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2)
1/ 2
2 2
2 1
2 2
2 1
2
r r
v v
t
(
3)
1/ 2
2 2
1 2
2 2
2 1
2
v v
r r
t
(
4)
1/ 2
2 2
1 2
2 2
2 1
1
2
v v
r r t
(
Ans : 1
93. Force constants of two wires A and B oft eh same material are K and 2K respectively. If the two wires
are stretched equally, then the ratio of work done in stretching
A
B
W
W
| |
|
\ .
is
1) 2) 1/3 3) 4) 3/2
Ans : 3
94. Water rises in a capillary tube upto a height of 10 cm whereas mercury depresses in it by 3.42 cm. If
the angle of contact and density of mercury are 135
0
and 13.6 gm/cc respectively, then the ratio of the
surface tension of water and mercury will be nearly
1) 2 : 13 2) 13 : 2 3) 5 : 16 4 ) 16 : 5
Ans : 1
95. Two capillary tubes of length in the ratio 2 : 1 and radii in the ratio 1 : 2 are connected in series.
Assume the flow of the liquid through the tube is steady. Then the ratio of pressure difference across
the tubes is
1) 1 : 1 2) 1 : 8 3) 1 : 16 4) 32: 1
Ans : 4
96. When a liquid is heated in a glass vessel, its coefficient of apparent expansion is 1.03 x 10
-3
/
0
C. When
the same liquid is heated in a copper vessel, its coefficient of apparent expansion is
3
1.006 10 C
.
If the coefficient of linear expansion of copper is
6
17 10 C
2)
4
8.5 10 C
3)
6
9 10 C
4)
4
27 10 C
Ans : 3
97. A horizontal uniform tube, open at both ends is containing a liquid of certain length at some
temperature. When the temperature is changed, the length of the liquid in the tube is not changed. If
is the coefficient of linear expansion of the material of the tube and is the coefficient of
volume expansion of the liquid, then
1) = 2) 2 = 3) 3 = 4) 4 =
Ans : 2
98. Match the following from Table A, in the case of gases, with those in Table B
Table A Table B
a) Work done in isobaric process d)
2
1
log
e
V
nR
V
| |
|
\ .
b) Work done in isothermal process e) ( )
2 1
P V V
c) Work done in adiabatic process f)
( )
1 2
1
nR T T
g) Zero
1) , , a g b h c e 2) , , a c b d c f
3) , , a h b g c e 4) , , a e b d c g
Ans : 2
99. Two cylinders A and B fitted with pistons contain equal amounts of an ideal diatomic gas at 300K.
Piston of A is free to move and piston of B is fixed. Same amount of heat is given to the gases in the
two cylinders. Temperature of the gas in cylinder A increases by 30K. Then, increase in temperature
of the gas in the cylinder B is ( = 1.4 for diatomic gas)
1) 42 K 2) 24 K c) 36 K 4) 54 K
Ans : 1
100. The temperatures at the two ends A and B of a rod of length 25cm and circular cross section are
100 C and 0 C respectively. In the steady state the temperature at a point 10cm from the end B is
(Ignore loss of heat from curved surface of the rod)
1) 40 C 2) 60 C 3) 80 C 4) 90 C
Ans : 1
101. A wire of length L and linear density m is stretched by a force T and the frequency is
1
n . Another
wire of the same material of length 2L an same linear density is stretched by a force 9T and its
frequency is
2
n . Value of ( )
2 1
n n is
1) 1 : 2 2) 4 : 1 3) 1 : 3 4) 3 : 2
Ans : 4
102. A pipe closed at one end and open at the other end resonates with a sound of frequency 135Hz and
also with 1675 Hz, but not at any other frequency intermediate between these two. Then, the frequency
of the fundamental note of the pipe is
1) 30 Hz 2) 15 Hz 3) 60 Hz 4) 7.5 Hz
Ans : 2
103. A small angled prism of refractive index 1.4 is combined with another small angled prism of refractive
index 1.6 to produce dispersion without deviation. If the angle of first prism is 6 , the angle of the
second prism is
1) 2 2) 8 3) 6 4) 4
Ans : 4
104. The magnifying power of the astronomical telescope for normal adjustment is 50. The focal length of
the eye piece is 2cm. The required length of the telescope for normal adjustment is
1) 25 cm 2) 102 cm 3) 100 cm 4) 98 cm
Ans : 2
105. Light of wavelength from a point source falls on a small circular obstacle of diameter d. Dark and
bright circular rings around a central bright spot are formed on a screen beyond the obstacle. The
distance between the screen and obstacle is D. Then, the condition for the formation of rings is
1)
4
D
~ 2)
4
d
D
~ 3)
2
4
d
D
~ 4)
2
d
D
~
Ans : 3
106. A bar magnet of moment of inertia I is vibrated in a magnetic field of induction
4
0.4 10 T
. The time
period of vibration is 12 sec. The magnetic moment of the magnet is
2
120Am . The moment of inertia
of the magnet is (in
2
kgm ) approximately
1)
2
1728 10
2)
4
172.8 10
3)
2 2
2.1 10
4)
2
1.57 10
Ans : 2
107. A short magnet of magnetic moment M, is placed on a straight line. The ratio of magnetic induction
fields
1 2 3
B , B , B values on this line at points which are at distances 30cm, 60cm and 90cm
respectively from the centre of the magnet is
1) 1 : 2 : 3 2) 27 : 3.37 : 1 3) 37.3 : 1 : 27 4) 27 : 8 : 3.37
Ans : 2
108. Two capacitors having capacitances
1
C and
2
C are charged with 120V and 200V batteries
respectively. When they are connected in parallel now, it is found that the potential on each one of
them is zero. Then
1)
1 2
3 5 C C = 2)
1 2
5 3 C C = 3)
1 2
8 5 C C = 4)
1 2
9 5 C C =
Ans : 1
109. A parallel plate capacitor with a dielectric slab of dielectric constant 3 filling the space between the
plates is charged to a potential V. The battery is then disconnected and the dielectric slab is withdrawn.
It is then replaced by another dielectric slab of dielectric constant 2. If the energies stored in the
capacitor before and after the dielectric slab is changed are
1
E and
2
E , then
1 2
E E is
1)
3
2
2)
9
5
3)
4
9
4)
2
3
Ans : 4
110. Copper and carbon wires are connected in series and the combined resistor is kept at 0 C . Assuming
the combined resistance does not vary with temperature, the ratio of the resistances of carbon and
copper wires at 0 C is (Temperature coefficients of resistivity of copper and carbon respectively are
3
4 10 C
and
3
0.5 10 C
)
1) 2 2) 4 3) 8 4) 6
Ans : 3
111. The emf of a cell E is 15V as shown in the figure with an internal resistance of 0.5O. Then the value
of the current drawn from the cell is
2O
1O
7O
0.5O
8O
10O
15V
1) 1A 2) 3A 3) 2A 4) 5A
Ans : 1
112. When the temperature difference between the junctions of a given thermocouple is 120 C , the thermo
emf is 30mV. The temperature of hot junction is decreased by 20 C and cold junctions temperature
is increased by 6 C . The percentage decrease in thermo emf is (assume thermo emf is directly
proportional to the temperature difference)
1) 21.6 2) 43 3) 2.16 4) 20.4
Ans : 1
113. A 0.01 H inductor and 3ohm resistance are connected in series with a 220 V, 50 Hz AC source.
The phase difference between the current and emf is
1)
4
radians 2)
2
radians 3)
6
radians 4)
3
radians
Ans : 3
114. An electron beam in a TV picture tube is accelerated through a potential difference of V volts. It
passes through a region of transverse magnetic induction field (B) and follows a circular orbit of
radius r. The induced magnetic field (B) is
1)
2mV
er
2)
2
2mV
er
3)
2mV
r
4)
2mVr
e
Ans : 2
115. In Moseleys law
( ) v a z b = , the values of the screening constant for K series and L series of
X rays are respectively
1) 2, 4 2) 1, 6.4 3) 1, 4 4) 4, 6
Ans : 2
116. The
=
1) 5.82 KeV 2) 17.5 KeV 3) 40.82 KeV 4) 23.32 KeV
Ans : 1
117. The purpose of using heavy water in nuclear reactor is
1) to decrease the energy of fast neutrons to the thermal energy
2) to increase the energy released in nuclear fission
3) to cool the reactor at room temperature
4) to make the dynamo blades to work well
Ans : 1
118. A
235
U reactor generates power at a rate of P producing
18
2 10 fissions per second. The energy
released per fission is 185 MeV. The value of P is
1) 370 Megawatts 2) 59.2 Megawatts
3)
8
370 10 Megawatts 4) 0.59 Megawatts
Ans : 2
119. A pnp transistor is used in common emitter mode in an amplifier circuit. When base current is changed
by an amount
B
I , the collector current changes by 4mA. If the current amplification factor is 60,
then the value of
B
I A is
1) 60A 2) 15A 3) 240 mA 4) 66.6A
Ans : 4
120. The necessary condition in making of a junction transistor (E emitter, B base and C collector)
1) E and B are heavily doped and C is lightly doped
2) E and B are lightly doped and C is heavily doped
3) E is heavily doped, B is thin and lightly doped and C is moderately doped
4) E and C are lightly doped and B is thick and heavily doped
Ans : 3
CHEMISTRY
121. The energy required to overcome the attractive forces on the electrons, w, of some metals is listed
below. The number of metals showing photoelectric effect when light of 300nm wavelength falls on it
is
1)
4 2) 6 3) 8 4) 5
Ans : 1
122. If the uncertainity in velocity of a moving object is
6 1
1.0 10 ms
and the uncertainity in its position
is 58m, the mass of this object is approximately equal to that of
( )
34
6.626 10 h Js
=
1) Electron 2) Helium 3) Deuterium 4) Lithium
Ans : 1
123. The correct order of atomic radius of Li, Be and B is
1) Li > Be > B 2) B > Be > Li 3) B > Li > Be 4) Li > B > Be
Ans : 1
124. The number of and bonds present in acetylene are respectively
1) 2, 3 2) 3, 2 3) 3, 3 34) 2, 2
Ans : 2
125. The total number of antibonding electrons in N
2
and O
2
molecules respectively is
1) 4, 8 2) 4, 6 3) 6, 8 4) 5, 8
Ans : 2
126. Consider the following statements for the reaction
3 2 2
5 6 3 6 3 KIO KI HCl I KCl H O + + + +
1) I
is reduced to
2
I 2)
3
IO
is oxidized to
2
I
3)
3
IO
is reduced to
2
I
4) Oxidation number of I increases from -1 (in KI) to zero (in
2
I )
The correct statements are
1) 1, 3 and 4 2) 1, 2 and 4 3) 3 and 4 4) 1 and 4
Ans : 3
127. Two gases of molecular masses M
A
and M
B
are at temperatures T
A
and T
B
respectively. If
A A B A
T M T M = , which one of the following properties has the same value for both the gases ?
1) Density 2) Pressure 3) Kinetic energy 4) RMS velocity
Ans : 4
128. The weight in gm, of the non volatile solute urea ( )
2 2
NH CONH to be dissolved in 100g of water in
order to decrease its vapour pressure by 1.8% is
1) 0.6 2) 6.0 3) 0.3 4) 3.0
Ans : 2
129. The boiling point of a solution containing 68.4g of sucrose (molar mass =
1
342gmol
) in 100g of
water is
1) 100.02 C 2) 98.98 C 3) 101.02 C 4) 100.512 C
Ans : 3
130. A certain quantity of electricity is passed through aqueous
( )
2 4
3
Al SO and
4
CuSO solutions
connected in series. 0.09g of Al is deposited on cathode during electrolysis. The amount of copper
deposited on cathode in grams is
1) 3.18 2) 0.318 3) 31.8 4) 0.636
Ans : 2
131. Molar conductivities of
2 2 4
BaCl , H SO and HCl at infinite dilution are
1 2
X , X and
3
X respectively.
Molar conductance of
4
BaSO at infinite dilution is
1)
( )
1 2 3
2
X X X +
2)
( )
1 2 3
2
2
X X X +
3)
1 2 3
X X X + 4)
1 2 3
2 X X X +
Ans : 4
132. Atoms of an element A occupy
2
3
tetrahedral voids in the hexagonal close packed (hcp) unit cell
lattice formed by the element B. The formula of the compound formed by A and B is
1)
2 3
A B 2)
2
A B 3)
2
AB 4)
4 3
A B
Ans : 4
133. The temperature coefficient of a reaction is 2.5. If its rate constant at
1
T K is
3 1
2.5 10 s
, the rate
constant at
2
T K in
1
s
is : ( )
2 1
T T >
1)
2
6.25 10
2)
3
1.0 10
3)
3
6.25 10
4)
2
1.0 10
Ans : 3
134. For the equilibrium
( ) ( ) ( )
; 0.82atm
P g g g
A B C K + = at 27 C . At the same temperatures its
C
K
in
1
mollit
is :
( )
1 1
0.082lit atmmol K R
=
1) 0.33 2) 0.033 3) 3.3 4) 1.0
Ans : 2
135. If the solubility product of
2
MgF at a certain temperature is
10
1.08 10
, its
solubility in
1
mol l
is
1)
4
3.0 10
2)
5
1.04 10
3)
4
7.3 10
4)
5
3.0 10
Ans : 1
136. In the reaction
( ) ( ) ( )
2 2 2 5
4 2 , 111
g g g
NO O N O H kJ + A = if
( )
2 5 s
N O is formed instead of
( )
2 5 g
N O , the H A value in kJ is (
sublimation
H A for
1
2 5
54 mol N O kJ
= )
1) 219 2) 165 3) 57 4) + 219
Ans : 1
137. In which of the following reactions,
2 2
H O acts as oxidizing agent ?
1)
2 2 2 3 2
KNO H O KNO H O + + 2)
2 2 2 2
2 Cl H O KCl O + +
3)
2 2 2 2 2
2 Ag O H O Ag H O O + + + 4)
2 2 2 2 2
2 2 NaOH H O Na O H O + +
Ans : 1
138. Zinc reacts with hot and concentrated NaOH and forms
1)
2
O 2)
2
H 3)
( )
2
2
Zn OH Na O + 4) ZnO
Ans : 2
139. Orange red coloured monoxide is
1)
2
Li O 2)
2
K O 3)
2
Na O 4)
2
Cs O
Ans : 4
140. Observe the following statements :
1)
3 3
H BO is used as antiseptic 2) In
2 6
B H , each boron is
2
sp hybridized
3) Aqueous solution of borax is alkaline in nature
The correct statements are
1) 1 and 2 2) 2 and 3 3) 1, 2 and 3 4) 1 and 3
Ans : 4
141. Assertion (A) :
4
GeF and
4
SiCl act as Lewis bases
Reason (R) : Ge and Si have d orbitals to accept electrons
1) Both A and R are correct and R is the correct explanation of A.
2) Both A and R are correct but R is not the correct explanation of A.
3) A is True but R is False. 4) R is True but A is False.
Ans : 4
142. Observe the following statements :
1) The solubility of group V hydrides in water decreases from
3
NH to
3
BiH
2) Phosphorous does not exhibit allotropy
3) The stability of group V hydrides decreases from
3
NH to
3
BiH
The correct statement(s) is/are
1) 1, 2 and 3 2) 1 and 3 3) 2 4) 1 and 2
Ans : 2
143. Sodium thiosulphate reacts with dil HCl to form NaCl,
2
H O, X and Y. X reacts with
2
Na S to form
2 2 3
Na S O and Y. Which one of the following is Y ?
1) S 2)
2
H S 3)
2
SO 4)
2 4
H SO
Ans : 1
144. Fluorine reacts with
4
KHSO to form HF and X. Which one of the following is X ?
1)
2
H S 2)
3
SO 3)
2 4
K SO 4)
2 2 8
K S O
Ans : 4
145. Identify the correct set
Molecule Hybridisation Shape Number of lone pairs of electrons
1)
2
XeF
3
sp d linear 2
2)
4
XeO
3 2
sp d pyramidal 1
3)
3
XeO
3
sp pyramidal 1
4)
4
XeF
3 2
sp d planar 3
Ans : 3
146. Observe the following statements :
1) Lanthanides actively participate in chemical reactions
2) The basic nature of hydroxides of lanthanides increases from
( )
3
La OH to
( )
3
Lu OH
3) Lanthanides do not form coordinate compounds as readily as d block metals
The correct statements are
1) 1 and 2 2) 2 and 3 3) 1, 2 and 3 4) 1 and 3
Ans : 4
147. During the manufacture of cast iron, the slag ( )
3
CaSiO is formed in
1) Zone of heat absorption 2) Zone of reduction only
3) Zone of fusion only 4) Zone of reduction and zone of fusion
Ans : 1
148. Match the following :
List I List II
A) pH of unpolluted rain water I)
2
H C CH CHO =
B) Acid rain II) 5.6
C) Acrolein III)
2 2
, NO CO
D) Freon IV)
2 2
CF Cl
V)
2
CaOCl
A B C D A B C D
1) II III I IV 2) II I III IV
3) I II III IV 4) III II IV I
Ans : 1
149. Carbon and hydrogen in an organic compound are detected as __________
1)
( )
3
2
, CaCO Cu OH 2)
3 3
, CaHCO CaCO
3)
3 4 2
, .5 CaHCO CuSO H O 4)
3 4 2
, .5 CaCO CuSO H O
Ans : 4
150. IUPAC name of is
1) 3 Ethyl - 4, 4 - dimethyl hexane 2) 2 Methyl - 2, 3 - diethyl pentane
3) 4 Ethyl 3, 3 dimethyl hexane 4) 3, 4 Diethyl 4 methyl pentane
Ans : 3
151. Which one of the following causes cancer ?
1) Cyclohexane 2) 1, 2 Benzpyrene 3) n Hexane 4) 2 Butene
Ans : 2
152. The correct Fischer projection formula of (2R, 3R) 2, 3 dihydroxy butanoic acid is
1) 2) 3) 4)
H OH
HO H
2
CO H
3
CH
H OH
H
2
CO H
3
CH
OH
H OH
HO H
2
CO H
3
CH
H
HO H
2
CO H
3
CH
HO
Ans : 2
153. Which one of the following is chloropicrin ?
1)
2 2
CHCl CHCl 2)
3
CCl CCO 3)
( )
3 3
2
CCl C CH
OH
4)
3 2
CCl NO
Ans : 4
154. The pair of chemicals used as food for yeast in the fermentation of molasses is
1)
2 4 3 4
, Na SO Na PO 2)
( )
4 4 3 4
2
, NH SO Na PO
3)
( ) ( )
4 4 4 4
2 3
, NH SO NH PO 4)
( )
2 4 4 4
3
, Na SO NH PO
Ans : 3
155. Which one of the following reactions is not correct ?
1)
CaCl
2
2 2 2 2 3
H
2 CH CH PdCl H O CH CHO Pd HCl
= + + + +
2)
( ) ( )
3 3 3
2 2
2 2 HCOO Ca H CCOO Ca CH CHO CaCO
A
+ +
3)
( )
Cu 300C
3 3 3 3 2
CH CH OH CH CH COCH H +
4)
Ag 300C
3 2 3 2
CH CH OH CH CHO H +
Ans : 1
156. Which one of the following reactions is not correct ?
1)
Ca , pressure
3 3
CH OH CO CH COOH +
2)
( ) Mn OAc air
2
3 2 3
1
2
CH CHO O CH COOH +
3)
Micoderma aceti
3 2 2 3 2
CH CH OH O CH COOH H O + +
4)
( )
( )
( )
1 CO
2
3 3
2 H O
2
CH MgBr CH COOH Mg OH Br
+
Ans : 1
157. The order of basic strength of
( ) ( ) ( ) ( )
6 5 2 2 5 2 2 5
2
1 , 2 , 3 C H NH C H NH C H NH and ( )
3
4 NH is
1) 3 < 2 < 4 < 1 2) 1 < 4 < 2 < 3 3) 1 < 3 < 2 < 4 4) 4 < 2 < 3 < 1
Ans : 2
158. Identify the pair of condensation polymers from the following :
1) Neoprene and PVP 2) Terylene and Nylon 6, 6
3) PVC and Polysterene 4) Polyvinylether and Polyisobutene
Ans : 2
159.
HNO HI
3
X Glucose Y
What are X and Y ?
X Y
1) n Hexane Saccharic acid
2) n Hexane Gluconic acid
3) Gluconic acid Saccharic acid
4) n Hexanol Saccharic acid
Ans : 1
160. Which one of the following statements is correct ?
1) Chloroxylenol is tranquilizer 2) Sucralose is an antiseptic
3) Lactic acid is an antimicrobial 4) Seconal is an antipyretic
Ans : 3