Answer Solution

AITS-CRT-II-(Paper-2)-PCM(S)-JEE(Advanced)/14
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1

ANSWERS, HINTS & SOLUTIONS
CRT II
(Paper-2)

Q.
No.
PHYSICS CHEMISTRY MATHEMATICS
1.
A B D
2.
B D B
3.
C A B
4.
C A B
5.
D D B
6.
A D B
7.
A A B
8.
A C C
9.
A D B
10.
A D A
11.
D A B
12.
A B A
13.
B D A
14.
A B C
15.
B, D B, C, D A, C
16.
B, C A, B A, D
17.
A, C A, B A, B, C
18.
B, C, D A, B, D B, D
19.
B, D A, D A, D
20.
A, B, C, D A, C, D A, C, D

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

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a
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2
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3


2
P P h hy ys si i c cs s PART I

2. | =o tan u
2
2 2
1
g
2 u cos
o
u

| =o tan u
( )
2
2
1
g 1 tan
2 2g
o
+ u
o

tan
2
u 4 tan u +
4
1
| | |
+
|
o
\ .
=0

(, )

u
2go
u

If particle will not hit the target.
(b
2
4ac) <0
16 4
4
1
| | |
+
|
o
\ .
<0
4| >3o

3. At B, mg sin | =
2
B
mv
r
. . . (1)
Using energy considerations

2
B
1
mv
2
=mgr(cos o sin |) . . . (2)

B
A

Smooth
N
vB

From (1) and (2)
mg sin | =2mg(coso sin |)
2coso =3 sin |

7. i = 5A

2 2
2 m
q q 1
Li
2C 2C 2
= + q
max
=6 C

8. Time period does not depend on amplitude SHM and both particle will exchange velocity at every
collision.

15. The slope of curve at such a point will be 1

dy x
2cos 1
dx L
t | |
= =
|
\ .

x =
L
3
or
2L
3

y

x

135

45

16.
1
P m 16 2m 0 16m = + =

' '
f A B
P mv 2mv = +

2
B
1
2mv 2mgh
2
=

B
v 10 = m/s
16 m =
'
A
mv 2m 10 +

'
A
v 4m/ s =

' '
B A
A B
v v
e
v v
=
10 ( 4) 14 7
16 0 16 8

= =


3

17. If v be the velocity at mean position in two cars then
2 2 2
1 2
1 1 1
mv KA KA
2 2 2
= =
and
1 2
m
T T 2
K
= = t
A
1
=A
2

18. Initially potential and kinetic both energies zero and from conservation of mechanical energy total
energy of the two object zero
Further, decrease in P.E. =increase in K.E.

2
r
G(m)(4m) 1
v
r 2
=

r
10Gm
v
r
=
Total K.E.
2
G(m)(4m) 4Gm
r r
= =

4
C Ch he em mi i s st tr r y y PART I I

SECTION A
1.
4
6
XeO

(perxenate ion) because oxidation state of Xe is +8 and it is highly unstable compound.
2. Br

Due to formation of resonance stabilized carbocation.
3.
293.4
CRT,So,C 0.1 mol / L
RT 8.31 293
t
t = = = =

If 100 ml contains 6.33 g of haematin.
1 L will contain 63.3 g of haematin.
Molecular mass of haematin =633 u
Estimating the empirical formula of compound
C : H : N : O : F =
64.6 5.2 8.8 12.6 8.8
: : : :
12 1 14 16 56

34: 33: 4: 5:1 ~
So, empirical formula is C
34
H
33
N
4
O
5
Fe, whose mass corresponds to the molecular mass.
4.
2 2 4 2
o o
Zn /ZnY /Y Zn /Zn
0.059
E E logK
2
+ + +
= +

2
f
4
f
ZnY
1
K K
K Y
(

= =
(

2 2 4
o
10 16 Zn /ZnY /Y
0.059 1
E 0.76 log
2 3.2 10
+
= +

=- 1.25 V
5.
f f
T 0.5K iK m A = =

f
f
T 0.5
i 1.022
K m 1.86 0.263
A
= = =

HA H A
1 0 0
1
+
+
o o o

i 1 0.022 = + o o =
K
a
=Co
2
=0.2 (0.022)
2
=9.6 10
-5

pK
a
=4.0177
On adding 0.25 M NaA, buffer is formed.

5

| |
| |
a 10
Salt
pH pK log 4.0177 0.0969
Acid
= + = +
=4.1146
6.
2 4 7 2 3 3
Strongbase
Weakacid
Alkaline
Na B O 7H O 2NaOH 4H BO + +
_

2 4 7 2 2 3
Glassybead
Na B O 2NaBO B O
A
+
_

( )
2 4 7 2 4 2 2 4 3 3
Whitecrystals
Na B O H SO 5H O Na SO 4H BO + + +

7.
C H
3
OH
CH CH
2
H
+
C H
3
OH
CH CH
3
Ring
expansion
O
C H
3
H
H
3
C
H
+
O
C H
3
H
3
C

8. O
O
N K
+
||
2 2 5
O
KCl
Cl CH C OC H

+
N
O
O
CH
2
C
O
OC
2
H
5
( ) X
( ) Y
2
2 5
H /H O
2 2 C H OH
Glycine
H N CH COOH
+
+
O
O
OH
OH
( ) Z

9.
( )
( )
Burning
2 3 2
A
B
3M N MN +

( )
( )
( )
( )
3 2 2 3
2
B D
C
M N 6H O 3M OH 2NH + +
All statement with respect to NH
3
are correct.
10. Ba and Ca quite readily liberate hydrogen.
In cold water Mg decomposes water only on heating. So, element (A) may be Ca and Ba not Mg.

( )
( )
( )
( )
2 2
Limewater Baryta water
Ca OH & Ba OH , both givess milkiness with CO
2
.
11.
2
1 1 2
P H 1 1
2.303log
P R T T
| | A
=
|
\ .

1
H 11.99 kJ mol
A =

6
12
( )
2
2
1
b 3
8.314 353 100
RT M
K 8.64Kkgmol
1000 H 1000 11.99 10

= = =
A

( )
b b
T K 1 m A = + o
( )
1 1000
1 8.64 1
100 100
= + o
o =0.158
13. Two structural isomers of (A) are:

Me
Me
Me
OH
& Me
Me
OH
Me

There are four geometrical isomers for each strucutre, i.e. total number of stereoiosmers =8.
14. Convert aldehyde and ketone to alcohol

(1)
OH (5C )

(2)
OH
OH
(6C )

(3)
(2C )
O H
OH

15.
O OH
H
H
CH
2
OH
H
OH
OH
H
H
O
O
H
CH
2
OH
H
OH
OH
H
H
OH
H

16. (A)
N
H
H
H
N
F
F
F

3 3
NH NF
>
(B) (I) is 3
o
allylic with extended conjugation.
(II) is 3
o
allylic, (III) is 3
o
free radical.
(C) Correct order is: ( )
3
RS CH O OH Basic strength

< <
(D) Correct order is: ( ) I Br Cl F Basic strength

< < <
17. (A)
4 3 3 3 2
NH NO NaOH NH NaNO H O + + +

3 2 2 3 2
7NaOH NaNO 4Zn 4Na ZnO NH 2H O + + + +
(B)
4 2 2 3 2
NH NO NaOH NaNO NH H O + + +

3 2 2 3 2
3Zn 5NaOH NaNO 3Na ZnO NH H O + + + +
18.
rms
3RT 3PV 3P
v
M M d
= = =
19. In metal carbonyls, M CO
t
o
, the C O bond length increases compared to that in CO

molecules due to synergic bonding between metal and carbonyl ligand.

7
Facial and meridenal isomers | |
n
3 3
Ma b
+
contains plane of symmetry.
20.
( )
3 2 3
CH COO H O CH COOH OH
0.11 h 0.1h 0.1h

+ +

( )( )
( )
2 5
h
0.1h 0.1h
K 0.1h h 7.48 10
0.1 1 h

= = =

5 1 6
OH Ch 7.48 10 10 7.48 10

( = = =

14
9 W
5
K 10
H 1.33 10
7.48 10 OH
+

( = = =

(

And pH =8.8 approx.


8
M Ma at th he em ma at ti i c cs s PART I I I

1. We express x in terms of a new variable y

1
x 1
y
=
y 1
x
y
+
=

( ) ( ) ( ) ( )
5 3 2
5 3 2
6 y 1 5 y 1 y 1 4 y 1
1
y
y y y
+ + + +
+ + + =
5 4 3 2
a b c d e
f
y y y y y
+ + + + +
Multiplying both side by y
6
we get 6y(y +1)
5
+5y
3
(y +1)
3
+y
4
(y +1)
2
+4y
5
(y +1) y
6

=ay +by
2
+cy
3
+dy
4
+ey
5
+fy
6

Differentiating both side and then satisfying y =1
Gives the value a +2b +3c +4d +5e +6f =910

2.
( ) ( )
( )
50
n 51 n
n 1
f x x n

=
=
[

( ) ( ) ( ) ( )
50
n 1
ln f x n 51 n ln x n
=
=

Differentiating both side w.r.t. x

( )
( )
( )
50
n 1
f ' x n 51 n
f x x n
=

( )
( )
f ' 51
1275
f 51
=

3. a
2
=b
2
+c
2
2bc cos A =(b c)
2
+2bc(1 cos A)
A =
1
bcsinA
2

4
2bc
sinA
A
=

( ) ( )
2
2
4
a b c 1 cosA
sinA
A
= + =(b c)
2
+
A
4 tan
2
A
Since A and A are fixed hence a is minimum when b =c
Hence 2bc =2b
2
=
4
sinA
A

4.
( )
( )
( )
( )
f 3x 3y f 3x 3y
sin 2x 3y sin 2x 2y
+
=
+
x, y e R

( )
2x
f x ksin
3
| |
=
|
\ .

( )
2
f ' 0 k 1
3
= =
3
k
2
=

( )
3 2x
f x sin
2 3
| |
=
|
\ .

3 3
f'
2 4
t | |
=
|
\ .

Equation of tangent is
3 3 1
y x
4 2 2
t | |
=
|
\ .

5.
i j
1 i j m
aa
s < s
=
2
m m
2
i i
i 1 i 1
1
a a
2
= =

| |

` |
|

\ . )


9
=
( ) ( )
2
m 2 2m
1 1
2
a 1 r a 1 r 1
2 1 r 1 r

| |

`
|
\ . )

=
( )
( )
2
2 m 2m
1
a 1 r 1 r
2 1 r 1 r 1 r

`

+ )

=
( ) ( )
m 1 m
1 1
a 1 r a 1 r r
1 r 1 r 1 r

` `
+ ) )

=
m 1 m
r
S S
1 r

+

6. Use LHospitals Rule twice

7. g(x) =
( )
( )
3
2
f x dx
x x 1 +
}
=
( ) ( )
2 2 3
A B C D E
dx
x x 1 x
x 1 x 1
| |
+ + + +
|
+
+ + \ .
}

=
( )
( )
2
B D E
Alnx cln 1 x
x 1 x
2 x 1
+ +
+
+

Since g(x) is a rational function, hence logarithmic function must be absent
A =C =0

( )
( ) ( )
2 2 3
B D E
g x dx
x
x 1 x 1
= + +
+ +
}

f(x) =(B +D)x
3
+(3B +D +E)x
2
+3Bx +B
B +D =0, f(0) =1 gives B =1 D =1
f(x) =(2 +E)x
2
+3x +1
f'(x) =2(2 +E)x +3
f'(0) =3

8. Denoting the two curve by S
1
and S
2
the equation of curve S passing through intersection of S
1

and S
2
can be S =S
1
+S
2
=0. Since S is circle
Coefficient of x
2
=Coefficient of y
2
, Coefficient of xy =0 we get =1
S =(a' +a)(x
2
+y
2
) 2(g' +g)x 2(f' +f)y +2c =0
The centre is
g' g f ' f
,
a' a a' a
+ + | |
|
+ + \ .
which is P
PA
2
+PB
2
+PC
2
=3(Radius)
2
=3(PD)
2

9.
( )
x
sinx sin
180
t
=
x
sinx sin
180
t | |
= t
|
\ .
or
x
sin 2
180
t | |
t +
|
\ .

x
x
180
t
= t ,
x
x 2
180
t
= t +

180
x
180
t
=
+ t
,
360
x
180
t
=
t

On comparing, m =360, n =180, p =180, q =180
(m +n +p +q) =900

10.
( )
2 2
x
A C x Bx
lim 2
B
x A C
x
+
=
| |
+ +
|
\ .

For existence of limit A =C
2


10
Hence, C A = ,
B
2
A C
=
+

B
4
C
=
For C A = limit does not exist

11. The visible are of P(2, 6) is the area of AABP AABP has base AB of length 4 and its height is the
distance from AB to point P. Which is 10, since AB is parallel to xaxis.
Thus area =
1
b h 20
2
=

12. Similarly area =AQBC =
1 1
b h 4 4 8
2 2
= =

13. LHD =
2
h 0
sinh tanh cosh 1
2h ln(2 h) tanh
lim
h
+ + | |
|

|
|
\ .

=
( )
2
2
h 0
sinh tanh 1 cosh
h
h h
h
lim 0
2h ln 2 h tanh
+
=

RHD =
2 2
h h
h 0
e 1 0 e 1
lim h 0
h h

= =
L
1
y =0, L
2
x =0

14.
1
2 cot cot 1
2 4 2 2
| | t u u | |
A = + +
| |
\ . \ .

=
2sin
4
1
2 sin sin
4 2 2
t
+
| | t u u | |
| |
\ . \ .

=
2
1
cos cos
4 4
+
t t | |
u
|
\ .

( ) ( )
min
2
1 1 2 2 1 3 2 2
1
1
2
A = + = + + = +

15. Four point A, B, C, D are coplanar if three vector AB
,
, AC
,
, AD
,
are coplanar or STP of there
vectors is 0

( )
AB AC AD 0 =
, , ,

( )
( )
1 0 0
3 f t 1 0
2 f ' t 2
= t e R
f'(t) =2f(t)
f(t) =ce
2t

Similarly for ( )

B i j +
,
differential equation will be f'(t) 2 f(t) =4
On solving f(x) =2 +ce
2x
, c e R

11

16. First use integrating by parts to show that

/ 2
n 1
n
0
u cos xsinxsinnx dx
t
=
}

=
/ 2 / 2
n 1 n
0 0
cos xcos(n 1)x cos xcosnx dx
t t

} }
(Use sin nx sin x =cos(n 1)x cos nx cos x)
=u
n 1
u
n

n
n 1
u 1
u 2
=
We have,
1
u
4
t
= ,
n
n 1 n 1
1
u
4
2 2
+
t t
= =

17. If three planes pass through the same line, their normal vector will be coplanar

1 sin sin
sin 1 sin 0
sin sin 1
o |
o u =
| u

sin
2
o +sin
2
| +sin
2
u +2 sin o sin | sin u =1 ..... (1)
Now the cross product r of normals of P
1
, and P
2
will parallel to line
Direction ratio of r =

i j k
1 sin sin
sin 1 sin
o |
o u
={(sin o sin u +sin |), (sin o sin | +sin u), (1 sin
2
o)}
r is parallel to given line

2
sin sin sin sin sin sin 1 sin
cos cos cos
o u + | o | + u o
= = =
u | o
..... (2)
Using (1) and (2) we get
cos o = sin (| +u) sin (| +u) =sin
2
t | |
o
|
\ .
=o +| +u =2n
2
t
t + (n e z)

18. Let the circle be x
2
+y
2
=r
2
, and the five points be P
i
=(r cos u
i
, r sin u
i
), i =1, 2, 3, 4, 5
Let (h
i
, k
i
) represent the centre of that rectangular hyperbola which passes through the four points
P
j
( j = i) let (h
1
, k
1
) is centre of hyperbola which passes through P
2
, P
3
, P
4
, P
5
.
Now ( )
1
2 3 4 5
h r
cos cos cos cos
2 4
= u + u + u + u , ( )
1
2 3 4 5
k r
sin sin sin sin
2 4
= u + u + u + u
(As we know if a circle and rectangular hyperbola intersect at four point then their means is mid
point of centre of two curves)

5
1 i 1
i 1
2h r cos rcos
=
= u u

5
1 i 1
i 1
2k r sin rsin
=
= u u

However, r,
5
i
i 1
cos
=
| |
= u |
|
\ .
and
5
i
i 1
sin
=
| |
= u |
|
\ .
are fixed
2h
1
= r cos u
1
, 2k
1
= r sin u

2 2 2
1 1
r
h k
2 2 2
| | | | | |
+ =
| | |
\ . \ . \ .

This equation is satisfied by all (h
i
, k
i
), i =1, 2, 3, 4, 5

12

19. Divided the given equation by ax
4
, and let
y
m
x
=
Equation become
4 3 2
b c d
m m m m 1 0
a a a
+ + + + = ..... (1)
Assuming that four slopes m
1
, m
2
, m
3
, m
4
m
1
m
2
m
3
m
4
=1
Now it is given pair of these lines, bisect the angle between the other pair. So let, m
1
m
2
=1
m
3
m
4
=1 which means other two lines are also perpendicular
Equation (1) can be written as
(m m
1
)(m m
2
)(m m
3
)(m m
4
) =(m m
1
) ( )
3
1 3
1 1
m m m m
m m
| | | |
+ +
| |
\ . \ .

=(m
2
+m 1)(m
2
+m 1) ..... (2)
Where
2
1
1
1 m
m
=
2
3
3
1 m
m
=
Comparing the coefficient (1) and (2)

b
a
+ = ,
c
2
a
= ,
d
a
+ = ..... (3)
Thus,
b d
a a
= b +d =0
Also, we have to use angle bisector fact

3
1 3 1
3 1 3
1
1
m
m m m
m 1 mm
1
m
+
=
+

(m
1
m
3
)
2
=(1 +m
1
m
3
)
2
..... (4)
From (3),
c
2
a
=
2 2
3 1
1 3
1 m 1 m c
2
m m a
| | | |

= | |
| |
\ .\ .
..... (5)
Using (4) and (5) we obtain (c +6a) =0

20. Since
k
i
k
P e
u
= ,
( )
k
2k
n
t
u =
Let A
k
=x
k
+iy
k
=a cos u
k
+ib sin u
k

k
k
x
cos
a
= u ,
k
k
y
sin
b
= u , which implies that
2 2
k k
2 2
x y
1
a b
+ = , A
k
lies on ellipse
( )
n n n
k k k
k 1 k 1 k 1
A S a ex na e x na
= = =
= = =

( ) ( )
n n n n
2 2
2 2 2
k k k k
k 1 k 1 k 1 k 1
A S a ex na 2ae x e x
= = = =
= = +

=
n
2 2 2 2
k
k 1
na a e cos
=
+ u
=
n 2 2
2 2 2
k
k 1
na e 1
na a e cos2
2 2
=
+ + u

=
2 2
2
2
na b
na 1
2 a
| |
+ |
\ .
=
( )
2 2
n
3a b
2

(
n
k
k 1
cos2 0
=
u =
sum of roots of
n/ 2
z 1 1 = )

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AITS-CRT-II-(Paper-2)-PCM(S)-JEE(Advanced)/14

, the C O bond length increases compared to that in CO

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