Ionic Equilibrium I

IE
IONIC EQUILIBRIUM
61.
68.
69.
73.
74.
75.
76.
78.
88.
62.
68.
81.
The pH of aqueous solution of sodium acetate is

(A) 7 (B) < 7
(C) > 7
(D) None
(C)
In a buffer solution consisting of a weak acid and its salt, the ratio of concentration of salt to
acid is increased 10 fold then the pH of the solution will
(A) Increase by one
(B) Increase ten fold
(C) Decrease by one
(D) Decrease ten fold
(A)
Which can act as a buffer?
(A) NH4Cl + NH4OH
(B) CH3COOH+CH3COONa
(C) 40 ml of 0.1 M NaCN + 20 ml of 0.1 M HCl
(D) All
(D)
What volume of 0.8 M solution contains 0.1 milimole of the solute?
(A) 100 ml
(B) 125 ml
(C) 500 ml
(D) 0.125 ml
(D)
1.5 litre of a solution of normality N and 2.5 litre of 2 M HCl are mixed together. The resultant
solution had normality 5. The value of N is
(A) 6
(B) 10
(C) 8
(D) 4
(B)
The [OH-] in 100 ml 0.015 M HCl (aq) is
(A) 510-12 M
(B) 310-10 M
(C) 6.710-13 M
(D) 210-9 M
(C)
Let the solubility of AgCl in H2O, 0.01 CaCl2, 0.01M NaCl and 0.05 M AgNO3 be S1,S2,S3,S4
respectively. The correct relationship between these quantities is
(A) S1>S2>S3>S4
(B) S1>S2= S3>S4
(C) S1> S3>S2>S4
(D) S4>S2>S3>S1
(C)
The solubility of CH3COOAg would be least amongst the following solvent in
(A) a solution of pH = 4
(B) pure water
(C) neutral solution of pH=7
(D) a solution of pH=9
(D)
The molarity of pure water is
(A) 55.6
(B) 50
(C) 100
(D) 18
(A)
The pH of a buffer is 4.325. When 0.01 mole of NaOH is added to 1 litre of it, the pH
changes to 4.625. It buffer capacity is
(A) 30
(B) 0.033
(C) 2.3
(D) 1
(B)
Ka for the acid HF is 10-6. The value of K for the reaction A- +H3O+
HA+H2O is
-6
12
(A) 10
(B) 10
(C) 10-12
(D) 106
(D)
If solubility product for the salts AB5, AB4C, AB3C2 are same then the solubility is maximum
for
(A) AB5
(B) AB4C
(C) AB3C2
(D) All are having same solubility
FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Terminal), New Delhi-16,Ph: 26515949, 26865182, 26854102, Fax: 26513942
62.
68.
81.
82.
70.
(C)
The Vant Hoft factor for 0.1 M Ca(NO3)2 solution is 2.74. The degree of dissociation is:
(A) 91.3%
(B) 87 %
(C) 100 %
(D) 74%
(B)
The PKa of HCN is 9.30. The pH of a solution prepared by mixing 2.5 mole of KCN & 2.5
mole HCN in water and making the total volume 500 ml is
(A) 9.30
(B) 7.30
(C) 10.30
(D) 8.30
(A)
The pKa of an acid whose ionization constant is 110-10 is:
(A) 10
(B) 4
(C) -10
(D) -4
(A)
The solubility product of BaCrO4 2.4 10-10 M2. The maximum concentration of Ba(NO 3)2
possible without precipitation in a 610-4 M K2CrO4 solution is
(A) 410-7M
(B) 1.21010 M
-4
(C) 610 M
(D) 310-4 M
(A)
An aqueous solution (2 litre volume) is 'C' molar w.r.t weak acid H 2A (acid constant = Ka) and
2 C molar w.r.t. H2SO4 then
K
Ka
H + OH
(A) [A2-] = a and [H2A] + [A2-] = C
(B) [A2-] =
and
=C+ [A2-]
16C
4C
2
+
Ka
K
H OH
(C) [A2-]
and
=C+ [A2-] (D) [OH-] a and [H2A] + 2[A2-] = C
16C
4C
2
(B)
Which of the following curves represents the graph of pH during titration of NaOH and HCl?
[ ] [
[ ] [
69.
pH
(B)
pH
(A)
Volume of NaOH solution
(C)
pH
pH
90.
(D)
88.
(B)
What volume of 0.8 M solution contains 0.1 milimole of the solute?
(A) 100 ml
(B) 125 ml
(C) 500 ml
(D) 0.125 ml
(D)
The density of NH4OH solution is 0.6 gm/ml. It contains 34% by weight of NH4OH. The
normality of the solution is
(A) 4.8 N
(B) 10 N
(C) 0.5 N
(D) 5.8 N
(D)
61.
A certain buffer solution contains equal concentration of X and HX. The Kb for X is 1010.
The pH of the buffer is
(A) 4
(B) 7
(C) 10
(D) 14
(A)
71.
The pH values of 1 M solutions of CH 3 CO2H (I), CH3CO2Na(II), CH3COONH4(III) and KOH

(IV) will be in the order
(A) IV >III>II>I
(B) IV>II>III>I
(C) I>III>II>IV
(D) II>I>III>IV
(B)
73.
For preparing a buffer solution of pH=6 by mixing sodium acetate and acetic acid, the ratio of
the concentration of salt and acid should be (Ka=10-5)
(A) 1:10
(B) 10:1
(C) 100:1
(D) 1:100
(B)
What is the pH value at which Mg(OH)2 begins to precipitate from a solution containing 0.10
M Mg2+ ions? [ Ksp of Mg(OH)2=110-11]
(A) 3
(B) 6
(C) 9
(D) 11
(C)
74.
85.
A solution of HCl is diluted so that its pH changes by 0.3. How does concentration of H + ion
change?
(A) 0.5 times of initial value
(B) 0.3 times of initial value
(C) 103 times increases
(D) None
(A)
86.
H A and H B are two weak monobasic acids. If their
Ka1
= 4, then their molar
Ka2
concentration ratio will be

1
2
(D) 0.25
(A) 2
(B)
(C) 4
(B)
87.
Which of the following is true for the equilibrium of the reaction?

C(s) + H2O(g)
CO(g) + H2(g)
(A) PH2 PH2 O
(B) PH2 PH2 O
(C) PH2 (PH2 O )
(D) PH
2
(P )
H2O
PCO
(A)
88.
1 cc of 0.1M HCl is added to 999 cc solution of 0.1M NaCl. The pH of the resulting solution
will be
(A) 7
(B) 4
(C) 2
(D) 1
(B)
89.
pH of a solution of the mixture of 0.1N HCl and 0.1N CH3COOH

(A) 1
(B) 2
(C) 1.7
(D) 2.7
(A)
90.
61.
64.
68.
79.
84.
86.
88.
90.
61.
62.
67.
68.
At 90C, pure water has [H+] = 106 moles/Lit. What is the value of Kw at this temperature?
(A) 106
(B) 1012
14
(C) 10
(D) 109
(B)
If a 0.1M solution of HCN is 0.01% ionised, the ionisation constant for HCN is
(A) 109
(B) 107
5
(C) 10
(D) 103
(A)
In which of the following cases the acid strength is highest
(A) Ka = 106
(B) pKa = 5
(C) pKb = 10
(D) Kb = 1011
(D)
The precipitate of CaF2(Ksp= 1.710-10) is obtained when equal volumes of which of the
following are mixed
(A) 10-4M Ca2++10-4M F(B) 10-2M Ca2++10-3 M F-2
2+
-5
(C) 10 M Ca +10 M F
(D) 10-3M Ca2+10-5 M F(A)
10 ml of 0.2 M acid is added to 250 ml of a buffer solution with pH = 6.34. The pH of the
solution becomes 6.32. The buffer capacity of the solution is
(A) 0.1
(B) 0.2
(C) 0.3
(D) 0.4
(A)
The pH of 0.1 M solution of the following salts increases in the order
(A) NaCl<NH4Cl<NaCN<HCl
(B) HCl<NH4Cl < NaCl<NaCN
(C) NaCN < NH4Cl < NaCl<HCl
(D) HCl < NaCl < NaCN < NH4Cl
(B)
For a sparingly soluble salt ApBq, the relationship of its solubility product (Ls) with its
solubility (s) is
(A) Ls =Sp+q.PP.qq
(B) Ls= SP+q. PqqP
(C) Ls= SPq.PP. qq
(D) Ls=Spq.(pq)p+q
(B)
What is the solubility of Mg(OH)2 in moles per litre if Ksp = 1.010-11?
(A) 2.4610-9
(B) 1.3610-4
-7
(C) 2.6010
(D) 1.210-10
(B)
In a buffer solution of a weak acid and its salt if the ratio of the concentration of salt to that of
the acid is increased ten times, the pH of the buffer,
(A) increases by 1
(B) increases 10 times
(C) decreases 10 times
(D) decreases by 1
(A)
Let Kw at 100C be 5.510-13 M2. If an aqueous solution at this temperature has pOH = 9. Its
nature will be
(A) acidic
(B) alkaline
(C) neutral
(D) can't say
(A)
10 ml of 0.2 M acid is added to 250 ml of a buffer solution with pH = 6.34. The pH of the
solution becomes 6.32. The buffer capacity of the solution is
(A) 0.1
(B) 0.2
(C) 0.3
(D) 0.4
(A)
0.1 M solution of three different sodium salt NaX, NaY and NaZ have pH values 7.0, 9.0 and
11.0 respectively. Correct order of dissociation constant value of these acids is
(A) KHX> KHY < KHZ
(B) KHX < HHY < KHZ
(C) KHX L KHY < KHZ
(D) KHX > KXZ > KNY
(B)
If each of the following solution in ten fold diluted the pH change will be maximum in
(A) 0.1 M HCl
74.
80.
61.
64.
65.
73.
78.
79.
80.
81.
(B) 0.1 M CH3COOH

(C) 0.1 M NH4Cl
(D) Equimolar mixture of CH3COOH & CH3COONa
(A)
% hydrolysis of 0.1 M CH3COONH4 when Ka = Kb = 1.810-5 is
(A) 0.5510-2
(B) 0.55
(C) 7.63
(D) 1.810
(B)
Which of the following statements is correct?
(A) The pH of 1.010-8 M HCl is 8
(B) The conjugate base of H2PO4- is HPO42(C) Autoprotolysis constant of water decreases with temperature
(D) When a solution of a weak monoprotic acid is titrated against a strong base at half
neutralization point pH=(1/2) pKa.
(B)
On dissolving copper sulphate in water, pH of the solution
(A) Decreases
(B) Increase
(C) May increase or decrease
(D) Remains unchanged
(A)
Which of the following solution will have pH close to 1.0?
(A) 100 ml of (M/10) HCl + 100 ml of (M /10) NaOH
(B) 55 ml of (M/10) HCl + 45 ml of (M/10) NaOH
(C) 10 ml of (M/10) HCl + 90 ml of (M /10) NaOH
(D) 75 ml of (M/5) HCl + 25 ml of (M /5) NaOH
(D)
The solubility of A2X3 is Y mol dm-3. Its solubility product is
(A) 6y4
(B) 64 y4
(C) 36 y5
(D) 108 y5
(D)
If is the fraction of HI dissociated at equilibrium is the reaction 2HI
H2 + I2. Then
starting with 2 mole of HI, the total number of moles of the reactants and products at
equilibrium are
(A) 1
(B) 1+
(C) 2
(D) 2 + 2
(C)
On adding few drops of H2SO4 to water
(A) Ionic product will increase
(B) Ionic product will decreases
(C) [OH-] will increase
(D) [OH-] will decrease
(D)
On increasing the Temperature pH of water will
(A) Decrease
(B) Increase
(C) Does not change
(D) Can't be said
(A)
Sulphide ions is alkaline solution reacts with solid sulphur to form polysulphid ions having
formula S2-, S3-2, Su-2 and So on. The equilibrium constant for the formation of S22- is 12 and
for the formation of S3-2 is 136, both form S and S2-. What is the equilibrium constant for the
formation of S3-2 form S2-2 and S?
(A) 12
(B) 11
(C) - 0.094
(D) 16
(B)
The following reactions are known to occur in the body
CO2 + H2O
H2CO3
H+ + HCO3If CO2 escapes form the system
(A) pH will decrease
(B) Hydrogen ion conc. will diminish
(C) H2CO3 conc. will remain unchanged
(D) The forward reaction will be favored
(B)
82.
83.
86.
71.
72.
73.
74.
75.
76.
77.
78.
66.
The PH of the neutralization point of 0.1 N NH4OH with 0.1 N HCl is

(A) 6
(B) 8
(C) 7
(D) 9
(A)
To a mixture of NH 4Cl and NH3in water, a further amount of NH 4Cl is added. The pH of the
mixture will
(A) Increase
(B) Decrease
(C) Remains same
(D) Be unpredictable
(B)
On dilution of weak acid solution pH
(A) Increase
(B) Decrease
(C) Does not change
(D) None of the above
(A)
Ka for HCN is 510-10 at 25C. For maintaining a constant pH =pKa, the volume of 5 M KCN
solution required to be added to 10 ml of 2M HCN solution
(A) 4 mL
(B) 7.95 mL
(C) 2 mL
(D) 9.3 mL
(A)
The solubility of AgCl (Ksp = 1.210-10) in a 0.10 M NaCl solution is
(A) 0.1 M
(B) 1.210-6 M
-9
(C) 1.210 M
(D) 1.210-10 M
(C)
Kb for the hydrolysis reaction
B++H2O
BOH + H+
-6
is 1.010 , the hydrolysis constant of the salt is
(A) 10-6
(B) 10-7
-8
(C) 10
(D) 10-9
(C)
If pKb for fluoride ion at 25C is 10,the ionisation constant of hydrofluoric acid in water at this
temperature is
(A) 10-5
(B) 10-3
-4
(C) 10
(D) 10-2
(C)
Solution prepared by dissolving equal no. of moles of HOCl (K a = 3.2 108) and NaOCl is a
buffer of pH
(A) 8.0
(B) 3.2
(C) 7.5
(D) 4.8
(C)
The pH of a solution is 2. Its pH is to be changed to 4. Then the H + concentration of the
original solution will have to be
(A) Halved
(B) Doubled
(C) Increased by 100 times
(D) Decreased by 100 times
(D)
In the hydrolytic equilibrium
A + H2O
HA + OH
Ka = 1 105. The degree of hydrolysis of 0.001 M solution of the salt is
(A) 103
(B) 104
5
(C) 10
(D) 106
(A)
Decinormal solution of CH3CO2H ionised to an extent of 1.3%. pH of the solution is (log 1.3 =
0.11)
(A) 2.89
(B) 1.945
(C) 3.40
(D) 4.98
(A)
Amongst the following hydroxides, the one which has the lowest value of K sp at ordinary
temperature (about 25C) is
70.
75.
61.
62.
(A) Mg(OH)2
(B) Ca(OH)2
(C) Ba(OH)2
(D) Be(OH)2
(D)
The pH of the neutralization point of 0.1 N ammonium hydroxide with 0.1 NHCl is
(A) 1
(B) 6
(C) 7
(D) 9
(B)
The pKa of HCN is 9.30. The pH of a solution prepared by mixing 2.5 moles of KCN and 2.5
moles of HCN in water and making up the total volume to 500 ml is
(A) 9.30
(B) 7.30
.
(C) 10 30
(D) 8.30
(A)
0.01 mole of NaOH are added to 10 litre water. How much the pH of water changes?
(A) 3
(B) 4
(C) 2
(D) 7
(B)
Determine the pH of a solution made by mixing 50 ml of 0.01 M Ba(OH) 2 with 50 ml water.
(A) 2
(B) 12
(C) 3
(D) 10
(B)
73.

(A) IV >III>II>I
(B) IV>II>III>I
(C) I>III>II>IV
(D) II>I>III>IV
(B)
82.
The Ksp of each of the following salts is 110-6. Which salt has the greatest molar solubility?
(A) MX
(B) MX2
(C) MX3
(D) All are equally soluble
(C)
In the reaction A+2B
2C+D, the initial concentration of B was 1.5 times that of A, but
equilibrium concentration of A and B are found to be equal. The equilibrium constant for the
reaction is
(A) 4
(B) 16
(C) 2
(D) 32
(A)
How much water must be added to 300 ml of 0.2 M solution of acetic acid for the degree of
dissociation of the acid to double ( Ka=1.810-5)
(A) 600 ml
(B) 300 ml
(C) 900 ml
(D) 1200 ml
(C)
M(OH)x has Ksp = 410-12 and solubility 10-4 M. x is
(A) 1
(B) 2
(C) 3
(D) 4
(B)
The degree of dissociation of water was found to be 1.810-9. Then Ka(dissociation
constant) of water is
(A) 1.810-9
(B) 1.810-16
(C) 1.010-14
(D) Can not be calculated
(B)
To a mixture of NH 4Cl and NH3 in water, a further amount of NH 4Cl is added. The pH of the
mixture
(A) Increase
(B) Decrease
(C) Remains same
(D) Be unpredictable
(B)
84.
90.
63.
65.
72.
77.
64.
69.
74.
81.
82.
85.
88.
61.
62.
64.
A buffer solution can be prepared from a mixture of

1. Sodium acetate and acetic acid in water
2. Sodium acetate and hydrochloric acid in water
3. Ammonia and ammonium chloride in water
4. Ammonia and sodium hydroxide in water
(A) 1,3,4
(B) 2,3,4
(C) 1,2,4
(D) 1,2,3
(D)
Approximate pH of 0.10 M aqueous H 2S solution having K1 and K2 for H2S at 25C are 107
and 1013 respectively is
(A) 4
(B) 5
(C) 6
(D) 8
(A)
Ksp= 1.2 105 of M2SO4 (M+ is a monovalent metal ion) at 298K. The maximum
concentration of M+ ions that could be attained in a saturated solution of this solid at 298 K is
(A) 3.46 103 M
(B) 7.0 103M
2
(C) 2.88 10 M
(D) 14.4 103M
(C)
Solution prepared by dissolving equal no. of moles of HOCl (K a = 3.2 108) and NaOCl is a
buffer of pH
(A) 8.0
(B) 3.2
(C) 7.5
(D) 4.8
(C)
The pH of a solution is 2. Its pH is to be changed to 4. Then the H + concentration of the
original solution will have to be
(A) Halved
(B) Doubled
(C) Increased by 100 times
(D) Decreased by 100 times
(D)
In the hydrolytic equilibrium
A + H2O
HA + OH
5
Ka = 1 10 . The degree of hydrolysis of 0.001 M solution of the salt is
(A) 103
(B) 104
5
(C) 10
(D) 106
(A)
Decinormal solution of CH3CO2H ionised to an extent of 1.3%. pH of the solution is (log 1.3 =
0.11)
(A) 2.89
(B) 1.945
(C) 3.40
(D) 4.98
(A)
An acid base indicator has Ka = 3 105. The acid form of the indicator is red and the basic
form of the indicator is blue. The [H +] required to change the indicator from 75% red to 75%
blue is
(A) 8 105M
(B) 9 105
(C) 1 105M
(D) 3 104 M
(D)
The solubility of CH3COOAg would be least amongst the following solvent in
(A) a solution of pH = 4
(B) pure water
(C) neutral solution of pH=7
(D) a solution of pH=9
(D)
The pH of a buffer is 4.325. When 0.01 mole of NaOH is added to 1 litre of it, the pH
changes to 4.625. It buffer capacity is
(A) 30
(B) 0.033
(C) 2.3
(D) 1
(B)
Ka for the acid HA is 10-6. The value of K for the reaction A- +H3O+
HA+H2O is
(A) 10-6
(B) 1012
65.
66.
67.
61.
62.
66.
67.
68.
72.
81.
80.
81.
(C)10-12
(D) 106
(D)
Which of the following mixture will be a buffer solution when dissolved in 500 ml. of water?
(A) 0.20 mole of aniline and 0.20 mole of HCl.
(B) 0.20 mole of aniline and 0.20 mole of NaOH
(C) 0.20 mole of NaCl and 0.20 mole of HCl
(D) 0.20 mole of aniline and 0.1 mole of HCl
(D)
pH of 0.01 (NH4)2SO4 and 0.02 M NH4OH buffer (pKa(NH4+) = 9.26) is
(A) 9.26
(B) 9.26 + log2
(C) 4.74
(D) 4.74 + log2
(A)
A solution is a mixture of 0.05M NaCl and 0.05M NaI. The concentration of iodide ion in the
solution when AgCl just starts precipitating is equal to
(Ksp(AgCl) = 1 1010, Ksp(AgI) = 4 1016)
(A) 4 106
(B) 2 108
7
(C) 2 10
(D) 8 1015
(B)
0.01 mole of NaOH are added to 10 litre water. How much the pH of water changes?
(A) 3
(B) 4
(C) 2
(D) 7
(B)
Determine the pH of a solution made by mixing 50 ml of 0.01 M Ba(OH)2 with 50 ml water.
(A) 2
(B) 12
(C) 3
(D) 10
(B)
(A) IV >III>II>I
(B) IV>II>III>I
(C) I>III>II>IV
(D) II>I>III>IV
(B)
For preparing a buffer solution of pH 6 by mixing sodium acetate and acetic acid, the ratio of
the concentration of salt and acid should be (Ka=10-5)
(A) 1:10
(B) 10:1
(C) 100:1
(D) 1:100
(B)
What is the pH value at which Mg(OH)2 begins to precipitate from a solution containing 0.10
M Mg2+ ions? [ Ksp of Mg(OH)2=110-11]
(A) 3
(B) 6
(C) 9
(D) 11
(C)
How much water must be added to 300 ml of 0.2 M solution of acetic acid for the degree of
dissociation of the acid to double ( Ka=1.810-5)
(A) 600 ml
(B) 300 ml
(C) 900 ml
(D) 1200 ml
(C)
50 ml of 0.1 M HCl is added to 50 ml 0.1 M CH3COONa solution. What will be the pH of the
final solution? [Ka(CH3COOH) = 10-5].
(A) 5
(B) 3
(C) 9
(D) 1
(A)
20 mL of 0.1N HCl is mixed with 20 mL of 0.1N KOH, pH of this solution is
(A) 0
(B) 7
(C) 2
(D) 9
(B)
If the solubility of magnesium phosphate is 'X' moles / litre, the solubility product K sp of
magnesium phosphate will be
10
82.
83.
84.
85.
86.
63.
64.
71.
70.
72.
(A) 216 X6
(B) 108X5
5
(C) 6X
(D) 27X4
(B)
In order to remove 90% of Ag+ from a solution originally 0.10M in Ag +, the [ CrO24 ] must be
(Ksp Ag2CrO4 = 2 1012)
(A) 2 1013
(B) 2 1011
(C) 2 1010
(D) 2 108
(C)
The solubility of AgCl in 0.1M KCl solution (Ksp = 1.2 1010) is
(A) 1.2 1010
(B) 1.2 106 M
(C) 1.2 109 M
(D) 1.2 104 M
(C)
Calculate the degree of hydrolysis of 0.1M solution of sodium acetate in water at 25C, K a for
CH3COOH is 1.8 105, Kw = 1 1014.
(A) 5.74 105
(B) 4.75 105
(C) 5.44 105
(D) 7.454 105
(D)
Which of the following solutions will have pH close to 1.0?
M
M
(A) 100ml of
HCl + 100ml of
NaOH
10
10
M
M
(B) 55ml of
HCl + 45ml of
NaOH
10
10
M
M
(C) 10ml of
HCl + 90ml of
NaOH
10
10
M
M
(D) 75ml of
HCl + 25ml of
NaOH
5
5
(D)
If the H+ ion concentration of a solution is increased to ten times its initial value, its pH will
(A) increase by one
(B) remain unchanged
(C) decrease by one
(D) increase by ten
(C)
Liquid NH3 ionises to a slight extent. At - 60C, its ionic product
K NH3 = [NH +4 ][NH 2 ] = 10 30
The number of NH2- ions present per c.c. of pure liquid NH3 is
(A) 3105
(B) 5102
(C) 6105
(D) 6103
(C)
The acid dissociation constant of HA is 210-5. The Kc for the reaction
CH3COOH + OHCH3COO- + H2O, is
(A) 6.6310-10
(B) 2x109
-9
(C) 1.810
(D) None of these
(B)
Determine the pH of a solution made by mixing 50 ml of 0.01 M Ba(OH)2 with 50 ml water.
(A) 2
(B) 12
(C) 3
(D) 10
(B)
The solubility of A2X3 is y mol dm-3. Its solubility product is
(A) 6y4
(B) 64y4
(C) 36y5
(D) 108y5
(D)
The pKa of acetylsalicylic and (aspirin) is 3.5. The pH of gastric juice in human stomach is
about 2-3 and the pH in the small intestine is about 8. Aspirin will be
11
73.
74.
75.
76.
77.
78.
(A) Unionized in the small intestine and in the stomach

(B) Completely ionized in the small intestine and in the stomach
(C) Ionized in the stomach and almost unionized in the small intestine
(D) Ionized in the small intestine and almost unionized in the stomach
(D)
Ka for HCN is 510-10 at 25C. For maintaining a constant pH a constant pH of the volume of
5 M KCN solution required to be added to 10 ml of 2M HCN solution
(A) 4 mL
(B) 7.95 mL
(C) 2 mL
(D) 9.3 mL
(C)
A certain weak acid has a dissociation constant 1.010-4. The equilibrium constant for its
reaction with a strong base is:
(A) 1.010-4
(B) 1.010-10
(C) 11010
(D) 1.010-14
(C)
If 50 ml of 0.2 M KOH is added to 40 ml of 0.5 M HCOOH, the pH of the resulting solution is
(Ka = 1.810-4)
(A) 3.75
(B) 5.6
(C) 7.5
(D) 3.4
(A)
The solubility of AgCl (Ksp = 1.210-10) in a 0.10 M NaCl solution is
(A) 0.1 M
(B) 1.210-6 M
(C) 1.210-9 M
(D) 1.210-10 M
(C)
Kb for the hydrolysis reaction
B++H2O
BOH + H+
is 1.010-6, the hydrolysis constant of the salt is
(A) 10-6
(B) 10-7
(C) 10-8
(D) 10-9
(C)
If pKb for fluoride ion at 25C is 10.83, the ionisation constant of hydrofluoric acid in water at
this temperature is
(A) 1.7410-5
(B) 3.5210-3
(C) 6.7510-5
79.
61.
62.
(D) 5.3810-2
(C)
A student wants to prepare a saturated solution of Ag+ ion. He has got three samples
AgCl(Ksp = 10-10), AgBr(Ksp = 10-13) and Ag2CrO4(Ksp = 10-12). Which of the above compound
will be used by him using minimum weight of prepare the saturated solution
(A) AgCl
(B) AgBr
(C) Ag2CO2
(D) All
(B)
On increasing the temperature, the pH will
(A) increase
(B) decrease
(C) remain same
(D) All , A, B & C
(B)
Which solution will have pH value closer to 1.0?
12
M
N
M
N
NaOH (B) 55 ml
HCl + 100 ml of
HCl + 45 ml of
NaOH
10
10
10
10
M
M
M
M
NaOH (D) 75 ml
NaOH
(C) 10 ml
HCl + 90 ml of
HCl + 25 ml of
10
10
5
5
(D)
The pH of the solution formed by mixing 40 ml of 0.1 m HCl and 40 ml of 0.54 m NaOH is
(A) 5
(B) 8
(C) 12
(D) 10
(C)
What volume of 1 M sodium format solution should be added to 50 ml of 0.05 m formic acid
to produce a buffer solution of pH = 4, Given
(A) 39.62 ml
(B) 62.39 ml
(C) 93.26 ml
(D) None
(A)
M
M
M
H2SO4, & 300 ml
H3PO4 & 300
The pH of mixture of 100 ml HCl, 300 ml
10
10
10
M
NaOH, Assuming that H3PO4 is tribasic acid and dissociates completely.

10
[Given that log 14.5=1.16]
(A) 1.84
(B) 0.84
(C) 2.85
(D) None
(B)
Number of OH- in 1 ml solution of pH = 13 is
(A) 110-13
(B) 6.00107
13
(C) 6.0010
(D) 6.021019
(D)
The solubility of A2X3 is "s" mol lit-1. Its solubility product is
(A) 6s4
(B) 64s4
5
(C) 36s
(D) 108s5
(D)
If the equilibrium constant of the reaction weak acid HA with strong base, NaOH is 10 9 then
pH of 0.1 M Na A is:
(A) 5
(B) 9
(C) 7
(D) 8
(B)
If E0 (Fe2+/Fe) = 0.44V & E0(Pb2+/Pb) = 0.13V, then adding powdered Pb & Fe to a
solution containing 1 M in each of Pb2+ & Fe2+ ions would result into the formation of
(A) more of Pb & Fe2+ ions
(B) more of Fe & Pb2+ions
(C) more of Fe & Pb
(D) more of Fe2+ & Pb2+ ions
(A)
(A) 100ml,
63.
64.
65.
67.
68.
69.
79.

Ionic Equilibrium I

Uploaded by

Document Information

Original Description:

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Ionic Equilibrium I

Uploaded by

Copyright:

Available Formats

IE

The pH of aqueous solution of sodium acetate is

Volume of NaOH solution

Volume of NaOH solution

Volume of NaOH solution

Volume of NaOH solution

The pH values of 1 M solutions of CH 3 CO2H (I), CH3CO2Na(II), CH3COONH4(III) and KOH

H A and H B are two weak monobasic acids. If their

concentration ratio will be

Which of the following is true for the equilibrium of the reaction?

pH of a solution of the mixture of 0.1N HCl and 0.1N CH3COOH

(B) 0.1 M CH3COOH

The PH of the neutralization point of 0.1 N NH4OH with 0.1 N HCl is

The pH values of 1 M solutions of CH 3 CO2H (I), CH3CO2Na(II), CH3COONH4(III) and KOH

A buffer solution can be prepared from a mixture of

(A) Unionized in the small intestine and in the stomach

NaOH, Assuming that H3PO4 is tribasic acid and dissociates completely.

You might also like