34 Chemical Arithmetic

1. A mixture of sand and iodine can be separated by

[Kerala CEE 2002]
(a) Crystallisation (b) Sublimation
(c) Distillation (d) Fractional distillation
2. The element similar to carbon is
(a) Mg (b)
Mn
(c)
Sn
(d)
Po
2. The law of multiple proportions was proposed by
[IIT 1992]
(a) Lavoisier (b) Dalton
(c) roust (d) !ay"Lussac
4. # L of
$
N combines with % L of
$
H to form $L of
%
NH under the same conditions& This illustrates
the
(a) Law of constant composition
(b) Law of multiple proportions
(c) Law of reciprocal proportions
(d) !ay"Lussac's law of (aseous volumes
5. )ne sample of atmospheric air is found to have
*&*%+ of carbon dioxide and another sample
*&*,+& This is evidence that
(a) The law of constant composition is not always
true
(b) The law of multiple proportions is true
(c) Air is a compound
(d) Air is a mixture
6. )ne part of an element A combines with two parts
of another B& Six parts of the element C combine
with four parts of the element B& if A and C
combine to(ether the ratio of their wei(hts will be
(overned by [AMU 1984]
(a) Law of de-nite proportion
(b) Law of multiple proportion
(c) Law of reciprocal proportion
(d) Law of conservation of mass
7. The maximum amount of
,
BaSO precipitated on
mixin( e.ual volumes of
$
BaCl (*&/ M) with
, $
SO H (#M) will correspond to
0AIIMS 1997]
(a) *&/ M (b) #&* M
(c) #&/ M (d) $&* M
8. Crystals of which pair are isomorphous [MP PMT
1985]
(a)
, ,
1 SnSO ZnSO (b)
, ,
1 CaSO MgSO
(c)
, ,
1 MgSO ZnSO (d)
, ,
1 NiSO PbSO
9. 2 is the molecular wei(ht of
,
KMnO & The
e.uivalent wei(ht of
,
KMnO when it is
converted into
, $
MnO K is
(a) M (b) % 3 M
(c) / 3 M (d) 4 3 M
10. An a.ueous solution of 5&% g of oxalic acid
dihydrate is made up of to $/* ml& The volume of
*&#
NaOH N
re.uired to completely neutralise
#* ml of this solution is [IIT 2001]
(a) ,* ml (b) $* ml
(c) #* ml (d) , ml
11. The normality of orthophosphoric acid havin(
purity of 4*+ by wei(ht and speci-c (ravity #&/,
would be [CPMT 1992]
(a) ##N (b) $$N
(c) %%N (d) ,,N
12. The e.uivalent wei(ht of phosphoric acid
) (
, %
PO H in the reaction1
O H PO NaH PO H NaOH
$ , $ , %
+ + is
[AIIMS 1999; BHU 2005]
(a) $/ (b) ,6
(c) /6 (d) 67
13. 8olume of *&5 M NaOH re.uired to neutrali9e
%
%*cm of *&, M HCl is [KCET 1995]
(a)
%
%*cm (b)
%
$*cm
(c)
%
/*cm (d)
%
,/cm
14. )ne mole of potassium dichromate completely
oxidises the followin( number of moles of ferrous
35 Chemical Arithmetic
sulphate in acidic medium
[MP PET 1998]
(a) # (b) %
(c) / (d) 5
15. The number of e.uivalents of
% $ $
O S Na re.uired
for the volumetric estimation of one e.uivalent of
+ $
Cu
is
[Kerala MEE 2000]
(a) # (b) $
(c) %3$ (d) %
1. (b) :odine shows sublimation and hence
volatali9es on heatin(1 the vapour condenses
on coolin( to (ive pure iodine&
2. (c) Carbon and tin both are same (roup elements
so have similarities in properties&
3. (b) Law of multiple proportions was proposed by
Dalton and veri-ed by ;er9elius&
4. (d) !ay" Lussac<s law = The volumes of the
reactin( (ases and those of the (aseous
products bear the simple ratio (also called the
law of (aseous volumes)&
5. (d)
6. (c) The wei(hts of two elements combinin( with a
-xed amount of the third element will bear the
same ratio(or simple multiple of it) in which
they themselves react&
7. (a) HCl BaSO SO H BaCl $
, , $ $
+ +
)ne mole of
$
BaCl reacts with one mole of
, $
SO H & >ence *&/ mole will react with *&/
mole of
, $
SO H i.e.
$
BaCl is the limitin(
rea(ent&
8. (c) :somorphous substance molecules contain the
same number of atoms bonded in similar
fashion&
9. (a)
5
, $
4
,
+ +
MnO K KMnO
Chan(e in *&/ per atom # 5 4 = =
?.uivalent wei(ht of
,
KMnO
atom per *&/ of Chan(e
of wei(ht 2olecular
,
KMnO
= M
M
= =
#
&
10. (a) )xalic acid NaOH
$ $ # #
V N V N =
$ $ #
#***
V N V
V E
W
=

V = # & * #*
$/*
#***
5%
% & 5
V@ ,*ml.
11. (a) 4*+ by wei(ht gm PO H gm #** 4*
, %

solution3sample
/, & #
#**
= =
d
W
V N N ##
/, & # 3 #** 67
#*** 4*
=

= &
12. (d)
) ( ) (
$
,
, $
%
,
, %

+
NaPO
PO NaH
PO
PO H NaOH
#
67
ionisable of no&
= =
+
H
MW
EW &
13. (b) NaOH HCl
$ $ # #
V N V N = A %* , & * 5 & *
#
= V A
ml V $*
#
= &
14. (d)
+

=
%
4 $
5
Cr
n
O Cr
A
+ + + + +

=
Fe
n
Fe
#
e.& of
4 $ $
O Cr K @ e.& of
,
FeSO
(SET -1)

Chemical Arithmetic
36

# 5 # =

15. (b)
$
$
$ Cu! ! Cu +
+

$ $ $ $
$ ! ! Cu Cu! +
5 , $ % $ $
$ $ $ O S Na Na! O S Na ! + +
% $ $
$
$ O S Na Cu
+