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Description
Desmomelt
(for
solvent adhesives) and Dispercoll
U (for
aqueous adhesive dispersions) have, as a
result, been supplemented by the new sol-
vent-free, carrier-free Desmomelt
prod-
ucts.
Desmomelt
ad-
hesive system is activated by heating it to a
relatively low temperature of e.g. 70 C.
As a result, the crystalline polyester seg-
ments melt and the adhesive becomes
soft and tacky. At this point in time, the
two substrates can be joined together. In
phase 1 of the process, the viscosity of the
adhesive increases further as it cools
down and the polyester segments begin to
recrystallize. With the crystallization of
the soft segments in phase 2, the adhe-
sive attains its final strength.
2. Desmomelt
Property spectrum
Time Seconds Minutes Days
Solvent and carrier-free
Low activation temperature for
heat-sensitive substrates
Fig. 1: Phases of the bonding process with thermo-
activatable polyurethane adhesives
Although the nature of the application can
vary considerably, all Desmomelt
grades
have a number of technical advantages:
The Desmomelt
Thermal activation
M
o
d
u
l
u
s
Phase
Phase
5
Temperature [C]
T
a
c
k
[
N
/
m
m
2
]
30 35 40 45 50 55 60 65 70 75 80
0
0
.
2
0
.
4
0
.
6
0
.
8
1
.
0
1
.
2
1
.
4
1
.
6
1
.
8
2
.
0
Fig. 2: Tack vs. temperature for Desmomelt 540
Wet film: 0,50 mm, substrate: coated AI,
piston: steel/PVC rigid, bonding pressure: 1 bar,
pressing time: 10 s
To illustrate the positive activation prop-
erties of adhesive systems based on
Desmomelt
is tacky, it
still behaves in virtually the same way as an
elastomer. The risk of the adhesive bleed-
ing into porous substrates is therefore min-
imal in the case of Desmomelt
.
Specific viscoelastic properties prevent the
adhesive from penetrating too far into
porous substrates. It remains in the joint
region wich has beneficial effects on the
properties of the laminated fabric.
Although this is of considerable practical im-
portance for the user, it means that, during
the bonding process, the sensitive equilib-
rium between wetting and penetration (for
example in the case of fabric bonding) has to
be maintained through the careful choice of
the process parameters. The so-called
Dahlquist criterion correlates the contact-
ability of an adhesive system with its storage
modulus, and provides a certain help in
establishing the right process parameters
6
High process reliability over a
broad temperature range
Fig. 3: Viscoelastic
properties of various
hot-melt adhesives
In contrast, Desmomelt
can be processed
over a broad temperature range, more or
less excusing any fluctuations in the pro-
cess conditions.
As Fig. 3 shows, other systems based on
other raw materials especially the tested
copolyesters are restricted by a very nar-
row process window.
Temperature [C]
Adhesive Tape
(Dahlquist criterion)
S
t
o
r
a
g
e
m
o
d
u
l
u
s
G
[
P
a
]
1
E
+
0
4
1
E
+
0
5
1
E
+
0
6
1
E
+
0
7
1
E
+
0
8
40 50 60 70 80 90 100 110 120
I
Copolyester film
I
Copolyamide film
I
Polyurethane (Desmomelt
530)
Fabric 1
Fabric 2
530. It
can be seen clearly that the Desmomelt
has out-
standing adhesion and excellent initial and
final strength.
Resistance to washing and
dry-cleaning
Another advantage is that all Desmomelt
does not
cause any nuisance from odor or have any
impact on the environment, and the coated
substrates can be stored for an unlimited
period before bonding.
Wide range of recrystallization
rates and thermoplasticities
Easy processing due to low
gel contents
The Desmomelt
granules
there is a wide choice of recrystallization
rates and thermoplasticities, as can be seen
from the Shore A hardness measurements
shown in Fig. 5 as a measure of increasing
crystallinity.
The present product range comprises two
granule types:
Desmomelt
540
G
Desmomelt
530
H
a
r
d
n
e
s
s
[
S
h
o
r
e
A
]
0
10 20 30 40 50 60
2
0
4
0
6
0
8
0
1
0
0
1
2
0
Fig. 5: Shore A hardness measurement as a measure of
the crystallization rates of the various Desmomelt
granule types at 23 C
Decrystallization: 25 min at 75 C
8
Substrates can, of course, also be provided
in advance with Desmomelt
adhesive films
(direct coating). Because of the thermally
reversible pseudo-network structure of the
Desmomelt
Product range
The range of Desmomelt
grades covers a
large number of fields of application for the
respective adhesive systems (film, nonwo-
ven fabric, direct coating), e.g. in the textile,
footwear, automotive and furniture indus-
tries.
Commercial products/ Form Particle size Crystallization Thermoplasticity Viscosity of a
Trial products supplied [m] rate 15% solution
in MEK [mPas]
Desmomelt
-coated fabric/nonwoven as a
stiffening element in the shoe
Fig. 6: Fabric-to-foam bonding for car interior trim
Short cycle times thanks to
high initial strength
4. Desmomelt
Application
10
5. Desmomelt
Granules
Processing hints
Desmomelt
is supplied as non-predried
granules. It is therefore urgently recom-
mended to dry them before processing.
Excessive moisture leads to processing
problems and to a reduction in the quality
of the finished part. Experience has shown
that no problems whatsoever occur in the
production process at a water content be-
low 0.1 %, resulting in perfect extrudates.
Feed zone* 165C
Compression zone* 185C
Metering zone* 185C
Die/head * 185C
*) must be adjusted to the geometry
Three-zone-screw total length 25 30 D
Function zone divided equally or
Feed 30 %
Compression 40 %
Metering 30 %
Pitch constant 1 D
Flight depth ratio 2 3: 1
Screw geometry:
Extruder drive rating:
Recommended temperature profile:
Screw diameter Drive rating
[mm] [kW]
30 16
45 25
60 40
90 60
120 90
11
Shear rate Gamma [1/s]
I
130C
I
150C
I
180C
M
e
l
t
v
i
s
c
o
s
i
t
y
E
T
A
[
P
a
s
]
1
.
0
E
+
0
2
1
.
0
E
+
0
3
1
.
0
E
+
0
4
1
.
0
E
+
0
5
1.0E+01 1.0E+02 1.0E+03
Shear rate Gamma [1/s]
I
130C
I
150C
I
180C
M
e
l
t
v
i
s
c
o
s
i
t
y
E
T
A
[
P
a
s
]
1
.
0
E
+
0
2
1
.
0
E
+
0
3
1
.
0
E
+
0
4
1
.
0
E
+
0
5
1.0E+01 1.0E+02 1.0E+03
Fig. 8: Flow curves of Desmomelt
530
Since Desmomelt
grades are
relatively sensitive to temperature fluctu-
ations above all at low shear rates.
Fig. 9: Flow curves of Desmomelt
540
12
Desmomelt
away
from direct sunlight.
Fig. 10: Pallet with Desmomelt
granules
6. Desmomelt
Quality assurance
Quality testing of
Desmomelt
granules under
practical conditions
Our customers throughout the world take it
for granted that we have the know-how, ex-
pertise and ability to correctly evaluate the
importance of these criteria.
14
Fig. 12: Determining the peel strength
Tailor-made problem solutions
through global proximity to
our customers
Innovative research, ongoing development,
and close proximity to our customers with
customer service bases throughout the
world guarantee continuous dialogue with
our partners and enable us to come up with
tailor-made problem solutions.
This information and our technical advice whether verbal,
in writing or by way of trials are given in good faith but
without warranty, and this also applies where proprietary
rights of third parties are involved. Our advice does not
release you from the obligation to verify the information
currently provided especially that contained in our safety
data and technical information sheets and to test our
products as to their suitability for the intended processes
and uses. The application, use and processing of our prod-
ucts and the products manufactured by you on the
basis of our technical advice are beyond our control and,
therefore, entirely your own responsibility. Our products are
sold in accordance with the current version of our General
Conditions of Sale and Delivery.
Edition: 10-2005 Order-no.: MS 00####
Printed in Germany E
Bayer MaterialScience AG
TPU Business Unit
51368 Leverkusen
Deutschland
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Tel. +49 214 30 81673, Leverkusen
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Tel. +852-28947150, Hongkong
NAFTA Region:
TPUinfo@bayer.com
Tel. +1-800-662-2927, Pittsburgh
For further information in the United States, Canada and Mexico,
visit our web site at
www.bayermaterialsciencenafta.com
Were there for you
with expertise and commitment all over the world:
Europe, Middle East, Africa Region:
TPUemea@bayermaterialscience.com
Tel. +49 214 30 81673, Leverkusen
Asia-Pacific Region:
TPUapac@bayermaterialscience.com
Tel. +852-28947150, Hongkong
NAFTA Region:
TPUinfo@bayer.com
Tel. +1-800-662-2927, Pittsburgh
For further information in the United States, Canada and Mexico,
visit our web site at
www.bayermaterialsciencenafta.com