Professional Documents
Culture Documents
Para el sistema 2-propanol(l)/agua(2), los valores siguientes de parmetros son recomendados para la ecuaci
a12=437.98 cal/mol, a21=1238 cal/mol
V, = 76.92
cm3/mol
V2 = 18.07 cm3/mol
Adems, se tienen las siguientes ecuaciones de Antoine:
ln P1sat 16.6780
3640.20
T 53.54
ln P2sat 16.28870
3816.44
T 46.13
A12
A21
ln 1 ln x1 x 2 A12 x 2
x1 x 2 A12 x 2 x1 A21
A12
A21
ln 2 ln x 2 x1 A21 x1
x1 x 2 A12 x 2 x1 A21
WILSON
V2
a12
A12 exp
V1
RT
V1
a 21
A21 exp
V2
RT
x1 1 P1*
y1
P
A21
x 2 x1 A21
A21
x 2 x1 A21
P x1 * 1 P1* x2 * 2 P
Ti sat
Bi
Ci
Ai ln P
T xi Ti sat
Presin de Burbuja
V2
V1
T
x1
P1 sat
P2 sat
R
a12
a21
A12
A21
gama1
gama2
P
y1
cm3/mol
cm3/mol
K
x2
1
kPa
*
P
x
*
P
x2 * 2 P
1
1
1
kPa
cal/molK
cal/mol
cal/mol
x1 1 P1*
y1
P
kPa
y2
Las cantidades en verde tienen frmula
Las cantidades en rosa son datos
Sacar P1 sat
Sacar P2 sat
Ecuacin Antonie
Sacar A12
x2 * 2 P
Sacar A21
Sacar 1
Sacar 2
Sacar P
Sacar y1
y2=1-y1
A12
V2
a
exp 12
V1
RT
A21
V1
a
exp 21
V2
RT
A1
ln 1 ln x1 x 2 A12 x 2
x1 x
A1
ln 2 ln x 2 x1 A21 x1
x1 x
A12
A21
x 2 A12 x 2
x1 x 2 A12 x 2 x1 A21
A12
A21
x1 A21 x1
x1 x 2 A12 x 2 x1 A21
Presin de Roco
b) P y {xi}, para T = 353.15 K y y1 = 0.60.
R
V1
V2
T
y1
P1 sat
P2 sat
a12
a21
P
67.01262
96.7214
96.71598
96.71358
96.71252
96.71206
96.71186
96.71178
96.71174
96.71172
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
96.71171
1.987
76.92
18.07
353.2
0.6
92.59
47.38
438
1238
cal/molK
cm3/mol
cm3/mol
K
y2
kPa
kPa
cal/mol
cal/mol
x1
0.434254
0.439235
0.442562
0.444773
0.446237
0.447205
0.447843
0.448264
0.448541
0.448724
0.448844
0.448923
0.448975
0.449009
0.449032
0.449047
0.449056
0.449063
0.449067
0.449070
0.449072
x2
0.565746
0.560765
0.557438
0.555227
0.553763
0.552795
0.552157
0.551736
0.551459
0.551276
0.551156
0.551077
0.551025
0.550991
0.550968
0.550953
0.550944
0.550937
0.550933
0.550930
0.550928
0.4
A12
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
0.125856
A21
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
0.729423
gama1
1.426964
1.416157
1.409083
1.404444
1.401398
1.399398
1.398082
1.397218
1.396649
1.396275
1.396029
1.395867
1.395761
1.395691
1.395645
1.395614
1.395594
1.395581
1.395573
1.395567
1.395563
1
y1
P1
y2
sat
P 2sat
y1P
P1 sat
x1
x 2 1 x1
gama2
1.456151
1.46476
1.470556
1.474428
1.477002
1.478707
1.479834
1.480577
1.481067
1.48139
1.481602
1.481742
1.481834
1.481895
1.481935
1.481961
1.481978
1.48199
1.481997
1.482002
1.482005
A 12
V2
a 12
exp
V1
RT
A 21
V1
a 21
exp
V2
RT
ln 1 ln x1 x2 A12 x2
x
1
ln 2 ln x2 x1 A21 x1
x
1
El cambio de P es muy
pequeo
A12
A21
x2 A12
x2 x1 A21
A12
A21
x2 A12
x2 x1 A21
1
y1
1 P1
x1
sat
y2
2 P2sat
y1 P
1 P1 sat
A12
A12
A21
x2 x1 A21
A21
x2 x1 A21
Temperatura de Burbuja
V2
V1
P
x1
R
B
A
C
Ti
T
P1 sat
a12
a21
A12
A21
l
ln gama1
ln gama 2
P1 sat
ITERACIONES
18.07
76.92
101.33
0.85
1.987
3640.2
16.678
53.54
355.39
358.05
cm3/mol
cm3/mol
kPa
x2
0.15
3816.4
16.289 Datos de Antoine
46.13
373.15 K
K
T
353.924485
353.848902
353.8475
353.847474
353.847474
353.847474
353.847474
A12
0.126021
0.126004
0.126004
0.126004
0.126004
0.126004
0.126004
A21
0.732062
0.731786
0.731781
0.731781
0.731781
0.731781
0.731781
gama 1
1.020288
1.020299
1.020299
1.020299
1.020299
1.020299
1.020299
95.242241 353.847474
95.242241 353.847474
95.242241 353.847474
0.126004
0.126004
0.126004
0.731781
0.731781
0.731781
1.020299
1.020299
1.020299
Ti
sat
T
ln P1sat 16.6780
Bi
Ai ln P
xT
i
sat
3640.20
T 53.54
V2
A12
exp
V1
R
V1
A21
exp
V2
R
ln 1 ln x1 x 2 A12 x 2
x1
ln 2 ln x 2 x1 A21 x1
x1
gama 2
2.562357232
2.563023943
2.563036316
2.563036546
2.56303655
2.56303655
2.56303655
y1
y1
sat
1
x1 1 x2 2 P
Bi
T
Ai ln P1sa
2.56303655
2.56303655
2.56303655 0.81515098 0.18484902
Bi
T
Ai ln P1sa
Ti
sat
3640.20
53.54
Bi
Ci
Ai ln P
xT
i
sat
ln P2sat 16.28870
V2
a12
A12
exp
V1
RT
V1
a 21
A21
exp
V2
RT
A12
A21
ln x1 x 2 A12 x 2
x1 x 2 A12 x 2 x1 A21
A12
A21
ln x 2 x1 A21 x1
x1 x 2 A12 x 2 x1 A21
sat
1
P2sat
x1 1 x2 2
sat
P
1
Bi
T
Ci
sat
Ai ln P1
3816.44
T 46.13
Bi
T
Ci
sat
Ai ln P1
DT son pequeas
y1
x P
P
*
1 1 1
T de Roco
d) T y {xi}, para P = 101.33 kPa y y1 = 0.40.
R
V2
V1
P
y1
B
A
C
Ti
T
1.987
18.07
76.92
101.33
0.4
3640.2
16.678
53.54
248.31
267.86
cal/molK
a12
cm3/mol
a21
cm3/mol
kPa
y2
0.6
3816
16.29 Datos de Antoine
46.13
280.9 K
K
ln P1 sat
P1 sat
ln P2 sat
0.7357
kPa
K
P1 sat
T
0.735667
437.98
1238
267.8588
A12
0.103166
A21
0.415811
x1
Ti sat
cal/mol
cal/mol
ln P1sat 16.6780
Bi
Ci
Ai ln P
xT
i
sat
3640.20
T 53.54
ln P2sat 16.28870
Pi sat P
i
yii Pj
i Pi sat
sat
Bi
Ci
sat
Ai ln P1
ln P2sat 16.28870
x2
3816.44
T 46.13
3816.44
T 46.13
A12
V2
a
exp 12
V1
RT
A21
V1
a 21
exp
V2
RT
x1
y1 P
1 P1 sat
A12
A21
ln 1 ln x1 x2 A12 x2
x
A
x
x
A
2 12
2
1 21
1
A12
A21
ln 2 ln x2 x1 A21 x1
x
A
x
x
A
2 12
2
1 21
1
ln P2sat 16.28870
3816.44
T 46.13
3816.44
T 46.13
A12
A21
x2 A12 x2 x1 A21
A12
A21
x2 A12 x2 x1 A21