HSC JUNE 2013

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t'lV
+2 PART - III
ilffinflflflflItflflffitflit

JJJ

Gor$luSlud/CHEMISTRY
/ ratu

601 1731

(p,6rti bpgb +rdClo tudl

& Enshsh ve6on,

[6]6trE9 6jtn6!6h6fi : 1so [Marinum Mark : ]50

(2)

(11 sr6@6gi 6tr@trir5@Li aflurB !6dtr61 L&mptr Fdupsd anutr,i5gr6 Gl6rdrnqii arr&nu66rt.$ Omplqou$6n sr@rdj a@a,cdl ,x.{ bL_ao .6E or}16$iaqj (2) 6oLi .e6ogr spn'r 6bu9d@ bLOGD nesrdppgn uutitruo6p GtuqiroLir. !Lrdr6.ir tuoqdpEg Gtu6na<ir !L.itrlopF6!6. (r) che.I the $sho. papd ror fanness or p ing. lf there is any t..k or Limess, intorm ihe I{a| suporisor inmednb\
Us
Black or Blue

int lo Niite and pm.it

ro draw diasrams

gdlnq,
,

Gpodutrd gr+61.i, lLLi do[Esr. s66n!tro6om d$s5.

Diaw dn8ram and wiite equations whdover nae$a.y.

uglil
Odlnq
(l)

r/rAR-r - r
Li,

(ii)

B5l 6$dr66(grt66 66loLU6fl6s6! sflum 6$oL@LE cp,i6cr5ops n(9gr6

,^nswd

cad

.ll

the qussiions.

(ii)

Choose and

wire

the

cotr(t.n$ver

(sr) ccL cHo

(g)ccllNo,

rlil) cHctl

(tr) cHiNo,

(a) cc\

cHo

{d)

cH3No'

HSC JUNE 2013

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333:

OrSo

d65

6,51d@!9.ii 6r9otr q@6 Drdl6)llilid 66lnLr

a6}ro rp.ir 3m'I drD! 6tro6

(er)

(6)

a. .Jildtr,+g.n

(")

(d)

6i
(J{)

ftds9'b

r@s6.j uarcdu

Mno,

(-s)ccor

(6)

N.o5

a. eO Gl !!6@0
(s) sadlu6
(g) {5-Pq

6rDtri'Gleu{n(!)opu9'i1 C!tr5r er6iLlii66r d.iLcrytr[l otrBPtb :

of the For an isoihermal Prccess, ihe enEoPv ctDn8e

urlee

durin8

Prnible prc'ess

(a) zerc G) I ss
5.

0) G)

\'Ioie
None ot the abo\'

(6) chH;\.cl
c6HiNH:

(n)

CiHroLl

-.r(:K (a) ciHrcl

0r)

C6II; NHOH

HSC JUNE 2013

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a 79 eirmrq
i6) !r.
D6

6irdm6 &llDgtrp GE,i.6pod

Ruby glass is a .olloidal soltrtion ol

(b) (d)
!ryraripg
(O)
BM p6h@Du9.fi

cel
sol

sdg

(+) 6lcdr
Paramagnetic moment is expre$ed

Agd6io

G)
3.
(sr)
P-

BM
:

sLLn(p) gr6fi d6i!5r

*1"0

(+)
as
:

,"0

(6)

1Ht

(F) Ire4

pdti.le ls represe.ted

h) *,",

(r)

1.0

(.) ,H'

e-

6.n.'"G!trdn.$ d.iiD 3r@66nu66p purfltit6

!ud!66

GEnDLil

(sr)

erflLcLriii /6' e\ier 6 .n +dsm'd (.)

Isolioptl al.ohol

(+)sclLcLtr"'.acdtrn
.

Co-aEtro
:

Ihe compound nscd ,n ihe pRparation ol the tranquilizer, sulPhoml is

r0.

do6L[r6n prLL66di elo(g : (sr) N,lev (+)lK 1

T}e

(6)
kl

"v

G) Mev

ffit

oI electron affinity is:

(b) K-r

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cH3cootl-6 Eotrd B+grE 9p6n

J)rn60otr Si696r{n
aoo eLj,

25"c

so

- t GlaL6'

eord6 1. srflLqd ldlo6(cHlcooH)(6)

0.1

Ab

r G.l8l sbrdib r DigLir

(s')
(i)

(er)

0.2

(tr) 0r

ltu !qr\J-.1.

Ci.Lrj,a
1

old. vit. cllr ooPitz.<isSOohn rtn)pq_ cndrnhnp {J T r,,-,q. r. Fr;dp8r+dfl al.honofChrCOO.r. (b) 02

dldfrrnoltsl.nn RoEU +65FDro 65ro646n6ir 6aitrdnad6 (") (s)2 (sr) 1 {6) 3

The mnrber of

s{onday alc.holic grcup

G)1
cll3o cH-cH3
CH:

(b) 2

nr gly.orol is

(c) 3

(d)

opiitr IUPACGuui:

(s) 1- dppr66l Lrfncldtr (s)6r.86.n aclr !do!6 Fpi (6) ecatr qru@u{n G1066{n rpi
(m) 2- Lfgpr66l rrilac!6ir
IUPAC Name of thls cof,pound cH3O - CH

CH3

cH3

(a) 1- Metholy prcpane (b) M.thyl isopropyl etnt (c) lsopropylmethyleiher (d) 2 - Merhoxy propane
1a. Cd6lr, aE6@@uElin pidmD (r) guEs+ 6EC@@

(6) s&sr6 g.ioo

State of chmi.al

(tr) Or6h06
:

(er

eqdlibdum js

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+-u@
(6)

661@m66tog

LLlLtrpCJ

6l@ud

s6rad
olTyndalG eff{r is

(E)

664

The phenomenon

16.

6@6G6r6iD 3... r

ls

.o

Optrr6 g(gc6tr6ft6 ltl4obtr6 DriDnlLrgr

(g)

Ltr@.ir6iD

er@n
b gl!.onic
acid

(F)
!y
:

...Gu60d

9 6aostu

3rLfr HNo3
FeNinSrs

Clu.ose is .or oxidi$d

(a) BrrlH,o

G)

rollens

rea8enr

0r) (d)

sobrio. con.. HNor

Gsn6rngdflrl d,!,csnDLir 6c[rmDdr

gcdro[O

ceip@tr,i;(q
c6Hscl

(q)Hscl?

(6)

zncr,

(n)

iolloaing comlounds will nor give positive .hromyt ciloride ted z (c) zncl, (d) c6Hrcl 0) HsCl2

2cl(s)jor(8) 60@du9.n

(s') +, -

(+) +, +

^H

DDg'n .$ 06nlr56n6h Odl6.n Gropcu

(6r)

(")
:

.+

Ior th rcacLnr 2cl(s)rcl,(s)

rhe si8ns

of AH and .\s rcsPdivc\ are

(.)

,-

(d) ,+
&trdl4ldl,6 rLE@Lb

19. e!6b6fl6ii d.irlg]

(er) atr68ddl6 cluslob

(6)

(+) er8L6L6

atr60rlo16qdeD0

(r)
{b)

L6E@p.i,

strdldcdL

(c)

Aetyl Mli.y]n aod

sali.ylaldehyde

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3331

GdSlnurnq6gdip6std

n$ pdptrdgr

(s) ddr5plir@blloLuSr
(+) 6pbe' 6ln,iq +lipdr cs@dnlodlps, (6) urnq6 6 oLb c!trOoad 6E u@ e{O,ig6etr (F) u q6,caidrnsdr p Odrdt.tpd
F6r clEhisorprio., wnich G

c$risj66t66lDgr

konB

(6) It Equires acrivation en6gy (c) Ii rolm multimoleculd layeE d (d) Slrface onpounds aE rormed

adsorbabe

H, qi@d, I, 6fl6r5loEgl Hr Lodtr(gLir s@6too 66td@9d

(er)

ans=2 (s)ans=1
(6)

(6) Ais=o
:

(a) ans=2

ln the iolfution of Hr 6on H2 and rr, (P ll !e.au* =

Ans=1

(.)

Ans=o

22. lr[ratr'6fr'5prii6D uanq 6rbuls ErrtrLi) (Jr) q3r+ n@6Lrr6hs{ir (+) sDe@DLtrE d unlLL n@6Lrr.ii L.n &66n

(6) (tr)

p@aBp dodjL[ftitrErir

CreoDUrG 6trdtur6 L{nm do6Lrr6h q(n

I

eo6d

Paramagnetisn is rhe properr, oI

G)
(b)
(c) (d)

P.ned

el(trotu

conplerEly tilied elchonic subshets

nnpaired ele.hoN
Comptere&

vacni elecEonk sub

shens

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,
rr,oorr&d.n glotrnqB grLrr
:

(-!)1

(+)2 (b)
2

(6)

(") r
G)

24. Gdilua6g g;.ir@Drr.in @r6p@do

(O) qc[6iiL6
R.rdrarhle el.'m.nt of lanthinlde is:

t)
25. s55Dtr5 z{nn dd&L[rdisdd(n 6-p5r6po6 Cluignd (9dp5+65n
(er) e5ll6reh

1+)n do6 EopoL6E)6.n (6) p do6 (6oE5L56lG6n (r) L6ldrsL6ptrn G!trol6d

6L6d6fi

ScmrondDdoE whi.h exhibit ondu.uvity due io Llp floh olei.essne8ativeelechns

La)

conduciors k) p iYPc rmicondud s

Super

(1,)

n rvpe semicondu.lors

(n)

L.nndd

iurdm DD9JD 6ootr Flri0! 6e;6dier6 s(mU!0rn ctu@in!Lo6616J

(6)

6trorcLtr 60d]06m

(i)
thc

sldlcdtr srdlob
hr:i'r:nd.f
au ncrvous thsue

oi.r

nr rhe n

r c nrnr.l

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9331

6tri6!o6l6h

66Loou5l@

trouo6 6flD6 Csi@6

crH,

(,l)(crHJzNn (q)
Tlr orgmi. comPound ti.t (.) (crHr, NH {b)

NH,

(6r) (c4rir N
6

(r)

(c7q)1Nrl

underSoes carbvlamine Pa'tion

czll:NH2 (.)

(qHriN
:

Urd6&dld 66(4tJ deDLra(n 6omnL9lD6rd aftns

(s) o - trpLcttrdtrr.n (g) p-opLcrrdtrrdD

The inbimoleDlar hYdrogen

(+)m-dpLcfrrldtr6

(r)

OdEsr.n d5l6!u'd@o

2e. (+o,6eg6(q,ti6l6Lr3u 6E)L[e?.i! 19@trnq Ep5r6hutrdiEl& 6e6

o060
(6)

(3r)cH3cooH
cH3cHrOH

(r)

c,H5Nlll

lntermoledlar hy&ogen bonds are nnt preseit in,

L{n6fl

$6rL+ri,t &@@!tmLugr

(er)

Hr?o4

(+) rlrPoj
garlic tasiE

(6)

P,o.

'lte cohpo0d wi$

is:
(d)

(a) HIPoJ

(lr)

HrPor

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!(951 -

iIlPAnr x

cdn! ,

(,)

6rcpsd !6@d6gr

60drd,6(Ddiq 6il6Ludi

AtuGltutrO 65a tr6$p$d e6iq3l

(i)

9!6!o$ ordiqGr

,^.swer any filtccn que(ions

(i,)

Ei.h ans*er shoulll

be

i| one.

Otr66o!6! a6,ru!r

32. l!R65lu6 G=r) Gb;di4lLb k:ir) DOprLir gtr.n8u6 (z=20) +dtudpdlitr noiLrr6n prt L Ddnqsfi GrpegdDu 9eu6 +gLb q6n 2
Tlr
Elochon al'nost zero

irai'rihis.r Berlllium k=.1) MaSpsium (,=12).nd..l.jnn1z=20) ap r\rN ?

rrrPor gO 5ui96!6 LdLLer Cl06

lliPor
is
d
i

protic. Pruve.

3,!

.'"Lrc@rfloi.n +dd0gc6dbp $tpd lEdl 6JtdR

Discnss

Lheoridrs s powpr oI fluonne.

35. N;+ Lnt]6dr !6lD(!D.nrddun51.nn6r +dtr6iznr+ Lnlrafl 61tu6r6butr6

Lflntr

.r6n

?
?

1!h! zn:- salBarerrlnh trtite Ni2: salts,,? cotoure!

36. ilddn opLG[L;,l- OdnlnuoEgrb GLtrE] m6rd llhat is th..rh.n.I h.rr.n sirvcr nrhrc,

6r9l@dq

rD!OLi

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3331

rlAlr'+.Her

J ,asil+

Hr+ Q n6np

sL6O 68dduqd

Edn@ld sairLdld

llcr=4.0026 rnu oDprn)

Caltulate Q latue ol rhe loilowing nuclad

FatrT+2He4

lsilo+rH1 +Q

33. 6@rffirq n6,dtr9 LOdr6lPSr

Hov
arP glasses

,oi,ned

3e. Gdn! gur,66dlu6 40,

2NOCI(8)

6[6itrLtrLb 66]6 uEdl! Clsd6$ldi ,l r," ol.he.To,lr,-k.

&oop aegr6

,r'n I -AOb Kl,.n o6noLd;

2NO(s) + Clr(g) 661@du9d

^,'3?i.lOLR =iriil21 dml.h r;rieHtu,r

De6ne

'.r'!"rqu.'rb.ru. \or l\$ aoldT ta aoq .a..aGK",' tnbequlbriun1rrl"atr

790'C rn 3.75x10_6 mot r) 6@&ClO5 (R- 0 0821 dn3 atn K_1 hol rNo\s)']rG' rhP \r' Por rL"{-'l:bnun'o-(dnr

(. ,n 66nq

I rmor r)

41. elm[ dtriloG 6roLi-d6[u&].

HilI lifc pcnod.

42. )k6i " ae.bdtr' ri"G99!A ai0a)-GlLo MdeBgs w " anv ttr . .nara.terisii.s ol lilsi order rea.tion.
43.
aa.
utrdDDd6.n d.nptrd dntr , 6[ah0 40pgri5tL6\6.n pC,4. r{hat are ehulsions , Give two examPl6

6fl6n sru6fln GuO6r66 d6irpro d6ird Whdi is onir prcdu.l ol water ?

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11
45.

6G5rsr@@u@! &dDrrir6 6@@du965loEeJ G@s!0.6s6. Dininguish D.emi. mixh]E 6om masoldm.

?

a6, 6om65r6$6Uoli'gl 6Lfl6sln 6.tudrp] Fionfldt6!!0ClDeJ

llow
ls Terylene

!!epa,ed lion Oycol

47. 'L.ir' grop@!

Eaplain Dov's

66ln6jg5.

procs.

s6lLGLtr@ (qcmrcrtr.'.utrngrL.ii KoH gr.fi aioou96 d.ndtrt 6616d qn6lp5 ? Hov dop! a&ionc r.^ch vith .hl.r6fm in ih.

ae. otrd,'+i
Wnt

srl6l@rj;6ld 6rCFglE Gr.irpr uL6nsom 6(gsro .ny thJee usds of La.ti. a.id.

HNO?
B

cll, NlI,
B

s1. 5l6tr@!9n dgflsdr(+rfi quurLqsd)

Whar aE antibiotiG ? Cive me example

ao

@68glli5trL0

I 6lOLqE

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,tu; A ' gJo i6' Ds - 0D 6\, 68fr 6d r'.s (qdnq: " n."' . ,-3e ,"d . pg 6L ,do 6U, 66@13' solio' Note: Aft*er ey sevcn que*ions thoosing rtle's! tuo qnesttons Iroh each A."6(e / sEcTIoN A ra.ii6aa'..5e6' ' "' ra6uq'"'5sado rr !Em2s I 6lmp m =qr '10 I tE)
Jlflq_e{
.1

u(951 _

nI/rARr _ III

,5

"'o

r ''c

(h=6626.10

!1!iJ.-'h 'n''rJ ,. ,,; , ,';

' , PDo'':o'

'_!''

rn_

il. p.60."'tur'rs.doss

Odlrs'du6e6196sao

drEp6@0 6$65gj6.itr
Discuss thd consequen.es of

lmth.nide.ontrr.tn,l
GEnD|n66fltin

g@tr6lp6n 19mdnq6 Gls tr6no5 r'9.i{ g!onJ Ai1tu(9Lir 6r5ldi;g6 +iOLL(o 6@r; sdnq Dpgb 6nEP! uddqson

tfe (cN)il]_ hrtiidisntion and magrcii. ptoPedl ot the rolloa'in8 'onPleics

(+)

r.hl-Gllr6uq.

G)

Jb / sEcIroN6lpnr9lu(nrr6od4 pO6
_
(s)

lflq

Cire the .harNteisti.s olenhoPt

s7.

PCl5

669qLir
the

661@ddrg

l<. Drigib

(! Dtrrl6il6i{956rd a@'iruno5@m
dns'cration of l'Cl;

lreive

efressions for Kc and

KrLr ilt'

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s3. GD#d edlLG_L6r c)ld6Fpd rd6!6e.1; E.r,u9ao@66@@ lsd

68ll6@Gd5 Drdls!@u 5liffiu96oLi Crtrpotrou 60n6t66. Explain fie expeimotal d.l,.minarion ol nte coretant ol a.id hydrolysir oi mdryl

se. g+/As 6!ig6Ie3+/Fe,+,

SdlL l6Bi4od6@65tr@ 6LL dl{hdG,5p rn6t6nGm0 grdpcu I) 7991 v, 0.771 v +(9b 8D66rgr6 6fl6tri6rd
Pt)

s66l@o 6rdl65l@u6 Bffiddl06.

AsG) + Fe3+ (aq) =A8+ (aq) + Fer+ Gq) Th standard elstrode potdrnL or rhe halt cets
0

Ag(s)+rer+(aq) :A8+(aq)+Fe2+riql

-.0 vr

0rl\...pAnvp\ I

Ltu

B+/A8 . , h" ,.tu I'l -un rcar4nl

and Fer+/Fer+, r) aE ol dle rcyr,on.

Lllnnl - 6l /SL( noN . ( 50- el6icer@o$ purfl666 ODdps@d 6@915.

NlenLion the nrethods of prep.rahon of anisole.

(i) 6lm66t56itr 90rje6 6dpLn (4 pdp6.n 6610@ uEril 6dl!r] d(9sr6. write a not on (i) CGmenson Edrciion and (ii) KnoevmgaL ra.rion.
a(6S161651.*

Wrilr tho
61.

m.h.

Jll61di4d qclrtdcdip 60ddu9id

sm of Brcmlnation of salrcylic acid.

dUil(go@p@u d(ugr6

ou66

D0rE&6.ir d6irDd.n n6td ? 6dldn. What are aEesrhetiG ? Explain

Odlnq

ue6l -Iv /
(i) (i,)
ClDtrSpLn Etr6itrg 66ldn n6i, 70

PARr -

rv
4x10=40

66ldrds@r;O

66l6Lu6n.
d$gldrm 6$dre66nd
the

slLrEof,Bq6

rcEgtti
remaining

gD6ii0l 661trni5reD66 68@LU6fl Question numlpr 70 is .onpulrory and answer ny three from
(ii)

A$wer four quBhons in

an.

(sr) s!#lutrEoLir elipoo ur96rgLir strr@fls@d 66tddlg5. (.a).'.qcffi@[066n66]oEs i.qcddlf].itr c.nturs tllfl E6plod6nu6dlp5}

O)

Delcribe.\.

La ros'nrlupr. -g Lhp, ni" ho1 clcrgr How nuorine is isolared hom rhen fluorides ?

HSC JUNE 2013

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65. (.:l) I(;Lancror)rl nlrL) @.n9

' " s''- r'u;"'?GsL: LrDtpsasq[li \o \r "r ''\'nPi'' "'('r a-r" ,. ;.",,.' .. , , .' rml{ (\) (:$nrn\ t
l,*rr.l (rl co oi.rDrrr'or Clvetlt usos olra\tioa'tilP nobpes
t,trr
nr

G6iDp6roE gdtuOdd"rr: (i!l ei-'r (i) GuLi (ii) @oL e Gor6 elan f i) .'an (v) qp 6ldnn gl@Duq

nrcdi'jnc'

66, (s) 5,j(trq!96ir

(+)ouidlrd ! aorcuu(d
(r,;

gen@Dmu 66lmd5 t 5 soJirEdl6sE GoFu9Ldi

GdP!r66@m d'l9p6r0

h\Dlaln thr fature of sla5s 1": ,",. ,

p.i
;

* *,

"
d.,.d ' tu 'b

67. (3) .51.d,'

". -.,0o,'-'ruf.tion

I!.hnr Ostrraldt rheoN ol indrc'toN

,,.1.",,*

",. -*,*".;

-,

or

srlE (sianddd

H-l

drogen Electrode)

63. (s') S$ts6ritrLdridroo 66EsL65n 0 &rl Ildeo6 rrlLo sflDiCsriDE6sno (,) tO !66 sg!!di4 0rP
6R6&GEi6rn66id (+)6pna,mL srbDEsln mddtrsr 66!ir6ldpd (i) otrgqrr .el6ldi d!O6I[i; 316]@Lir
(ii) e6ntrqLliir

6rpd!b

(ii) \a)
(b)

s6lo6 e,6rao60 (' L) JEpSa ssL.:LL 6pdo s4lLGLL

3.!d;sr6ui;
t-PLJtr, th<

I !\hmrr!mdsmnuq n' trfruNs (rl orrtri Fnmcr{n o ssin ' onpfutur'

tlurv

to u(mE Do {rmnrrht'JnPlP'

re

the ro

(i) l[ti. a.id 10 FYruvi' a' (n) ouli. r. t. oraDide 0ii) Methyl a.ct Le b Eihvl a'elaL

HSC JUNE 2013

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be. (3r) Oouq tumi6'

t) 6trioldl6ltn
(in) arcnL

djlmd

(ii) 60O fidinGdu 6$lod Csui

661@d

(+).'.n[6qLrdl@ sl@ouq

nddrg 6!,,6'r,LLa?
r

(! (ii)
(iij)

carbyhmine

rea'r

Mlstard ail r ea'ton

sand Meler
the

r'ction
or

(b)

Hou'is

sttu!tuE

ftuctE

derernnred

70. ' s,"'Go '-' e i-io^,r1.

rJr

bs aeD'
o.i

c'ie

u gJ. .,," a60".., @i 3 c nML'6, '3 . .- ""s ., +d .rltsa " _ " ",, .q;. r+l'Grn'oP Po"'oe '

6fa "

"; ; ,j ' "'J .'1. ,f IEru' ir6u.$d6

":

"-;

6$o66om

6$lm3;q5'

a,dluf ii0di6rua &'add!;0

'

,;' " :' :' j'1.,',,"' i '" "..:.:':.i,''l;" :i':.,';;:: ,,r'',''

; :-::1- ;, ;,;' " T
',

' 1.,-,.,-"*''re'ocs'' l!o! ri$,, _.6d *,;'"."" od iifS'] "* rr"*'"6 sr'@e 6 6r' ,**,,t*,,tt'),,1":,,',t,., ::i;l
1 ''1

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dl '

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,]ljll
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(6) ciHr

(,\) n6irp 5flo.i CtiILDLi \'ror Lbnclloouq.n

,3 (;l'

=-'iilin

(E). Lrd6n6iD

.e.C.3 J m Jdo'6, L 3a r \!o-6, "s o"o 14

9 o:i'Dr 69ddn6l!r19am eGi,g6l!,5r

qsnoLi,

(l)sdLq; ;i:l 'rs C 6 "" oao-lr;

(ft) 6trnli s6.'.G!L Elodi.,DLGIL obgir lutrL-rAuLb sCuroLG)

6lL
6,59'

Bdr4.n6@n 616tr.inood tj.itrg 30EP05p 6;;tr6ode6nn d0GL L6l.;trcdtrLLLir 6lsgrpp!!O6lqg I 25 Cl[tr6 5trn!n

""r, | "

r''.

,-'-G'

" .S. " r"oe

. i

(6rn!n.ir sDrtr

mol fl6ndfl6n,bnd 6oL

=517
= r08

ecLrkr{ir sDrtr rmL=127

(.)

An orsani. conrFound ( ) c7tls, or oxidition ar Tir K i,r rht Presen.d ol \.()i avesc.mpound (B) ormole.ul.r iormnla CiH6Lr (R)rPdu.es lollen s ftigent (B) on h.ad1g Nith soJiDnr ac.rate in the PreQni or ictii. anh)Jrme grcs .onpound (q of.xne.nlir lotmul. ceHro' Idenha! A, u and c E\rlai'r rhE An elecbic.urrent is pa$ed tldorgl three.ells in ser'es.onh'nLng n!P..h!ety s.luiions of.opper su\ ate, sillernih.teand Poii'sium ioil . r\h nPrg]lb oI silver rDd iodnre will Le librrale!l ntile 1.25 g ol.oPP.r bclng JePoslted
's

(d)

lEtuivalenL Weight of .opper=31 7

E$ivllenl weiAhr of nlver=103

Fqulvalcnr 1\.ishi of iodi.e=

l2I

iEl

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3331

(6) cl{i

K 4..--. .i dld q4iDgdF; 6tr9pL6, +{i6,5lgcdppodLpgr c:Hio ddn!, (q aatt3 (DslaLq; csnDlb ;j:l (Bl. Lro6t6iD 6gl6trn6l!1066 e06,5C195 En6i( GDritr6,iootrqd Gdiqurb STCILGLLOLd Gldn!n!6EgE c: I crrrso: d6nD (c) G4nDir 6ldl-641!r , B DbgE c a6 g@rLdlE 6[i6d66m 66]d6156

(A) neiiD 6Ro6 Crnb6 v,o; lDsiron@rDlgd

,3

(tr) Btrnli s .G!L Sodi @pLGIL Digln ,!nL!trr]uLir srcur@Lo -?16lu 66[,.n4mn 45trd6tr6r Ur.itrg s 095099 d];nsdrn66fl6ii d0ALL 6linCtrtrLLLb ClE995!!6dlDg 1.23 6lrno 5rn!n a5Fuqtutrotr@. Aotui rpgrLb sGLtrrra .r5$!L+turgd sn6rtu;
(sr!!6eir 5D d d@L :r1.7 ,l;,6 n;; sirm 6mL =los
glcLr4.in 6s[d eoL:127
)

G)

An o8ank compound (A)(iH& or oaiLiaton it 775 K in ihe Ptrf,en.e ol \.o: Avesco'npouml (B).1nolecular n nnh c7ll6o 1B)rduc.s Lillen s rei3enr (3) on he nr8 L'iih sodinm a.elat. in the ln.sen.e 01 a.cli. 3.lil drJd gives conrpoumt (C)olnole.ul.r Iormula CrIIsO.. ldenhJr,\, B ind (: E\Phin rhc An eleckic cu,reni is piss.d through threc.ells in seriPs.onraln,ng resfe.lively solutions olcop!ersuLpharq sil!er nitQreand Poiassi!m ioJ'de l\tLit iv.ights of silvci rnd iodine Ni11be liberaidd whilel.25sof.oFPe s beu,3 JePostcll.

(d)

llituivalent Weisht of .oppo=11.7 Eqniv^lenr W8ighi.f silvei =10s

Iq!,vilcnt lveisht.l

iodine=

1271

!E