargo control room. Preparatory tasks as starting machinery, connecting loading hoses, opening of cargo manifold valves may be arranged for local control only. Similarly, tasks to be carried out after loading/unloading is ended may be arranged for local control only. Table A1 lists operations required to be arranged for remote control. Other solutions will be accepted if same level of operation safety is maintained.  Indication of parameters necessary for control and supervision of cargo handling and ballasting operations is to be provided in the cargo control room. For critical parameters alarm monitoring is to be provided. $  &DUJR FRQWURO URRP  Controls and indications as given in 100 are to be located in a cargo control room fitted with air condition capable of maintaining a temperature between 20C and 30C.  The cargo control room is to be so located and arranged that direct visual surveillance of the cargo loading and discharge manifold area is possible.  Cargo control rooms located within the cargo area are to have boundaries insulated to A-60 standard. The entrance(s) is to be located and arranged with a view to safest possible escape in a case of emergency. Three sets of emergency escape masks (breathing apparatuses) and protective clothing are to be stored in the cargo control room. %  6HJUHJDWLRQ RI SLSLQJ V\VWHPV  Segregation of cargo systems required for incompatible cargoes or between cargo systems and other systems required for safety purposes is to be achieved by means of separate piping systems. For tank cleaning systems, inert gas systems and gasfreeing/dry air systems, segregations by means of portable pipe sections or short lengths of hoses may be accepted.
7DEOH $ 5HPRWHO\ FRQWUROOHG RSHUDWLRQV 2SHUDWLRQ &RPPHQWV Starting/stopping of cargo Manual start of cargo pumps in pumps and operation of case of pump room cargo system valves may be accepted Remote operation of valves Cargo manifold valves are to be manin loading/unloading system ually operable locally inde-pendent of any remote control Cargo tank washing opera- Connecting of water supply may tions be carried out locally Inerting Connecting of actual tank(s) to i.g. main may be done locally Ballasting/de-ballasting Bilge drainage for cargo pump room Fire extinguishing for cargo pump room Start of fire pump and start of cargo deck foam extinguishing system and water spray system (if provided)

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&  *HQHUDO  The Rules in Pt.4 Ch.9 apply in general. In the case of computer based systems the requirements contained in Pt.4 Ch.9 Sec.4 are to be complied with.  Means for local manual operation of valves and machinery in the event of failure of the remote control system are to be provided. &  $ODUP DQG UHPRWH UHDGLQJ  The extent of alarm and indication are to be according to Table C1 as applicable. &  (PHUJHQF\ VWRSVKXW GRZQ DUUDQJHPHQWV  Arrangement for emergency stop of cargo pumps from the cargo loading/unloading manifold area is to be fitted.  Arrangements for emergency closing of valves in the cargo loading lines are to be fitted in cargo control room and at the loading manifolds. &  &DUJR WDQNV VHFRQGDU\ XOODJLQJ V\VWHP  In addition to the remote ullaging system required by Table C1, arrangements for closed type ullaging by means of portable equipment are to be provided. At least two sets of portable ullaging equipment are to be kept onboard

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%  *HQHUDO  The Rules of Pt.5 Ch.3 and Pt.5 Ch.4 apply in general for oil carriers or chemical carriers respectively. %  &DUJR WDQN FOHDQLQJ  Tank cleaning machines are to be permanently installed.  Portable means (e.g. short hoses) for connecting individual machines to the tank washing main line may be accepted.  In the case of particular cargoes requiring extraordinary high cleanliness standards for commercial reasons, additional portable washing machines may be used. %  &DUJR WDQN JDVIUHHLQJ  A fixed cargo tank gasfreeing system is to be fitted.  Portable means for connecting the inlet to cargo tanks to the supply main, e.g. by means of short hoses, may be accepted provided such connecting may easily be performed by one person only.  For smaller vessels the use of portable ventilation fans may be accepted provided the arrangement facilitates easy and quick connecting.

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 Sec.2 Page 7

7DEOH & ([WHQW RI DODUP DQG LQGLFDWLRQ 3DUDPHWHU 5HPRWH UHDGLQJ Cargo tank level Ballast tank level Cargo temperature Cargo tank ullage pressure Cargo pressure at loading manifold Cargo pressure at pump discharge Cargo pump rpm Cargo pump housing, cargo pump shaft bearing and bulkhead shaft seal temperatures Hydraulic and pneumatic power supply Inert gas generator Tank washing medium supply pressure Valves positions Status of pumps and other machinery Oil content of wash-water discharge Bilge level in cargo pump room Explosive gas concentration in cargo pump room x x x x x x x

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&RPPHQWV For carriage of certain chemicals an additional high-high level alarm is required Only for tanks with heating or cooling systems For each segregation

x x

x x x

Not for constant speed electrically driven pumps. Alternative parameters for hydraulically driven pumps may be considered Not for submerged pumps Supply for hydraulic pump motors, cargo line stripping, valve operation etc. Monitoring as required by Pt.5 Ch.3 Sec.11

x Open/shut indications Running/stop indications x x x Automatic changeover to recirculation

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 Sec.3 Page 8

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$  ,QIRUPDWLRQ UHWULHYDO DQG SUHVHQWDWLRQ  An information system is to be provided which will enable the operation to easily retrieve and display all information needed for observing limitations and operational requirements set forth by rules and regulations for particular cargo operations. $  ([WHQW RI LQIRUPDWLRQ  The information system is to contain the following information as applicable: physical data of the product. pollution categorization of the product. toxicity information. carriage requirements and limitations stipulated by certificate. special operational requirements mandatory for particular cargoes. mandatory tank washing procedures, general procedures (e.g. cow or prewash for category A chemicals) and specific procedures for particular products. cargo tank and cargo lines' stripping procedures. cargo heating requirements/limitations. sischarge procedures for cargo tank washwater. ship and cargo tank certification data. Cargo tank coating compatibility guide. Recommended tank washing procedures for particular products. Synonym names/trade names' interpreter. Rules, regulations and industry standards' references for particular products. $  9HULILFDWLRQ RI ORDGLQJ FRQGLWLRQV  The information system is to enable easy checking of any loading condition and combination of products loaded or planned to be loaded with respect to strength of hull and cargo tanks and to present actual cargo tank filling limits (if any).  The information system is to enable easy checking of any planned loading for compatibility requirements and to provide information of any required piping segregations to be executed.  The information system is to enable easy checking of any planned loading conditions against applicable damage stability requirements (MARPOL Annex I and IBC- Code).
*XLGDQFH QRWH a) b) Appendix A contains compatibility guidelines for groups of products. It is anticipated that a computer installation will be necessary for fulfilling required functions of the information system in the case of the most sophisticated tankers (parcel chemical tankers and multi purpose product oil tankers). For simpler single grade cargo tankers other solutions may suffice.
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 It is recommended that information additional to that listed in 201, which may assist the operator in performing the actual operations in an efficient and correct manner be included. E.g. information such as:

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 9

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$  'HILQLWLRQ RI KD]DUGRXV UHDFWLRQ  As a first approximation, a mixture of two cargoes is considered hazardous when, under specified condition, the temperature rise of the mixture exceeds 25C or a gas is evolved. It is possible for the reaction of two cargoes to produce a product that is significantly more flammable or toxic than the original cargoes even though the reaction is non-hazardous from temperature or pressure considerations, although no examples of such a reaction are known at this time. $  &KDUW IRUPDW  There are different degrees of reactivity among the various cargoes. Many of them are relatively non-reactive: for example, aromatic hydrocarbons or paraffins. Others will form hazardous combinations with many groups: for example, the in-organic acids. The cargo groups in the compatibility chart (see fig. 1) are separated into two categories: 1 through 22 are Reactive Groups and 30 through 43 are Cargo Groups. Left unassigned and available for future expansion are groups 23 through 29 and those past 43. Reactive Groups contain products which are chemically the most reactive; dangerous combinations may result between members of different Reactive Groups and between members of Reactive Groups and Cargo Groups. Products assigned to Cargo Groups, however, are much less reactive; dangerous combinations involving these can be formed only with members of certain Reactive Groups. Cargo Groups do not react hazardously with one another.

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%  3URFHGXUH  The following procedure explains how the compatibility chart should be used to find compatibility information: 1) Determine the group numbers of the two cargoes by referring to the alphabetical listing of cargoes and the corresponding groups (Table I). Many cargoes are listed under their parent names; unless otherwise indicated, isomers or mixtures of isomers of a particular cargo are assigned to the same group. For example, to find the group number for Isobutyl Alcohol, look under the parent name Butyl Alcohol. Similarly, the group number for para-Xylene is found under the entry Xylene. 2) If both group numbers are between 30 and 43 inclusive, the products are compatible and the chart need not be used. 3) If both group numbers do not fall between 30 and 43 inclusive, locate one of the numbers on the left of the chart (Cargo Groups) and the other across the top (Reactive Groups). (Note that if a group number is between 30 and 43, it can only be found on the left side of the chart.) The box formed by the intersection of the column and row containing the two numbers will contain one of the following: i) blankThe two cargoes are compatible. ii) XThe two cargoes are not compatible. iii) a letter other than XReactivity varies among the group members. Refer to the footnotes following the chart to find whether the products in question are included in the footnotes. Unless the combination is specifically mentioned in these footnotes, it is compatible.

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 10

)LJXUH  &RPSDWLELOLW\ &KDUW 5($&7,9( *52836 1. Non-oxidizing mineral acids

5($&7,9( *52836 1. Non-oxidizing mineral acids 2. Sulfuric acid 3. Nitric acid 4. Organic acids 5. Caustics 6. Ammonia 7. Aliphatic amines 8. Alkanolamines 9. Aromatic amines 10. Amides 11. Organic anhydrides 12. Isocyanates 13. Vinyl acetate 14. Acrylates 15. Substituted allyls 16. Alkylene oxides 17. Epichlorohydrin 18. Ketones 19. Aldehydes 20. Alcohols, glycols 21. Phenols, cresols 22. Caprolactam solution &$5*2 *52836 30. Olefins 31. Paraffins 32. Aromatic hydrocarbons 33. Misclaneousl. hydrocarbon mixtures 34. Esters 35. Vinyl halides 36. Halogenated hydrocarbons 37. Nitriles 38. Carbon disulfide 39. Sulfolane 40. Glycol ethers 41. Ethers

x x x x x x x x x x x x x x x x x x x x x x x x x

x x x x

x x x x

x x x x

x x x x

x x x C

x x x

x x x x x x x x

x x x x x x x x x

x x A E

x x x x x x x x x x x x x x x x x

x x x x C x x x x x x x x x x x x x x x x x x x x x x x x x B x x x

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22. Caprolactam solution x x x x 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 30 31 32 33 x 34 35 36 37 38 39 40 41

11. Organic anhydrides

20. Alcohols, glycols x

15. Substituted allyls

9. Aromatic amines

7. Aliphatic amines

17. Epichlorohydrin

16. Alkylene oxides

x B

x x

x x x x x x

x x x

x x x x

x x x

x x H I x x x x

x x

DET NORSKE VERITAS

21. Phenols, cresols x x x x x

8. Alkanolamines

13. Vinyl acetate

4. Organic acids

2. Sulfuric acid

12. Isocyanates

19. Aldehydes

3. Nitric acid

14. Acrylates

6. Ammonia

18. Ketones

5. Caustics

10. Amides

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 11

)LJXUH  &RPSDWLELOLW\ &KDUW &RQWLQXHG 5($&7,9( *52836 1. Non-oxidizing mineral acids

42. Nitrocompounds 43. Miscellaneous water solutions 1

x B Incompatible groups.

x x 2 3 4 5

x 6

x 7

x 8

42 x 43 9 10 11 12 13 14 15 16 17 18 19 20 21 22

A Acrolein (19), Crotonaldehyde (19), and 2-Ethyl-3-propyl acrolein (19) are not compatible with Group 1, Non-Oxidizing Mineral Acids. Isophorone (18), and Mesityl Oxide (18) are not compatible with Group 8, Alkanolamines. C Acrylic Acid (4) is not compatible with Group 9, Aromatic Amines. D Allyl Alcohol (15) is not compatible with Group 12, Isocyanates. E F Furfuryl Alcohol (20) is not compatible with Group 1, Non-oxidizing Mineral Acids. Furfuryl Alcohol (20) is not compatible with Formic acid.

G (Reserved) H Trichloroethylene (36) is not compatible with Group 5, Caustics. I Ethylenediamine (7) is not compatible with Ethylene Dichloride (36).

DET NORSKE VERITAS

22. Caprolactam solution

11. Organic anhydrides

20. Alcohols, glycols

15. Substituted allyls

9. Aromatic amines

17. Epichlorohydrin

7. Aliphatic amines

16. Alkylene oxides

21. Phenols, cresols

8. Alkanolamines

13. Vinyl acetate

4. Organic acids

2. Sulfuric acid

12. Isocyanates

19. Aldehydes

3. Nitric acid

14. Acrylates

6. Ammonia

18. Ketones

5. Caustics

10. Amides

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 12

In the accompanying Table I an alphabetic list of cargoes with reference to groups is provided. In Table II a list of cargoes within each group is given. 7$%/(   $/3+$%(7,&$/ /,67 2) &$5*2(6 (See footnote at the end of the table)
1DPH Acetaldehyde Acetic Acid Acetic Anhydride Acetone Acetonitrile Acetophenone Acetyl Tibutyl Citrate Acrolein (inhibited) Acrylamid Solution Acrylic Acid (inhibited) Acrylonitrile (inhibited) Adiponitrile Alcohols (Mixed) Alkyl Phthalates (n-) Allyl Alcohol Allyl Chloride (2-Aminoethoxy) Ethanol, 2Aminoethylethanolamine Ammonia, Anhydrous Ammonium Hydroxide (28% or less) Ammonium Nitrate, Urea, Water Solutions (containing Ammonia) Ammonium Nitrate, Urea, Water Solutions (not containing Ammonia) Ammonium Polyphosphate Ammonium Sulfate Solution (20% or less) Amyl Acetate Amyl Alcohol Amyl Tallate Aniline Asphalt Asphalt Blending Stocks: Roofers Flux Straight Run Residue Behenyl Alcohol Benzene Benzene, Toluene Xylene (crude) Butadiene (inhibited) Butane Butene Butyl Acrylate (inhibited) Butyl Acetate Butyl Alcohol Butylamine Butyl Benzyl Phthalate Butylene 1,3-Butylene Glycol Butylene Oxide Butyl Ether Butyl Heptyl Ketone (iso-) Butyl Methacrylate, Decyl Methacrylate, Cetyl Eicosyl Methacrylate Mixture Butyl Methacrylate (inhibited) Butyraldehyde *URXS 1R 19 4 11 18 37 18 34 19 10 4 15 37 20 34 15 15 8 8 6 6 6 43 43 43 34 20 34 9 33 33 33 20 33 32 30 31 30 14 34 20 7 34 30 20 16 41 18 14 14 19

1DPH Butyric Acid Calcium Bromide Solution Calcium Chloride Solutions Camphor Oil (light) Caprolactam Solution Carbolic Oil Carbon Black Base Carbon Disulfide Carbon Tetrachloride Cashew Nut Shell Oil (untreated) Caustic Potash Solution Caustic Soda Solution Chlorine Chlorobenzene Chloroform Chloronitrobenzene, 2-See Nitrochlorobenzene, ortho- Chlorotoluene (m-, o-, p-) Chlorosulphonic Acid Choline Chloride Solutions Corn Syrup Creosote, Coal Tar Cresols Cresylate Spent Caustic Solution Cresylic Acid Crotonaldehyde Cumene Cycloaliphatic Resins Cyclohexane Cyclohexanol Cyclohexanone Cyclohexylamine Cyclopentadiene Polymers Cyclopentadiene, Styrene, Benzene Mixture Cymene Decaldehyde Decane Decene Decyl Alcohol Decyl Acrylate (inhibited) Decylbenzene Dextrose Solution Diacetone Alcohol Diammonium Salt of Zinc Ethylene Diamine Tetracetic Acid Solution Dibutylamine Dibutyl Phthalate Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane Dichloroethyl Ether Dichloroisopropyl Ether Dichloromethane Dichlorophenol, 2,41,1-Dichloropropane 1,2-Dichloropropane Dichloropropane/ 1,3-Dichloropropene Mixture 1,3-Dichloropropene Dichloropropionic Acid, 2,2Dicyclopentadine Diethanolamine

*URXS 1R 4 43 43 18 22 21 33 38 36 4 5 5
(1)

36 36 36
(1)

20 43 21 21 5 21 19 32 31 31 20 18 7 7 30 32 19 31 30 20 14 32 43 20 43 7 34 36 36 36 41 36 36 21 36 36 15 15 4 30 8

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 13

1DPH Diethylamine Diethylbenzene Diethylene Glycol Diethylene Glycol Monobutyl Ether Diethylene Glycol Monobutyl Ether Acetate Diethylene Glycol Monoethyl Ether Diethylene Glycol Monomethyl Ether Diethylene Glycol Monophenyl Ether Diethylenetriamine Diethylethanolamine Diethyl Sulfate Diglycidyl Ether of Bisphenol A Diheptyl Phthalate Diisobutylene Diisobutyl Carbinol Diisobutyl Ketone Diisodecyl Phthalate Diisononyl Phthalate Diisooctyl Phthalate Diisopropanolamine Diisopropylamine Diisopropyl Benzene Diisopropyl Naphthalene Dimethyl Acetamide Dimethylamine Dimethylcyclohexylamine Dimethylethanolamine Dimethylformamide Dimethyloctanoic Acid, 2,2Dimethyl Phthalate Dimethyl Polysiloxane Dimethylpropane-1.3-Diol, 2,2Dinonyl Phthalate Dioctyl Phthalate 1,4-Dioxane Dipentene Dipropylamine Dipropylene Glycol Dibenzoate Diphenyl-Diphenyl Oxide Diphenylmethane Diisocyanate Di-n-propylamine Dipropylene Glycol Distillates: Straight Run Flashed Feed Stocks Diundecyl Phthalate Dodecane Dodecanol Dodecene Dodecylamine, Tetradsecylamine Mixture Dodecylbenzene Dodecyl Diphenyl Oxide Disulphonate Solution Dodecyl Pentadecyl Methacrylate Epichlorohydrin Epoxy Resin Ethane Ethanolamine Ethoxylated Alcohols C11-C15 Ethoxy Triglycol

*URXS 1R 7 32 40 40 34 40 40 40 7 8 34 41 34 30 20 18 34 34 34 8 7 32 32 10 7 7 8 10 4 34 34 20 34 34 41 30 7 34 33 12 7 40 33 33 34 31 20 30 7 32 43 14 17 18 31 8 20 40

1DPH Ethyl Acetate Ethyl Alcohol Ethyl Acrylate (inhibited) Ethylamine Ethyl Benzene Ethyl Butanol Ethylbutylamine(n-) Ethyl Chloride Ethylene Ethylene Chlorohydrin Ethylene Cyanohydrin Ethylenediamine Ethylene Dibromide Ethylene Dichloride Ethylene Glycol Ethylene Glycol Monobutyl Ether Ethylene Glycol Monobutyl Ether Acetate Ethylene Glycol Monoethyl Ether Ethylene Glycol Monoethyl Ether Acetate Ethylene Glycol Monoisopropyl Ether Ethylene Glycol Monomethyl Ether Ethylene Glycol Phenyl Ether Ethylene Oxide Ethyl Ether Ethylhexaldehyde 2-Ethyl Hexanol Ethylhexoic Acid, 22-Ethylhexyl Acrylate (inhibited) Ethyl Hexylamine Ethyl Hexyl Tallate Ethylidene Norbornene Ethyl Methacrylate (inhibited) Ethyl-6-Methyl-n-(1-Methyl-2-Methoxy Ethyl) Aniline,22-Ethyl-3-Propyl Acrolein Fatty Acid Amides Formaldehyde, Methanol Mixtures Formaldehyde Solution (37-50%) Formic Acid Furfural Furfuryl Alcohol Gas Oil: Cracked Gasoline Blending Stocks: Alkylates Reformates Gasolines: Casing head (natural) Automotive (containing over 4.23 grams lead per gallon) Aviation (containing not over 4.86 grams lead per gallon) Polymer Straight Run Glutaraldehyde Solution Glycerine Glyceryl Triacetate Glycidyl Ester of Versatic Acid Glycol Diacetate Glycols, Resins, and Solvents Mixture Glyoxal Solution

*URXS 1R 34 20 14 7 32 20 7 36 30 20 20 7 36 36 20 40 34 40 34 40 40 40
(1)

41 19 20 4 14 7 34 30 14 9 19 33 19 19 4 19 20 33 33 33 33 33 33 33 33 19 34 34 34 34 33 19

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 14

1DPH Heptane Heptanoic Acid(n-) Heptene, 1 Herbicide (C12H22NO2Cl) Hexamethyleneimine Hexane Hexanol Hexene Hexylene Glycol Hydrochloric Acid Hydrofluoric Acid Hydrofluorosilicic Acid Isophorone Isoprene (inhibited) Jet Fuels: JP-1 (Kerosene) JP-3 JP-4 JP-5 (Kerosene, Heavy) Kaolin Clay Slurry Kerosene Latex, Liquid Synthetic Lignin Liquor (Calcium Ligno-Sulphonate, Water Solution) Magnesium Nonyl Phenol Sulfide Maleic Anhydride Maleic Anhydride Copolymer Mesityl Oxide Methacrylic Acid Methane Methoxy Triglycol Methyl Acetate Methyl Acetoacetate Methyl Acetylene, Propadiene Mixture (Stabilized) Methyl Acrylate (inhibited) Methyl Alcohol Methylamine Methylamine Solutions Methyl Amyl Acetate Methyl Amyl Alcohol Methyl Bromide 3-Methyl Butyraldehyde Methyl Chloride Methyl-6-Ethyl Aniline, 2Methyl Ethyl Ketone 2-Methyl-5-Ethyl Pyridine Methyl Formal (Dimethyl Formal) Methyl Heptyl Ketone Methyl-2-Hydroxy-3-Butyne, 2Methyl iso-Amyl Ketone Methyl Isobutyl Ketone Methyl Isobutyl Carbinol Methyl Methacrylate (inhibited) Methyl Naphthalene Methylolureas (20% Free Formaldehyde) Methyl Pyridine,2 Methyl Pyridine,3 Methyl Pyrrolidone (N-) (alpha-) Methyl Styrene (inhibited)

*URXS 1R 31 4 30 33 7 31 20 30 20 1 1 1 18 30 33 33 33 33 43 33 43 43 33 11 33 18 4 31 40 34 34 30 14 20 7 7 34 20 36 19 36 9 18 9 41 18 20 18 18 20 14 32 19 9 9 9 30

1DPH Methyl tert-Butyl Ether Mineral Spirits Molasses Monochlorodifluoromethane Morpholine Motor Fuel Antiknock Compounds Containing Lead Alkyls Naphtha: Coal Tar Cracking Fraction Solvent Stoddard Solvent Varnish Markers and Painters (75%) Naphthalene (molten) Naphthenic Acid NHric Acid (70% or less) Nitric Acid (95%) Nitrobenzene Nitrochlorobenzene, ortho1- or 2-Nitropropane Nitrotoluene Nonane Nonene Nonyl Alcohol Nonyl Phenol Nonyl Phenol (ethyoxylated) Nonyl Phenol Sulfide Octadecene-1 Octadecenoamide (Oleamide) Octane Octene Octyl Alcohol Octyl Aldehyde Octyl Epoxytallate Oils: Aliphatic Clarified Coal Oil Crude Oil Diesel Oil Oiticica Residual Road Seal Soapstock Transformer Tung White (Mineral)

*URXS 1R 41 33 20 36 7
(1)

33 33 33 33 33 32 4 3
(1)

42 42 42 42 31 30 20 21 40 33 30 10 31 30 20 19 34 33 33 33 33 33 34 33 33 34 34 33 34 33

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 15

1DPH Edible Oils, including: Babassu Castor Coconut Coconut, Methyl Ester Corn Cotton Seed Cotton Seed Fatty Acid Fish Lard Olive Palm Peanut Rapeseed Rice Bran Safflower Soya Bean Soybean, Epoxidized Sunflower Seed Tucum Vegetable Fuel Oils: No. 1 (Kerosene) No. 1-D No. 2 No. 4 No. 2-D No. 5 No. 6 Miscellaneous Oils, including: Absorption Aromatic Coal Tar Heartcut Distillate Linseed Lubricating Mineral Mineral Seal Motor Neatsfoot Penetrating Range Resin Resinous Petroleum Rosin Sperm Spindle Spray Tall Tanners Turbine Oleic Acid Oleum Pentadecanol Pentadiene, 1,3Pentane Pentene Pentenenitrile (crude), 3Pentyl Aldehyde Perchloroethylene Petrolatum Petroleum Naphtha Phenol Pentachloroethane Phosphoric Acid Phosphorus Phthalic Anhydride (molten) Pinene Polybutene

*URXS 1R 34 34 34 34 34 34 34 34 34 34 34 34 34 34 34 34 40 34 34 34 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 34 33 33 4
(1)

20 30 31 30 37 19 36 33 33 21 36 1
(1)

11 30 30

1DPH Polyethylene Glycols Polyethylene Polyamines Polymethylene Polyphenyl isocyanate Polypropylene Polypropylene Glycol Methyl Ether Polypropylene Glycols Polyvinylbenzyltrimethyl Ammonium Chloride Solution Propane Propanolamine Propionaldehyde Propionic Acid Propionic Anhydride Propionitrile Propyl Acetate Propyl Alcohol Propylamine Propylene Propylene Butylene Polymer Propylene Glycol Propylene Oxide Propylene Tetramer Propyl Ether Pseudocumene (1,2,4-Trimethylbenzene) Pyridine Rum Sewap Sludge Sodium Borohydride Solution (15% or less) / Sodium Hydroxide Solution Sodium Carbonate Solutions Sodium Cyanide Solution (30% or less) Sodium Dimethyl Naphthalene Sulphonate, Aq. Solution Sodium Hydrosulfide Solution (45% or less) Sodium Hypochlorite Solution (15% or less) Sodium Polyacrylate Solution Sodium Silicate Solution Sorbitol Stearic Acid Styrene (inhibited) Sulpholane Sulfur (molten) Sulfuric Acid Sulfuric Acid, Spent Tall Oil, Fatty Acid Tallow Tallow Fatty Acid Tallow Fatty Alcohol Tallow Nitrile 1,1,2,2-Tetrachloroethane Tetradecanol Tetradecene Tetradecylbenzene Tetraethylene Glycol Tetraethylenepentamine Tetrahydrofuran Tetrahydronaphthalene Tetrasodium Salt of EDTA Solution Toluene Toluenediamine

*URXS 1R 40 7 12 30 40 40 43 31 8 19 4 11 37 34 20 7 30 30 20 16 30 41 32 9 20 43 5 5 5 34 5 5 43 43 20 4 30 39
(1)

2 2 34 34 34 20 37 36 20 30 32 40 7 41 32 43 32 9

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 16

1DPH Toluene Diisocyanate Toluidine (ortho-) Triarylphosphate Tributyl Phosphate 1,2,4-Trichlorobenzene Trichloroethane, 1,1,1Trichloroethylene Trichloro-1 -2-2-Trifluoroethane, 1,1,2Tridecane Tridecanol Tridecene Tridecylbenzene Triethanolamine Triethylamine Triethyl Benzene Triethylene Glycol Triethylene Glycol Butyl Ether Mixture Triethylene Glycol Ether Mixture Triethylenetetramine Triethyl Phosphate Triisooctyl Trimellitate Trimethyl Benzene, 1,2,4 Trimethyl Pentanediol-1-3-Diisobutyrate, 2,2,4Trimethyl-3-Pentanol-1-isobutyrate, 2,2,4Tripropylene Tripropylene Glycol Turpentine Undecanol Undecene Undecylbenzene Valeraldehyde Vinyl Acetate (inhibited) Vinyl Acetate, Fumarate Copolymer Vinyl Chloride (inhibited) Vinyl Neodecanate Vinylidene Chloride (inhibited) Vinyl Toluene (inhibited) Xylene Zinc Bromide, Calcium Bromide Solution

*URXS 1R 12 9 34 34 36 36 36 36 34 20 30 32 8 7 32 40 40 40 7 34 34 32 34 34 30 40 30 20 30 32 19 13 34 35 13 35 30 32 43

Acetic Acid Acrylic Acid (inhibited) Butyric Acid Cashew Nut Shell Oil (untreated) Dichloropropionic Acid, 2,2Dimethyloctanoic Acid, 2,2Ethylhexoic Acid, 2Formic Acid Heptanoic Acid (n-) Methacrylic Acid Naphthenic Acid Oleic Acid Propionic Acid Stearic Acid 5. &DXVWLFV Caustic Potash Solution Caustic Soda Solution Cresylate Spent Caustic Solution Sodium Borohydride Solution ( 15% or less) Sodium Hydroxide Solution Sodium Carbonate Solutions Sodium Cyanide Solution (30% or less) Sodium Hydrosulfide Solution (45% or less) Sodium Hypochlorite Solution (15% or less) $PPRQLD Ammonia, Anhydrous Ammonium Hydroxide (28% or less) Ammonium Nitrate, Urea, Water Solutions (containing Ammonia) $OLSKDWLF $PLQHV Butylamine Cyclohexylamine Dibutylamine Diethylamine Diethylenetriamine Diisopropylamine Dimethylamine Dimethylcyclohexylamine Di-n-propylamine Dipropylamine Dodecylamine, Tetradecylamine Mixture Ethylamine Ethylbutylamine (n-) Ethylenediamine Ethyl Hexylamine Hexamethyleneimine Methylamine Methylamine Solutions Morpholine Polyethylene Polyamines Propylamine

6.

7.

Footnote to Table I: 1) Because of very high reactivity or unusual conditions of carriage, this product is not included in the Compatibility Chart.

TABLE II GROUPINGS OF CARGOES 1. 1RQ2[LGL]LQJ 0LQHUDO $FLGV Hydrochloric Acid Hydrofluoric Acid Hydrofluorosilicic Acid Phosphoric Acid 6XOIXULF $FLGV Spent Sulfuric Acid Sulfuric Acid (98% or less) 1LWULF $FLG Nitric Acid (70% or less) 2UJDQLF $FLGV

2.

3.

4.

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 17

Tetraethylenepentamine Triethylamine Triethylenetetramine 8. $ONDQRODPLQHV (2-Aminoethoxy) Ethanol, 2Aminoethylethanolamine Diethanolamine Diethylethanolamine Diisopropanolamine Dimethylethanolamine Ethanolamine Propanolamine Triethanolamine $URPDWLF $PLQHV Aniline Ethyl-6-Methyl-n-(1-Methyl-2-Methoxy Ethyl) Aniline, 2Methyl-6-Ethyl Aniline, 2Methyl Pyridine, 2 Methyl Pyridine, 3 Methyl Pyrrolidone (N-) Pyridine 2-Methyl-5-Ethylpyridine Toluenediamine Toluidine (ortho-) $PLGHV Acrylamide Solution Dimethyl Acetamide Dimethylformamide Octadecenoamide (Oleamide) 2UJDQLF $QK\GULGHV Acetic Anhydride Maleic Anhydride Phthalic Anhydride Propionic Anhydride ,VRF\DQDWHV Diphenylmethane Diisocyanate Polyphenyl Polymethyleneisocyanate Toluene Diisocyanate 9LQ\O $FHWDWH Vinyl Acetate (inhibited) Vinyl Neodecanate $FU\ODWHV Butyl Acrylate (inhibited) Butyl Methacrylate, Decyl Methacrylate, Cetyl Eicosyl Methacrylate Mixture Butyl Methacrylate (inhibited) Decyl Acrylate (inhibited) Dodecyl Pentadecyl Methacrylate 19.

Ethyl Acrylate (inhibited) 2-Ethylhexyl Acrylate (inhibited) Ethyl Methacrylate (inhibited) Methyl Acrylate (inhibited) Methyl Methacrylate (inhibited) 15. 6XEVWLWXWHG $OO\OV Acrylonitrile (inhibited) Allyl Alcohol Allyl Chloride Dichloropropane/ 1,3-Dichloropropene Mixture 1,3-Dichloropropene $ON\OHQH 2[LGHV Propylene Oxide Butylene Oxide (SLFKORURK\GULQ Epichlorohydrin .HWRQHV Acetone Acetophenone Butyl Heptyl Ketone (iso-) Camphor Oil Cyclohexanone Diisobutyl Ketone Epoxy Resin Isophorone Mesityl Oxide Methyl iso-Amyl Ketone Methyl Ethyl Ketone Methyl Heptyl Ketone Methyl Isobutyl Ketone $OGHK\GHV Acetaldehyde Acrolein (inhibited) Butyraldehyde Crotonaldehyde Decaldhyde Ethylhexaldehyde 2-Ethyl-3-Propyl Acrolein Formaldehyde Formaldehyde, Methanol Mixtures Furfural Glutaraldehyde Solution Glyoxal SollltioIl Methylbutyraldehyde Methylorlureas (20% free Formaldehyde) Octyl Aldehyde Pentyl Aldehyde Propionaldehyde Valeraldehyde

16.

9.

17.

18.

10.

11.

12.

13.

14.

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 18

20.

$OFRKROV *O\FROV Alcohol Diisobutyl Carbinol Alcohols (Mixed) Behenyl Alcohol Amyl Alcohol Butyl Alcohol 1,3-Butylene Glycol Choline Chloride Solutions Cyclohexanol Decyl Alcohol Diacetone Dimethylpropane-1-3-Diol, 2,2Dodecanol Ethanol Ethoxylated Alcohols C11-C15 Ethyl Alcohol Ethylbutanol Ethylene Chlorohydrin Ethylene Cyanohydrin Ethylene Glycol 2-Ethyl Hexanol Furfuryl Alcohol Glycerin Hexanol Hexylene Glycol Methanol Methyl Alcohol Methylamyl Alcohol Methyl-2-Hydroxy-3-Butyne, 2Methylisobutyl Carbinol Octyl Alcohol Nonyl Alcohol Pentadecanol Propyl Alcohol Propylene Glycol Sorbitol Tallow Fatty Alcohol Tetradecanol Tridecanol Undecanol 3KHQROV DQG &UHVROV Carbolic Oil Creosote, Coal Tar Cresols Cresylic Acid Dichlorophenol, 2,4Nonyl Phenol Phenol &DSURODFWDP 6ROXWLRQ Caprolactam Solution

30.

2OHILQV Butadiene (inhibited) Butene Butylene Cyclopentadiene Polymers Cyclopentadiene, Styrene, Benzene Mixture Decene Dicyclopentadiene Diisobutylene Dipentene Dodecene Ethylene Ethylidene Norbornene Heptene, 1Hexene Isoprene (inhibited) Methyl Acetylene, Propadiene Mixture (stabilized) (alpha-) Methyl Styrene (inhibited) Nonene Octadecene-1 Octene Pentadiene, 1,3Pentene Pinene Polybutene Polypropylene Propylene Propylene Butylene Polymer Propylene Tetramer Styrene (inhibited) Vinyl Toluene (inhibited) Tetradecene Tridecene Tripropylene Turpentine Undecene 3DUDIILQV Butane Cycloaliphatic Resins Cyclohexane Decane Dodecane Ethane Heptane Hexane Methane Nonane Octane Pentane Propane

31.

21.

22.

23-29. 8QDVVLJQHG

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 19

32.

$URPDWLF +\GURFDUERQV Benzene Benzene, Toluene, Xylene (crude) Cumene Cymene Decylbenzene Diethylbenzene Diisopropyl Benzene Diisopropyl Naphthalene Dodecylbenzene Ethylbenzene Methyl Naphthalene Naphthalene Pseudocumene (1,2,4-Trimethylbenzene) Tetradecylbenzene Tetrahydronaphthalene Toluene Tridecylbenzene Triethylbenzene Trimethyl Benzene, 1,2,4Undecylbenzene Xylene 0LVF +\GURFDUERQ 0L[WXUHV Asphalt Asphalt Blending Stocks Carbon Black Base Diphenyl-Diphenyl Oxide Distillates Fatty Acid Amides Gas Oil, Cracked Gasoline Blending Stocks Gasolines Glycols, Resins, and Solvents Mixture Herbicide (C15H22NO2Cl) Jet Fuels Kerosene Magnesium Nonyl Phenol Sulfide Maleic Anhydride Copolymer Mineral Spirits Naphtha Naphtha, Cracking Fraction Naphtha, Varnish Makers and Painters (75%) Nonyl Phenol Sulfide Oils, Aliphatic Oils, Clarified Oils, Coal Oils, Crude Oils, Diesel Oils, Fuel (No. 1 through No. 6) Oils, Miscellaneous Oils, Residual

Oils, Road Oils, Transformer Oils, White (Mineral) Petrolatum Petroleum Naphtha 34. (VWHUV Acetyl Tributyl Citrate Alkyl Phthalates (n-) Amyl Acetate Amyl Tallate Butyl Acetate Butyl Benzyl Phthalate Castor Oil Coconut Oil Cottonseed Oil Dibutyl Phthalate Diethylene Glycol Monobutyl Ether Acetate Diethyl Sulfate Diheptyl Phthalate Diisodecyl Phthalate Diisononyl Phthalate Diisooctyl Phthalate Dimethyl Phthalate Dimethyl Polysiloxane Dinonyl Phthalate Dioctyl Phthalate Dipropylene Glycol Dibenzoate Diundecyl Phthalate Ethyl Acetate Ethylene Glycol Monobutyl Ether Acetate Ethylene Glycol Monoethyl Ether Acetate Ethylhexyl Tallate Fish Oil Glyceryl Triacetate Glycidyl Ester of Varsatic Acid Glycol Diacetate Lard Methyl Acetate Methyl Acetoacetate Methyl Amyl Acetate Octyl Epoxy Tallate Oils, Edible, Babassu Oils, Edible, Coconut, Methyl Ester Oils, Edible Corn Oils, Edible Cotton Seed Fatty Acid Oils, Edible, Rapeseed Oils, Edible, Rice Bran Oils, Edible, Sunflower Seed Oils Oiticica Oils Seal Oils, Soapstock

33.

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 20

Oils, Tung Olive Oil Palm Oil Peanut Oil Propyl Acetate Safflower Oil Sodium Dimethyl Naphthalene Sulphonate, Aq. Solution Soybean Oil Tall Oil, Fatty Acid Tallow Tallow Fatty Acid Triarylphosphate Tributyl Phosphate Tridecane Triethyl Phosphate Triisooctyl Trimellitate Trimethyl Pentanediol-1-3-Diisobutyrate, 2,2,4Trimethyl-3-Pertanol-1-Isobutyrate, 2,2.4Tucum Oil Vegetable Oil Vinyl Acetate, Fumarate Copolymer 35. 9LQ\O +DOLGHV Vinyl Chloride (inhibited) Vinylidene Chloride (inhibited ) +DORJHQDWHG +\GURFDUERQV Carbon Tetrachloride Chlorobenzene Chlorodifluoromethane (mono-) Chloroform Chlorotoluene (m-, o-, p-) Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane Dichloroisopropyl Ether Dichloromethane 1,1-Dichloropropane 1,2-Dichloropropane Ethyl Chloride Ethylene Dibromide Ethylene Dichloride Methyl Bromide Methyl Chloride Pentachloroethane Perchloroethylene 1,1,2,2-Tetrachloroethane 1,2,4-Trichlorobenzene Trichloroethane, 1,1,1Trichloroethylene Trichloro-1-2-2-Trifluoroethane, 1,1,21LWULOHV

Acetonitrile Adiponitrile Pentenenitrile (crude), 3Propionitrile Tallow Nitrile 38. 39. 40. &DUERQ 'LVXOILGH 6XOSKRODQH *O\FRO (WKHUV Diethylene Glycol Diethylene Glycol Monobutyl Ether Diethylene Glycol Monoethyl Ether Diethylene Glycol Monomethyl Ether Diethylene GlYcol Monophenyl Ether Dipropylene Glycol Ethoxy Triglycol Ethylene Glycol Monobutyl Ether Ethylene Glycol Monoethyl Ether Ethylene Glycol Monoisopropyl Ether Ethylene Glycol Monomethyl Ether Ethylene Glycol Phenyl Ether Methoxy Triglycol Nonylphenol, Ethoxylated Oils, Edible, Soybean (epoxidized) Polyethylene Glycols Polypropylene Glycols Polypropylene Glycol Methyl Ether Soybean Oil, Epoxidized Tetraethylene Glycol Triethylene Glycol Triethylene Glycol Butyl Ether Mixture Triethylene Glycol Ether Mixture Tripropylene Glycol (WKHUV Butyl Ether Dichloroethylether Diglycidyl Ether of Bisphenol A 1,4-Dioxane Ethyl Ether Methyl Formal (Dimethyl Formal) Methyl tert-Butyl Ether Propyl Ether Tetrahydrofuran 1LWURFRPSRXQGV (mono-) Nitrobenzene Nitrochlorobenzene, ortho1- or 2-Nitropropane Nitrotoluene 0LVFHOODQHRXV :DWHU 6ROXWLRQV Ammonium Nitrate. Urea, Water Solu-

36.

41.

42.

43.

37.

DET NORSKE VERITAS

Rules for Ships, January 1998 Pt.6 Ch.6 App.A Page 21

tions (not containing Ammonia) Ammonium Polyphosphate Ammonium Sulfate Solution (20% or less) Calcium Bromide Solution Calcium Chloride Solutions Corn Syrup Dextrose Solution Diammonium Salt of Zinc Ethylene Diamine Tetraacetic Acid Solution Dodecyl Diphenyl Oxide Disulphonate Solution Kaolin Clay Slurry Latex Solutions Lignin Liquor (Calcium Ligno-Sulphonate, Water Solution)
0HPEHU RI UHDFWLYH JURXS Caustic soda 50% or less

Polyvinylbenzyltrimethyl Ammonium Chloride Solution Sewage Sludge Sodium Polyacrylate Solution Sodium Silicate Solution Tetrasodium Salt of EDTA Solution Zinc Bromide, Calcium Bromide Solution ([FHSWLRQV WR WKH FKDUW The binary combinations listed below have been tested and found not to be dangerously reactive. These combinations are exceptions to the Compatibility Chart (Figure 1) and may be stowed in adjacent tanks.

Ethylene Diamine

Sulfuric Acid, 98% or less Acrylonitrite Dodecyl and Tetradecylamine mixture

&RPSDWLEOH ZLWK Butyl Alcohol Diacetone Alcohol Diethylene Glycol Diethylene Glycol, Ethylene Glycol mixture Ethylene Glycol (pure) Ethyl Alcohol Ethyl Hexanol (Octyl Alcohol) Methyl Alcohol Propyl Alcohol Propyl Alcohol, Water mixture Propylene Glycol. Ethyl Hexanol Isophorone Propyl Alcohol Creosole Propylene Glycol Methyl Ethyl Ketone Choice White Grease Triethanolamine Tall Oil Fatty Acid

DET NORSKE VERITAS