IIT Section

Subject Topic Grand Test Paper II Date

C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

Max. Marks : 237 Duration : 3 Hrs


1. This paper consists of 57 questions with 3 parts of Chemistry, Mathematics and Physics

Each Part consist of 4 Sections
- Section I : 6 Multiple Choice Questions with one correct answer (with negative marks). A
correct answer carries 5 Marks. A wrong answer carries a penalty of 2 mark
- Section II : 5 Integer type questions. A correct answer carries 3 Marks. No negative marks.
- Section III : 6 Comprehension Type questions. A correct answer carries 3 Marks. A wrong
answer carries a penalty of 1 mark
- Section IV : 2 Matrix Match type questions. A correct answer carries 8 Marks. No
negative mark.

2. Darken the appropriate bubble using a pen in the OMR sheet provided to you. Once
entered, the answer cannot be changed. Any corrections or modifications will
automatically draw a penalty of 1 mark.

3. Use of calculators and log tables is prohibited.

4. No clarification will be entertained during the examination. Doubts in the paper can be
reported to the coordinator after the exam.

5. All the best !!


Useful Data
At. Wt.:
N = 14; O = 16; H = 1; S = 32; Cl = 35.5; Mn = 55; Na = 23; C = 12; Ag = 108; K = 39; Fe = 56; Pb = 207
Physical constants:
34
6.626 10 J.sec h

= ,
23 -1
a
N 6.022 10 mol = ,
8 -1
C 2.998 10 ms = ,
31
e
m 9.1 10 kg

=
IIT Section
Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
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I20140510

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Chemistry
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 5 marks. A wrong
answer carries a penalty of 2 marks 6 x 5 = 30

1. The shape and hybridisation of some xenon oxyfluorides are given choose the wrong set
(a)
3
2
Shape XeOF T sp d (b)
3 2
4
Square pyramidal XeOF sp d
(c)
3
2 2
Distorted trigonalbipyramidal XeO F sp d (d)
3
3 2
Octahedral XeO F sp d

2. The standard half-cell reduction potential for | Ag Ag
+
is 0.7991V at 25 c . Given the
experimental value
sp
K =
10
1.56 10

for AgCl , calculate the standard half-cell reduction

potential for the | Ag AgCl electrode
(a) 0.2192V (b) 0.2192V (c) 1.2192V (d) 1.2192V
3. Give the structure of the compound X formed in the following reaction.












(a )


O
O
(b )

OCH
3


OH
O
(c )
O
O
C H
3
H
5
C
2
(d)
O
O
OCH
3

O
O
X
2 5
(i) C H MgI
3
(ii) H O

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IIT GT 07
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4. Which is optically inactive?








5. Which of the following acids will not evolve
2
H gas on reaction with alkali metals?
(a) hydrazoic acid only (b) perxenic acid only
(c) boric acid only (d) all of these
6. Stomach acids, a dilute solution of HCl in water, can be neturalized by reaction with sodium
hydrogen carbonate.
( )
3( ) ( ) ( ) 2 2( ) aq aq aq g l
NaHCO HCl NaCl H O CO + + + . How many millilitres
of 0.125 M
3
NaHCO solution are needed to neutralize 18.0mLof 0.100M HCl ?
(a) 14.4 mL (b) 12.0 mL (c) 14.0 mL (d) 13.2mL

Section II
Integer answers type questions. Each carries 3 marks. No negative marks. 5 x 3 = 15

7. In a certain polluted atmosphere containing
3
O at steady state concentration of
8
2.0 10 , M

the hourly production of
3
O by all sources was estimated as
15
7.2 10 . M

if the only mechanism

for destruction of
3
O is the second order reaction,
3 2
2 3 . O O The rate constant for the
destruction reaction defined by the rate law for
| |
3 3 1 1
10
d O
is x Lmol s
dt

. Value of x is
C C C C
a
b
C
a
b
(a)

(b)
(c)
(d)
C C C
a
b
a
b
C C C
a
b
C
a
b
a
N
d
e
b
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8. The density of phosphorous vapour at 310 C and 775 torr is
3
2.64 / g dm . Number of
phosphorous atoms in a molecule is
9. When a compound, on reaction with
2 3
Na CO gives compound( ) B with which sulphur gives
compound( ) C . The compound ( ) C is used in photography. The number of t bonds in a
molecule of ( ) C is
10. ( )
3
6
Fe CN has

(

1.41BM = and ( )
3
2
6
Fe H O
+
(

has 5.92 . BM = The sum of unpaired
3d electrons in Fe in both the compounds is
11. An organic compound ( ) A fumes in moist air and reacts with cold water to give an acid ( ) B .
Acid( ) B reacts with
3
NH to give amide ( ) C . ( ) C on heating with
2 5
P O gives propane nitrile.
The number of functional isomers of ( ) A is

Section III
Comprehension type questions. A correct answer carries 3 marks. A wrong answer carries a
penalty of 1 mark 6 x 3 = 18
Comprehension I
In presence of metal catalyst ( ) , , Ni Pt Pd hydrogen adds to




When nickel is used as a catalyst, the reaction is carried out at 200 300 C and in presence of Pt or
Pd , the hydrogenation can occur even at room temperature. Hydrogenation reactions are
exothermic in nature. Hydrogenation follows free radical mechanism. The metal catalysts are used
in finely divided state in solvent like ethanol. These are classified as heterogenous catalysts. Both
C C



C C and
bonds
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2
H and alkene get adsorbed at the surface of metal. The less crowded alkene adsorbs with faster
rate. Both breaking of bond t of alkene and bond o of
2
H take place at metal surface. If palladium
is precipitate at the surface of calcium carbonate and is treated with quinolone it becomes deactivated
for adsorption of alkenes. But it can effectively catalyse hydrogenation of C C . The alkene can
adsorb at the surface of poisoned metal catalyst and syn addition of hydrogen atoms take place.
If sodium or lithium metals dissolved in liquid ammonia are used with alkynes then the metal
transfers its electrons to t framework of C C bond and an anion radical is formed. Liquid
ammonia provides H atom and a vinylic radical is formed

12. Which of the following involves homogeneous reduction?
(a)
2
/
2 2 3 3
H Ni
CH CH CH CH =
(b)
3( )
/
3 3 3 3 2
l
Na NH
CH C C CH CH CH CH CH NaNH = +
(c)
2 3
/ / /
3 3
H Pd CaCO Quinoline
CH COCl CH CHO
(d)
2 4
/ / /
3 3 2
H Pd BaSO quinoline
CH C CH CH CH CH =


13. The relative rate of catalytic hydrogenation of following alkenes is






(a) I >IV>III >II (b) II >III >IV>I (c) III >IV>I >II (d) II >IV>I >III


(I)
(II) (III)
(IV)






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14. In which case the reaction is most exothermic with
2
/ ? H Ni









Comprehension II
On adding copper sulphate to an aqueous solution of a compound ( ) A a brown precipitate is
obtained which turns white on addition of excess of sodium thiosulphate solution. When Ag
+
ion
solution is added to the aqueous solution of ( ) A . A yellow curdy precipitate is obtained which is
insoluble in ammonium hydroxide

15. The yellow curdy ppt. which is insoluble in
4
NH OH is of
(a) AgBr (b) AgCl (c) AgI (d) none of these

16. The compound (A) is
(a) KI (b) KCl (c) NaCl (d) NaBr

17. The brown ppt. which turns white on addition of excess of
2 2 3
Na S O solution is of
(a)
2
CuI (b)
2 2
Cu I (c)
2
CuCl (d)
2 2
Cu Cl




(a) (b)
(c)
(d)
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Section IV
Matrix Match type questions (4 rows per matrix type, 2 marks per row) 2 x 8 = 16
18. Matrix Match I

Column I (Complex)

Column II (Magnetic Moment in B. M)

(A)

( )
4
6
Fe CN

(


(p)

1.73

(B)
( )
3
2
6
Ti H O
+
(


(q) 5.91

(C)
( )
2
2
6
Ni H O
+
(


(r) 0.00

(D)
| |
3
6
FeF


(s) 2.83




19. Matrix Match II

Column I

Column II

(A)

zero

(p)

1 1
mol lit s


(B) first

(q)
1 1
mol lit s


(C) second

(r)
1
s

(D) third

(s)
2 2 1
mol lit s




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IIT GT 07
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Mathematics
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 5 marks. A wrong
answer carries a penalty of 2 marks 6 x 5 = 30

20. Two cards are selected randomly from a pack of 52 cards. The probability that the first is a club
and the second is not a queen is
(a)
82
221
(b)
51
221
(c)
1
221
(d)
4
17

21. Let 0 x > . If the angle between the vectors ( )
2

log 6 3 a c x i j k = + and
( ) ( )
2 2

log 2 2 log b x i j c x k = + + is obtuse, then c

belongs to
(a) ( ) 0, (b) ( ) , 0 (c)
4
, 0
3
| |

|
\ .
(d) ( )
2
1, 0 0,
3
| |

|
\ .

22. If
2 2 2
2 0 a b c ab + = , then the point of concurrency of the family of straight lines
0 ax by c + + = lies on the line
(a) y x = (b) 1 y x = + (c) y x = (d) 1 x y + =
23. Let , , , x y z n be positive integers and let 6 n > . If 2 3 x y z n + + = , then the number of ordered
triplets ( ) , , x y z satisfying the above equation is
(a)
6
n
n
C

(b)
3
n
n
C

(c)
2
3
n
C
+
(d) none of these

24. The quadratic equation
( )( )
( )( )
( )( )
( )( )
( )( )
( )( )
1
x b x c x c x a x a x b
b a c a c b a b a c b c
+ + + + + +
+ + =

has
(a) two real and distinct roots (b) two equal roots
(c) complex roots (d) infinite roots

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25. Let , z w

be complex numbers such that 0 z iw + =

and argzw t = . Then arg z equals
(a)
4
t
(b)
2
t
(c)
3
4
t
(d)
5
4
t


Section II
Integer answers type questions. Each carries 3 marks. No negative marks. 5 x 3 = 15

26. Suppose a matrix A satisfies the equation
2
5 7 0 A A I + = . If
5
, A aA bI = + then the value of
2 3 1450 a b is
27. Let [ ] x denote the greatest integer x s . If the period of the function
| | | |
sin cos tan
12 4 3
x x x t t t | | | |
| |
+ +
| | |
\ .
\ . \ .
is , then the value of 201 4820 is
28. If
( )
2 3 97
1
97
lim
1 x
x x x x
l
x
+ + + +
=

, then 4760 l is equal to

29. A balloon is in the form of a right circular cylinder of radius 1.5 m

and length 4 m and is
surmounted by hemispherical ends. If the radius is increased by 0.01m and the length by
0.055 m, the percentage change in the volume of the balloon is % abcd . If

abcd is equal to
2380 k + , then k =
30. A special dice is so constructed that the probabilities of throwing 1, 2, 3, 4, 5 and 6 are
1 1 2 1 1 1 2
, , , ,
6 6 6 6 6
k k k k k + +

and
1
6
k +
respectively. If two such dice are thrown and the
probability of getting a sum equal to 9 lies between
1
9
and
2
9
, then the number of integral
solutions of k is



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Section III
Comprehension type questions. A correct answer carries 3 marks. A wrong answer carries a
penalty of 1 mark 6 x 3 = 18

Comprehension I
Eulers substitution
Integrals of the form ( )
2
( , ) R x ax bx c dx + +
}
are calculated with the aid of one of three Euler
substitutions
1.
2
ax bx c t x a + + =

if 0 a >
2.
2
ax bx c tx c + + = if 0 c >
3. ( )
2
ax bx c x t o + + =

if ( )( )
2
ax bx c a x x o | + + = , o | = , if o

is a real root of

2
0 ax bx c + + =
31. Which of the following functions does not appear in the primitive of
2
1
1 2 2 x x + + +

if t is a function of x ?
(a) log 1
e
t + (b) log 2
e
t + (c)
1
2 t +
(d) none of these

32. Which of the following functions does not appear in the primitive of
2
1
dx
x x x + +
if t is a
function of ? x
(a) log
e
t (b) log 2
e
t (c) log 1
e
t (d) log 1 t +


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33. Which of the following substitutions can be used for evaluating
2
7 10
xdx
x x
}
?
(a)
2
2
5 2
1
t
x
t
+
=
+
(b)
2
2
5
2
t
x
t

=
+
(c)
2
2
2 5
3 1
t
x
t

=

(d) none of these

Comprehension II
Consider the relation
2 2
4 5 6 1 0, l m l + + = where , l meR and let the line 1 0 lx my + + =

touch a
fixed circle C

34. The centre and radius of C are
(a) ( ) 2, 0 , 3 (b) ( ) 3, 0 , 3 (c) ( ) 3, 0 , 5 (d) none of these

35. Tangents PA and PB are drawn to C from the points P on the line 1 0 x y + = . Then the
chord of contact AB

passes though the fixed point

(a)
1 5
,
2 2
| |

|
\ .
(b)
1 4
,
3 3
| |
|
\ .
(c)
1 3
,
2 2
| |

|
\ .
(d) none of these

36. The number of tangents which can be drawn from the point ( ) 2, 3 to the circle C is
(a) 0 (b) 1 (c) 2 (d) 1 or 2





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Section IV
Matrix Match type questions (4 rows per matrix type, 2 marks per row) 2 x 8 = 16
37. Matrix Match I
Column I Column II
(A)
Let 2 7 . z i z i k + = The values of k for which the

locus of z is an ellipse are


(p) 7
(B) For any complex number , z the minimum value of
2 z z i + is
(q) 8
(C)
Let 3 4 z z i k =
.
The values of k for which the
locus of z is a hyperbola, are
(r) 2
(D)
Let ( ) 3 4 ,
50
k
z i az az b + = + + where 3 4 . a i = + Then
the locus of z is a hyperbola if k =
(s) 4
(t) 5

38. Matrix Match II
Let A and B are two independent events such that ( ) ( )
1 1
, .
3 4
P A P B = =
Column I

Column II

(A)

( ) P A B =

(p)

1
12

(B) ( )
P A A B =

(q)
1
2

(C) ( )
P B A B ' ' =

(r)
2
3

(D) ( )
P A B ' =

(s) 0


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Physics
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 5 marks. A wrong
answer carries a penalty of 2 marks 6 x 5 = 30

39. A projectile of mass 3 m explodes at highest point of its path. It breaks into three equal parts.
One part retraces its path; the second one comes to rest. The range of the projectile was 100 m. If
no explosion would have taken place, the distance of the third part from the point of projection
when it finally lands on the ground is
(a) 100 m (b) 150 m (c) 250 m (d) 300 m

40. Three capillary tubes of same radius 1 cm but of lengths 1m, 2m and 3m are fitted horizontally to
the bottom of a long cylinder containing a liquid at constant pressure flowing through these
tubes. What is the length of a single tube which can replace the three capillaries
(a)
6
11
m (b) 6m (c) 5 m (d)
13
4
m


41. 5.6 litre of helium gas at STP is adiabatically compressed to 0.7 litres. Taking the initial
temperature to be
1
T the work done in this process is
(a)
1
9
8
RT (b)
1
3
2
RT (c)
1
15
8
RT (d)
1
9
2
RT


42. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561
o
A . The
wave length of second spectral line in the Balmer series of singly-ionized helium atom is
(a) 1215
o
A (b) 1640
o
A (c) 2430
o
A (d) 4687
o
A
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43. A 2 F capacitor is charged as shown in figure. The
percentage of its stored energy dissipated after the switch S
is turned to position 2 is
(a) 6%
(b) 20%
(c) 75%
(d) 80%
44. A particle of charge q and mass m moves in a circular orbit of radius r with angular speed e .
The ratio of the magnitude of its magnetic moment to that of its angular momentum depends on
(a) e and q (b) e , q and m (c) q and m (d) e and m

Section II
Integer answers type questions. Each carries 3 marks. No negative marks. 5 x 3 = 15

45. A car leaves station X for station Y every 10 min. The distance between X and Y is 60 km. The
car travels at speed 60 km/h. A man drives a car from Y towards X at speed 60 km/h. If he
starts the moment when first car leaves station X , how many cars would he meet on route?

46. Power supplied to a particle of mass 2 kg varies with time as
2
3

2
t
P W = . Here t is in second. If
velocity of particle at 0 t = is 0 v = . The velocity of particle at time 2 t s = in m/s will be
47. In Youngs double slit experiment
4
10
d
D

= ( d = distance between slits, D = distance of screen
from the slits). At a point P on the screen resulting intensity is equal to the intensity due to
individual slit
o
I . Then the distance of point P from the central maximum in mm is (Wave
length of source is 6000A
o
= )

2
s
1
2 F
8 F
V
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48. Mean free path ( ) in a fission reaction is the average distance covered by a neutron between two
fissions. Generation of nearly 200 neutrons are needed to fission all the nuclei in 10kg of U
235
92
.
If cm = 4 and the fastest moving neutrons generated in a fission reaction have an energy of
2MeV, then the time for 200 neutron generation is found to be p

7
10 seconds. Find ' ' p .


49. Some magnetic flux is changed from a coil of resistance 10O. As a
result an induced current is developed in it, which varies with time
as shown in figure. the magnitude of change in flux through the coil
in webers is


Section III
Comprehension type questions. A correct answer carries 3 marks. A wrong answer carries a
penalty of 1 mark 6 x 3 = 18
Comprehension I
Two rods 1 and 2 are released from rest as shown in figure. Given :
1
4 l l = ,
1
2 m m = ,
2
2 l l = and
2
m m = . There is no friction between the
two rods. If o be the angular acceleration of rod 1 just after the rods
are released. Then

50. What is the normal reaction between the two rods at this instant?
(a)
16 3mlo (b)
4
3
mlo
(c)
32
3 3
mlo
(d)12 3mlo

( ) t s
4
0.1
( ) i amp
B
l
A
2
1
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51. What is the horizontal force on rod 1 by hinge A at this instant?
(a)
32 12 3
3 3
mlo
| |

|
|
\ .
(b)
16 2 3
3
mlo
| |

|
|
\ .
(c) (14 2 3)mlo + (d) 3mlo

52. What is initial angular acceleration of rod 2 in terms of the given parameters in the question?
(a)
2 3
2 3
2
g
l
o
| |
+
|
|
\ .
(b)
3 3
3
g
l
o
| |

|
|
\ .
(c)
6 3
5 3
8
g
l
o
| |
+
|
|
\ .
(d)
3 3 8
8
3
g
l
o
| |

|
|
\ .


Comprehension II
(i) When a conducting rod of length l is moved in a magnetic field B , a potential difference V Bvl =
is developed across its two ends. Here v is the velocity of the rod. Condition is that, the three vectors
, B v and I should be mutually perpendicular to each other.
(ii) ,
R C
q
V iR V
C
= = and
L
di
V L
dt
=

(iii) Magnetic force on a current carrying conductor in a magnetic field is given by ( )
m
F i l B = .
In the figure shown a conducting wire PQ of length 1 , l m = is moved
in a uniform magnetic field 4 B T = with constant velocity 2 / v m s =
towards right. Given : 2 , 1 R C F = O = and 4 L H = .
Current through resistance, capacitor and inductor at any time t are
1 2
, I I and
3
I respectively. Current through wire PQ is I .

53. At 2 t s = , the value of
3
I is
(a) 0 (b) 2A (c) 4 A (d) 6 A
54. Find the force required to move the wire with the given constant velocity of 2m/s at 2 t s =
(a) 8 N (b) 16 N (c) 24 N (d) 32 N

R
C L V
B
P
Q
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55. At 2 t s = , suppose P is the total power generated by the applied force,
1
P the power stored in
magnetic field of inductor and
2
P the power dissipated in resistance, Then
(a) 72 / P J s = (b)
1
40 / P J s = (c)
2
32 / P J s = (d)
2
80 / P J s =

Section IV
Matrix Match type questions (4 rows per matrix type, 2 marks per row) 2 x 8 = 16
56. Matrix Match I
A charged particle with some initial velocity is projected in a region, where non-zero electric
and / or magnetic fields are present. In column I, information about the existence of electric
and / or magnetic field and direction of initial velocity of charged particle are given, while in
column II the probable path of the charged particle is mentioned. Match the entries of Column I
with the entries of Column II.

Column I Column II
(A)
0, 0, E B = = and initial velocity of the
particle is at any angle with B
(p) Straight line
(B)
0, 0, E B = = and initial velocity of the
particle is at any angle with E
(q) Parabola
(C)
0, 0, E B E B = = and initial
velocity of the particle is perpendicular
to both
(r) Circular
(D)
0, 0, E B E = = perpendicular to B and
initial velocity of the particle is
perpendicular to both E and B
(s) Helical path with non-uniform pitch

IIT Section
Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

Ace Insignia Rough Work Page 18

F
Ring

F
Disc

F
Solid Cylinder
R/2
57. Matrix Match II
Assume sufficient friction to prevent slipping.
Column I Column II
(A)




(p) Body accelerates forward
(B)




(q) Rotation about the centre of mass is
clockwise
(C)





(r) Friction force acts backward
(D)




(s) No friction acts


F
Solid Cylinder
R/2