Physicochemical Analysis of Municipal Water in Al-Khums City, Libya
S. Khalid Hasan 1 , Fouzia Usmani 2 , Galal M. Zaiad 2 and Salem Edra 2
1 Department of Applied Chemistry, Institute of Technology, GIDA, Gorakhpur, India 2 Department of Chemistry, Al-Khums, University of Misurata, Libya *E-mail: drskhasan@yahoo.com
Abstract A laboratory study was conducted to monitor the municipal water quality of selected sites of Al-Khums city, Libya by examining the various physico-chemical parameters like pH, conductivity, TDS, chloride content, total hardness, dissolved oxygen etc. A comparison with EPA standard shows that the water is nearly suitable for drinking purpose, pH, chloride, dissolved oxygen and conductivity lye within the maximum permissible limit prescribed by EPA. But hardness and TDS ware found beyond the permissible limit of EPA standards. The high TDS and hardness is supposed to be due to sea water intrusion. Key words: TDS, conductivity, municipal water, seawater intrusion, dissolved oxygen . WaterR&D. All rights reserved
Introduction Libya is an arid nation, mostly desert, in which freshwater is perpetually scarce. Rainfall is meager-only five percent of the nation receives more than 100 mm of rain each year. Libya has long relied on ground water reserves to quench its thirst; but surging demand has stressed supply, and many coastal groundwater aquifers have become salty with an influx of seawater (Das, 2001; www.drinking-water.org). The main source of water is ground water, which is limited and over exploited. The deficit is increasing and certain measures must be taken to resolve the problem (Nair, 2006). The effect of water degradation on vegetation of Libya has been discussed in detail (Almdny, 2010). The present study includes the analysis of physicochemical parameters such as pH, conductivity, TDS, chloride content, total hardness, and Dissolved oxygen. A laboratory study was conducted to monitor the ground water quality of municipal water supplied in Al-Khums city of Libya. Al Khums is a city on the Mediterranean coast of Libya.
Physicochemical Analysis of Municipal Water in Al-Khums City, Libya S. Khalid Hasan, Fouzia Usmani, Galal M. Zaiad and Salem Edra Experimental Experiments were performed for the determination of physico-chemical parameters of water for the assessment of quality of water. Water pH, electrical conductivity, total dissolved solid (TDS), hardness and chloride content, dissolved oxygen and sodium ion content were measured. Sample Collection Water was collected from the municipal supply provided in certain parts of the city Al-Khums, Libya in the month of November (temperature 18C). The water supply in this region is basically from underground water. All the studies were carried out in Analytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Al- Khums, Misurata University, Libya
Analysis of water pH Measurement The pH of the soil was determined by using pH meter with combined electrode (Model Hanna, sensitivity 0.01). Prior to the estimation of pH, the instrument was calibrated with buffer solutions of pH 4, 7 and 10. Conductivity Measurement Electrical conductivity was determined with the help of calibrated conductivity meter (Model Jenway-4520). Total Dissolved Solid (TDS) Measurement Total dissolved solid (TDS) was determined with the help of Conductivity-TDS meter (Model Jenway-4520) and Water evaporation method. 100 ml of water sample was evaporated to dryness and then dissolved solid was calculated. Chloride Content Determination Chloride content of the water sample was determined by Mohrs method (Argentometric titration method). Total Hardness Determination Total hardness was determinate by complex-metric titration method. Determination of Dissolved Oxygen Dissolve oxygen was measured using standard procedure mentioned in APHA (APHA, 1995).
Table-1 S.No. Physico-chemical Parameters Result Recommended * limits 1 pH 7.82 6.5-8.5 2 Total dissolved Solid (TDS) by TDS meter (ppm) 2600 500 3 TDS by evaporation method (ppm) 2720 4 Total Hardness (ppm of CaCO 3 ) 1050 ** 4 Chloride Content (ppm) 136.5 250 5 Dissolved oxygen (mg/L) 7.8 4-6 6 Conductivity 4.19 mS/cm ** * Limits recommended for good quality domestic water. Limits suggested by U.S. Environmental Protection Agency; Drinking Water Regulations and Health Advisories, EPA, 822-R-94-001, May 1994. ** Limits not established.
Results and Discussion The value of pH was found 7.8 which is in the prescribed limit of EPA standards. The value of total dissolved solid was observed 2700 and 2720 ppm measuring by TDS-meter and evaporation method respectively. The TDS was very high which may be due to presence of dissolved salts of Mg, Ca, Fe etc., the values of total dissolved solid is higher than the prescribed limit of EPA standards. The presence of dissolved solids in water may affect its taste(Bruvold, 1966, 1967, 1968, 1969, 1970; Cox, 1955; Bryan,1973; Pangborn, 1972 and Pangborn, 1971). A high concentration of dissolved solids is usually not a health hazard (Rozelle,1993; Guidelines for drinking-water quality, Geneva 1996), but increased concentrations of dissolved solids can have technical effects. Dissolved solids can produce hard water, which leaves deposits and films on fixtures, and on the insides of hot water pipes and boilers. Total hardness was found 1050 ppm, In the present study water was very hard and crossed the permissible limits. It is well known that hardness is not caused by a single substance but by a variety of dissolved polyvalent metallic ions, predominantly calcium and magnesium cation, although other cation likes barium, iron, manganese, strontium and zinc also contribute. The high concentration of total hardness in water samples may be due to dissolution of 58
Physicochemical Analysis of Municipal Water in Al-Khums City, Libya S. Khalid Hasan, Fouzia Usmani, Galal M. Zaiad and Salem Edra polyvalent metallic ions from sedimentary rocks, seepage and run off from soil (Nawlakhe, 1995; Shastri, 1996) and hardness mainly originates in areas with thick top soil and limestone formation , Chloride content was 136.5 ppm. Chloride content is also in the limit of EPA standards. Dissolved oxygen, an essential parameter for life of aquatic bodies which was 7.8 ppm and it is well agreed with the permissible limit of EPA standards.
Conclusion The ground water which were taken from the various places of Al-Khums City of Libya were analyzed and the analysis reports that the water quality parameters like pH, chloride, dissolved oxygen and conductivity lye within the maximum permissible limit prescribed by EPA. But hardness and TDS ware found beyond the permissible limit of EPA standatds. The high TDS and hardness is supposed to be due to sea water intrusion. It has also been concluded that the water has no hazardous effect on human health.
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