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Guess Paper
Class XII
Subject CHEMISTRY

CHEMICAL KINETICS


Q.1 A reaction is 50% complete in 30 minutes and 75% complete
in 60 minutes. What is the order of reaction?

Q.2 State two factors that affect the rate of a chemical reaction.

Q.3 Define the activation energy of a reaction.

Q.4 3H
2
+ N
2
2NH
3
how are d[H
2
]/dt and d[NH
3
]/dt are related.

Q.5 Under what condition the rate of a reaction is equal to its rate
constant?

Q.6 A first order reaction is 20% complete in 10 minutes.
Calculate time for 75% completion.

Q.7 During nuclear explosion one of the product is
90
Sr with half
life of 28.1 year. If 1g of
90
Sr was absorbed in bones of a newly
born baby how much of it will remain after 10 years and 60 years.

Q.8 The rate constant for decomposition of a hydrocarbon is 2.418
x 10
-5
s
-1
at 546 K. if the energy of activation is 179.9 k j/mol what
will be pre exponential factor?





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Q.9 The activation energy for 2HI -> H
2
+ I
2
is 209.5 k j mol
-1
at
581 K. calculate fraction of molecules of reactants having energy
equal to or greater than activation energy?

Q.10 The rate constant for the first order decomposition of H
2
O
2

is given by following equation
Log k = 14.34 1.25 x 10
4
K/T
Calculate E
a
and at what temperature t
1/2
will be 256 minutes.

Q.11 Time required to decompose SO
2
Cl
2
to half of its initial
amount is 60 minutes. If the decomposition is a first order
reaction, calculate the rate constant of the reaction.
Q.12 The rate of a reaction quadruples when the temperature
changes from 293 K to 313 K. Calculate the energy of activation of
the reaction assuming that it does not change with temperature.
Q.13 A first order decomposition reaction takes 40 minutes for
30% decomposition. Calculate its t
1/2
value.
Q.14 The half life for decay of radioactive
14
C is 5730 years.
An archaeological sample containing wood has only 80 % of the
14
C
activity as found in living trees. Calculate the age of the sample.
Q.15 What do you mean by a photochemical reaction?
Give one example.

RAHUL CHEMISTRY CLASSES,
BRANCH I-TURNER ROAD, DEHRADUN
BRANCH II- TAPKESHWAR ROAD, DEHRADUN