2013 Jee-Advanced Model Paper-1

2013_JEE-ADVANCED_MODEL PAPER
PAPER-1
Max Marks :240
PHYSICS:
Section Question Type
+Ve
Marks
- Ve
Marks
No.of
Qs
Total
marks
Sec I(Q.N : 1 8) Questions with Single Correct Choice 3 -1 8 24
Sec II(Q.N : 9 12)
Questions with Multiple Correct
Choice
4 0 4 16
Sec III(Q.N : 13 16) Comprehension Type Questions(2+2) 4 0 4 16
Sec IV(Q.N : 17 22) Integer Type 4 0 6 24
Total 22 80
CHEMISTRY:
+Ve
Marks
- Ve
Marks
No.of
Qs
Total
marks
Sec II(Q.N : 31 34)
Choice
4 0 4 16
Total 22 80
MATHEMATICS:
+Ve
Marks
- Ve
Marks
No.of
Qs
Total
marks
Sec II(Q.N : 53 56)
Choice
4 0 4 16
Total 22 80

Prepared by Sri Chaitanya Narayana IIT Academy, Vijayawada
2013_JEE-Advanced_ Model_Paper-1
Paper-1 Page 2
PHYSICS: Max.Marks : 80
SECTION I
Single Correct Answer Type
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. A steel bar of length L is held between rigid supports and heated non uniformly in
such a manner that the temperature increases T at a distance x from one end is given
by
2
0
2
T x
T
L
as shown in figure. The stress in the bar is (Assume that modulus of
elasticity for steel is E and thermal expansion coefficient is )
x
L
T

A)
0
E T
3
B)
0
E T
9
C)
0
3E T D)
0
9E T

2. Two thin convex lenses of focal lengths
1
f and
2
f are separated by a horizontal distance
d (where
1
d f < and
2
d f < ) and their centres are displaced by a vertical separation A as
shown. Taking the origin of coordinates Oat the centre of first lens, x and
y coordinates of the focal point of this lens system, for a parallel beam of rays coming
from the left, are given by: (Assume that f A << )
y
0
d
x
A

A)
1 2
1 2
,
f f
x y
f f
= = A
+
B)
1 2
1 2 1 2
( )
,
f f d
x y
f f d f f
+ A
= =
+ +

C)
1 2 1 1
1 2 1 2
( ) ( )
,
f f d f d f d
x y
f f d f f d
+ A
= =
+ +
D)
.
1 2 1
1 2
( )
, 0
f f d f d
x y
f f d
+
= =
+

Paper-1 Page 3
3. Two blocks Aand B, each of mass mare connected with two identical springs which
are initially unstretched, placed on a smooth horizontal surface as shown . Initially the
blocks touch each other. The spring connected with block A, is compressed by / 4 A
and the other connected to B is compressed by / 2 A along with their respective blocks.
Both blocks are released simultaneously to collide inelastically. Find the amplitude of
combined mass:
A B
A/4 A/2

A) /12 A B) / 6 A C) /10 A D) /8 A
4. Pressure p, volume V and temperature T for a certain gas are related by
2
AT BT
p
V
= ,
where A and B are constants. The work done by the gas as its temperature changes
from
1
T to
2
T while pressure remains constant is
A) ( )
2 1
2
B
A T T B) ( ) ( )
2 2
2 1 2 1
A T T B T T
C)
( ) ( )
2 2 3 3
2 1 2 1
3
A B
T T T T
T
D
)
( ) ( )
2 3
2 1 2 1
3
B
A T T T T
5. Two thin rods of mass m and length l each are joined to form L shape as shown. The
moment of inertia of rods about an axis passing through free end ( ) O of a rod and
perpendicular to both the rod is
l
l
O

A)
2
2
7
ml B)
2
6
ml
C)
2
ml D)
2
5
3
ml

Paper-1 Page 4
6. Two sources
1 2
S and S emitting coherent light waves of wavelength in the same
phase are situated as shown. The minimum distance OP, so that the light intensity
detected at P is equal to that at O is(D>> )
D
O
Screen
1
S
2
S
P
2

A) 2 D B) / 2 D C) 3 D D) / 3 D
7. At 0 t = the positions and velocities of the two particles are as shown in the figure. They
are kept on a smooth horizontal surface and being mutually attracted by gravitational
force. Then position of the center of mass at 2sec t = .

0 x =
10 x m =
1 kg
1 kg
x
y
1
5 / m s u =
2
3 / m s u =

A) 5 x m = B) 7 x m = C) 3 x m = D) 2 x m =
8. A railway engine whistling at a constant frequency moves with a constant speed. It goes
past a stationary observer standing beside the railway track. The frequency (n) of the
sound heard by the observer is plotted against time (t). Which of the following best
represents the resulting curve?

n
t
a)
n
t
b)
n
t
c)
n
t
d)

Paper-1 Page 5
SECTION II
Multiple Correct Answer(s) Type
of which ONE or MORE are correct.
9. Two blocks A and B, each of mass m, are connected by a massless spring of natural
length L and spring constant k. The blocks are initially resting on a smooth horizontal
floor with the spring at its natural length as shown in Fig. A third identical block C, also
of mass m moves on the floor with a speed v along the line joining A and B and collides
elastically with A, then :

v
L
A B C

A) The KE of the AB system at maximum compression of the spring is zero
B) The KE of the AB system at maximum compression of the spring is
2
1
4
mv
C) The maximum compression of the spring is
m
v
k

D) The maximum compression of the spring is
2
m
v
k

10. In YDSE, the source is placed symmetrical to the slits. If a transparent slab is placed in
front of the upper slit, then (slab may absorb a fraction of light)
A) Intensity of central maxima may change
B) Intensity of central maxima may not change
C) Central maxima will be shifted up
D) Intensity of dark fringes will be always zero
Paper-1 Page 6
11. Two parallel resistance less rails are connected by an inductor of self inductance L at
one end as shown in figure. A magnetic field B exists in the space which is
perpendicular to the plane of the rails inwards. Now a conductor of length l and mass
m is placed transverse on the rails and given an impulse J towards the rightward
direction. Then select the correct option (s):

L
l

A) Velocity of the conductor is half of the initial velocity after a displacement of the
conductor
2
2 2
3
4
J L
is
B l m

B) Velocity of the conductor is half of the initial velocity after a displacement of the
conductor
2
2 2
3J L
is
B l m

C) Current flowing through the inductor at the instant when velocity of conductor is
half of the initial velocity is
2
3
4
J
Lm

D) Current flowing through the inductor at the instant when velocity of the conductor
is half of the initial velocity is
2
3J
mL

Paper-1 Page 7
12. There is a fixed semicircular ring of radius R, lying in y z plane, with centre of arc at
origin and it is uniformly charged with charge Q. There is a long hollow pipe of very
small radius, inner surface of pipe is smooth and it is made of insulated material. Pipe
is fixed along x axis from origin. A small ball with charge q and mass m is projected
into the pipe with negligible velocity. Ball can smoothly move in pipe. Whole
arrangement lies in gravity free space. Assume that there is no effect of hollow pipe on
the electrostatic interaction between the charges Q and q. Then,

A) The maximum acceleration of the ball in the pipe is
2
0
6 3
Qq
mR t e

B) The maximum acceleration of the ball in the pipe is
2
0
3 3
Qq
mR t e

C) The maximum electric field exists along the axis at a distance of
2
R
x = .
D) The kinetic energy of the particle when its acceleration is maximum is
0
2
1
4 3
Qq
R t
| |
|
|
e
\ .

SECTION III
Paragraph Type
This section contains 4 multiple choice questions relating to Two paragraphs with two questions on each
paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Passage: - 1

One end of a light string L is tied to a ball and the other end is connected to a fixed
point O. The ball is released from rest with string horizontal and just taut. The ball
then moves in a vertical circular path as shown in figure; let the velocity of ball at B
and C be B V
and C V
respectively
C
B
A
u
O

Paper-1 Page 8
13. If C B V 2V =

then the value of u as shown is
A)
1
1
cos
4
| |
|
\ .
B)
1
1
sin
4
| |
|
\ .
C)
1
1
cos
2
| |
|
\ .
D)
1
1
sin
2
| |
|
\ .

14. If C B B V V V =

, then the value of u as shown is
A)
1/3
1
1
cos
4
| |
|
\ .
B)
1/3
1
1
sin
4
| |
|
\ .
C)
1/3
1
1
cos
2
| |
|
\ .
D)
1/3
1
1
sin
2
| |
|
\ .

Passage - II
In the Youngs double slit experiment a monochromatic light of wavelength is used. The
slits are (in air medium) separated by distanced as shown in the figure. The medium between the
plane of the slits and the screen is having a medium of refractive index which varies with time as
( )
0
n n kt = +

15. The y co-ordinate of central maxima at any time t is
A)
0
sin D
n kt
|
+
B)
0
cos D
n kt
|
+
C)
( )
2
0
sin D
n kt
|
+
D)
( )
2
0
cos D
n kt
|
+

16. The velocity of central maxima at any timet as a function of timet is
A)
( )
2
0
2 sin kD
n kt
|
+
B)
( )
2
0
sin kD
n kt
|
+
C)
( )
0
2 sin kD
n kt
|
+
D)
( )
0
sin kD
n kt
|
+

Paper-1 Page 9
SECTION IV
Integer Answer Type
This section contains 6 questions. The answer to each question is single digit integer,
ranging from 0 to 9 (both inclusive).
17. A tank of cross sectional area
0
A is filled with a liquid. A small orifice of area
( )
0
A A A << is present at the bottom of tank. At a moment the height of liquid in the tank
is H, what is acceleration of top layer of liquid at this moment as a multiple of
2
0
A
A
| |
|
\ .
g

H

18. A bob of mass m =4 kg is suspended from a massless string of length l. Other end of
the string is fixed from the ceiling. A horizontal force
3
4
F mg = is applied on the bob
when it at rest at the lowest position. The maximum tension (in Newton) in the string
during the motion. is 10x. Then the value of x is (Take
2
10 / g m s = )
3
4
mg
F =

19. The circuit was in the shown state for a long time. Now the switch S is closed. The
charge that flown through the switch is 10x C then the value of x is

Paper-1 Page 10

20. A particle of mass 4m at rest decays into two particles of masses m and 3m having
non-zero velocities. The de-Broglie wavelength of the particle of mass m is x times the
de-Broglie wavelengths of the particle of mass 2m. Then the value of x is
21. Two identical containers A and B with frictionless pistons contain the same ideal gas
at the same temperature and the same volume V. The mass of the gas in A is
A
m and
that in the B is
B
m . The gas in each cylinder is now allowed to expand isothermally to
the same final volume 2V. The changes in the pressure in A and B are found to be P A
and 1.5 P A respectively.
3
A
B
m x
m
= .Then the value of x is
22. A slightly tapering wire of length l and end radii a and b is subjected to stretching
forces F, F as shown in the Figure. If Y is its Youngs modulus, The extension
produced in the wire is
5
K Fl
Yab t
. Then the value of k is

Paper-1 Page 11
CHEMISTRY: Max.Marks: 80
SECTION I
23. If ( ) P d Vs P (where P is pressure in atm and d is density in gm/L) is plotted for
He gas (assume ideal) at a particular temperature. If
( )
P 8.21atm
d
P d 5
dP
=
(
=
(

,
then the temperature will be
A) 160 K B) 320 K C) 80 K D) 240 K
24. A black, water insoluble powder (A) liberates yellowish green gas (B) on treatment
with conc. HCl and (A) dissolves to give a clear solution. Solid (A) when heated with
PbO
2
and HNO
3
(or) sodium bismuthate &
2 4
H SO gives a purple solution (C). The
purple solution is due to the formation of
A)
4
MnO
B)
2
4
MnO

C)
4
Mn
+
D)
2 3
Mn O

25.
Two liquids A and B are mixed at temperature T in a certain ratio to form an ideal
solution. It is found that the partial pressure of A i.e., P
A
is equal to P
B
, the pressure of
B for liquid mixture. What is the total pressure of the liquid mixture in terms of
0
A
P and
0
B
P ?
A)
0 0
A B
0 0
A B
P P
P P +
B)
0 0
A B
0 0
A B
2P .P
P P +
C)
0
A
0 0
A B
2P
P P +
D)
0
B
0 0
A B
2P
P P +

26. Salt AB has zinc blende structure. The nearest distance between
2 2
& A B
+
ions is
2.5
0
A .The edge length of AB unit cell is
A) 2.5
0
A B)
0
3.5A C)
0
5.0A D)
0
5.77A
27. Which of the following has maximum vapour pressure at a given temperature?
A)
OH
CHO
B)
OH
NO
2
C)
OH
COOH
D)
OH
CHO

Paper-1 Page 12
28. Which of the following represents Freundlich adsorption isotherm ?

x
m
1
P
a)

x
m
b)
P

x
m
1
P
c) log

x
m
d)
P

29. The number of d-electrons in Fe
2+
(Z =26) is not equal to that of
A) p electrons in Ne B) s electrons in Mg
C) d electrons in Fe D) p electrons in Cl

30.
.
B is ethyl alcohol then A is

A)

B)

C)

D)

Paper-1 Page 13
SECTION II
31. Which of the following reactions are correctly given?
A)
2 5 2 4 2
1
N O N O O
2

B)
2 3 2 2 2 4 2
Na SO H O Na SO H O
C)
4 3 2 2
NH NO N O 2H O

D)
2 2 2 2
SO Cl SO Cl
32. Which of the following is the correct structure for aspartic acid
O
OH
O
O H
N H
2
at the pH
indicated
A)

B)

C)

D)

33. Which of the following will produce acetone?
A)
2 4
4
3
H SO
HgSO
CH C CH B)
( )
( )
2 6
2
3
/
i B H
ii H O OH
CH C CH

C)
CH
3
C =C CH
3
KMnO
4
KOH heat
CH
3
CH
3
D)
3
CH CH CH OH +
34. 100ml 0.1M HCl is mixed with 100ml 0.1M NaOH. Identify the correct statement (s)
A) 0.137 . H k Cal A = B) 0.573 H kJ A =
C)
0
0.685 T C A = D)
0
2.865 T C A =
Paper-1 Page 14
SECTION III
Paragraph Type
Passage-I:
One mole of hydrocarbon (A) reacts with 1 mole of bromine giving a dibromo
compound
10 2 5
. C H Br (A) on treatment with cold dil. alkaline
4
KMnO solution forms a
compound
5 12 2
. C H O On ozonolysis gives equimolar amounts of propanone and ethanal.
(A) on reduction gives alkane (B).
35. The compound A must be
A)
3 3
CH CH CH CH = B) ( )
3 3
2
CH C CHCH =
C) ( ) ( )
3 3
2 2
CH C C CH = D)
3 2 2
CH CH CH CH =
36. The compound B must be
A) ( )
3 2 3
2
CH CH CH CH B) ( )
3 3
3
CH C CH
C)
3 2 2 3
CH CH CH CH D) ( )
3 2 3
3
CH C CH CH

PASSAGE 2
The cell potential ( )
cell
E of a reaction is related as
cell
G nFE , A = where G A represents
max. useful electrical work
n =no. of moles of electrons exchanged during the reaction for reversible cell reaction
( ) ( ) ( )
r r
d G V dp S .dT A = A A at constant pressure ( ) ( )
r
d G S .dT A = A
At constant pressure G H T. S A = A A ..1

( )
p
d G
G H
dT
A | |
A = A +
|
\ .
..2
cell
p
dE
dT
| |
|
\ .
is known as temperature coefficient of the e.m.f of the cell
37. The temperature coefficient of the e.m.f of cell,
p
dE
dT
| |
|
\ .
is given
A)
nF
S A
B)
S
nF
A
C)
S
nFT
A
D) nFE
Paper-1 Page 15
38. At 300 K, H A for the reaction ( ) ( ) ( ) ( )
2
Zn s AgCl s ZnCl aq 2Ag s is + + 218kJ / mol while
the e.m.f of the cell was 1.015v.
p
dE
dT
| |
|
\ .
of the cell is
A)
4 1
4.2 10 VK

B)
4 1
3.81 10 VK

C)
1
0.11VK
D)
4 1
7.62 10 VK

SECTION IV
Integer Answer Type
39. In a borax molecule the number of boron atoms having sp
3
hybridised are
40. The concentration of R in the reaction, R P , was measured as a function of time and
the following data is obtained :
[R] (molar) 1.0 0.75 0.40 0.10
t (min.) 0.0 0.05 0.12 0.18
The order of the reaction is :
41. How many aliphatic saturated alcohols having five carbon atoms show optical
isomerism?
42. The no. of chlorine atoms that are directly bonded to C in LEWISITE _______
43. The minimum
H
P required to prevent the precipitation of ZnS in a solution containing
0.01M
2
ZnCl and saturated with 0.10 M H
2
S is____
(Given ( ) ( )
1 2
21 20
sp a a 2
K ZnS 10 ; K K of H S 10

= = )
44. At STP the volume of nitrogen gas required to cover a sample of silica gel, assuming
Langmuir monolayer adsorption, is found to be
3 -1
1.33cm g of the gel. The area
occupied by each nitrogen molecule is
2
0.14nm . What is the surface area
( )
2
inm per gm
of silica gel ?
Paper-1 Page 16
MATHEMATICS: Max.Marks : 80
SECTION I
45.
a
and b
are non zero noncollinear vectors such that |a
| =2, a
. b
=1 and angle
between a
and b
is
3
t
. If r
is any vector satisfying r
. a
=2, r
. b
=8, ( r
+2a

10 b
) . (a
) =6 and r
+2a
10 b
= (a b
) then =
A)
1
2
B) 2 C)
4
3
D) 3
46. O is the circumcentre of ABC and
1
R ,
2
R and
3
R are the radii of the circum circles of
les
A
OBC,OCA and OAB, respectively. Let a, b and c be the sides of
le
A ABC. The value of
1 1 1
1 2 3
aR bR cR

+ + is
A)
3
abc
R
B)
3
4
abc
R
C)
3
2
abc
R
D)
abc
R

47. The set of values of o for which three distinct chords drawn from (o, 0) to the
ellipse
2 2
2 1 x y + = are bisected by the parabola
2
4 y x = is
A) (8, ) B)
( )
0, - 4+ 17 C)
( )
0, 4+ 17 D)
( )
8, 4+ 17

48. The area bounded by the curve
2
2 1 y x x = + + and tangent at (1, 4) and y-axis is
A) 2 sq. units B) 4 sq. units C)
4
3
sq. units D)
1
3
sq. units
49. The value of
0 0
0 0
3 cot76. cot16
cot76 cot16
+
+
is not equal to
A) Tan
0
46 B) Tan
0
226 C) cot
0
134

D) cot
0
136
50. If A is a (3x3) skew symmetric matrix, formed by using the digits 0,1,-1, then the
number of such matrices is
A) 10 B) 27 C) 8 D) 15
51. Total number of ways in which
2
n number of identical balls can be put in n numbered
boxes ( ) 1,2,3.....n such that
th
i box contains at least i number of balls is :
A)
2
1 n
c
n
B)
2
1
1
n
c
n
C)
1
2
2
2
n
C
n n
| | +
|
\ .
D) None
52. If ( ) 1 f x x = then the points where
( ) ( )
1
sin f x
is non differentiable, are

A) { } 0,1 B) { } 0, 1 C) { } 0,1, 1 D) { } 1,1

Paper-1 Page 17
SECTION II
53. The length of the normal chord at ( ) 8,7 on
2
2 4 3 0 y y x = is
A)
3 10
7
B)
45 10
9
C)
37 5
11
D)
40 10
9

54. If ( )
1
3
2 3 2 3 3 2
4 3 2 .
3 2 3 2
x x
x dx C
x x
|
o
+ | | | |
= +
| |
+
\ . \ .
}
( & | are prime nos.) then
A) , , o | are in G.P B) , , o | are in H.P
C) ,2 , o | are in H.P D) o | =
55. In , ABC A if 0
c a b
b c a
a b c
= then which of the following are correct.
A) tan tan 1
2 2
A B
=
B)
2 2
3
sin cos
2 2
A
A
| |
+ =
|
\ .

C)
2
9
sin sin cos
2 2
A
A B
| |
+ =
|
\ .
D) 3 cot tan A A =
56) Let :[0,1] [0,1] f be a function defined as
,
( )
1 ,
x x is rational
f x
x x is irrational
.Then which of the

following is incorrect
(A) f is bijective, invertible but not monotonic function
(B) f is discontinuous at exactly one point
(C) f is continuous at exactly one point
(D) f is differentiable nowhere
SECTION III
Paragraph Type
Passage I
Suppose
1 2
, z z and
3
z represent the vertices A, B and C of an equilateral triangle ABC
on the Argand plane. Then
2 1 3 2 1 3
AB BC CA z z z z z z = = = = Also
3 1
2 1
arg
3 3
z z
CAB
z z
t t
Z = =

Paper-1 Page 18

3 1 3 1
2 1 2 1
1 3
3 2 2
z z z z
cis i
z z z z
t | |
= =
` |

\ . )

( )
3 1 3 1 2
2 1 2 1
2 1 3 3
2 2 2 2
z z z z z
i i
z z z z

= =

On squaring, we get ( ) ( )
2 2
3 1 2 2 1
2 3 . z z z z z =

( )
1
A z
( )
2
B z ( )
3
C z

57. If the complex number
1 2 3
, , z z z represent the vertices of an equilateral triangle such that
1 2 3
, z z z = = then
1 2 3
z z z + + is equal to :
A) 0 B) 3 C) e D)
2
e
58. Let the complex numbers
1 2
, z z and
3
z be the vertices of an equilateral triangle. Let
0
z
be the circumcentre of the triangle, then
2 2 2
1 2 3
z z z + + is equal to :
A)
2
0
z B)
2
0
3z C)
2
0
9z D) 0
Passage II :
If the squares of a 8 8 chess board are painted either red or black at random.
59. The probability that not all squares in any column are alternating in colour is
A)
8
7
1
1
2
| |
|
\ .
B)
56
1
2
C)
7
1
1
2
D)
7
7
1
1
2
| |
|
\ .

60. The probability that the chess board contains equal number of red and black squares is
A)
64
32
64
2
C
B)
64
64
2 32
C)
32
64
2 1
2
D)
63
64
2 32

Paper-1 Page 19
SECTION IV
Integer Answer Type
61. If
2 2
0, , 4sec 9cos
2
and k ec
t
u u u
| |
e = +
|
\ .
, then the number of solutions of the system of
equations 3 4 3, 2 3 2,6 5 3 x y z x y z x y kz + = + = + + = is
62. The shortest distance between the two opposite edges of a regular tetrahedron of edge
8 units is
63. The straight lines 3 2 1,3 13 x y x y = + = and 6 5 x y = form a triangle. Let the set
3 5 5 21 3 3 5 14 11 13
, , , , ,
2 2 2 5 2 2 2 5 4 2
s
| || || || || |
=
`
| | | | |
\ .\ .\ .\ .\ . )
then the number of points which lies in the
interior of the triangle is
64. The solution of the differential equation ( ) ( )
3
3
1
dy
x x y x x y
dx
+ + = + is
( )
2
2
1
k
x
x y ce x
+ = + + then
( )
3
4
2
___
k
k
+
=
65. A man starts from the point ( ) 3,4 P and reaches point ( ) 0,1 Q touching x axis at
( ) ,0 R o such that PR RQ + is minimum, then 5o =
66. If d is the minimum distance between the curves ( ) ( ) log
x x
e
f x e and g x = = then the value
of
6
d .

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2013_JEE-ADVANCED_MODEL PAPER

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are non zero noncollinear vectors such that |a

is any vector satisfying r

is non differentiable, are

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