Dr. S. S. Verma Professor, Department of Physics, S.L.I.E.T, Longowal, Distt.-Sangrur (Pmiiab)-148106, INDIA 'E-mail: ssvermal23@re(f&nail.com DEMAND and energy crisis have always prompted scientists, engineers and planners to look for its new natural as well as artificial resources. Development and exploitation of natural energy resources have always attracted attention due to many advantages associated with these. Shale gas is one of such resource which has recently attracted much attention of energy seekers. Shale gas is one of the most rapidly growing forms of natural gas. Shale gas refers to natural gas that is trapped within shale formations. It, along with other non- conventional forms of natural gas, such as tight gas and coal bed methane, will make a major contribution to future of gas production. Unconventional gas production is forecast to increase from 42 percent of total US gas production in 2007 to 64 percent in 2020. Unconventional natural gas deposits are difficult to characterize overall, but in general are often lower in resource concentration, more dispersed over large areas, and require well stimulation or some other extraction or conversion technology. Extremely large natural gas in-place volumes are represented by these resources, and the US has produced only a fraction of their ultimate potential. Shale gas is defined as natural gas from shale formations. The shale acts as both the source and the reservoir for the natural gas. Older shale gas wells were vertical while more recent wells are primarily horizontal and need artificial stimulation, like hydraulic fracturing, to produce. Only shale formations with certain characteristics will produce gas. The most significant trend in US natural gas production is the rapid rise in production from shale formations. In large measure this is attributable to significant advances in the use of horizontal drilling and well stimulation technologies and refinement in the cost-effectiveness of these technologies. Hydraulic fracturing is the most significant of these. Shales are fine-grained sedimentary rocks that can be rich sources of petroleum and natural gas. Shale gas is found in shale "plays," which are shale formations containing significant accumulations of natural gas and which share similar geologic and geographic properties. Conventional gas reservoirs are created when natural gas migrates from an organic-rich source formation into permeable reservoir rock, where it is trapped by an overlying layer of impermeable rock. In contrast, shale gas resources form within the organic-rich shale source rock. The low permeability of the shale greatly inhibits the gas from migrating to more permeable reservoir rocks. Extraction of shale gas Over the past decade, the combination of horizontal drilling and hydraulic fracturing has allowed access to large volumes of shale gas that were previously uneconomical to produce. The production of natural gas from shale formations is supposed to rejuvenate the natural gas industry all over the world. Hydraulic fracturing (commonly called "fracking" or "fracing") is a technique in which water, chemicals, and sand are pumped into the well to unlock the hydrocarbons trapped in shale formations by opening cracks (fractures) in the rock and allowing natural gas to flow from the shale into the well. When used in conjunction with horizontal drilling, hydraulic fracturing enables gas producers to extract shale gas economically. Without these techniques, natural gas does not flow to the well rapidly, and commercial quantities cannot be produced from shale. Production requirements and profile for shale oil and gas is different from conventional gas and oil. While they may be massive untapped energy sources, the risks of extracting them have drawn calls fortighter regulation or an all-out ban. Hydraulic fracturing is the process of pumping a fluid or a gas down a well, many hundreds or thousands of metres below ground, to a depth considered appropriate for natural gas production. The pressure this creates causes the surrounding rock to crack, or fracture. A fluid (usually water with some additives) holding a suspended proppant (usually sand) then flows into the cracks. When the pumping pressure is relieved, the water disperses leaving a thin layer of the sand to prop open the cracks. This layer acts as a conduit to allow the natural gas to escape froiTi tight (low permeability) formations and flow to the well so * hat it can be recovered. The technology is carefully used and managed to minimize any environmental impact, particularly on groundwater. Wellbores are carefully constructed to efficiently recover gas while prot ect i ng the surroundi ng envi ronment , parti cul arl y underground drinking water. A well bore is drilled to allow a narrow pipe to be sunk deep into the ground. This pipe is surrounded in the bore hole with cement to ensure that both the pipe and the underground area it travels through are compl etel y separat ed. At the producti on si te, deep underground and several hundred meters below the water table, the production pipe is perforated to allow the natural gas to flow into the pipe and rise up to the surface. CHEMICAL BUSINESS <> JANUARY 2014 g Growing Dimensions of Shaie Gas Use U.S. Shale Gas Development The development of natural gas from shale has proceeded quickly in the United States, where the energy industry has long known about huge gas resources trapped in shale rock formations. According to the U.S. Energy Information Administration (EIA), of the 2,300 trillion cubic feet of technically recoverable natural gas resources estimated to be in the U.S., almost a quarter is held in shale rock formations. It is only over the past decade that energy companies have been able to economically unlock natural gas from shale by combining two established technologies: hydraulic fracturing and horizontal drilling. As a result, natural gas from shale has grown to about 35 percent of U.S. gas production during that time. According to EIA estimates, this resource could account for nearly 50 percent of U.S. production by 2035. Of the natural gas consumed in the United States In 2011, about 95% was produced domestically; thus, the supply of natural gas is not as dependent on foreign producers as is the supply of crude oil, and the delivery system is less subject to Interruption. The availability of large quantities of shale gas should enable the United States to consume a predominantly domestic supply of gas for many years and produce more natural gas than it consumes. The U.S. Energy Information Administration's Annual Energy Outlook 2013 Early Release projects U.S. natural gas production to increase from 23.0 trillion cubic feet in 2011 to 33.1 trillion cubic feet in 2040, a 44% increase. Almost all of this increase in domestic natural gas production is due to projected growth in shale gas production, which grows from 7.8 trillion cubic feet in 2011 to 16.7 trillion cubic feet in 2040. Global Potential for Developing Natural Gas From Shale The International Energy Agency currently estimates that global recoverable shale gas resources stand at 7,345 trillion cubic feet, so it's conceivable that this resource could one day offer similar benefits to other countries. Although exploration and development of these resources outside of the United States are still in the early stages. Chevron is acquiring shale acreage around the world. Exploration of shale gas is at various stages in a number of countries, including India, Argentina, Canada, China, Lithuania, Poland, Romania and Ukraine. Bottlenecks in Shaie Gas Production Natural gas is cleaner-burning than coal or oil. The combustion of natural gas emits significantly lower levels of carbon dioxide (COJ and sulfur dioxide than does the combustion of coal or oil. When used in efficient combined- cycle power plants, natural gas combustion can emit less than half as much CO2 as coal combustion, per unit of electricity output. However, there are some potential environmental concerns associated with the production of shale gas. The fracturing of wells requires large amounts of water. In some areas of the country, significant use of water for shale gas production may affect the availability of water for other uses and can affect aquatic habitats. Second, if mismanaged, hydraulic fracturing fluid which may contain potentially hazardous chemicals can be released by spills, leaks, faulty well construction, or other exposure pathways. Any such releases can contaminate surrounding areas. Third, fracturing also produces large amounts of wastewater, which may contain dissolved chemicals and other contaminants that could require treatment before disposal or reuse. Because of the quantities of water used and the complexities inherent in treating some of the wastewater components, treatment and disposal is an important and challenging issue. Finally, hydraulic fracturing "causes small earthquakes, but they are almost always too small to be a safety concern. In addition to natural gas, tracking fluids and formation waters are returned to the surface. These wastewaters are frequently disposed of by injection into deep wells. The injection of wastewater into the subsurface can cause earthquakes that are large enough to be felt and may cause damage." The injection wells typically discharge the wastewater into non-potable salt-water aquifers. Shaie gas in Canada While large-scale commercial production of shale gas has not yet been achieved in Canada, many companies are now exploring for and developing shale gas resources in Alberta, British Columbia, Ouebec, and New Brunswick. Development of shale gas, and other unconventional resources, will help ensure supplies of natural gas are available to the growing North American natural gas market for many decades. Dependence on Russia The potential shale gas production in Europe will have huge geopolitical importance. Since gas prices are often higher in Europe than in the US, oil companies are keen on drilling for shale gas prospects even though profits at this stage are only speculative. Europe is today dependent on Russia for its gas supplies to the extent of about 31 per cent. Future shale gas production may reduce this dependence on Russian gas supplies for Europe and improve their energy security. In reality India's gas demand is limited by its access to gas supplies based on domestic production and imports availability. If India can produce more gas than it can reduce its coal imports which is environmentally more unfriendly, its gasoline consumption through the use of compressed natural gas, and its demand for LPG through piped natural gas to meet residential cooking and heating requirements, etc. Natural gas is a versatile fuel and more environments friendly. Giobal Potentiai for Deveioping Naturai Gas From Shale The International Energy Agency currently estimates that global recoverable shale gas resources stand at 7,345 trillion cubic feet, so it's conceivable that this resource could one day offer similar benefits to other countries. Although exploration and development of these resources outside of the United States are still in the early stages. Chevron is acquiring shale acreage around the world. Exploration of shale gas is at 10 CHEMICAL BUSINESS < JANUARY 2014 various stages in a number of countries, including India, Argentina, Canada, China, Lithuania, Poland, Romania and Ukraine. Progress in India Companies including Reliance Industries Limited (E&P), RNRL, Vikas WSP Limited have expressed interest in exploring for shale gas in India, which is estimated to hold 63 trillion cubic feet of recoverable shale gas. Reliance Industries paid a reported US$1.7 billion for a 4 0 % share in Atlas Energy's leasehold in the Marcellus shale gas play in the eastern US. A complication to shale gas in India is that the government-issued leases for conventional petroleum exploration do not include unconventional sources such as shale gas. In August 2010, a delegation including the director-general of hydrocarbons and officials of the oil ministry is scheduled to meet in Washington with the US Geological Survey to discuss help in identifying and exploiting shale-gas resources in India. Basins of preliminary interest identified by Indian geologists are the Cambay Basin in Gujarat, the Assam-Arakan basin in northeast India, and the Gondwana Basin in central India. Oil and Natural Gas Corp. Ltd. (ONGC) will explore 30 additional shale gas wells in India over the next two years. The company will invest about Rs600 crore for this in the next two years. ONGC had first struck shale gas in at Ichhapur in Burdwan, West Bengal as a pilot project. Oil minister of India said that shale gas exploration would be a major step for India in achieving 'economic freedom'. "It took six years for the US to become a net exporter from being a net importer of energy with the use of shale gas and oil. Canada was the next country to do so. I want India to do the same." Last year, ONGC had signed a memorandum of understanding with ConocoPhillips to explore shale gas. The two undertook joint studies in Cambay, Krishna Godavari, Cauvery and Damodar basins based on which a drilling programme was firmed up in Cambay Basin area in Gujarat. ONGC's shale gas project is in line with the New Shale Gas Policy that was announced by the Centre. The policy allows ONGC and Oil India Ltd. to explore shale gas and oil in their nomination blocks. India, the world's fourth-largest consumer of energy, could be sitting on as much as 96 trillion cubic feet (tcf) of recoverable shale gas reserves, equivalent to about 26 years of the country's gas demand, according to the US Energy Information Administration. But production from shale remains a long way off for India, which relies on imports for much of its energy needs. As per available data, six basins - Cambay (in Gujarat), Assam-Arakan (in the North-East), Gondawana (in central India), KG onshore (in Andhra Pradesh), Cauvery onshore and Indo-Gangetic basins, hold shale gas potential. Future for Shaie Gas As demand is growing for more and more energy all over the world, the role that natural gas will play in that demand is uncertain. One thing that is certain is the shale gas resouces are shaping up to be key suppliers for domestic About the Author Dr. S.S. Verma is at present working as Professor in the Sant Longowal Institute of Engineering and Technology (SLIET) (Deemed-to-be University), Longowal, Punjab. Worked as an Assistant Professor, Dept. of Physics at Gondar University, Ethiopia from Oct. 2004 to July 2006. Did M.Sc. (Physics) from H.P.University, Shimla in 1982 and Ph.D. from I.I.T.Delhi in 1990. Worked as Research associate (CSIR) in IIT Delhi. Did postdoctoral studies in Japan under Japanese Govt. fellowship from October 1991 to March 1993. Has publ i shed about 40 research papers in national/international referred journals and about 300 science and technology related articles towards science popularization in various magazines/newspapers of national repute. Biography has been included in Marquis' Who's Who in Science and Engineering 8th and 9th editions. Also has been nominated to different awards and honors by the International Biographic Centre (IBC), London. natural gas. Impacts from this industry are uncertain as well. Historically, the energy industry has gone through times of "boom and bust" and is driven by the economical conditions present across the nation. The industry is also known for paying a higher wage, on average, compared to an equivalent manufacturing job. One thing that is not uncertain is that the natural gas industry associated with shale gas exploration will give the nation another source to potentially reduce the intake of foreign supplies of natural gas. References [I] http://en.wikipeclia.org/wiki/Shale_gas_by_country [2] h t t p : / / www. a p i . o r g / p o l i c y - a n d - i s s u e s / p o l i c y - items/exploration/facts_about_shaie_gas [3] http://www.business-standard.com/articie/economy-policy/ongc-to- put - i ndi a- on- shai e- gas- expi or at i on- map- on- t uesday- 113112300667_1.htmi [ 4 ] ht t p: / / www. c app. c a/ c anadal ndus t r y / nat ur al Gas / ShaieGas/Pages/defauit.aspx [5] http://www.chevron.com/deiiveringenergy/naturalgas/shalegas/ [6] http://www.deccanheraid.com/content/4 4 366/shale-gas-game- changer-india.html [7] http://www.eia.gov/energy_in_brief/articie/about_shaie_gas.cfm [8] http://www.hindustantimes.com/india-news/newdelhi/india- approves-poiicy-for-shale-gas-and-oii-expioration/articiei- 1126658.aspx [9] http://www.iivemint.com/lndustry/fYIQ5qBr4 EXkoDEJHS0 mXJ/ ONGC-begins-shaie-gas-expioration-in-lndia.html [10] http://www.shaletec.org/whatis.htm [II] http://www.thehindubusinessiine.com/companies/india-takes-its- first-step-into-shaie-gas-oii-expioration/articie5390558.ece CHEMICAL BUSINESS < JANUARY 2014 11