rite the half-cell reaction for the following cells:

3+,
.:
, Ti
4+
II Fe Fe
2+

(b) Pb(s) I PbS0
4(s)
I so II Zn
2+
n(s)
(Cl@ Hg
2C12
I cr H+ I H
2
, Pt(s)
(d) Pt(s) I QH2, Q, H+ CI-I AgCI(s) ts
oquinone and Q =Quinone
0)

It' '3.-t

-/
eo....---
k.2--t

-+
--'-

b) -t rb
-- -1
rL.2-f m
C:
VI
(01-)
C) J,H} Cr

__,: J\1 t t e -;;;;:!
-- CD..f-J
A C .q H' e.
L
@Wr'e the electrochemical notations forthe following reactions:
(a) H
2(g)
+ Cu
2
+ -7 ~ + Cu(s)
(b) C1
2(g)
+ 2Fe
2
+ -7 2Fe
3
+ + 2Cr
(e) Zo(s) + 2AgCI(s) -7 2Ag(s) +ZnCI
2
(d) [Fe(CNli- + ~ H
2(gl
-7 [Fe(CNll- + H+
d)
)
L()Cr-f'LcJJ'v.> 1
.3 ii)..Answerwhetherthefollowingreactionswilloccurspontaneouslyornot,understandardcondition. k:'V .... 1./-
fj)
'11 d 3+ 2+? EO( 2+/ ) d E
O(
3-1: 2+).\ r'Y/V}JOq !tnn V
() a WI Fe re uces Fe to Fe. Fe Fe =-0.44Van Fe/Fe =O.77v . \j I r !:"I
.{b) Wil4lefiildilgallateiOIl libelate 02(g) tramwaterirl acidicmedium? EO (Oz,HzO/H+)';"1.22V {Ef'()Yl 0'I'""
t
I J')JYl
t
:
(c) willO
2
(g)oxidizesgoldtoAu(CN); in presenceofCN-(aq) and OH- (aq) ?


EO [Au(CN);/Au, CN-l =-0.60Vand EO (OJOW, H
20)
=0.40V.
'hz

(d) wouldyouusesilverspoontostirasolutionofCu(N0
3h?
EO (Ag+/ Ag) =0.80Vand EO (Cu
2+
ICu) =0.34V
(e) reactionofPbwithAgN0
3.
EO (Ag+/Ag) =0.80Vand EO (Pb
2+/Pb)
=-0.126V
toFe
2+?
EO (Fe
3+/Fe2+)
(f) willSnreduceFe
3+
=0.77 Vand E"(Sn
2+/Sn)
=0.15V
kZ:t
--
-
'"2--1 - C-
k -t x.e. -sz:

O,Ti- -( ,= +r .2 IV
t'W;lt :'1: J
'-/
L-\
tv\n
o
-
-r-
02-
..,......


10
f?JOU

'a
-.::--
f:"
+-

0).- -:'
e
--
b-
H
f_



_
'"
]12-0
-t
Ece-H

r-.
Eo,-1J-l>-

\
'.

v .'

s: n" 0"1 0 -6 2- \J. f
+ve-
. v/
-------
E3' Forthe cell reaction 2C.
4+
+ Co 2C.3+ + eo2+
EO "is1.89V. If P . 0 .
ce co2',co IS - .28 V, what IS the value of EO ?
ee
4
+/Ce3+
Co c;--++ Le-
e
o
-
-
{e41Ct-1T -
to
Fee
4
ot .: /. b I v
@Determine the standard reduction potential for the half reaction'
CI
2
+2el}72C\-
Given pt
2
++2CI- Pt+C1
2
EO =- 0.15V
EO =1.20 V
o

-0, Is;-
f .. 2- 0 -' f
o
cJ:L/ U ,-
- vL
@Wrae cell reactionfor the following cell anddeterminestandard state emf of the cell
EO (Ag+/Ag) =0.80 V e
EO (Sn
2+/Sn)
= -0.14 V
I
tSt,1
.r'
\
'i1Given the standard reduction potentials TI+ + : TI, EO =-0.34 V and T13+ + 2e- TI+, EO =1.2SV.
V Examine the sponaneity of the reaction, 3TI+ 2TI + TI3+. Also find EO for this disproportionation.
E
e
U1-/ T) - 0 t 34 \I
"""""-1 0 ?:,.t -.--!' T,.q -t-
1\ --t
o
12.S-V
El/Tf+ -
3-rQ-+
\1+ T).
{) ::::- .SRf --< R(A-
c
::=- -l J.. J-d
=r-I.S-j v-I
-\I1I
Dr1
1
Calculate the equilibrium constnant for the reactin Fe+ cuso4 <=> FeSO4+ Cu at 25C. Given EO

(Fe/Fe
2+)
= 0.44V, EO(Cu/Cu
2+)
=-0.336V.
-
-
-
-
o
bee1)::c. c. SRfp,
z: o.33-' -CO'44)


II _,J' __0 .
_Ce..-v,- - I/(...e-\;\ '.- _ - - a-1
M- t G-cU.:o-- 0
C)' k
'1 .z, 0 , 1-10-U J
oracellMg(s) IMg
2+(aq)
IIAg+(aq) IAg.Findthe .
operatingthecell. E /M )_ maximumworkthatcanbeobtain db
O(Mg2+
g _-2.37V, EO(Ag+/Ag) =0.8V. e y

. .
?.-i
A:
M- --f 2-C
--


Q

-2
L

+
"-i f\I\([
r'
l Q)
D

O: q- C- '2-"31) :::?" l';l'V
o
'=- 'Y\ F
::-f6 ,1/ g, I 0
st;ndardreductionpotentialat 'S'Cforthe d . Un re uction ofwater
2H
2H
20
0
+ 2e-
+
H2+ 20H- .IS-0.8277 volt.Calculate !1GO& the equilib .
nurn constantfarthereaction
2 H30 + OH- at 25C.
p
EI -=-0 .'6
211-
()), :=: L.
1<J Md-d. '"fd>
-i. 4'\CD I /.g.UcPL
p.-etclLol /-0 cDI' 'vvL Y Let{

,tj ;) H)..-0
J( -t. --
-+- ffl1 -- CD
y"" ,
MiA

c::.
H
L
-
"

-f'2-C 2-
qj2
to
Crt

;;}'
-\- 0
(9
\-", 2-,
,

l rf
'Q
Q!L-
'0
()
, --

Q-
=- 2-

- - L1Ct "':: ,Q"if K..
JS-9 :::: -::;>-3
0
>1 (t;i.?,J'!J(2 n) k.
k ::: [O-t-
., K e.rv-'
2- MP l'it t L 21t>r-titJ (Y!I\'-
2
V
Q At 25C the value of Kfor the equilibrium Fe
3+
+ Ag :> Fe
2+
+ Ag+ is 0.531 mol/litre. The standard
Fe
2+?
electrode potential for Ag+ + e :> Ag is 0.799V. What is the standard potential for Fe
3+
+ e :>
Af
l()
~ ~
O ~ ~
~ ~
\I'-.. '1--1\\/1 J
tA (j ,L.J"1 ,


-
1L , ,
7./) c'-""
fJ bi / en 1-b 4;; w Lf/ill .: 0 .. >Y
-Q. '1.- -h normal potential of Zn referred SHE is O.76V and that of Cu is -0.34V at 25C. When ofZn is )
6?d to CuS 4' Zn displaces Cu
2
+till equilibrium is reached. What is the ratio of Zn
2
+to Cu
2
+ions at
equilibrium?
---
-


C9> :::--

cO
- 'ZY'/'2n \4'
:= + 0- 1Y - l D fr:r
G
)
z: I,
2-
: ;:LK
o
.. .

2-

, nll' d
1
-
,OS!
2-
D
CkecJ<:

c -=
W.ConSlder the followlng sequence of re ctlons :urrlng inthe acid medium. AU emf [standard) ---.. d
Cand expressed in volt unit: are measure at
MnO- 0.564) I. 02- 2.26 . 0.95 ) Mn3+ 1.51 ) Mn2+ -1.18 > Mn
4 1V1n 4 ) Mn0
2
(a) Determine EO for: MnO -7 Mn
2
+
2-
MnO4 when the
. I "'....
tV
+ ,e--
MV\0(
E,
c
:::Os-r,Y/l)"')
'J..;
N.Y\02- E
.0
k -=: o? \'2 /, 1 1J.v 2-
@
MV\ -+
1}
-
Nr?i
E I(). 15') 11
3::::
1
0J
NY\ D2- -t' e.
o
::, rC'S' I I I)'i ::::. J
(2;-= -J. J g f Yl,,"".2..
CD + Q)
T -rev

_ /. (\ -f 6U",>-- 4
.. 6G

6
z:
F
t Yl2-ft-.: t
I(O'sb'i) -!-'2--('1' )..{,) -+1(O'l'fS-) +1( IS))
E{,O-::
E;
Q)
@)
f\'IV\Di +
6) f\ V/.- 1 0
--+- -re.
..:. i ::t 2l 2 2 b) tiC D ' 'l-'>j i- \ cr'('i)
f=!- =:- 2- C2-.2- c.) -\- L0 - --\ L
4

l

G:t;::- J
1----
-r-- r'!> 0'-- b ef;I-vL. 0 r: A
8 calculatethe EMF of following cells at 2S
0
C.
(i) Fe I FeS04{a =0.1) II CuS04(a = 0.01) I Cu E
O
{Fe
2
+IF e) =-0.44 V
(ii) Fe I Fe
2
+ (a =0.3) II Sn
2
+ (a =0.1) I Sn E
O(CU 2
+ICu) =+0.34 V
,)
(iii) Pt, H
2{2atm)
I HCI I H
2
{10 atm), Pt.
A2 k
te
-
(SJ
(c; .1)
C- ." l.-u2-t

c.:
fU

-
-
C)I 0 1-'
,.
E
O(Sn 2
+ISn) =-0.14 V
.,
L ell
R-
(Or?)
eVA
-
-
rt
L2-) ( C-J
-+ -;;; }fII-
U
o
( )
(
.
,
E == -002.- V-
,_---------<L--l".
r:
\
\
What is the electrode potential of Mg
2
+ I Mg electrode at 25C, in which the concentration Of Mg
2
+ is
l __::> 0.01 M. E
O(Mg2
+ I Mg} =-2.36 V.
5
1
q -(m-----'(J
--
O'DC'1_ j\)j lluJ
\J

--'- lid V
j
j
j
IeUI
0 . , . E''ndEfa,'h.cell SnISn
2
(1M) /IPb2(lO-3 IPb.
j
M)
EO(So2+ I So} =-0.14 V EO(Pb2+ I Pb) _
j
J - -0.13 V. Whatdo you inferfrom cell EMF?

5n
-,
+
j
..:e:::::-
(tM)
j
L:+ j
L--:
Ph +2-e-- .>
-
Pb
j
-==--.
(<;;)

j
C'eL,1
>
j
rpb2-
f
-+ " ,r' i:.-n'2-:/ f-
fb
l (t)1
M
) CS) j
('3)
C'M.)
j

-
-
SR.P
c
- RPA-
j
- '=-h-b1 =:E:eMl
j
j
j
I' --- * I _ -:::
l0'- ..1
j
j
Q-on (lO'?
j
j
L
- O 01 - () 'Og gr-
j
j
I E =--O.01-SSS-"l,
j
j
j
_ r LeJl c-(V\ l6 tyJot

r- 1-tt.z
j
0-(""1 C- cJJ
'. I j
j
e At what concentrationof Cu
2
+Inasolution of CuSO. wfll the electrode potential be zeroat 25'C?Can the
oxidation potential become positive? EO (Cu I Cu
2
+) = -O.34V.
~ ~ L \ i L ~ -:2 ~ t:::::- ~
COl"J (SJ [ Q'l-'J
12'\) -:::: O ~ ~ V /' 'Yl -::- 2-
tJ ~ O>LJ ~ O O ~ _ ~ r ~ ~ ~
./
.. ~ ...
~
@A zrnc electrode Is placed in a 0.1 M solution at 25C. Assuming that the salt Is 20% dissociated at this
dilution calculate the electrode potential. EO(Zn
2
+ I Zn) =-0.76V.
[711'21)= 0-2-1'0"
: : : ; ; z - ~
~
-
_ o.. :},(, - O ~ O-rJ_
~
Calculatethe EMFof aDaniel cell when the concentration of ZnS04 and CuS04are0.001 M and0.1 M
C.7respectively.Thestandard potentialofthe cellis1.1 V.
c. \ (42-
1
ilL CM '
P\ t-A'L4


t:ce1\
Calculate the pH of following solutions.
(i) Pt, H
2
1 HC!, E=0.25 V (ii) Pt, H
2
I H
2
S0
4,
E=0.30 V
iJ
-

'0 0
l:-
I
,i'W-
i
4": _
a,3D -==- t)
- ? '/- [1<1'
- [s-' 0 := r ]
--
G The EMFof the cell M I M"+(O.02 M) II H+(lM) I H2(g)(1 atm), Pt at 2S'Cis O.81V. Calculatethe valency
~ e t a l if the standard oxidation of the metal is O.76V.
L: :L\--t -+
-
-
If\ fv\)
~ t ~ A
@) EMFof the cell Zn I ZnSO4
1
a O.Z} II ZnSO41aZ} I Zn" -0.0088V at ZSc. calculate the value of aZ
. +
-
-=::::::--
-
l C\ t J3
f bl
( "
----------------'"
bn?-i
-r:en --::.
CCA-z) 0)
2.) f
0-1-
4-
10
,
- , ce..t\ ::::-. 0 7
Nt..{'1\0.t- =+"""' \ >
EC-eA)
,)

o'2-q & ,
ern. \rlfdJ
Equinormal solutions of two weak acids, HA(pKa =3) and HB(pKa =5) are each placed in contact with
l7standard hydrogen electrode at 25C. When a cell is constructed by interconnecting them through a salt
bridge, find the emf of the cell.
L

. . r\- -- .>
s: H t
...------

J2 't-\'i +\12.-
19)
::-0
/
v\ ;...-1-
\ -==- D- or os)
/-
Ece\\ --D' l!
I ......-r
@ In two vessels ea<h containing 500ml water, 0.5 m mol of aniline (Kb =10-
9)
and 25mmol of Hel a are
added separately. Twohydrogen electrodes areconstructed using these solutions. Calculate theemfof
cell madebyconnectingthemappropriately.
t-tAcUs

""\0"3 - c... It):\

-
H.t -+ Irt-V-
<
- l c-,)
-i:
-
)

o
........

r-, t--q ]04_ X r,
/'
The emf of the cell Ag I Agi I KI(O.OSM) II AgN0
3
(O.022 M) I Ag is 0.769 V. Calculate the solubility
C/product of Agl.
-
-

-t-
H r
"
CJ- t: Q. 0 2--2-
.
<;; 4 "-A
J

.
-
t
.
CD'
[9,2
[}, 02-2)
-
Considerthe cell Ag I AgBr(s) I Br-II AgCI(s)lcn Ag at 25C. The solubility product constants of
C/ AgBr and AgCI are respectively 5 x 10-1
3
and 1x 10-
1
.For what ratio of the concentrations of
Br- and CI- ions would the emf of the cell be zero?
-
-
Lel.t "
0-051
11
E
t
o
.-

...

... ,
,.
K).f

"a
CJ
[ PoIJ
LCLj
)
r
'I""""'">
c- --

"'---
0
13
--....
- CC--r
)

1 Y-lcr-'O
p
----
( calculatetheemfofthecell
Pt, H
2(1.0
atm) I CH3COOH(O.lM) II NH3(aq.O.01M) I H
2(1.0
atm), Pt

:t.

-r
+1
'y
..L.
cJ \A --\- /Le,-
.k
((7-)
to d\'I --di' k,\"'"\ "t -

1
.... Clr'\t J Cz-:=- Rw
T\< b 0- ,'" J -M()::C')(O'
, -
\--j 2- + l--t t J \--1 rt -t'-4-,
(el-) eel)
&
,
'='- (C I _)
L
I
, /' g r- I 0 ~ 0 -, )
Kw
)g t -q-J
? - i ~
. r 1--- 10 .--i-
I o.-J4
-
-
e Thecell Pt, H
2(latm)
I H+(pH =x) II Normal calomel Electrode hasan EMF of O.67V at 25C. Calculate the
pHof the solution. Theoxidationpotential of the calomel electrodeon hydrogen scale is -O.28V.
\{ t \-l H.-\ t2J"if-

'L-
:2-. [H 7J
,
-
()
?-g v--
NUYlJ-+- 4
() ", b '1 ::=-. o 2- g
(.
B

Voltage of the cell Pt, H,(l atm) I HOCN (10-
3M)
II A + (0
HOCN. Neglect [H+j b . . g .8M) I Ag(s) is 1.0006 V. Calculate the K for
ecause of oxidation of H2(g). a
Ag+ + e -7 Ag(s) =0.8 V.
-..
-
('
E
.....
l' c z.
(- tZ
::- f /155;( IDVl
.... 1"_
10---
3_

Z- XILJ--Lj
&Iculatethe voltage, E, of the cell at 25'C
. Mn(s) IMn(OH!l(s) IMFl
2
giventhatK
sp
=1.9x 10-
13
forMn(OH)2(s)
+111M), OH-(l.OOx10-
4
M) IICu
2+(O.19
M) ICu(s)
EO (Mn
2+/Mn)
=-1.18V
o .
: (U..A"1( u.;)z; e\.H
fV)'Y)!l.--f +:::< - -

y=-
fvlY)\Q}1)L
[ (JYl-J'1-./
CLe-
(S)
E
The overall formation constant for the reaction of 6 mol of CN- with cobalt(ll) is 1 x 10
19.
standard
L7 reduction potential for the reaction
[CO(CN)613- +: -7 Co(CN)6
4-
is -0.83 V.
Calculate the formation constant of [CO(CN)613-
Given C0
3
+ + e- -7 C0
2
+; EO =1.82 V

'i...-
+Ie:-

0 ,ot:;;4
k,a S-
I
Ir):::.
2-
Co ?---t .-1- te. -7 Co1---\-
b'" ;:: 0 '0 _ 1-0-( K
3
lJO
r
k
j.. -==- '1 Qj "'1-- to '
Thevoltageof the cell
Zn(s) I Zn(CN)/-(0.450M), CW(2.65 x 10-3M) II Zn
2+(3.84
x 10-
4
M) I Zn(s)
is E=+ 0.099 V. Calculate the constant Kffor Zn
2+
+ 4CN-1il Zn(CN)4
2-,
the only Zn
2+
+ CN
complexation of importance.
-
:> VI +2-e
c.r-> ""?""" ( e, )
t'l.--t -\- 2L

3 '<6\.\ 7- \6
L--

kf t-O

C,LNr-J '1 y: C
l
,
- .
t'r, S AI c)


Dl w1-
t
x-- "/A1 -t- L..... 1)
$
I .f:dl ~ o
, ,.,
LrTYlt.~ ~
C
l
-::. I 6&fz x lO-7-
1<1- = [Zh C'CiI/);j
[Zn
2
J[crvj'it
L 5J 3C[ )( ~ D/6
--- -- @,volt.
g
ofthe"II
Pt' H {g,608torr) I HCIO (4.34 x lO-3M) \ I S.C.E. is E=+O.s32V. Calculae the dissociation constant
2
for HCIO. Given, E{SCE) = 0.242.
......
...0
A:.
0
2-
+2e-
---
---



:,r'
e
.,--
o-cs-1
EA-
-
-
E
--.-------..

2---.
'0
0'
.S;:"3 I-
-
-
'=.Cct=
EPr

2-
(yc-. .,. '1V
0.051
E-A--
-
--
r
3
kt\
Ylu
-
..--
-
......,.
O.1-q -:- -
2..-
n
u.,: JJ , r-
2-/ (J Clllculaleenlropy and enthal h . .
pyc angeIn their standard state.
vel p- .$01 T
$::- ,6(,
'J -)p
6 Q ==-- _ Y\ l \ = --2-'f. S
'f- \4 '2-
=-i5{b2-/"{ROT
6 H 3,

6)1 :: -- d 2- tJ t 300
J
r L:, \-\ -?, "I' g oS-
@HoW longacurrent of 2Ahasto be passed throuh asolutionof A,ND, to coat ametal surface of 80 .
cm
2
with sum thick layer? Density of silver = 10.8g/cm
3.
~ 7 e : -rlT
~ ~ t Ay . ~ } e ~ ~
~
-
QAcurrent was passedthoroughan aqueous solution of an unknown salt of pdfor 160 min 50sec.
~ ~ 3 2 gmof Pd+
n
was deposited at cathode. Find n. (Atomic wt. of pd = 106.4)
fet rn-t t Y1e: ~ Pet
~ ~ I \ L/AW'_
s- '.S2-- '::0 t 0 (, '''1 t< ~ ')( ~ OJ b sro)
'Y) ~ ~ q ~
metal Is known to form fluoride M',. When IDA of electricitv Ispassedthrough a molten "It for
sec" 1.95 g of metal isdeposited. Find the atomic weight of M. What will bethe quantityof
electricity required to deposit the same mass of Cu fromCuS04?

I, qs ;;C (rnwt> y. 1,0 3.3b

({StF r 6)
2- X '1
l e7S at$lI.M:-hJ
fA

r;;:j;Jmlof 0.1 M(uSO.solution Iselectrolyzed with a current of 0.965 Afor a period of 200 sec. the
at electrodes are:
Cathode: Cu
2+
+ 2e- rn Cu(s)
Assuming nochange involume during electrolysis, calculate the molarconcentration of Cu
2+,
H+and
54
2-
at the end of electrolysis.
fA.:)'\ U.
)lor- c..ko\
\f' _ '
__
L.
:{ 21+ :Le. - ---7 1 _: 'h-F- ""'.L3 c:
')
S-0 '( 0' \
- ..
ID /
IO()D
(--- ..
, ()-oo
------
!j 'S"1YU
(!Y\ 0 )
-,
l '.: v t-1c,::
LCWJ ewt::. D' 0\.1 tvJ]
"--">
@ '0. fal,1y concentrated solutionof CuSO4 iselectrolyzed usln.O.o1Fof electricltv. calculate:
(a)Theweightofresultingsolution (b)Equivalentofacidoralkaliinthesolution.
,
~ M ~ ~ ~ f ~
t\
C)'O\
--
Q An electric current ispassedthrough electrolytic cellsin series one containing Ag(N0
3)(aq).
and other
V H2S04(aq). What volume of 02 measuredat 27"C, 1atm and 750 mm
3
Hgpressure would beliberated
fromH
2S04
if
(a)onemoleofAg+isdeposited from AgN03solution
(b)8x10
22
ionsofAg+aredepositedfromAON":!solution.gN. 6x10")

- .

0 _0& +
I tp.rvJ
CA t; _
1 4y.. /j(,'=V
P>2-}(
- 2-2.-

rr'1if
g ...-

1-.1
1i6.n-o

-,

B66"'OD X 8
0"
-6 Il\ 0
o",r A /'
amalgam is prepared by electrolysis of a solution of Cdel
2
using a mercury cathode. How long should a
currecnt of SAbe passed in order to prepare 12% Cd-Hg amalgam on a cathode of 2gm Hg (Cd=112.4).
G\-Her
U -7 }!r
.,
'l-t t{( 9
( 1: '1 [A/.A;J )
2 'A 12- ::= 112,4!: (s:X b)
2---1 Q6StJO
electrolysis of NaCI solution with inert electrodes for a certanin period of time. 600 mL of the
V solution was left. Which was found to be IN in NaOH. Duringthe sametime, 31.75 g of Cuwas
deposited in the copper voltammeter in serieswith the electrolytic cell. Calculatethe percentage yield of
NaOH obtained.

--.

oJ Le -7 Hi.,
N
1- l-e-- >12-+
e 1
,st
Y)

2- ; 6"ru
v
(" 2 b '},S ;>( 6\
- ....
2-'><
I
of el.ect'idty;s being used to liberate lodlne tat anode) and a metal' (at The
V;ass of x hb:rated IS 0.54g and theiodine is completely reduced by50 cc of 0.1 M sodium thiosul hate.
Flnd the equivalent mass of x, P
\J 1" &l:v:o (0At).12- 'f- 5)
1- " 4'
-s - --Q
L- c; 6
nJO

==
'j.-
{
lrr*1
If<<

0'
r-
l&-J l\1
0
oZr'fIJ} '1-10:

1" /"
\
50xO'}.Y)
- -=---
-
l ()770
standard reduction potential values, E
O(Bi 3+IBi)
and E
O(Cu 2+
I CuI are 0.226 V and 0.344 V
L:Y respectively. A mixture of salts of bismuth and copper at unit concentration each is electrolysedat 25C
to what value can [Cu
2
+] be brought down before bismuth starts to deposit, in electrolysis.
7
E:- ca- cd{
'U -::v 0
. E. (st!dJf:,r'
LluUJ J,.
U .ucu
--t

:::- 0' 4'i f Q t: L +j
j z: ,(/, fVJ
Acurrentof 2ampsisusedfor60min.to electrolyzecopper fromasolutionofCu
2
+atapotentialof0.337
L/VOltS. .
(a) Howmanycoulombs areused
(b) HowmanymolesCuts)areplatedout?
-(e) WhatweightCuts)ingramsisplated out?
(d) What powerinwatts wasused?
Ck)
'j Ij} ;'lttW

. eJr
l
o 1- Gt0
p'.
li
J9

<t
N

f V1- l;X C

+ (aq) to form Ni(s) for 2.00 h using a current of 2.50 amp, what massof if' you electrolyze a solution of Ni
2
(AW =58.69 g/rnol] is produced at the cathode?
Nl'l-'f --r Nt'
(txfr) . lS)
r I />+ r
. --,
(Wt)N; h"t ')( 'Y-3(;0-0
L 1--
C;; e zrrn I
,"
wasused to supplyaconstantcurrent of what wasbelieved to be exactly0.45Aasreadona
inthe external circuit. The cell was based onthe electrolysis of a copper sulphate solution. During
the 30 min, that current was allowed to flow, atotal of 0.3gof copper metal was deposited at the
cathode. Determine theextentto which themeterwas inaccurate
J }c;tw

0
(i.! 601'- ( )

"

(, -Q' '1-9
Or ru"
---
" CCJUk-7 % paf;J.
bz 1NJI/\ J ttlY 4 J1L
.. be
_/"lIt0I -'lO.. A balloon is being filled with hydrogen produced by the electrolysis of an aqueous solution of an acid. How long

will it take to generate enough hydrogen to lift 1.5 kg by using a current of 8.5 A?
\t,OL gez
4:t 0
-
'<,

.\
\,
1>O\? z
V
p?\

-....
/Z-T
V)H
lSOV
7.---.
L
Ly
e>>
-----=-
qS7lD
.: ,,3S() Ju;up \
~ current of 3.7 A is passed for 6 hrs. between Ni electrodes in O.5Lof 2M solution of Ni(N0
3
)2' What is
V ~ h e molarity of solution at the end of electrolysis?
[N ~ J
@
t
/.
I
t
I
f
i
r
I
!
,
!
i
I
1
!
!
I
i
" I
[
!
---
e The reslstance of a conductivity cell filled with O.OIN solution of N,el is 210 ohm
at18C.Calculate the e ~ ent conductivity of the solution. The cell constant of the
conductivity cell is O ~ Cm---l
elk-)
$( D\63)
210 ohm CrY)
-
OlBB
,II. ~ ,_ ~ , --l
,
r
'-f" 1.9 X 10-- 0 n m em
- .
~
~ 4-'$ )(\/((r
Ol'l1 J
rJ 419
--
---
@
. .. --- t
2
o a IS e speer IC
i .'.")1 he molar conductivity of 0.1 M CH3COOH solution is 4 6 5 cm mol Wh t l th lfl
conductivity and resistivity of the solution?

K thFrt U>d,,-wmty -7
M -7 M.,{axl7--
1"'
"
rY1
A",
-( ryz fcfn-f r-?
Ui'b I V\ 1
-:7JlE=-
AJ
I
(JJ
,---.
<-S
em
L
ro.o
4,1
r-
l
.;-
k
it e-o D
...
ro I
<
t
1/
-
rJ--7'
I
he conductivity of pure water i onductivity cell with electrodes of cross sectional area 4
cm
2
and 2 cm apart is 8 x 10
rn7
S cm
lill
, g'-f 10.-
1
.5 .... 1
Ii) What is resistance of conductivity cell ?
Iii) What current would flow through the cell under an applied potential difference of 1
volt?
R
-
.....,
)

(0
si.
ohm
.....
.......
g ')('0;+ .:
g
-
b
-
'--
6'
h J, C ,,'
8
o rY\ m

g
I::: L G'2 s I b S-)
....
(,=-
-b A l
----- <.
~ Resls tlvitv of O.1M KCI solution Is 213 ohm em In a conductIvity cell. Calculate the cell
~ constant if its resistance is 330 ohm. . ~ c>"
~ tell C_etJtV)1Nv'i
R= ~ t ~
S ~ ~ l:Ll3) (7;-)

& '. Resistance of aO.lM KCI solution in aconductance cell is 300 ohm and specificconductance of
O.lM KCI is 1.29 x 10-
2
ohm-
1
cm-
1.
The resistance of O.lM NaCI solution in the same

cell is 380 ohm. Calculate the equivalentconductance of the O.lM NaCIsolution.
.LJ.-

,
.......,
)
e,
" ._-
f (So-o XY
-
.1<2-
r
@
" OhM
'. For 0.01N KCI. the resistivity 709.22 Scm. Caicuiate the conductivity and eqUivalent
conductance.
,
\"
iW
[ A--)
fo;- 7oCft
k
en']
2 7.- o12.1- oIrm fYj
/1
It(.. E- O/Itt) rYJ-I
J .
ai ci . 1
L
( ,4hwr 8:P-.:2'?> 1- .5)
. A solution containing 2.08 g of anhydrous is 400 CC of water has a specific
conductivity 0.0058 ohm-1cm-
1.
What are molar and equivalent conductivities of this
solution.
/Iv IV\. ";c k )< I {YUO z: 0' (lO>g "1- I Ct('J\:')
0' O D2'i
[AW\ :::: 2-3 'L l
M '/..
...\,.

"
()f
&9.Equivalent conductance of0.0' N Na,S04 solution is '12.4ohm-'em' eq-lThe equivalent
conductance at infinite dilution is 129.9 ohm-
1
cm
2.
What is the degree of dissociation in
0.01 N Na2S04 solution?
\\

==- 0r bS'L
;0
'\
f l-j1

LY--' .. Specific conductance of . a saturated solution of AgBr is 8:486x10-
7
-1-
Speclflc conductance of ohm . em 1 at 25C.
6 2
pure water at 2SC . @
AgNO, and KNO rs 0.
7
S .,0- ohm- cm- . A"
3 are 137.4 I 133 131 ( S cm
2
-1 m For KBr I I
solubility of AgBr in gm/litre. mol ) respectively. Calculate the
(<2
:::- . 4 g s "f...\ 0 - 1,<;; 1- I0 /
o1rJ m" 1 em,-l
0'.1 g{;Alo1-
--
-

(
r 1 D:=J- 1-10-:7- YYll:>ll L
I' '?,3> X (J/ L.
solution of AgCI at 2S'C has specific conductance of1.12.,0-
6
ohm-
1
em-I
A.: Ag" and A.:CI- are 54.3 and 65.5 ohm-
1
cm
2
/ equi. respectively. Calculate the
solubility product of AgCI at 25'C.
M C'- /

..0
- GL
.r'
.
< J'- I 0-0-0
r
l
1
l'
i
5 -A.. Ai d.)'-
'dC?J . 5
2-
.s
acid is weak acid. :t 25'C, the molar conductivity of O.002M HF is
\:7;76.2 ohm-
1
cm
2
mole-
1.
If its Am = 405.2 ohm"",l cm
2
mole-
1,
calculate its degree of
dissociation and equilibrium constant at the given concentration.
o 0
-
kl). :::- (Ld-) CoZ)_
.--
Ld.'L

0:-
'"
-
....
[[r-c)
r
,

{, ..
1
.-
...
--
@
e-
I&' " mo respectively. , a an CH are 426.1 1265 and 91 S cm
2
1-
1
.
. ! The value of A% for HCI N CI
3COAIa
Calculatethe valueof A% foraceticacid If the' . .
at 250 C, calculateitsdegreeofdlssodatl squlvelentconductivityof the givenaceticacidis48.15
Ion.
('2 vt
J:
hi-

r
viC
10
f

...,
'Il()13LDD11
pC) .
J\; \-{ -
J\-
0()
Nt\cJ z:
1\'fJ
V'-' ,crAl 10"- -z: t
l1
2
I)
vL -J
1-
A
oO
f-S(
IVu'1;}ll\1 t;vrJ.. -
-(j)
-0
r-(j)
0) -h)
-4.4'I Iii-s-t:3J !,!JO'
0Wt2me/'""'1
the specific of 0.1 of at conductance a M aqueous solution NaCI room
V':emperature, given that the mobilities of Na+ and CI- ions at this temperature are
4.26xlO-
8
and 6.80x10-
8
m
2
v-
1
s-l, respectively.
IL,tJo.. t .: ))N'fA 't
... ......
-S(;K'OQ
Y' I' 1- )'0
3
/ 6, 3
b i r l Or-L- 0 1-f'(Y1DV"
,
s- J

\( :;. t(hJO X 0 . J
[.067
the strong NaOH, and BaCI
2
the molar ionic conductivities at infinite
2
are 248.1x10 4, 126.5 x10 4 and 280.0 x10-
4
mho cm mol-
1
respectively.
Calculate the molar conductivity of Ba(OH12 at infinite dilution.
($ r
l
rIC f1:J..h)1-- ':0-
[) :::- cD +2--CD - 2- (3)
- 2-&0 +
--I {Or-7 I
.: l2-g0 t qj. .2- - ) fled .
3 2- ,(I ] _
. -
@
2mol-1
At 25'C, .. : IH+I = 3.4982 xlO-
2
5 m
2
mol-
1
and ..: (OH-I=\8 x10-
2
5 m .
Given: Sp. conductance = 5.1 x10-
6
S m-
1
for H
2
0, determine pH and K '
w
.. r. \00'0
(S;;S-9
Q:4''1 ' 2--)

g
t<IO
If. qq 6LII( ~ 1/ -- L -=- S' I >I. l 0 ~ 6' )I ~ - - - -
l armfMj
I
-0) It HE] c j<OL03)(lO
f
,. .
..
,