SL IB Final Exam 2013

Multiple Choice
Identify the choice that best completes the statement or answers the question.
____ 1. Which of the following measurements contains two significant figures?
a
.
0.004 00 L c
.
0.000 44 L
b
.
0.004 04 L d
.
0.004 40 L
____ 2. Which of the following measurements is expressed to three significant figures?
a
.
0.007 m c
.
7.0 10 !m
b
.
7077 mg d
.
0.070 mm
____ . "ow man# significant figures are in the measurement 40$%00 mg?
a
.
two c
.
four
b
.
three d
.
fi&e
____ 4. 'f ( is the s#mbol for an element$ which two of the following s#mbols represent isotopes of the same
element?
1. ( 2. ( . ( 4. (
a
.
1 and 2 c
.
1 and 4
b
.
and 4 d
.
2 and
____ %. "ow is the number of neutrons in the nucleus of an atom calculated?
a
.
)dd the number of electrons and protons together.
b
.
*ubtract the number of electrons from the number of protons.
c
.
*ubtract the number of protons from the mass number.
d
.
)dd the mass number to the number of electrons.
____ +. Which of the following statements is ,-. true?
a /rotons ha&e a positi&e charge.
.
b
.
(lectrons are negati&el# charged and ha&e a mass of 1 amu.
c
.
.he nucleus of an atom is positi&el# charged.
d
.
,eutrons are located in the nucleus of an atom.
____ 7. "ow does the energ# of an electron change when the electron mo&es closer to the nucleus?
a
.
't decreases. c
.
't sta#s the same.
b
.
't increases. d
.
't doubles.
____ 0. When an electron mo&es from a lower to a higher energ# le&el$ the electron ____.
a
.
alwa#s doubles its energ#
b
.
absorbs a continuousl# &ariable amount of energ#
c
.
absorbs a 1uantum of energ#
d
.
mo&es closer to the nucleus
____ 2. 'f the spin of one electron in an orbital is cloc!wise$ what is the spin of the other electron in that orbital?
a
.
3ero c
.
countercloc!wise
b
.
cloc!wise d
.
both cloc!wise and countercloc!wise
____ 10. Which t#pe of electromagnetic radiation includes the wa&elength 10 m?
a
.
gamma ra# c
.
radio wa&e
b
.
microwa&e d
.
&isible light
____ 11. Which of the following elements is in the same period as phosphorus?
a
.
carbon c
.
nitrogen
b
.
magnesium d
.
ox#gen
____ 12. -f the elements 4e$ "g$ 5$ and .e$ which is a representati&e element?
a
.
4e c
.
5
b
.
"g d
.
.e
____ 1. )tomic si3e generall# ____.
a
.
increases as #ou mo&e from left to right across a period
b
.
decreases as #ou mo&e from top to bottom within a group
c
.
remains constant within a period
d
.
decreases as #ou mo&e from left to right across a period
____ 14. 'n which of the following sets are the charges gi&en correctl# for all the ions?
a
.
,a $ 6g $ )l
c
.
7b $ 8a $ /
b
.
9 $ *r $ -
d
.
, $ - $ 4
____ 1%. "ow man# electrons does sil&er ha&e to gi&e up in order to achie&e a pseudo:noble:gas electron
configuration?
a
.
1 c
.

b
.
2 d
.
4
____ 1+. "ow man# electrons does nitrogen gain in order to achie&e a noble:gas electron configuration?
a 1 c
. .
b
.
2 d
.
4
____ 17. "ow does ox#gen obe# the octet rule when reacting to form compounds?
a
.
't gains electrons.
b
.
't gi&es up electrons.
c
.
't does not change its number of electrons.
d
.
-x#gen does not obe# the octet rule.
____ 10. What does the term coordination number in ionic cr#stals refer to?
a
.
the total number of &alence electrons in an atom
b
.
the number of oppositel# charged ions surrounding a particular ion
c
.
the number of atoms in a particular formula unit
d
.
the number of li!e:charged ions surrounding a particular ion
____ 12. Which of the following elements can form diatomic molecules held together b# triple co&alent bonds?
a
.
carbon c
.
fluorine
b
.
ox#gen d
.
nitrogen
____ 20. Where are the electrons most probabl# located in a molecular bonding orbital?
a
.
an#where in the orbital
b
.
between the two atomic nuclei
c
.
in stationar# positions between the two atomic nuclei
d
.
in circular orbits around each nucleus
____ 21. What t#pe of h#bridi3ation occurs in the orbitals of a carbon atom participating in a triple bond with another
carbon atom?
a
.
c
.
b
.
d
.
____ 22. What are the wea!est attractions between molecules?
a
.
ionic forces c
.
co&alent forces
b
.
;an der Waals forces d
.
h#drogen forces
____ 2. What is the correct name for the ,

ion?
a
.
nitrate ion c
.
nitride ion
b
.
nitrogen ion d
.
nitrite ion
____ 24. 'n which of the following is the name and formula gi&en correctl#?
a
.
sodium oxide$ ,a- c
.
cobaltous chloride$ <o<l
b
.
barium nitride$ 8a, d
.
stannic fluoride$ *n4
____ 2%. Which of the following compounds contains the lead=''> ion?
a
.
/b- c
.
/b2-
b
.
/b<l4 d
.
/b2*
____ 2+. Which set of chemical name and chemical formula for the same compound is correct?
a
.
iron=''> oxide$ 4e -
c
.
tin=';> bromide$ *n8r
b
.
aluminum fluorate$ )l4
d
.
potassium chloride$ 9 <l
____ 27. What is the formula for h#drosulfuric acid?
a
.
" *
c
.
"*-
b
.
" *-
d
.
" *
____ 20. Which of the following pairs of substances best illustrates the law of multiple proportions?
a
.
" and -
c
.
<a<l and <a8r
b
.
/ - and /"
d
.
,- and ,-
____ 22. "ow man# atoms are in 0.07% mol of titanium?
a
.
1.2 10
:2%
c
.
+.4 10
b
.
2.2 10
d
.
4.% 10
____ 0. What is the mass of sil&er in .4 g )g,- ?
a
.
0.02% g c
.
2.2 g
b
.
0.+4 g d
.
.0 g
____ 1. Which combination of temperature and pressure correctl# describes standard temperature and pressure$ *./?
a
.
0 < and 101 !/a c
.
0 < and 22.4 !/a
b
.
1 < and 0 !/a d
.
100 < and 100 !/a
____ 2. What is the percent composition of chromium in 8a<r- ?
a
.
4.07? c
.
20.%?
b
.
2.47? d
.
2%.2?
____ . 'f 20.0 grams of <a combines completel# with 1+.0 grams of * to form a compound$ what is the percent
composition of <a in the compound?
a
.
1.2%? c
.
44.4?
b
.
20.0? d
.
%%.+?
____ 4. What is the percent b# mass of carbon in acetone$ < " -?
a
.
20.7? c
.
1.+1?
b
.
+2.1? d
.
0.0?
____ %. <hemical e1uations ____.
a
.
describe chemical reactions
b
.
show how to write chemical formulas
c
.
gi&e directions for naming chemical compounds
d
.
describe onl# biological changes
____ +. 'f #ou rewrite the following word e1uation as a balanced chemical e1uation$ what will the coefficient and
s#mbol for fluorine be?
nitrogen trifluoride nitrogen fluorine
a
.
+4
c
.
+4
b
.
4
d
.
4
____ 7. Which of the following statements is ,-. true about what happens in all chemical reactions?
a
.
.he wa#s in which atoms are @oined together are changed.
b
.
,ew atoms are formed as products.
c
.
.he starting substances are called reactants.
d
.
.he bonds of the reactants are bro!en and new bonds of the products are formed.
____ 0. When the e1uation 9<l- =s> 9<l=s> A - =g> is balanced$ the coefficient of 9<l- is ____.
a
.
1 c
.

b
.
2 d
.
4
____ 2. 'n order to predict whether or not a single:replacement reaction ta!es place$ #ou need to consult a chart that
shows the ____.
a
.
periodic table
b
.
acti&it# series of metals
c
.
common pol#atomic ions
d
.
ionic charges of representati&e elements
____ 40. 'n order for the reaction 2)l +"<l 2)l<l " to occur$ which of the following must be true?
a
.
)l must be abo&e <l on the acti&it# series.
b
.
)l must be abo&e " on the acti&it# series.
c
.
"eat must be supplied for the reaction.
d
.
) precipitate must be formed.
____ 41. 'n the acti&it# series of metals$ which metal=s> will displace h#drogen from an acid?
a
.
onl# metals abo&e h#drogen c
.
an# metal
b
.
onl# metals below h#drogen d
.
onl# metals from Li to ,a
____ 42. .he complete combustion of which of the following substances produces carbon dioxide and water?
a
.
< "
c
.
<a"<-
b
.
9 <-
d
.
,-
____ 4. Which of the following is an ',<-77(<. interpretation of the balanced e1uation shown below?
2*=s> A - =g> 2*- =g>
a
.
2 atoms * A molecules - 2 molecules *-
b
.
2 g * A g - 2 g *-
c
.
2 mol * A mol - 2 mol *-
d
.
none of the abo&e
____ 44. "ow man# moles of " /- are produced when 71.0 g / - reacts completel# to form " /- ?
a
.
0.0+ % mol c
.
4.00 mol
b
.
1.00 mol d
.
1+.0 mol
____ 4%. Which of the following statements is true about the following reaction?
,a"<- =aq> A < " - =aq> <- =g> A " -=s> A,a < " - =aq>
a
22.4 L of <- =g> are produced for e&er# liter of < " - =aq> reacted.
.
b
.
1 mole of water is produced for e&er# mole of carbon dioxide produced.
c
.
+.02 10 molecules of ,a < " - =aq> are produced for e&er# mole of ,a"<- =aq>
used.
d
.
%4 g of water are produced for e&er# mole of ,a"<- =aq> produced.
____ 4+. Blucose$ < " - $ is a good source of food energ#. When it reacts with ox#gen$ carbon dioxide and water are
formed. "ow man# liters of <- are produced when 12+ g of glucose completel# react with ox#gen?
< " - =s> A +- =g> +<- =g> A +" -=l> A +7 !cal
a
.
4.21 L c
.
1%.7 L
b
.
%. L d
.
24.1 L
____ 47. 6ethane and h#drogen sulfide form when h#drogen reacts with carbon disulfide. 'dentif# the excess reagent
and calculate how much remains after + L of " reacts with 12 L of <* .
4" =g> A <* =g> <" =g> A 2" *=g>
a
.
L <*
c
.
2 L <*
b
.
+ L <*
d
.
12 L "
____ 40. Which of the following would be the limiting reagent in the reaction shown below?
2" =g> A - =g> 2" -=g>
a
.
%0 molecules of "
b
.
%0 molecules of -
c
.
,either a nor b is limiting.
d
.
8oth a and b are considered limiting reagents.
____ 42. Which of the following statements is part of the !inetic theor#?
a
.
.he particles of a gas mo&e independentl# of each other.
b
.
.he particles in a gas mo&e rapidl#.
c
.
.he particles in a gas are relati&el# far apart.
d all of the abo&e
.
____ %0. Which of the following statements is ,-. true$ according to the !inetic theor#?
a
.
.here is no attraction between particles of a gas.
b
.
-nl# particles of matter in the gaseous state are in constant motion.
c
.
.he particles of a gas collide with each other and with other ob@ects.
d
.
)ll of the statements are true.
____ %1. .he a&erage !inetic energ# of water molecules is greatest in ____.
a
.
steam at 100 < c
.
li1uid water at 7 9
b
.
li1uid water at 20 < d
.
ice at 0 <
____ %2. Which of the following will e&aporate the fastest?
a
.
water at 0 <
b
.
water at 20 <
c
.
water at 40 <
d
.
)ll samples will e&aporate at the same rate.
____ %. 'f energ# is added to a boiling li1uid$ what happens to the temperature of the li1uid?
a
.
't increases. c
.
't does not change.
b
.
't decreases. d
.
.he change cannot be determined.
____ %4. What is the pressure when a li1uid is boiling at its normal boiling point?
a
.
0 !/a c
.
202 !/a
b
.
101. !/a d
.
%0% !/a
____ %%. What is the specific heat of a substance if 1%+0 cal are re1uired to raise the temperature of a 12:g sample b#
1% <?
a
.
0.0
c
.
0.22
b
.
0.
d
.
1.
____ %+. Which of the following substances has the highest specific heat?
a
.
steel c
.
alcohol
b
.
water d
.
chloroform
____ %7. .he amount of heat transferred from an ob@ect depends on which of the following?
a
.
the specific heat of the ob@ect c
.
the mass of the ob@ect
b
.
the initial temperature of the ob@ect d
.
all of the abo&e
____ %0. <alculate H for the following reaction.
< " =g> A " =g> < " =g>
= H for < " =g> C %2.% !DEmolF H for < " =g> C G04.7 !DEmol>
a
.
G17.2 !D c
.
2.2 !D
b
.
G2.2 !D d
.
17.2 !D
____ %2. When 1.0 g of solid ,a-" = H C G44%.1 !DEmol> dissol&es in 10 L of water$ how much heat is released?
a
.
44%.1 !D c
.
11.1 D
b
.
40%.1 !D d
.
11.1 !D
____ +0. Wh# does a higher concentration ma!e a reaction faster?
a
.
.here are more collisions per second onl#.
b
.
<ollisions occur with greater energ# onl#.
c
.
.here are more collisions per second and the collisions are of greater energ#.
d
.
.here are more collisions per second or the collisions are of greater energ#.
____ +1. Wh# does a catal#st cause a reaction to proceed faster?
a
.
.here are more collisions per second onl#.
b
.
.he collisions occur with greater energ# onl#.
c
.
.he acti&ation energ# is lowered onl#.
d
.
.here are more collisions per second and the collisions are of greater energ#.
____ +2. Which of the following substances act as catal#sts in the bod#?
a
.
carboh#drates c
.
lipids
b
.
nucleic acids d
.
en3#mes
____ +. .he melting of ice at temperatures abo&e 0 < ____.
a
.
liberates heat c
.
is not fa&orable
b
.
is not spontaneous d
.
is endothermic
____ +4. When nitrous oxide is con&erted to nitrogen and ox#gen$ what is the term used to describe the ox#gen atoms
formed?
a
.
reactants c
.
acti&ated complexes
b
.
products d
.
intermediates
____ +%. Which h#droxide compound #ields the lowest concentration of h#droxide ions in a1ueous solution?
a
.
sodium h#droxide c
.
calcium h#droxide
b
.
potassium h#droxide d
.
magnesium h#droxide
____ ++. Which compound can act as both a 8rHnsted:Lowr# acid and a 8rHnsted:Lowr# base?
a
.
water c
.
sodium h#droxide
b
.
ammonia d
.
h#drochloric acid
____ +7. 'n the reaction <- A " - "<- A -" $ the carbonate ion is acting as a=n> ____.
a
.
)rrhenius base c
.
8rHnsted:Lowr# base
b
.
)rrhenius acid d
.
8rHnsted:Lowr# acid
____ +0. 'f the h#drogen ion concentration of a solution is 10 M$ is the solution acidic$ al!aline$ or neutral?
a
.
acidic c
.
neutral
b
.
al!aline d
.
.he answer cannot be determined.
____ +2. 'f an acid has a K C 1.+ 10 $ what is the acidit# of the solution?
a
.
acidic c
.
neutral
b
.
basic d
.
.he answer cannot be determined.
____ 70. Which base is strong$ but ne&er concentrated?
a
.
magnesium h#droxide c
.
ammonia
b
.
sodium h#droxide d
.
water
____ 71. What is the oxidi3ing agent in the following reaction?
' A 6n- ' A 6n-
a
.
'
c
.
'
b
.
6n-
d
.
6n-
____ 72. Which element decreases its oxidation number in the following reaction?
8i<l A ,a *- 2,a<l A 8i*-
a
.
bismuth
b
.
chlorine
c
.
ox#gen
d
.
,o element decreases its oxidation number.
____ 7. What is the reduction half:reaction for the following unbalanced redox e1uation?
<r - A ," <r - A ,
a
.
<r - <r -
c
.
," ,
b
.
<r - <r -
d
.
, ,"
____ 74. When the half:reactions 8r A 2e 28r and ,a ,a A e are combined$ the balanced redox e1uation is
____.
a
.
,a A 8r A e ,a A 28r
c
.
2,a A 8r 2,a A 28r
b
.
,a A 8r ,a A 28r
d
.
,a A 8r A 2e ,a A 28r A e
____ 7%. "ow man# carbons are in a molecule of hexane?
a
.
c
.
%
b
.
4 d
.
+
____ 7+. Which of the following is true about structural isomers?
a
.
*tructural isomers ha&e the same molecular formula.
b
.
*tructural isomers ha&e different ph#sical and chemical properties.
c
.
*tructural isomers ha&e the same elemental composition.
d
.
all of the abo&e
____ 77. 'n a c#clic h#drocarbon with onl# carbon:carbon single bonds and n number of carbon atoms$ how man#
h#drogen atoms are there in terms of n?
a
.
2 G n c
.
2 A n
b
.
2
d
.
2n
____ 70. What is the first stage in the formation of coal?
a
.
lignite c
.
peat
b
.
anthracite coal d
.
bituminous coal
____ 72. )n example of a secondar# alcohol is shown b# the structure ____.
a
.
<" <" -"
c
.
<" <" <" -"
b
.
d
.
____ 00. Which of these compounds would #ou expect to be most soluble in water?
a
.
<" <" <l
c
.
<" <" <" <"
b
.
<" <" <" 4
d
.
<" <" <" -"
____ 01. Which of the following carbon s!eletons represents a carbox#lic acid?
a
.
<<<<<-
c
.
b
.
d
.
____ 02. Which form of pol#saccharide is found in animals?
a
.
starch c
.
sucrose
b
.
gl#cogen d
.
glucose
____ 0. What is the role of an en3#me?
a
.
speeds up biochemical reactions
b
.
causes biochemical reactions
c
.
is a product in biochemical reactions
d
.
pro&ides extra heat for biochemical reactions
____ 04. Which of the following terms represents the entire set of chemical reactions carried out b# an organism?
a
.
anabolism c
.
metabolism
b
.
catabolism d
.
omnibolism