CHEMISTRY

1.Number of waves made by an electron in one complete revolution in 3

rd
Bohr orbit is
(A) 2 (B) 3
(C) 4 (D) 1

2. Two substance A and B are present [A] = 4 [B]. The half life of A is 5 minute and that of B is
15 minute. If they start decaying at the same time following first order kinetics how
much time later the concentration of both of them would be same
(A) 15 minute (B) 10 minute
(C) 5 minute (D) 12 minute
3. A solution of sodium sulphate in water is electrolysed using platinum electrodes. The
products at cathode and anode are respectively.
(A) H
2
, O
2
(B) O
2
, H
2

(C) O
2
, Na (D) O
2
, SO
2

4. M(OH)
x
has K
SP
4 10
12
and solubility 10
4
M. Then the value of x is
(A) 1 (B) 2
(C) 3 (D) 4

5. A mixture of two immiscible liquids nitrobenzene & water boiling at 99C has a partial vapour
pressure of water 733 mm & that of nitrobenzene 27 mm. The ratio of the weights of
nitrobenzene to the water in the distillate is
(A) 2:1 (B) 4:1
(C) 3:1 (D) 1:4
6. Solubilites of carbonates decreases down the magnesium group due to decrease in
(A) entropy of solution formation (B) lattice energies of solids
(C) hydration energy of cations (D) inter-ionic attraction

7. Boric acid is prepared from borax by the action of
(A)
2 4
H SO (B) NaOH
(C)
2
CO (D)
2 3
Na CO

8. Which of the following ions can cause coagulation of proteins?
(A) Ag
+
(B) Fe
3+

(C) Cu
+
(D) Ni
2+


9. For the reaction,
C
7
H
8
(l) + 9O
2
(g) 7CO
2
(g) + 4H
2
O(l), the calculated heat of reaction is 232 kJ/mol
and observed heat of reaction is 50.4 kJ/mol, then the resonance energy is
(A) 182.2 kJ / mol (B) + 182.2 kJ / mol
(C) 172 kJ/ mol (D) None

10. If 0.5 mole of
2
BaCl is mixed with 0.2 mol of
3 4
Na PO , the maximum amount of
3 4 2
Ba (PO ) that
can be formed is:
(A) 0.7 mol (B) 0.5 mol
(C) 0.2 mol (D) 0.1 mol

11. In a face centered cubic arrangement of X and Y atoms, whose Y atoms are at the corner of
the unit cell and X-atoms at the face centers. One of the X-atoms is missing from
one of the faces in the unit cell. The simplest formula of the compound is
(A) X
5
Y
2

(B) X
2
Y
5

(C) XY
3
(D) X
3
Y

12. A box of 1 litre capacity is divided into two equal compartments by a thin partition which are
filled with 6g H
2
and 16g CH
4
respectively. The pressure in each compartment is
recorded as P atm. The total pressure when partition is removed will be
(A) P (B) 2P
(C) P/2 (D) P/4

13. Aniline reacts with phosgene and KOH to form
(A)

OH

(B)
C
O
Cl

(C)
NHCOCl

(D)
NCO

14. Which of the following can not be oxidized by
2 2
H O ?
(A) KI + HCl (B)
3
O
(C) PbS (D)
2 3
Na SO

15. Which of the following is present in maximum amount in acid rain?
(A)
3
HNO (B)
2 4
H SO
(C) HCl (D)
2 3
H CO

16. In Nesslers reagent for the detection of NH
3
, the active species is
(A) Hg
2
Cl
2
(B) HgI
2

(C) Hg
2
I
2
(D) HgI
4
2


17. If pressure is applied to the following equilibrium, liquid vapours the boiling point of
liquid
(A) will increase (B) will decrease
(C) may increase or decrease (D) will not change

18. The types of bond present in ZnSO
4
.7H
2
O are only
(A) Electrovalent and covalent
(B) Electrovalent and co-ordinate
(C) Electrovalent, Covalent and co- ordinate
(D) None of these

19. End product of the reaction
|| ||
3 2 2 2
O O
H C C CH CH CH COH
4
2
1. NaBH
2. H O, H
+
is
(A)
O
C H
3
O

(B)
O
O
CH
3

(C)
H
3
CHC
OH
CH
2
CH
2
CH
2
CH
2
OH

(D)
CH
3
C
O
CH
2
CH
2
CH
2
CH
2
OH

20. The order of reactivities of the following alkyl halides for SN
2
reaction is:
(A) RF > RCl > RBr > RI (B) RF > RBr > RCl > RI
(C) RCl > RBr > RF > RI (D) RI > RBr > RCl > RF


21.
CH
2
Cl
2
Anhyd.
AlCl
3
Z
Excess



Z is

(A)
CH
2
Cl

(B)
CHCl
2

(C)
(D)
CH
2



22.Which of the following will not give aldol condensation?
(A) RCH
2
CHO (B) RCOCH
2
R
(C) C
6
H
5
CHO (D) C
6
H
5
CH
2
CHO

23. A mixture of benzoic acid and phenol may be separate by treatment with
(A) NaHCO
3
(B) NaOH
(C) NH
3
solution (D) KOH

24.

C H
3
C CH
2
CH
3
O
18
2
H O
H
+

A, A is



(A)
C H
3
C
CH
3
OH
CH
2
OH
18

(B)
C H
3
C
CH
3
OH
CH
2
OH
18


(C) Both (D) none

25. 2-acetoxy benzoic acid is called
(A) antiseptic (B) aspirin
(C) antibiotic (D) mordant dye






26.


C H
3
CH CH CH
2
CH
3
HBr A (predominant). A is



(A)
C H
3
CH CH CH
3
CH
3
Br

(B)
C H
3
CH CH
2
CH
2
Br
CH
3

(C)
C H
3
C CH
2
CH
3
CH
3
Br


(D) None is correct

27. Consider the following reaction

C H
3
CH CH CH
3
D CH
3
Br
'X'
HBr

Identify the structure of the product X
(A)
H
3
C CH CH CH
2
D CH
3

(B)
H
3
C CH C CH
3
D CH
3

(C)
H
3
C C CH CH
3
D CH
3

(D)
H
3
C CH CH CH
3
CH
3





28. The IUPAC name
of
(C
2
H
5
)
2
NCH
2
CH COOH is
Cl

(A) 2 chloro 4 (N ethyl) pentanone acid
(B) 2 chloro 3 (N, N diethyl amino) propanoic acid
(C) 2 chloro 2 oxo diethyl amine
(D) 2 chloro 2 carboxy N ethyl ethane




29. In the commercial electrochemical process for aluminium extraction, the electrolyte used is
(A)
3
Al(OH) in NaOH solution
(B) An aqueous solution of
2 4 3
Al (SO )
(C) A molten mixture of
2 3 3 6
Al O and Na AlF
(D) A molten mixture of
2 3 3
Al O and Al(OH)

30. Which substance is not present in nucleic acids?
(A) cytosine (B) adenine
(C) thymine (D) guanidine



SOLUTION
1. Circumference of 3
rd
orbit = 2tr
3

According to Bohrs angular momentum of electron in 3
rd
orbit is
mvr
3
=
h
3
2t
or
3
2 r h
mv 3
t
=
By de-Broglie equation,
=
h
mv

=
3
2 r
3
t

2tr
3
= 3
i.e. circumference of 3
rd
orbit is three times the wavelength of electron or number of
waves made by Bohr electron in one complete revolution in 3
rd
orbit is three.
(B)
2. Amount of A in n
1
halves = | |
| |
=
|
\ .
1
n
0
1
A
2

Amount of B in n
2
halves = | |
| |
=
|
\ .
2
n
0
1
B
2

If | |
| |
|
\ .
1
n
0
1
A
2
= | |
| |
=
|
\ .
2
n
0
1
B
2
When A decays to n
1
halves and B decays to n
2
halves
| |
0
A = 4| |
0
B
4 =

= =
1
1 2
2
n
n n
1 2 n
2
2 (n n ) 2
2

n
2
= (n
1
-2) (1)
Now t = n
1
t
1/2(A)
= n
2
t
2(B)
=

1
2
n 5
1
n 15

=
1
2
n
3
n
(2)
by (1) & (2) n
1
= 3, n
2
=1 t=35 = 15 minute
(A)

3. Discharge potential of H
+
is less than Na
+
and OH

is less than
2
4
SO

.
Hence, (A) is correct
4. M(OH)
x
will ionize in the way
M(OH)
x
M
+

x
+ x OH

10
4
x 10
4

K
sp
= [M
+x
] [OH

]
x
(10
4
) (x 10
4
)
x
= 4 10
12

by inspection we get this relation will hold good when x = 2
(B)
.
5.
M A
P' P X =
Where X
A
is mole fraction in gaseous phase.

2
1 2
W /123
27 760 for nitrobenzene
W W
18 123
=
+

&
2
1 2
W /18
733 760
W W
18 123
=
+


1
2
W
4
W
=
(B)
6. (C) Hydration energy decreases as size of cation increases.

7.A

8.C

9. (A) As we know that,
Resonance energy = AH (observed) AH (calculated)
= (50.4 232.6) kJ / mol
= 182.2 kJ mol
1


10. Let us first solve this problem by writing the complete balanced reaction.

2 3 4 3 4 2
3BaCl + 2 Na PO Ba (PO ) + 6NaCl +
We can see that the moles of
2
BaCl used is
3
2
times the moles of
3 4
Na PO .
So, to react with 0.2 mol of
3 4
Na PO , the moles of BaCl
2
required would be
3
0.2
2
=
0.3. Since
2
BaCl is 0.5mol, we can conclude that
3 4
Na PO is the limiting reagent.
Therefore, moles of
3 4 2
Ba (PO ) formed is
1
0.2
2
= 0.1 mol.
11.A

12.A As pressure in each compartment is P atm, after the partition is removed the total pressure
will be P atm.

13.

2 2
PhNH COCl KOH Ph NCO + +
Hence (D) is correct.

14.B
3
O is more powerful oxidizing agent than
2 2
H O . So
2 2
H O reduces
3
O to
2
O .

3 2 2 2 2
O H O H O 2O + +

15.B

16.D

17.A
Boiling point of a liquid is the temperature at which vapour pressure became equal to
atm pressure. If the pressure is applied to the above equilibrium the reaction will go to the
backward direction, i.e. vapour pressure decrease hence the boiling point increase.

18.C

19 A NaBH
4
reduces ketonic group but not acidic group

C H
3
CH
OH
CH
2
CH
2
CH
2
COOH

is the intermediate which forms cyclic ester.

O
C H
3
O


20.D

21.D
22.C Aldol condensation is given by those carbonyl compounds, which possess at least
one o - H.
(C) is not having o hydrogen hence it will not give aldol condensation

23.A

24.A Stability of carbocation is 3 > 2 > 1

25.(B)

26.(C).

C H
3
CH CH
2
CH
3
H
C H
3
CH CH
CH
3
CH
3
1, 2 H shift
C H
3
C CH
2
CH
3
CH
3
Br
C H
3
C CH
2
CH
3
CH
3
Br

27.B more stable free radical will be formed as an intermediate

28.B
29.C

30.D Nitrogenous base in nucleic acids are Purine - Adenine and guanine Pyrimidine
Cytosine and Thymine or uracil




CHEMISTRY PAPER 2
1.If the radius of 2
nd
Bohr orbit of hydrogen atom is r
2
. The radius of third Bohr orbit will be
(A)
2
4
r
9
(B) 4r
2

(C)
2
9
r
4
(D) 9r
2

2. The chemical reaction 20
3
30
2
proceeds as following:
O
3


O
2
+ O (fast)
O + O
3
2O
2
(slow)
The rate expression should be
(A) r= K
I
[O
3
]
2
(B) r= K
I
(O
3
)
2
[O
2
]
-1

(C) r = K
I
[O
3
] [O
2
] (D) unpredictable

3. A certain current liberated 0.504 g of hydrogen in 2 hours. How many grams of copper can be
liberated by the same current flowing for the same time in CuSO
4
solution?
(A) 12.7 g (B) 15.9 g
(C)31.8 g (D) 63.5 g

4. The hydrolysis constant for ZnCl
2
will be
(A) K
h
=
K
w
K
b
(B)
2
K
w
K =
h
K
b

(C) K
h
=
2
K
w
2
K
b
(D)
K
b
K =
h 2
K
w

Where K
b
is effective dissociation constant of base Zn
++

5. Dry air was passed successively through a solution of 5 gm of a solute in 180 gm of water
and then through pure water. The loss in weight of solution was 2.50 gm and that of
pure solvent is 0.04 gm. The molecular weight of the solute is
(A) 31.25 (B) 3.125
(C) 312.5 (D) none of these

6. AlCl
3
forms dimmer in vapour phase but BCl
3
dose not because
(A) In Al there are vacant d orbitals in which it accommodates lone pair from chlorine
atoms
(B) In BCl
3
there is back bonding
(C) There is hydrogen bonding in between two AlCl
3
molecules in vapour phase
(D) None of the above

.
7. The paramagnetic species is
(A)
2
KO (B)
2
SiO
(C)
2
TiO (D)
2
BaO

8. Which of the following is less than zero during adsorption?
(A) AG (B) AS
(C) AH (D) All the above





9 The difference between heats of reaction at constant pressure and constant volume for the
reaction
( ) ( ) ( ) ( )
6 6 2 2 2
2C H 15O g 12CO g 6H O + + at 25C in KJ mol
1
is
(A) 7.43 KJmol
1
(B) 7.43 KJmol
1

(C) 2.477 KJmol
1


(D) 2.477 KJmol
1


10. Equal volumes of 1 M each of
4 2 2 7
KMnO and K Cr O are used to oxidise Fe(II) solution in acidic
medium. The amount of Fe oxidized will be
(A) more with
4
KMnO (B) equal with both oxidizing agents
(C) more with
2 2 7
K Cr O (D) cannot be determined


11. A solid crystal is composed of X, Y and Z atoms. Y atoms are occupying 50% of octahedral
voids, where as X atoms are occupying the 100% tetrahedral void with Z atoms
in ccp array arrangement, then the rational formula of the compound in the given
crystal is
(A) X
8
Y
2
Z
4
(B) X
5
Y
10
Z
8

(C) X
4
YZ
2
(D) X
16
Y
4
Z
8


12. An LPG cylinder contains 15 kg of butane gas at 27C and 10 atmospheric pressure.
It was leaking and its pressure fell down to 8 atmospheric pressure after one day.
The gas leaked is:
(A)1kg (B) 2 kg
(C)3 kg (D) 4 kg

13. Which of the following reactions will not give primary amine?
(A)
2
Br / KOH
3 2
CH CONH (B)

4
LiAlH
3
CH CN
(C)
4
LiAlH
3
CH NC (D)
4
LiAlH
3 2
CH CONH

14 When the same amount of zinc is treated separately with excess of sulphuric acid and
excess of sodium hydroxide, the ratio of volumes of hydrogen evolved is
(A) 1 : 1 (B) 1 : 2
(C) 2 : 1 (D) 9 : 4

15. Which of the following has greatest affinity for haemoglobin :
(A) CO (B) NO
(C)
2
O (D)
2
CO

16. The basic character of the transition metal monoxides follows the order
(A) CrO > VO > FeO > TiO (B) TiO > FeO > VO > CrO
(C) TiO > VO > CrO > FeO (D) VO > CrO > TiO > FeO

17. The enthalpies of two reaction are AH
1
and AH
2
(both positive) with
AH
2
> AH
1
. If the temperature of reacting system is increased from T
1
to T
2
, predict
which of the following alternatives is correct?
(A)
' '
1 2
1 2
K K
=
K K
(B)
' '
1 2
1 2
K K
>
K K

(C)
' '
1 2
1 2
K K
<
K K
(D) None
18. When NH
3
is treated with HCl, state of hybridisation on central nitrogen
(A) Changes from sp
3
to sp
2
(B) Remains unchanged
(C) Changes from sp
3
to sp
3
d (D) Changes from sp
3
to sp

19. The ease of alkaline hydrolysis is more for
(A)
COOCH
3
NO
2

(B)
COOCH
3
Cl

(C)
COOCH
3

(D)
COOCH
3
OCH
3

20. SN
1
reaction of alkyl halides leads to
(A) retention of configuration
(B) inversion of configuration
(C) reacemisation
(D) none of the above

21. Compound [X] gives very unpleasant odour with CHCl
3
/alc. KOH. [X] is
(A) C
6
H
5
NHCH
3
(B) C
6
H
5
CONH
2

(C) C
6
H
5
NH
2
(D) C
6
H
5
NHC
2
H
5


22. Which of the following compound gives a positive iodoform test?
(A) pentanal (B) 1 phenyl ethanol
(C) 2 phenyl ethanol (D) 3 pentanol










23. Which of the following is the strongest acid?

(A)
OH
NO
2

(B)
O H Cl


(C)
NO
2
O H

(D)
OH
NO
2


24. The product of the following reaction

C H
3
CH
2
( )
( )
3
2 2
i BH / THF
ii H O ,OH

(A) 1 pentanol (B) 2 pentanol
(C) pentane (D) 1, 2 pentane diol

25. Diazo coupling is useful to prepare some
(A) vitamin (B) proteins
(C) dyes (D) pesticides


26. In the reaction with Tollens reagent acetylene shows
(A) oxidizing property (B) reducing property
(C) basic property (D) acidic property


.
27 By which of the following reagent butanoic acid can be converted into butane
(A) HI/P/A (B) NaOH/CaO
(C) CH
3
MgBr (D) All of these

28. The IUPAC name of the compound

3 3
CH CH = CH - CH = CH - C CCH is
(A) 4, 6 octadien 2 yne (B) 2, 4 octadien 6 yne
(C) 2 octyn 4, 6 diene (D) 6 octyn 2, 4 diene

29. On igniting
o
2 3
Fe O at 1400 C, the product obtained is
(A)
2 3
Fe O melt (B) FeO
(C)
3 4
Fe O (D) Metallic iron

30. Which of the following is not a condensation polymer?
(A) Glyptal (B) Nylon-66
(C) Dacron (D) PTFE




SOLUTION

1.
2 2
2 2
n h
r
4 mZe
=
t

2
2
2
3
r 2
r 3
=
r
3
=
2
9
r
4

(C)
2. K
c
=
| || |
| |
2 2
3
O O
O

| |
| |
=
c 3
2
K O
O
O

Rate= K [O] [O
3
]
Rate =
| || |
| |
| | | |

=
2 1
c 3 3 1
3 2
2
K.K O O
K O O
O

(B)
3. According to Faradays second law
1 2
1 2
m m
E E
=
m
2
= 15.9 g.
Hence, (B) is correct.
4. Zn
++
+ 2H
2
O

Zn(OH)
2

+ 2H
+

K
h
=
( )
2
2
Zn OH H
Zn
+
++
( (

(

(1)
Zn(OH)
2


Zn
++
+ 2OH

K
b
=
( )
2
2
Zn OH
Zn OH
++
( (

(

, K
w
= [H
+
] [OH

]

2
w
b
K
K
= K
h

(B)
5. P
0
P
s
loss in weight of water chamber
P
s
loss in weight of solution chamber

0 s
s
P P n w n
P N m W

= =

0.04 5 18
2.50 m 180

hence m = 31.25
6. (A)
7.A O
2
-
have unpaired electrons.
8.A
9 A
10
. The 'n' factor of
4
KMnO is 5 while that of
2 2 7
K Cr O is 6. So for the same number of moles,
2 2 7
K Cr O will have greater equivalence than
4
KMnO . (C)
11.A
12 C For the cylinder V = constant
Hence P
1
V = n
1
RT and P
2
V = n
2
RT

1
1 1 1
2
2 2 2
w
P n w
M
w
P n w
M
= = =
Hence
2
10 15
8 w
= w
2
= 12 kg
Gas leaked out = 15 12 = 3 kg
(C)
13 (C) Isocyanides on reduction give 2 amine.
14. A
2 4 4 2
Zn H SO ZnSO H + +

2 2 2
Zn 2NaOH Na ZnO H + +
The ratio of volumes of
2
H evolved in both the cases is 1 : 1.
15.B
16.C
17.C As the temperature of reacting system is increased the equilibrium constant of
reaction is also increased for endothermic reactions so for two reactions on increasing
the temperature by equal amounts

1 2
1 2
K K
K K
' '
<
Hence, (C) is correct.
18 B On NH
4
+
state of hybridisation on central nitrogen atom is sp
3
as
in NH
3
.

N
H
H
H
H
+

Hence (B) is the correct answer.

19.A There is more electron deficiency on carbonyl carbon in
COOCH
3
NO
2

20.B
21.C
22.B Haloform test is used to identify COCH
3
group or CH
3
CH(OH) group which
can be oxidised to
||
3
O
CH C . 1 phenyl ethanol will give this test.
23.C Due to -M effect of NO
2
nitrophenols are stronger acids than pchloro phenol
among nitro phenols P nitro phenol is the strongest acid.
24. A Anti Markowvnikov product.
25(C)
26(D). Acidic hydrogen of acetylene is replaced by Ag
+
ion of Tollens reagent.
27. (A). Only HI in presence of P on heating can reduce carboxylic acids into alkanes.

P
3 2 2 3 2 2 3 2 2
CH CH CH COOH 4HI CH CH CH CH 2H O I
A
+ + +
28.B 29D 30D