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12. A hollow cylinder has a charge q coulomb within 17. A block B is pushed momentarily along a
i. If φ is the electric flux in units of voltmeter horizontal surface with an initial velocity V. If µ
associated with the curved surface B, the flux is the coefficient of sliding friction between B
linked with the plane surface A in units of and the surface, block B will come to rest after a
voltmeter will be time
B
B V
C A
(a)
q
(b) φ (c) V/g (d) V/(g µ ).
2ε0 3 18. A particle moving along x-axis has acceleration
13. The frequency of a light wave in a material is and T are constants. The particle at t = 0 has
2 × 1014 Hz and wavelength is 5000 Å. The zero velocity. In the time interval between t = 0
refractive index of material will be and the instant when f = 0, the particle’s velocity
(a) 1.50 (b) 3.00 (c) 1.33 (d) 1.40 (vx) is
14. A nucleus A
Z X has mass represented by M(A, 1
(a) f T2 (b) f0T2
Z). If Mp and M n denote the mass of proton and 2 0
neutron respectively and B.E. the binding energy
in MeV, then 1
(c) fT (d) f0T.
(a) B.E. = [ZMp + (A – Z)Mp – M(A, Z)]c2 2 0
(b) B.E. = [ZMp + ZMn – M(A, Z)]c2 19. A common emitter amplifier has a voltage gain
(c) B.E. = M(A, Z) – ZMp – (A – Z)Mn of 50, an input impedance of 100Ω and an output
(d) B.E. = [M(A, Z) – ZMp – (A – Z)Mn]c2 impedance of 200Ω. The power gain of the
15. The total power dissipated in watts in the circuit
amplifier is
shown here is
(a) 1000 (b) 1250 (c) 100 (d) 500.
20. Three resistances P, Q, R each of 2Ω and an
6Ω unknown resistance S form the four arms of a
Wheatstone bridge circuit. When a resistance
3Ω
of 6Ω is connected in parallel to S the bridge
4Ω gets balanced. What is the value of S?
18 V
(a) 3Ω (b) 6Ω
(a) 40 (b) 54 (c) 4 (d) 16 (c) 1Ω (d) 2Ω
16. If the nucleus 27 has nuclear radius of about 21. A steady current of 1.5 amp flows through a
13 Al
copper voltameter for 10 minutes. If the
3.6 fm, then 125 would have its radius
32 Te electrochemical equivalent of copper is
approximately as 30 × 10–5 g coulomb–1, the mass of copper
(a) 9.6 fm (b) 12.0 fm deposited on the electrode will be
(c) 4.8 fm (d) 6.0 fm. (a) 0.50 g (b) 0.67 g (c) 0.27 g (d) 0.40 g.
22. A small coin is resting on the bottom of a beaker 26. A particle of mass m moves in the XY plane with
filled with liquid. A ray of light from the coin a velocity v along the straight line AB. If the
travels upto the surface of the liquid and moves angular momentum of the particle with respect
along its surface. How fast is the light travelling tooriginO isLA when it is at A and LB when it is
in the liquid? at B, then
3 cm Y
B
A
4 cm
X
O
coin
(a) LA = LB
(a) 2.4 × 108 m/s (b) 3.0 × 108 m/s (b) the relationship between LA and LB depends
8
(c) 1.2 × 10 m/s (d) 1.8 × 108 m/s upon the slope of the line AB
23. A transformer is used to light a 100 W and 110 V (c) LA < LB
lamp from a 220 V mains. If the main current is 0.5 (d) LA > LB.
amp, the efficiency of the transformer is 27. The particle executing simple harmonic motion
approximately has a kinetic energy K 0 cos 2 ωt . The maximum
(a) 50% (b) 90% (c) 10% (d) 30%.
values of the potential energy and the total
24. Dimensions of resistance in an electrical circuit,
energy are respectively
in terms of dimension of mass M, of length L, of
(a) K0/2 and K0 (b) K0 and 2K0
time T and of current I, would be
(c) K0 and K0 (d) 0 and 2K0.
(a) ML2T–2 (b) ML2T–1I–1
2 –3 –2 28. Charges +q and –q are placed at points A and B
(c) ML T I (d) ML2T–3I–1
respectively which are a distance 2L apart, C is
25. A uniform rod AB of length l, and mass m is free
the midpoint between A and B. The work done
to rotate about point A. The rod is released from
in moving a charge +Q along the semicircle CRD
rest in the horizontal position. Given that the
is
ml 2 R
moment of inertia of the rod about A is ,
3
the initial angular acceleration of the rod will be
A C B D
l qQ qQ
(a) (b)
A B 2πε0 L 6πε0 L
qQ qQ
(c) − (d)
6πε0 L 4πε0 L
29. Monochromatic light of frequency 6.0 × 1014 Hz
mgl 3
(a) (b) gl is produced by a laser. The power emitted is
2 2 2 × 10–3 ω. The number of photons emitted, on
the average, by the sources per second is
3g 2g
(c) (d) . (a) 5 × l 016 (b) 5 × 1017
2l 3l (c) 5 × 10 14 (d) 5 × 1015
30. Three point charges +q, –q and +q are placed at 35. The total energy of electron in the ground state
points (x = 0, y = a, z = 0), (x = 0, y = 0, z = 0) and of hydrogen atom is – 13.6 eV. The kinetic energy
(x = a, y = 0, z = 0) respectively. The magnitude of an electron in the first excited state is
and direction of the electric dipole moment (a) 6.8 eV (b) 13.6 eV
vector of this charge assembly are (c) 1.7 eV (d) 3.4 eV.
36. A 5 watt source emits monochromatic light of
(a) 2qa along the line joining points wavelength 5000 Å. When placed 0.5 m away, it
(x = 0, y = 0, z = 0) and (x = a, y = a, z = 0) liberates photoelectrons from a photosensitive
(b) qa along the line joining points (x = 0, y = 0, metallic surface. When the source is moved to a
distance of 1.0 m, the number of photoelectrons
z = 0) and (x = a, y = a, z = 0)
liberated will be reduced by a factor of
(c) 2qa along +ve x direction (a) 8 (b) 16 (c) 2 (d) 4
37. A particle executes simple harmonic oscillation
(d) 2qa along +ve y direction with an amplitude a. The period of oscillation is
31. Two satellites of earth, S1 and S2 are moving in T. The minimum time taken by the particle to
the same orbit. The mass of S1 is four times the travel half of the amplitude from the equilibrium
position is
mass of S 2 . Which one of the following
(a) T/8 (b) T/12 (c) T/2 (d) T/4
statements is true?
38. For a cubic crystal structure which one of the
(a) The potential energies of earth satellites in following relations indicating the cell
the two cases are equal. characteristics is correct?
(b) S1 and S2 are moving with the same speed. (a) a ≠ b ≠ c and α = β = γ = 90°
(c) The kinetic energies of the two satellites are (b) a = b = c and α ≠ β ≠ γ = 90°
equal. (c) a = b = c and α = β = γ = 90°
(d) The time period of S1 is four times that of S2. (c) a ≠ b ≠ c and α ≠ β and γ ≠ 90°
uur uur 39. Two condensers, one of capacity C and other of
32. A and B are two vectors and θ is the angle capacity C/2 are connected to a V-volt battery,
uur uur uur uur as shown.
between them, if | A × B |= 3(A .B ) , the value
of θ is
(a) 45° (b) 30° (c) 90° (d) 60° V C C/2
33. A mass of 2.0 kg is put on a flat pan attached to
a vertical spring fixed on the ground as shown
in the figure. The mass of the spring and the pan The work done in charging fully both the
is negligible. When pressed slightly and released condensers is
the mass executes a simple harmonic motion. The 3
1
spring constant is 200 N/m. What should be the (a) CV 2 (b) CV 2
4 4
minimum amplitude of the motion so that the
mass gets detached from the pan (take g = 10 1
(c) CV 2 (d) 2CV2.
m/s2)? 2
m 40. A black body is at 727° C. It emits energy at a
(a) 10.0 cm rate which is proportional to
(b) any value less than 12.0 cm (a) (1000)4 (b) (1000)2
(c) 727) 4 (d) (727)2
(c) 4.0 cm
(d) 8.0 cm 41. The resistance of an ammeter is 13 Ω and its
34. A charged paritcle (charge q) is moving in a circle scale is graduated for a current upto 100 amps.
After an additional shunt has been connected
of radius R with uniform speed v. The associated
to this ammeter it becomes possible to measure
magnetic moment µ is given by
currents upto 750 amperes by this meter. The
(a) qvR2 (b) qvR2/2 value of shunt-resistance is
(c) qvR (d) qvR/2 (a) 2 Ω (b) 0.2 Ω (c) 2 k Ω (d) 20 Ω
42. An engine has an efficiency of 1/6. When the 48. If the cold junction of a thermo-couple is kept at
temperature os sink is reduced by 62°C, its 0°C and the hot junction is kept at T°C then the
efficiency is doubled. Temperature of the source relation between neutral temperature (Tn) and
is temperature of inversion (Ti) is
(a) 37°C (b) 62°C (c) 99°C (d) 124°C (a) Tn = 2Ti (b) Tn = Ti – T
43. The electric and magnetic field of an (c) Tn = Ti + T (d) Tn = Ti/2
electromagnetic wave are 49. Assuming the sun to have a spherical outer
(a) in opposite phase and perpendicular to each surface of radius r, radiating like a black body at
other temperature t°C, the power received by a unit
(b) in opposite phase and parallel to each other surface, (normal to the incident rays) at a
(c) in phase and perpendicular to each other distance R from the centre of the sun is
(d) in phase and parallel to each other.
44. What is the value of inductance L for which the r 2 σ(t + 273) 4 16π2 r2 σt 4
(a) (b)
current is maximum in a series LCR circuit with 4πR 2 R2
C = 10 µF and ω = 1000s– 1
(a) 1 mH r 2 σ(t + 273) 4 4πr 2 σt 4
(b) cannot be calculated unless R is known (c) (d)
R2 R2
(c) 10 mH
(d) 100 mH where σ is the Stefan’s constant.
45. Nickel shows ferromagnetic property at room 50. In the energy band diagram of a material shown
temperature. If the temperature is increased below, the open circles and filled circles denote
beyond Curie temperature, then it will show holes and electrons respectively. The material is
(a) anti ferromagnetism
(b) no magnetic property
(c) diamagnetism Ec
(d) paramagnetism
46. A vertical spring with force constant k is fixed
Eg
on a table. A ball of mass m at a height h above
the free upper end of the spring falls vertically
on the spring so that the spring is compressed
by a distance d. The net work done in the process
is Ev
1
(a) mg(h + d) − kd 2
2
1 (a) an insulator
(b) mg(h − d) − kd 2 (b) a metal
2
(c) an n-type semiconductor
1 (d) a p-type semiconductor
(c) mg(h − d) + kd 2
2
1
(d) mg(h + d) + kd 2
2 CHEMISTRY
47. Under the influence of a uniform magnetic field
a charged particle is moving in a circle of radius 51. Which one of the following on reduction with
R with constant speed v. The time period of the lithium aluminium hydride yields a secondary
motion amine?
(a) depends on both R and v (a) Methyl isocyanide
(b) is independent of both R and v (b) Acetamide
(c) depends on R and not on v (c) Methyl cyanide
(d) depends on v and not on R (d) Nitroethane.
52. RNA and DNA are chiral molecules, their chirality 57. Consider the following reactions:
is due to (i) H +(aq) + OH–(aq) = H2O(l),
∆H = – X1 kJ mol–1
(a) chiral bases
(b) chiral phosphate ester units 1
(ii) H2(g) + O = H2O(l),
(c) D-sugar component 2 2(g)
(d) L-sugar component. ∆H = – X2 kJ mol–1
53. The Langmuir adsorption isotherm is deduced (iii) CO2(g) + H2(g) = CO(g) + H2O,
∆H = – X3 kJ mol–1
using the assumption
(a) the adsorption sites are equivalent in their 5
(iv) C2 H 2(g) + O 2(g) = 2CO2(g) + H2O(l)’
ability to adsorb the particles 2
(b) the heat of adsorption varies with coverage ∆H = – X3 kJ mol–1
Enthalpy of formation of H2O (l) is
(c) the adsorbed molecules interact with each
(a) + X 3 kJ mol– 1 (b) – X 4 kJ mol– 1
other (c) + X 1 kJ mol – 1 (d) – X 2 kJ mol– 1
(d) the adsorption takes place in multilayers. 58. The correct order of increasing thermal stability
44. A weak acid, HA, has a Ka of 1.00 × 10–5. If 0.100 of K2CO3, MgCO3, CaCO3 and BeCO3 is
mole of this acid disolved in one litre of water, (a) BeCO3< MgCO3 < CaCO3 < K2CO3
the percentage of acid dissociated at equilbrium (b) MgCO3 < BeCO3 < CaCO3 < K2CO3
(c) K2CO3 < MgCO3 < CaCO3 < BeCO3
is closest to
(d) BeCO3 < MgCO3 < K2CO3 < CaCO3
(a) 1.00% (b) 99.9% 59. In which of the following pairs, the two species
(c) 0.100% (d) 99.0% are iso-structure?
55. The reaction of hydrogen and iodine (a) SO32– and NO3– (b) BF3 an NF3
monochloride is given as: (c) BrO3– and XeO3 (d) SF4 and XeF4
60. Which of the following oxidation states are the
H 2(g) + 2ICl(g)
→ 2HCl(g) + I 2(g) most characteristic for lead and tin respectively?
(a) + 2, + 4 (b) + 4, + 4
The reaction is of first order with respect to H2(g) (c) + 2, + 2 (d) + 4, + 2
and ICI(g), following mechanisms were proposed. 61. Which of the following statements, about the
Mechanism A: advantage of roasting of sulphide ore before
reduction is not true?
H 2(g) + 2ICl(g)
→ 2HCl(g) + I 2(g)
(a) The ∆G of of the sulphide is greater than
Mechanism B: those for CS2 and H 2S.
H 2(g) + ICl(g)
→ HI(g) ;slow (b) The ∆G of is negative for roasting of
sulphide ore to oxide.
HI(g) + ICl(g)
→ HCl(g) + I 2(g) ;fast (c) Roasting of the sulphide to the oxide is
thermodynamically feasible.
Which of the above mechanism(s) can be (d) Carbon and hydrogen are suitable reducing
consistent with the given information about the agents for metal sulphides.
reaction? 62. In a first-order reaction A → B, if k is rate
constant and inital concentration of the reactant
(a) A and B both (b) neither A nor B
A is 0.5 M, then the half-life is
(c) A only (d) B only
56. The efficiency of a fuel cell is given by log 2 log 2
(a) (b)
k k 0.5
∆G ∆G ∆S ∆H
(a) (b) (c) (d) ln 2 0.693
∆S ∆H ∆G ∆G (c) (d)
k 0.5k
63. Consider the following compounds. 67. Given that bond energies of H – H and Cl – Cl are
(i) C6H5COCl 430 kJ mol– 1 and 240 kJ mol–1 respectively and
∆Hf for HCl is – 90 kJ mol– 1, bond enthalpy of
(ii) O 2N COCl HCl is
(a) 380 kJ mol–1 (b) 425 kJ mol–1
(c) 245 kJ mol –1 (d) 290 kJ mol–1
(iii) H 3C COCl
68. Which of the following represents the correct
order of the acidity in the given compounds?
(iv) OHC COCl (a) FCH2COOH > CH3COOH > BrCH2COOH >
ClCH2COOH
(b) BrCH2COOH > ClCH2COOH > FCH2COOH
The correct decreasing order of their reactivity
> CH3COOH
towards hydrolysis is
(a) (i) > (ii) > (iii) > (iv) (c) FCH2COOH > ClCH2COOH > BrCH2COOH
(b) (iv) > (ii) > (i) > (iii) > CH3COOH
(c) (ii) > (iv) > (i) > (iii) (d) CH3 COOH > BrCH2COOH > ClCH2COOH >
(d) (ii) > (iv) > (iii) > (i) FCH2COOH
64. Predict the product C obtained in the following 69. If threre is no rotation of plane polarised light by
reaction of butyne-1. a compound in a specific solvent, though to be
chiral, it may mean that
HI
CH 3CH 2 − C ≡ CH + HCl
→ B → C (a) the compound is certainly meso
(b) there is no compound in the solvent
I (c) the compound may be a racemic mixture
|
(a) CH3 − CH 2 − CH 2 − C − H (d) the compound is certainly a chiral.
| 70. CH3 – CHCl – CH2 – CH3 has a chiral centre.
Cl which one of the following represents its R-
configuration?
I
| C2 H5 C2 H5
(b) CH3 − CH 2 − CH − CH 2 Cl | |
(a) H − C − CH3 (b) Cl − C − CH3
I | |
| Cl H
(c) CH3CH 2 − C − CH3
| CH3 C2 H5
Cl | |
(c) H − C − Cl (d) H3C − C − Cl
(d) CH3 − CH − CH 2 CH 2 I | |
| C2 H5 H
Cl
71. Which of the following is water-soluble?
65. Concentrated aqueous sulphuric acid is 98% (a) Vitamin E (b) Vitamin K
H2SO4 by mass and has a density of 1.80 g mL– 1. (c) Vitamin A (d) Vitamin B
Volume of acid required to make one litre of 72. Identify the correct order of the size of the
0.1MH2SO4 solution is following:
(a) 16.65 mL (b) 22.20 mL (a) Ca2+ < K+ < Ar < Cl– < S2–
(c) 5.55 mL (d) 11.10 mL (b) Ar < Ca2+ < K+ < Cl– < S 2–
66. Reduction of aldehydes and ketones into (c) Ca2+ < Ar < K+ < Cl– < S2–
hydrocarbons using zinc amalgam and conc. HCl (d) Ca2+ < K+ < Ar < S2– < Cl–
is called 73. 0.5 molal aqueous solution of a weak acid (HX)
(a) Cope reduction is 20% ionised. If Kf for water is 1.86 K kg mol–
(b) Dow reduction 1,the lowering in freezing point of the solution is
(c) Wolf-Kishner reduction (a) 0.56 K (b) 1.12 K
(d) Clemmensen redcution. (c) – 0.56 K (d) – 1.12 K
90. Consider the following sets of quantum numbers: 97. In the reaction:
n l m s
CH3
(i) 3 0 0 + 1/2 |
(ii) 2 2 1 + 1/2 Heated
CH3 − CH − CH 2 − O − CH 2 − CH3 + HI →
(iii) 4 3 –2 – 1/2
(iv) 1 0 –1 – 1/2 Which of the following compounds will be
(v) 3 2 3 + 1/2 formed?
Which of the following sets of quantum number
(a) CH3 − CH − CH 3 + CH3CH 2 OH
is not possible? |
(a) (i), (ii), (iii) and (iv)(b) (ii), (iv) and (v) CH 3
(c) (i) and (iii) (d) (ii), (iii) and (iv)
91. The equilibrium constant of the reaction: (b) CH − CH − CH OH + CH CH
3 2 3 3
|
Cu (s) + 2Ag + (aq)
→ Cu 2 + (aq) + 2Ag (s) ; CH 3
E° = 0.46 V at 298 K is
(a) 2.0 × 1010 (b) 4.0 × 1010 CH3
(c) 4.0 × 10 15 (d) 2.4 × 1010 |
(c) CH3 − CH − CH2 OH + CH3 − CH 2 − I
92. Which one of the following polymers is prepared
by condensation polymerisation?
(a) Teflon (b) Natural rubber CH3
|
(c) Styrene (d) Nylon-66 (d) CH3 − CH − CH 2 − I + CH3CH 2 OH
93. The order of decreasing reactivity towards an
electrophilic reagent, for the following would be 98. The product formed in Aldol condensation is
(i) benzene (ii) toluene (a) a beta-hydroxy aldehyde or a beta-hydroxy
(iii) chlorobenzene (iv) phenol ketone
(a) (ii) > (iv) > (i) > (iii) (b) an alpha-hydroxy aldehyde or ketone
(b) (iv) > (iii) > (ii) > (i) (c) an alpha, beta unsaturated ester
(c) (iv) > (ii) > (i) > (iii) (d) a beta-hydroxy acid
(d) (i) > (ii) > (iii) > (iv) 99. The number of moles of KMnO4 that will be
94. Which of the folloiwng anions is present in the needed to react with one mole of sulphite ion in
chain structure of silicates? acidic solution is
(a) (Si2O52–)n (b) (SiO32–)n (a) 4/5 (b) 2/5 (c) 1 (d) 3/5
(c) SiO4 4– (d) Si2O76– 100. Identify the incorrect statement among the
95. An element, X has the following isotopic following:
composition: (a) Lanthanoid contraction is the accumulation
200X : 90% 199X : 8.0 % 202X : 2.0 %
of successive shrinkages.
The weighted average atomic mass of the
(b) As a result of lanthanoid contraction, the
naturally occuring element X is closest to
properties of 4d series of the transition
(a) 201 amu (b) 202 amu
elements have no similarities with the 5d
(c) 199 amu (d) 200 amu
96. The fraction of total volume occupied by the series of elements.
atoms present in a simple cube is (c) Shielding power of 4f electrons is quite weak.
(d) There is a decrease in the radii of the atoms
π π or ions as one proceeds from La to Lu.
(a) (b)
3 2 4 2
π π
(c) (d)
4 6
116. A person who is one along hunger strike and is (c) self-fertilization is prevented
surviving only on water, will have. (d) there is no change in success rate of
(a) less amino acids in his urine fertilization
(b) more glucose in his blood 125. Ergot of rye is caused by a species of
(c) less urea in his urine (a) uncimula (b) ustilago
(d) more sodium in his urine . (c) claviceps (d) phytophthora.
117. The length of DNA molecule greatly exceeds 126. The finches of Galapagos islands provide an
the dimensions of the nucleus in eukaryotic evidence in favour of
cells. How is this DNA accommodated?
(a) evolution due to mutation
(a) super-coiling in nucleosomes
(b) retrogressive evolution
(b) DNase digestion
(c) biogeographical evolution
(c) through elemination of repititive DNA
(d) deletion of non-essential genes. (d) special creation .
118. A sequential expression of a set of human genes 127. Which one of the following is a slime mould?
(a) messenger RNA (b) DNA sequence (a) physarum (b) Thiobacillus
(c) ribosome (d) transfer RNA. (c) Anabaena (d) Rhizopus.
119. In a coal fired power plant electrostatic 128. The population of an insect species shows an
precipitators are installed to control emission of explosive increase in numbers during rainy
(a) NO× (b) SPM (c) CO (d) SO2 season followed by its disappearance at the end
120. Select the wrong statement fom the following. of the season. What does this show?
(a) Both chloroplasts and mitochondria have (a) the food plants mature and die at the end
an internal compartment, the thylakoid of the rainy season
space bounded by teh thylakoid membrane (b) its population growth curve is of J-type
(b) Both chloroplasts and mitochondria (c) the population of its predators increases
contain DNA enormously
(c) The chloroplasts are generally much large (d) S-shaped or sigmoid growth of this insect.
than mitochondria 129. Which of the following is a flowering plant with
(d) Both chloroplasts and mitochondria nodules containing filamentous nitrogen-fixing
contain an inner and an outer membrane. micro-organism
121. Geometric representation of age structure is a
(a) crotalaria juncea (b) cycas revoluta
characteristic of
(c) cicer arietinum
(a) population (b) landscape
(d) casuarina equisetifolia
(c) ecosystem (d) biotic community.
122. During transcription, RNA polymerase 130. Which one of the following is being utilized as a
holoenzyme binds to a gene promoter and source of biodiesel in the Indian countryside?
assumes a saddle-like structure, what is it’s (a) betroot (b) sugarcane
DNA-binding sequence? (c) pongamia (d) euphorbia
(a) AATT (b) CACC 131. For a critical study of secondary growth in
(c) TATA (d) TTAA plants. which one of the folowing pairs is
123. A plant requires magnesium for suitable?
(a) protein synthesis (a) teak and pine (b) deodar and fern
(b) chlorophyll synthesis (c) wheat and maiden hair fern
(c) cell wall development (d) sugarcane and sunflower.
(d) holding cells together. 132. Which one of the following is a fat-soluble
124. In the prothallus of a vascular cryptogam, the vitamin and its related deficiency disease?
antherozoids and eggs mature a different times. (a) Retinol - Xerophtahalmia
As a result (b) Cobalamine - Beri-beri
(a) there is high degree of sterility (c) Calciferol - Pellagra
(b) one can conclude that the plant is (d) A scorbic acid - Scurvy.
apomictic
147. The first acceptor of electrons from an excited 156. One gene-one enzyme relationship was
chlorophyll molecule of photosystem II is established for the first time in
(a) iron-sulphur protein (a) Salmonella typhimurium
(b) ferredoxin (b) Escherichia coli
(c) quinone (d) cytochrome (c) Diplocococcus pneumoniae
148. Differentiation of organs and tissues in a (d) Neurospora crassa.
developing organism, is associated with 157. Two genes R and Y are located very close on
(a) differential expession of genes the chromosomal linkage map of maize plant.
(b) lethal mutations (c) deletion of genes When RRYY and rryy genotypes are hybridized,
(d) developmental mutations. the F2 segreagation will show
149. Which one of the following statements about (a) segregation in the expected 9 : 3 : 3 : 1 ratio
mycoplasma is wrong ? (b) segregation in 3 : 1 ratio
(c) higher number of the parental types
(a) They are pleomorphic
(d) higher number of the recombinant types.
(b) They are sensitive to penicillin
158. In cloning of cattle, a fertillized egg is taken out
(c) They cause diseases in plants
of the mother’s womb and
(d) They are also called PPLO.
(a) in the eight cell stage, cells are separated
150. Which one of the following pairs is mismatched? and cultured untill small embryos are
(a) Apis indica - honey formed which are implanted into the womb
(b) kenia lacca - lac of other cow
(c) Bombyx mori - silk (b) in the eight cell stage the individual cells
(d) Pila globosa - pearl are separated under electrical field for
151. A person is having problems with calcium and further development in culture media.
phosphorus metabolism in his body. Which one (c) from this upto eight identical twins can be
of following glands may not be functioning produced
properly ? (d) the egg is divided into 4 pairs of cells which
(a) parotid (b) pancreas are implanted into the womb of other cows
(c) thyroid (d) parathyroid 159. Ultrasound of how much frequency is beamed
152. A genetically engineered micro-organism use into human body for sonography ?
successfully in bioremediation of oil spills is a (a) 15 - 30 MHZ (b) 1 - 15 MHZ
species of (b) 45 - 70 MHZ (d) 30 - 45 MHZ.
(a) Trichoderma (b) Xanthomonas 160. Two plants can be conclusively said to belong
(c) Bacillus (d) Pseudomonas. to the same species if they.
153. In the leaves of C4 plants, malic acid formation (a) have more than 90 per cent similar genes
during CO2 fixation occurs in the cells of (b) look similar and possess identical
(a) bundle sheath (b) phloem secondary metabolites
(c) epidermis (d) mesophyll (c) have same number of chromosomes
154. Flagellated male gametes are present in all the (d) can reproduce freely with each other and
three of which one of the following sets ? form seeds.
(a) Zygnema, Saprolegnia and Hydrilla 161. Inheritances of skin colour in humans is an
(b) fucus, Marsilea and Calotropis example of
(c) Riccia, Dryopteris and Cycas (a) point mutation
(b) polygenic inheritance
(d) Anthoceros, Funaria and Spirogyra
(c) codominance
155. In the mean and the median pertaining to a certain
(d) chromosomal aberration.
character of a population are of the same value,
162. When two species of different genealogy come
which of the follwing is most likely to occur
to resemble each other as a result of adaptation,
(a) a bi-modal distribution the phenomenon is termed
(b) a T-shaped curve (a) microevolution (b) co-evolution
(c) a skewed curve (c) convergent evolution
(d) a normal distribution. (d) divergent evolution
163. Increased asthmatics attacks in certain seasons 170. Telomere repetitive DNA sequences control the
are related to function of eukaryotic chromosomes because they
(a) eating fruits preserved in tin containers (a) are RNA transcription initiator
(b) inhalation of seasonal pollen (b) help chromosome pairing
(c) low temperature (c) prevent chromosome loss
(d) hot and humid environment. (d) act as replicons.
164. Among the human ancestors the brain size was 171. Spore diseminiation in some liverworts is aided by
more that 1000 CC in (a) indusium (b) calyptra
(a) Homo erectus (b) Ramapithecus (c) peristome teeth (d) elaters.
(c) Homo habilis 172. Which one of the following elements is not an
(d) Homo neanderthalensis essential micronutrient for plant growth?
165. Industrial melanism as observed in peppered (a) Zn (b) Cu (c) Ca (d) Mn
173. The overall goal of glycolysis, krebs cycle and
moth proves that
the electron transport system is the formation of
(a) the melanic form of the moth has no
(a) ATP in one large oxidation reaction
selective advantage over lighter form in
(b) sugars (c) nucleic acids
industrial area
(d) ATP in small stepwise units.
(b) the lighter-form moth has no selective 174. Adaptive radiation refers to
advantage either in polluted industrial area (a) evolution of different species from a
or non-polluted area common ancestor
(c) melanism is a pollution-generated feature (b) migration of members of a species to
(d) the true black melanic forms arise by a different geographical areas
recurring random mutation. (c) power of adaptation in an individual to a
166. A high density of elephant population in an area variety of environments
can result in (d) adaptations due to geographical isolation.
(a) intra specific competition 175. Which one of the follwoing pairs, is not
(b) inter specific competition correctly matched?
(c) predation on one another (a) Gibberellic acid - Leaf fall
(d) mutualism. (b) Cytokinin - Cell wall elongation
167. A drop of each of the following, is placed (c) IAA - Cell wall elongation
separately on four slides. Which of them will (d) Abscissic acid - Stomatal closure.
not coagulate? 176. Select the correct statement from the following?
(a) blood serum (a) Fitness is the end result of the ability to
(b) sample from the thoracic duct of lymphatic adapt and gets selected by nature
system (b) All mammals except whales and camels
(c) Whole blood from pulmonary vein have seven cervical vertebrae
(d) blood plasma. (c) Mutations are random and directional
168. Which one of the following ecosystem types (d) Darwinian variations are small and
has the highest annuial net primary directionless.
productivity? 177. Male gametes in angiosperms are formed by the
(a) tropical deciduous forest division of
(b) temperate evergreen forest (a) generative cell (b) vegetative cell
(c) microspore mother cell
(c) temperate deciduous forest
(d) microspore.
(d) tropical rain forest.
178. In pea plants, yellow seeds are dominant to
169. In human body, which one of the following is
green. If a heterozygous yellow seeded plant is
anatomically correct?
crossed with a green seeded plant, what ratio of
(a) Collar bones - 3 pairs yellow and green seeded plants would you
(b) Salivary glands - 1 pairs expect in F1 generation ?
(c) Cranial nerves - 10 pairs (a) 9 : 1 (b) 1 : 3
(d) Floating ribs - 2 pairs (c) 3 : 1 (d) 50 :50
179. Which one of the follwing mammalian cells is (b) first negative, then positive and continue
not capable of metabolising glucose to carbon- to be positive.
dioxide aerobically? (c) first positive, then negative and again back
(a) unstraited muscle cells to positive
(b) liver cells (c) red blood cells (d) first negative, then positive and again back
(d) white blood to negative .
180. A human male produces sperms with the 188. Which one of the follwoing pairs of organisms
genotypes AB, Ab, aB, and ab pertaining to two are exotic species introduced in India ?
diallelic characters in equal proportions. What (a) lantana camara, water hyacinth
is the corresponding genotype of this person? (b) water hyacinth, prosopis cinereria
(a) AaBB (b) AABb (c) nile perch, licus religiosa
(c) AABB (d) AaBb. (d) ficus religiosa , lantana camara.
181. What is common to whale, seal and shark? 189. In gymnosperms, the pollen chamber represents
(a) thick subcutaneous fat (a) a cavity in the ovule in which pollen grains
(b) convergent evolution are stored after pollination
(c) homoiothermy (b) an opening in the megagametophyte
(d) seasonal migration. through which the pollen tube approaches
182. One of the important consequences of the egg
geographical isolation is (c) the microsporangium in which pollen
(a) preventing speciation grains develop
(b) speciation through reproductive isolation (d) a cell in the pollen grain in which the sperms
(c) random creation of new species are formed.
(d) no change in the isolated fauna. 190. Molecular basis of organ differentiation dpends
183. Lysozyme that is present in perspiration, saliva
on the modulation in transcription by
and tears, destroys
(a) ribosome (b) transcription factor
(a) certain types of bacteria
(c) anticodon (d) RNA polymerase.
(b) all viruses
191. Which of the follwoing is an example of negative
(c) most virus-infected cells
feedback loop in humans?
(d) certain fungi
184. In the human female, menstruation can be (a) secretion of tears after falling of sand
deferred by the administration of particles into the eye.
(a) combination of FSH and LH (b) salivation of mouth at the sight of delicious
(b) combination of estrogen and progesterone food
(c) FSH only (d) LH only (c) secretion of sweat glands and constriction
185. Which one of the following is not a constituent of skin blood vessels when it is too hot
of cell membrane? (d) constriction of skin blood vessels and
(a) glycolipids (b) proline contraction of skeletal mucles when it is
(c) phospholipids (d) cholesterol. too cold
186. Compared to a bull a bullock is docile because 192. The two polynucleotide chains in DNA are
of (a) discontinuous (b) antiparallel
(a) higher levels of cortisone (c) semiconservative(d) parallel.
(b) lower levels of blood testosterone 193. Which of the following pairs are correctly
(c) lower levels of adrenaline/ noradrenaline matched ?
in its blood Animals - Morphological features
(d) higher levels of thyroxine.
(i) Crocodile - 4-chambered heart
187. During the transmission of nerve impulse
(ii) Sea urchin - Parapodia
through a nerve fibre, the potential on the inner
side of the plasma membrane has which type of (iii) Obelia - Thecodont
electric change? (iv) Lemur - Thecodont
(a) first positive, then negative and continue (a) (ii), (iii) and (iv) (b) only (i) and (iv)
to be positive (c) only (i) and (ii) (d) (i), (iii) and (iv)
194. Which one of the following pairs of structures 197. The wavelength of light absorbed by Pr form of
distinguishes a nerve cell from other types of phytochrome is
cells? (a) 680 nm (b) 720 nm
(a) vacuoles and fibres (c) 620 nm (d) 640 nm
(b) flagellum and modulloary sheath 198. Which one of the following is not a bioindicator
(c) nucleus and mitochondria of water pollution?
(d) perikaryon and dendrites. (a) blood-worms (b) stone flies
195. In maize, hybrid vigour is exploited by (c) sewage fungus (d) sludge-worms.
(a) crossing of two inbred parental lines 199. Feeling the tremors of an earthquake a scared
(b) harvesting seeds from the most productive resident of seventh floor of a multistoryed
plants building starts climbing down the stairs rapidly.
(c) inducing mutations Which hormone initiated this action ?
(d) bombarding the seeds with DNA. (a) adrenaline (b) glucagon
196. Which one of the following is a viral disease of (b) gastrin (d) thyroxine
poultry ? 200. “Foolish seedling’’ disease of rice led to the
(a) coryza (b) new castle disease discovery of
(c) pasteurellosis (d) salmonellosis. (a) ABA (b) 2, 4-D
(c) IAA (d) GA
Acceleration = − Aω 2 sin ωt 1 q
⇒ φ' = − φ
= Aω2sin(π + ωt) 2 ε0
π 13. (b) By using v = nλ
∴φ = = 0.5π
2 Here, n = 2 × 1014 Hz
10. (a) In mass spectrometer, when ions are
accelerated through potential V λ = 5000Å = 5000 × 10 −10 m
1 For 27
13 Al, R1 = R 0 (27)1/ 3 = 3R 0
θ = 2× 2+ × 3(2) 2 = 4 + 6 = 10 rad
2
32Te, R 2 = R 0 (125)
For 125 = 5R 0
1/ 3
q
12. (d) Since φ total = φA + φB + φC = ε R 2 5R 0 5
=
5
= R1 = × 3.6 = 6fm.
0 R1 3R 0 3 3
Where q is the total charge. 17. (d) Friction is the retarding force for the block
As shown in the figure, flux associated with F = ma = µR = µmg
the curved surface B is φ = φB Therefore, from the first equation of motion
Let us assume flux linked with the plane v = u – at
surfaces A and C be v
φA = φC = φ' 0 = v – µg × t ⇒ =t
µg
1
25. (c) ∴ K0 = mω2 a 2
2
l
1
Hence, total energy, E = mω 2 a 2 = K 0
2
l/2 mg
∴ U max = K 0 & E = K 0 .
28. (c)
R
Weight of the rod will produce torque,
l
+q –q
τ = mg × A C D
2 B
2L L
Also, τ = Iα Potential at C = VC = 0
Potential at D = VD
ml 2
Where, I is the moment of inertia = −q Kq 2 Kq
3 = K + =−
L 3L 3 L
and α is the angular acceleration
Potential difference
ml 2 l 3g −2 Kq 1 2 q
∴ α = mg × ⇒ α = =
3 2 2l VD – VC = − .
3 L 4π ∈0 3 L
26. (a) Angular momentum = Linear momentum × ⇒ Work done = Q(VD – V C)
distance of line of action of linear
2 1 qQ − qQ
momentum about the origin. =− × =
3 4πε 0 L 6πε0 L
Y
29. (d) Since p = nhν
B
A p 2 × 10−3
⇒n= =
hν 6.6 × 10−34 × 6 × 1014
= 5 × 1015
d 30. (a) Three point charges +q, –2q and +q are
0 X
placed at points B (x = 0, y = a, z = 0),
O (x = 0, y = 0, z = 0) and A(x = a, y = 0, z = 0)
LA = P A × d, LB = PB × d
The system consists of two dipole moment
As linear momenta are equal, vectors due to (+q and –q) and again due
therefore, LA = LB. to (+q and –q) charges having equal
27. (c) We have, U + K = E uuur
magnitudes qa units – one along OA and
where, U = potential energy, K = Kinetic uuur
energy, E = Total energy. other along OB . Hence, net dipole moment,
Also, we know that, in S.H.M., when uuur
potential energy is maximum, K.E. is zero pnet = (qa)2 + (qa)2 = 2qa along OP
and vice-versa. at an angle 45° with positive X-axis.
∴ U max + 0 = E ⇒ U max = E y
+q(0, a, 0) P
B B
Further,
1 (–2q) A 45°
K.E. = mω2 a 2 cos2 ωt x
O
2 (0, 0, 0) O +q(a, 0, 0) A
d
whereas, alkyl cyanides give 1° amine on
reduction.
52. (c) Each nucleic acid consists of a pentose
sugar a heterocyclic base, and phosphoric
z v acid. The sugar present in DNA is 2-deoxy
x
-D (–) ribose and the sugar present in RNA
is D (–)- ribose. The chirality of DNA and
RNA molecules are due to the presence of
v sugar components.
47. (b)
x O
HOCH2 OH
λ
When a test charge q0 enters a magnetic H H
r
field B directed along z-axis, with a velocity H H
r
v making angles d with the z-axis. The time
OH OH
period of the motion is independent of R
D(–)–ribose
and v.
Total = 25 + 1 = 26
O 26
HOCH2 = = 3(Q) + 2(R) = 5
OH 8
hybridization = dsp3
H H hybridization of Xe in XeO3
H H Total valence electrons
26
OH H = 8 + 3 × 6 = 26 = = 3(Q) + 2(R) = 5
8
2-deoxy–D(–)–ribose
Hybridization = dsp3
In both cases, the structure is trigonal
53. (a) Langmuir adsorption isotherm is based on
pyramidal.
the assumption that every adsorption site 60. (a) All the group IV elements show
is equivalent and the ability of a particle to tetravalency which can be explained on the
bind there is independent of whether or not basis of shifting of one e– of ns to the vacant
nearby sites are occupied. np orbital.These four orbitals give rise to
54. (a) Given Ka = 1.00×10–5, C= 0.100 mol four sp3 hybrid orbitals.
for a weak electrolyte, When ns2 electrons of the outermost shell
degree of dissociation do not participate in bonding it is called
inert pair and the effect is called inert pair
KA 1× 10 –5
= 10−2 = 1%
effect. The last three elements of group 4
(α) = =
C 0.100 i.e. Ge, Sn and Pb, have a tendency to form
55. (d) As the slowest step is the rate determining divalent as well as tetravalent ions. Since
step thus the mechanism B will be more the inert pair effect increases from Ge to Pb,
consistent with the given information also the stability of tetravalent ion decreases
because it involve one molecule of H2 and and that of divalent ion increases that is
one molecule of ICl it can expressed as why Pb++ is more stable than Pb4+ and Sn4+
r = k [H2][ICl] ions is more stable than Sn2+.
Which shows that the reaction is first order 61. (d) The sulphide ore is roasted to oxide before
w.r.t. both H2 & ICl. reduction because the ∆G of of most of the
∆G sulphides are greater than those of CS2 and
56. (b) Efficiency of a fuel cell ( η) =
∆H H2S, therefore neither C nor H can reduce
57. (d) This reaction shows the formation of H 2O, metal sulphide to metal. Further, the standard
and the X 2 represents the enthalpy of free energies of formation of oxide are much
formation of H2O because as the definition less than those of SO2. Hence oxidation of
suggests that the enthalpy of formation is metal sulphides to metal oxide is
the heat evolved or absorbed when one thermodynamically favourable.
mole of substance is formed from its 62. (c) For a first order reaction
constituent atoms. 2.303 a
58. (a) As the basicity of metal hydroxides k= log10
t a−x
increases down the group from Be to Ba,
the thermal stability of their carbonates also when t = t½
increases in the same order. Further group 2.303 a
1 compounds are more thermally stable than k= log10
t½ a−a/2
group 2 because their hydroxide are much
basic than group 2 hydroxides therefore, 2.303 ln 2
the order of thermal stability is or t½ = log10 2 =
k k
BeCO3 < MgCO3< CaCO3< K2CO3. 63. (c) The degree of hydrolysis increases as the
59. (c) Hybridisation of Br is BrO3– magnitude of positive charge on carbonyl
Total valence elctrons = 7 + 3 × 6 = 25 group increases. Electron withdrawing
Charge = –1 hence
∑ B.E. of reactant
group increases the positive charge and
electron releasing group decreases the ∆H HCl =
negative change. Among these NO2 & CHO − ∑ B.E. of products
are electron withdrawing group from which
NO2 has more –I effect than –CHO. On the 1 1 1
other hand CH3 is a electron releasing group −90 = × 430 + + × 240 − B.E. of HCl
2 2 2
therefore the order of reactivity towards ∴ B.E. of HCl = 215 + 120 + 90
hydrolysis is = 425 kJ mol–1
COCl COCl COCl COCl 68. (c) Electron withdrawing substituent increases
the acidity by increasing the ionic character
> > > of –O–H by inductive effect.
Electronegativity decreases in the order.
NO2 CHO CH3 F > Cl > Br
64. (c) This reaction occurs according to and hence –I effect also decreases in the
Markownikoff’s rule which states that when same order, therefore the correct option is
an unsymmetrical alkene undergo FCH2COOH > ClCH2COOH >
hydrohalogenation, the negative part goes BrCH2COOH > CH3COOH
to that C-atom which contain lesser no. of 69. (a) Compounds which do not show optical
H-atom. activity inspite of the presence of chiral
CH3 − CH 2 − C ≡ CH + HCl carbonatomsarecalledmeso-compounds.
The absence of optical activity in these
→ CH3 − CH 2 − C = CH 2 compound is due to the presence of a plane
| of symmetry in their molecules. e.g. meso-
Cl tartaric acid is optically inactive.
I COOH
|
HI
→ CH3 − CH 2 − C − CH 2 H OH
|
Cl (Plane of symmetry)
65. (c) Molarity of H 2SO4 solution H OH
98 × 1000
= × 1.84 = 18.4 COOH
98 × 100
Suppose V ml of this H2SO4 is used to 2
prepare 1 lit. of 0.1M H2SO4 C2H5
∴ V ×18.02 = 1000 × 0.1 3
70. (b) Cl — C — CH3
1000 × 0.1
or V = = 5.55 ml. 1
18.02
Zn-Hg / conc. HCl
H 4
66. (d) C=O CH2 + H2 O R-configuration
Clemmensen reduction 71. (d) Vitamin B is water soluble whereas all other
e.g. are water insoluble.
CH3 Zn-Hg / CH3 72. (a) For isoelectronic species, size of anion
conc. HCl
C=O CH2 + H2 O increases as negative charge increases
CH3 CH3 whereas size of cation decreases with
increase in positive charge. Further ionic
1 1
67. (b) H 2 + Cl2
→ HCl radii of anions is more than that of cations.
2 2 Thus the correct order is
Ca++ < K+ < Ar < Cl– < S– –
73. (b) As ∆Tf = i Kg m
For
10−4
+ − = × 6.023 × 1023 = 6.023 × 1017
HX ˆˆ†
‡ˆˆ H + X 100
t=0 1 0 0 78. (b) Lesser is the number of unpaired electrons
smaller will be the paramagnetic behaviour.
teq (1 − 0.20) 0.20 0.20 As Cr++, Mn++, Fe++ & Ni++ contains.
Total no. of moles = 1 – 0.20 + 0.20 + 0.20 =
1 + 0.20 = 1.2 Cr++ (3d4) =
∴ ∆Tf = 1.2 × 1.86 × 0.5 = 1.1160 ≈ 1.12 K = 4 unpaired e –.
74. (d) Leaching is the selective dissolution of the
desired mineral leaving behind the Mn++ (3d5) =
impurities in a suitable dissolving agent eg = 5 unpaired e –.
Argentitie or Silver glance, Ag2S is an ore
of silver. Silver is extracted from argentite Fe++ (3d6)=
by the mac-Arthur and Forest process
= 4 unpaired e –.
(leaching process).
Ag 2S + 4NaCN → 2Na[Ag ( CN )2 ] + Na 2S Ni++ (3d8) =
= 2 unpaired e –.
4Au + 8KCN + 2H 2 O + O 2 As Ni++ has minimum no. of unpaired e–
→ 4K[Au ( CN )2 ] + 4KOH thus this is least paramagnetic.
79. (a) The solubility of sulphates of alkaline earth
75. (a) For a first order reaction
metals decreases as we move down the
2.303 a group from Be to Ba due to the reason that
k= log
t a−x ionic size increases down the group. The
when t = 60 and x = 60% lattice energy remains constant because
sulphate ion is so large, so that small
2.303 100 2.303 100
k= log = log change in cationic sizes do not make any
60 100 − 60 60 40 difference. Thus the order:
Now, BeSO 4 > MgSO 4 > CaSO 4 > SrSO 4 > BaSO 4
2.303 100 2.303
t½ = log = × log 2 80. (d) H3C — C = CH — CH3
0.0153 100 − 50 0.0153
CH3
2.303
= × 0.3010 = 45.31 min .
0.0153 O3
H3C O H
76. (b) Non superimposable mirror images are C C
H3C CH3
called optical isomers and may be described O O
as “chiral’. They are also called enantiomers
and rotate plane polarised light in opposite O O
H 2O
directions. CH3 – C – CH3 + CH3 – C – H
–H2O2 acetone acetaldehyde
N N N
N 81. (b) The factors on which the ionisation energy
N Co Cl Cl Co N depend are :
N N
(i) Atomic size – I.E. decreases as the
Cl Cl
atomic size increases. So the attractive
77. (b) Since each Sr++ ion provides one cation force decreases.
vacancy, hence (ii) Number of electrons in the inner shell
Concentration of cation vacancies = mole (screening effect). As the number of
% of SrCl2 added shells increases screening effect also
= 10–4 mole % increases and hence the I.E. tends to
decrease.
ˆˆ† 2NO; K 2
N 2 + O 2 ‡ˆˆ ....(ii) −
.. +
→ :O
..
≡ C−O:
1
H2 + ˆˆ† H 2 O; K 3
O 2 ‡ˆˆ ....(iii)
2 More is the single bond character. More
We have to calculate will be the bond length. Hence, the corret
4NH3 + 5O2 → 4NO + 6H 2 O; K = ? order is :
5 CO < CO2 < CO3– –
or 2NH3 + O2 → 2NO + 3H 2 O 86. (d) HOCl < HOClO < HOClO 2 < HOClO3
2 +1 +3 +5 +7
2
[NO] [H 2 O] 3 As the oxidation number of the central atom
For this equation, K = increases, strength of acid also increases.
[NH3 ]2 [O 2 ]5 / 2 87. (a) Aldehydes containing no α-hydrogen
atom on warming with 50% NaOH or KOH
[NH3 ]2 [NO]2 undergo disproportionation i.e. self
but K1 = , K2 = oxidation - reduction known as cannizzaro’s
[N 2 ] [H 2 ]3 [N 2 ] [O2 ]
reaction.
50% NaOH
[H2 O] 2 C6 H 5 CHO + NaOH →
& K3 =
½
[H 2 ] [O2 ] C6 H 5COONa + C6 H 5CH 2 OH
88. (a) Nucleophilicity increases down the periodic
[H 2 O]3 table.
or K3 =
[H 2 ]3 [O2 ]3/ 2 I − > Br − > Cl− > F−
Now operate, 89. (a) Given [H3O+] = 1 × 10–10 M
at 25º [H3O+] [OH–] = 10–14
K 2 . K33
10 −14
K1 ∴ [OH − ] = = 10 −4
10 −10
[NO]2 [H2 O]3 [N ] [H 2 ]3 OH
= 10−4 = 10− p
OH
= × . 2 Now, [OH − ] = 10−p
[N2 ] [O2 ] [H 2 ]3 [O2 ]3 / 2 [NH3 ]2
∴ p =4OH
92. (d) Copolymer of adipic acid (6C) and group that forms alkyl iodide therefore
hexamethylene diamine (6C). ∆
CH3 − CH − CH 2 − O − CH 2 − CH3 + HI →
n HOOC(CH 2 ) 4 COOH + nH 2 N (CH 2 ) 6 NH 2 → |
Adipic acid Hexamethyl ene diamine CH3
O O CH3
|| ||
−( C− (CH 2 ) 4 − C− NH − (CH 2 ) 6 − NH −) n |
Nylon 66 CH3 − CH − CH 2 OH + CH3CH 2 I
It has high tenacity and elasticity. It is 98. (a) Aldehydes and ketones having at least one
resistant to abrasion and not affected by α-hydrogen atom in presence of dilute alkali
sea water. It is used for reinforcement of give β-hydroxy aldehyde or β-hydroxy
rubber tyres, manufacture of parachute, ketone
safety belts, carpets and fabrics.
O
93. (c) Electrophiles have high affinity for ||
electrons. They attack at the site where CH3 − C + HCH 2 CHO
electron-density is highest. Electron |
H
withdrawing substances increases the Acetaldehyde
electron density. The electron withdrawing
tendency decreases in the order : OH
–OH > –CH3 > –H > –Cl |
dil.NaOH
Therefore, the correct order of reactivity
→ CH3 − C − CH 2 − CHO
|
towards electrophile is H
C6H5OH > C6H5CH3 > C6H6 > C6H5Cl Aldol
94. (b) (SiO 32–) n Two oxygen atoms per SiO4
∆
tetrahedron are shared giving polymeric → CH3 − CH = CH.CHO
anion chains. − H 2O Crotonaldehyde
Example : Spodumene LiAl (SiO 3 ) 2 , 99. (b) The balance chemical equation is :
Diposide CaMg(SiO3)2.
95. (d) Average isotopic mass of 2MnO −4 + 6H + + 5SO3−−
→
X=
200 × 90 + 199 × 8 + 202 × 2 2Mn ++ + 5SO4−− + 3H 2 O
90 + 8 + 2 From the equation it is clear that
18000 + 1892 + 404 Moles of MnO4– require to oxidise 5 moles
= of SO3– – are 2
100 Moles of MnO4– require to oxidise 1 mole
19996 of SO3– – are 2/5.
= = 199.96 amu 100. (b) There is a steady decrease in the radii as
100
the atomic number of the lanthanide
96. (d) Number of atoms per unit cell = 1
elements increases. For every additional
Atoms touch each other along edges.
proton added in nucleus the corresponding
a electron goes to 4f subshell.
Hence r = The shape of f -orbitals is very much
2
( r = radius of atom and a = edge length) diffused and they have poor shielding effect.
The effective nuclear charge increases
4 3
πr which causes the contraction in the size of
π
Therefore % fraction = 3 3 = = 0.52 electron charge cloud. This contraction in
(2r) 6 size is quite regular and known as
97. (c) In the cleavage of mixed ethers with two Lanthanoid contraction.
different alkyl groups, the alcohol and alkyl Since the change in the ionic radii in the
iodide that form depend on the nature of lanthanide series is very small, thus their
alkyl group. When primary or secondary chemical properties are similar.
alkyl groups are present, it is the lower alkyl
transcription which requires RNA 197. (a) The Pr form: It absorbs light between 660
polymerase chain. RNA polymerase chains to 680nm and absorbs at a peak of 666 nm.
are of 3-types in eukaryotes It is the form synthesized in dark-grown
(i) RNA polymesase-I seedlings. When Pr absorbs red light, it is
(ii) RNA polymesase II convertedto the Pfr form
(iii) RNA polymesase-III 198. (b) Stone flies are not bio indicators.
191. (d) When the set point of hypothalamus is Bioindicators provide a range of
disturbed by high temperature, it stimulates techniques to assess the impcts of air
vasodialation and sweating while in low pollution from reactive nitrogen (N)
temperature there is vasoconstriction and compounds on statutory nature
shivering conservation sites. They complement
192. (b) The two chains are antiparallel, one aligned physical monitoring of atmospheric
in 5’ → 3’ direction the other in 3’ → 5’ concentrations and deposition and risk
direction. assessment based on the critical loads
193. (d) Crocodile belongs to reptilia class which approach by providing site-based
has four chambered heart lemur teeth are information on atmospheric N
combedded in the rockets of two which is concentrations, N deposition and/or
known as there don’t . In obelia polyps ecological impacts.
reproduce meduseas asexually and 199. (a) It is commonly called as ‘emergency
medusae form the polyps sexually. Such hormone’ or 3F – hormone (For fear, fight &
atteraction of asixual and sexual phases in flight). Its secretion is regulated by SNS,
the life cycle of obelia is called me tagenesis. and not bypituitary as in case of adrenal
194. (d) The cytoplarm immediately surrounding cortex. It stimulates sweating, heart beat and
the nucleus is loaded with profein synthetic breathing rate. It causes the dilation of
machinery and is called perikaryon coronary artery (supplying blood to the
dendrites are usually shorter, tapering and heart muscles), bronchioles (for increasing
much branched processes which may be inspiratory volume) and pupil (for better
one to several. These two are only present vision)
in nerve cells. 200. (d) The effect of gibberellins had been known
195. (a) Hybrid vigour is also called Helorosis in japnan since early 1800 where certain
which is measured in terms of size growth rice plants were found to suffer from bakane
rate / field and number of other characters. or bakanae ( foolish seedling ) disease.
Hybridisation increases vigour and fertility. Such rice plants were thin, pale green,
It is exploited by crosing of two in bred spindle-shaped, longer by 50% than the
parental lines. It is best maintained in healthy plants, and were sterile.
vegetatively reproducing crops because of
genetic recombinations .
196. (b) Newcastle disease (ND) is a highly
contagious, generalised virus disease of
domestic poultry and wild birds
characterised by gastro-intestinal,
respiratory and nervous signs.