ANNA UNIVERSITY: CHENNAI-600 025

B.E./B.TECH DEGREE EXAMINATIONS, APRIL/MAY-2014

Regulations: R-2013

Second Semester
(Common to All Branches)

GE6262-Physics and Chemistry Laboratory-II

(Chemistry Laboratory - II)

Duration: 3 Hours Maximum Marks: 50

1. Determine the amount of alkalinity present in the given water sample. 50
You are provided with a standard solution of Sodium hydroxide and a
link solution of hydrochloric acid.

2. Estimate the amount of hydroxide and carbonates ions present in the 50
the given water sample. A standard solution of Na
2
CO
3
and a link
solution of HCl are provided.

3. Which of the two given water samples A and B more alkalinity? 50
You are provided with standard solution of HCl.

4. Compare the total hardness present in the given hard water samples 50
A& B by EDTA method. You are provided with standard hard water
and link solution of EDTA.

5. Estimate the amount of total hardness present in the given hard 50
water sample. You are provided with 0.01M solution of EDTA.


6. Estimate the total hardness of the given water sample. You are 50
provided with a standard solution of MgSO
4
and a link EDTA
solution.

7. Estimate the amount of copper present in the given CuSO
4
50
solution. You are provided with a standard solution of ZnSO
4

and a link EDTA solution.

8. Estimate the amount of copper ions present in the given CuSO
4
50
solution by complexometric titrations. You are provided with
a standard solution of MgSO
4
and a link solution of EDTA.

9. Compare the strength of the copper ions present in the brass 50
solution A and B by complexometrically. You are provided
with a standard EDTA solution.

10. Estimate the amount of ferric ion present in the given ferrous 50
ammonium sulphate solution by potentiometric titration. You
are provided with a standard solution of K
2
Cr
2
O
7
.

11. Estimate the amount of ferric ion present in the given Ferrous 50
ammonium sulphate solution by potentiometric estimation. You
are provided with a standard solution of K
2
Cr
2
O
7
. Draw the
following graph. Plot the volume of K
2
Cr
2
O
7
Vs E/V

12. Determine the strength of the given BaCl
2
solution by conductometric 50
precipitation method using a standard K
2
SO
4
solution.

13. Determine the strength of the given Na
2
SO
4
solution by conductometric 50
precipitation method using a standard BaCl
2

solution.

14. Determine the strength of the given BaCl
2
solution by conductometric 50
precipitation method using a standard Na
2
SO
4
solution.


15. Compare the iron content in the given water samples A & B using 50
Flame photometry. Draw the following graph.
(i) Calibration curve (plot of concentration of sodium Vs emission
intensity).


16. Estimate the amount of sodium present in the given water sample 50
using flame photometry method. Draw the following graph.
(i) Plot of concentration of sodium solution Vs Emission intensity).



17. Determine the rate of corrosion of mild steel by weight loss method 50
using HCl at different concentrations.



18. Determine the rate of corrosion of mild steel in HCl using 50
Potentiometric method. You are provided standard solution of
K
2
Cr
2
O
7.
Plot the volume of K
2
Cr
2
O
7
Vs E/V.




19. Estimate the amount of CaO present in the given cement sample. 50
You are provided with standard solution of KMnO
4
.



20. Compare the CaO content present the given cement samples. 50
You are provided with standard solution of KMnO
4
.


STATEMENT OF MARK DISTRIBUTION

Short
Procedure
Experiment Result Viva Total
15 20 10 5 50