Natural gas and its products are discussed using the following topics. Natural gas is principally methane; crude oil is principally liquid hydrocarbons. The spectrum of produced hydrocarbon fluids includes methane and paraffin.
Natural gas and its products are discussed using the following topics. Natural gas is principally methane; crude oil is principally liquid hydrocarbons. The spectrum of produced hydrocarbon fluids includes methane and paraffin.
Natural gas and its products are discussed using the following topics. Natural gas is principally methane; crude oil is principally liquid hydrocarbons. The spectrum of produced hydrocarbon fluids includes methane and paraffin.
As indicated in Chapter 1, the conditioning of natural gas for transportation and sale involves two process objectives: 1. Separation of the natural gas from free liquids (crude oil, brine) and entrained solids (sand), 2. Removal of impurities from the natural gas and any condensate formed to meet sales/reinjection specifications while observing all environmental regulations. Sales specifications can be described most readily in terms of the composition and properties of the produced hydrocarbons. Also, the selection, design, and operation of the processes required to separate gas from liquid and to remove impurities depend on the wellstream properties. Accordingly, natural gas and its products are discussed using the following topics: spectrum of produced hydrocarbon fluids, natural-gas constituents, natural-gas compositions, heating values, analysis of natural gases, sampling, and product specifications. SPECTRUM OF PRODUCED HYDROCARBON FLUIDS The desirable constituents of crude oil and natural gas are hydrocarbons. These compounds range from methane (CH 4 ) at the low-molecular-weight end all the way up to paraffin hydrocarbons with 33 carbon atoms and poly nuclear aromatic hydrocarbons with 20 or more carbon atoms (Hatch and Matar, 1977). Natural gas is principally methane. Crude oil is principally liquid hydrocarbons having four or more carbon atoms. There is a tendency to regard crude oil as a liquid and natural gas as a gas and to consider production of the two phases as separate operations. However, in the reservoir, crude oil almost always contains dissolved methane and other light hydrocarbons that are released as gas when the pressure on the oil is reduced. As the gas evolves, the remaining crude-oil liquid volume decreases; this phenomenon is known as shrinkage. The gas so produced is called associated or separator gas or casinghead gas. Shrinkage is expressed in terms of barrels of stock-tank oil per barrel of reservoir fluid. Crude-oil shrinkage is the reciprocal of oil formation volume factor (FVF). Similarly, natural gas produced from a gas reservoir may contain small amounts of heavier hydrocarbons that are separated as a liquid called condensate. Natural gas containing condensate is said to be wet. Conversely, if no condensate forms when the gas is produced to the surface, the gas is called dry. A spectrum of well fluids is actually produced, as noted by McCain (1973) and summarized in Table 2-1. The type of fluid produced depends on the phase diagram of the reservoir fluid and the reservoir temperature and pressure, as will be discussed in Chapter 3, Phase Behavior of Natural Gas. Figure 2-1 depicts a typical gas-oil separation sequence (including incidental water and sand removal). Table 2-1 lists the five common types of wellstream fluids and summarizes typical yields and liquid properties. When crude oil is separated from its associated gas during production, the total gas evolved while reducing the oil to atmospheric pressure divided by the volume of the remaining crude oil is called the gas-oil ratio or GOR. The GOR is expressed as the total standard cubic feet of gas evolved per 60F barrel of stock-tank or atmospheric-pressure oil (scf/bsto), in English engineering units and standard cubic meters of gas per cubic meter (or metric ton) of 15C oil in SI or metric units. Standard conditions for natural gas are 60F and 1 atm (English engineering units) and 15C and 1 atm (SI or metric). The total GOR depends on the number of stages used in the separation sequence, as well as the operating pressure of each stage. For three or more stages, the GOR approaches a limiting value. Optimization of the separation sequence usually involves either maximizing crude-oil yield or