., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
ANSWERS, HINTS & SOLUTIONS
FULL TEST II
(Main)
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
A A B
2.
B C A
3.
C B A
4.
B D A
5.
D B B
6.
C C B
7.
A C B
8.
C C C
9.
A. B B
10.
C B B
11.
D D D
12.
C B B
13.
C C A
14.
A B A
15.
B C B
16.
D B A
17.
A C A
18.
C B A
19.
A C A
20.
C B C
21.
A B D
22.
D B C
23.
A D D
24.
C B B
25.
D D C
26.
B B C
27.
B D C
28.
D D A
29.
C C A
30.
D D A
A
L
L
I
N
D
I
A
T
E
S
T
S
E
R
I
E
S
FI I TJEE JEE (Main)2014
F
r
o
m
C
l
a
s
s
r
o
o
m
/
I
n
t
e
g
r
a
t
e
d
S
c
h
o
o
l
P
r
o
g
r
a
m
s
7
i
n
T
o
p
2
0
,
2
3
i
n
T
o
p
1
0
0
,
5
4
i
n
T
o
p
3
0
0
,
1
0
6
i
n
T
o
p
5
0
0
A
l
l
I
n
d
i
a
R
a
n
k
s
&
2
3
1
4
S
t
u
d
e
n
t
s
f
r
o
m
C
l
a
s
s
r
o
o
m
/
I
n
t
e
g
r
a
t
e
d
S
c
h
o
o
l
P
r
o
g
r
a
m
s
&
3
7
2
3
S
t
u
d
e
n
t
s
f
r
o
m
A
l
l
P
r
o
g
r
a
m
s
h
a
v
e
b
e
e
n
A
w
a
r
d
e
d
a
R
a
n
k
i
n
J
E
E
(
A
d
v
a
n
c
e
d
)
,
2
0
1
3
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
2
P P h hy ys si i c cs s PART I
1. Avg. speed
2 2
r mr
(v t) (v t)
3
t
+
=
2
r
v 5 9 + =
r
v 2m/ s =
2.
avg
1 t 1
v v
3v
2 2 2
v
t 4
+
= =
3.
m m
g T a
2 2
= (i)
T cos 60 =
ma
cos 60
(ii)
Solving (i) and (ii) acceleration of ring =
2g
9
4. Work done by all the forces on the block equal to change in kinetic energy.
6. No effect of a and g on time period of spring pendulum.
7.
3 1
1
=R
2 2
1 1 8R
1 3 9
 
=

\ .
2 1
1
=R
2 2
1 1 3R
1 2 4
 
=

\ .
3 1
2 1
27
32
8. Work done by friction
x
0
dx
F ds mgcos
cos
= = u
u
} }
=mg x =20 J
N
f
mg dx
cos
ds
u =
dx
dy
ds
9. There will be no change.
h' =h
h'
A
10. Conservation of energy
2
1 3
mv mg mg m 3 2
2 2 2 2
 
= + 

\ .
g
v 8g =
60
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
3
11. Potential across capacitor is zero, hence energy stored is zero.
12. v
A
v
B
=} E. dx =10 (1)
=10 volt.
13. Z =
2 2
R X + =
2
9 X +
but cos  =
R 3
Z 5
=
X =4 O.
14. c =
0
o
c
v
A
v
B
=
0 0
(b) (a)
o o
c c
W =Q(v
A
v
B
) =
0
Q
(b a)
o
c
15. e =0 +1 10 =10 rad/sec
2
v =re =1 10 =10 m/s
0
3
q(v r)
B
r
=
4t
B=
0
2
qv
4 r
t
B =
7
2
10 0.1 10
(1)
=10
7
T
16. P =oAT
4
4
A B B
B A A
P A T
P A T
 
=

\ .
16 =
4
B
A
T 2
1 T
 

\ .
T
B
=T
A
(8)
1/4
Since
m
T =constant, ( )
1 4
A B
B A
T
8
T
= =
B
=
( ) ( )
A
14 14
5000
8 8
=
17. For adiabatic process, TV
1
=constant
T
1
m
 

\ .
=constant
1
T
=constant
( ) 1 1
1
T 3
1
=
=4/3
f =
2 2
6
4 1
1
3
= =
 

\ .
18. P(x, y), A(3a, 0), B =(3a, 0)
V
PA
=
0
1 2Q
4 PA
tc
, V
PB
=
0
1 Q
4 PB tc
According to equation
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
4
0 0
1 2Q 1 Q
4 PA 4 PB
 
+

tc tc
\ .
=0
2 1
PA PB
= 4PB
2
=PA
2
(x 5a)
2
+y
2
=(4a)
2
19. i = 5A
2 2
2 m
q q 1
Li
2C 2C 2
= + q
max
=6 C
21. f =ma
2
o =
2f
I mR
t
=
a
2
=F/4m, f =F/4
F
a1
f
f
a2
22. The process is equivalent to TV
1/2
=C
Compare with TV
x1
=C x =3/2
C =
R R
1 1 X
+
=
( )
R R
2 3 1 3 2
+
=
3 1
R 2R R
2 2
=
23. Intensity will be highest at the nearest point.
28. tan u =
2 2
u u 100 10
R
Rg gtan
10 3 3
= = =
u
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
5
C Ch he em mi i s st tr r y y PART I I
14.
19
hc
E 2.9 10 J
= =
Total energy of 10 quanta =10 2.9 10
19
J
Energy stored for process
3
19
23
112 4.18 10
7.8 10 J
6 10
= =
% efficiency
19
19
7.8 10
100
29 10
=26.9%
15.
a b
b a
r M 2
r 1 M
= =
rms
T
V
M
(As
rms
3RT
V
M
=
)
( )
( )
rms a
a b
b a rms b
V
T M 2 2 2 2
V T M 1 1 1
= = =
16.
1 1
1 1 2
k E 1 1
n
k R T T
' (
=
(
... (i)
2 2
2 1 2
k E 1 1
n
k R T T
' (
=
(
... (ii)
Eqn. (ii) Eqn.(i)
( )
2 1 2 1
2 1 1 2
E E k k 1 1
n
k k R T T
' (
=
(
'
(For equimolar formation of B and C,
2 1
k k ' ' = )
1 2
2 2
k T 300 8314
n
k 8.314 300 T
     
=
 

\ .
\ . \ .
n2 =
2
2
T 300 8314
8.314 300 T
   
=


\ .
\ .
T
2
=329.77 K.
17.
( ) ( ) ( )
( ) ( )
3 2 2
2SO g 2SO g O g
at equilibrium 1 2x 2x x
+
Only SO
2
will oxidized.
Equivalent of SO
2
=Equivalent of KMnO
4
2x 2 =0.2 5
2x =0.5
2
c 2
0.5 0.25
2 2
K 0.125
0.5
2
( (
( (
= =
(
(
18.
b b
T i k m A =
2.08 =0.52 1 i
i =4
It means salt on dissociation gives 4 ions. Thus the salt that gives 4 ions is K
3
[Fe(CN)
6
].
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
6
19.
2 o o
1 1 1
Cu e Cu ; E X V G FX
+ +
+ = A = ... (i)
3 1 o o
2 2 2
In 2e In E X V G 2FX
+ +
+ = A = ...(ii)
2 o o
3 3 3
In e In E X V G FX
+ +
+ = A = ... (iii)
From Eqn. (i) +(iii) (ii)
2 2 3 o o
In Cu In Cu G FE
+ + + +
+ + A =
( )
o o
1 3 2
G F X X 2X FE A = + =
( )
o
1 3 2
E X X 2X = +
20. Due to Fajans rule.
23. Green ppt. is Cr(OH)
3
25.
C H
3
C
O
OH
2
HVZ
Br /P
C OH
O
2
BrCH
3
KCN
H O
+
( ) Y

2
O
OH C CH COOH
( ) X Malonic acid
26. 1
o
aromatic amine on diazotisation followed by coupling with napthol gives azo dye test.
28. (A) Viscosity o intermolecular attraction
o intermolecualr Hbonding tendency
(B) No intramoecular Hbonding in the cisisomer due to loss in planarity as a result of steric and
electronic repulsion.
stability o symmetry.
(C) Even though onitrophenol shows intramolecular Hbonding but has greater R and I effect
than Cl.
(D) H
3
BO
3
+3 C
2
H
5
OH B(OC
2
H
5
)
3
+3H
2
O.
No cage lattice structure of H
3
BO
3
.
29. Because phenol is less acidic than H
2
CO
3
.
30. S is less electronegative and therefore more reactive towards S
N
2.
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
7
M Ma at th he em ma at ti i c cs s PART I I I
1. Given equation can be written as x 1
2
+x 1 6 =0
t
2
+t 6 =0
t =2 or 3 x 1 =2
x 1 =2 or x =3, 1
2. z
1
z
2

2
+z
2
z
3

2
+z
3
z
4

2
+z
4
z
1

2
=2(z
1

2
+z
2

2
+z
3

2
+z
4

2
) +z
1
+z
3

2
+z
2
+z
4

2
> 8 +z
1
+z
3

2
+z
2
+z
4

2
3.
( )
r
4 2
2 2
r r
T
r 4
r 2 4r
= =
+
+
=
( ) ( )
2 2
r
r 2r 2 r 2r 2 + + +
=
2 2
1 1 1
4 r 2r 2 r 2r 2
(
(
+ + +
=
( ) ( )
2 2
1 1 1
4
r 1 1 r 1 1
(
(
+ + +
( )
n
2 2
1 1 1 1
S 1
4 2 n 1
n 1 1
(
= +
(
+
+ +
5
1 1 1 1 1 38 37 26 1
S 1
4 2 26 37 4 26 37
( (
= + =
( (
=
1 1380 345
4 26 37 26 37
=
5
7 338
37S 13
26 26
= =
4. Number of terms =Number of nonnegative integral solution of the equation p +q +r +s =50
=
50 +4 1
C
50
=
53
C
50
=
53
C
3
5. If a function is symmetric about two mutually perpendicular lines, it must be symmetric about their
point of intersection.
6.
5 5
2 2
6 6
x y dy dy
a x y
dx dx
1 x 1 y
 
=

\ .
5 5
2 2
6 6
y dy x
ay ax
dx
1 y 1 x
 
= + 

\ .
( )
( )
6 2 6 3
6 2 6 3
1 y dy x a 1 x x
dx
1 x y a 1 y y
+
=
..... (1)
Also,
( )
( )
( )
6 6
3 3
6 6
1 x 1 y
a x y
1 x 1 y
=
or ( )
3 3 6 6
x y a 1 y 1 x + =
6 3 6 3
a 1 y y a 1 x x = +
Hence, from equation (1),
6 2
2
6
1 y dy x
dx y
1 x
7. For a triangle formed by joining any three conormal points, orthocentre consides with the fourth
point.
8. HM of SP and SQ =
( )( )
2 3 6
4
3 6
=
+
=semi latus rectum.
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
8
9. If a circle cuts two circles orthogonally, radical axis of the two circles pass through the centre of
the first circle
Here radical axis of given circles is 6x 4y +4 =0 or 3x 2y +2 =0
Hence 3o 2 +2 =0
3 1
4 2 2

o =
10. sin o =
2 1
2 1
r r
r r
+
u =2 sin
1


.

\

+
2 1
2 1
r r
r r
O1
O
2
r2
r1
o
o
11. Let j b i a r
+ = a
2
+b
2
=1 (1)
Also,
cos 45 =
 j i  r 
) j i ( r
+
+
a +b =1 (2)
cos 60 =
 j 4 i 3  r 
) j 4 i 3 ( r
3a 4b =
2
5
(3)
There exists no real values of a and b satisfying (1), (2) and (3)
Hence no such unit vector exists
12. (1 +x)
n
= ....
3
240
3
80
3
8
3
4 3
+ + + + =1 +nx +
2
x ) 1 n ( n
2
+. . . .
On comparison, n =3 and x =
2
3
13. From the given conditions,
a b
x y
= 1,
b c
y z
= 1,
a c
x z
= 1
x +a = y +b = z +c The determinant is a symmetric one. The determinant will be equal to zero if
x +a +y +b +z +c =0
but a +b +c =0 (given)
x +y +z =0
x +z =2 
.

\

2
y
x, z ,
2
y
are in A.P.
14. For x =1, y =a +b +c
Tangent at (1, a +b +c) is ( ) ( ) c 1 x
2
b
ax c b a y
2
1
+ + + = + + +
Comparing with y =2x, c =a, b =2(1 a)
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
9
15. x e (2, 3) 1 <x
2
4x +3 <0, so f(x) is increasing in (1, 0)
f(sin x) is increasing on
n I
(4n 1) ,2n
2
e
t  
t

\ .
16. Let point P on the straight line x +y =4 be (m, 4 m), this will be nearest to the parabola if at
this point to the straight line becomes normal to the parabola.
Let it is normal at x 10 =t
2
, y =2t
Perpendicular to x +y =4 at (m, 4 m) is y (4 m) =(x m) ..(1)
Normal at parabola at (t
2
+10, 2t) is y +t(x 10) =12t +t
3
..(2)
(1) and (2) are same t =1, m =
17
2
so required point is
17 9
,
2 2
 

\ .
17.
( )
a a c 3b 3b = =
( )
a. a c sin 3.1
2
t
= 3 =
( )
a. a c sinu
3 =3.2 sin u sin u =
1
2
cos
2
u =
3
4
18. A'(x) = ( )
x 2 2
2 x 2
e 2cos2x 2xsec x
ln 1 x cosx sinx
cosx e 1 sinx
+
+
( )
x 2
2 x 2
e sin2x tanx
1
sinx cosx
1 x
cosx e 1 sinx
+ ( )
x 2
2 x 2
e sin2x tanx
ln 1 x cosx sinx
2xsinx e 2xcosx
+
=B +2Cx +.
Put x =0, B =
1 2 0 1 0 0 1 0 0
0 1 0 1 0 1 0 1 0
1 0 0 1 0 0 0 1 0
+ + =0
19. Let g(x) be the inverse of f, then f(g(x)) =x
3
g (x)(g(x)2)
=x
(g(x))
2
2g(x) log
3
x =0
g(x) =
3
3
2 4 4log x
1 1 log x
2
+
= +
Since g : [1, ] [2, ]
So g(x) =
3
1 1 log x + +
20. Since
2
x 3x 2 0 + > 0 s
1 2
tan x 3x 2
+ <
2
t
Since
2
4x x 3 > 0 0 <
1 2
cos 4x x 3
s
2
t
0 <L.H.S <t The given equation has no solution
21. Let f =(5 2 7)
19
x f =an integer [x] +{x} f =an integer
{x} f =an integer, but 1 <{x} f <1 {x}=f
So, x{x}=x.f =1
19
=1
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
10
23.
1
x
=2e
1 2 3
...
3 ! 5 ! 7 !
(
+ + +
(
=2eS
S =
r 1 r 1 r 1
r 1 (2 r 1) 1 1 1 1
(2 r 1)! 2 (2 r 1)! 2 (2 r)! (2 r 1)!
= = =
( +
= =
(
+ + +
=
1 1 1 1 1
...
2 2 ! 3 ! 4 ! 5 !
(
+ +
(
=
1
2
e
1
=
1
2 e
1
x
=2eS =
2 e
2 e
=1
So,
1
0
f (y)
}
log
y
x dy =0
24. Let any point on second line be (, 2, 3)
cos u =
6
42
sin u =
6
42
A
OAB
=
1
2
(OA).OB sin u =
1
2
3 . 14
6
42
= 6
=2
So, B is (2, 4, 6)
B(, 2, 3) O
A (1, 1, 1)
25. Centroid of triangle will be
a b c
3
+ +
Now line joining the orthocentre and the circumcentre is divided by centroid in 2 : 1 ratio
internally, so orthocentre will be a b c + + .
26. If we draw the graph of tan x and cot x, we
observes that range of f (x) is [1, 0) [1, )
So f (x) =
1
3
does not have any root.
27.
300
1
S S
n
<
300
1
3
1
1
3
1
1
3
1
1
1
n
<
00
1
3
1
1 1
2
3
n
3
<
(
+
3
2
300
1
3
1
n
<
450
1
3
1
n
< 3
n
>450
Least value of n =6
AITSFTIIPCM(S)JEE(Mai n)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
11
28. f(x) =
x 4
t x t x
0 x
e dt e dt
+
} }
=
x 4
x t t x
0 x
e dt e dt
+
} }
=
x 4
x t t x x 4 x
0 x
e e e e 2
+ = +
f'(x) =e
x
e
4x
=0 x =4 x x =2
f(0) =f(4) =e
4
1, f(2) =2(e
2
1), so maximum value of f(x) is e
4
1.
29. Given inequation can be rewritten as
2
sec x 2
2y 2
3 y
3 9
+ s 1
2
2
sec x
1 1
3 y
3 9
 
+

\ .
s 1
Now,
2
2
sec x
1 1 1
3 3 and y
3 9 3
 
> + >

\ .
So, we should have sec
2
x =1, y =
1
3
x =0, t, 2t, 3t
30. arc(AC) =3, arc(AB) =4, arc(BC) =5
Let radius of the circle be r
ro =3 o =3 /r,  =4/r, =5/r
Now, 3 +4 +5 =2tr r =6/t
6 r
1 t
=
A
ABC
=A
OAC
+A
OAB
+A
OBC
=


.

\


.

\

+ 
.

\

+ 
.

\

r
5
sin
r
4
sin
r
3
sin r
2
1
2
=


.

\


.

\
 t
+ 
.

\
 t
+ 
.

\
 t
t 6
5
sin
3
2
sin
2
sin
36
.
2
1
2
B
A
C
o 
O
=
( )
2 2
3 1 3 9
2
1
2
3
1
18
t
+
=


.

\

+ +
t