(Approved by AICTE, New Delhi and Affiliated to Anna University of Technology, Coimbatore An I!" #$$%&'$$( Certified Instit)tion DEPARTMENT OF FASHION TECHNOLOGY FT2255 - DYEING, PRONITING AND POLLUTION CONTROL TWO MARK QUESTION WITH ANSWER Branch: B.Tech Year / Sem: II / III Unit - II COLOURATION 1. How dyes are classified based on application? 2. Distinguish between i) a dye and pigment Points of Difference Dyes Pigments Solubility They are sol)ble *igments are colo)rants that are insol)ble in water and most of the solvents Number Available in +arge n)mber Comparatively lesser in n)mber Product resistance +ower as compared to pigments ,ery high Light fastness +ower Dyes are very m)ch v)lnerable- +ights destroy colored ob.ects by brea/ing open electronic bonding within the molec)le Traditionally pigments have been fo)nd to be more lightfast than dyes Size Dye molec)les are comparatively smaller it0s li/e comparing a football (pigment to say a head of a pin (dye *igment particles are abo)t %1' microns in si2e- (% micron 3%4%$$$ meter- It means that the particles can be seen )nder a magnifying glass Bonding Ta/ing the e5ample of dyeing a wood s)rface, the dye and the s)bstrate (wood that is dyed are chemicals, which have certain feat)res called f)nctional gro)ps- At the level of molec)les these gro)ps serve as open poc/ets of electrostatic charges (6 or 1- The f)nctional gro)p in dyes, serve as a method for attaching the dye to the wood 7or e5ample ta/ing the e5ample of a wood s)rface *igment re8)ires the help of a binder for gl)ing- As it is an inert s)bstance which is merely s)spended in a carrier4binder Structure during the application process D)ring application process there is a temporary alteration in the str)ct)re of the dyes D)ring application, pigments have the capacity to retain partic)late or crystalline str)ct)re Imparting of Colours Dyes can only impart colo)r by selective absorption of the dyes *igments impart colo)rs by either scattering of light or by selective absorption Combustible properties Ta/ing the e5ample of a Candle ma/ing process, if the candles are dyed it is easily comb)stible and can be applied thro)gho)t the candle In the e5ample of a candle ma/ing as pigments are colored particles, they tend to clog a wic/ when b)rned- This ma/es them )ndesirable for a candle if it is colored thro)gho)t and )sed for b)rning Chemical Composition Us)ally the dyes are organic (i-e- carbon1 based compo)nds 9hile pigments are normally inorganic compo)nds, often involving heavy to5ic metals Longevity factor The dye based printing in/s do not last as long as the pigment in/s In case of in/ based printing prints made with pigments lasts longer Printing on substrates Compatible with almost all the s)bstrates that needs to be dyed "wing to the physical ma/e)p of the pigment in/s the range for s)itable s)bstrates are limited Colour gamut Ta/ing the case of printing in/s, dye based in/s offers a wide variety As compared to dye1based in/s, pigment in/sets somewhat lags behind, on the same paper stoc/ :- Indicate the fibres for which the following dyes have affinity: a. Reactive dyes b. Acid dyes c. Vat dyes d. Disperse dyes e. Direct dyes? ;eactive dyes < cotton, wool, sil/, polyamide and viscose rayon Acid dyes < sil/ and nylon ,at dyes < cotton Disperse dyes < polyester and acrylic Direct dyes < cotton and wool 4. Define : Substantivity or affinity The process in which dye molec)les are attracted by physical forces at the molec)lar level to the te5tile- The amo)nt of this attraction is /nown as =s)bstantivity=- The higher the s)bstantivity the greater the attraction of the dye for the fiber 5. Define : Exhaustion The amo)nt dyes absorbed by the fibre e5pressed in percentage is called as E5ha)stion 6. Define : M:L ratio The relationship between material and li8)or that means amo)nt of dye li8)or re8)ired for dyeing of )nit weight of material- E5& >& +& ; is %&'$ means '$ liters of dye sol)tion re8)ired for dyeing of % /g fabric- 7. Define: Shade percentage. The 8)antity of dyest)ff ta/en for a dyeing e5pressed as a percentage of the dry weight of the fibre to be dyed- !hade percentage is ' means ' gram of dyes ta/en for dyeing of %$$g of a te5tile material- 8. List the common dyeing assistants used dyeing. 9ater softening, E5ha)sting agents, 9etting Agent, Dispersing agents, +eveling agents, ;etarding agents- 9. Write down the liquor ratio commonly used in the following machines. ?igger, @ier, 9inch, ATA* machines for yarn and fabric, !oft overflow .et dyeing, Barn pac/age dyeing ?igger < %-C @ier < %& C 9inches < %& '$ to %& D$ ATA* machines for yarn and fabric 1 %&( to %&%$ !oft overflow .et dyeing < %&( to %&%$ Barn pac/age dyeing < %&C 10. What classes of dye are suitable for dyeing cotton fabric? ;eactive dye, direct dye, s)lph)r dye, a2oic dyes and vat dyes 11. What are the advantage & disadvantage of a beam dyeing machine? Advantage The fabric is p)t )nder controlled tension, and is wo)nd on to a perforated beam- This res)lts in elimination of creases from the fabric- It also ens)res total control of dimensions of the roll of fabric- The fabric is not allowed to do any movement d)ring the process of dyeing- This act)ally means that there is no application of mechanical action on to the fabric- As shown in the fig)re, there is no movement of the fabric as the hydrostatic press)re of the p)mp forces the dye li8)or thro)gh the fabric roll- Disadvantage The machine is not s)itable for light weight and /nitted fabric dyeing- 12. What are steps involved for mechanism of dyeing? Absorption *enetration and 7i5ation 13. Give the relative strength, dyes and suitable fibers for following bonds. a- van der 9aalsE forces b- Aydrogen bonds c- salt lin/age d- Covalent bonds ,an der 9aalsE forces 1 % Aydrogen bonds 1 : !alt lin/age 1 F Covalent bonds 1 :$ 14. Why are direct dyes also called as substantive`? Direct dyes have direct affinity with cotton fibres- !o that it is called s)bstantive dyes- 15. List any four properties of direct dyes. Direct dyes give bright shades b)t e5hibit poor wash fastness- Direct dyes are defined as anionic dyes with s)bstantivity for cell)losic fibres, normally applied from an a8)eo)s dye bath containing an electrolyte, either sodi)m chloride (NaCl or sodi)m s)lfate (Na'!"D Their ionic nat)re is anionic They are sol)ble in water They have an affinity for a wide variety of fibers s)ch as cotton ,viscose, sil/ .)te ,linen etc 16. How are direct dyes classified? !elf < leveling dyes !alt controllable dyes Temperat)re controllable dyes 17. Why are reactive dyes so called? Classify the reactive dyes with examples on the basis of application? Its chemically react with cell)lose fibre to form a covalent bond- !o that it is called as reactive dyes- Aot brand Cold brand ,! brand 18. List any four properties of reactive dyes. ;eactive dyes are cationic dyes, which are )sed for dyeing cell)lose, protein and polyamide fibres- ;eactive dyes are fo)nd in power, li8)id and print paste form- D)ring dyeing the reactive gro)p of this dye forms covalent bond with fibre polymer and becomes an integral part of the fibre- ;eactive dyes are sol)ble in water- They have very good light fastness with rating abo)t The dyes have very stable electron arrangement and can protect the degrading effect of )ltra1 violet ray- Te5tile materials dyed with reactive dyes have very good wash fastness with rating abo)t D1C d)e to strong covalent bonds formed between fibre polymer and reactive gro)p of dye- ;eactive dye gives brighter shades and has moderate r)bbing fastness- Dyeing method of reactive dyes is easy- It re8)ires less time and low temperat)re for dyeing- ;eactive dyes are comparatively cheap ;eactive dyes have good perspiration fastness with rating D1C- ;eactive dyes have good perspiration fastness- 19. In reactive dyeing, a) Why salt is added in two or more portion? To provide the )niform dyeing for entire fabric- b) Why Glauber`s salt is preferred in the case of dyesG ;e8)ired less amo)nt salt and provide the higher e5ha)stion rate 20. Why is after-treatment necessary for the reactive dyed goods? To remove the fi5ed dyes from s)rface dyed fabric- To improve the fastness properties of dyed materials- 21. What are the advantages of reactive dyes over other dyes classes with respect to dyeing cellulosic material? Hood washing fastness d)e to formation of covalent bond between the fibres and dyes Iright colo)r and more shades are possible +ow cost Easy to apply 22. What steps are involved in the application of a reactive dye to a cellulose fibre? *reparation fabric *reparation of dye sol)tion Dyeing E5ha)stion 7i5ation 9ashing !oaping 9ashing 23. What dyeing assistants are used in reactive dyeing? State their functions. E5ha)sting agents < To promote e5ha)stion process or dye )p ta/e- E5- Common salt 7i5ing agents 1 To increase the pA val)e to %$ to%% (al/aline pA 1 To fi5 the dye molec)le on the fibre to ma/e covalent bond 24. Indicate the colour fastness properties of reactive dyes. 9ashing fastness < good (D1C +ight fastness < moderate and good (:1D Dyeing with Vat Dyes 25. What are vat dyes? The dye is named from the container (,at that )sed for rotting the dye with al/ali sol)tion 26. State the sub-classes of vat dyes. The %N (indanthrene normal1gro)p of dyeing temperat)res of J$KC- In s)ch dyeing s)bstances no salt is added to the dye bath beca)se they have high portion of le)co dyes for cotton- The %9 (indanthrene 9arm 1 gro)p of dyeing temperat)res of C$KC- In s)ch dyeing s)bstances some addition of salt is re8)ired so to aid e5ha)stion- The I@1 gro)p of dyeing s)bstances re8)ires low concentration of Na"A with dyeing temperat)re of '$KC- 27. How would you classify the vat dyes according to the chemical constitution? 1 Anthra8)inonoid vat dyes 1 Indigoid vat dyes 1 !)lph)rised vat dyes 28. What is vatting? ,atting is a process of insol)ble vat dyes is convert to sol)ble by )sing of hydrose and sodi)m hydro5ide- 29. Write down the properties of vat dyes? 1 !)perior color fastness properties, which are e5ceptional in other dye classes 1 Needs vatting for application 1 9ater insol)ble dyes 1 A n)mber of colors can be prod)ced 1 ;)bbing fastness is not good, b)t is can be easily lessened with special treatments to the fabric 1 Especially )sed for cell)lose fiber with pA (meas)re of hydrogen ion concentration control- 30. State the different methods of oxidation of vat dyed goods. Air o5idation Chemical o5idation 31. What fibres can be dyed with vat dyes? Cotton fibres 32. What are the dyeing conditions for vat dyes? Temp 1 ($KC Time < ' hrs pA 1 Al/aline (%$ 33. Write down the steps involved in the dyeing of cotton with vat dyes. *reparation fabric *reparation of dye sol)tion Dyeing E5ha)stion "5idation (7i5ation 9ashing !oaping 9ashing Disperse dyes 34. Why are disperse dyes called so? Dyes with e5tremely low sol)bility in water which is in finely dispersed state- 35. List any four properties of disperse dyes. Disperse dyes are nonionic dyes- !o they are free from ioni2ing gro)p- They are ready made dyes and are insol)ble in water or have very low water sol)bility- They are organic colo)ring s)bstances which are s)itable for dyeing hydrophobic fibres- Disperse dyes are )sed for dyeing man made cell)lose ester and synthetic fibres specially acetate and polyester fibres and sometimes nylon and acrylic fibres- Carrier or dispersing agents are re8)ired for dyeing with disperse dyes- Disperse dyes have fair to good light fastness with rating abo)t D1C- The wash fastness of these dyes is moderate to good with rating abo)t :1D- "f all dyest)ffs disperse dyes are of smallest molec)lar si2e- Henerally disperse dyes are derivatives of a2o, anthro8)inone, nitro and 8)inine gro)ps- They do not )ndergo any chemical change d)ring dyeing- In presence of nitro)s o5ide, te5tile materials dyed with certain bl)e and violet disperse dyes with an anthra8)inone str)ct)re will fade- This is called gas fading of disperse dyes which is a defect of this dye 36. List the auxiliaries used in disperse dyeing of polyester stating their function. 9etting agents < ;ed)ce s)rface tension of water and ma/e water wettablity Disperse dyes < To disperse the dyes and red)ce the molec)le si2e of dyes- Acetic acid < To maintain the pA of dye sol)tion (pA 1 D- $ 37. What is the principle of carrier dyeing? It is nothing b)t swelling the polyester fibres with help of carrier sol)tion and increase the pore si2e of polyester fibres to facilitate dye penetration- 38. State the factors to be considered while selecting a carrier for polyester dyeing? Economy, leveling and barer coverage Effect on light fastness high, ;esistance to spotting, Ease of removal To5icity, "dor d)ring and after dyeing 39. List the different machines used for dyeing polyester with disperse dyes. ATA* Ieam dyeing machine, ATA* !oft flow dyeing m4c, ATA* .igger m4c 40. List the different method used for dyeing polyester with disperse dyes. Carrier method ATA* dyeing method Thermosol >ethod 41. Why the reduction clearing treatment given to the polyester dyed goods? 1 To remove the )nfi5ed dyes with help of hydrose- 42. What are the advantage and disadvantage of a jet dyeing machine? Advantages 1 Dyeing time is short compared to beam dyeing- 1 >aterial to li8)or ratio is %&C (or %&J 1 *rod)ction is high compared to beam dyeing machine- Disadvantages 1 Cloth is dyed in rope form 1 ;is/ of entanglement 1 Chance for crease formation- 43. State the steps involved in thermosol process. 7o)r steps involved for dyeing i- padding the material ii- Drying the padded fabric iii- 7i5ation of the dyest)ff Dry heat at %($LC for #$ seconds (or Dry heat at '%$LC for J$ seconds iv- After treatment 44. What are the advantages of the thermosol process. 1 Ieing contin)o)s, large lots can be dyed economically- 1 !ince no carrier is involved, resid)es, and fastness problems are red)ced- 1 Dye fi5ation is e5cellent- 1 ;ope mar/s are eliminated beca)se the fabric is processed in open width- 1 Aeat1setting and dyeing may be carried o)t sim)ltaneo)sly- 1 Dyeability is not affected by prior heat1setting 45. Why is heat setting necessary for polyester fabric dyeing? Aeat1setting thermoplastic fibres helps the polymer molec)les settle into conformations 9here they are closer together- Intermolec)lar attractive forces are increased- This may decrease both the rate of dyeing and the amo)nt of dye that can be e5ha)sted to the fabric- If this is a problem, heat1setting may be done after the fabric has been dyed 46. What are the methods used for polyester and cotton blend dyeing? E5ha)st Dyeing >ethods& %- Two Iath Dyeing *rocesses & 7irst to dye the polyester and then cotton '- "ne Iath Dyeing *rocess& Disperse and ,at, Disperse and ;eactive, Disperse and Direct Dyes :- Inverse >ethod& 7irst to dye the cotton and then polyester Contin)o)s processes %- Contin)o)s dyeing with Disperse and ,at dyes, Disperse and ;eactive, Disperse and Direct Dyes '- Thermosol4thermo1fi5ation process with disperse and reactive dyes :- Contin)o)s dyeing with pigment colo)rs D- Contin)o)s dyeing with Disperse and sol)bilised ,at dyes C- Contin)o)s dyeing with Disperse dyes alone )sing a special a)5iliary 47. What do you mean by fastness properties? 7astness is the resistance colo)r of a te5tile material to specific chemical agencies "r Color fastness refers to the resistance of color to fade or bleed of a dyed or printed te5tile materials to vario)s types of infl)ences e-g- water, light, r)bbing, washing, perspiration etc- to which they are normally e5posed in te5tile man)fact)ring and in daily )se- 48. List out the fastness method. 9ashing, ;)bbing, Daylight, Artificial light, *erspiration, Dry cleaning, Aeat setting !)blimation