Erg 2004

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Secretariat of Transport and Communications
Transport Transports
Canada Canada
Safety and Security
THIS DOCUMENT SHOULD NOT BE USED TO
DETERMINE COMPLIANCE WITH THE
DANGEROUS GOODS REGULATIONS
OR
TO CREATE WORKER SAFETY DOCUMENTS
FOR SPECIFIC CHEMICALS
U.S. Department of Transportation
Research and Special Programs Administration
N O T F O R S A L E
This document is distributed free of charge to Public Safety Organizations
and may not be resold.
2004
A GUIDEBOOK FOR
FIRST RESPONDERS
DURING THE INITIAL PHASE
OF A DANGEROUS GOODS/
HAZARDOUS MATERIALS
INCIDENT
Emergency
Response
Guidebook
EMERGENCY CONTACT
1-000-000-0000
NO. & TYPE
OF PACKAGES
QUANTITY
DESCRIPTION OF
ARTICLES
1 TANK TRUCK ISOPROPANOL 3 UN1219 II 3,000 LITERS
EXAMPLE OF EMERGENCY
RESPONSE TELEPHONE NUMBER
HAZARD CLASS
OR DIVISION NO.
SHIPPING NAME ID NUMBER PACKING GROUP
SHIPPING DOCUMENTS (PAPERS)*
The shipping document provides vital information when responding to a
hazardous materials/dangerous goods** incident. The shipping document
contains information needed to identify the materials involved. Use this
information to initiate protective actions for your own safety and the safety
of the public. The shipping document contains the proper shipping name
(see blue-bordered pages), the hazard class or division of the material(s),
ID number (see yellow-bordered pages), and, where appropriate, the
Packing Group. In addition, there must be information available that
describes the hazards of the material which can be used in the mitigation
of an incident. The information must be entered on or be with the shipping
document. This requirement may be satisfied by attaching a guide from the
ERG2004 to the shipping document, or by having the entire guidebook
available for ready reference. Shipping documents are required for most
dangerous goods in transportation. Shipping documents are kept in
the cab of the motor vehicle,
the possession of the train crew member,
a holder on the bridge of a vessel, or
an aircraft pilots possession.
The 4-digit ID Number may be shown on the diamond-shaped placard or on
an adjacent orange panel displayed on the ends and sides of a cargo tank,
vehicle or rail car.
* For the purposes of this book, the terms shipping document/shipping paper are synonymous.
** For the purposes of this book, the terms hazardous materials/dangerous goods are synonymous.
EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER
or A Numbered
Placard
A Placard
and an
Orange Panel
1219
1219
FLAMMABLE
EnglishCover2004.qxd 9/8/2004 8:51 AM Page 2
Page 1
RESIST RUSHING IN !
APPROACH INCIDENT FROM UPWIND
STAY CLEAR OF ALL SPILLS, VAPORS, FUMES AND SMOKE
HOW TO USE THIS GUIDEBOOK DURING AN INCIDENT INVOLVING
DANGEROUS GOODS
ONE IDENTIFY THE MATERIAL BY FINDING ANY ONE OF THE FOLLOWING:
THE 4-DIGIT ID NUMBER ON A PLACARD OR ORANGE PANEL
THE 4-DIGIT ID NUMBER (after UN/NA) ON A SHIPPING DOCUMENT OR PACKAGE
THE NAME OF THE MATERIAL ON A SHIPPING DOCUMENT, PLACARD OR PACKAGE
IF AN ID NUMBER OR THE NAME OF THE MATERIAL CANNOT BE FOUND, SKIP
TO THE NOTES BELOW.
TWO LOOK UP THE MATERIALS 3-DIGIT GUIDE NUMBER IN EITHER:
THE ID NUMBER INDEX..(the yellow-bordered pages of the guidebook)
THE NAME OF MATERIAL INDEX..(the blue-bordered pages of the guidebook)
If the guide number is supplemented with the letter P, it indicates that the material may
undergo violent polymerization if subjected to heat or contamination.
If the index entry is highlighted (in either yellow or blue), it is a TIH (Toxic Inhalation Hazard) material,
a chemical warfare agent or a Dangerous Water Reactive Material (produces toxic gas upon contact
with water). LOOK FOR THE ID NUMBER AND NAME OF THE MATERIAL IN THE TABLE
OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES (the green-bordered pages).
Then, if necessary, BEGIN PROTECTIVE ACTIONS IMMEDIATELY (see Protective Actions on
page 298). If protective action is not required, use the information jointly with the 3-digit guide.
USE GUIDE 112 FOR ALL EXPLOSIVES EXCEPT FOR EXPLOSIVES 1.4
(EXPLOSIVES C) WHERE GUIDE 114 IS TO BE CONSULTED.
THREE TURN TO THE NUMBERED GUIDE (the orange-bordered pages) AND READ CAREFULLY.
NOTES IF A NUMBERED GUIDE CANNOT BE OBTAINED BY FOLLOWING THE ABOVE
STEPS, AND A PLACARD CAN BE SEEN, LOCATE THE PLACARD IN THE TABLE
OF PLACARDS (pages 16-17), THEN GO TO THE 3-DIGIT GUIDE SHOWN NEXT TO
THE SAMPLE PLACARD.
IF A REFERENCE TO A GUIDE CANNOT BE FOUND AND THIS INCIDENT IS BELIEVED TO
INVOLVE DANGEROUS GOODS, TURN TO GUIDE 111 NOW, AND USE IT UNTIL ADDITIONAL
INFORMATION BECOMES AVAILABLE. If the shipping document lists an emergency response
telephone number, call that number. If the shipping document is not available, or no emergency response
telephone number is listed, IMMEDIATELY CALL the appropriate emergency response agency listed
on the inside back cover of this guidebook. Provide as much information as possible, such as the
name of the carrier (trucking company or railroad) and vehicle number. AS A LAST RESORT, CONSULT
THE TABLE OF RAIL CAR AND ROAD TRAILER IDENTIFICATION CHART (pages 18-19). IF THE
CONTAINER CAN BE IDENTIFIED, REMEMBER THAT THE INFORMATION ASSOCIATED
WITH THESE CONTAINERS IS FOR THE WORST CASE POSSIBLE.
Page 2
ERG2004 USERS GUIDE
The 2004 Emergency Response Guidebook (ERG2004) was developed jointly by Transport
Canada (TC), the U.S. Department of Transportation (DOT), the Secretariat of Transport and
Communications of Mexico (SCT) and with the collaboration of CIQUIME (Centro de Informacin
Qumica para Emergencias) of Argentina, for use by fire fighters, police, and other emergency
services personnel who may be the first to arrive at the scene of a transportation incident
involving dangerous goods. It is primarily a guide to aid first responders in quickly
identifying the specific or generic hazards of the material(s) involved in the incident,
and protecting themselves and the general public during the initial response phase
of the incident. For the purposes of this guidebook, the initial response phase is that period
following arrival at the scene of an incident during which the presence and/or identification of
dangerous goods is confirmed, protective actions and area securement are initiated, and
assistance of qualified personnel is requested. It is not intended to provide information on the
physical or chemical properties of dangerous goods.
This guidebook will assist responders in making initial decisions upon arriving at the scene of a
dangerous goods incident. It should not be considered as a substitute for emergency response
training, knowledge or sound judgment. ERG2004 does not address all possible circumstances
that may be associated with a dangerous goods incident. It is primarily designed for use at a
dangerous goods incident occurring on a highway or railroad. Be mindful that there may be
limited value in its application at fixed facility locations.
ERG2004 incorporates dangerous goods lists from the most recent United Nations
Recommendations as well as from other international and national regulations. Explosives are
not listed individually by either proper shipping name or ID Number. They do, however,
appear under the general heading Explosives on the first page of the ID Number index
(yellow-bordered pages) and alphabetically in the Name of Material index (blue-bordered
pages). Also, the letter P following the guide number in the yellow-bordered and blue-
bordered pages identifies those materials which present a polymerization hazard under certain
conditions, for example: Acrolein, stabilized 131P.
First responders at the scene of a dangerous goods incident should seek additional specific
information about any material in question as soon as possible. The information received by
contacting the appropriate emergency response agency, the emergency response number on
the shipping document, or by consulting the information on or accompanying the shipping
document, may be more specific and accurate than this guidebook in providing guidance for the
materials involved.
BECOME FAMILIAR WITH THIS GUIDEBOOK BEFORE USING IT DURING AN
EMERGENCY! In the U.S., according to the requirements of the U.S. Department of Labors
Occupational Safety and Health Administration (OSHA, 29 CFR 1910.120), and regulations
issued by the U.S. Environmental Protection Agency (EPA, 40 CFR Part 311), first responders
must be trained regarding the use of this guidebook.
Page 3
GUIDEBOOK CONTENTS
1-Yellow-bordered pages: Index list of dangerous goods in numerical order of ID number.
This section quickly identifies the guide to be consulted from the ID Number of the material
involved. This list displays the 4-digit ID number of the material followed by its assigned
emergency response guide and the material name.
For example: ID No. GUIDE No. Name of Material
1090 127 Acetone
2-Blue-bordered pages: Index list of dangerous goods in alphabetical order of material
name. This section quickly identifies the guide to be consulted from the name of the material
involved. This list displays the name of the material followed by its assigned emergency
response guide and 4-digit ID number.
For example: Name of Material GUIDE No. ID No.
Sulfuric acid 137 1830
3-Orange-bordered pages: This section is the most important section of the guidebook
because it is where all safety recommendations are provided. It comprises a total of 62 individual
guides, presented in a two-page format. Each guide provides safety recommendations and
emergency response information to protect yourself and the public. The left hand page provides
safety related information whereas the right hand page provides emergency response guidance
and activities for fire situations, spill or leak incidents and first aid. Each guide is designed to
cover a group of materials which possess similar chemical and toxicological characteristics.
The guide title identifies the general hazards of the dangerous goods covered.
For example: GUIDE 124 - Gases-Toxic and/or Corrosive-Oxidizing.
Each guide is divided into three main sections: the first section describes potential hazards
that the material may display in terms of fire/explosion and health effects upon exposure. The
highest potential is listed first. The emergency responder should consult this section first. This
allows the responder to make decisions regarding the protection of the emergency response
team as well as the surrounding population.
The second section outlines suggested public safety measures based on the situation at hand. It
provides general information regarding immediate isolation of the incident site, recommended type of
protective clothing and respiratory protection. Suggested evacuation distances are listed for small
and large spills and for fire situations (fragmentation hazard). It also directs the reader to consult the
tables listing Toxic Inhalation Hazard materials (TIH), chemical warfare agents and water-reactive
materials (green-bordered pages) when the material name is highlighted in the yellow-bordered and
blue-bordered pages.
The third section covers emergency response actions, including first aid. It outlines special
precautions for incidents which involve fire, spill or chemical exposure. Several recommendations
are listed under each part which will further assist in the decision making process. The information
on first aid is general guidance prior to seeking medical care.
Page 4
4-Green-bordered pages: This section contains a table which lists, by ID number, TIH
materials, including certain chemical warfare agents, and water-reactive materials which produce
toxic gases upon contact with water. The table provides two different types of recommended
safe distances which are Initial isolation distances and Protective action distances. The
materials are highlighted for easy identification in both numeric (yellow-bordered pages) and
alphabetic (blue-bordered pages) lists of the guidebook. The table provides distances for both
small (approximately 200 liters or less) and large spills (more than 200 liters) for all highlighted
materials. The list is further subdivided into daytime and nighttime situations. This is necessary
due to varying atmospheric conditions which greatly affect the size of the hazardous area. The
distances change from daytime to nighttime due to different mixing and dispersion conditions in
the air. During the night, the air is generally calmer and this causes the chemical to disperse less
and therefore create a toxicity zone which is greater than would usually occur during the day.
During the day, the chemical is generally dispersed by a more active atmosphere. The chemical
will be present in a larger area; however, the actual area where toxic levels are reached will be
smaller (due to increased dispersion). It is the quantity or concentration of the chemical vapor
that poses problems not its mere presence.
The Initial Isolation Distance is a distance within which all persons should be considered for
evacuation in all directions from the actual spill/leak source. It is a distance (radius) which
defines a circle (Initial Isolation Zone) within which persons may be exposed to dangerous
concentrations upwind of the source and may be exposed to life threatening concentrations
downwind of the source. For example, in the case of Compressed gas, toxic, n.o.s., ID No.
1955, Inhalation Hazard Zone A, the isolation distance for small spills is 600 meters, therefore,
representing an evacuation circle of 1200 meters in diameter.
For the same material, the Protective Action Distance is 5.9 kilometers for a daytime incident
and 11.0+ kilometers for a nighttime incident, these distances represent a downwind distance
from the spill/leak source within which Protective Actions could be implemented. Protective
Actions are those steps taken to preserve the health and safety of emergency responders and
the public. People in this area could be evacuated and/or sheltered in-place. For more
information, consult the INTRODUCTION TO THE TABLE OF INITIAL ISOLATION AND
PROTECTIVE ACTION DISTANCES (pages 295-296).
What is a TIH?
It is a gas or volatile liquid which is known to be so toxic to humans as to pose a hazard to health
during transportation, or in the absence of adequate data on human toxicity, is presumed to be toxic
to humans because when tested on laboratory animals it has an LC50 value of not more than 5000
ppm.
It is important to note that even though the term zone is used, the hazard zones do not represent
any actual area or distance. The assignment of the zones is strictly a function of their Lethal
Concentration 50 (LC50); for example, TIH Zone A is more toxic than Zone D. All distances
which are listed in the green-bordered pages are calculated by the use of mathematical models
for each TIH material.
Page 5
Assignment of hazard zones:
HAZARD ZONE A: Gases: LC50 of less than or equal to 200 ppm,
Liquids: V equal to or greater than 500 LC50 and LC50 less than or
equal to 200 ppm,
HAZARD ZONE B: Gases: LC50 greater than 200 ppm and less than or equal to 1000 ppm,
Liquids: V equal to or greater than 10 LC50; LC50 less than or equal to
1000 ppm and criteria for Hazard Zone A are not met,
HAZARD ZONE C: LC50 greater than 1000 ppm and less than or equal to 3000 ppm,
HAZARD ZONE D: LC50 greater than 3000 ppm and less than or equal to 5000 ppm.
ISOLATION AND EVACUATION DISTANCES
Isolation or evacuation distances are shown in the guides (orange-bordered pages) and in the
Table of Initial Isolation and Protective Action Distances (green-bordered pages). This may
confuse users not thoroughly familiar with ERG2004.
It is important to note that some guides refer only to non-TIH materials (36 guides), some refer
to both TIH and non-TIH materials (21 guides) and some (5 guides) refer only to TIH or Water-
reactive materials (WRM). A guide refers to both TIH and non-TIH materials (for example see
GUIDE 131) when the following sentence appears under the title EVACUATION-Spill: See the
Table of Initial Isolation and Protective Action Distances for highlighted substances. For non-
highlighted substances, increase, in the downwind direction, as necessary, the isolation distance
shown under PUBLIC SAFETY. A guide refers only to TIH or WRM materials (for example
see GUIDE 124) when the following sentence appears under the title EVACUATION-Spill:
See the Table of Initial Isolation and Protective Action Distances. If the previous sentences do
not appear in a guide, then this particular guide refers only to non-TIH materials (for example
see GUIDE 128).
In order to identify appropriate isolation and protective action distances, use the following:
If you are dealing with a TIH/WRM/Chemical warfare material (highlighted entries in the index
lists), the isolation and evacuation distances are found directly in the green-bordered pages.
The guides (orange-bordered pages) also remind the user to refer to the green-bordered
pages for evacuation specific information involving highlighted materials.
If you are dealing with a non-TIH material but the guide refers to both TIH and non-TIH
materials, an immediate isolation distance is provided under the heading PUBLIC SAFETY as
a precautionary measure to prevent injuries. It applies to the non-TIH materials only. In
addition, for evacuation purposes, the guide informs the user under the title EVACUATION-Spill
to increase, for non-highlighted substances, in the downwind direction, if necessary, the immediate
isolation distance listed under PUBLIC SAFETY. For example, GUIDE 131 Flammable
Liquids-Toxic, instructs the user to: "As an immediate precautionary measure, isolate spill or
leak area for at least 50 meters (150 feet) in all directions." In case of a large spill, the isolation
area could be expanded from 50 meters to a distance deemed as safe by the On-scene-
commander and emergency responders.
If you are dealing with a non-TIH material and the guide refers only to non-TIH materials,
the immediate isolation and evacuation distances are specified as actual distances in the guide
(orange-bordered pages) and are not referenced in the green-bordered pages.
Page 6
SAFETY PRECAUTIONS
APPROACH CAUTIOUSLY FROM UPWIND. Resist the urge to rush in; others cannot be
helped until the situation has been fully assessed.
SECURE THE SCENE. Without entering the immediate hazard area, isolate the area and
assure the safety of people and the environment, keep people away from the scene and outside
the safety perimeter. Allow enough room to move and remove your own equipment.
IDENTIFY THE HAZARDS. Placards, container labels, shipping documents, material safety
data sheets, Rail Car and Road Trailer Identification Charts, and/or knowledgeable persons on
the scene are valuable information sources. Evaluate all available information and consult the
recommended guide to reduce immediate risks. Additional information, provided by the
shipper or obtained from another authoritative source, may change some of the
emphasis or details found in the guide. Remember, the guide provides only the most
important and worst case scenario information for the initial response in relation to a family or
class of dangerous goods. As more material-specific information becomes available, the response
should be tailored to the situation.
ASSESS THE SITUATION. Consider the following:
- Is there a fire, a spill or a leak?
- What are the weather conditions?
- What is the terrain like?
- Who/what is at risk: people, property or the environment?
- What actions should be taken: Is an evacuation necessary? Is diking
necessary? What resources (human and equipment) are required and
are readily available?
- What can be done immediately?
OBTAIN HELP. Advise your headquarters to notify responsible agencies and call for assistance
from qualified personnel.
DECIDE ON SITE ENTRY. Any efforts made to rescue persons, protect property or the
environment must be weighed against the possibility that you could become part of the problem.
Enter the area only when wearing appropriate protective gear (see PROTECTIVE CLOTHING,
page 350).
RESPOND. Respond in an appropriate manner. Establish a command post and lines of
communication. Rescue casualties where possible and evacuate if necessary. Maintain control
of the site. Continually reassess the situation and modify the response accordingly. The first
duty is to consider the safety of people in the immediate area, including your own.
ABOVE ALL Do not walk into or touch spilled material. Avoid inhalation of fumes, smoke and
vapors, even if no dangerous goods are known to be involved. Do not assume that gases or
vapors are harmless because of lack of a smellodorless gases or vapors may be harmful.
Use CAUTION when handling empty containers because they may still present hazards until
they are cleaned and purged of all residues.
Page 7
WHO TO CALL FOR ASSISTANCE
Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous
goods, protect oneself and the public, secure the area, and call for the assistance of trained
personnel as soon as conditions permit. Follow the steps outlined in your organizations
standard operating procedures and/or local emergency response plan for obtaining qualified
assistance. Generally, the notification sequence and requests for technical information beyond
what is available in this guidebook should occur in the following order:
1. ORGANIZATION/AGENCY
Notify your organization/agency. This will set in motion a series of events based upon the
information provided. Actions may range from dispatching additional trained personnel to the
scene to activating the local emergency response plan. Ensure that local fire and police
departments have been notified.
2. EMERGENCY RESPONSE TELEPHONE NUMBER
Locate and call the telephone number listed on the shipping document. The person answering
the phone at the listed emergency response number must be knowledgeable of the materials
and mitigation actions to be taken, or must have immediate access to a person who has the
required knowledge.
3. NATIONAL ASSISTANCE
Contact the appropriate emergency response agency listed on the inside back cover of this
guidebook when the emergency response telephone number is not available. Upon receipt of
a call describing the nature of the incident, the agency will provide immediate advice on handling
the early stages of the incident. The agency will also contact the shipper or manufacturer of the
material for more detailed information and request on-scene assistance when necessary.
Collect and provide as much of the following information as can safely be obtained to your chain-of-
command and specialists contacted for technical guidance:
Your name, call back telephone number, FAX number
Location and nature of problem (spill, fire, etc.)
Name and identification number of material(s) involved
Shipper/consignee/point of origin
Carrier name, rail car or truck number
Container type and size
Quantity of material transported/released
Local conditions (weather, terrain, proximity to schools, hospitals, waterways, etc.)
Injuries and exposures
Local emergency services that have been notified
Page 8
CANADA
1. CANUTEC
CANUTEC is the Canadian Transport Emergency Centre operated by the Transport Dangerous
Goods Directorate of Transport Canada.
CANUTEC provides a national bilingual (French and English) advisory service and is staffed by
professional scientists experienced and trained in interpreting technical information and providing
emergency response advice.
In an emergency, CANUTEC may be called collect at
613-996-6666 (24 hours)
*666 cellular (Press Star 666, Canada only)
In a non-emergency situation, please call the information line at 613-992-4624 (24 hours).
2. PROVINCIAL AGENCIES
Although technical information and emergency response assistance can be obtained from CANUTEC,
there are federal and provincial regulations requiring the reporting of dangerous goods incidents to
certain authorities.
The following list of provincial agencies is supplied for your convenience.
Province Emergency Authority and/or
Telephone Number
Alberta ......................................... Local Police and Provincial Authorities
1-800-272-9600* or 780-422-9600
British Columbia .......................... Local Police and Provincial Authorities
1-800-663-3456
Manitoba ..................................... Provincial Authority 204-945-4888 and
Local Police or fire brigade, as
appropriate
New Brunswick ........................... Local Police or 1-800-565-1633** or
902-426-6030
Newfoundland ............................ Local Police and 709-772-2083
Northwest Territories .................. 867-920-8130
Nova Scotia ................................ Local Police or 1-800-565-1633** or
902-426-6030
Nunavut Territory ....................... Local Police and 1-800-693-1666 or
867-979-6262
Ontario ......................................... Local Police
Prince Edward Island ................. Local Police or 1-800-565-1633** or
902-426-6030
Quebec ........................................ Local Police
Saskatchewan ............................ Local Police or 1-800-667-7525
Yukon Territory ........................... 867-667-7244
* This number is not accessible from outside Alberta.
** This number is not accessible from outside of New Brunswick, Nova Scotia or Prince Edward Island.
Page 9
NOTE:
1. The appropriate federal agency must be notified in the case of rail, air or marine incidents.
2. The nearest police department must be notified in the case of lost, stolen or misplaced explosives,
radioactive materials or infectious substances.
3. CANUTEC must be notified in the case of:
a. lost, stolen or misplaced infectious substances;
b. an incident involving infectious substances;
c. an accidental release from a cylinder that has suffered a catastrophic failure;
d. an incident where the shipping documents display CANUTECs telephone number 613-996-
6666 as the emergency telephone number; or
e. a dangerous goods incident in which a railway vehicle, a ship, an aircraft, an aerodrome or
an air cargo facility is involved.
Page 10
UNITED STATES
1. CHEMTREC
, a 24-hour emergency response communication service, can be reached as follows:

CALL CHEMTREC
(24 hours)
1-800-424-9300
(Toll-free in the U.S., Canada, and the U.S. Virgin Islands)
For calls originating elsewhere:
703-527-3887 (Collect calls are accepted)
or
2. CHEM-TEL, INC., a 24-hour emergency response communication service, can be reached as follows:
CALL CHEM-TEL, INC. (24 hours)
1-800-255-3924
or
3. INFOTRAC, a 24-hour emergency response communication service, can be reached as follows:
CALL INFOTRAC (24 hours)
1-800-535-5053
or
4. 3E COMPANY, a 24-hour emergency response communication service, can be reached as follows:
CALL 3E COMPANY (24 hours)
1-800-451-8346
The emergency response information services shown above have requested to be listed as providers of
emergency response information and have agreed to provide emergency response information to all
callers. They maintain periodically updated lists of state and Federal radiation authorities who provide
information and technical assistance on handling incidents involving radioactive materials.
Page 11
5. NATIONAL RESPONSE CENTER (NRC)
The NRC, which is operated by the U.S. Coast Guard, receives reports required when dangerous
goods and hazardous substances are spilled. After receiving notification of an incident, the NRC will
immediately notify the appropriate Federal On-Scene Coordinator and concerned Federal agencies.
Federal law requires that anyone who releases into the environment a reportable quantity of a
hazardous substance (including oil when water is, or may be affected) or a material identified as a
marine pollutant, must immediately notify the NRC. When in doubt as to whether the amount
released equals the required reporting levels for these materials, the NRC should be notified.
CALL NRC (24 hours)
1-800-424-8802
202-267-2675 in the District of Columbia
Calling the emergency response telephone number, CHEMTREC
, CHEM-TEL, INC., INFOTRAC

or 3E COMPANY, does not constitute compliance with regulatory requirements to call the NRC.
6. MILITARY SHIPMENTS
For assistance at incidents involving materials being shipped by, for, or to the Department of Defense
(DOD), call one of the following numbers (24 hours):
703-697-0218 (call collect) (U.S. Army Operations Center) for incidents involving explosives and
ammunition.
1-800-851-8061 (toll-free in the U.S.) (Defense Logistics Agency) for incidents involving dangerous
goods other than explosives and ammunition.
7. NATIONWIDE POISON CONTROL CENTER (United States Only)
Emergency and information calls are answered by the nearest Poison Center (24 hours):
1-800-222-1222 (toll-free in the U.S.).
The above numbers are for emergencies only.
Page 12
MEXICO
1. SETIQ (Emergency Transportation System for the Chemical Industry), a service of the National
Association of Chemical Industries (ANIQ), can be reached as follows:
CALL SETIQ (24 hours)
01-800-00-214-00 in the Mexican Republic
For calls originating in Mexico City and the Metropolitan Area
5559-1588
For calls originating elsewhere, call
011-52-555-559-1588
2. CENACOM, the National Center for Communications of the Civil Protection Agency, can be reached
as follows:
CALL CENACOM (24 hours)
5550-1496, 5550-1552, 5550-1485, or 5550-4885
011-52-555-550-1496, or 011-52-555-550-1552
011-52-555-550-1485, or 011-52-555-550-4885
ARGENTINA
1. CIQUIME (Information Center for Chemical Emergencies) a 24-hour emergency response information
service, can be reached as follows:
CALL CIQUIME (24 hours)
0-800-222-2933 in the Republic of Argentina
+54-11-4613-1100
BRAZIL
1. PR-QUMICA a 24-hour emergency response information service, can be reached as follows:
CALL PRO-QUMICA (24 hours)
0-800-118270 in the Federal Republic of Brazil
+55-11-232-1144
Page 13
COLOMBIA
1. CISPROQUIM a 24-hour emergency response information service, can be reached as follows:
CALL CISPROQUIM (24 hours)
01-800-091-6012 in Colombia
For calls originating in Bogot, Colombia call
288-6012
011-57-1-288-6012
Page 14
HAZARD CLASSIFICATION SYSTEM
The hazard class of dangerous goods is indicated either by its class (or division) number or name. For a
placard corresponding to the primary hazard class of a material, the hazard class or division number must
be displayed in the lower corner of the placard. However, no hazard class or division number may be
displayed on a placard representing the subsidiary hazard of a material. For other than Class 7 or the
OXYGEN placard, text indicating a hazard (for example, CORROSIVE) is not required. Text is shown
only in the U.S. The hazard class or division number must appear on the shipping document after each
shipping name.
Class 1 - Explosives
Division 1.1 Explosives with a mass explosion hazard
Division 1.2 Explosives with a projection hazard
Division 1.3 Explosives with predominantly a fire hazard
Division 1.4 Explosives with no significant blast hazard
Division 1.5 Very insensitive explosives with a mass explosion hazard
Division 1.6 Extremely insensitive articles
Class 2 - Gases
Division 2.1 Flammable gases
Division 2.2 Non-flammable, non-toxic* gases
Division 2.3 Toxic* gases
Class 3 - Flammable liquids (and Combustible liquids [U.S.])
Class 4 - Flammable solids; Spontaneously combustible materials; and Dangerous when wet
materials/Water-reactive substances
Division 4.1 Flammable solids
Division 4.2 Spontaneously combustible materials
Division 4.3 Water-reactive substances/Dangerous when wet materials
Class 5 - Oxidizing substances and Organic peroxides
Division 5.1 Oxidizing substances
Division 5.2 Organic peroxides
Class 6 - Toxic* substances and Infectious substances
Division 6.1 Toxic*substances
Division 6.2 Infectious substances
Class 7 - Radioactive materials
Class 8 - Corrosive substances
Class 9 - Miscellaneous hazardous materials/Products, Substances or Organisms
* The words poison or poisonous are synonymous with the word toxic.
Page 15
INTRODUCTION TO THE TABLE OF PLACARDS
USE THIS TABLE ONLY IF YOU HAVE NOT BEEN ABLE TO IDENTIFY
THE MATERIAL(S) IN TRANSPORT BY ID NUMBER OR NAME
The next two pages display the placards used on transport vehicles carrying
dangerous goods. As you approach a reported or suspected dangerous goods
incident involving a placarded vehicle:
1. Approach the incident cautiously from upwind to a point from which you
can safely identify and/or read the placard or orange panel information. If
wind direction allows, consider approaching the incident from uphill. Use
binoculars, if available.
2. Match the vehicle placard(s) with one of the placards displayed on the
following pages.
3. Consult the numbered guide associated with the sample placard. Use
that information for now. For example, a FLAMMABLE (Class 3) placard
leads to GUIDE 127. A CORROSIVE (Class 8) placard leads to GUIDE 153. If
multiple placards point to more than one guide, initially use the most
conservative guide (i.e., the guide requiring the greatest degree of protective
actions).
4. Remember that the guides associated with the placards provide the most
significant risk and/or hazard information.
5. When specific information, such as ID number or shipping name, becomes
available, the more specific guide recommended for that material must
be consulted.
6. If GUIDE 111 is being used because only the DANGER/DANGEROUS
placard is displayed or the nature of the spilled, leaking, or burning material
is not known, as soon as possible, get more specific information
concerning the material(s) involved.
7. Asterisks (*) on orange placards represent explosives Compatibility
Group letters; refer to the Glossary (page 359).
8. Double asterisks (**) on orange placards represent the division of the
explosive.
Page 16
TABLE OF PLACARDS AND INITIAL
USE THIS TABLE ONLY IF MATERIALS CANNOT BE SPECIFICALLY IDENTIFIED BY
Page 17
RESPONSE GUIDE TO USE ON-SCENE
USING THE SHIPPING DOCUMENT, NUMBERED PLACARD, OR ORANGE PANEL NUMBER
Page 18
CAUTION: Emergency response personnel must be aware that rail tank cars vary widely in
construction, fittings and purpose. Tank cars could transport products that may be solids, liquids
or gases. The products may be under pressure. It is essential that products be identified by
consulting shipping documents or train consist or contacting dispatch centers before emergency
response is initiated.
The information stenciled on the sides or ends of tank cars, as illustrated above, may be used to
identify the product utilizing:
a. the commodity name shown; or
b. the other information shown, especially reporting marks and car number which,
when supplied to a dispatch center, will facilitate the identification of the product.
* The recommended guides should be considered as last resort if product
cannot be identified by any other means.
RAIL CAR IDENTIFICATION CHART*
Page 19
CAUTION: This chart depicts only the most general shapes of road trailers. Emergency
response personnel must be aware that there are many variations of road trailers, not illustrated
above, that are used for shipping chemical products. The suggested guides are for the most
hazardous products that may be transported in these trailer types.
* The recommended guides should be considered as last resort if product
cannot be identified by any other means.
ROAD TRAILER IDENTIFICATION CHART*
Page 20
HAZARD IDENTIFICATION CODES
DISPLAYED ON SOME INTERMODAL CONTAINERS
Hazard identification codes, referred to as hazard identification numbers under European and some
South American regulations, may be found in the top half of an orange panel on some intermodal bulk
containers. The 4-digit identification number is in the bottom half of the orange panel.
The hazard identification code in the top half of the orange panel consists of two or three digits.
In general, the digits indicate the following hazards:
2 - EMISSION OF GAS DUE TO PRESSURE OR CHEMICAL REACTION
3 - FLAMMABILITY OF LIQUIDS (VAPORS) AND GASES OR SELF-HEATING LIQUID
4 - FLAMMABILITY OF SOLIDS OR SELF-HEATING SOLID
5 - OXIDIZING (FIRE-INTENSIFYING) EFFECT
6 - TOXICITY OR RISK OF INFECTION
7 - RADIOACTIVITY
8 - CORROSIVITY
9 - MISCELLANEOUS DANGEROUS SUBSTANCE
Doubling of a digit indicates an intensification of that particular hazard (i.e. 33, 66, 88).
Where the hazard associated with a material can be adequately indicated by a single
digit, the digit is followed by a zero (i.e. 30, 40, 50).
A hazard identification code prefixed by the letter X indicates that the material will
react dangerously with water (i.e. X88).
When 9 appears as a 2
nd
or 3
rd
digit, this may present a risk of spontaneous violent
reaction.
33
1203
Page 21
The hazard identification codes listed below have the following meanings:
20 Inert gas
22 Refrigerated gas
223 Refrigerated gas, flammable
225 Refrigerated gas, oxidizing (fire-intensifying)
23 Flammable gas
236 Flammable gas, toxic
239 Flammable gas which can spontaneously lead to violent reaction
25 Oxidizing (fire-intensifying) gas
26 Toxic gas
263 Toxic gas, flammable
265 Toxic gas, oxidizing (fire-intensifying)
266 Highly toxic gas
268 Toxic gas, corrosive
30 Flammable liquid
323 Flammable liquid which reacts with water, emitting flammable gas
X323 Flammable liquid which reacts dangerously with water, emitting flammable gas
33 Highly flammable liquid
333 Pyrophoric liquid
X333 Pyrophoric liquid which reacts dangerously with water
336 Highly flammable liquid, toxic
338 Highly flammable liquid, corrosive
X338 Highly flammable liquid, corrosive, which reacts dangerously with water
339 Highly flammable liquid which can spontaneously lead to violent reaction
36 Flammable liquid, toxic, or self-heating liquid, toxic
362 Flammable liquid, toxic, which reacts with water, emitting flammable gas
X362 Flammable liquid, toxic, which reacts dangerously with water, emitting flammable gas
368 Flammable liquid, toxic, corrosive
38 Flammable liquid, corrosive
382 Flammable liquid, corrosive, which reacts with water, emitting flammable gas
X382 Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gas
39 Flammable liquid which can spontaneously lead to violent reaction
40 Flammable solid, or self-reactive material, or self-heating material
423 Solid which reacts with water, emitting flammable gas
Page 22
X423 Flammable solid which reacts dangerously with water, emitting flammable gas
43 Spontaneously flammable (pyrophoric) solid
44 Flammable solid, in the molten state at an elevated temperature
446 Flammable solid, toxic, in the molten state at an elevated temperature
46 Flammable solid, toxic, or self-heating solid, toxic
462 Toxic solid which reacts with water, emitting flammable gas
X462 Solid which reacts dangerously with water, emitting toxic gas
48 Flammable or self-heating solid, corrosive
482 Corrosive solid which reacts with water, emitting flammable gas
X482 Solid which reacts dangerously with water, emitting corrosive gas
50 Oxidizing (fire-intensifying) substance
539 Flammable organic peroxide
55 Strongly oxidizing (fire-intensifying) substance
556 Strongly oxidizing (fire-intensifying) substance, toxic
558 Strongly oxidizing (fire-intensifying) substance, corrosive
559 Strongly oxidizing (fire-intensifying) substance which can spontaneously lead to
violent reaction
56 Oxidizing (fire-intensifying) substance, toxic
568 Oxidizing (fire-intensifying) substance, toxic, corrosive
58 Oxidizing (fire-intensifying) substance, corrosive
59 Oxidizing (fire intensifying) substance which can spontaneously lead to violent reaction
60 Toxic material
606 Infectious substance
623 Toxic liquid which reacts with water, emitting flammable gas
63 Toxic liquid, flammable
638 Toxic liquid, flammable, corrosive
639 Toxic liquid, flammable, which can spontaneously lead to violent reaction
64 Toxic solid, flammable or self-heating
642 Toxic solid which reacts with water, emitting flammable gas
65 Toxic material, oxidizing (fire-intensifying)
66 Highly toxic material
663 Highly toxic liquid, flammable
664 Highly toxic solid, flammable or self-heating
665 Highly toxic material, oxidizing (fire-intensifying)
668 Highly toxic material, corrosive
Page 23
669 Highly toxic material which can spontaneously lead to violent reaction
68 Toxic material, corrosive
69 Toxic material which can spontaneously lead to violent reaction
70 Radioactive material
72 Radioactive gas
723 Radioactive gas, flammable
73 Radioactive liquid, flammable
74 Radioactive solid, flammable
75 Radioactive material, oxidizing (fire-intensifying)
76 Radioactive material, toxic
78 Radioactive material, corrosive
80 Corrosive material
X80 Corrosive material which reacts dangerously with water
823 Corrosive liquid which reacts with water, emitting flammable gas
83 Corrosive liquid, flammable
X83 Corrosive liquid, flammable, which reacts dangerously with water
839 Corrosive liquid, flammable, which can spontaneously lead to violent reaction
X839 Corrosive liquid, flammable, which can spontaneously lead to violent reaction
and which reacts dangerously with water
84 Corrosive solid, flammable or self-heating
842 Corrosive solid which reacts with water, emitting flammable gas
85 Corrosive material, oxidizing (fire-intensifying)
856 Corrosive material, oxidizing and toxic
86 Corrosive material, toxic
88 Highly corrosive material
X88 Highly corrosive material which reacts dangerously with water
883 Highly corrosive liquid, flammable
884 Highly corrosive solid, flammable or self-heating
885 Highly corrosive material, oxidizing (fire-intensifying)
886 Highly corrosive material, toxic
X886 Highly corrosive material, toxic, which reacts dangerously with water
89 Corrosive material which can spontaneously lead to violent reaction
90 Miscellaneous dangerous substance; environmentally hazardous substance
99 Miscellaneous dangerous substance transported at elevated temperature
Page 24
Note: If an entry is highlighted in either the yellow-bordered or blue-bordered pages AND
THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective
Action Distances (green-bordered pages) and look up the ID number and name of
material to obtain initial isolation and protective action distances. IF THERE IS A
FIRE, or IF A FIRE IS INVOLVED, go directly to the appropriate guide (orange-
bordered pages) and use the evacuation information shown under PUBLIC SAFETY.
ID Guide Name of Material
No. No.
No. No.
Page 25
112 Ammoni um ni t rat e-f uel oi l
mi xt ures
158 Biological agents
112 Bl asti ng agent, n.o.s.
112 Expl osi ve A
112 Expl osi ve B
114 Expl osi ve C
112 Expl osi ves, di vi si on 1. 1, 1. 2,
1. 3, 1. 5 or 1. 6
114 Expl osi ves, di vi si on 1. 4
153 Toxi ns
1001 116 Acet yl ene
1001 116 Acet yl ene, di ssol ved
1002 122 Ai r, compressed
1003 122 Ai r, ref ri gerat ed l i qui d
(cryogeni c l i qui d)
1003 122 Ai r, ref ri gerat ed l i qui d
(cryogeni c l i qui d), non-
pressuri zed
1005 125 Ammoni a, anhydrous
1005 125 Ammoni a, anhydrous, l i quef i ed
1005 125 Ammoni a sol ut i on, wi t h more
t han 50% Ammoni a
1005 125 Anhydrous ammoni a
1005 125 Anhydrous ammoni a, l i quef i ed
1006 121 Argon
1006 121 Argon, compressed
1008 125 Boron t ri f l uori de
1008 125 Boron t ri f l uori de, compressed
1009 126 Bromot ri f l uoromet hane
1009 126 Ref ri gerant gas R-13B1
1010 116P But adi enes, i nhi bi t ed
1010 116P But adi enes, st abi l i zed
1010 116P But adi enes and hydrocarbon
mi xt ure, st abi l i zed
1011 115 Butane
1011 115 Butane mi xture
1012 115 Butyl ene
1013 120 Carbon di oxi de
1013 120 Carbon di oxi de, compressed
1014 122 Carbon dioxide and Oxygen mixture
1014 122 Carbon di oxi de and Oxygen
mi xt ure, compressed
1014 122 Oxygen and Carbon di oxi de
mi xt ure
1014 122 Oxygen and Carbon di oxi de
1015 126 Carbon di oxi de and Ni t rous
oxi de mi xt ure
1015 126 Ni t rous oxi de and Carbon
di oxi de mi xt ure
1016 119 Carbon monoxi de
1016 119 Carbon monoxi de, compressed
1017 124 Chl ori ne
1018 126 Chl orodi f l uoromet hane
1018 126 Ref ri gerant gas R-22
1020 126 Chl oropent af l uoroet hane
1021 126 1-Chl oro-1, 2, 2, 2-
t et raf l uoroet hane
1021 126 Chl orot et raf l uoroet hane
1022 126 Chl orot ri f l uoromet hane
1023 119 Coal gas
1023 119 Coal gas, compressed
1026 119 Cyanogen
1026 119 Cyanogen, l i quef i ed
1026 119 Cyanogen gas
No. No.
No. No.
Page 26
1043 125 Fertilizer, ammoniating solution,
wi th free Ammoni a
1044 126 Fi re exti ngui shers wi th
compressed gas
1044 126 Fi re ext i ngui shers wi t h
l i quef i ed gas
1045 124 Fl uori ne
1045 124 Fl uori ne, compressed
1046 121 Hel i um
1046 121 Hel i um, compressed
1048 125 Hydrogen bromi de, anhydrous
1049 115 Hydrogen
1049 115 Hydrogen, compressed
1050 125 Hydrogen chl ori de, anhydrous
1051 117 AC
1051 117 Hydrocyani c aci d, aqueous
sol ut i ons, wi t h more t han
20% Hydrogen cyani de
1051 117 Hydrocyani c aci d, l i quef i ed
1051 117 Hydrogen cyani de, anhydrous,
st abi l i zed
1051 117 Hydrogen cyani de, st abi l i zed
1052 125 Hydrogen f l uori de, anhydrous
1053 117 Hydrogen sul f i de
1053 117 Hydrogen sul f i de, l i quef i ed
1053 117 Hydrogen sul phi de
1053 117 Hydrogen sul phi de, l i quef i ed
1055 115 I sobut yl ene
1056 121 Krypt on
1056 121 Krypt on, compressed
1057 115 Li ght er ref i l l s (ci garet t es)
(f l ammabl e gas)
1057 115 Li ght ers (ci garet t es)
(f l ammabl e gas)
1058 120 Liquefied gas (nonflammable)
1027 115 Cycl opropane
1027 115 Cycl opropane, l i quefi ed
1028 126 Dichlorodifluoromethane
1028 126 Refrigerant gas R-12
1029 126 Dichlorofluoromethane
1030 115 1,1-Difluoroethane
1030 115 Difluoroethane
1030 115 Refrigerant gas R-152a
1032 118 Di methyl ami ne, anhydrous
1033 115 Di methyl ether
1035 115 Ethane
1035 115 Ethane, compressed
1036 118 Ethyl ami ne
1037 115 Ethyl chl ori de
1038 115 Ethylene, refrigerated liquid
1039 115 Ethyl methyl ether
1039 115 Met hyl et hyl et her
1040 119P Et hyl ene oxi de
1040 119P Et hyl ene oxi de wi t h Ni t rogen
1041 115 Carbon di oxi de and Et hyl ene
oxi de mi xt ure, wi t h more t han
9% but not mor e t han 87%
Et hyl ene oxi de
oxi de mi xt ures, wi t h more
t han 6% Et hyl ene oxi de
1041 115 Et hyl ene oxi de and Carbon
di oxi de mi xt ure, wi t h more
t han 9% but not more t han
87% Et hyl ene oxi de
1041 115 Et hyl ene oxi de and Carbon
di oxi de mi xt ures, wi t h more
t han 6 % Et hyl ene oxi de
No. No.
No. No.
Page 27
1058 120 Liquefied gases, non-flammable,
charged wi th Ni trogen, Carbon
di oxi de or Ai r
1060 116P Methyl acetyl ene and Propadi ene
mi xture, stabi l i zed
1060 116P Propadi ene and Methyl acetyl ene
1061 118 Methyl ami ne, anhydrous
1062 123 Methyl bromi de
1063 115 Methyl chl ori de
1064 117 Methyl mercaptan
1065 121 Neon
1065 121 Neon, compressed
1066 121 Nitrogen
1066 121 Ni trogen, compressed
1067 124 Dinitrogen tetroxide
1067 124 Dinitrogen tetroxide, liquefied
1067 124 Ni trogen di oxi de
1067 124 Ni trogen di oxi de, l i quefi ed
1069 125 Ni trosyl chl ori de
1070 122 Ni trous oxi de
1070 122 Ni trous oxi de, compressed
1071 119 Oi l gas
1071 119 Oi l gas, compressed
1072 122 Oxygen
1072 122 Oxygen, compressed
1073 122 Oxygen, refri gerated l i qui d
1075 115 But ane
1075 115 But ane mi xt ure
1075 115 But yl ene
1075 115 I sobut ane
1075 115 I sobut ane mi xt ure
1075 115 I sobut yl ene
1075 115 Li quef i ed pet rol eum gas
1075 115 LPG
1075 115 Pet rol eum gases, l i quef i ed
1075 115 Propane
1075 115 Propane mi xt ure
1075 115 Propyl ene
1076 125 CG
1076 125 Di phosgene
1076 125 DP
1076 125 Phosgene
1077 115 Propyl ene
1078 126 Di spersant gas, n.o.s.
1078 126 Ref ri gerant gas, n. o. s.
1079 125 Sul f ur di oxi de
1079 125 Sul f ur di oxi de, l i quef i ed
1079 125 Sul phur di oxi de
1079 125 Sul phur di oxi de, l i quef i ed
1080 126 Sul f ur hexaf l uori de
1080 126 Sul phur hexaf l uori de
1081 116P Tet raf l uoroet hyl ene, i nhi bi t ed
1081 116P Tet raf l uoroet hyl ene, st abi l i zed
1082 119P Tri f l uorochl oroet hyl ene
1082 119P Tri f l uorochl oroet hyl ene,
i nhi bi t ed
1082 119P Tri f l uorochl oroet hyl ene,
st abi l i zed
1083 118 Tri met hyl ami ne, anhydrous
1085 116P Vi nyl bromi de, i nhi bi t ed
1085 116P Vi nyl bromi de, st abi l i zed
1086 116P Vi nyl chl ori de, i nhi bi t ed
1086 116P Vi nyl chl ori de, stabi l i zed
1087 116P Vi nyl methyl ether
No. No.
No. No.
Page 28
1087 116P Vi nyl methyl ether, i nhi bi ted
1087 116P Vi nyl methyl ether, stabi l i zed
1088 127 Acetal
1089 129 Acetal dehyde
1090 127 Acetone
1091 127 Acetone oi l s
1092 131P Acrolein, inhibited
1092 131P Acrol ei n, stabi l i zed
1093 131P Acryl oni tri l e, i nhi bi ted
1093 131P Acryl oni tri l e, stabi l i zed
1098 131 Al l yl al cohol
1099 131 Al l yl bromi de
1100 131 Al l yl chl ori de
1104 129 Amyl acetates
1105 129 Amyl al cohol s
1105 129 Pentanols
1106 132 Amyl ami nes
1107 129 Amyl chl ori de
1108 128 n-Amyl ene
1108 128 1-Pentene
1109 129 Amyl formates
1110 127 n-Amyl methyl ketone
1110 127 Amyl methyl ketone
1110 127 Methyl amyl ketone
1111 130 Amyl mercaptan
1112 140 Amyl ni trate
1113 129 Amyl ni tri te
1114 130 Benzene
1120 129 Butanols
1123 129 Butyl acetates
1125 132 n-Butyl ami ne
1126 130 1-Bromobutane
1126 130 n-Butyl bromi de
1127 130 Butyl chl ori de
1127 130 Chlorobutanes
1128 129 n-Butyl formate
1129 129 Butyral dehyde
1130 128 Camphor oi l
1131 131 Carbon bisulfide
1131 131 Carbon bisulphide
1131 131 Carbon disulfide
1131 131 Carbon disulphide
1133 128 Adhesi ves (fl ammabl e)
1134 130 Chlorobenzene
1135 131 Ethyl ene chl orohydri n
1136 128 Coal tar di sti l l ates, fl ammabl e
1139 127 Coating solution
1143 131P Crotonaldehyde, inhibited
1143 131P Crotonal dehyde, stabi l i zed
1144 128 Crotonyl ene
1145 128 Cycl ohexane
1146 128 Cycl opentane
1147 130 Decahydronaphthalene
1148 129 Diacetone alcohol
1149 128 Butyl ethers
1149 128 Di butyl ethers
1150 130P 1,2-Dichloroethylene
1150 130P Dichloroethylene
1152 130 Dichloropentanes
1153 127 Ethyl ene gl ycol di ethyl ether
1154 132 Diethylamine
1155 127 Di ethyl ether
1155 127 Ethyl ether
1156 127 Di ethyl ketone
1157 128 Diisobutyl ketone
1158 132 Diisopropylamine
No. No.
No. No.
Page 29
1159 127 Di i sopropyl ether
1160 132 Di methyl ami ne, aqueous sol uti on
1160 132 Di methyl ami ne, sol uti on
1161 129 Dimethyl carbonate
1162 155 Dimethyldichlorosilane
1163 131 1,1-Di methyl hydrazi ne
1163 131 Di methyl hydrazi ne,
unsymmetri cal
1164 130 Dimethyl sulfide
1164 130 Di methyl sul phi de
1165 127 Dioxane
1166 127 Dioxolane
1167 128P Di vi nyl ether, i nhi bi ted
1167 128P Di vi nyl ether, stabi l i zed
1169 127 Extracts, aromati c, l i qui d
1170 127 Ethanol
1170 127 Ethanol, solution
1170 127 Ethyl al cohol
1170 127 Ethyl al cohol , sol uti on
1171 127 Ethyl ene gl ycol monoethyl ether
1172 129 Ethyl ene gl ycol monoethyl ether
acetate
1173 129 Ethyl acetate
1175 130 Ethyl benzene
1176 129 Ethyl borate
1177 130 2-Ethyl butyl acetate
1177 130 Ethyl butyl acetate
1178 130 2-Ethyl butyral dehyde
1179 127 Ethyl butyl ether
1180 130 Ethyl butyrate
1181 155 Ethyl chloroacetate
1182 155 Ethyl chloroformate
1183 139 Ethyl di chl orosi l ane
1184 131 Ethyl ene di chl ori de
1185 131P Ethyl enei mi ne, i nhi bi ted
1185 131P Ethyl enei mi ne, stabi l i zed
1188 127 Ethyl ene gl ycol monomethyl
et her
1189 129 Et hyl ene gl ycol monomet hyl
et her acet at e
1190 129 Et hyl f ormat e
1191 129 Et hyl hexal dehydes
1191 129 Oct yl al dehydes
1192 129 Et hyl l act at e
1193 127 Et hyl met hyl ket one
1193 127 Met hyl et hyl ket one
1194 131 Et hyl ni t ri t e, sol ut i on
1195 129 Et hyl propi onat e
1196 155 Et hyl t ri chl orosi l ane
1197 127 Ext ract s, f l avori ng, l i qui d
1197 127 Ext ract s, f l avouri ng, l i qui d
1198 132 Formal dehyde, sol ut i on,
f l ammabl e
1198 132 Formal dehyde, sol ut i ons
(Formal i n)
1199 132P Fural dehydes
1199 132P Furf ural
1199 132P Furf ural dehydes
1201 127 Fusel oi l
1202 128 Di esel f uel
1202 128 Fuel oi l
1202 128 Fuel oi l , no. 1, 2, 4, 5, 6
1202 128 Gas oi l
1202 128 Heat i ng oi l , l i ght
1203 128 Gasohol
1203 128 Gasoline
1203 128 Motor spi ri t
No. No.
No. No.
Page 30
1203 128 Petrol
1204 127 Ni trogl yceri n, sol uti on i n al cohol ,
wi th not more than 1%
Ni trogl yceri n
1206 128 Heptanes
1207 130 Hexal dehyde
1208 128 Hexanes
1208 128 Neohexane
1210 129 Ink, pri nter s, fl ammabl e
1210 129 Pri nti ng i nk, fl ammabl e
1210 129 Printing ink related material
1212 129 Isobutanol
1212 129 Isobutyl al cohol
1213 129 Isobutyl acetate
1214 132 Isobutyl ami ne
1216 128 Isooctenes
1218 130P Isoprene, inhibited
1218 130P Isoprene, stabi l i zed
1219 129 Isopropanol
1219 129 Isopropyl al cohol
1220 129 Isopropyl acetate
1221 132 Isopropyl ami ne
1222 130 Isopropyl nitrate
1223 128 Kerosene
1224 127 Ketones, l i qui d, n.o.s.
1226 128 Lighters for cigars, cigarettes
(f l ammabl e l i qui d)
1228 131 Mercapt an mi xt ure, l i qui d,
f l ammabl e, poi sonous, n. o. s.
f l ammabl e, t oxi c, n. o. s.
1228 131 Mercaptan mi xtures, l i qui d,
n.o.s.
1228 131 Mercaptans, l i qui d, fl ammabl e,
poi sonous, n. o. s.
1228 131 Mercapt ans, l i qui d, f l ammabl e,
t oxi c, n. o. s.
1229 129 Mesi t yl oxi de
1230 131 Met hanol
1230 131 Met hyl al cohol
1231 129 Met hyl acet at e
1233 130 Met hyl amyl acet at e
1234 127 Met hyl al
1235 132 Met hyl ami ne, aqueous sol ut i on
1237 129 Met hyl but yrat e
1238 155 Met hyl chl orof ormat e
1239 131 Met hyl chl oromet hyl et her
1242 139 Met hyl di chl orosi l ane
1243 129 Met hyl f ormat e
1244 131 Met hyl hydrazi ne
1245 127 Met hyl i sobut yl ket one
1246 127P Met hyl i sopropenyl ket one,
i nhi bi t ed
1246 127P Met hyl i sopropenyl ket one,
st abi l i zed
1247 129P Met hyl met hacryl at e monomer,
i nhi bi t ed
1247 129P Met hyl met hacryl at e monomer,
st abi l i zed
1248 129 Met hyl propi onat e
1249 127 Met hyl propyl ket one
1250 155 Met hyl t ri chl orosi l ane
1251 131P Met hyl vi nyl ket one
1251 131P Met hyl vi nyl ket one, st abi l i zed
1259 131 Ni ckel carbonyl
1261 129 Nitromethane
1262 128 Isooctane
1262 128 Octanes
1263 128 Paint (flammable)
No. No.
No. No.
Page 31
1263 128 Paint related material (flammable)
1264 129 Paral dehyde
1265 128 Isopentane
1265 128 n-Pentane
1265 128 Pentanes
1266 127 Perfumery products, wi th
f l ammabl e sol vent s
1267 128 Pet rol eum crude oi l
1268 128 Pet rol eum di st i l l at es, n. o. s.
1268 128 Pet rol eum product s, n. o. s.
1270 128 Oi l , pet rol eum
1270 128 Pet rol eum oi l
1272 129 Pi ne oi l
1274 129 n-Propanol
1274 129 normal Propyl al cohol
1274 129 Propyl al cohol , normal
1275 129 Propi onal dehyde
1276 129 n-Propyl acet at e
1277 132 Monopropyl ami ne
1277 132 Propyl ami ne
1278 129 1-Chl oropropane
1278 129 Propyl chl ori de
1279 130 1, 2-Di chl oropropane
1279 130 Di chl oropropane
1279 130 Propyl ene di chl ori de
1280 127P Propyl ene oxi de
1281 129 Propyl f ormat es
1282 129 Pyri di ne
1286 127 Rosi n oi l
1287 127 Rubber solution
1288 128 Shal e oi l
1289 132 Sodi um methyl ate, sol uti on i n
al cohol
1292 129 Ethyl si l i cate
1292 129 Tetraethyl silicate
1293 127 Tinctures, medicinal
1294 130 Toluene
1295 139 Trichlorosilane
1296 132 Triethylamine
1297 132 Trimethylamine, aqueous solution
1298 155 Trimethylchlorosilane
1299 128 Turpentine
1300 128 Turpentine substitute
1301 129P Vi nyl acetate
1301 129P Vi nyl acetate, i nhi bi ted
1301 129P Vi nyl acetate, stabi l i zed
1302 127P Vi nyl ethyl ether
1302 127P Vi nyl ethyl ether, i nhi bi ted
1302 127P Vi nyl ethyl ether, stabi l i zed
1303 130P Vi nyl i dene chl ori de, i nhi bi ted
1303 130P Vi nyl i dene chl ori de, stabi l i zed
1304 127P Vi nyl i sobutyl ether
1304 127P Vi nyl i sobutyl ether, i nhi bi ted
1304 127P Vi nyl i sobutyl ether, stabi l i zed
1305 155P Vi nyl tri chl orosi l ane
1305 155P Vi nyl tri chl orosi l ane, i nhi bi ted
1305 155P Vi nyl tri chl orosi l ane, stabi l i zed
1306 129 Wood preservati ves, l i qui d
1307 130 Xyl enes
1308 170 Zirconium metal, liquid
suspensi on
1308 170 Zi rconi um suspended i n a
flammable liquid
1308 170 Zi rconi um suspended i n a l i qui d
(f l ammabl e)
1309 170 Al umi num powder, coat ed
No. No.
No. No.
Page 32
1310 113 Ammoni um pi crate, wetted wi th
not l ess than 10% water
1312 133 Borneol
1313 133 Cal ci um resi nate
1314 133 Cal ci um resi nate, fused
1318 133 Cobalt resinate, precipitated
1320 113 Dinitrophenol, wetted with not
l ess t han 15% wat er
1321 113 Di ni t rophenol at es, wet t ed wi t h
not l ess t han 15% wat er
1322 113 Di ni t roresorci nol , wet t ed wi t h
1323 170 Ferroceri um
1324 133 Fi l ms, ni t rocel l ul ose base
1325 133 Fl ammabl e sol i d, n. o. s.
1325 133 Fl ammabl e sol i d, organi c, n.o.s.
1325 133 Fusee (rai l or hi ghway)
1325 133 Medi ci nes, f l ammabl e, sol i d,
n. o. s.
1326 170 Haf ni um powder, wet t ed wi t h
1327 133 Bhusa, wet , damp or
cont ami nat ed wi t h oi l
1327 133 Hay, wet , damp or cont ami nat ed
wi t h oi l
1327 133 St raw, wet , damp or
cont ami nat ed wi t h oi l
1328 133 Hexamet hyl enet et rami ne
1328 133 Hexami ne
1330 133 Manganese resinate
1331 133 Mat ches, st ri ke anywhere
1332 133 Metal dehyde
1333 170 Ceri um, sl abs, i ngots or rods
1334 133 Naphthalene, crude
1334 133 Naphthalene, refined
1336 113 Ni troguani di ne (Pi cri te), wetted
wi t h not l ess t han 20% wat er
1336 113 Ni t roguani di ne, wet t ed wi t h not
1336 113 Pi cri t e, wet t ed
1337 113 Ni t rost arch, wet t ed wi t h not l ess
t han 20% wat er
1337 113 Ni t rost arch, wet t ed wi t h not l ess
t han 30% sol vent
1338 133 Phosphorus, amorphous
1338 133 Phosphorus, amorphous, red
1338 133 Red phosphorus
1338 133 Red phosphorus, amorphous
1339 139 Phosphorus hept asul f i de, f ree
f rom yel l ow and whi t e
Phosphorus
1339 139 Phosphorus hept asul phi de, f ree
Phosphorus
1340 139 Phosphorus pent asul f i de, f ree
Phosphorus
1340 139 Phosphorus pent asul phi de, f ree
Phosphorus
1341 139 Phosphorus sesqui sul f i de, f ree
Phosphorus
1341 139 Phosphorus sesqui sul phi de,
f ree f rom yel l ow and whi t e
Phosphorus
1343 139 Phosphorus trisulfide, free from
yel l ow and whi t e Phosphorus
1343 139 Phosphorus tri sul phi de, free from
yel l ow and whi te Phosphorus
1344 113 Pi cri c aci d, wet , wi t h not l ess
t han 10% wat er
No. No.
No. No.
Page 33
1344 113 Trinitrophenol, wetted with not
l ess than 30% water
1345 133 Rubber scrap, powdered or
granul at ed
1345 133 Rubber shoddy, powdered or
granul at ed
1346 170 Si l i con powder, amorphous
1347 113 Si l ver pi crat e, wet t ed wi t h not
1348 113 Sodi um di ni t ro-o-cresol at e,
wet t ed wi t h not l ess t han 15%
wat er
1348 113 Sodi um di ni t ro-ort ho-cresol at e,
wet t ed
1349 113 Sodi um pi cramat e, wet t ed wi t h
1350 133 Sul f ur
1350 133 Sul phur
1352 170 Ti t ani um powder, wet t ed wi t h
1353 133 Fabri cs i mpregnat ed wi t h
weakl y ni t rat ed
Ni t rocel l ul ose, n. o. s.
1353 133 Fi bers i mpregnat ed wi t h weakl y
ni t rat ed Ni t rocel l ul ose, n. o. s.
1353 133 Fi bres i mpregnat ed wi t h weakl y
ni t rat ed Ni t rocel l ul ose, n. o. s.
1353 133 Toe puffs, ni trocel l ul ose base
1354 113 Tri ni t robenzene, wet t ed wi t h not
1355 113 Tri ni trobenzoi c aci d, wetted wi th
1356 113 TNT, wetted wi th not l ess than
30% wat er
1356 113 Trinitrotoluene, wetted with not
1357 113 Urea ni t rat e, wet t ed wi t h not
1358 170 Zi rconi um metal , powder, wet
1358 170 Zi rconi um powder, wetted wi th
1360 139 Cal ci um phosphi de
1361 133 Carbon, ani mal or veget abl e
ori gi n
1361 133 Charcoal
1362 133 Carbon, act i vat ed
1363 135 Copra
1364 133 Cot t on wast e, oi l y
1365 133 Cot t on
1365 133 Cot t on, wet
1366 135 Di et hyl zi nc
1369 135 p-Ni t rosodi met hyl ani l i ne
1370 135 Di met hyl zi nc
1372 133 Fi ber, ani mal or vegetabl e,
n.o.s., burnt, wet or damp
1372 133 Fi bers, ani mal or vegetabl e,
burnt, wet or damp
1372 133 Fi bres, ani mal or vegetabl e,
burnt, wet or damp
1373 133 Fabri cs, ani mal or vegetabl e or
synt het i c, n. o. s. wi t h oi l
1373 133 Fi bers, ani mal or veget abl e or
1373 133 Fi bres, ani mal or veget abl e or
1374 133 Fi sh meal , unst abi l i zed
1374 133 Fi sh scrap, unstabi l i zed
1376 135 Iron oxi de, spent
1376 135 Iron sponge, spent
1378 170 Metal catal yst, wetted
1379 133 Paper, unsaturated oil treated
1380 135 Pentaborane
No. No.
No. No.
Page 34
1381 136 Phosphorus, whi te, dry or under
water or i n sol uti on
1381 136 Phosphorus, yel l ow, dry or
under wat er or i n sol ut i on
1381 136 Whi t e phosphorus, dry
1381 136 Whi t e phosphorus, i n sol ut i on
1381 136 Whi t e phosphorus, under wat er
1381 136 Yel l ow phosphorus, dry
1381 136 Yel l ow phosphorus, i n sol ut i on
1381 136 Yel l ow phosphorus, under wat er
1382 135 Pot assi um sul f i de, anhydrous
1382 135 Pot assi um sul f i de, wi t h l ess
t han 30% wat er of
cryst al l i zat i on
1382 135 Pot assi um sul f i de, wi t h l ess
t han 30% wat er of hydrat i on
1382 135 Pot assi um sul phi de, anhydrous
1382 135 Pot assi um sul phi de, wi t h l ess
t han 30% wat er of
1382 135 Pot assi um sul phi de, wi t h l ess
t han 30% wat er of hydrat i on
1383 135 Al umi num powder, pyrophori c
1383 135 Pyrophori c al l oy, n. o. s.
1383 135 Pyrophori c met al , n. o. s.
1384 135 Sodi um di t hi oni t e
1384 135 Sodi um hydrosul f i t e
1384 135 Sodi um hydrosul phi t e
1385 135 Sodi um sul f i de, anhydrous
1385 135 Sodi um sul f i de, wi t h l ess t han
30% wat er of cryst al l i zat i on
1385 135 Sodi um sul phi de, anhydrous
1385 135 Sodi um sul phi de, wi t h l ess t han
30% wat er of cryst al l i zat i on
1386 135 Seed cake, wi t h more t han 1. 5%
oi l and not more than 11%
moisture
1387 133 Wool wast e, wet
1389 138 Al kal i metal amal gam
1389 138 Al kal i metal amal gam, l i qui d
1389 138 Al kal i metal amal gam, sol i d
1390 139 Al kal i metal ami des
1391 138 Al kal i metal di spersi on
1391 138 Al kal i ne earth metal di spersi on
1392 138 Alkaline earth metal amalgam
1392 138 Al kal i ne earth metal amal gam,
l i qui d
1393 138 Al kal i ne eart h met al al l oy,
n. o. s.
1394 138 Al umi num carbi de
1395 139 Al umi num f errosi l i con powder
1396 138 Al umi num powder, uncoated
1397 139 Al umi num phosphi de
1398 138 Al umi num si l i con powder,
uncoat ed
1400 138 Bari um
1401 138 Cal ci um
1402 138 Cal ci um carbi de
1403 138 Cal ci um cyanami de, wi t h more
t han 0. 1% Cal ci um carbi de
1404 138 Cal ci um hydri de
1405 138 Cal ci um si l i ci de
1406 138 Cal ci um si l i con
1407 138 Caesi um
1407 138 Cesi um
1408 139 Ferrosilicon
1409 1388 Hydri des, met al , n. o. s.
1409 138 Metal hydri des, water-reacti ve,
n.o.s.
No. No.
No. No.
Page 35
1410 138 Li thi um al umi num hydri de
1411 138 Li thi um al umi num hydri de,
et hereal
1412 139 Li t hi um ami de
1413 138 Li t hi um borohydri de
1414 138 Li t hi um hydri de
1415 138 Li t hi um
1417 138 Li t hi um si l i con
1418 138 Magnesi um al l oys powder
1418 138 Magnesi um powder
1419 139 Magnesium aluminum phosphide
1420 138 Potassi um, metal al l oys
1420 138 Potassi um, metal al l oys, l i qui d
1421 138 Al kal i metal al l oy, l i qui d, n.o.s.
1422 138 Potassi um sodi um al l oys
1422 138 Potassi um sodi um al l oys, l i qui d
1422 138 Sodi um potassi um al l oys
1422 138 Sodi um potassi um al l oys, l i qui d
1423 138 Rubidium
1423 138 Rubidium metal
1426 138 Sodi um borohydri de
1427 138 Sodi um hydri de
1428 138 Sodium
1431 138 Sodium methylate
1431 138 Sodi um methyl ate, dry
1432 139 Sodium phosphide
1433 139 Stannic phosphides
1435 138 Zinc ashes
1435 138 Zinc dross
1435 138 Zinc residue
1435 138 Zi nc ski mmi ngs
1436 138 Zinc dust
1436 138 Zi nc powder
1437 138 Zirconium hydride
1438 140 Aluminum nitrate
1439 141 Ammonium dichromate
1442 143 Ammonium perchlorate
1444 140 Ammonium persulfate
1444 140 Ammonium persulphate
1445 141 Bari um chl orate
1445 141 Bari um chl orate, sol i d
1446 141 Barium nitrate
1447 141 Barium perchlorate
1447 141 Bari um perchl orate, sol i d
1448 141 Barium permanganate
1449 141 Bari um peroxi de
1450 141 Bromates, i norgani c, n.o.s.
1451 140 Caesi um ni trate
1451 140 Cesi um ni trate
1452 140 Cal ci um chl orate
1453 140 Cal ci um chl ori te
1454 140 Cal ci um ni trate
1455 140 Calcium perchlorate
1456 140 Calcium permanganate
1457 140 Cal ci um peroxi de
1458 140 Borate and Chl orate mi xtures
1458 140 Chl orate and Borate mi xtures
1459 140 Chl orate and Magnesi um chl ori de
mixture
mi xture, sol i d
1459 140 Magnesi um chl ori de and Chl orate
mixture
mi xture, sol i d
1461 140 Chl orates, i norgani c, n.o.s.
1462 143 Chl ori tes, i norgani c, n.o.s.
No. No.
No. No.
Page 36
1463 141 Chromi c aci d, sol i d
1463 141 Chromi um tri oxi de, anhydrous
1465 140 Didymium nitrate
1466 140 Ferric nitrate
1467 143 Guanidine nitrate
1469 141 Lead nitrate
1470 141 Lead perchlorate
1470 141 Lead perchlorate, solid
1470 141 Lead perchlorate, solution
1471 140 Li thi um hypochl ori te, dry
1471 140 Li thi um hypochl ori te mi xture
1471 140 Li thi um hypochl ori te mi xtures,
dry
1472 143 Li t hi um peroxi de
1473 140 Magnesi um bromat e
1474 140 Magnesi um ni t rat e
1475 140 Magnesi um perchl orat e
1476 140 Magnesi um peroxi de
1477 140 Ni t rat es, i norgani c, n. o. s.
1479 140 Medi ci nes, oxi di zi ng
subst ances, sol i d, n. o. s.
1479 140 Oxi di zi ng sol i d, n. o. s.
1479 140 Oxi di zi ng subst ances, sol i d,
n. o. s.
1481 140 Perchl orat es, i norgani c, n. o. s.
1482 140 Permanganat es, i norgani c,
n. o. s.
1483 140 Peroxi des, i norgani c, n. o. s.
1484 140 Potassium bromate
1485 140 Potassium chlorate
1486 140 Potassium nitrate
1487 140 Potassi um ni trate and Sodi um
ni t ri t e mi xt ure
1487 140 Sodi um ni tri te and Potassi um
nitrate mixture
1488 140 Potassi um ni tri te
1489 140 Potassium perchlorate
1490 140 Potassium permanganate
1491 144 Potassi um peroxi de
1492 140 Potassium persulfate
1492 140 Potassium persulphate
1493 140 Si l ver ni trate
1494 141 Sodium bromate
1495 140 Sodi um chl orate
1496 143 Sodi um chl ori te
1498 140 Sodium nitrate
1499 140 Potassi um ni trate and Sodi um
ni t rat e mi xt ure
1499 140 Sodi um ni t rat e and Pot assi um
ni t rat e mi xt ure
1500 140 Sodi um ni t ri t e
1502 140 Sodi um perchl orat e
1503 140 Sodi um permanganat e
1504 144 Sodi um peroxi de
1505 140 Sodi um persul f at e
1505 140 Sodi um persul phat e
1506 143 St ront i um chl orat e
1506 143 St ront i um chl orat e, sol i d
1506 143 St ront i um chl orat e, sol ut i on
1507 140 St ront i um ni t rat e
1508 140 St ront i um perchl orat e
1509 143 Strontium peroxide
1510 143 Tetranitromethane
1511 140 Urea hydrogen peroxi de
1512 140 Zinc ammonium nitrite
1513 140 Zinc chlorate
1514 140 Zinc nitrate
1515 140 Zinc permanganate
No. No.
No. No.
Page 37
1516 143 Zi nc peroxi de
1517 113 Zi rconi um pi cramate, wetted wi th
1541 155 Acetone cyanohydri n, stabi l i zed
1544 151 Al kal oi ds, sol i d, n. o. s.
(poi sonous)
1544 151 Al kal oi d sal t s, sol i d, n. o. s.
(poi sonous)
1545 155 Al l yl i sot hi ocyanat e, i nhi bi t ed
1545 155 Al l yl i sot hi ocyanat e, st abi l i zed
1546 151 Ammoni um arsenat e
1547 153 Ani l i ne
1548 153 Ani l i ne hydrochl ori de
1549 157 Ant i mony compound, i norgani c,
n. o. s.
sol i d, n. o. s.
1549 157 Ant i mony t ri bromi de, sol i d
1549 157 Ant i mony t ri bromi de, sol ut i on
1549 157 Ant i mony t ri f l uori de, sol i d
1549 157 Ant i mony t ri f l uori de, sol ut i on
1550 151 Ant i mony l act at e
1551 151 Ant i mony pot assi um t art rat e
1553 154 Arseni c aci d, l i qui d
1554 154 Arseni c aci d, sol i d
1555 151 Arseni c bromi de
1556 152 Arseni c compound, l i qui d, n.o.s.
1556 152 Arseni c compound, l i qui d, n.o.s.,
inorganic
1556 152 MD
1556 152 Methyl di chl oroarsi ne
1556 152 PD
1557 152 Arseni c compound, sol i d, n.o.s.
1557 152 Arseni c compound, sol i d, n.o.s.,
inorganic
1557 152 Arseni c sul fi de
1557 152 Arseni c sul phi de
1557 152 Arsenic trisulfide
1557 152 Arseni c tri sul phi de
1558 152 Arseni c
1559 151 Arseni c pentoxi de
1560 157 Arseni c chl ori de
1560 157 Arseni c tri chl ori de
1561 151 Arseni c tri oxi de
1562 152 Arseni cal dust
1564 154 Bari um compound, n.o.s.
1565 157 Bari um cyani de
1566 154 Beryl l i um compound, n.o.s.
1567 134 Beryl l i um powder
1569 131 Bromoacetone
1570 152 Brucine
1571 113 Bari um azi de, wetted wi th not
1572 151 Cacodyl i c aci d
1573 151 Cal ci um arsenat e
1574 151 Cal ci um arsenat e and Cal ci um
arseni t e mi xt ure, sol i d
1574 151 Cal ci um arseni t e, sol i d
1574 151 Cal ci um arseni te and Cal ci um
arsenat e mi xt ure, sol i d
1575 157 Cal ci um cyani de
1577 153 Chlorodinitrobenzenes
1577 153 Chlorodinitrobenzenes, liquid
1577 153 Chlorodinitrobenzenes, solid
1577 153 Dinitrochlorobenzenes
1578 152 Chloronitrobenzenes
1578 152 Chloronitrobenzenes, liquid
1578 152 Chloronitrobenzenes, solid
No. No.
No. No.
Page 38
1579 153 4-Chloro-o-toluidine
hydrochl ori de
hydrochl ori de, sol i d
1580 154 Chl oropi cri n
1581 123 Chl oropi cri n and Met hyl
bromi de mi xt ure
1581 123 Met hyl bromi de and
Chl oropi cri n mi xt ure
1582 119 Chl oropi cri n and Met hyl
chl ori de mi xt ure
1582 119 Met hyl chl ori de and
Chl oropi cri n mi xt ure
1583 154 Chl oropi cri n mi xt ure, n. o. s.
1585 151 Copper acet oarseni t e
1586 151 Copper arseni t e
1587 151 Copper cyani de
1588 157 Cyani des, i norgani c, n. o. s.
1588 157 Cyani des, i norgani c, sol i d,
n. o. s.
1589 125 CK
1589 125 Cyanogen chl ori de, i nhi bi t ed
1589 125 Cyanogen chl ori de, stabi l i zed
1590 153 Dichloroanilines
1590 153 Di chl oroani l i nes, l i qui d
1590 153 Di chl oroani l i nes, sol i d
1591 152 o-Dichlorobenzene
1593 160 Dichloromethane
1593 160 Methyl ene chl ori de
1594 152 Di ethyl sul fate
1594 152 Diethyl sulphate
1595 156 Dimethyl sulfate
1595 156 Dimethyl sulphate
1596 153 Dinitroanilines
1597 152 Dinitrobenzenes
1597 152 Dinitrobenzenes, liquid
1597 152 Dinitrobenzenes, solid
1598 153 Dinitro-o-cresol
1599 153 Dinitrophenol, solution
1600 152 Dinitrotoluenes, molten
1601 151 Di si nfectant, sol i d, poi sonous,
n. o. s.
1601 151 Di si nf ect ant , sol i d, t oxi c, n. o. s.
1601 151 Di si nf ect ant s, sol i d, n. o. s.
(poi sonous)
1602 151 Dye, l i qui d, poi sonous, n. o. s.
1602 151 Dye, l i qui d, t oxi c, n. o. s.
1602 151 Dye i nt ermedi at e, l i qui d,
1602 151 Dye i nt ermedi at e, l i qui d, t oxi c,
n. o. s.
1603 155 Et hyl bromoacet at e
1604 132 Et hyl enedi ami ne
1605 154 Et hyl ene di bromi de
1606 151 Ferri c arsenat e
1607 151 Ferri c arseni t e
1608 151 Ferrous arsenat e
1610 159 Halogenated irritating liquid, n.o.s.
1611 151 Hexaet hyl t et raphosphat e
1611 151 Hexaet hyl t et raphosphat e,
l i qui d
1611 151 Hexaet hyl t et raphosphat e, sol i d
1612 123 Hexaet hyl t et raphosphat e and
compressed gas mi xture
sol uti on, wi th l ess than 5%
Hydrogen cyani de
sol uti on, wi th not more than
No. No.
No. No.
Page 39
1613 154 Hydrogen cyani de, aqueous
sol ut i on, wi t h not more t han
1614 152 Hydrogen cyani de, anhydrous,
st abi l i zed (absorbed)
1614 152 Hydrogen cyani de, st abi l i zed
(absorbed)
1616 151 Lead acetate
1617 151 Lead arsenates
1618 151 Lead arseni t es
1620 151 Lead cyani de
1621 151 London purpl e
1622 151 Magnesi um arsenat e
1623 151 Mercuri c arsenat e
1624 154 Mercuri c chl ori de
1625 141 Mercuri c ni t rat e
1626 157 Mercuri c pot assi um cyani de
1627 141 Mercurous ni t rat e
1629 151 Mercury acet at e
1630 151 Mercury ammoni um chl ori de
1631 154 Mercury benzoat e
1634 154 Mercuri c bromi de
1634 154 Mercurous bromi de
1634 154 Mercury bromi des
1636 154 Mercuri c cyani de
1636 154 Mercury cyani de
1637 151 Mercury gl uconate
1638 151 Mercury i odi de
1639 151 Mercury nucl eate
1640 151 Mercury ol eate
1641 151 Mercury oxi de
1642 151 Mercuri c oxycyani de
1642 151 Mer cur y oxycyani de,
desensitized
1643 151 Mercury potassi um i odi de
1644 151 Mercury sal i cyl at e
1645 151 Mercuric sulfate
1645 151 Mercuri c sul phate
1645 151 Mercury sul fate
1645 151 Mercury sul phate
1646 151 Mercury thi ocyanate
1647 151 Ethyl ene di bromi de and Methyl
bromi de mi xt ure, l i qui d
1647 151 Met hyl bromi de and Et hyl ene
di bromi de mi xt ure, l i qui d
1648 127 Acet oni t ri l e
1648 127 Met hyl cyani de
1649 131 Mot or f uel ant i -knock mi xt ure
1649 131 Tet raet hyl l ead, l i qui d
1650 153 bet a-Napht hyl ami ne
1650 153 bet a-Napht hyl ami ne, sol i d
1650 153 Napht hyl ami ne (bet a)
1650 153 Napht hyl ami ne (bet a), sol i d
1651 153 Napht hyl t hi ourea
1652 153 Napht hyl urea
1653 151 Ni ckel cyani de
1654 151 Ni cot i ne
1655 151 Ni coti ne compound, sol i d, n.o.s.
1655 151 Nicotine preparation, solid, n.o.s.
1656 151 Ni coti ne hydrochl ori de
1656 151 Ni coti ne hydrochl ori de, l i qui d
1656 151 Ni coti ne hydrochl ori de, sol i d
1656 151 Ni coti ne hydrochl ori de, sol uti on
1657 151 Ni coti ne sal i cyl ate
1658 151 Ni coti ne sul fate, sol i d
1658 151 Nicotine sulfate, solution
1658 151 Ni coti ne sul phate, sol i d
No. No.
No. No.
Page 40
1658 151 Nicotine sulphate, solution
1659 151 Nicotine tartrate
1660 124 Ni t ri c oxi de
1660 124 Ni tri c oxi de, compressed
1661 153 Nitroanilines
1662 152 Nitrobenzene
1663 153 Nitrophenols
1664 152 Nitrotoluenes
1664 152 Nitrotoluenes, liquid
1664 152 Ni trotol uenes, sol i d
1665 152 Ni t roxyl enes
1665 152 Ni troxyl enes, l i qui d
1665 152 Ni t roxyl enes, sol i d
1669 151 Pentachloroethane
1670 157 Perchloromethyl mercaptan
1671 153 Phenol , sol i d
1672 151 Phenyl carbyl ami ne chl ori de
1673 153 Phenylenediamines
1674 151 Phenyl mercuri c acetate
1677 151 Potassium arsenate
1678 154 Potassium arsenite
1679 157 Potassi um cuprocyani de
1680 157 Potassi um cyani de
1680 157 Potassi um cyani de, sol i d
1683 151 Si l ver arseni te
1684 151 Si l ver cyani de
1685 151 Sodium arsenate
1686 154 Sodi um arseni te, aqueous
sol ut i on
1687 153 Sodi um azi de
1688 152 Sodi um cacodyl at e
1689 157 Sodi um cyani de
1689 157 Sodi um cyani de, sol i d
1690 154 Sodi um f l uori de
1690 154 Sodi um f l uori de, sol i d
1691 151 St ront i um arseni t e
1692 151 St rychni ne
1692 151 St rychni ne sal t s
1693 159 Tear gas devi ces
1693 159 Tear gas substance, l i qui d,
n. o. s.
1693 159 Tear gas subst ance, sol i d,
n. o. s.
1694 159 Bromobenzyl cyani des
1694 159 Bromobenzyl cyani des, l i qui d
1694 159 Bromobenzyl cyani des, sol i d
1694 159 CA
1695 131 Chl oroacet one, st abi l i zed
1697 153 Chl oroacet ophenone
1697 153 Chl oroacet ophenone, l i qui d
1697 153 Chl oroacet ophenone, sol i d
1697 153 CN
1698 154 Adamsi t e
1698 154 Di phenyl ami ne chl oroarsi ne
1698 154 DM
1699 151 DA
1699 151 Diphenylchloroarsine
1699 151 Di phenyl chl oroarsi ne, l i qui d
1699 151 Di phenyl chl oroarsi ne, sol i d
1700 159 Tear gas candles
1700 159 Tear gas grenades
1701 152 Xyl yl bromi de
1701 152 Xyl yl bromi de, l i qui d
1702 151 1,1,2,2-Tetrachloroethane
1702 151 Tetrachloroethane
1704 153 Tetraethyl dithiopyrophosphate
No. No.
No. No.
Page 41
1704 153 Tetraethyl dithiopyrophosphate,
mi xt ure, dry or l i qui d
1707 151 Thal l i um compound, n. o. s.
1707 151 Thal l i um sul f at e, sol i d
1707 151 Thal l i um sul phat e, sol i d
1708 153 Tol ui di nes
1708 153 Tol ui di nes, l i qui d
1708 153 Tol ui di nes, sol i d
1709 151 2, 4-Tol uenedi ami ne
1709 151 2, 4-Tol uyl enedi ami ne
1709 151 2, 4-Tol uyl enedi ami ne, sol i d
1710 160 Tri chl oroet hyl ene
1711 153 Xyl i di nes
1711 153 Xyl i di nes, l i qui d
1711 153 Xyl i di nes, sol i d
1712 151 Zi nc arsenat e
1712 151 Zi nc arsenat e and Zi nc arseni t e
mi xt ure
1712 151 Zi nc arseni t e
1712 151 Zi nc arseni t e and Zi nc arsenat e
mi xt ure
1713 151 Zi nc cyani de
1714 139 Zinc phosphide
1715 137 Aceti c anhydri de
1716 156 Acetyl bromi de
1717 155 Acetyl chl ori de
1718 153 Aci d butyl phosphate
1718 153 Butyl aci d phosphate
1719 154 Causti c al kal i l i qui d, n.o.s.
1722 155 Al l yl chl orocarbonate
1722 155 Al l yl chl oroformate
1723 132 Al l yl i odi de
1724 155 Al l yl tri chl orosi l ane, stabi l i zed
1725 137 Al umi num bromi de, anhydrous
1726 137 Al umi num chl ori de, anhydrous
1727 154 Ammoni um bi fl uori de, sol i d
1727 154 Ammonium hydrogendifluoride,
sol i d
1727 154 Ammoni um hydrogen fl uori de,
sol i d
1728 155 Amyl t ri chl orosi l ane
1729 156 Ani soyl chl ori de
1730 157 Ant i mony pent achl ori de, l i qui d
1731 157 Ant i mony pent achl ori de,
sol ut i on
1732 157 Ant i mony pent af l uori de
1733 157 Ant i mony t ri chl ori de
1733 157 Ant i mony t ri chl ori de, l i qui d
1733 157 Ant i mony t ri chl ori de, sol i d
1733 157 Ant i mony t ri chl ori de, sol ut i on
1736 137 Benzoyl chl ori de
1737 156 Benzyl bromi de
1738 156 Benzyl chl ori de
1739 137 Benzyl chl orof ormat e
1740 154 Hydrogendi fl uori des, n.o.s.
1741 125 Boron trichloride
1742 157 Boron trifluoride acetic acid
compl ex
1742 157 Boron t ri f l uori de acet i c aci d
compl ex, l i qui d
1743 157 Boron t ri f l uori de propi oni c aci d
compl ex
compl ex, l i qui d
1744 154 Bromine
1744 154 Bromine, solution
1745 144 Bromine pentafluoride
No. No.
No. No.
Page 42
1746 144 Bromine trifluoride
1747 155 Butyl tri chl orosi l ane
1748 140 Cal ci um hypochl ori te, dry
1748 140 Cal ci um hypochl ori te mi xture,
dry, wi t h more t han 39%
avai l abl e Chl ori ne (8. 8%
avai l abl e Oxygen)
1749 124 Chl ori ne t ri f l uori de
1750 153 Chl oroacet i c aci d, l i qui d
1750 153 Chl oroacet i c aci d, sol ut i on
1751 153 Chl oroacet i c aci d, sol i d
1752 156 Chl oroacet yl chl ori de
1753 156 Chl orophenyl t ri chl orosi l ane
1754 137 Chl orosul f oni c aci d
1754 137 Chl orosul f oni c aci d and Sul f ur
t ri oxi de mi xt ure
1754 137 Chl orosul phoni c aci d
1754 137 Chl orosul phoni c aci d and
Sul phur t ri oxi de mi xt ure
1754 137 Sul f ur t ri oxi de and
Chl orosul f oni c aci d mi xt ure
1754 137 Sul phur t ri oxi de and
Chl orosul phoni c aci d mi xt ure
1755 154 Chromi c aci d, sol ut i on
1756 154 Chromi c f l uori de, sol i d
1757 154 Chromi c f l uori de, sol ut i on
1758 137 Chromi um oxychl ori de
1759 154 Corrosi ve sol i d, n. o. s.
1759 154 Ferrous chl ori de, sol i d
1759 154 Medi ci nes, corrosi ve, sol i d,
n.o.s.
1760 154 Chemi cal ki t
1760 154 Compound, cl eani ng l i qui d
(corrosi ve)
1760 154 Compound, tree or weed ki l l i ng,
l i qui d (corrosi ve)
1760 154 Corrosi ve l i qui d, n. o. s.
1760 154 Ferrous chloride, solution
1760 154 Medicines, corrosive, liquid, n.o.s.
1760 154 Titanium sulfate, solution
1760 154 Titanium sulphate, solution
1761 154 Cupriethylenediamine, solution
1762 156 Cycl ohexenyl tri chl orosi l ane
1763 156 Cycl ohexyl tri chl orosi l ane
1764 153 Dichloroacetic acid
1765 156 Di chl oroacetyl chl ori de
1766 156 Dichlorophenyltrichlorosilane
1767 155 Diethyldichlorosilane
1768 154 Difluorophosphoric acid,
anhydrous
1769 156 Di phenyl di chl orosi l ane
1770 153 Di phenyl met hyl bromi de
1771 156 Dodecyl t ri chl orosi l ane
1773 157 Ferri c chl ori de
1773 157 Ferri c chl ori de, anhydrous
1774 154 Fi re ext i ngui sher charges,
corrosi ve l i qui d
1775 154 Fl uobori c aci d
1775 154 Fluoroboric acid
1776 154 Fl uorophosphori c aci d,
anhydrous
1777 137 Fl uorosul f oni c aci d
1777 137 Fl uorosul phoni c aci d
1778 154 Fl uorosi l i ci c aci d
1778 154 Fl uosi l i ci c aci d
1778 154 Hydrof l uorosi l i ci c aci d
1779 153 Formi c aci d
1780 156 Fumaryl chl ori de
No. No.
No. No.
Page 43
1781 156 Hexadecyl tri chl orosi l ane
1782 154 Hexafl uorophosphori c aci d
1783 153 Hexamethyl enedi ami ne, sol uti on
1784 156 Hexyl tri chl orosi l ane
1786 157 Hydrofl uori c aci d and Sul furi c
aci d mi xt ure
1786 157 Hydrof l uori c aci d and Sul phuri c
aci d mi xt ure
1786 157 Sul f uri c aci d and Hydrof l uori c
aci d mi xture
1786 157 Sul phuri c aci d and Hydrofl uori c
aci d mi xture
1787 154 Hydri odi c aci d
1787 154 Hydri odi c aci d, sol uti on
1788 154 Hydrobromi c aci d
1788 154 Hydrobromi c aci d, sol uti on
1789 157 Hydrochl ori c aci d
1789 157 Hydrochl ori c aci d, sol uti on
1789 157 Muri ati c aci d
1790 157 Hydrofl uori c aci d
1790 157 Hydrofl uori c aci d, sol uti on
1791 154 Hypochl ori te sol uti on
1791 154 Hypochl ori te sol uti on, wi th more
t han 5% avai l abl e Chl ori ne
1792 157 I odi ne monochl ori de
1793 153 I sopropyl aci d phosphat e
1794 154 Lead sul f at e, wi t h more t han 3%
f ree aci d
1794 154 Lead sul phat e, wi t h more t han
3% f r ee aci d
1796 157 Ni t rat i ng aci d mi xt ure
1798 157 Aqua regi a
1798 157 Ni trohydrochl ori c aci d
1799 156 Nonyl tri chl orosi l ane
1800 156 Octadecyl tri chl orosi l ane
1801 156 Octyl tri chl orosi l ane
1802 140 Perchl ori c aci d, wi th not more
t han 50% aci d
1803 153 Phenol sul f oni c aci d, l i qui d
1803 153 Phenol sul phoni c aci d, l i qui d
1804 156 Phenyl t ri chl orosi l ane
1805 154 Phosphori c aci d
1805 154 Phosphori c aci d, l i qui d
1805 154 Phosphori c aci d, sol i d
1805 154 Phosphori c aci d, sol ut i on
1806 137 Phosphorus pent achl ori de
1807 137 Phosphorus pent oxi de
1808 137 Phosphorus t ri bromi de
1809 137 Phosphorus t ri chl ori de
1810 137 Phosphorus oxychl ori de
1811 154 Pot assi um hydrogendi f l uori de
1811 154 Pot assi um hydrogen di f l uori de,
sol i d
1812 154 Pot assi um f l uori de
1812 154 Pot assi um f l uori de, sol i d
1813 154 Caust i c pot ash, dry, sol i d
1813 154 Pot assi um hydroxi de, dry, sol i d
1813 154 Potassi um hydroxi de, fl ake
1813 154 Potassi um hydroxi de, sol i d
1814 154 Causti c potash, l i qui d
1814 154 Causti c potash, sol uti on
1814 154 Potassi um hydroxi de, sol uti on
1815 132 Propi onyl chl ori de
1816 155 Propyl tri chl orosi l ane
1817 137 Pyrosul furyl chl ori de
1817 137 Pyrosul phuryl chl ori de
1818 157 Silicon tetrachloride
1819 154 Sodium aluminate, solution
No. No.
No. No.
Page 44
1823 154 Causti c soda, bead
1823 154 Causti c soda, fl ake
1823 154 Causti c soda, granul ar
1823 154 Causti c soda, sol i d
1823 154 Sodi um hydroxi de, bead
1823 154 Sodi um hydroxi de, dry
1823 154 Sodi um hydroxi de, fl ake
1823 154 Sodi um hydroxi de, granul ar
1823 154 Sodi um hydroxi de, sol i d
1824 154 Causti c soda, sol uti on
1824 154 Sodi um hydroxi de, sol uti on
1825 157 Sodi um monoxi de
1826 157 Ni trati ng aci d mi xture, spent
1827 137 Stanni c chl ori de, anhydrous
1827 137 Tin tetrachloride
1828 137 Sulfur chlorides
1828 137 Sulphur chlorides
1829 137 Sul fur tri oxi de
1829 137 Sul fur tri oxi de, i nhi bi ted
1829 137 Sul fur tri oxi de, stabi l i zed
1829 137 Sulfur trioxide, uninhibited
1829 137 Sul phur tri oxi de
1829 137 Sul phur tri oxi de, i nhi bi ted
1829 137 Sul phur tri oxi de, stabi l i zed
1829 137 Sulphur trioxide, uninhibited
1830 137 Sul furi c aci d
1830 137 Sul furi c aci d, wi th more than
51% aci d
1830 137 Sul phuri c aci d
1830 137 Sul phuri c aci d, wi th more than
51% aci d
1831 137 Sul furi c aci d, fumi ng
1831 137 Sul furi c aci d, fumi ng, wi th l ess
than 30% free Sul fur tri oxi de
1831 137 Sul furi c aci d, fumi ng, wi th not
l ess t han 30% f ree Sul f ur
t ri oxi de
1831 137 Sul phuri c aci d, f umi ng
1831 137 Sul phuri c aci d, f umi ng, wi t h
l ess t han 30% f ree Sul phur
t ri oxi de
1831 137 Sul phuri c aci d, f umi ng, wi t h not
l ess t han 30% f ree Sul phur
t ri oxi de
1832 137 Sul f uri c aci d, spent
1832 137 Sul phuri c aci d, spent
1833 154 Sul f urous aci d
1833 154 Sul phurous aci d
1834 137 Sul f uryl chl ori de
1834 137 Sul phuryl chl ori de
1835 153 Tet ramet hyl ammoni um
hydroxi de
hydroxi de, sol ut i on
1836 137 Thi onyl chl ori de
1837 157 Thi ophosphoryl chl ori de
1838 137 Ti t ani um t et rachl ori de
1839 153 Tri chl oroacet i c aci d
1840 154 Zi nc chl ori de, sol ut i on
1841 171 Acet al dehyde ammoni a
1843 141 Ammoni um di ni t ro-o-cresol at e
1843 141 Ammoni um di ni t ro-o-cresol at e,
sol i d
1845 120 Carbon di oxi de, sol i d
1845 120 Dry i ce
1846 151 Carbon tetrachloride
No. No.
No. No.
Page 45
1847 153 Potassi um sul fi de, hydrated, wi th
not l ess than 30% water of
crystal l i zati on
1847 153 Potassi um sul fi de, hydrated, wi th
not l ess than 30% water of
hydration
1847 153 Potassi um sul phi de, hydrated,
of cryst al l i zat i on
1847 153 Pot assi um sul phi de, hydrat ed,
of hydrati on
1848 132 Propi oni c aci d
1849 153 Sodi um sul f i de, hydrat ed, wi t h
1849 153 Sodi um sul phi de, hydrat ed, wi t h
1851 151 Medi ci ne, l i qui d, poi sonous,
n.o.s.
1851 151 Medi ci ne, l i qui d, t oxi c, n. o. s.
1854 135 Bari um al l oys, pyrophori c
1855 135 Cal ci um, met al and al l oys,
pyrophori c
1855 135 Cal ci um, pyrophori c
1855 135 Cal ci um al l oys, pyrophori c
1856 133 Rags, oi l y
1857 133 Text i l e wast e, wet
1858 126 Hexafl uoropropyl ene
1859 125 Silicon tetrafluoride
1859 125 Silicon tetrafluoride, compressed
1860 116P Vi nyl fl uori de, i nhi bi ted
1860 116P Vi nyl fl uori de, stabi l i zed
1862 130 Ethyl crotonate
1863 128 Fuel , avi ati on, turbi ne engi ne
1865 131 n-Propyl nitrate
1866 127 Resin solution
1868 134 Decaborane
1869 138 Magnesium
1869 138 Magnesi um, i n pel l ets, turni ngs
or ri bbons
1869 138 Magnesi um al l oys, wi t h more
t han 50% Magnesi um, i n
pel l et s, t urni ngs or ri bbons
1870 138 Pot assi um borohydri de
1871 170 Ti t ani um hydri de
1872 141 Lead di oxi de
1873 143 Perchl ori c aci d, wi t h more t han
50% but not more t han 72%
aci d
1884 157 Bari um oxi de
1885 153 Benzi di ne
1886 156 Benzyl i dene chl ori de
1887 160 Bromochl oromet hane
1888 151 Chl orof orm
1889 157 Cyanogen bromi de
1891 131 Et hyl bromi de
1892 151 ED
1892 151 Et hyl di chl oroarsi ne
1894 151 Phenyl mercuri c hydroxi de
1895 151 Phenyl mercuri c ni trate
1897 160 Perchloroethylene
1897 160 Tetrachloroethylene
1898 156 Acetyl i odi de
1902 153 Di i sooctyl aci d phosphate
1903 153 Di si nfectant, l i qui d, corrosi ve,
n. o. s.
1903 153 Di si nf ect ant s, corrosi ve, l i qui d,
n. o. s.
1905 154 Sel eni c aci d
1906 153 Aci d, sl udge
No. No.
No. No.
Page 46
1906 153 Sl udge aci d
1907 154 Soda l i me, wi th more than 4%
Sodi um hydroxi de
1908 154 Chl ori t e sol ut i on
1908 154 Chl ori t e sol ut i on, wi t h more
1908 154 Sodium chlorite, solution, with
more than 5% available
Chlorine
1910 157 Cal ci um oxi de
1911 119 Di borane
1911 119 Di borane, compressed
1911 119 Di borane mi xt ures
1912 115 Met hyl chl ori de and Met hyl ene
1912 115 Met hyl ene chl ori de and Met hyl
1913 120 Neon, ref ri gerat ed l i qui d
1914 130 But yl propi onat es
1915 127 Cycl ohexanone
1916 152 2, 2' -Di chl orodi et hyl et her
1916 152 Di chl oroet hyl et her
1917 129P Et hyl acryl at e, i nhi bi t ed
1917 129P Ethyl acryl ate, stabi l i zed
1918 130 Cumene
1918 130 Isopropylbenzene
1919 129P Methyl acryl ate, i nhi bi ted
1919 129P Methyl acryl ate, stabi l i zed
1920 128 Nonanes
1921 131P Propyleneimine, inhibited
1921 131P Propyl enei mi ne, stabi l i zed
1922 132 Pyrrol i di ne
1923 135 Calcium dithionite
1923 135 Cal ci um hydrosul fi te
1923 135 Cal ci um hydrosul phi te
1928 135 Methyl magnesi um bromi de i n
Et hyl et her
1929 135 Pot assi um di t hi oni t e
1929 135 Pot assi um hydrosul f i t e
1929 135 Pot assi um hydrosul phi t e
1931 171 Zi nc di t hi oni t e
1931 171 Zi nc hydrosul f i t e
1931 171 Zi nc hydrosul phi t e
1932 135 Zi rconi um scrap
1935 157 Cyani de sol ut i on, n. o. s.
1938 156 Bromoacet i c aci d
1938 156 Bromoacet i c aci d, sol ut i on
1939 137 Phosphorus oxybromi de
1939 137 Phosphorus oxybromi de, sol i d
1940 153 Thi ogl ycol i c aci d
1941 171 Di bromodi f l uoromet hane
1942 140 Ammoni um ni t rat e, wi t h not
more t han 0. 2% combust i bl e
subst ances
1944 133 Mat ches, saf et y
1945 133 Mat ches, wax vest a
1950 126 Aerosol di spensers
1950 126 Aerosol s
1951 120 Argon, refrigerated liquid
1952 126 Carbon di oxi de and Ethyl ene
oxi de mi xt ures, wi t h not more
oxi de mi xt ures, wi t h not more
1952 126 Ethyl ene oxi de and Carbon
di oxi de mi xt ures, wi t h not
more than 6% Ethyl ene oxi de
No. No.
No. No.
Page 47
1952 126 Ethyl ene oxi de and Carbon
di oxi de mi xtures, wi th not
1953 119 Compressed gas, fl ammabl e,
poi sonous, n. o. s. (I nhal at i on
Hazard Zone A)
1953 119 Compressed gas, f l ammabl e,
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
t oxi c, n. o. s. (I nhal at i on
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
1953 119 Compressed gas, fl ammabl e,
Hazard Zone D)
1953 119 Compressed gas, poi sonous,
fl ammabl e, n.o.s.
f l ammabl e, n. o. s. (I nhal at i on
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
fl ammabl e, n.o.s. (Inhal ati on
Hazard Zone D)
1953 119 Compressed gas, t oxi c,
f l ammabl e, n. o. s.
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
1953 119 Li quef i ed gas, f l ammabl e,
Hazard Zone A)
Hazard Zone B)
1953 119 Liquefied gas, flammable,
Hazard Zone C)
poi sonous, n.o.s. (Inhal ati on
Hazard Zone D)
1953 119 Li quefi ed gas, fl ammabl e, toxi c,
n. o. s.
1953 119 Li quef i ed gas, f l ammabl e, t oxi c,
n. o. s. (I nhal at i on Hazard
Zone A)
Zone B)
No. No.
No. No.
Page 48
n.o.s. (Inhal ati on Hazard
Zone C)
Zone D)
1954 115 Compressed gas, flammable,
n.o.s.
1954 115 Di spersant gas, n.o.s.
(f l ammabl e)
1954 115 Insecti ci de gas, fl ammabl e,
n.o.s.
1954 115 Li quefi ed gas, fl ammabl e, n.o.s.
1954 115 Ref ri gerant gas, n. o. s.
(f l ammabl e)
1954 115 Ref ri gerat i ng machi nes,
cont ai ni ng f l ammabl e, non-
poi sonous, non-corrosi ve,
l i quef i ed gas
n. o. s.
Zone A)
Zone B)
Zone C)
Zone D)
1955 123 Compressed gas, toxi c, n.o.s.
1955 123 Compressed gas, t oxi c, n. o. s.
(I nhal at i on Hazard Zone A)
(I nhal at i on Hazard Zone B)
1955 123 Compressed gas, t oxi c, n. o. s.
(I nhal at i on Hazard Zone C)
(I nhal at i on Hazard Zone D)
1955 123 Li quef i ed gas, poi sonous, n. o. s.
1955 123 Li quef i ed gas, t oxi c, n. o. s.
1955 123 Organi c phosphat e compound
mi xed wi t h compressed gas
1955 123 Organi c phosphat e mi xed wi t h
compressed gas
1955 123 Organi c phosphorus compound
mi xed wi th compressed gas
1956 126 Accumul ators, pressuri zed,
pneumat i c or hydraul i c
1956 126 Compressed gas, n. o. s.
1956 126 Hexaf l uoropropyl ene oxi de
1956 126 Li quef i ed gas, n. o. s.
1957 115 Deut eri um
1957 115 Deut eri um, compressed
1958 126 1, 2-Di chl oro-1, 1, 2, 2-
t et raf l uoroet hane
No. No.
No. No.
Page 49
1958 126 Di chl orot et raf l uoroet hane
1959 116P 1, 1-Di f l uoroet hyl ene
1959 116P Ref ri gerant gas R-1132a
1960 115 Engi ne st art i ng f l ui d
1961 115 Et hane, ref ri gerat ed l i qui d
1961 115 Et hane-Propane mi xt ure,
ref ri gerat ed l i qui d
1961 115 Propane-Et hane mi xt ure,
1962 116P Et hyl ene
1962 116P Et hyl ene, compressed
1963 120 Hel i um, ref ri gerat ed l i qui d
1964 115 Hydrocarbon gas, compressed,
n. o. s.
1964 115 Hydrocarbon gas mi xt ure,
compressed, n. o. s.
1965 115 Hydrocarbon gas, liquefied, n.o.s.
1965 115 Hydrocarbon gas mi xt ure,
l i quef i ed, n. o. s.
1966 115 Hydrogen, ref ri gerat ed l i qui d
1967 123 I nsect i ci de gas, poi sonous,
n. o. s.
1967 123 I nsect i ci de gas, t oxi c, n. o. s.
1967 123 Parathi on and compressed gas
mi xt ure
1968 126 I nsect i ci de gas, n. o. s.
1969 115 I sobut ane
1969 115 I sobut ane mi xt ure
1970 120 Krypton, refrigerated liquid
1971 115 Met hane
1971 115 Met hane, compressed
1971 115 Natural gas, compressed
1972 115 Li quefi ed natural gas (cryogeni c
l i qui d)
1972 115 LNG (cryogeni c l i qui d)
1972 115 Met hane, ref ri gerat ed l i qui d
1972 115 Nat ural gas, ref ri gerat ed l i qui d
1973 126 Chl orodi f l uoromet hane and
Chl oropent af l uoroet hane
mi xt ure
1973 126 Chl oropent af l uoroet hane and
Chl orodi f l uoromet hane
mi xt ure
1974 126 Bromochl orodi f l uoromet hane
1974 126 Chl orodi f l uorobromomet hane
1974 126 Ref ri gerant gas R-12B1
1975 124 Di ni t rogen t et roxi de and Ni t ri c
oxi de mi xt ure
1975 124 Ni t ri c oxi de and Di ni t rogen
t et roxi de mi xt ure
1975 124 Ni t ri c oxi de and Ni t rogen
di oxi de mi xt ure
1975 124 Ni tri c oxi de and Ni trogen
t et roxi de mi xt ure
1975 124 Ni trogen di oxi de and Ni tri c oxi de
mixture
1975 124 Ni trogen tetroxi de and Ni tri c
oxi de mi xt ure
1976 126 Oct af l uorocycl obut ane
1976 126 Ref ri gerant gas RC-318
1977 120 Nitrogen, refrigerated liquid
1978 115 Propane
1978 115 Propane mi xt ure
No. No.
No. No.
Page 50
1979 121 Rare gases mi xture
1979 121 Rare gases mi xture, compressed
1980 121 Oxygen and Rare gases mi xture
1980 121 Oxygen and Rare gases mi xture,
compressed
1980 121 Rare gases and Oxygen mi xture
1980 121 Rare gases and Oxygen mi xture,
compressed
1981 121 Ni trogen and Rare gases mi xture
1981 121 Ni trogen and Rare gases
1981 121 Rare gases and Ni t rogen
mi xt ure
1981 121 Rare gases and Ni t rogen
1982 126 Ref ri gerant gas R-14,
compressed
1982 126 Tet raf l uoromet hane
1982 126 Tet raf l uoromet hane,
compressed
1983 126 1-Chl oro-2, 2, 2-t ri f l uoroet hane
1983 126 Chlorotrifluoroethane
1984 126 Trifluoromethane
1986 131 Al cohol s, fl ammabl e, poi sonous,
n.o.s.
1986 131 Al cohol s, fl ammabl e, toxi c, n.o.s.
1986 131 Al cohol s, poi sonous, n.o.s.
1986 131 Al cohol s, t oxi c, n. o. s.
1986 131 Denatured alcohol (toxic)
1986 131 Propargyl al cohol
1987 127 Al cohol s, n.o.s.
1987 127 Denatured alcohol
1988 131 Al dehydes, fl ammabl e,
1988 131 Al dehydes, f l ammabl e, t oxi c,
n. o. s.
1988 131 Al dehydes, poi sonous, n. o. s.
1988 131 Al dehydes, t oxi c, n. o. s.
1989 129 Al dehydes, n. o. s.
1990 129 Benzal dehyde
1991 131P Chl oroprene, i nhi bi t ed
1991 131P Chl oroprene, st abi l i zed
1992 131 Fl ammabl e l i qui d, poi sonous,
n. o. s.
1992 131 Fl ammabl e l i qui d, t oxi c, n. o. s.
1993 128 Combust i bl e l i qui d, n. o. s.
1993 128 Compound, cl eani ng l i qui d
(f l ammabl e)
1993 128 Compound, t ree or weed ki l l i ng,
l i qui d (f l ammabl e)
1993 128 Di esel f uel
1993 128 Fl ammabl e l i qui d, n. o. s.
1993 128 Fuel oi l
1993 128 Medi ci nes, f l ammabl e, l i qui d,
n. o. s.
1993 128 Ref ri gerat i ng machi ne
1994 131 I ron pent acarbonyl
1999 130 Asphal t
1999 130 Tars, l i qui d
2000 133 Cel l ul oi d, i n bl ocks, rods, rol l s,
sheet s, t ubes, et c. , except
scrap
2001 133 Cobal t napht henat es, powder
2002 135 Cel l ul oi d, scrap
2003 135 Met al al kyl s, n. o. s.
2003 135 Met al al kyl s, wat er-react i ve,
n. o. s.
No. No.
No. No.
Page 51
2003 135 Met al aryl s, n. o. s
2003 135 Metal aryl s, water-reacti ve,
n. o. s.
2004 135 Magnesi um di ami de
2005 135 Magnesi um di phenyl
2006 135 Pl ast i c, ni t rocel l ul ose-based,
spont aneousl y combust i bl e,
n. o. s.
2006 135 Pl ast i cs, ni t rocel l ul ose-based,
sel f -heat i ng, n. o. s.
2008 135 Zi rconi um powder, dry
2009 135 Zi rconi um, dry, f i ni shed sheet s,
st ri ps or coi l ed wi re
2010 138 Magnesi um hydri de
2011 139 Magnesi um phosphi de
2012 139 Pot assi um phosphi de
2013 139 St ront i um phosphi de
2014 140 Hydrogen peroxi de, aqueous
sol ut i on, wi t h not l ess t han
Hydrogen peroxi de
(st abi l i zed as necessary)
sol ut i on, st abi l i zed, wi t h
more t han 60% Hydrogen
peroxide
2015 143 Hydrogen peroxi de, stabi l i zed
2016 151 Ammuni ti on, poi sonous,
non-expl osi ve
2016 151 Ammuni t i on, t oxi c,
non-expl osi ve
2017 159 Ammuni t i on, t ear-produci ng,
non-expl osi ve
2018 152 Chl oroani l i nes, sol i d
2019 152 Chl oroani l i nes, l i qui d
2020 153 Chl orophenol s, sol i d
2021 153 Chl orophenol s, l i qui d
2022 153 Cresyl i c aci d
2023 131P 1-Chl oro-2, 3-epoxypropane
2023 131P Epi chl orohydri n
2024 151 Mercury compound, l i qui d,
n. o. s.
2025 151 Mercury compound, sol i d, n. o. s.
2026 151 Phenyl mercuri c compound,
n. o. s.
2027 151 Sodi um arseni t e, sol i d
2028 153 Bombs, smoke, non-expl osi ve,
wi t h corrosi ve l i qui d, wi t hout
i ni t i at i ng devi ce
2029 132 Hydrazi ne, anhydrous
2029 132 Hydrazi ne, aqueous sol ut i ons,
wi t h more t han 64%
Hydrazi ne
2030 153 Hydrazi ne, aqueous sol ut i on,
wi t h more t han 37%
Hydrazi ne
2030 153 Hydrazi ne, aqueous sol ut i on,
wi t h not l ess t han 37% but not
more t han 64% Hydrazi ne
2030 153 Hydrazi ne hydrat e
2031 157 Ni t ri c aci d, ot her t han red
fuming
2032 157 Ni tri c aci d, fumi ng
2032 157 Ni tri c aci d, red fumi ng
2033 154 Potassi um monoxi de
2034 115 Hydrogen and Methane mi xture,
compressed
2034 115 Met hane and Hydrogen mi xt ure,
compressed
2035 115 1,1,1-Trifluoroethane
2035 115 Trifluoroethane, compressed
2036 121 Xenon
No. No.
No. No.
Page 52
2036 121 Xenon, compressed
2037 115 Gas cartri dges
2037 115 Receptacl es, smal l , contai ni ng
gas
2038 152 Di ni t rot ol uenes
2038 152 Di ni t rot ol uenes, l i qui d
2038 152 Di ni t rot ol uenes, sol i d
2044 115 2, 2-Di met hyl propane
2045 130 Isobutyl al dehyde
2045 130 Isobutyral dehyde
2046 130 Cymenes
2047 129 Dichloropropenes
2048 130 Dicyclopentadiene
2049 130 Diethylbenzene
2050 128 Di i sobutyl ene, i someri c
compounds
2051 132 2-Di met hyl ami noet hanol
2051 132 Di met hyl et hanol ami ne
2052 128 Di pent ene
2053 129 Met hyl amyl al cohol
2053 129 Met hyl i sobut yl carbi nol
2053 129 M. I . B. C.
2054 132 Morpholine
2055 128P Styrene monomer, inhibited
2055 128P Styrene monomer, stabi l i zed
2056 127 Tetrahydrofuran
2057 128 Tripropylene
2058 129 Val eral dehyde
2059 127 Ni trocel l ul ose, sol uti on,
f l ammabl e
2059 127 Ni t rocel l ul ose, sol ut i on, i n a
f l ammabl e l i qui d
2067 140 Ammoni um ni t rat e f ert i l i zers
2068 140 Ammoni um ni trate ferti l i zers, wi th
Calcium carbonate
Ammonium sulfate
Ammonium sulphate
2069 140 Ammoni um ni trate mi xed
f ert i l i zers
2070 143 Ammoni um ni t rat e f ert i l i zers,
wi t h Phosphat e or Pot ash
2071 140 Ammoni um ni t rat e f ert i l i zer,
wi t h not more t han 0. 4%
combustible material
2071 140 Ammonium nitrate fertilizers
2072 140 Ammonium nitrate fertilizer, n.o.s.
2072 140 Ammonium nitrate fertilizers
2073 125 Ammoni a, sol uti on, wi th more
50% Ammoni a
2074 153P Acryl ami de
2074 153P Acryl ami de, sol i d
2075 153 Chl oral , anhydrous, i nhi bi t ed
2075 153 Chl oral , anhydrous, st abi l i zed
2076 153 Cresol s
2076 153 Cresol s, l i qui d
2076 153 Cresol s, sol i d
2077 153 alpha-Naphthylamine
2077 153 Naphthyl ami ne (al pha)
2078 156 Toluene diisocyanate
2079 154 Diethylenetriamine
2186 125 Hydrogen chl ori de, refri gerated
liquid
2187 120 Carbon di oxi de, refri gerated
l i qui d
2188 119 Arsi ne
2188 119 SA
No. No.
No. No.
Page 53
2189 119 Dichlorosilane
2190 124 Oxygen di fl uori de
2190 124 Oxygen di fl uori de, compressed
2191 123 Sulfuryl fluoride
2191 123 Sul phuryl fl uori de
2192 119 Germane
2193 126 Hexafluoroethane
2193 126 Hexafluoroethane, compressed
2193 126 Refrigerant gas R-116,
compressed
2194 125 Sel eni um hexaf l uori de
2195 125 Tel l uri um hexaf l uori de
2196 125 Tungst en hexaf l uori de
2197 125 Hydrogen i odi de, anhydrous
2198 125 Phosphorus pent af l uori de
2198 125 Phosphorus pent af l uori de,
compressed
2199 119 Phosphi ne
2200 116P Propadi ene, i nhi bi t ed
2200 116P Propadi ene, st abi l i zed
2201 122 Ni t rous oxi de, ref ri gerat ed
liquid
2202 117 Hydrogen sel eni de, anhydrous
2203 116 Silane
2203 116 Si l ane, compressed
2204 119 Carbonyl sul fi de
2204 119 Carbonyl sul phi de
2205 153 Adiponitrile
2206 155 Isocyanate sol uti on, poi sonous,
n. o. s.
2206 155 I socyanat e sol ut i on, t oxi c,
n. o. s.
2206 155 I socyanat e sol ut i ons, n. o. s.
2206 155 I socyanat es, n. o. s.
2206 155 Isocyanates, poi sonous, n.o.s.
2206 155 I socyanat es, t oxi c, n. o. s.
2208 140 Bl eachi ng powder
2208 140 Cal ci um hypochl ori te mi xture,
dry, wi t h more t han 10% but
not more t han 39% avai l abl e
Chl ori ne
2209 132 Formal dehyde, sol ut i ons
(Formal i n) (corrosi ve)
2210 135 Maneb
2210 135 Maneb preparat i on, wi t h not
l ess t han 60% Maneb
2211 133 Pol ymeri c beads, expandabl e
2211 133 Pol yst yrene beads, expandabl e
2212 171 Asbest os
2212 171 Asbest os, bl ue
2212 171 Asbest os, brown
2212 171 Bl ue asbest os
2212 171 Brown asbest os
2213 133 Paraf ormal dehyde
2214 156 Pht hal i c anhydri de
2215 156 Mal ei c aci d
2215 156 Mal ei c anhydri de
2215 156 Mal ei c anhydri de, mol ten
2216 171 Fi sh meal , stabi l i zed
2216 171 Fi sh scrap, stabi l i zed
2217 135 Seed cake, wi th not more than
1. 5% oi l and not more t han
11% moi st ur e
2218 132P Acryl i c aci d, i nhi bi ted
2218 132P Acryl i c aci d, st abi l i zed
2219 129 Al l yl gl yci dyl et her
2222 128 Anisole
2224 152 Benzonitrile
No. No.
No. No.
Page 54
2225 156 Benzenesul fonyl chl ori de
2225 156 Benzenesulphonyl chloride
2226 156 Benzotrichloride
2227 130P n-Butyl methacryl ate
2227 130P n-Butyl methacryl ate, i nhi bi ted
2227 130P n-Butyl methacryl ate, stabi l i zed
2232 153 Chloroacetaldehyde
2232 153 2-Chloroethanal
2233 152 Chloroanisidines
2234 130 Chlorobenzotrifluorides
2235 153 Chl orobenzyl chl ori des
2235 153 Chl orobenzyl chl ori des, l i qui d
2236 156 3-Chl oro-4-methyl phenyl
i socyanat e
2236 156 3-Chl oro-4-met hyl phenyl
i socyanat e, l i qui d
2237 153 Chl oroni t roani l i nes
2238 129 Chl orot ol uenes
2239 153 Chl orot ol ui di nes
2239 153 Chl orot ol ui di nes, l i qui d
2239 153 Chl orot ol ui di nes, sol i d
2240 154 Chromosul furi c aci d
2240 154 Chromosul phuri c aci d
2241 128 Cycl oheptane
2242 128 Cycl oheptene
2243 130 Cycl ohexyl acet at e
2244 129 Cycl opentanol
2245 128 Cycl opentanone
2246 128 Cycl opentene
2247 128 n-Decane
2248 132 Di-n-butylamine
2249 131 Di chl orodi methyl ether,
symmet ri cal
2250 156 Di chl orophenyl i socyanat es
2251 128P Bi cycl o[ 2. 2. 1] hept a-2, 5-di ene
2251 128P Bi cycl o[ 2. 2. 1] hept a-2, 5-di ene,
i nhi bi t ed
2251 128P Bi cycl o[ 2. 2. 1] hept a-2, 5-di ene,
st abi l i zed
2251 128P Di cycl ohept adi ene
2251 128P 2, 5-Norbornadi ene
2251 128P 2, 5-Norbornadi ene, i nhi bi t ed
2251 128P 2, 5-Norbornadi ene, st abi l i zed
2252 127 1, 2-Di met hoxyet hane
2253 153 N, N-Di met hyl ani l i ne
2254 133 Mat ches, f usee
2256 130 Cycl ohexene
2257 138 Pot assi um
2257 138 Pot assi um, met al
2258 132 1, 2-Propyl enedi ami ne
2258 132 1, 3-Propyl enedi ami ne
2259 153 Tri et hyl enet et rami ne
2260 132 Tri propyl ami ne
2261 153 Xyl enol s
2261 153 Xyl enol s, sol i d
2262 156 Di methyl carbamoyl chl ori de
2263 128 Di methyl cycl ohexanes
2264 132 N, N-Di met hyl cycl ohexyl ami ne
2264 132 Di met hyl cycl ohexyl ami ne
2265 129 N,N-Di methyl formami de
2266 132 Di methyl -N-propyl ami ne
2267 156 Di methyl thi ophosphoryl chl ori de
2269 153 3,3' -Imi nodi propyl ami ne
2270 132 Ethyl ami ne, aqueous sol uti on,
wi t h not l ess t han 50% but not
more t han 70% Et hyl ami ne
2271 128 Ethyl amyl ketone
2272 153 N-Et hyl ani l i ne
No. No.
No. No.
Page 55
2273 153 2-Et hyl ani l i ne
2274 153 N-Et hyl -N-benzyl ani l i ne
2275 129 2-Ethylbutanol
2276 132 2-Ethyl hexyl ami ne
2277 130P Ethyl methacryl ate
2277 130P Ethyl methacryl ate, i nhi bi ted
2277 130P Ethyl methacryl ate, stabi l i zed
2278 128 n-Heptene
2279 151 Hexachlorobutadiene
2280 153 Hexamethyl enedi ami ne, sol i d
2281 156 Hexamethyl ene di i socyanate
2282 129 Hexanol s
2283 130P Isobutyl methacryl ate
2283 130P Isobutyl methacryl ate, i nhi bi ted
2283 130P Isobutyl methacryl ate, stabi l i zed
2284 131 Isobutyronitrile
2285 156 Isocyanatobenzotrifluorides
2286 128 Pentamethylheptane
2287 128 Isoheptenes
2288 128 Isohexenes
2289 153 Isophoronediamine
2290 156 IPDI
2290 156 Isophorone di i socyanate
2291 151 Lead compound, sol ubl e, n.o.s.
2293 128 4-Methoxy-4-methyl pentan-2-
one
2294 153 N-Methyl ani l i ne
2295 155 Methyl chl oroacetate
2296 128 Met hyl cycl ohexane
2297 128 Methyl cycl ohexanone
2298 128 Methyl cycl opentane
2299 155 Methyl di chl oroacetate
2300 153 2-Methyl -5-ethyl pyri di ne
2301 128 2-Methylfuran
2302 127 5-Methyl hexan-2-one
2303 128 Isopropenylbenzene
2304 133 Naphthalene, molten
2305 153 Nitrobenzenesulfonic acid
2305 153 Nitrobenzenesulphonic acid
2306 152 Nitrobenzotrifluorides
2306 152 Nitrobenzotrifluorides, liquid
2307 152 3-Nitro-4-chlorobenzotrifluoride
2308 157 Ni trosyl sul furi c aci d
2308 157 Ni trosyl sul furi c aci d, l i qui d
2308 157 Ni trosyl sul furi c aci d, sol i d
2308 157 Ni trosyl sul phuri c aci d
2308 157 Ni trosyl sul phuri c aci d, l i qui d
2308 157 Ni trosyl sul phuri c aci d, sol i d
2309 128P Octadiene
2310 131 Pentan-2,4-dione
2310 131 2,4-Pentanedione
2310 131 Pentane-2,4-dione
2311 153 Phenetidines
2312 153 Phenol , mol ten
2313 129 Pi col i nes
2315 171 Articles containing Polychlorinated
biphenyls (PCB)
2315 171 PCB
2315 171 Pol ychl ori nated bi phenyl s
2315 171 Pol ychl ori nated bi phenyl s, l i qui d
2315 171 Pol ychl ori nated bi phenyl s, sol i d
2316 157 Sodi um cuprocyani de, sol i d
2317 157 Sodi um cuprocyani de, sol uti on
2318 135 Sodi um hydrosul fi de, sol i d, wi th
l ess than 25% water of
crystal l i zati on
No. No.
No. No.
Page 56
2318 135 Sodi um hydrosul fi de, wi th l ess
than 25% water of
crystal l i zati on
2318 135 Sodi um hydrosul phi de, sol i d,
wi t h l ess t han 25% wat er of
2318 135 Sodi um hydrosul phi de, wi t h
l ess t han 25% wat er of
2319 128 Terpene hydrocarbons, n. o. s.
2320 153 Tet raet hyl enepent ami ne
2321 153 Tri chl orobenzenes, l i qui d
2322 152 Tri chl orobut ene
2323 130 Tri et hyl phosphi t e
2324 128 Tri i sobut yl ene
2325 129 1, 3, 5-Tri met hyl benzene
2326 153 Tri met hyl cycl ohexyl ami ne
2327 153 Tri met hyl hexamet hyl enedi ami nes
2328 156 Tri methyl hexamethyl ene
di i socyanat e
2329 130 Tri met hyl phosphi t e
2330 128 Undecane
2331 154 Zi nc chl ori de, anhydrous
2332 129 Acet al dehyde oxi me
2333 131 Al l yl acet at e
2334 131 Al l yl ami ne
2335 131 Al l yl et hyl et her
2336 131 Al l yl f ormat e
2337 131 Phenyl mercaptan
2338 127 Benzotrifluoride
2339 130 2-Bromobutane
2340 130 2-Bromoethyl ethyl ether
2341 130 1-Bromo-3-methylbutane
2342 130 Bromomethylpropanes
2343 130 2-Bromopentane
2344 129 2-Bromopropane
2344 129 Bromopropanes
2345 130 3-Bromopropyne
2346 127 Butanedione
2346 127 Di acetyl
2347 130 Butyl mercaptan
2348 130P But yl acryl at e
2348 130P Butyl acryl ates, i nhi bi ted
2348 130P Butyl acryl ates, stabi l i zed
2350 127 Butyl methyl ether
2351 129 Butyl ni tri tes
2352 127P Butyl vi nyl ether, i nhi bi ted
2352 127P Butyl vi nyl ether, stabi l i zed
2353 132 Butyryl chl ori de
2354 131 Chl oromethyl ethyl ether
2356 129 2-Chloropropane
2357 132 Cycl ohexyl ami ne
2358 128P Cyclooctatetraene
2359 132 Di al l yl ami ne
2360 131P Di al l yl ether
2361 132 Di i sobutyl ami ne
2362 130 1,1-Dichloroethane
2363 129 Ethyl mercaptan
2364 128 n-Propyl benzene
2366 128 Diethyl carbonate
2367 130 al pha-Methyl val eral dehyde
2367 130 Methyl val eral dehyde (al pha)
2368 128 alpha-Pinene
2368 128 Pinene (alpha)
2369 152 Ethyl ene gl ycol monobutyl ether
2370 128 1-Hexene
2371 128 Isopentenes
2372 129 1,2-Di-(dimethylamino)ethane
No. No.
No. No.
Page 57
2373 127 Di ethoxymethane
2374 127 3,3-Diethoxypropene
2375 129 Di ethyl sul fi de
2375 129 Diethyl sulphide
2376 127 2,3-Di hydropyran
2377 127 1,1-Dimethoxyethane
2378 131 2-Dimethylaminoacetonitrile
2379 132 1,3-Di methyl butyl ami ne
2380 127 Di methyl di ethoxysi l ane
2381 130 Di methyl di sul fi de
2381 130 Di methyl di sul phi de
2382 131 1,2-Di methyl hydrazi ne
2382 131 Di methyl hydrazi ne, symmetri cal
2383 132 Di propyl ami ne
2384 127 Di-n-propyl ether
2384 127 Di propyl ether
2385 129 Ethyl i sobutyrate
2386 132 1-Ethylpiperidine
2387 130 Fluorobenzene
2388 130 Fluorotoluenes
2389 128 Furan
2390 129 2-Iodobutane
2391 129 Iodomethylpropanes
2392 129 Iodopropanes
2393 129 Isobutyl formate
2394 129 Isobutyl propionate
2395 132 Isobutyryl chl ori de
2396 131P Methacryl al dehyde
2396 131P Methacryl al dehyde, i nhi bi ted
2396 131P Methacryl al dehyde, stabi l i zed
2397 127 3-Methylbutan-2-one
2398 127 Methyl tert-butyl ether
2399 132 1-Methylpiperidine
2400 130 Methyl i soval erate
2401 132 Piperidine
2402 130 Propanethiols
2403 129P Isopropenyl acetate
2404 131 Propionitrile
2405 129 Isopropyl butyrate
2406 127 Isopropyl i sobutyrate
2407 155 Isopropyl chl oroformate
2409 129 Isopropyl propionate
2410 129 1,2,3,6-Tetrahydropyridine
2410 129 1,2,5,6-Tetrahydropyridine
2411 131 Butyroni tri l e
2412 130 Tetrahydrothiophene
2413 128 Tetrapropyl orthotitanate
2414 130 Thiophene
2416 129 Trimethyl borate
2417 125 Carbonyl fl uori de
2417 125 Carbonyl fl uori de, compressed
2418 125 Sulfur tetrafluoride
2418 125 Sulphur tetrafluoride
2419 116 Bromotrifluoroethylene
2420 125 Hexafluoroacetone
2421 124 Ni trogen tri oxi de
2422 126 Octafluorobut-2-ene
2424 126 Octafluoropropane
2426 140 Ammonium nitrate, liquid (hot
concent rat ed sol ut i on)
2427 140 Pot assi um chl orat e, aqueous
sol ut i on
2427 140 Pot assi um chl orat e, sol ut i on
2428 140 Sodi um chl orate, aqueous
solution
No. No.
No. No.
Page 58
2429 140 Cal ci um chl orate, aqueous
sol ut i on
2429 140 Cal ci um chl orat e, sol ut i on
2430 153 Al kyl phenol s, sol i d, n. o. s.
(i ncl udi ng C2-C12
homol ogues)
2431 153 Ani si di nes
2431 153 Ani si di nes, l i qui d
2431 153 Ani si di nes, sol i d
2432 153 N, N-Di et hyl ani l i ne
2433 152 Chl oroni t rot ol uenes
2433 152 Chl oroni t rot ol uenes, l i qui d
2433 152 Chl oroni t rot ol uenes, sol i d
2434 156 Di benzyl di chl orosi l ane
2435 156 Et hyl phenyl di chl orosi l ane
2436 129 Thioacetic acid
2437 156 Methyl phenyl di chl orosi l ane
2438 132 Tri methyl acetyl chl ori de
2439 154 Sodium hydrogendifluoride
2440 154 Stannic chloride, pentahydrate
2440 154 Tin tetrachloride, pentahydrate
2441 135 Titanium trichloride, pyrophoric
2441 135 Titanium trichloride mixture,
pyrophori c
2442 156 Tri chl oroacet yl chl ori de
2443 137 Vanadi um oxyt ri chl ori de
2444 137 Vanadium tetrachloride
2445 135 Li thi um al kyl s
2445 135 Li thi um al kyl s, l i qui d
2446 153 Ni trocresol s
2446 153 Ni trocresol s, sol i d
2447 136 Phosphorus, whi te, mol ten
2447 136 White phosphorus, molten
2447 136 Yel l ow phosphorus, mol ten
2448 133 Sul fur, mol ten
2448 133 Sul phur, mol ten
2451 122 Nitrogen trifluoride
2451 122 Nitrogen trifluoride, compressed
2452 116P Ethyl acetyl ene, i nhi bi ted
2452 116P Ethyl acetyl ene, stabi l i zed
2453 115 Ethyl fl uori de
2454 115 Methyl fl uori de
2455 116 Methyl ni tri te
2456 130P 2-Chloropropene
2457 128 2,3-Dimethylbutane
2458 130 Hexadi ene
2459 128 2-Methyl-1-butene
2460 128 2-Methyl-2-butene
2461 128 Methylpentadiene
2463 138 Al umi num hydri de
2464 141 Beryl l i um ni trate
2465 140 Di chl oroi socyanuri c aci d, dry
2465 140 Di chl oroi socyanuri c aci d sal ts
2465 140 Sodium dichloroisocyanurate
2465 140 Sodium dichloro-s-triazinetrione
2466 143 Potassi um superoxi de
2467 140 Sodium percarbonates
2468 140 Tri chl oroi socyanuri c aci d, dry
2468 140 (mono)-(Trichloro)-tetra-
(monopot assi um di chl oro)-
pent a-s-t ri azi net ri one, dry
2469 140 Zi nc bromat e
2470 152 Phenyl acet oni t ri l e, l i qui d
2471 154 Osmi um tetroxi de
2473 154 Sodium arsanilate
No. No.
No. No.
Page 59
2474 157 Thiophosgene
2475 157 Vanadium trichloride
2477 131 Methyl i sothi ocyanate
2478 155 Isocyanate sol uti on, fl ammabl e,
2478 155 I socyanat e sol ut i on, f l ammabl e,
t oxi c, n. o. s.
2478 155 I socyanat e sol ut i ons, n. o. s.
2478 155 I socyanat es, f l ammabl e,
2478 155 I socyanat es, f l ammabl e, t oxi c,
n. o. s.
2480 155 Methyl i socyanate
2481 155 Ethyl i socyanate
2482 155 n-Propyl i socyanate
2483 155 Isopropyl i socyanate
2484 155 tert-Butyl i socyanate
2485 155 n-Butyl i socyanate
2486 155 Isobutyl i socyanate
2487 155 Phenyl i socyanate
2488 155 Cycl ohexyl i socyanat e
2490 153 Di chl oroi sopropyl ether
2491 153 Ethanolamine
2491 153 Ethanolamine, solution
2491 153 Monoethanolamine
2493 132 Hexamethyl enei mi ne
2495 144 Iodine pentafluoride
2496 156 Propi oni c anhydri de
2498 129 1,2,3,6-Tetrahydrobenzaldehyde
2501 152 1-Azi ri di nyl phosphi ne oxi de
(Tri s)
2501 152 Tri -(1-azi ri di nyl )phosphi ne
oxi de, sol uti on
2501 152 Tris-(1-aziridinyl)phosphine
oxi de, sol ut i on
2502 132 Val eryl chl ori de
2503 137 Zi rconi um t et rachl ori de
2504 159 Acet yl ene t et rabromi de
2504 159 Tet rabromoet hane
2505 154 Ammoni um f l uori de
2506 154 Ammoni um hydrogen sul f at e
2506 154 Ammoni um hydrogen sul phat e
2507 154 Chl oropl at i ni c aci d, sol i d
2508 156 Mol ybdenum pent achl ori de
2509 154 Potassium hydrogen sulfate
2509 154 Potassi um hydrogen sul phate
2511 153 2-Chl oropropi oni c aci d
2511 153 2-Chl oropropi oni c aci d, sol i d
2511 153 2-Chl oropropi oni c aci d, sol uti on
2512 152 Aminophenols
2513 156 Bromoacetyl bromi de
2514 130 Bromobenzene
2515 159 Bromoform
2516 151 Carbon tetrabromide
2517 115 1-Chloro-1,1-difluoroethane
2517 115 Chlorodifluoroethanes
2517 115 Difluorochloroethanes
2517 115 Refrigerant gas R-142b
2518 153 1,5,9-Cycl ododecatri ene
2520 130P Cycl ooctadi enes
2521 131P Diketene, inhibited
2521 131P Diketene, stabilized
2522 153P 2-Dimethylaminoethyl
met hacryl at e
2522 153P Di methyl ami noethyl methacryl ate
2524 129 Ethyl orthoformate
No. No.
No. No.
Page 60
2525 156 Ethyl oxal ate
2526 132 Furfurylamine
2527 130P Isobutyl acryl ate
2527 130P Isobutyl acryl ate, i nhi bi ted
2527 130P Isobutyl acryl ate, stabi l i zed
2528 130 Isobutyl i sobutyrate
2529 132 Isobutyri c aci d
2530 132 Isobutyri c anhydri de
2531 153P Methacryl i c aci d, i nhi bi ted
2531 153P Methacryl i c aci d, stabi l i zed
2533 156 Methyl trichloroacetate
2534 119 Methyl chl orosi l ane
2535 132 4-Methylmorpholine
2535 132 N-Methyl morphol i ne
2535 132 Methylmorpholine
2536 127 Methyltetrahydrofuran
2538 133 Nitronaphthalene
2541 128 Terpinolene
2542 153 Tributylamine
2545 135 Hafni um powder, dry
2546 135 Ti tani um powder, dry
2547 143 Sodi um superoxi de
2548 124 Chlorine pentafluoride
2552 151 Hexafluoroacetone hydrate
2552 151 Hexafl uoroacetone hydrate,
l i qui d
2554 130P Met hyl al l yl chl ori de
2555 113 Ni t rocel l ul ose wi t h wat er, not
2556 113 Ni t rocel l ul ose wi t h al cohol
2556 113 Ni t rocel l ul ose wi t h not l ess t han
25% al cohol
2557 133 Ni t rocel l ul ose mi xt ure, wi t hout
pl ast i ci zer, wi t hout pi gment
2557 133 Ni trocel l ul ose mi xture, wi thout
pl ast i ci zer, wi t h pi gment
2557 133 Ni t rocel l ul ose mi xt ure, wi t h
pl ast i ci zer, wi t hout pi gment
2557 133 Ni t rocel l ul ose mi xt ure, wi t h
pl ast i ci zer, wi t h pi gment
2557 133 Ni t rocel l ul ose wi t h pl ast i ci zi ng
subst ance
2558 131 Epi bromohydri n
2560 129 2-Met hyl pent an-2-ol
2561 128 3-Met hyl -1-but ene
2564 153 Tri chl oroacet i c aci d, sol ut i on
2565 153 Di cycl ohexyl ami ne
2567 154 Sodi um pent achl orophenat e
2570 154 Cadmi um compound
2571 156 Al kyl sul f uri c aci ds
2571 156 Al kyl sul phuri c aci ds
2571 156 Et hyl sul f uri c aci d
2571 156 Et hyl sul phuri c aci d
2572 153 Phenyl hydrazi ne
2573 141 Thal l i um chl orat e
2574 151 Tri cresyl phosphat e
2576 137 Phosphorus oxybromi de,
mol t en
2577 156 Phenyl acet yl chl ori de
2578 157 Phosphorus tri oxi de
2579 153 Piperazine
2580 154 Aluminum bromide, solution
2581 154 Al umi num chl ori de, sol uti on
2582 154 Ferri c chl ori de, sol uti on
2583 153 Al kyl sul f oni c aci ds, sol i d, wi t h
more t han 5% f ree Sul f uri c
aci d
No. No.
No. No.
Page 61
2583 153 Al kyl sul phoni c aci ds, sol i d, wi t h
more than 5% free Sul phuri c
acid
2583 153 Aryl sul f oni c aci ds, sol i d, wi t h
aci d
2583 153 Aryl sul phoni c aci ds, sol i d, wi t h
more t han 5% f ree Sul phuri c
aci d
2583 153 Tol uene sul foni c aci d, sol i d,
wi t h more t han 5% f ree
Sul f uri c aci d
2583 153 Tol uene sul phoni c aci d, sol i d,
Sul phuri c aci d
2584 153 Alkyl sulfonic acids, liquid, with
more than 5% free Sulfuric acid
2584 153 Al kyl sul phoni c aci ds, l i qui d,
Sul phuri c aci d
2584 153 Aryl sul f oni c aci ds, l i qui d, wi t h
aci d
2584 153 Aryl sul phoni c aci ds, l i qui d,
Sul phuri c aci d
2584 153 Dodecyl benzenesul f oni c aci d
2584 153 Dodecyl benzenesul phoni c aci d
2584 153 Tol uene sul foni c aci d, l i qui d, wi th
more than 5% free Sul furi c
acid
2584 153 Tol uene sul phoni c aci d, l i qui d,
Sul phuri c aci d
2585 153 Al kyl sul f oni c aci ds, sol i d, wi t h
not more t han 5% f ree
Sul f uri c aci d
2585 153 Al kyl sul phoni c aci ds, sol i d, wi t h
not more than 5% free
Sul phuri c aci d
2585 153 Aryl sul f oni c aci ds, sol i d, wi t h
Sul f uri c aci d
2585 153 Aryl sul phoni c aci ds, sol i d, wi t h
Sul phuri c aci d
2585 153 Tol uene sul foni c aci d, sol i d,
wi t h not more t han 5% f ree
Sul f uri c aci d
2585 153 Tol uene sul phoni c aci d, sol i d,
Sul phuri c aci d
2586 153 Alkyl sulfonic acids, liquid, with
not more than 5% free Sulfuric
acid
2586 153 Al kyl sul phoni c aci ds, l i qui d,
wi th not more than 5% free
Sul phuri c aci d
2586 153 Aryl sul f oni c aci ds, l i qui d, wi t h
Sul f uri c aci d
2586 153 Aryl sul phoni c aci ds, l i qui d,
Sul phuri c aci d
2586 153 Tol uene sul f oni c aci d, l i qui d,
Sul furi c aci d
2586 153 Tol uene sul phoni c aci d, l i qui d,
Sul phuri c aci d
2587 153 Benzoqui none
2588 151 Pest i ci de, sol i d, poi sonous
2588 151 Pest i ci de, sol i d, poi sonous,
n. o. s.
2588 151 Pest i ci de, sol i d, t oxi c, n. o. s.
2589 155 Vi nyl chl oroacetate
2590 171 Asbestos, whi te
2590 171 White asbestos
No. No.
No. No.
Page 62
2591 120 Xenon, refrigerated liquid
2599 126 Chlorotrifluoromethane and
Tri f l uoromet hane azeot ropi c
mi xt ure wi t h approxi mat el y
60% Chl orot ri f l uoromet hane
2599 126 Ref ri gerant gas R-13 and
Ref ri gerant gas R-23
azeot ropi c mi xt ure wi t h 60%
2599 126 Ref ri gerant gas R-23 and
(azeot ropi c mi xt ure of
Ref ri gerant gas R-13 and
Ref ri gerant gas R-23 wi t h
approxi mat el y 60%
Refri gerant gas R-13)
2599 126 Tri f l uoromet hane and
Chl orot ri f l uoromet hane
azeot ropi c mi xt ure wi t h
Chl orot ri f l uoromet hane
2600 119 Carbon monoxi de and Hydrogen
mi xt ure
2600 119 Carbon monoxi de and Hydrogen
2600 119 Hydrogen and Carbon monoxi de
mi xt ure
2600 119 Hydrogen and Carbon monoxi de
2601 115 Cycl obut ane
2602 126 Di chl orodi f l uoromet hane and
Difluoroethane azeotropic
mi xture wi th approxi matel y
74% Di chl orodi f l uoromet hane
2602 126 Difluoroethane and
Di chl orodi f l uoromet hane
azeotropi c mi xture wi th
Dichlorodifluoromethane
2602 126 Refrigerant gas R-12 and
Ref ri gerant gas R-152a
2602 126 Ref ri gerant gas R-152a and
(azeot ropi c mi xt ure of
Ref ri gerant gas R-12 and
Ref ri gerant gas R-152a wi t h
Refri gerant gas R-12)
2603 131 Cycloheptatriene
2604 132 Boron trifluoride diethyl etherate
2605 155 Met hoxymet hyl i socyanat e
2606 155 Methyl orthosi l i cate
2607 129P Acrol ei n di mer, stabi l i zed
2608 129 Nitropropanes
2609 156 Tri al l yl borate
2610 132 Triallylamine
2611 131 Propyl ene chl orohydri n
2612 127 Methyl propyl ether
2614 129 Methal l yl al cohol
2615 127 Ethyl propyl ether
2616 129 Triisopropyl borate
2617 129 Met hyl cycl ohexanol s
2618 130P Vi nyl tol uenes, i nhi bi ted
2618 130P Vi nyl tol uenes, stabi l i zed
2619 132 Benzyl di methyl ami ne
2620 130 Amyl but yrat es
No. No.
No. No.
Page 63
2621 127 Acetyl methyl carbi nol
2622 131P Gl yci dal dehyde
2623 133 Fi rel i ghters, sol i d, wi th
f l ammabl e l i qui d
2624 138 Magnesi um si l i ci de
2626 140 Chl ori c aci d, aqueous sol ut i on,
wi t h not more t han 10%
Chl ori c aci d
2627 140 Ni t ri t es, i norgani c, n. o. s.
2628 151 Pot assi um f l uoroacet at e
2629 151 Sodium fluoroacetate
2630 151 Selenates
2630 151 Selenites
2630 151 Sodi um sel eni te
2642 154 Fluoroacetic acid
2643 155 Methyl bromoacetate
2644 151 Methyl i odi de
2645 153 Phenacyl bromi de
2646 151 Hexachl orocycl opentadi ene
2647 153 Malononitrile
2648 154 1,2-Dibromobutan-3-one
2649 153 1,3-Dichloroacetone
2650 153 1,1-Dichloro-1-nitroethane
2651 153 4,4' -Diaminodiphenylmethane
2653 156 Benzyl i odi de
2655 151 Potassium fluorosilicate
2655 151 Potassi um si l i cofl uori de
2656 154 Quinoline
2657 153 Selenium disulfide
2657 153 Selenium disulphide
2658 152 Sel eni um powder
2659 151 Sodium chloroacetate
2660 153 Mononitrotoluidines
2660 153 Nitrotoluidines (mono)
2661 153 Hexachloroacetone
2662 153 Hydroqui none
2662 153 Hydroqui none, sol i d
2664 160 Dibromomethane
2666 156 Ethyl cyanoacetate
2667 152 Butyl tol uenes
2668 131 Chloroacetonitrile
2669 152 Chl orocresol s
2669 152 Chl orocresol s, l i qui d
2669 152 Chl orocresol s, sol i d
2669 152 Chl orocresol s, sol uti on
2670 157 Cyanuri c chl ori de
2671 153 Ami nopyri di nes
2672 154 Ammoni a, sol uti on, wi th more
35% Ammoni a
2672 154 Ammoni um hydroxi de
2672 154 Ammoni um hydroxi de, wi t h
more t han 10% but not more
t han 35% Ammoni a
2673 151 2-Ami no-4-chl orophenol
2674 154 Sodi um f l uorosi l i cat e
2674 154 Sodi um si l i cof l uori de
2676 119 St i bi ne
2677 154 Rubi di um hydroxi de, sol ut i on
2678 154 Rubi di um hydroxi de
2678 154 Rubi di um hydroxi de, sol i d
2679 154 Li t hi um hydroxi de, sol ut i on
2680 154 Li t hi um hydroxi de
2680 154 Li t hi um hydroxi de, monohydrat e
2680 154 Li t hi um hydroxi de, sol i d
2681 154 Caesi um hydroxi de, sol ut i on
2681 154 Cesi um hydroxi de, sol ut i on
2682 157 Caesi um hydroxi de
No. No.
No. No.
Page 64
2682 157 Cesi um hydroxi de
2683 132 Ammonium sulfide, solution
2683 132 Ammoni um sul phi de, sol uti on
2684 132 3-Diethylaminopropylamine
2684 132 Di ethyl ami nopropyl ami ne
2685 132 N,N-Di ethyl ethyl enedi ami ne
2686 132 2-Diethylaminoethanol
2686 132 Diethylaminoethanol
2687 133 Di cycl ohexyl ammoni um ni tri te
2688 159 1-Bromo-3-chloropropane
2688 159 1-Chloro-3-bromopropane
2689 153 Gl ycerol al pha-monochl orohydri n
2690 152 N,n-Butyl i mi dazol e
2691 137 Phosphorus pentabromide
2692 157 Boron tribromide
2693 154 Bi sul fi tes, aqueous sol uti on,
n. o. s.
2693 154 Bi sul fi tes, i norgani c, aqueous
sol uti on, n.o.s.
2693 154 Bi sul phi tes, aqueous sol uti on,
n. o. s.
2693 154 Bi sul phi tes, i norgani c, aqueous
sol uti on, n.o.s.
2698 156 Tetrahydrophthalic anhydrides
2699 154 Trifluoroacetic acid
2705 153P 1-Pentol
2707 127 Di methyl di oxanes
2708 127 But oxyl
2709 128 Butyl benzenes
2710 128 Di propyl ketone
2711 129 Dibromobenzene
2713 153 Acridine
2714 133 Zinc resinate
2715 133 Aluminum resinate
2716 153 1,4-Butynedi ol
2717 133 Camphor
2717 133 Camphor, syntheti c
2719 141 Barium bromate
2720 141 Chromium nitrate
2721 141 Copper chl orate
2722 140 Lithium nitrate
2723 140 Magnesium chlorate
2724 140 Manganese nitrate
2725 140 Ni ckel ni trate
2726 140 Ni ckel ni tri te
2727 141 Thallium nitrate
2728 140 Zirconium nitrate
2729 152 Hexachlorobenzene
2730 152 Ni troani sol es
2730 152 Ni troani sol es, l i qui d
2730 152 Ni troani sol es, sol i d
2732 152 Nitrobromobenzenes
2732 152 Nitrobromobenzenes, liquid
2732 152 Nitrobromobenzenes, solid
2733 132 Al kyl ami nes, n. o. s.
2733 132 Ami nes, fl ammabl e, corrosi ve,
n. o. s.
2733 132 Pol yal kyl ami nes, n. o. s.
2733 132 Pol yami nes, f l ammabl e,
corrosi ve, n. o. s.
2734 132 Ami nes, l i qui d, corrosi ve,
2734 132 Pol yami nes, l i qui d, corrosi ve,
2735 153 Ami nes, l i qui d, corrosi ve, n. o. s.
No. No.
No. No.
Page 65
2735 153 Pol yami nes, l i qui d, corrosi ve,
n. o. s.
2738 153 N-But yl ani l i ne
2739 156 But yri c anhydri de
2740 155 n-Propyl chl orof ormat e
2741 141 Bari um hypochl ori t e, wi t h more
2742 155 sec-Butyl chl oroformate
2742 155 Chl oroformates, n.o.s.
2742 155 Chloroformates, poisonous,
corrosi ve, f l ammabl e, n. o. s.
2742 155 Chl orof ormat es, t oxi c,
2742 155 I sobut yl chl orof ormat e
2743 155 n-But yl chl orof ormat e
2744 155 Cycl obut yl chl orof ormat e
2745 157 Chl oromet hyl chl orof ormat e
2746 156 Phenyl chl orof ormat e
2747 156 t ert -But yl cycl ohexyl
chl orof ormat e
2748 156 2-Et hyl hexyl chl orof ormat e
2749 130 Tet ramet hyl si l ane
2750 153 1, 3-Di chl oropropanol -2
2751 155 Di et hyl t hi ophosphoryl chl ori de
2752 127 1, 2-Epoxy-3-et hoxypropane
2753 153 N-Et hyl benzyl t ol ui di nes
2753 153 N-Et hyl benzyl t ol ui di nes, l i qui d
2753 153 N-Et hyl benzyl t ol ui di nes, sol i d
2754 153 N-Et hyl t ol ui di nes
2757 151 Carbamat e pest i ci de, sol i d,
poi sonous
2757 151 Carbamat e pest i ci de, sol i d,
t oxi c
2758 131 Carbamate pesti ci de, l i qui d,
f l ammabl e, poi sonous
2758 131 Carbamat e pest i ci de, l i qui d,
f l ammabl e, t oxi c
2759 151 Arseni cal pest i ci de, sol i d,
poi sonous
2759 151 Arseni cal pest i ci de, sol i d, t oxi c
2760 131 Arseni cal pest i ci de, l i qui d,
2760 131 Arseni cal pest i ci de, l i qui d,
2761 151 Al dri n, sol i d
2761 151 Di el dri n
2761 151 Organochl ori ne pest i ci de, sol i d,
poi sonous
2761 151 Organochl ori ne pest i ci de, sol i d,
t oxi c
2762 131 Al dri n, l i qui d
2762 131 Organochl ori ne pest i ci de,
l i qui d, f l ammabl e, poi sonous
2762 131 Organochl ori ne pest i ci de,
l i qui d, f l ammabl e, t oxi c
2763 151 Tri azi ne pest i ci de, sol i d,
poisonous
2763 151 Tri azi ne pesti ci de, sol i d, toxi c
2764 131 Triazine pesticide, liquid,
2764 131 Tri azi ne pest i ci de, l i qui d,
2765 152 Phenoxy pest i ci de, sol i d,
poi sonous
2765 152 Phenoxy pest i ci de, sol i d, t oxi c
2766 131 Phenoxy pest i ci de, l i qui d,
fl ammabl e, toxi c
No. No.
No. No.
Page 66
2767 151 Phenyl urea pesti ci de, sol i d,
poi sonous
2767 151 Phenyl urea pesti ci de, sol i d,
t oxi c
2768 131 Phenyl urea pest i ci de, l i qui d,
2769 151 Benzoi c deri vat i ve pest i ci de,
sol i d, poi sonous
sol i d, t oxi c
2771 151 Di thi ocarbamate pesti ci de, sol i d,
poisonous
2771 151 Di thi ocarbamate pesti ci de, sol i d,
t oxi c
2771 151 Thiocarbamate pesticide, solid,
poi sonous
2771 151 Thi ocarbamat e pest i ci de, sol i d,
t oxi c
2772 131 Dithiocarbamate pesticide, liquid,
flammable, poisonous
fl ammabl e, toxi c
2772 131 Thiocarbamate pesticide, liquid,
fl ammabl e, toxi c
2773 151 Phthal i mi de deri vati ve pesti ci de,
solid, poisonous
sol i d, t oxi c
liquid, flammable, poisonous
l i qui d, fl ammabl e, toxi c
2775 151 Copper based pesti ci de, sol i d,
poi sonous
2775 151 Copper based pest i ci de, sol i d,
t oxi c
2776 131 Copper based pesti ci de, l i qui d,
2776 131 Copper based pest i ci de, l i qui d,
2777 151 Mercury based pest i ci de, sol i d,
poi sonous
2777 151 Mercury based pesti ci de, sol i d,
t oxi c
2778 131 Mercury based pest i ci de, l i qui d,
2779 153 Subst i t ut ed ni t rophenol
pest i ci de, sol i d, poi sonous
pest i ci de, sol i d, t oxi c
pesti ci de, l i qui d, fl ammabl e,
poisonous
2780 131 Substituted nitrophenol pesticide,
2781 151 Bi pyri di l i um pesti ci de, sol i d,
poi sonous
2781 151 Bi pyri di l i um pest i ci de, sol i d,
t oxi c
2782 131 Bi pyri di l i um pest i ci de, l i qui d,
2783 152 Met hyl parat hi on, sol i d
2783 152 Organophosphorus pest i ci de,
solid, poisonous
No. No.
No. No.
Page 67
2783 152 Organophosphorus pesticide,
sol i d, t oxi c
2783 152 Parat hi on
2783 152 Tet raet hyl pyrophosphat e, sol i d
2785 152 4-Thi apent anal
2785 152 Thi a-4-pent anal
2786 153 Organoti n pesti ci de, sol i d,
poi sonous
2786 153 Organot i n pest i ci de, sol i d, t oxi c
2787 131 Organot i n pest i ci de, l i qui d,
2788 153 Organotin compound, liquid, n.o.s.
2789 132 Acet i c aci d, gl aci al
2789 132 Acet i c aci d, sol ut i on, more t han
80% aci d
2790 153 Aceti c aci d, sol uti on, more than
aci d
2793 170 Ferrous met al bori ngs,
shavi ngs, t urni ngs or cut t i ngs
2794 154 Bat t eri es, wet , f i l l ed wi t h aci d
2795 154 Bat t eri es, wet , f i l l ed wi t h al kal i
2796 157 Bat t ery f l ui d, aci d
2796 157 Sul f uri c aci d, wi t h not more t han
51% aci d
2796 157 Sul phuri c aci d, wi t h not more
t han 51% aci d
2797 154 Bat t ery f l ui d, al kal i
2797 154 Bat t ery f l ui d, al kal i , wi t h bat t ery
2797 154 Battery fl ui d, al kal i , wi th
electronic equipment or
actuating device
2798 137 Benzene phosphorus dichloride
2798 137 Phenylphosphorus dichloride
2799 137 Benzene phosphorus
t hi odi chl ori de
2799 137 Phenyl phosphorus
t hi odi chl ori de
2800 154 Bat t eri es, wet , non-spi l l abl e
2801 154 Dye, l i qui d, corrosi ve, n. o. s.
2801 154 Dye i ntermedi ate, l i qui d,
2802 154 Copper chl ori de
2803 172 Gal l i um
2805 138 Li t hi um hydri de, f used sol i d
2806 138 Li t hi um ni t ri de
2807 171 Magnet i zed mat eri al
2809 172 Mercury
2809 172 Mercury met al
2810 153 Buzz
2810 153 BZ
2810 153 Compound, tree or weed ki l l i ng,
l i qui d (t oxi c)
2810 153 CS
2810 153 DC
2810 153 GA
2810 153 GB
2810 153 GD
2810 153 GF
2810 153 H
2810 153 HD
2810 153 HL
2810 153 HN-1
No. No.
No. No.
Page 68
2810 153 HN- 2
2810 153 HN- 3
2810 153 L (Lewi si te)
2810 153 Lewisite
2810 153 Mustard
2810 153 Mustard Lewi si te
2810 153 Poi son B, l i qui d, n. o. s.
2810 153 Poi sonous l i qui d, n.o.s.
2810 153 Poi sonous l i qui d, organi c,
n. o. s.
Zone A)
Zone B)
2810 153 Sari n
2810 153 Soman
2810 153 Tabun
2810 153 Thi ckened GD
2810 153 Toxi c l i qui d, n. o. s.
2810 153 Toxi c l i qui d, n. o. s. (I nhal at i on
Hazard Zone A)
2810 153 Toxi c l i qui d, n. o. s. (I nhal at i on
Hazard Zone B)
2810 153 Toxi c l i qui d, organi c, n. o. s.
2810 153 VX
2811 154 CX
2811 154 Poi sonous sol i d, organi c, n.o.s.
2811 154 Sel eni um oxi de
2811 154 Toxi c sol i d, organi c, n.o.s.
2812 154 Sodi um al umi nate, sol i d
2813 138 Substances, whi ch i n contact
wi t h wat er emi t f l ammabl e
gases, sol i d, n. o. s.
2813 138 Wat er-react i ve sol i d, n. o. s.
2813 138 Wat er-react i ve subst ances,
sol i d, n. o. s.
2814 158 Infectious substance, affecting
humans
2815 153 N-Ami noet hyl pi perazi ne
2817 154 Ammoni um bi f l uori de, sol ut i on
2817 154 Ammoni um hydrogendi f l uori de,
sol ut i on
2817 154 Ammoni um hydrogen fl uori de,
sol ut i on
2818 154 Ammoni um pol ysul f i de, sol ut i on
2818 154 Ammoni um pol ysul phi de,
solution
2819 153 Amyl aci d phosphate
2820 153 But yri c aci d
2821 153 Phenol solution
2822 153 2-Chloropyridine
2823 153 Crotoni c aci d
2823 153 Crotoni c aci d, l i qui d
2823 153 Crotoni c aci d, sol i d
2826 155 Ethyl chlorothioformate
2829 153 Caproi c aci d
2829 153 Hexanoi c aci d
2830 139 Lithium ferrosilicon
2831 160 1,1,1-Trichloroethane
2834 154 Phosphorous acid
2834 154 Phosphorous aci d, ortho
No. No.
No. No.
Page 69
2835 138 Sodi um al umi num hydri de
2837 154 Bisulfates, aqueous solution
2837 154 Bisulphates, aqueous solution
2837 154 Sodium bisulfate, solution
2837 154 Sodium bisulphate, solution
2837 154 Sodi um hydrogen sul fate,
sol ut i on
2837 154 Sodi um hydrogen sul phat e,
sol ut i on
2838 129P Vi nyl butyrate, i nhi bi ted
2838 129P Vi nyl butyrate, stabi l i zed
2839 153 Al dol
2840 129 Butyral doxi me
2841 131 Di -n-amyl ami ne
2842 129 Nitroethane
2844 138 Cal ci um manganese si l i con
2845 135 Ethyl phosphonous di chl ori de,
anhydrous
2845 135 Methyl phosphonous di chl ori de
2845 135 Pyrophori c l i qui d, n.o.s.
2845 135 Pyrophori c l i qui d, organi c, n.o.s.
2846 135 Pyrophori c sol i d, n. o. s.
2846 135 Pyrophori c sol i d, organi c, n.o.s.
2849 153 3-Chloropropanol-1
2850 128 Propylene tetramer
2851 157 Boron trifluoride, dihydrate
2852 113 Di pi cryl sul fi de, wetted wi th not
2852 113 Di pi cryl sul phi de, wet t ed wi t h
2853 151 Magnesi um f l uorosi l i cat e
2853 151 Magnesi um si l i cof l uori de
2854 151 Ammoni um f l uorosi l i cat e
2854 151 Ammoni um si l i cofl uori de
2855 151 Zinc fluorosilicate
2855 151 Zinc silicofluoride
2856 151 Fl uorosi l i cates, n.o.s.
2856 151 Si l i cofl uori des, n.o.s.
2857 126 Refrigerating machines,
cont ai ni ng Ammoni a
sol ut i ons (UN2073)
containing Ammonia solutions
(UN2672)
cont ai ni ng non-f l ammabl e,
l i quef i ed gas
non-poisonous gases
non-poi sonous, l i quefi ed gas
non-poi sonous, non-
corrosi ve, l i quef i ed gas
non-t oxi c gases
non-t oxi c, l i quef i ed gas
non-t oxi c, non-corrosi ve,
l i quef i ed gas
2858 170 Zi rconi um, dry, coi l ed wi re,
f i ni shed met al sheet s or
st ri ps
2859 154 Ammoni um met avanadat e
2861 151 Ammoni um pol yvanadat e
2862 151 Vanadium pentoxide
No. No.
No. No.
Page 70
2863 154 Sodi um ammoni um vanadate
2864 151 Potassium metavanadate
2865 154 Hydroxyl ami ne sul fate
2865 154 Hydroxyl ami ne sul phate
2869 157 Titanium trichloride mixture
2870 135 Al umi num borohydri de
2870 135 Al umi num borohydri de i n devi ces
2871 170 Anti mony powder
2872 159 Dibromochloropropanes
2873 153 Dibutylaminoethanol
2874 153 Furfuryl al cohol
2875 151 Hexachl orophene
2876 153 Resorcinol
2878 170 Titanium sponge granules
2878 170 Titanium sponge powders
2879 157 Sel eni um oxychl ori de
2880 140 Cal ci um hypochl ori te, hydrated,
wi t h not l ess t han 5. 5% but
not more t han 16% wat er
2880 140 Cal ci um hypochl ori t e, hydrat ed
mi xt ure, wi t h not l ess t han
5. 5% but not more t han 16%
wat er
2881 135 Met al cat al yst , dry
2881 135 Ni ckel cat al yst , dry
2900 158 I nf ect i ous subst ance, af f ect i ng
ani mal s onl y
2901 124 Bromi ne chl ori de
2902 151 Pest i ci de, l i qui d, poi sonous,
n. o. s.
2902 151 Pest i ci de, l i qui d, t oxi c, n. o. s.
2903 131 Pest i ci de, l i qui d, poi sonous,
2903 131 Pesti ci de, l i qui d, toxi c,
fl ammabl e, n.o.s.
2904 154 Chlorophenates, liquid
2904 154 Chlorophenolates, liquid
2904 154 Phenolates, liquid
2905 154 Chl orophenates, sol i d
2905 154 Chl orophenol ates, sol i d
2905 154 Phenolates, solid
2907 133 Isosorbide dinitrate mixture
2908 161 Radi oacti ve materi al , empty
packages
2908 161 Radi oact i ve mat eri al , except ed
package, empt y packagi ng
2909 161 Radi oact i ve mat eri al , art i cl es
manuf act ured f rom depl et ed
Urani um
2909 161 Radi oact i ve mat eri al , art i cl es
manufactured from natural
Thori um
2909 161 Radi oacti ve materi al , arti cl es
Urani um
package, art i cl es
Urani um
Thori um
Urani um
Urani um
2910 161 Radi oacti ve materi al , excepted
package, articles manufactured
from natural Thorium
No. No.
No. No.
Page 71
manuf act ured f rom nat ural
Urani um
package, empt y packagi ng
package, i nst rument s or
art i cl es
package, l i mi t ed quant i t y of
mat eri al
2910 161 Radi oact i ve mat eri al , l i mi t ed
quant i t y, n. o. s.
package, i nstruments or
articles
2911 161 Radi oacti ve materi al , i nstruments
or arti cl es
2912 162 Radi oacti ve materi al , l ow
speci f i c act i vi t y (LSA), n. o. s.
2912 162 Radi oact i ve mat eri al , l ow
speci f i c act i vi t y (LSA-I )
2913 162 Radi oact i ve mat eri al , surf ace
cont ami nat ed obj ect s (SCO)
2913 162 Radi oact i ve mat eri al , surf ace
cont ami nat ed obj ect s (SCO-I )
2913 162 Radi oacti ve materi al , surface
contami nated obj ects (SCO-II)
2915 163 Radi oact i ve mat eri al , Type A
package
2916 163 Radi oact i ve mat eri al , Type B(U)
package
2917 163 Radi oact i ve mat eri al , Type
B(M) package
2918 165 Radi oacti ve materi al , fi ssi l e,
n.o.s.
2919 163 Radioactive material, transported
under special arrangement
2920 132 Corrosive liquid, flammable, n.o.s.
2920 132 Dichlorobutene
2921 134 Corrosive solid, flammable, n.o.s.
2922 154 Corrosive liquid, poisonous, n.o.s.
2922 154 Corrosi ve l i qui d, t oxi c, n. o. s.
2922 154 Sodi um hydrosul fi de, sol uti on
2922 154 Sodi um hydrosul phi de, sol uti on
2923 154 Corrosive solid, poisonous, n.o.s.
2923 154 Corrosi ve sol i d, t oxi c, n. o. s.
2924 132 Flammable liquid, corrosive, n.o.s
2925 134 Flammable solid, corrosive, n.o.s.
2925 134 Fl ammabl e sol i d, corrosi ve,
organi c, n. o. s.
2926 134 Fl ammabl e sol i d, poi sonous,
n. o. s.
organi c, n. o. s.
2926 134 Fl ammabl e sol i d, t oxi c, organi c,
n. o. s.
2927 154 Et hyl phosphonot hi oi c
di chl ori de, anhydrous
2927 154 Et hyl phosphorodi chl ori dat e
2927 154 Poi sonous l i qui d, corrosi ve,
n.o.s.
Zone A)
Zone B)
2927 154 Toxi c l i qui d, corrosi ve, organi c,
n. o. s.
Zone A)
No. No.
No. No.
Page 72
Zone B)
2928 154 Poi sonous sol i d, corrosi ve, n.o.s.
2928 154 Toxi c sol i d, corrosi ve, organi c,
n. o. s.
2929 131 Poi sonous l i qui d, fl ammabl e,
n.o.s.
Zone A)
2929 131 Poi sonous l i qui d, f l ammabl e,
Zone B)
organi c, n. o. s.
organi c, n. o. s. (I nhal at i on
Hazard Zone A)
organi c, n. o. s. (I nhal at i on
Hazard Zone B)
2929 131 Toxi c l i qui d, f l ammabl e, n. o. s.
2929 131 Toxi c l i qui d, f l ammabl e,
organi c, n. o. s.
2929 131 Toxi c l i qui d, fl ammabl e, organi c,
Zone A)
2929 131 Toxi c l i qui d, fl ammabl e, organi c,
Zone B)
2930 134 Poisonous solid, flammable, n.o.s.
2930 134 Poi sonous sol i d, fl ammabl e,
organi c, n. o. s.
2930 134 Toxi c sol i d, fl ammabl e, n.o.s.
2930 134 Toxi c sol i d, fl ammabl e, organi c,
n.o.s.
2931 151 Vanadyl sul fate
2931 151 Vanadyl sul phate
2933 129 Methyl 2-chloropropionate
2934 129 Isopropyl 2-chloropropionate
2935 129 Ethyl 2-chloropropionate
2936 153 Thiolactic acid
2937 153 al pha-Methyl benzyl al cohol
2937 153 al pha-Methyl benzyl al cohol ,
l i qui d
2937 153 Met hyl benzyl al cohol (al pha)
2938 152 Met hyl benzoat e
2940 135 Cycl ooct adi ene phosphi nes
2940 135 9-Phosphabi cycl ononanes
2941 153 Fl uoroani l i nes
2942 153 2-Tri f l uoromet hyl ani l i ne
2943 129 Tet rahydrof urf uryl ami ne
2945 132 N-Met hyl but yl ami ne
2946 153 2-Ami no-5-di et hyl ami nopent ane
2947 155 I sopropyl chl oroacet at e
2948 153 3-Tri f l uoromet hyl ani l i ne
2949 154 Sodi um hydrosul fi de, wi th not
2949 154 Sodi um hydrosul phi de, wi t h not
2950 138 Magnesium granules, coated
2956 149 5-tert-Butyl-2,4,6-trinitro-
m-xyl ene
2956 149 Musk xyl ene
2965 139 Boron t ri f l uori de di met hyl
et herat e
No. No.
No. No.
Page 73
2966 153 Thioglycol
2967 154 Sul fami c aci d
2967 154 Sul phami c aci d
2968 135 Maneb, stabi l i zed
2968 135 Maneb preparation, stabilized
2969 171 Castor beans, meal , pomace or
f l ake
2974 164 Radi oact i ve mat eri al , speci al
form, n.o.s.
2975 162 Thorium metal, pyrophoric
2976 162 Thorium nitrate, solid
2977 166 Radi oacti ve materi al , Urani um
hexaf l uori de, f i ssi l e
2977 166 Urani um hexaf l uori de, f i ssi l e
cont ai ni ng more t han 1%
Urani um-235
2978 166 Radi oact i ve mat eri al , Urani um
hexaf l uori de
2978 166 Radi oact i ve mat eri al , Urani um
hexafl uori de, non-fi ssi l e or
f i ssi l e-except ed
2978 166 Urani um hexaf l uori de
2978 166 Urani um hexaf l uori de, f i ssi l e-
except ed
2978 166 Urani um hexafl uori de, l ow
speci f i c act i vi t y
2978 166 Urani um hexaf l uori de,
non-f i ssi l e
2979 162 Urani um metal , pyrophori c
2980 162 Urani um ni trate, hexahydrate,
solution
2980 162 Uranyl ni trate, hexahydrate,
sol ut i on
2981 162 Uranyl ni t rat e, sol i d
2982 163 Radi oact i ve mat eri al , n. o. s.
2983 129P Ethyl ene oxi de and Propyl ene
oxi de mi xture, wi th not more
2983 129P Propyl ene oxi de and Ethyl ene
oxi de mi xt ure, wi t h not more
sol ut i on, wi t h not l ess t han
8% but l ess t han 20%
Hydrogen peroxi de
2985 155 Chl orosi l anes, fl ammabl e,
2985 155 Chl orosi l anes, n. o. s.
2986 155 Chl orosi l anes, corrosi ve,
2987 156 Chl orosi l anes, corrosi ve, n. o. s.
2988 139 Chl orosi l anes, wat er-react i ve,
f l ammabl e, corrosi ve, n. o. s.
2989 133 Lead phosphi t e, di basi c
2990 171 Li f e-savi ng appl i ances, sel f -
i nf l at i ng
poi sonous, f l ammabl e
t oxi c, f l ammabl e
poisonous
t oxi c
2993 131 Arseni cal pesti ci de, l i qui d,
poisonous, flammable
2993 131 Arseni cal pesti ci de, l i qui d, toxi c,
flammable
No. No.
No. No.
Page 74
2994 151 Arseni cal pesti ci de, l i qui d,
poisonous
2994 151 Arseni cal pesti ci de, l i qui d, toxi c
2995 131 Organochl ori ne pesti ci de, l i qui d,
toxi c, fl ammabl e
poisonous
t oxi c
2997 131 Triazine pesticide, liquid,
2997 131 Tri azi ne pest i ci de, l i qui d, t oxi c,
f l ammabl e
2998 151 Tri azi ne pest i ci de, l i qui d,
poi sonous
2998 151 Tri azi ne pest i ci de, l i qui d, t oxi c
2999 131 Phenoxy pest i ci de, l i qui d, t oxi c,
f l ammabl e
poi sonous
3000 152 Phenoxy pest i ci de, l i qui d, t oxi c
3001 131 Phenyl urea pesti ci de, l i qui d,
poi sonous
t oxi c
3003 131 Benzoi c deri vati ve pesti ci de,
liquid, poisonous, flammable
l i qui d, t oxi c, f l ammabl e
l i qui d, poi sonous
l i qui d, t oxi c
3005 131 Di t hi ocarbamat e pest i ci de,
l i qui d, poi sonous, f l ammabl e
3005 131 Di t hi ocarbamat e pest i ci de,
3005 131 Thi ocarbamat e pest i ci de,
3005 131 Thi ocarbamat e pest i ci de,
l i qui d, toxi c, fl ammabl e
poisonous
t oxi c
poisonous
t oxi c
liquid, poisonous
l i qui d, toxi c
poi sonous
t oxi c
No. No.
No. No.
Page 75
3011 131 Mercury based pesti ci de, l i qui d,
3012 151 Mercury based pesti ci de, l i qui d,
poi sonous
t oxi c
pest i ci de, l i qui d, poi sonous,
f l ammabl e
pest i ci de, l i qui d, t oxi c,
flammable
liquid, poisonous
l i qui d, toxi c
3015 131 Bi pyri di l i um pesti ci de, l i qui d,
poi sonous
t oxi c
3018 152 Met hyl parat hi on, l i qui d
l i qui d, t oxi c
3018 152 Tetraethyl pyrophosphate, liquid
3019 131 Organoti n pesti ci de, l i qui d,
toxi c, fl ammabl e
3020 153 Organoti n pesti ci de, l i qui d,
poisonous
3020 153 Organoti n pesti ci de, l i qui d, toxi c
3021 131 Pesti ci de, l i qui d, fl ammabl e,
3021 131 Pesti ci de, l i qui d, fl ammabl e,
t oxi c, n. o. s.
3022 127P 1, 2-But yl ene oxi de, st abi l i zed
3023 131 2-Methyl-2-hepthanethiol
3023 131 tert-Octyl mercaptan
3024 131 Coumari n deri vati ve pesti ci de,
3024 131 Coumari n deri vat i ve pest i ci de,
l i qui d, t oxi c
3027 151 Coumari n deri vati ve pesti ci de,
sol i d, poi sonous
sol i d, t oxi c
3028 154 Bat t eri es, dry, cont ai ni ng
Potassi um hydroxi de sol i d
3048 157 Aluminum phosphide pesticide
3049 138 Met al al kyl hal i des, n. o. s.
3049 138 Metal al kyl hal i des, water-
react i ve, n. o. s.
3049 138 Met al aryl hal i des, n. o. s.
3049 138 Met al aryl hal i des, wat er-
reacti ve, n.o.s.
3050 138 Met al al kyl hydri des, n. o. s.
No. No.
No. No.
Page 76
3050 138 Metal al kyl hydri des, water-
reacti ve, n.o.s.
3050 138 Met al aryl hydri des, n. o. s.
3050 138 Metal aryl hydri des, water-
reacti ve, n.o.s.
3051 135 Al umi num al kyl s
3052 135 Al umi num al kyl hal i des
3052 135 Al umi num al kyl hal i des, l i qui d
3052 135 Al umi num al kyl hal i des, sol i d
3053 135 Magnesi um al kyl s
3054 129 Cycl ohexanethi ol
3054 129 Cycl ohexyl mercapt an
3055 154 2-(2-Aminoethoxy)ethanol
3056 129 n-Heptaldehyde
3057 125 Trifluoroacetyl chloride
3064 127 Ni trogl yceri n, sol uti on i n al cohol ,
wi th more than 1% but not
more than 5% Ni trogl yceri n
3065 127 Al cohol i c beverages
3066 153 Pai nt (corrosi ve)
3066 153 Pai nt rel ated materi al (corrosi ve)
3070 126 Dichlorodifluoromethane and
Et hyl ene oxi de mi xt ure, wi t h
not more t han 12. 5%
Et hyl ene oxi de
3070 126 Di chl orodi f l uoromet hane and
Et hyl ene oxi de mi xt ures, wi t h
not more t han 12% Et hyl ene
oxi de
3070 126 Ethyl ene oxi de and
mi xt ure, wi t h not more t han
12. 5% Et hyl ene oxi de
mi xt ures, wi t h not more t han
3071 131 Mercaptan mi xture, l i qui d,
poi sonous, f l ammabl e, n. o. s.
3071 131 Mercaptan mi xture, l i qui d, toxi c,
fl ammabl e, n.o.s.
3071 131 Mercaptan mi xtures, l i qui d,
n. o. s.
3071 131 Mercapt ans, l i qui d, n. o. s.
3071 131 Mercaptans, l i qui d, poi sonous,
3071 131 Mercapt ans, l i qui d, t oxi c,
3072 171 Li f e-savi ng appl i ances, not sel f -
i nf l at i ng
3073 131P Vi nyl pyri di nes, i nhi bi t ed
3073 131P Vi nyl pyri di nes, st abi l i zed
3076 138 Al umi num al kyl hydri des
3077 171 Envi ronment al l y hazardous
subst ances, sol i d, n. o. s.
3077 171 Hazardous waste, sol i d, n.o.s.
3077 171 Other regulated substances,
sol i d, n. o. s.
3078 138 Ceri um, t urni ngs or gri t t y
powder
3079 131P Met hacryl oni t ri l e, i nhi bi t ed
3079 131P Met hacryl oni t ri l e, st abi l i zed
3080 155 I socyanat e sol ut i on, poi sonous,
3080 155 I socyanat e sol ut i on, t oxi c,
3080 155 Isocyanate sol uti ons, n.o.s.
3080 155 Isocyanates, poi sonous,
fl ammabl e, n.o.s.
3080 155 Isocyanates, toxi c, fl ammabl e,
n. o. s.
3082 171 Envi ronmental l y hazardous
substances, l i qui d, n.o.s.
No. No.
No. No.
Page 77
3082 171 Hazardous waste, l i qui d, n.o.s.
3082 171 Other regulated substances,
l i qui d, n.o.s.
3083 124 Perchl oryl fl uori de
3084 140 Corrosi ve sol i d, oxi di zi ng, n. o. s.
3085 140 Oxi di zi ng sol i d, corrosi ve, n. o. s.
3085 140 Oxi di zi ng substances, sol i d,
3086 141 Poi sonous sol i d, oxi di zi ng,
n. o. s.
3086 141 Toxi c sol i d, oxi di zi ng, n. o. s.
3087 141 Oxidizing solid, poisonous, n.o.s.
3087 141 Oxi di zi ng sol i d, t oxi c, n. o. s.
3087 141 Oxi di zi ng substances, sol i d,
t oxi c, n. o. s.
3088 135 Sel f-heati ng sol i d, organi c,
n. o. s.
3088 135 Sel f -heat i ng subst ances, sol i d,
n. o. s.
3089 170 Met al powder, f l ammabl e, n. o. s.
3090 138 Li t hi um bat t eri es
3090 138 Li t hi um bat t eri es, l i qui d or sol i d
cat hode
3091 138 Li t hi um bat t eri es cont ai ned i n
equipment
3091 138 Lithium batteries packed with
equi pment
3092 129 1-Met hoxy-2-propanol
3093 140 Corrosi ve l i qui d, oxi di zi ng,
n. o. s.
3094 138 Corrosi ve l i qui d, wat er-react i ve,
n. o. s.
3094 138 Corrosi ve l i qui d, whi ch i n
cont act wi t h wat er emi t s
fl ammabl e gases, n.o.s.
3095 136 Corrosi ve sol i d, sel f-heati ng,
n.o.s.
3096 138 Corrosi ve sol i d, water-reacti ve,
n.o.s.
3096 138 Corrosi ve sol i d, whi ch i n contact
wi th water emi ts fl ammabl e
gases, n. o. s.
3097 140 Flammable solid, oxidizing, n.o.s.
3098 140 Oxi di zi ng l i qui d, corrosi ve, n.o.s.
3098 140 Oxi di zi ng substances, l i qui d,
3099 142 Oxidizing liquid, poisonous, n.o.s.
3099 142 Oxi di zi ng l i qui d, t oxi c, n. o. s.
3099 142 Oxi di zi ng subst ances, l i qui d,
t oxi c, n. o. s.
3100 135 Oxi di zi ng sol i d, sel f -heat i ng,
n. o. s.
3100 135 Oxi di zi ng subst ances, sel f -
heat i ng, n. o. s.
sel f -heat i ng, n. o. s.
3101 146 Organi c peroxi de t ype B, l i qui d
3102 146 Organi c peroxi de t ype B, sol i d
3103 146 Organi c peroxi de type C, l i qui d
3104 146 Organi c peroxi de type C, sol i d
3105 145 Organi c peroxi de type D, l i qui d
3106 145 Organi c peroxi de type D, sol i d
3107 145 Organi c peroxi de type E, l i qui d
3108 145 Organi c peroxi de type E, sol i d
3109 145 Organi c peroxi de type F, l i qui d
3110 145 Organi c peroxi de type F, sol i d
3111 148 Organi c peroxi de type B, l i qui d,
temperature controlled
No. No.
No. No.
Page 78
3112 148 Organi c peroxi de type B, sol i d,
3113 148 Organi c peroxi de type C, l i qui d,
3114 148 Organi c peroxi de t ype C, sol i d,
t emperat ure cont rol l ed
3115 148 Organi c peroxi de t ype D, l i qui d,
3116 148 Organi c peroxi de t ype D, sol i d,
3117 148 Organi c peroxi de t ype E, l i qui d,
3118 148 Organi c peroxi de t ype E, sol i d,
3119 148 Organi c peroxi de type F, l i qui d,
3120 148 Organi c peroxi de t ype F, sol i d,
3121 144 Oxi di zi ng sol i d, wat er-react i ve,
n. o. s.
whi ch i n cont act wi t h wat er
emi t f l ammabl e gases, n. o. s.
3122 142 Poi sonous l i qui d, oxi di zi ng,
n. o. s.
Zone A)
Zone B)
3122 142 Toxi c l i qui d, oxi di zi ng, n. o. s.
3123 139 Poi sonous l i qui d, wat er-
reacti ve, n.o.s.
3123 139 Poi sonous l i qui d, water-reacti ve,
Zone A)
3123 139 Poi sonous l i qui d, water-reacti ve,
Zone B)
3123 139 Poi sonous l i qui d, whi ch i n
f l ammabl e gases, n. o. s.
3123 139 Toxi c l i qui d, wat er-react i ve,
n. o. s.
Zone A)
Zone B)
3123 139 Toxi c l i qui d, whi ch i n cont act
wi t h wat er emi t s f l ammabl e
gases, n. o. s.
3123 139 Toxi c l i qui d, whi ch i n contact
gases, n.o.s. (Inhal ati on
Hazard Zone A)
3123 139 Toxi c l i qui d, whi ch i n cont act
gases, n. o. s. (I nhal at i on
Hazard Zone B)
3124 136 Poi sonous sol i d, sel f -heat i ng,
n.o.s.
3124 136 Toxi c sol i d, sel f-heati ng, n.o.s.
No. No.
No. No.
Page 79
3125 139 Poi sonous sol i d, water-reacti ve,
n.o.s.
3125 139 Poi sonous sol i d, whi ch i n contact
gases, n. o. s.
3125 139 Toxi c sol i d, water-reacti ve,
n. o. s.
3125 139 Toxi c sol i d, whi ch i n cont act
gases, n. o. s.
3126 136 Sel f -heat i ng sol i d, corrosi ve,
organi c, n. o. s.
3126 136 Sel f-heati ng substance, sol i d,
3127 135 Sel f -heat i ng sol i d, oxi di zi ng,
n. o. s.
3127 135 Sel f -heat i ng subst ances, sol i d,
oxi di zi ng, n. o. s.
3128 136 Sel f -heat i ng sol i d, organi c,
3128 136 Sel f -heat i ng sol i d, organi c,
t oxi c, n. o. s.
3128 136 Sel f -heat i ng sol i d, poi sonous,
organi c, n. o. s.
3128 136 Sel f -heat i ng sol i d, t oxi c,
organi c, n. o. s.
3128 136 Sel f-heati ng substances, sol i d,
poi sonous, n.o.s.
3128 136 Sel f-heati ng substances, sol i d,
t oxi c, n. o. s.
3129 138 Subst ances, whi ch i n cont act
gases, l i qui d, corrosi ve,
n. o. s.
3129 138 Wat er-react i ve l i qui d,
3129 138 Water-reactive substances,
l i qui d, corrosi ve, n.o.s.
wi th water emi t fl ammabl e
gases, l i qui d, poi sonous,
n.o.s.
gases, l i qui d, t oxi c, n. o. s.
3130 139 Wat er-react i ve l i qui d,
3130 139 Wat er-react i ve l i qui d, t oxi c,
n. o. s.
l i qui d, poi sonous, n. o. s.
l i qui d, t oxi c, n. o. s.
gases, sol i d, corrosi ve, n. o. s.
3131 138 Wat er-react i ve sol i d, corrosi ve,
n. o. s.
sol i d, corrosi ve, n. o. s.
gases, sol i d, f l ammabl e,
n. o. s.
3132 138 Water-reacti ve sol i d, fl ammabl e,
n.o.s.
3132 138 Water-reactive substances,
sol i d, fl ammabl e, n.o.s.
gases, sol i d, oxi di zi ng, n.o.s.
3133 138 Wat er-react i ve sol i d, oxi di zi ng,
n. o. s.
sol i d, oxi di zi ng, n. o. s.
No. No.
No. No.
Page 80
gases, sol i d, poi sonous, n.o.s.
gases, sol i d, t oxi c, n. o. s.
3134 139 Wat er-react i ve sol i d,
3134 139 Water-reactive solid, toxic, n.o.s.
sol i d, poi sonous, n. o. s.
sol i d, t oxi c, n. o. s.
3135 138 Substances, which in contact with
water emit flammable gases,
solid, self-heating, n.o.s.
3135 138 Wat er-react i ve sol i d, sel f -
heat i ng, n. o. s.
sol i d, sel f -heat i ng, n. o. s.
3136 120 Tri f l uoromet hane, ref ri gerat ed
l i qui d
3137 140 Oxi di zi ng sol i d, fl ammabl e,
n. o. s.
3138 115 Acetyl ene, Ethyl ene and
Propyl ene i n mi xture,
ref ri gerat ed l i qui d cont ai ni ng
at l east 71.5% Ethyl ene wi th
not more than 22.5%
Acet yl ene and not more t han
6% Pr opyl ene
3138 115 Et hyl ene, Acet yl ene and
ref ri gerat ed l i qui d cont ai ni ng
not more than 22.5%
Acet yl ene and not more t han
6% Pr opyl ene
3138 115 Propyl ene, Ethyl ene and
Acetyl ene i n mi xture,
refrigerated liquid containing at
l east 71.5% Ethyl ene wi th not
more than 22.5% Acetyl ene
and not more than 6%
Propyl ene
3139 140 Oxi di zi ng l i qui d, n. o. s.
n. o. s.
3140 151 Al kal oi ds, l i qui d, n. o. s.
(poi sonous)
3140 151 Al kal oi d sal ts, l i qui d, n.o.s.
(poi sonous)
l i qui d, n. o. s.
3142 151 Di si nf ect ant , l i qui d, poi sonous,
n. o. s.
3142 151 Di si nf ect ant , l i qui d, t oxi c, n. o. s.
3142 151 Di si nf ect ant s, l i qui d, n. o. s.
(poi sonous)
3143 151 Dye, sol i d, poi sonous, n. o. s.
3143 151 Dye, sol i d, t oxi c, n. o. s.
3143 151 Dye i nt ermedi at e, sol i d,
3143 151 Dye i ntermedi ate, sol i d, toxi c,
n. o. s.
3144 151 Ni coti ne compound, l i qui d, n.o.s.
3144 151 Ni coti ne preparati on, l i qui d,
n. o. s.
3145 153 Al kyl phenol s, l i qui d, n. o. s.
homol ogues)
3146 153 Organot i n compound, sol i d,
n.o.s.
3147 154 Dye, sol i d, corrosi ve, n. o. s.
3147 154 Dye i ntermedi ate, sol i d,
No. No.
No. No.
Page 81
gases, l i qui d, n. o. s.
3148 138 Wat er-react i ve l i qui d, n. o. s.
l i qui d, n. o. s.
3149 140 Hydrogen peroxi de and
Peroxyacet i c aci d mi xt ure,
wi t h aci d(s), wat er and not
more t han 5% Peroxyacet i c
aci d, st abi l i zed
3150 115 Devi ces, smal l , hydrocarbon
gas powered, wi t h rel ease
devi ce
3150 115 Hydrocarbon gas ref i l l s f or
smal l devi ces, wi t h rel ease
devi ce
3151 171 Pol yhal ogenat ed bi phenyl s,
l i qui d
3151 171 Pol yhal ogenat ed t erphenyl s,
l i qui d
3152 171 Pol yhal ogenat ed bi phenyl s,
sol i d
3152 171 Pol yhal ogenat ed t erphenyl s,
sol i d
3153 115 Perfl uoromethyl vi nyl ether
3153 115 Perfl uoro(methyl vi nyl ether)
3154 115 Perfl uoroethyl vi nyl ether
3154 115 Perfl uoro(ethyl vi nyl ether)
3155 154 Pentachlorophenol
3156 122 Compressed gas, oxi di zi ng,
n. o. s.
3157 122 Li quef i ed gas, oxi di zi ng, n. o. s.
3158 120 Gas, ref ri gerat ed l i qui d, n. o. s.
3159 126 Ref ri gerant gas R-134a
3159 126 1, 1, 1, 2-Tet raf l uoroet hane
3160 119 Liquefied gas, poisonous,
fl ammabl e, n.o.s.
Hazard Zone A)
3160 119 Li quefi ed gas, poi sonous,
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
3160 119 Li quef i ed gas, t oxi c, f l ammabl e,
n. o. s.
Zone A)
Zone B)
Zone C)
3160 119 Li quefi ed gas, toxi c, fl ammabl e,
Zone D)
3161 115 Li quefi ed gas, fl ammabl e, n.o.s.
3162 123 Li quefi ed gas, poi sonous, n.o.s.
3162 123 Li quefi ed gas, poi sonous, n.o.s.
(Inhal ati on Hazard Zone D)
No. No.
No. No.
Page 82
3162 123 Li quefi ed gas, toxi c, n.o.s.
3162 123 Li quefi ed gas, toxi c, n.o.s.
3163 126 Li quef i ed gas, n. o. s.
3164 126 Arti cl es, pressuri zed, hydraul i c
(cont ai ni ng non-f l ammabl e
gas)
3164 126 Art i cl es, pressuri zed,
pneumat i c (cont ai ni ng non-
f l ammabl e gas)
3165 131 Ai rcraf t hydraul i c power uni t
f uel t ank
3166 128 Engi nes, i nt ernal combust i on,
f l ammabl e gas powered
f l ammabl e l i qui d powered
i ncl udi ng when f i t t ed i n
machi nery or vehi cl es
3166 128 Vehi cl e, fl ammabl e gas powered
3166 128 Vehi cl e, fl ammabl e l i qui d
powered
3167 115 Gas sampl e, non-pressuri zed,
f l ammabl e, n. o. s. , not
poi sonous, f l ammabl e, n. o. s. ,
not ref ri gerat ed l i qui d
t oxi c, f l ammabl e, n. o. s. , not
poi sonous, n.o.s., not
refrigerated liquid
t oxi c, n. o. s. , not ref ri gerat ed
l i qui d
3170 138 Al umi num dross
3170 138 Al umi num processi ng
by-product s
3170 138 Al umi num remel t i ng by-
product s
3170 138 Al umi num smel t i ng by-product s
3171 154 Bat t ery-powered equi pment
(wet bat t ery)
3171 154 Bat t ery-powered vehi cl e (wet
bat t ery)
3171 154 Wheel chai r, el ect ri c, wi t h
bat t eri es
3172 153 Toxi ns, ext ract ed f rom l i vi ng
sources, l i qui d, n. o. s.
sources, n. o. s.
sources, sol i d, n. o. s.
3174 135 Ti t ani um di sul f i de
3174 135 Ti t ani um di sul phi de
3175 133 Solids containing flammable
l i qui d, n.o.s.
3176 133 Fl ammabl e sol i d, organi c,
mol t en, n. o. s.
3178 133 Flammable solid, inorganic, n.o.s.
3178 133 Smokel ess powder f or smal l
arms
i norgani c, n. o. s.
3179 134 Fl ammabl e sol i d, t oxi c,
No. No.
No. No.
Page 83
3180 134 Fl ammabl e sol i d, corrosi ve,
i norgani c, n.o.s.
3180 134 Fl ammabl e sol i d, i norgani c,
3181 133 Met al sal t s of organi c
compounds, f l ammabl e,
n. o. s.
3182 170 Metal hydri des, fl ammabl e,
n. o. s.
3183 135 Self-heating liquid, organic,
n.o.s.
3184 136 Self-heating liquid, poisonous,
organi c, n. o. s.
3184 136 Sel f -heat i ng l i qui d, t oxi c,
organi c, n. o. s.
3185 136 Sel f -heat i ng l i qui d, corrosi ve,
organi c, n. o. s.
3186 135 Sel f -heat i ng l i qui d, i norgani c,
n. o. s.
3187 136 Sel f -heat i ng l i qui d, poi sonous,
3187 136 Sel f -heat i ng l i qui d, t oxi c,
3188 136 Sel f -heat i ng l i qui d, corrosi ve,
3189 135 Metal powder, self-heating, n.o.s.
3189 135 Self-heating metal powders, n.o.s.
3190 135 Sel f-heati ng sol i d, i norgani c,
n. o. s.
3191 136 Sel f -heat i ng sol i d, i norgani c,
3191 136 Sel f -heat i ng sol i d, i norgani c,
t oxi c, n. o. s.
3191 136 Sel f -heat i ng sol i d, poi sonous,
3191 136 Sel f -heat i ng sol i d, t oxi c,
3192 136 Sel f-heati ng sol i d, corrosi ve,
i norgani c, n.o.s.
3194 135 Pyrophoric liquid, inorganic, n.o.s.
3200 135 Pyrophoric solid, inorganic, n.o.s.
3203 135 Pyrophoric organometallic
compound, n. o. s.
3203 135 Pyrophori c organomet al l i c
compound, wat er-react i ve,
n. o. s.
3205 135 Al kal i ne earth metal al cohol ates,
n.o.s.
3206 136 Al kal i metal al cohol ates, sel f-
heat i ng, corrosi ve, n. o. s.
3207 138 Or ganomet al l i c compound,
wat er - r eact i ve, f l ammabl e,
n. o. s.
3207 138 Organomet al l i c compound
di spersi on, wat er-react i ve,
3207 138 Organomet al l i c compound
sol ut i on, wat er-react i ve,
3208 138 Met al l i c subst ance, wat er-
react i ve, n. o. s.
3209 138 Met al l i c subst ance, wat er-
react i ve, sel f -heat i ng, n. o. s.
3210 140 Chl orat es, i norgani c, aqueous
sol ut i on, n. o. s.
3211 140 Perchl orates, i norgani c, aqueous
sol uti on, n.o.s.
3212 140 Hypochl ori tes, i norgani c, n.o.s.
3213 140 Bromates, i norgani c, aqueous
3214 140 Permanganat es, i norgani c,
aqueous sol ut i on, n. o. s.
3215 140 Persul f at es, i norgani c, n. o. s.
3215 140 Persul phat es, i norgani c, n. o. s.
No. No.
No. No.
Page 84
3216 140 Persul fates, i norgani c, aqueous
sol uti on, n.o.s.
3216 140 Persul phates, i norgani c, aqueous
sol uti on, n.o.s.
3217 140 Percarbonates, i norgani c, n.o.s.
3218 140 Ni trates, i norgani c, aqueous
3219 140 Ni t ri t es, i norgani c, aqueous
3220 126 Pent af l uoroet hane
3221 149 Sel f -react i ve l i qui d t ype B
3222 149 Sel f -react i ve sol i d t ype B
3223 149 Sel f -react i ve l i qui d t ype C
3224 149 Sel f -react i ve sol i d t ype C
3225 149 Sel f -react i ve l i qui d t ype D
3226 149 Sel f -react i ve sol i d t ype D
3227 149 Sel f -react i ve l i qui d t ype E
3228 149 Sel f -react i ve sol i d t ype E
3229 149 Sel f -react i ve l i qui d t ype F
3230 149 Sel f -react i ve sol i d t ype F
3231 150 Sel f-reacti ve l i qui d type B,
3232 150 Sel f -react i ve sol i d t ype B,
3233 150 Sel f-reacti ve l i qui d type C,
3234 150 Sel f -react i ve sol i d t ype C,
3235 150 Sel f -react i ve l i qui d t ype D,
3236 150 Sel f -react i ve sol i d t ype D,
3237 150 Sel f-reacti ve l i qui d type E,
3238 150 Sel f-reacti ve sol i d type E,
3239 150 Sel f -react i ve l i qui d t ype F,
3240 150 Sel f -react i ve sol i d t ype F,
3241 133 2-Bromo-2-ni t ropropane-1, 3-
di ol
3242 149 Azodi carbonami de
3243 151 Solids containing poisonous
l i qui d, n. o. s.
3243 151 Sol i ds cont ai ni ng t oxi c l i qui d,
n. o. s.
3244 154 Sol i ds cont ai ni ng corrosi ve
l i qui d, n. o. s.
3245 171 Genet i cal l y modi f i ed mi cro-
organi sms
3246 156 Met hanesul f onyl chl ori de
3246 156 Met hanesul phonyl chl ori de
3247 140 Sodi um peroxoborat e,
anhydrous
3248 131 Medi ci ne, l i qui d, f l ammabl e,
3248 131 Medi ci ne, l i qui d, f l ammabl e,
t oxi c, n. o. s.
3249 151 Medicine, solid, poisonous, n.o.s.
3249 151 Medi ci ne, sol i d, t oxi c, n. o. s.
3250 153 Chl oroaceti c aci d, mol ten
3251 133 Isosorbide-5-mononitrate
3252 115 Difluoromethane
3253 154 Di sodi um tri oxosi l i cate
3253 154 Di sodi um tri oxosi l i cate,
pent ahydrat e
3254 135 Tri but yl phosphane
3254 135 Tri but yl phosphi ne
No. No.
No. No.
Page 85
3255 135 t ert -But yl hypochl ori t e
3256 128 Elevated temperature liquid,
f l ammabl e, n. o. s. , wi t h f l ash
poi nt above 37. 8C (100F),
at or above i t s f l ash poi nt
3256 128 El evat ed t emperat ure l i qui d,
f l ammabl e, n. o. s. , wi t h f l ash
at or above i t s f l ash poi nt
3257 128 Elevated temperature liquid,
n. o. s. , at or above 100C
(212F), and bel ow i ts fl ash
poi nt
3258 171 El evat ed t emperat ure sol i d,
(464F)
3259 154 Ami nes, sol i d, corrosi ve, n. o. s.
3259 154 Polyamines, solid, corrosive,
n.o.s.
3260 154 Corrosi ve sol i d, aci di c,
3261 154 Corrosi ve sol i d, aci di c, organi c,
n. o. s.
3262 154 Corrosi ve sol i d, basi c,
3263 154 Corrosi ve sol i d, basi c, organi c,
n. o. s.
3264 154 Corrosi ve l i qui d, aci di c,
i norgani c, n.o.s.
3265 153 Corrosi ve l i qui d, aci di c, organi c,
n.o.s.
3266 154 Corrosi ve l i qui d, basi c,
3267 153 Corrosi ve l i qui d, basi c, organi c,
n. o. s.
3268 171 Ai r bag i nf l at ors
3268 171 Ai r bag i nf l at ors, pyrot echni c
3268 171 Ai r bag modul es
3268 171 Ai r bag modul es, pyrotechni c
3268 171 Seat-belt modules
3268 171 Seat-belt pre-tensioners
3268 171 Seat-belt pre-tensioners,
pyrot echni c
3269 128 Pol yest er resi n ki t
3270 133 Ni t rocel l ul ose membrane f i l t ers
3271 127 Et hers, n. o. s.
3272 127 Est ers, n. o. s.
3273 131 Ni t ri l es, f l ammabl e, poi sonous,
n. o. s.
3273 131 Ni t ri l es, f l ammabl e, t oxi c, n. o. s.
3274 132 Al cohol at es sol ut i on, n. o. s. , i n
al cohol
3275 131 Ni t ri l es, poi sonous, f l ammabl e,
n. o. s.
3275 131 Ni t ri l es, t oxi c, f l ammabl e, n. o. s.
3276 151 Ni t ri l es, poi sonous, l i qui d,
n. o. s.
3276 151 Ni t ri l es, poi sonous, n. o. s.
3276 151 Ni t ri l es, t oxi c, l i qui d, n. o. s
3276 151 Ni t ri l es, t oxi c, n. o. s.
3277 154 Chl orof ormat es, poi sonous,
3277 154 Chl oroformates, toxi c, corrosi ve,
n.o.s.
3278 151 Organophosphorus compound,
poi sonous, l i qui d, n. o. s.
t oxi c, l i qui d, n. o. s.
t oxi c, n. o. s.
poi sonous, fl ammabl e, n.o.s.
No. No.
No. No.
Page 86
t oxi c, f l ammabl e, n. o. s.
3280 151 Organoarseni c compound,
l i qui d, n. o. s.
3280 151 Organoarseni c compound, n.o.s.
3281 151 Metal carbonyl s, l i qui d, n.o.s.
3281 151 Met al carbonyl s, n. o. s.
3282 151 Organometallic compound,
poi sonous, l i qui d, n. o. s.
3282 151 Organomet al l i c compound,
t oxi c, n. o. s.
3283 151 Sel eni um compound, n. o. s.
3283 151 Sel eni um compound, sol i d,
n. o. s.
3284 151 Tel l uri um compound, n. o. s.
3285 151 Vanadi um compound, n. o. s.
3286 131 Fl ammabl e l i qui d, poi sonous,
3286 131 Fl ammabl e l i qui d, t oxi c,
3287 151 Poi sonous l i qui d, i norgani c,
n. o. s.
Zone A)
Zone B)
3287 151 Toxi c l i qui d, i norgani c, n. o. s.
3287 151 Toxi c l i qui d, i norgani c, n. o. s.
(Inhal ati on Hazard Zone A)
3287 151 Toxi c l i qui d, i norgani c, n.o.s.
3288 151 Poi sonous sol i d, i norgani c,
n. o. s.
3288 151 Toxi c sol i d, i norgani c, n. o. s.
i norgani c, n. o. s. (I nhal at i on
Hazard Zone A)
Hazard Zone B)
3289 154 Toxi c l i qui d, corrosi ve,
Hazard Zone A)
Hazard Zone B)
3290 154 Poi sonous sol i d, corrosi ve,
3290 154 Toxi c sol i d, corrosi ve,
3291 158 (Bi o)Medi cal wast e, n. o. s.
3291 158 Cl i ni cal wast e, unspeci f i ed,
n.o.s.
3291 158 Medi cal wast e, n. o. s.
3291 158 Regul ated medi cal waste, n.o.s.
3292 138 Batteries, containing Sodium
3292 138 Cel l s, contai ni ng Sodi um
3293 152 Hydrazi ne, aqueous sol uti on,
Hydrazi ne
3294 131 Hydrogen cyani de, sol ut i on i n
al cohol , wi t h not more t han
3295 128 Hydrocarbons, l i qui d, n.o.s.
No. No.
No. No.
Page 87
3296 126 Heptafluoropropane
3297 126 Chlorotetrafluoroethane and
not more t han 8. 8% Et hyl ene
oxi de
Chlorotetrafluoroethane
mi xture, wi th not more than
8.8% Ethyl ene oxi de
Pent af l uoroet hane mi xt ure,
Et hyl ene oxi de
3298 126 Pent af l uoroet hane and
not more t han 7. 9% Et hyl ene
oxi de
3299 126 Et hyl ene oxi de and
Tet raf l uoroet hane mi xt ure,
Et hyl ene oxi de
3299 126 Tet raf l uoroet hane and Et hyl ene
oxi de mi xt ure, wi t h not more
t han 5. 6% Et hyl ene oxi de
3300 119P Carbon di oxi de and Ethyl ene
oxi de mi xt ure, wi t h more t han
3300 119P Ethyl ene oxi de and Carbon
di oxi de mi xture, wi th more
3301 136 Corrosi ve l i qui d, sel f-heati ng,
n. o. s.
3302 152 2-Di met hyl ami noet hyl acryl at e
oxi di zi ng, n. o. s. (I nhal at i on
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
oxi di zi ng, n.o.s. (Inhal ati on
Hazard Zone D)
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
corrosi ve, n.o.s. (Inhal ati on
Hazard Zone A)
Hazard Zone B)
corrosi ve, n. o. s. (I nhal at i on
Hazard Zone C)
Hazard Zone D)
No. No.
No. No.
Page 88
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
fl ammabl e, corrosi ve, n.o.s.
oxi di zi ng, corrosi ve, n. o. s.
(Inhal ati on Hazard Zone B)
(Inhal ati on Hazard Zone C)
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
No. No.
No. No.
Page 89
Hazard Zone D)
3307 124 Li quef i ed gas, t oxi c, oxi di zi ng,
n. o. s.
3307 124 Li quefi ed gas, toxi c, oxi di zi ng,
Zone A)
Zone B)
Zone C)
Zone D)
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
3308 123 Li quef i ed gas, t oxi c, corrosi ve,
n. o. s.
Zone A)
Zone B)
3308 123 Li quefi ed gas, toxi c, corrosi ve,
Zone C)
Zone D)
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
No. No.
No. No.
Page 90
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
3311 122 Gas, ref ri gerat ed l i qui d,
3312 115 Gas, ref ri gerat ed l i qui d,
3313 135 Organi c pi gment s, sel f -heat i ng
3314 171 Pl asti c mol di ng compound
3314 171 Pl asti cs moul di ng compound
3315 151 Chemi cal sampl e, poi sonous
liquid
sol i d
3315 151 Chemi cal sampl e, t oxi c
3315 151 Chemi cal sampl e, toxi c l i qui d
3315 151 Chemi cal sampl e, t oxi c sol i d
3316 171 Chemi cal ki t
3316 171 Fi rst ai d ki t
3317 113 2-Amino-4,6-dinitrophenol,
wat er
3318 125 Ammoni a sol uti on, wi th more
t han 50% Ammoni a
3319 113 Ni t rogl yceri n mi xt ure,
desensi t i zed, sol i d, n. o. s. ,
wi t h more t han 2% but not
more t han 10% Ni t rogl yceri n
3319 113 Ni t rogl yceri n mi xt ure wi t h more
10% Ni t rogl yceri n,
desensi t i zed
3320 157 Sodi um borohydri de and
Sodi um hydroxi de sol ut i on,
Sodi um borohydri de and not
more t han 40% Sodi um
hydroxi de
3321 162 Radi oact i ve mat eri al , l ow
speci f i c act i vi t y (LSA-I I )
3322 162 Radi oacti ve materi al , l ow
speci f i c act i vi t y (LSA-I I I )
3323 163 Radi oact i ve mat eri al , Type C
package
3324 165 Radioactive material, low specific
acti vi ty (LSA-II), fi ssi l e
3325 165 Radi oacti ve materi al , l ow speci fi c
acti vi ty (LSA-III), fi ssi l e
3326 165 Radi oacti ve materi al , surface
contaminated objects (SCO-I),
fissile
3326 165 Radioactive material, surface
contami nated obj ects (SCO-II),
fi ssi l e
3327 165 Radi oact i ve mat eri al , Type A
package, fi ssi l e
No. No.
No. No.
Page 91
3328 165 Radi oacti ve materi al , Type B(U)
package, f i ssi l e
3329 165 Radi oact i ve mat eri al , Type
B(M) package, f i ssi l e
3330 165 Radi oact i ve mat eri al , Type C
package, fi ssi l e
3331 165 Radioactive material, transported
under special arrangement,
fissile
3332 164 Radi oacti ve materi al , Type A
package, speci al f orm
3333 165 Radi oacti ve materi al , Type A
package, speci al f orm, f i ssi l e
3334 171 Avi at i on regul at ed l i qui d, n. o. s.
3334 171 Sel f -def ense spray, non-
pressuri zed
3335 171 Avi ati on regul ated sol i d, n.o.s.
3336 130 Mercapt ans, l i qui d, f l ammabl e,
n. o. s.
3337 126 Ref ri gerant gas R-404A
3338 126 Refrigerant gas R-407A
3339 126 Refrigerant gas R-407B
3340 126 Refri gerant gas R-407C
3341 135 Thiourea dioxide
3342 135 Xanthates
3343 113 Ni trogl yceri n mi xture,
desensi t i zed, l i qui d,
f l ammabl e, n. o. s. , wi t h not
more than 30% Ni trogl yceri n
3344 113 Pentaerythrite tetranitrate
mi xt ure, desensi t i zed, sol i d,
n. o. s. , wi t h more t han 10%
but not more t han 20% PETN
3345 153 Phenoxyacet i c aci d deri vat i ve
pesti ci de, sol i d, poi sonous
3345 153 Phenoxyaceti c aci d deri vati ve
pest i ci de, sol i d, t oxi c
pest i ci de, l i qui d, f l ammabl e,
poisonous
3346 131 Phenoxyaceti c aci d deri vati ve
pest i ci de, l i qui d, f l ammabl e,
t oxi c
pest i ci de, l i qui d, poi sonous,
f l ammabl e
pest i ci de, l i qui d, t oxi c,
f l ammabl e
pest i ci de, l i qui d, poi sonous
pest i ci de, l i qui d, t oxi c
3349 151 Pyret hroi d pest i ci de, sol i d,
poi sonous
3349 151 Pyret hroi d pest i ci de, sol i d,
t oxi c
3350 131 Pyrethroi d pesti ci de, l i qui d,
3350 131 Pyret hroi d pest i ci de, l i qui d,
3351 131 Pyrethroi d pesti ci de, l i qui d,
poisonous
3352 151 Pyrethroid pesticide, liquid, toxic
3353 126 Air bag inflators, compressed gas
3353 126 Air bag modules, compressed gas
3353 126 Seat-belt pre-tensioners,
compressed gas
3354 115 I nsecticide gas, flammable, n.o.s.
No. No.
No. No.
Page 92
3355 119 Insecti ci de gas, poi sonous,
fl ammabl e, n.o.s.
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
3355 119 I nsect i ci de gas, t oxi c,
Hazard Zone A)
3355 119 Insecti ci de gas, toxi c,
Hazard Zone B)
Hazard Zone C)
3355 119 Insecti ci de gas, toxi c,
Hazard Zone D)
3356 140 Oxygen generator, chemi cal
3356 140 Oxygen generator, chemi cal ,
spent
3357 113 Ni trogl yceri n mi xture,
desensi t i zed, l i qui d, n. o. s. ,
Ni t rogl yceri n
cont ai ni ng f l ammabl e, non-
t oxi c, l i quef i ed gas
3359 171 Fumigated unit
3360 133 Fi bers, vegetabl e, dry
3360 133 Fi bres, vegetabl e, dry
3361 156 Chl orosi l anes, poi sonous,
3361 156 Chl orosi l anes, t oxi c, corrosi ve,
n. o. s.
3362 155 Chl orosi l anes, poi sonous,
3362 155 Chl orosi l anes, t oxi c, corrosi ve,
3363 171 Dangerous goods i n apparat us
3363 171 Dangerous goods i n machi nery
3364 113 Pi cri c aci d, wet t ed wi t h not l ess
t han 10% wat er
3364 113 Tri ni t rophenol , wet t ed wi t h not
3365 113 Pi cryl chl ori de, wet t ed wi t h not
3365 113 Trinitrochlorobenzene, wetted
3366 113 TNT, wet t ed wi t h not l ess t han
10% wat er
3366 113 Tri ni t rot ol uene, wet t ed wi t h not
3367 113 Tri ni t robenzene, wet t ed wi t h not
3368 113 Tri ni t robenzoi c aci d, wet t ed
3369 113 Sodium dinitro-o-cresolate,
wat er
3370 113 Urea ni t rat e, wet t ed wi t h not
3371 129 2-Met hyl but anal
sol i d, wat er-react i ve,
fl ammabl e, n.o.s.
No. No.
No. No.
Page 93
3373 158 Cl i ni cal speci mens
3373 158 Di agnosti c speci mens
3374 116 Acetyl ene, sol vent free
3375 140 Ammonium nitrate emulsion
3375 140 Ammonium nitrate gel
3375 140 Ammonium nitrate suspension
3376 113 4-Ni trophenyl hydrazi ne, wi th not
3377 140 Sodium perborate monohydrate
3378 140 Sodi um carbonate peroxyhydrate
3379 128 Desensi ti zed expl osi ve, l i qui d,
n. o. s.
3380 133 Desensi t i zed expl osi ve, sol i d,
n. o. s.
3381 151 Poi sonous by i nhal at i on l i qui d,
Zone A)
3381 151 Toxi c by i nhal ati on l i qui d, n.o.s.
Zone B)
3382 151 Toxi c by i nhal at i on l i qui d, n. o. s.
3383 131 Poi sonous by i nhal ati on l i qui d,
Hazard Zone A)
3383 131 Toxi c by i nhal at i on l i qui d,
Hazard Zone A)
Hazard Zone B)
Hazard Zone B)
wat er-react i ve, n. o. s.
3385 139 Toxi c by i nhal ati on l i qui d, water-
reacti ve, n.o.s. (Inhal ati on
Hazard Zone A)
wat er-react i ve, n. o. s.
water-reacti ve, n.o.s.
Hazard Zone A)
Hazard Zone A)
Hazard Zone B)
3388 142 Toxi c by i nhal ati on l i qui d,
Hazard Zone B)
Hazard Zone A)
Hazard Zone A)
Hazard Zone B)
Hazard Zone B)
3391 135 Organomet al l i c subst ance,
sol i d, pyrophori c
3392 135 Organomet al l i c subst ance,
l i qui d, pyrophori c
No. No.
No. No.
Page 94
3393 135 Organometal l i c substance, sol i d,
pyrophori c, water-reacti ve
3394 135 Organometal l i c substance, l i qui d,
pyrophori c, water-reacti ve
water-reacti ve
water-reactive, flammable
water-reactive, self-heating
water-reacti ve
water-reactive, flammable
self-heating
3401 138 Al kal i metal amal gam, sol i d
3402 138 Al kal i ne earth metal amal gam,
sol i d
3403 138 Potassi um, metal al l oys, sol i d
3404 138 Potassi um sodi um al l oys, sol i d
3404 138 Sodi um potassi um al l oys, sol i d
3405 141 Barium chlorate, solution
3406 141 Barium perchlorate, solution
mi xture, sol uti on
mi xture, sol uti on
3408 141 Lead perchlorate, solution
3409 152 Chloronitrobenzenes, liquid
hydrochl ori de, sol ut i on
3411 153 bet a-Napht hyl ami ne, sol ut i on
3411 153 Napht hyl ami ne (bet a), sol ut i on
3413 157 Pot assi um cyani de, sol ut i on
3414 157 Sodi um cyani de, sol ut i on
3415 154 Sodium fluoride, solution
3416 153 Chloroacetophenone, liquid
3417 152 Xyl yl bromi de, sol i d
3418 151 2,4-Toluylenediamine, solution
3419 157 Boron trifluoride acetic acid
compl ex, sol i d
compl ex, sol i d
3421 154 Pot assi um hydrogen di f l uori de,
sol ut i on
3422 154 Pot assi um f l uori de, sol ut i on
hydroxi de, sol i d
3424 141 Ammoni um di ni t ro-o-cresol at e,
sol ut i on
3425 156 Bromoaceti c aci d, sol i d
3426 153P Acryl ami de, sol uti on
3427 153 Chl orobenzyl chl ori des, sol i d
3428 156 3-Chl oro-4-methyl phenyl
i socyanat e, sol i d
3429 153 Chl orot ol ui di nes, l i qui d
3430 153 Xyl enol s, l i qui d
3431 152 Nitrobenzotrifluorides, solid
3432 171 Pol ychl ori nated bi phenyl s, sol i d
3433 135 Li thi um al kyl s, sol i d
3434 153 Ni trocresol s, l i qui d
3435 153 Hydroqui none, sol uti on
3436 151 Hexafl uoroacetone hydrate, sol i d
3437 152 Chl orocresol s, sol i d
3438 153 al pha-Methyl benzyl al cohol ,
sol i d
3439 151 Ni t ri l es, poi sonous, sol i d, n. o. s.
3439 151 Ni t ri l es, t oxi c, sol i d, n. o. s.
3440 151 Sel eni um compound, l i qui d,
n.o.s.
No. No.
No. No.
Page 95
3441 153 Chlorodinitrobenzenes, solid
3442 153 Di chl oroani l i nes, sol i d
3443 152 Dinitrobenzenes, solid
3444 151 Ni coti ne hydrochl ori de, sol i d
3445 151 Ni coti ne sul fate, sol i d
3445 151 Ni coti ne sul phate, sol i d
3446 152 Ni trotol uenes, sol i d
3447 152 Ni t roxyl enes, sol i d
3448 159 Tear gas substance, sol i d, n.o.s.
3449 159 Bromobenzyl cyani des, sol i d
3450 151 Di phenyl chl oroarsi ne, sol i d
3451 153 Toluidines, solid
3452 153 Xyl i di nes, sol i d
3453 154 Phosphori c aci d, sol i d
3454 152 Dinitrotoluenes, solid
3455 153 Cresol s, sol i d
3456 157 Ni trosyl sul furi c aci d, sol i d
3456 157 Ni trosyl sul phuri c aci d, sol i d
3457 152 Chloronitrotoluenes, solid
3458 152 Ni troani sol es, sol i d
3459 152 Nitrobromobenzenes, solid
3460 153 N-Ethyl benzyl tol ui di nes, sol i d
3461 135 Al umi num al kyl hal i des, sol i d
3462 153 Toxi ns, extracted from l i vi ng
poi sonous, sol i d, n. o. s.
t oxi c, sol i d, n. o. s.
3465 151 Organoarseni c compound,
sol i d, n. o. s.
3466 151 Met al carbonyl s, sol i d, n. o. s.
3467 151 Organometallic compound,
poi sonous, sol i d, n.o.s.
3467 151 Organometal l i c compound, toxi c,
sol i d, n. o. s.
3468 115 Hydrogen, i n a metal hydri de
st orage syst em
8000 171 Consumer commodi t y
8013 171 Gas generat or assembl i es
8038 171 Heat produci ng art i cl e
9035 123 Gas i dent i f i cat i on set
9163 171 Zi rconi um sul f at e
9163 171 Zi rconi um sul phat e
9191 143 Chl ori ne di oxi de, hydrate,
f rozen
9192 167 Fl uori ne, ref ri gerat ed l i qui d
9195 135 Met al al kyl , sol ut i on, n. o. s.
9202 168 Carbon monoxi de, ref ri gerat ed
l i qui d (cryogeni c l i qui d)
9206 137 Methyl phosphoni c di chl ori de
9260 169 Aluminum, molten
9263 156 Chl oropi val oyl chl ori de
9264 151 3,5-Dichloro-2,4,6-
trifluoropyridine
9269 132 Trimethoxysilane
9275 158 Regul ated medi cal waste
9279 115 Hydrogen, absorbed i n metal
hydri de
Note: If an entry is highlighted in either the yellow-bordered or blue-bordered pages AND THERE
IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances
(green-bordered pages) and look up the ID number and name of material to obtain initial
isolation and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED,
go directly to the appropriate guide (orange-bordered pages) and use the evacuation
information shown under PUBLIC SAFETY.
Name of Material Guide ID
No. No.
No. No.
Page 97
AC 117 1051
Accumul ators, pressuri zed, 126 1956
pneumati c or hydraul i c
Acetal 127 1088
Acetal dehyde 129 1089
Acetaldehyde ammonia 171 1841
Acetal dehyde oxi me 129 2332
Aceti c aci d, gl aci al 132 2789
Aceti c aci d, sol uti on, more than 153 2790
10% but not more than 80%
acid
Aceti c aci d, sol uti on, more than 132 2789
80% aci d
Aceti c anhydri de 137 1715
Acetone 127 1090
Acetone cyanohydri n, stabi l i zed 155 1541
Acetone oi l s 127 1091
Acetonitrile 127 1648
Acetyl bromi de 156 1716
Acetyl chl ori de 155 1717
Acetyl ene 116 1001
Acetyl ene, di ssol ved 116 1001
Acetyl ene, sol vent free 116 3374
Acetyl ene, Ethyl ene and 115 3138
refrigerated liquid containing
not more than 22.5%
Acetyl ene and not more than
6% Pr opyl ene
Acetylene tetrabromide 159 2504
Acetyl i odi de 156 1898
Acetyl methyl carbi nol 127 2621
Aci d, sl udge 153 1906
Aci d butyl phosphate 153 1718
Acridine 153 2713
Acrolein, inhibited 131P 1092
Acrol ei n, stabi l i zed 131P 1092
Acrol ei n di mer, stabi l i zed 129P 2607
Acryl ami de 153P 2074
Acryl ami de, sol i d 153P 2074
Acryl ami de, sol uti on 153P 3426
Acryl i c aci d, i nhi bi ted 132P 2218
Acryl i c aci d, st abi l i zed 132P 2218
Acryl oni tri l e, i nhi bi ted 131P 1093
Acryl oni tri l e, stabi l i zed 131P 1093
Adamsite 154 1698
Adhesi ves (fl ammabl e) 128 1133
Adiponitrile 153 2205
Aerosol di spensers 126 1950
Aerosol s 126 1950
Ai r, compressed 122 1002
Ai r, refri gerated l i qui d 122 1003
Ai r, refri gerated l i qui d 122 1003
(cryogeni c l i qui d), non-
pressurized
Air bag inflators 171 3268
Ai r bag i nfl ators, compressed gas 126 3353
Ai r bag i nfl ators, pyrotechni c 171 3268
Ai r bag modul es 171 3268
Air bag modules, compressed gas 126 3353
Ai r bag modul es, pyrotechni c 171 3268
Ai rcraft hydraul i c power uni t fuel 131 3165
tank
Al cohol ates sol uti on, n.o.s., i n 132 3274
alcohol
Al cohol i c beverages 127 3065
Al cohol s, fl ammabl e, poi sonous, 131 1986
n.o.s.
Al cohol s, fl ammabl e, toxi c, 131 1986
n.o.s.
Al cohol s, n.o.s. 127 1987
Al cohol s, poi sonous, n.o.s. 131 1986
No. No.
No. No.
Page 98
Al cohol s, t oxi c, n. o. s. 131 1986
Al dehydes, fl ammabl e, 131 1988
poi sonous, n.o.s.
Al dehydes, fl ammabl e, toxi c, 131 1988
n.o.s.
Al dehydes, n. o. s. 129 1989
Al dehydes, poi sonous, n.o.s. 131 1988
Al dehydes, t oxi c, n. o. s. 131 1988
Al dol 153 2839
Al dri n, l i qui d 131 2762
Al dri n, sol i d 151 2761
Al kal i metal al cohol ates, sel f- 136 3206
heati ng, corrosi ve, n.o.s.
Al kal i metal al l oy, l i qui d, n.o.s. 138 1421
Al kal i metal amal gam 138 1389
Al kal i metal amal gam, l i qui d 138 1389
Al kal i metal amal gam, sol i d 138 1389
Al kal i metal amal gam, sol i d 138 3401
Al kal i metal ami des 139 1390
Al kal i metal di spersi on 138 1391
Alkaline earth metal 135 3205
al cohol ates, n.o.s.
Al kal i ne earth metal al l oy, n.o.s. 138 1393
Alkaline earth metal amalgam 138 1392
Al kal i ne earth metal amal gam, 138 1392
liquid
Al kal i ne earth metal amal gam, 138 3402
sol i d
Al kal i ne earth metal di spersi on 138 1391
Al kal oi ds, l i qui d, n.o.s. 151 3140
(poisonous)
Al kal oi ds, sol i d, n. o. s. 151 1544
(poisonous)
Al kal oi d sal ts, l i qui d, n.o.s. 151 3140
(poisonous)
Al kal oi d sal ts, sol i d, n.o.s. 151 1544
(poisonous)
Al kyl ami nes, n. o. s. 132 2733
Al kyl phenol s, l i qui d, n. o. s. 153 3145
homologues)
Al kyl phenol s, sol i d, n. o. s. 153 2430
homologues)
Al kyl sul f oni c aci ds, l i qui d, wi t h 153 2584
acid
Al kyl sul f oni c aci ds, l i qui d, wi t h 153 2586
not more than 5% free Sul furi c
acid
Al kyl sul f oni c aci ds, sol i d, wi t h 153 2583
acid
Al kyl sul f oni c aci ds, sol i d, wi t h 153 2585
acid
Al kyl sul furi c aci ds 156 2571
Al kyl sul phoni c aci ds, l i qui d, 153 2584
wi th more than 5% free
Sul phuri c aci d
Al kyl sul phoni c aci ds, l i qui d, 153 2586
Sul phuri c aci d
Al kyl sul phoni c aci ds, sol i d, wi t h 153 2583
acid
Al kyl sul phoni c aci ds, sol i d, wi t h 153 2585
Sul phuri c aci d
Al kyl sul phuri c aci ds 156 2571
Al l yl acetate 131 2333
No. No.
No. No.
Page 99
Al l yl al cohol 131 1098
Al l yl ami ne 131 2334
Al l yl bromi de 131 1099
Al l yl chl ori de 131 1100
Al l yl chl orocarbonate 155 1722
Al l yl chl oroformate 155 1722
Al l yl ethyl ether 131 2335
Al l yl formate 131 2336
Al l yl gl yci dyl et her 129 2219
Al l yl i odi de 132 1723
Al l yl i sothi ocyanate, i nhi bi ted 155 1545
Al l yl i sothi ocyanate, stabi l i zed 155 1545
Al l yl tri chl orosi l ane, stabi l i zed 155 1724
Aluminum, molten 169 9260
Al umi num al kyl hal i des 135 3052
Al umi num al kyl hal i des, l i qui d 135 3052
Al umi num al kyl hal i des, sol i d 135 3052
Al umi num al kyl hal i des, sol i d 135 3461
Al umi num al kyl hydri des 138 3076
Al umi num al kyl s 135 3051
Al umi num borohydri de 135 2870
Al umi num borohydri de i n 135 2870
devi ces
Al umi num bromi de, anhydrous 137 1725
Aluminum bromide, solution 154 2580
Aluminum carbide 138 1394
Al umi num chl ori de, anhydrous 137 1726
Al umi num chl ori de, sol uti on 154 2581
Al umi num dross 138 3170
Al umi num ferrosi l i con powder 139 1395
Al umi num hydri de 138 2463
Aluminum nitrate 140 1438
Aluminum phosphide 139 1397
Aluminum phosphide pesticide 157 3048
Al umi num powder, coated 170 1309
Al umi num powder, pyrophori c 135 1383
Al umi num powder, uncoated 138 1396
Al umi num processi ng 138 3170
by-products
Al umi num remel ti ng by-products 138 3170
Aluminum resinate 133 2715
Al umi num si l i con powder, 138 1398
uncoated
Al umi num smel ti ng by-products 138 3170
Ami nes, fl ammabl e, corrosi ve, 132 2733
n.o.s.
Ami nes, l i qui d, corrosi ve, 132 2734
fl ammabl e, n.o.s.
Ami nes, l i qui d, corrosi ve, n. o. s. 153 2735
Ami nes, sol i d, corrosi ve, n. o. s. 154 3259
2-Amino-4-chlorophenol 151 2673
2-Amino-5-diethylaminopentane 153 2946
2-Amino-4,6-dinitrophenol, 113 3317
wetted wi th not l ess than 20%
water
2-(2-Aminoethoxy)ethanol 154 3055
N-Ami noethyl pi perazi ne 153 2815
Aminophenols 152 2512
Ami nopyri di nes 153 2671
Ammoni a, anhydrous 125 1005
Ammoni a, anhydrous, l i quefi ed 125 1005
Ammoni a, sol uti on, wi th more 154 2672
than 10% but not more than
35% Ammoni a
Ammoni a, sol uti on, wi th more 125 2073
50% Ammoni a
Ammoni a sol uti on, wi th more 125 1005
than 50% Ammoni a
No. No.
No. No.
Page 100
Ammoni a sol uti on, wi th more 125 3318
than 50% Ammoni a
Ammonium arsenate 151 1546
Ammoni um bi fl uori de, sol i d 154 1727
Ammonium bifluoride, solution 154 2817
Ammonium dichromate 141 1439
Ammonium dinitro-o-cresolate 141 1843
Ammonium dinitro-o-cresolate, 141 1843
sol i d
Ammonium dinitro-o-cresolate, 141 3424
solution
Ammonium fluoride 154 2505
Ammonium fluorosilicate 151 2854
Ammonium hydrogendifluoride, 154 1727
sol i d
Ammonium hydrogendifluoride, 154 2817
solution
Ammoni um hydrogen fl uori de, 154 1727
sol i d
Ammoni um hydrogen fl uori de, 154 2817
solution
Ammonium hydrogen sulfate 154 2506
Ammonium hydrogen sulphate 154 2506
Ammoni um hydroxi de 154 2672
Ammoni um hydroxi de, wi th more 154 2672
35% Ammoni a
Ammonium metavanadate 154 2859
Ammonium nitrate, liquid (hot 140 2426
concentrated solution)
Ammoni um ni trate, wi th not more 140 1942
than 0.2% combusti bl e
substances
Ammonium nitrate emulsion 140 3375
Ammonium nitrate fertilizer, 140 2072
n.o.s.
Ammoni um ni trate ferti l i zer, wi th 140 2071
not more than 0.4%
combustible material
Ammonium nitrate fertilizers 140 2067
Ammonium nitrate fertilizers, 140 2069
wi th Ammoni um sul fate
wi th Ammoni um sul phate
wi th Cal ci um carbonate
wi th Phosphate or Potash
Ammonium nitrate-fuel oil 112
mi xtures
Ammonium nitrate gel 140 3375
Ammoni um ni trate mi xed 140 2069
fertilizers
Ammonium nitrate suspension 140 3375
Ammonium perchlorate 143 1442
Ammonium persulfate 140 1444
Ammonium persulphate 140 1444
Ammoni um pi crate, wetted wi th 113 1310
Ammoni um pol ysul fi de, sol uti on 154 2818
Ammoni um pol ysul phi de, 154 2818
solution
Ammoni um pol yvanadate 151 2861
Ammoni um si l i cofl uori de 151 2854
Ammonium sulfide, solution 132 2683
Ammoni um sul phi de, sol uti on 132 2683
Ammuni ti on, poi sonous, 151 2016
non-expl osi ve
Ammunition, tear-producing, 159 2017
non-expl osi ve
No. No.
No. No.
Page 101
Ammuni ti on, toxi c, 151 2016
non-expl osi ve
Amyl acetates 129 1104
Amyl aci d phosphate 153 2819
Amyl al cohol s 129 1105
Amyl ami nes 132 1106
Amyl but yrat es 130 2620
Amyl chl ori de 129 1107
n-Amyl ene 128 1108
Amyl formates 129 1109
Amyl mercaptan 130 1111
n-Amyl methyl ketone 127 1110
Amyl methyl ketone 127 1110
Amyl ni trate 140 1112
Amyl ni tri te 129 1113
Amyl tri chl orosi l ane 155 1728
Anhydrous ammoni a 125 1005
Anhydrous ammoni a, l i quefi ed 125 1005
Aniline 153 1547
Ani l i ne hydrochl ori de 153 1548
Ani si di nes 153 2431
Ani si di nes, l i qui d 153 2431
Ani si di nes, sol i d 153 2431
Anisole 128 2222
Ani soyl chl ori de 156 1729
Anti mony compound, i norgani c, 157 3141
l i qui d, n.o.s.
n.o.s.
sol i d, n. o. s.
Antimony lactate 151 1550
Anti mony pentachl ori de, l i qui d 157 1730
Anti mony pentachl ori de, 157 1731
solution
Antimony pentafluoride 157 1732
Antimony potassium tartrate 151 1551
Anti mony powder 170 2871
Anti mony tri bromi de, sol i d 157 1549
Anti mony tri bromi de, sol uti on 157 1549
Anti mony tri chl ori de 157 1733
Anti mony tri chl ori de, l i qui d 157 1733
Anti mony tri chl ori de, sol i d 157 1733
Anti mony tri chl ori de, sol uti on 157 1733
Anti mony tri fl uori de, sol i d 157 1549
Anti mony tri fl uori de, sol uti on 157 1549
Aqua regia 157 1798
Argon 121 1006
Argon, compressed 121 1006
Argon, refrigerated liquid 120 1951
Arseni c 152 1558
Arseni c aci d, l i qui d 154 1553
Arseni c aci d, sol i d 154 1554
Arseni cal dust 152 1562
Arseni cal pesti ci de, l i qui d, 131 2760
fl ammabl e, toxi c
poisonous
Arseni cal pesti ci de, l i qui d, toxi c 151 2994
Arseni cal pesti ci de, l i qui d, toxi c, 131 2993
flammable
Arseni cal pesti ci de, sol i d, 151 2759
poisonous
No. No.
No. No.
Page 102
Arseni cal pesti ci de, sol i d, toxi c 151 2759
Arseni c bromi de 151 1555
Arseni c chl ori de 157 1560
Arseni c compound, l i qui d, n.o.s. 152 1556
Arseni c compound, l i qui d, 152 1556
n.o.s., i norgani c
Arseni c compound, sol i d, n.o.s. 152 1557
Arseni c compound, sol i d, n.o.s., 152 1557
inorganic
Arseni c pentoxi de 151 1559
Arseni c sul fi de 152 1557
Arseni c sul phi de 152 1557
Arseni c tri chl ori de 157 1560
Arseni c tri oxi de 151 1561
Arsenic trisulfide 152 1557
Arseni c tri sul phi de 152 1557
Arsine 119 2188
Articles containing 171 2315
Pol ychl ori nated bi phenyl s
( PCB)
Arti cl es, pressuri zed, hydraul i c 126 3164
(containing non-flammable
gas)
Arti cl es, pressuri zed, pneumati c 126 3164
(containing non-flammable
gas)
Aryl sul f oni c aci ds, l i qui d, wi t h 153 2584
acid
Aryl sul f oni c aci ds, l i qui d, wi t h 153 2586
acid
Aryl sul f oni c aci ds, sol i d, wi t h 153 2583
acid
Aryl sul f oni c aci ds, sol i d, wi t h 153 2585
acid
Aryl sul phoni c aci ds, l i qui d, wi th 153 2584
acid
Aryl sul phoni c aci ds, l i qui d, wi th 153 2586
Sul phuri c aci d
Aryl sul phoni c aci ds, sol i d, wi t h 153 2583
acid
Aryl sul phoni c aci ds, sol i d, wi t h 153 2585
Sul phuri c aci d
Asbestos 171 2212
Asbestos, bl ue 171 2212
Asbestos, brown 171 2212
Asbestos, whi te 171 2590
Asphalt 130 1999
Avi ati on regul ated l i qui d, n.o.s. 171 3334
Avi ati on regul ated sol i d, n.o.s. 171 3335
1-Azi ri di nyl phosphi ne oxi de 152 2501
(Tris)
Azodicarbonamide 149 3242
Barium 138 1400
Bari um al l oys, pyrophori c 135 1854
Bari um azi de, wetted wi th not 113 1571
Barium bromate 141 2719
Bari um chl orate 141 1445
Bari um chl orate, sol i d 141 1445
Barium chlorate, solution 141 3405
Bari um compound, n.o.s. 154 1564
Bari um cyani de 157 1565
Bari um hypochl ori te, wi th more 141 2741
than 22% avai l abl e Chl ori ne
Barium nitrate 141 1446
Bari um oxi de 157 1884
No. No.
No. No.
Page 103
Barium perchlorate 141 1447
Bari um perchl orate, sol i d 141 1447
Barium perchlorate, solution 141 3406
Barium permanganate 141 1448
Bari um peroxi de 141 1449
Batteries, containing Sodium 138 3292
Batteri es, dry, contai ni ng 154 3028
Potassi um hydroxi de sol i d
Batteri es, wet, fi l l ed wi th aci d 154 2794
Batteri es, wet, fi l l ed wi th al kal i 154 2795
Batteri es, wet, non-spi l l abl e 154 2800
Battery fl ui d, aci d 157 2796
Battery fl ui d, al kal i 154 2797
Battery fl ui d, al kal i , wi th battery 154 2797
Battery fl ui d, al kal i , wi th 154 2797
electronic equipment or
actuating device
Battery-powered equi pment (wet 154 3171
battery)
Battery-powered vehi cl e (wet 154 3171
battery)
Benzal dehyde 129 1990
Benzene 130 1114
Benzene phosphorus dichloride 137 2798
Benzene phosphorus 137 2799
thiodichloride
Benzenesul fonyl chl ori de 156 2225
Benzenesulphonyl chloride 156 2225
Benzidine 153 1885
Benzoi c deri vati ve pesti ci de, 131 2770
liquid, poisonous
l i qui d, toxi c
solid, poisonous
sol i d, t oxi c
Benzonitrile 152 2224
Benzoquinone 153 2587
Benzotrichloride 156 2226
Benzotrifluoride 127 2338
Benzoyl chl ori de 137 1736
Benzyl bromi de 156 1737
Benzyl chl ori de 156 1738
Benzyl chl oroformate 137 1739
Benzyl di methyl ami ne 132 2619
Benzyl i dene chl ori de 156 1886
Benzyl i odi de 156 2653
Beryl l i um compound, n.o.s. 154 1566
Beryl l i um ni trate 141 2464
Beryl l i um powder 134 1567
Bhusa, wet, damp or 133 1327
contaminated with oil
Bi cycl o[2.2.1]hepta-2,5-di ene 128P 2251
Bi cycl o[2.2.1]hepta-2,5-di ene, 128P 2251
inhibited
Bi cycl o[2.2.1]hepta-2,5-di ene, 128P 2251
stabilized
Biological agents 158
(Bi o)Medi cal wast e, n. o. s. 158 3291
Bi pyri di l i um pesti ci de, l i qui d, 131 2782
No. No.
No. No.
Page 104
fl ammabl e, toxi c
poisonous
t oxi c
toxi c, fl ammabl e
Bi pyri di l i um pesti ci de, sol i d, 151 2781
poisonous
Bi pyri di l i um pesti ci de, sol i d, 151 2781
t oxi c
Bisulfates, aqueous solution 154 2837
Bi sul fi tes, aqueous sol uti on, 154 2693
n.o.s.
Bi sul fi tes, i norgani c, aqueous 154 2693
sol uti on, n.o.s.
Bisulphates, aqueous solution 154 2837
Bi sul phi tes, aqueous sol uti on, 154 2693
n.o.s.
Bi sul phi tes, i norgani c, aqueous 154 2693
sol uti on, n.o.s.
Bl asti ng agent, n.o.s. 112
Bl eachi ng powder 140 2208
Bl ue asbestos 171 2212
Bombs, smoke, non-expl osi ve, 153 2028
wi th corrosi ve l i qui d, wi thout
initiating device
Borate and Chl orate mi xtures 140 1458
Borneol 133 1312
Boron tribromide 157 2692
Boron trichloride 125 1741
Boron trifluoride 125 1008
Boron trifluoride, compressed 125 1008
Boron trifluoride, dihydrate 157 2851
Boron trifluoride acetic acid 157 1742
compl ex
compl ex, l i qui d
compl ex, sol i d
Boron trifluoride diethyl etherate 132 2604
Boron trifluoride dimethyl 139 2965
etherate
Boron trifluoride propionic acid 157 1743
compl ex
compl ex, l i qui d
compl ex, sol i d
Bromates, i norgani c, aqueous 140 3213
sol uti on, n.o.s.
Bromates, i norgani c, n.o.s. 141 1450
Bromine 154 1744
Bromine, solution 154 1744
Bromine chloride 124 2901
Bromine pentafluoride 144 1745
Bromine trifluoride 144 1746
Bromoaceti c aci d 156 1938
Bromoaceti c aci d, sol i d 156 3425
Bromoaceti c aci d, sol uti on 156 1938
Bromoacetone 131 1569
Bromoacetyl bromi de 156 2513
Bromobenzene 130 2514
Bromobenzyl cyani des 159 1694
Bromobenzyl cyani des, l i qui d 159 1694
Bromobenzyl cyani des, sol i d 159 1694
Bromobenzyl cyani des, sol i d 159 3449
1-Bromobutane 130 1126
No. No.
No. No.
Page 105
2-Bromobutane 130 2339
Bromochlorodifluoromethane 126 1974
Bromochloromethane 160 1887
1-Bromo-3-chloropropane 159 2688
2-Bromoethyl ethyl ether 130 2340
Bromoform 159 2515
1-Bromo-3-methylbutane 130 2341
Bromomethylpropanes 130 2342
2-Bromo-2-nitropropane-1,3-diol 133 3241
2-Bromopentane 130 2343
2-Bromopropane 129 2344
Bromopropanes 129 2344
3-Bromopropyne 130 2345
Bromotrifluoroethylene 116 2419
Bromotrifluoromethane 126 1009
Brown asbestos 171 2212
Brucine 152 1570
Butadienes, inhibited 116P 1010
Butadienes, stabilized 116P 1010
Butadienes and hydrocarbon 116P 1010
Butane 115 1011
Butane 115 1075
Butanedione 127 2346
Butane mi xture 115 1011
Butane mi xture 115 1075
Butanols 129 1120
But oxyl 127 2708
Butyl acetates 129 1123
Butyl aci d phosphate 153 1718
But yl acryl at e 130P 2348
Butyl acryl ates, i nhi bi ted 130P 2348
Butyl acryl ates, stabi l i zed 130P 2348
n-Butyl ami ne 132 1125
N-Butyl ani l i ne 153 2738
Butyl benzenes 128 2709
n-Butyl bromi de 130 1126
Butyl chl ori de 130 1127
n-Butyl chloroformate 155 2743
sec-Butyl chl oroformate 155 2742
t ert -But yl cycl ohexyl 156 2747
chloroformate
Butyl ene 115 1012
Butyl ene 115 1075
1,2-Butyl ene oxi de, stabi l i zed 127P 3022
Butyl ethers 128 1149
n-Butyl formate 129 1128
tert-Butyl hypochl ori te 135 3255
N,n-Butyl i mi dazol e 152 2690
n-Butyl i socyanate 155 2485
tert-Butyl i socyanate 155 2484
Butyl mercaptan 130 2347
n-Butyl methacryl ate 130P 2227
n-Butyl methacryl ate, i nhi bi ted 130P 2227
n-Butyl methacryl ate, stabi l i zed 130P 2227
Butyl methyl ether 127 2350
Butyl ni tri tes 129 2351
Butyl propionates 130 1914
Butyl tol uenes 152 2667
Butyl tri chl orosi l ane 155 1747
5-tert-Butyl-2,4,6-trinitro- 149 2956
m-xyl ene
Butyl vi nyl ether, i nhi bi ted 127P 2352
Butyl vi nyl ether, stabi l i zed 127P 2352
1,4-Butynedi ol 153 2716
Butyral dehyde 129 1129
No. No.
No. No.
Page 106
Butyral doxi me 129 2840
But yri c aci d 153 2820
Butyri c anhydri de 156 2739
Butyroni tri l e 131 2411
Butyryl chl ori de 132 2353
Buzz 153 2810
BZ 153 2810
C A 159 1694
Cacodyl i c aci d 151 1572
Cadmium compound 154 2570
Caesi um 138 1407
Caesi um hydroxi de 157 2682
Caesi um hydroxi de, sol uti on 154 2681
Caesi um ni trate 140 1451
Cal ci um 138 1401
Cal ci um, metal and al l oys, 135 1855
pyrophori c
Cal ci um, pyrophori c 135 1855
Cal ci um al l oys, pyrophori c 135 1855
Calcium arsenate 151 1573
Cal ci um arsenate and Cal ci um 151 1574
arseni te mi xture, sol i d
Cal ci um arseni te, sol i d 151 1574
Cal ci um arseni te and Cal ci um 151 1574
arsenate mi xture, sol i d
Cal ci um carbi de 138 1402
Cal ci um chl orate 140 1452
Cal ci um chl orate, aqueous 140 2429
solution
Cal ci um chl orate, sol uti on 140 2429
Cal ci um chl ori te 140 1453
Cal ci um cyanami de, wi th more 138 1403
than 0.1% Cal ci um carbi de
Cal ci um cyani de 157 1575
Calcium dithionite 135 1923
Cal ci um hydri de 138 1404
Cal ci um hydrosul fi te 135 1923
Cal ci um hydrosul phi te 135 1923
Cal ci um hypochl ori te, dry 140 1748
Cal ci um hypochl ori te, hydrated, 140 2880
wi th not l ess than 5.5% but not
more than 16% water
Cal ci um hypochl ori te, hydrated 140 2880
mi xture, wi th not l ess than
5.5% but not more than 16%
water
Cal ci um hypochl ori te mi xture, 140 2208
dry, wi th more than 10% but
not more than 39% avai l abl e
Chlorine
Cal ci um hypochl ori te mi xture, 140 1748
dry, wi t h more t han 39%
avai l abl e Chl ori ne (8. 8%
avai l abl e Oxygen)
Cal ci um manganese si l i con 138 2844
Cal ci um ni trate 140 1454
Cal ci um oxi de 157 1910
Calcium perchlorate 140 1455
Calcium permanganate 140 1456
Cal ci um peroxi de 140 1457
Cal ci um phosphi de 139 1360
Cal ci um resi nate 133 1313
Cal ci um resi nate, fused 133 1314
Cal ci um si l i ci de 138 1405
Cal ci um si l i con 138 1406
Camphor 133 2717
Camphor, syntheti c 133 2717
Camphor oi l 128 1130
Caproi c aci d 153 2829
No. No.
No. No.
Page 107
Carbamate pesti ci de, l i qui d, 131 2758
fl ammabl e, toxi c
poisonous
t oxi c
toxi c, fl ammabl e
Carbamate pesti ci de, sol i d, 151 2757
poisonous
Carbamate pesti ci de, sol i d, 151 2757
t oxi c
Carbon, acti vated 133 1362
Carbon, ani mal or vegetabl e 133 1361
origin
Carbon bisulfide 131 1131
Carbon bisulphide 131 1131
Carbon di oxi de 120 1013
Carbon di oxi de, compressed 120 1013
Carbon di oxi de, refri gerated 120 2187
liquid
Carbon di oxi de, sol i d 120 1845
Carbon di oxi de and Ethyl ene 115 1041
oxi de mi xture, wi th more than
Ethyl ene oxi de
Carbon di oxi de and Ethyl ene 119P 3300
oxi de mi xture, wi th more than
oxi de mi xtures, wi th more
oxi de mi xtures, wi th not more
oxi de mi xtures, wi th not more
Carbon di oxi de and Ni trous 126 1015
oxi de mi xture
Carbon di oxi de and Oxygen 122 1014
mixture
Carbon di oxi de and Oxygen 122 1014
mi xture, compressed
Carbon disulfide 131 1131
Carbon disulphide 131 1131
Carbon monoxi de 119 1016
Carbon monoxi de, compressed 119 1016
Carbon monoxide, refrigerated 168 9202
l i qui d (cryogeni c l i qui d)
Carbon monoxi de and Hydrogen 119 2600
mi xture
Carbon monoxi de and Hydrogen 119 2600
Carbon tetrabromide 151 2516
Carbon tetrachloride 151 1846
Carbonyl fl uori de 125 2417
Carbonyl fl uori de, compressed 125 2417
Carbonyl sul fi de 119 2204
Carbonyl sul phi de 119 2204
Castor beans, meal , pomace or 171 2969
flake
Causti c al kal i l i qui d, n.o.s. 154 1719
Causti c potash, dry, sol i d 154 1813
Causti c potash, l i qui d 154 1814
Causti c potash, sol uti on 154 1814
Causti c soda, bead 154 1823
Causti c soda, fl ake 154 1823
No. No.
No. No.
Page 108
Causti c soda, granul ar 154 1823
Causti c soda, sol i d 154 1823
Causti c soda, sol uti on 154 1824
Cel l s, contai ni ng Sodi um 138 3292
Cel l ul oi d, i n bl ocks, rods, rol l s, 133 2000
sheets, tubes, etc., except
scrap
Cel l ul oi d, scrap 135 2002
Ceri um, sl abs, i ngots or rods 170 1333
Ceri um, turni ngs or gri tty powder 138 3078
Cesi um 138 1407
Cesi um hydroxi de 157 2682
Cesi um hydroxi de, sol uti on 154 2681
Cesi um ni trate 140 1451
CG 125 1076
Charcoal 133 1361
Chemi cal ki t 154 1760
Chemi cal ki t 171 3316
Chemi cal sampl e, poi sonous 151 3315
liquid
sol i d
Chemi cal sampl e, toxi c 151 3315
Chemi cal sampl e, toxi c l i qui d 151 3315
Chemi cal sampl e, toxi c sol i d 151 3315
Chl oral , anhydrous, i nhi bi ted 153 2075
Chl oral , anhydrous, stabi l i zed 153 2075
Chl orate and Borate mi xtures 140 1458
Chl orate and Magnesi um 140 1459
chloride mixture
chl ori de mi xture, sol i d
chl ori de mi xture, sol uti on
Chl orates, i norgani c, aqueous 140 3210
sol uti on, n.o.s.
Chl orates, i norgani c, n.o.s. 140 1461
Chl ori c aci d, aqueous sol uti on, 140 2626
Chl ori c aci d
Chlorine 124 1017
Chl ori ne di oxi de, hydrate, frozen 143 9191
Chlorine pentafluoride 124 2548
Chlorine trifluoride 124 1749
Chlorite solution 154 1908
Chl ori te sol uti on, wi th more than 154 1908
5% avai l abl e Chl ori ne
Chl ori tes, i norgani c, n.o.s. 143 1462
Chloroacetaldehyde 153 2232
Chl oroaceti c aci d, l i qui d 153 1750
Chl oroaceti c aci d, mol ten 153 3250
Chl oroaceti c aci d, sol i d 153 1751
Chl oroaceti c aci d, sol uti on 153 1750
Chloroacetone, stabilized 131 1695
Chloroacetonitrile 131 2668
Chloroacetophenone 153 1697
Chloroacetophenone, liquid 153 1697
Chloroacetophenone, liquid 153 3416
Chloroacetophenone, solid 153 1697
Chl oroacetyl chl ori de 156 1752
Chl oroani l i nes, l i qui d 152 2019
Chl oroani l i nes, sol i d 152 2018
Chloroanisidines 152 2233
Chlorobenzene 130 1134
Chlorobenzotrifluorides 130 2234
Chl orobenzyl chl ori des 153 2235
Chl orobenzyl chl ori des, l i qui d 153 2235
Chl orobenzyl chl ori des, sol i d 153 3427
No. No.
No. No.
Page 109
1-Chloro-3-bromopropane 159 2688
Chlorobutanes 130 1127
Chl orocresol s 152 2669
Chl orocresol s, l i qui d 152 2669
Chl orocresol s, sol i d 152 2669
Chl orocresol s, sol i d 152 3437
Chl orocresol s, sol uti on 152 2669
Chlorodifluorobromomethane 126 1974
1-Chloro-1,1-difluoroethane 115 2517
Chlorodifluoroethanes 115 2517
Chlorodifluoromethane 126 1018
Chlorodifluoromethane and 126 1973
Chloropentafluoroethane mixture
Chlorodinitrobenzenes 153 1577
Chlorodinitrobenzenes, liquid 153 1577
Chlorodinitrobenzenes, solid 153 1577
Chlorodinitrobenzenes, solid 153 3441
1-Chloro-2,3-epoxypropane 131P 2023
2-Chloroethanal 153 2232
Chloroform 151 1888
Chl oroformates, n.o.s. 155 2742
Chloroformates, poisonous, 155 2742
corrosi ve, fl ammabl e, n.o.s.
Chloroformates, poisonous, 154 3277
Chl oroformates, toxi c, 155 2742
Chl oroformates, toxi c, 154 3277
Chloromethyl chloroformate 157 2745
Chl oromethyl ethyl ether 131 2354
3-Chl oro-4-methyl phenyl 156 2236
i socyanate
i socyanate, l i qui d
i socyanate, sol i d
Chloronitroanilines 153 2237
Chloronitrobenzenes 152 1578
Chloronitrobenzenes, liquid 152 1578
Chloronitrobenzenes, liquid 152 3409
Chloronitrobenzenes, solid 152 1578
Chloronitrotoluenes 152 2433
Chloronitrotoluenes, liquid 152 2433
Chloronitrotoluenes, solid 152 2433
Chloronitrotoluenes, solid 152 3457
Chloropentafluoroethane 126 1020
Chloropentafluoroethane and 126 1973
Chlorodifluoromethane
mixture
Chlorophenates, liquid 154 2904
Chl orophenates, sol i d 154 2905
Chlorophenolates, liquid 154 2904
Chl orophenol ates, sol i d 154 2905
Chl orophenol s, l i qui d 153 2021
Chl orophenol s, sol i d 153 2020
Chlorophenyltrichlorosilane 156 1753
Chl oropi cri n 154 1580
Chl oropi cri n and Methyl bromi de 123 1581
mixture
Chl oropi cri n and Methyl chl ori de 119 1582
mixture
Chl oropi cri n mi xture, n.o.s. 154 1583
Chl oropi val oyl chl ori de 156 9263
Chl oropl ati ni c aci d, sol i d 154 2507
Chloroprene, inhibited 131P 1991
Chl oroprene, stabi l i zed 131P 1991
1-Chloropropane 129 1278
2-Chloropropane 129 2356
No. No.
No. No.
Page 110
3-Chloropropanol-1 153 2849
2-Chloropropene 130P 2456
2-Chl oropropi oni c aci d 153 2511
2-Chl oropropi oni c aci d, sol i d 153 2511
2-Chl oropropi oni c aci d, sol uti on 153 2511
2-Chloropyridine 153 2822
Chl orosi l anes, corrosi ve, 155 2986
fl ammabl e, n.o.s.
Chl orosi l anes, corrosi ve, n. o. s. 156 2987
Chl orosi l anes, fl ammabl e, 155 2985
Chl orosi l anes, n.o.s. 155 2985
Chl orosi l anes, poi sonous, 155 3362
Chl orosi l anes, poi sonous, 156 3361
Chl orosi l anes, toxi c, corrosi ve 155 3362
fl ammabl e, n.o.s.
Chl orosi l anes, t oxi c, corrosi ve, 156 3361
n.o.s.
Chl orosi l anes, water-reacti ve, 139 2988
Chl orosul foni c aci d 137 1754
Chl orosul foni c aci d and Sul fur 137 1754
tri oxi de mi xture
Chl orosul phoni c aci d 137 1754
Chl orosul phoni c aci d and 137 1754
Sul phur tri oxi de mi xture
1-Chl oro-1,2,2,2- 126 1021
tetrafluoroethane
Chlorotetrafluoroethane 126 1021
Chlorotetrafluoroethane and 126 3297
Ethyl ene oxi de mi xture, wi th
not more than 8.8% Ethyl ene
oxi de
Chlorotoluenes 129 2238
4-Chloro-o-toluidine 153 1579
hydrochl ori de
hydrochl ori de, sol i d
hydrochl ori de, sol uti on
Chlorotoluidines 153 2239
Chl orotol ui di nes, l i qui d 153 2239
Chl orotol ui di nes, l i qui d 153 3429
Chl orotol ui di nes, sol i d 153 2239
1-Chloro-2,2,2-trifluoroethane 126 1983
Chlorotrifluoroethane 126 1983
Chlorotrifluoromethane 126 1022
Chlorotrifluoromethane and 126 2599
Trifluoromethane azeotropic
60% Chlorotrifluoromethane
Chromi c aci d, sol i d 141 1463
Chromi c aci d, sol uti on 154 1755
Chromi c fl uori de, sol i d 154 1756
Chromi c fl uori de, sol uti on 154 1757
Chromium nitrate 141 2720
Chromi um oxychl ori de 137 1758
Chromi um tri oxi de, anhydrous 141 1463
Chromosul furi c aci d 154 2240
Chromosul phuri c aci d 154 2240
CK 125 1589
Cl i ni cal speci mens 158 3373
Cl i ni cal waste, unspeci fi ed, 158 3291
n.o.s.
No. No.
No. No.
Page 111
CN 153 1697
Coal gas 119 1023
Coal gas, compressed 119 1023
Coal tar di sti l l ates, fl ammabl e 128 1136
Coating solution 127 1139
Cobalt naphthenates, powder 133 2001
Cobalt resinate, precipitated 133 1318
Combusti bl e l i qui d, n.o.s. 128 1993
Compound, cleaning liquid 154 1760
(corrosi ve)
Compound, cleaning liquid 128 1993
(flammable)
Compound, tree or weed ki l l i ng, 154 1760
l i qui d (corrosi ve)
liquid (flammable)
l i qui d (toxi c)
Compressed gas, fl ammabl e, 115 1954
n.o.s.
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
toxi c, n.o.s. (Inhal ati on
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
Compressed gas, n. o. s. 126 1956
Compressed gas, oxi di zi ng, 122 3156
n.o.s.
Compressed gas, poi sonous, 123 3304
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
fl ammabl e, n.o.s.
No. No.
No. No.
Page 112
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
n.o.s.
Zone A)
Zone B)
Zone C)
Zone D)
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
Compressed gas, t oxi c, 123 3304
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
No. No.
No. No.
Page 113
fl ammabl e, n.o.s.
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
Compressed gas, t oxi c, n. o. s. 123 1955
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
Consumer commodi ty 171 8000
Copper acetoarsenite 151 1585
Copper arseni te 151 1586
Copper based pesti ci de, l i qui d, 131 2776
fl ammabl e, toxi c
poisonous
t oxi c
toxi c, fl ammabl e
Copper based pesti ci de, sol i d, 151 2775
poisonous
Copper based pesti ci de, sol i d, 151 2775
t oxi c
Copper chl orate 141 2721
Copper chl ori de 154 2802
No. No.
No. No.
Page 114
Copper cyani de 151 1587
Copra 135 1363
Corrosi ve l i qui d, aci di c, 154 3264
i norgani c, n.o.s.
Corrosi ve l i qui d, aci di c, organi c, 153 3265
n.o.s.
Corrosi ve l i qui d, basi c, 154 3266
i norgani c, n.o.s.
Corrosi ve l i qui d, basi c, organi c, 153 3267
n.o.s.
Corrosi ve l i qui d, fl ammabl e, 132 2920
n.o.s.
Corrosi ve l i qui d, n. o. s. 154 1760
Corrosi ve l i qui d, oxi di zi ng, 140 3093
n.o.s.
Corrosi ve l i qui d, poi sonous, 154 2922
n.o.s.
Corrosi ve l i qui d, sel f-heati ng, 136 3301
n.o.s.
Corrosi ve l i qui d, t oxi c, n. o. s. 154 2922
Corrosi ve l i qui d, water-reacti ve, 138 3094
n.o.s.
Corrosi ve l i qui d, whi ch i n 138 3094
contact wi th water emi ts
Corrosi ve sol i d, aci di c, 154 3260
i norgani c, n.o.s.
Corrosi ve sol i d, aci di c, organi c, 154 3261
n.o.s.
Corrosi ve sol i d, basi c, 154 3262
i norgani c, n.o.s.
Corrosi ve sol i d, basi c, organi c, 154 3263
n.o.s.
Corrosive solid, flammable, n.o.s. 134 2921
Corrosi ve sol i d, n. o. s. 154 1759
Corrosi ve sol i d, oxi di zi ng, n. o. s. 140 3084
Corrosi ve sol i d, poi sonous, 154 2923
n.o.s.
Corrosi ve sol i d, sel f-heati ng, 136 3095
n.o.s.
Corrosi ve sol i d, t oxi c, n. o. s. 154 2923
Corrosi ve sol i d, water-reacti ve, 138 3096
n.o.s.
Corrosi ve sol i d, whi ch i n contact 138 3096
gases, n. o. s.
Cotton 133 1365
Cotton, wet 133 1365
Cotton waste, oi l y 133 1364
Coumari n deri vati ve pesti ci de, 131 3024
liquid, poisonous
l i qui d, toxi c
solid, poisonous
sol i d, t oxi c
Cresol s 153 2076
Cresol s, l i qui d 153 2076
Cresol s, sol i d 153 2076
Cresol s, sol i d 153 3455
Cresyl i c aci d 153 2022
Crotonaldehyde, inhibited 131P 1143
Crotonal dehyde, stabi l i zed 131P 1143
No. No.
No. No.
Page 115
Crotoni c aci d 153 2823
Crotoni c aci d, l i qui d 153 2823
Crotoni c aci d, sol i d 153 2823
Crotonyl ene 128 1144
C S 153 2810
Cumene 130 1918
Cupriethylenediamine, solution 154 1761
CX 154 2811
Cyani de sol ut i on, n. o. s. 157 1935
Cyani des, i norgani c, n.o.s. 157 1588
Cyani des, i norgani c, sol i d, 157 1588
n.o.s.
Cyanogen 119 1026
Cyanogen, l i quefi ed 119 1026
Cyanogen bromi de 157 1889
Cyanogen chl ori de, i nhi bi ted 125 1589
Cyanogen chl ori de, stabi l i zed 125 1589
Cyanogen gas 119 1026
Cyanuri c chl ori de 157 2670
Cycl obutane 115 2601
Cycl obutyl chl oroformate 155 2744
1,5,9-Cycl ododecatri ene 153 2518
Cycl oheptane 128 2241
Cycloheptatriene 131 2603
Cycl oheptene 128 2242
Cycl ohexane 128 1145
Cycl ohexanethi ol 129 3054
Cycl ohexanone 127 1915
Cycl ohexene 130 2256
Cycl ohexenyl tri chl orosi l ane 156 1762
Cycl ohexyl acet at e 130 2243
Cycl ohexyl ami ne 132 2357
Cycl ohexyl i socyanat e 155 2488
Cycl ohexyl mercapt an 129 3054
Cycl ohexyl tri chl orosi l ane 156 1763
Cycl ooctadi ene phosphi nes 135 2940
Cycl ooctadi enes 130P 2520
Cyclooctatetraene 128P 2358
Cycl opentane 128 1146
Cycl opentanol 129 2244
Cycl opentanone 128 2245
Cycl opentene 128 2246
Cycl opropane 115 1027
Cycl opropane, l i quefi ed 115 1027
Cymenes 130 2046
DA 151 1699
Dangerous goods in apparatus 171 3363
Dangerous goods i n machi nery 171 3363
DC 153 2810
Decaborane 134 1868
Decahydronaphthalene 130 1147
n-Decane 128 2247
Denatured alcohol 127 1987
Denatured alcohol (toxic) 131 1986
Desensi ti zed expl osi ve, 128 3379
l i qui d, n.o.s.
Desensi ti zed expl osi ve, 133 3380
sol i d, n. o. s.
Deuterium 115 1957
Deuterium, compressed 115 1957
Devi ces, smal l , hydrocarbon gas 115 3150
powered, wi th rel ease devi ce
Diacetone alcohol 129 1148
Di acetyl 127 2346
Di agnosti c speci mens 158 3373
Di al l yl ami ne 132 2359
Di al l yl ether 131P 2360
No. No.
No. No.
Page 116
4,4' -Diaminodiphenylmethane 153 2651
Di -n-amyl ami ne 131 2841
Di benzyl di chl orosi l ane 156 2434
Diborane 119 1911
Diborane, compressed 119 1911
Diborane mixtures 119 1911
Dibromobenzene 129 2711
1,2-Dibromobutan-3-one 154 2648
Dibromochloropropanes 159 2872
Dibromodifluoromethane 171 1941
Dibromomethane 160 2664
Di-n-butylamine 132 2248
Dibutylaminoethanol 153 2873
Di butyl ethers 128 1149
Dichloroacetic acid 153 1764
1,3-Dichloroacetone 153 2649
Di chl oroacetyl chl ori de 156 1765
Dichloroanilines 153 1590
Di chl oroani l i nes, l i qui d 153 1590
Di chl oroani l i nes, sol i d 153 1590
Di chl oroani l i nes, sol i d 153 3442
o-Dichlorobenzene 152 1591
Dichlorobutene 132 2920
2,2' -Dichlorodiethyl ether 152 1916
Dichlorodifluoromethane 126 1028
Dichlorodifluoromethane and 126 2602
Difluoroethane azeotropic
74% Dichlorodifluoromethane
Ethyl ene oxi de mi xture, wi th
not more than 12.5% Ethyl ene
oxi de
Ethyl ene oxi de mi xtures, wi th
not more than 12% Ethyl ene
oxi de
Di chl orodi methyl ether, 131 2249
symmetri cal
1,1-Dichloroethane 130 2362
1,2-Dichloroethylene 130P 1150
Dichloroethylene 130P 1150
Dichloroethyl ether 152 1916
Dichlorofluoromethane 126 1029
Di chl oroi socyanuri c aci d, dry 140 2465
Di chl oroi socyanuri c aci d sal ts 140 2465
Di chl oroi sopropyl ether 153 2490
Dichloromethane 160 1593
1,1-Dichloro-1-nitroethane 153 2650
Dichloropentanes 130 1152
Di chl orophenyl i socyanates 156 2250
Dichlorophenyltrichlorosilane 156 1766
1,2-Dichloropropane 130 1279
Dichloropropane 130 1279
1,3-Dichloropropanol-2 153 2750
Dichloropropenes 129 2047
Dichlorosilane 119 2189
1,2-Di chl oro-1,1,2,2- 126 1958
tetrafluoroethane
Dichlorotetrafluoroethane 126 1958
3,5-Dichloro-2,4,6- 151 9264
trifluoropyridine
Dicycloheptadiene 128P 2251
Di cycl ohexyl ami ne 153 2565
Di cycl ohexyl ammoni um ni tri te 133 2687
Dicyclopentadiene 130 2048
1,2-Di-(dimethylamino)ethane 129 2372
No. No.
No. No.
Page 117
Didymium nitrate 140 1465
Dieldrin 151 2761
Diesel fuel 128 1202
Diesel fuel 128 1993
Di ethoxymethane 127 2373
3,3-Diethoxypropene 127 2374
Diethylamine 132 1154
2-Diethylaminoethanol 132 2686
Diethylaminoethanol 132 2686
3-Diethylaminopropylamine 132 2684
Di ethyl ami nopropyl ami ne 132 2684
N,N-Di ethyl ani l i ne 153 2432
Diethylbenzene 130 2049
Diethyl carbonate 128 2366
Diethyldichlorosilane 155 1767
Diethylenetriamine 154 2079
Di ethyl ether 127 1155
N,N-Di ethyl ethyl enedi ami ne 132 2685
Di ethyl ketone 127 1156
Di ethyl sul fate 152 1594
Di ethyl sul fi de 129 2375
Diethyl sulphate 152 1594
Diethyl sulphide 129 2375
Di ethyl thi ophosphoryl chl ori de 155 2751
Di ethyl zi nc 135 1366
Difluorochloroethanes 115 2517
1,1-Difluoroethane 115 1030
Difluoroethane 115 1030
Difluoroethane and 126 2602
1,1-Difluoroethylene 116P 1959
Difluoromethane 115 3252
Difluorophosphoric acid, 154 1768
anhydrous
2,3-Di hydropyran 127 2376
Di i sobutyl ami ne 132 2361
Di i sobutyl ene, i someri c 128 2050
compounds
Diisobutyl ketone 128 1157
Di i sooctyl aci d phosphate 153 1902
Diisopropylamine 132 1158
Di i sopropyl ether 127 1159
Diketene, inhibited 131P 2521
Diketene, stabilized 131P 2521
1,1-Dimethoxyethane 127 2377
1,2-Dimethoxyethane 127 2252
Di methyl ami ne, anhydrous 118 1032
Di methyl ami ne, aqueous 132 1160
solution
Di methyl ami ne, sol uti on 132 1160
2-Dimethylaminoacetonitrile 131 2378
2-Dimethylaminoethanol 132 2051
2-Di methyl ami noethyl acryl ate 152 3302
2-Dimethylaminoethyl 153P 2522
methacrylate
Dimethylaminoethyl 153P 2522
methacrylate
N,N-Di methyl ani l i ne 153 2253
2,3-Dimethylbutane 128 2457
1,3-Di methyl butyl ami ne 132 2379
Di methyl carbamoyl chl ori de 156 2262
Dimethyl carbonate 129 1161
Di methyl cycl ohexanes 128 2263
N, N-Di met hyl cycl ohexyl ami ne 132 2264
Di met hyl cycl ohexyl ami ne 132 2264
No. No.
No. No.
Page 118
Dimethyldichlorosilane 155 1162
Di methyl di ethoxysi l ane 127 2380
Di methyl di oxanes 127 2707
Di methyl di sul fi de 130 2381
Di methyl di sul phi de 130 2381
Dimethylethanolamine 132 2051
Di methyl ether 115 1033
N,N-Di methyl formami de 129 2265
1,1-Di methyl hydrazi ne 131 1163
1,2-Di methyl hydrazi ne 131 2382
Di methyl hydrazi ne, symmetri cal 131 2382
Di methyl hydrazi ne, 131 1163
unsymmetri cal
2,2-Dimethylpropane 115 2044
Di methyl -N-propyl ami ne 132 2266
Dimethyl sulfate 156 1595
Dimethyl sulfide 130 1164
Dimethyl sulphate 156 1595
Di methyl sul phi de 130 1164
Di methyl thi ophosphoryl chl ori de 156 2267
Di methyl zi nc 135 1370
Dinitroanilines 153 1596
Dinitrobenzenes 152 1597
Dinitrobenzenes, liquid 152 1597
Dinitrobenzenes, solid 152 1597
Dinitrobenzenes, solid 152 3443
Dinitrochlorobenzenes 153 1577
Dinitro-o-cresol 153 1598
Dinitrogen tetroxide 124 1067
Dinitrogen tetroxide, liquefied 124 1067
Di ni trogen tetroxi de and Ni tri c 124 1975
oxi de mi xture
Dinitrophenol, solution 153 1599
Dinitrophenol, wetted with not 113 1320
Dinitrophenolates, wetted with 113 1321
Di ni troresorci nol , wetted wi th 113 1322
Dinitrotoluenes 152 2038
Dinitrotoluenes, liquid 152 2038
Dinitrotoluenes, molten 152 1600
Dinitrotoluenes, solid 152 2038
Dinitrotoluenes, solid 152 3454
Dioxane 127 1165
Dioxolane 127 1166
Dipentene 128 2052
Diphenylamine chloroarsine 154 1698
Diphenylchloroarsine 151 1699
Di phenyl chl oroarsi ne, l i qui d 151 1699
Di phenyl chl oroarsi ne, sol i d 151 1699
Di phenyl chl oroarsi ne, sol i d 151 3450
Diphenyldichlorosilane 156 1769
Di phenyl methyl bromi de 153 1770
Diphosgene 125 1076
Di pi cryl sul fi de, wetted wi th not 113 2852
Di pi cryl sul phi de, wetted wi th 113 2852
Di propyl ami ne 132 2383
Di-n-propyl ether 127 2384
Di propyl ether 127 2384
Di propyl ketone 128 2710
Di si nfectant, l i qui d, corrosi ve, 153 1903
n.o.s.
Di si nfectant, l i qui d, poi sonous, 151 3142
n.o.s.
Di si nfectant, l i qui d, toxi c, n.o.s. 151 3142
No. No.
No. No.
Page 119
Disinfectant, solid, poisonous, n.o.s. 151 1601
Di si nfectant, sol i d, toxi c, n.o.s. 151 1601
Di si nfectants, corrosi ve, l i qui d, 153 1903
n.o.s.
Di si nfectants, l i qui d, n.o.s. 151 3142
(poisonous)
Di si nfectants, sol i d, n.o.s. 151 1601
(poisonous)
Di sodi um tri oxosi l i cate 154 3253
Di sodi um tri oxosi l i cate, 154 3253
pentahydrate
Di spersant gas, n.o.s. 126 1078
Di spersant gas, n.o.s. 115 1954
(flammable)
Dithiocarbamate pesticide, 131 2772
liquid, poisonous
l i qui d, toxi c
solid, poisonous
sol i d, t oxi c
Di vi nyl ether, i nhi bi ted 128P 1167
Di vi nyl ether, stabi l i zed 128P 1167
DM 154 1698
Dodecylbenzenesulfonic acid 153 2584
Dodecylbenzenesulphonic acid 153 2584
Dodecyltrichlorosilane 156 1771
DP 125 1076
Dry i ce 120 1845
Dye, l i qui d, corrosi ve, n. o. s. 154 2801
Dye, l i qui d, poi sonous, n.o.s. 151 1602
Dye, l i qui d, t oxi c, n. o. s. 151 1602
Dye, sol i d, corrosi ve, n. o. s. 154 3147
Dye, sol i d, poi sonous, n. o. s. 151 3143
Dye, sol i d, t oxi c, n. o. s. 151 3143
Dye i ntermedi ate, l i qui d, 154 2801
Dye i ntermedi ate, l i qui d, 151 1602
poi sonous, n.o.s.
Dye i ntermedi ate, l i qui d, toxi c, 151 1602
n.o.s.
Dye i ntermedi ate, sol i d, 154 3147
Dye i ntermedi ate, sol i d, 151 3143
poi sonous, n.o.s.
Dye i ntermedi ate, sol i d, toxi c, 151 3143
n.o.s.
ED 151 1892
Elevated temperature liquid, 128 3256
fl ammabl e, n.o.s., wi th fl ash
at or above i ts fl ash poi nt
fl ammabl e, n.o.s., wi th fl ash
at or above i ts fl ash poi nt
(212F), and bel ow i ts fl ash
point
Elevated temperature solid, 171 3258
(464F)
Engine starting fluid 115 1960
No. No.
No. No.
Page 120
Engi nes, i nternal combusti on, 128 3166
fl ammabl e gas powered
fl ammabl e l i qui d powered
i ncl udi ng when fi tted i n
machi nery or vehi cl es
Envi ronmental l y hazardous 171 3082
substances, l i qui d, n.o.s.
Envi ronmental l y hazardous 171 3077
substances, sol i d, n.o.s.
Epi bromohydri n 131 2558
Epi chl orohydri n 131P 2023
1,2-Epoxy-3-ethoxypropane 127 2752
Est ers, n. o. s. 127 3272
Ethane 115 1035
Ethane, compressed 115 1035
Ethane, refrigerated liquid 115 1961
Ethane-Propane mi xture, 115 1961
refrigerated liquid
Ethanol 127 1170
Ethanol, solution 127 1170
Ethanolamine 153 2491
Ethanolamine, solution 153 2491
Et hers, n. o. s. 127 3271
Ethyl acetate 129 1173
Ethyl acetyl ene, i nhi bi ted 116P 2452
Ethyl acetyl ene, stabi l i zed 116P 2452
Ethyl acryl ate, i nhi bi ted 129P 1917
Ethyl acryl ate, stabi l i zed 129P 1917
Ethyl al cohol 127 1170
Ethyl al cohol , sol uti on 127 1170
Ethyl ami ne 118 1036
Ethyl ami ne, aqueous sol uti on, 132 2270
wi th not l ess than 50% but not
more than 70% Ethyl ami ne
Ethyl amyl ketone 128 2271
2-Ethyl ani l i ne 153 2273
N-Ethyl ani l i ne 153 2272
Ethyl benzene 130 1175
N-Et hyl -N-benzyl ani l i ne 153 2274
N-Ethyl benzyl tol ui di nes 153 2753
N-Ethyl benzyl tol ui di nes, l i qui d 153 2753
N-Ethyl benzyl tol ui di nes, sol i d 153 2753
N-Ethyl benzyl tol ui di nes, sol i d 153 3460
Ethyl borate 129 1176
Ethyl bromi de 131 1891
Ethyl bromoacetate 155 1603
2-Ethylbutanol 129 2275
2-Ethyl butyl acetate 130 1177
Ethyl butyl acetate 130 1177
Ethyl butyl ether 127 1179
2-Ethyl butyral dehyde 130 1178
Ethyl butyrate 130 1180
Ethyl chl ori de 115 1037
Ethyl chloroacetate 155 1181
Ethyl chloroformate 155 1182
Ethyl 2-chloropropionate 129 2935
Ethyl chlorothioformate 155 2826
Ethyl crotonate 130 1862
Ethyl cyanoacetate 156 2666
Ethyl di chl oroarsi ne 151 1892
Ethyl di chl orosi l ane 139 1183
Ethyl ene 116P 1962
No. No.
No. No.
Page 121
Ethyl ene, Acetyl ene and 115 3138
not more than 22.5%
6% Pr opyl ene
Ethyl ene, compressed 116P 1962
Ethylene, refrigerated liquid 115 1038
Ethyl ene chl orohydri n 131 1135
Ethylenediamine 132 1604
Ethylene dibromide 154 1605
Ethyl ene di bromi de and Methyl 151 1647
bromi de mi xture, l i qui d
Ethyl ene di chl ori de 131 1184
Ethyl ene gl ycol di ethyl ether 127 1153
Ethyl ene gl ycol monobutyl ether 152 2369
Ethyl ene gl ycol monoethyl ether 127 1171
Ethyl ene gl ycol monoethyl ether 129 1172
acetate
Ethylene glycol monomethyl ether 127 1188
Ethyl ene gl ycol monomethyl 129 1189
ether acetate
Ethyl enei mi ne, i nhi bi ted 131P 1185
Ethyl enei mi ne, stabi l i zed 131P 1185
Ethyl ene oxi de 119P 1040
Ethyl ene oxi de and Carbon 115 1041
Ethyl ene oxi de and Carbon 119P 3300
di oxi de mi xtures, wi th more
t han 6 % Et hyl ene oxi de
Ethyl ene oxi de and 126 3297
Chlorotetrafluoroethane
8.8% Ethyl ene oxi de
12. 5% Et hyl ene oxi de
mi xtures, wi th not more than
Pentafluoroethane mixture,
wi th not more than 7.9%
Ethyl ene oxi de
Ethyl ene oxi de and Propyl ene 129P 2983
Tetrafluoroethane mixture,
wi th not more than 5.6%
Ethyl ene oxi de
Ethyl ene oxi de wi th Ni trogen 119P 1040
Ethyl ether 127 1155
Ethyl fl uori de 115 2453
Ethyl formate 129 1190
Ethyl hexal dehydes 129 1191
2-Ethyl hexyl ami ne 132 2276
2-Ethyl hexyl chl oroformate 156 2748
Ethyl i sobutyrate 129 2385
Ethyl i socyanate 155 2481
No. No.
No. No.
Page 122
Ethyl l actate 129 1192
Ethyl mercaptan 129 2363
Ethyl methacryl ate 130P 2277
Ethyl methacryl ate, i nhi bi ted 130P 2277
Ethyl methacryl ate, stabi l i zed 130P 2277
Ethyl methyl ether 115 1039
Ethyl methyl ketone 127 1193
Ethyl ni tri te, sol uti on 131 1194
Ethyl orthoformate 129 2524
Ethyl oxal ate 156 2525
Ethyl phenyl di chl orosi l ane 156 2435
Ethyl phosphonothioic 154 2927
di chl ori de, anhydrous
Ethyl phosphonous di chl ori de, 135 2845
anhydrous
Ethyl phosphorodichloridate 154 2927
1-Ethylpiperidine 132 2386
Ethyl propionate 129 1195
Ethyl propyl ether 127 2615
Ethyl si l i cate 129 1292
Ethyl sul furi c aci d 156 2571
Ethyl sul phuri c aci d 156 2571
N-Ethyl tol ui di nes 153 2754
Ethyl tri chl orosi l ane 155 1196
Expl osi ve A 112
Expl osi ve B 112
Expl osi ve C 114
Expl osi ves, di vi si on 1. 1, 1. 2, 112
1. 3, 1. 5 or 1. 6
Expl osi ves, di vi si on 1. 4 114
Extracts, aromati c, l i qui d 127 1169
Extracts, fl avori ng, l i qui d 127 1197
Extracts, fl avouri ng, l i qui d 127 1197
Fabri cs, ani mal or vegetabl e 133 1373
or syntheti c, n.o.s. wi th oi l
Fabri cs i mpregnated wi th weakl y 133 1353
ni trated Ni trocel l ul ose, n.o.s.
Ferric arsenate 151 1606
Ferri c arseni te 151 1607
Ferri c chl ori de 157 1773
Ferri c chl ori de, anhydrous 157 1773
Ferri c chl ori de, sol uti on 154 2582
Ferric nitrate 140 1466
Ferrocerium 170 1323
Ferrosilicon 139 1408
Ferrous arsenate 151 1608
Ferrous chl ori de, sol i d 154 1759
Ferrous chloride, solution 154 1760
Ferrous metal bori ngs, 170 2793
shavi ngs, turni ngs or cutti ngs
Fertilizer, ammoniating solution, 125 1043
wi th free Ammoni a
Fi ber, ani mal or vegetabl e, 133 1372
n.o.s., burnt, wet or damp
Fi bers, ani mal or vegetabl e 133 1373
Fi bers, ani mal or vegetabl e, 133 1372
burnt, wet or damp
Fi bers, vegetabl e, dry 133 3360
Fi bers i mpregnated wi th weakl y 133 1353
Fi bres, ani mal or vegetabl e, 133 1372
burnt, wet or damp
Fi bres, ani mal or vegetabl e 133 1373
Fi bres, vegetabl e, dry 133 3360
Fi bres i mpregnated wi th weakl y 133 1353
Fi l ms, ni trocel l ul ose base 133 1324
No. No.
No. No.
Page 123
Fi re exti ngui sher charges, 154 1774
corrosi ve l i qui d
Fi re exti ngui shers wi th 126 1044
compressed gas
Fi re exti ngui shers wi th 126 1044
liquefied gas
Fi rel i ghters, sol i d, wi th 133 2623
flammable liquid
Fi rst ai d ki t 171 3316
Fi sh meal , stabi l i zed 171 2216
Fi sh meal , unstabi l i zed 133 1374
Fi sh scrap, stabi l i zed 171 2216
Fi sh scrap, unstabi l i zed 133 1374
Fl ammabl e l i qui d, corrosi ve, 132 2924
n. o. s
Fl ammabl e l i qui d, n.o.s. 128 1993
Fl ammabl e l i qui d, poi sonous, 131 3286
Fl ammabl e l i qui d, poi sonous, 131 1992
n.o.s.
Fl ammabl e l i qui d, toxi c, 131 3286
Fl ammabl e l i qui d, toxi c, n.o.s. 131 1992
Fl ammabl e sol i d, corrosi ve, 134 3180
i norgani c, n.o.s.
n.o.s.
organi c, n.o.s.
Fl ammabl e sol i d, i norgani c, 134 3180
Fl ammabl e sol i d, i norgani c, 133 3178
n.o.s.
Fl ammabl e sol i d, n.o.s. 133 1325
Fl ammabl e sol i d, organi c, 133 3176
mol ten, n.o.s.
Fl ammabl e sol i d, organi c, n.o.s. 133 1325
Fl ammabl e sol i d, oxi di zi ng, 140 3097
n.o.s.
Fl ammabl e sol i d, poi sonous, 134 3179
i norgani c, n.o.s.
n.o.s.
organi c, n.o.s.
Fl ammabl e sol i d, toxi c, 134 3179
i norgani c, n.o.s.
Fl ammabl e sol i d, toxi c, organi c, 134 2926
n.o.s.
Fl uobori c aci d 154 1775
Fluorine 124 1045
Fl uori ne, compressed 124 1045
Fluorine, refrigerated liquid 167 9192
Fluoroacetic acid 154 2642
Fluoroanilines 153 2941
Fluorobenzene 130 2387
Fluoroboric acid 154 1775
Fl uorophosphori c aci d, 154 1776
anhydrous
Fl uorosi l i cates, n.o.s. 151 2856
Fl uorosi l i ci c aci d 154 1778
Fluorosulfonic acid 137 1777
Fluorosulphonic acid 137 1777
Fluorotoluenes 130 2388
Fl uosi l i ci c aci d 154 1778
Formal dehyde, sol uti on, 132 1198
flammable
Formal dehyde, sol uti ons 132 1198
(Formalin)
Formal dehyde, sol uti ons 132 2209
(Formal i n) (corrosi ve)
Formi c aci d 153 1779
No. No.
No. No.
Page 124
Fuel , avi ati on, turbi ne engi ne 128 1863
Fuel oi l 128 1202
Fuel oi l 128 1993
Fuel oi l , no. 1,2,4,5,6 128 1202
Fumaryl chl ori de 156 1780
Fumigated unit 171 3359
Fural dehydes 132P 1199
Furan 128 2389
Furfural 132P 1199
Furfuraldehydes 132P 1199
Furfuryl al cohol 153 2874
Furfurylamine 132 2526
Fusee (rai l or hi ghway) 133 1325
Fusel oi l 127 1201
GA 153 2810
Gallium 172 2803
Gas, refrigerated liquid, 115 3312
fl ammabl e, n.o.s.
Gas, refri gerated l i qui d, n.o.s. 120 3158
Gas, refrigerated liquid, 122 3311
Gas cartri dges 115 2037
Gas generator assembl i es 171 8013
Gas identification set 123 9035
Gasohol 128 1203
Gas oi l 128 1202
Gasoline 128 1203
Gas sampl e, non-pressuri zed, 115 3167
fl ammabl e, n.o.s., not
refrigerated liquid
poi sonous, fl ammabl e, n.o.s.,
not refrigerated liquid
poi sonous, n.o.s., not
refrigerated liquid
toxi c, fl ammabl e, n.o.s., not
refrigerated liquid
toxi c, n.o.s., not refri gerated
liquid
GB 153 2810
GD 153 2810
Geneti cal l y modi fi ed mi cro- 171 3245
organisms
Germane 119 2192
GF 153 2810
Gl ycerol al pha- 153 2689
monochlorohydrin
Gl yci dal dehyde 131P 2622
Guanidine nitrate 143 1467
H 153 2810
Hafni um powder, dry 135 2545
Hafni um powder, wetted wi th not 170 1326
Halogenated irritating liquid, 159 1610
n.o.s.
Hay, wet, damp or contami nated 133 1327
wi th oi l
Hazardous waste, l i qui d, n.o.s. 171 3082
Hazardous wast e, sol i d, n. o. s. 171 3077
HD 153 2810
Heati ng oi l , l i ght 128 1202
Heat produci ng arti cl e 171 8038
Hel i um 121 1046
Hel i um, compressed 121 1046
Helium, refrigerated liquid 120 1963
No. No.
No. No.
Page 125
Heptafluoropropane 126 3296
n-Heptaldehyde 129 3056
Heptanes 128 1206
n-Heptene 128 2278
Hexachloroacetone 153 2661
Hexachlorobenzene 152 2729
Hexachlorobutadiene 151 2279
Hexachl orocycl opentadi ene 151 2646
Hexachl orophene 151 2875
Hexadecyl tri chl orosi l ane 156 1781
Hexadi ene 130 2458
Hexaethyl tetraphosphate 151 1611
Hexaethyl tetraphosphate, l i qui d 151 1611
Hexaethyl tetraphosphate, sol i d 151 1611
Hexaethyl tetraphosphate and 123 1612
compressed gas mi xture
Hexafluoroacetone 125 2420
Hexafluoroacetone hydrate 151 2552
Hexafl uoroacetone hydrate, 151 2552
liquid
Hexafl uoroacetone hydrate, 151 3436
sol i d
Hexafluoroethane 126 2193
Hexafluoroethane, compressed 126 2193
Hexafl uorophosphori c aci d 154 1782
Hexafl uoropropyl ene 126 1858
Hexafl uoropropyl ene oxi de 126 1956
Hexal dehyde 130 1207
Hexamethyl enedi ami ne, sol i d 153 2280
Hexamethyl enedi ami ne, 153 1783
solution
Hexamethyl ene di i socyanate 156 2281
Hexamethyl enei mi ne 132 2493
Hexamethylenetetramine 133 1328
Hexami ne 133 1328
Hexanes 128 1208
Hexanoi c aci d 153 2829
Hexanol s 129 2282
1-Hexene 128 2370
Hexyl tri chl orosi l ane 156 1784
HL 153 2810
HN- 1 153 2810
HN- 2 153 2810
HN- 3 153 2810
Hydrazi ne, anhydrous 132 2029
Hydrazi ne, aqueous sol uti on, 153 2030
wi th more than 37%
Hydrazi ne
wi th not l ess than 37% but not
more t han 64% Hydrazi ne
Hydrazi ne
Hydrazi ne, aqueous sol uti ons, 132 2029
wi t h more t han 64% Hydrazi ne
Hydrazi ne hydrate 153 2030
Hydri des, met al , n. o. s. 138 1409
Hydri odi c aci d 154 1787
Hydri odi c aci d, sol uti on 154 1787
Hydrobromi c aci d 154 1788
Hydrobromi c aci d, sol uti on 154 1788
Hydrocarbon gas, compressed, 115 1964
n.o.s.
Hydrocarbon gas, l i quefi ed, 115 1965
n.o.s.
Hydrocarbon gas mi xture, 115 1964
compressed, n.o.s.
Hydrocarbon gas mi xture, 115 1965
l i quefi ed, n.o.s.
No. No.
No. No.
Page 126
Hydrocarbon gas refi l l s for smal l 115 3150
devi ces, wi th rel ease devi ce
Hydrocarbons, l i qui d, n.o.s. 128 3295
Hydrochl ori c aci d 157 1789
Hydrochl ori c aci d, sol uti on 157 1789
Hydrocyani c aci d, aqueous 154 1613
sol uti on, wi th l ess than 5%
Hydrogen cyani de
sol uti ons, wi th more than 20%
Hydrogen cyani de
Hydrocyani c aci d, l i quefi ed 117 1051
Hydrofl uori c aci d 157 1790
Hydrofl uori c aci d, sol uti on 157 1790
Hydrofl uori c aci d and Sul furi c 157 1786
aci d mi xture
Hydrofl uori c aci d and Sul phuri c 157 1786
aci d mi xture
Hydrofl uorosi l i ci c aci d 154 1778
Hydrogen 115 1049
Hydrogen, absorbed i n metal 115 9279
hydride
Hydrogen, compressed 115 1049
Hydrogen, i n a metal hydri de 115 3468
storage system
Hydrogen, refri gerated l i qui d 115 1966
Hydrogen and Carbon monoxi de 119 2600
mixture
Hydrogen and Carbon monoxi de 119 2600
Hydrogen and Methane mi xture, 115 2034
compressed
Hydrogen bromi de, anhydrous 125 1048
Hydrogen chl ori de, anhydrous 125 1050
Hydrogen chl ori de, refri gerated 125 2186
liquid
Hydrogen cyani de, anhydrous, 117 1051
stabilized
Hydrogen cyani de, anhydrous, 152 1614
stabilized (absorbed)
Hydrogen cyani de, aqueous 154 1613
Hydrogen cyani de, sol uti on i n 131 3294
al cohol , wi th not more than
Hydrogen cyani de, stabi l i zed 117 1051
Hydrogen cyani de, stabi l i zed 152 1614
(absorbed)
Hydrogendi fl uori des, n.o.s. 154 1740
Hydrogen fl uori de, anhydrous 125 1052
Hydrogen i odi de, anhydrous 125 2197
Hydrogen peroxi de, aqueous 143 2015
sol uti on, stabi l i zed, wi th more
than 60% Hydrogen peroxi de
sol uti on, wi th not l ess than 8%
but l ess than 20% Hydrogen
peroxide
sol uti on, wi th not l ess than
Hydrogen peroxi de (stabi l i zed
as necessary)
Hydrogen peroxi de, stabi l i zed 143 2015
Hydrogen peroxi de and 140 3149
Peroxyaceti c aci d mi xture,
wi th aci d(s), water and not
more t han 5% Peroxyacet i c
acid, stabilized
Hydrogen sel eni de, anhydrous 117 2202
Hydrogen sul fi de 117 1053
No. No.
No. No.
Page 127
Hydrogen sul fi de, l i quefi ed 117 1053
Hydrogen sul phi de 117 1053
Hydrogen sul phi de, l i quefi ed 117 1053
Hydroqui none 153 2662
Hydroqui none, sol i d 153 2662
Hydroqui none, sol uti on 153 3435
Hydroxyl ami ne sul fate 154 2865
Hydroxyl ami ne sul phate 154 2865
Hypochl ori te sol uti on 154 1791
Hypochl ori te sol uti on, wi th more 154 1791
than 5% avai l abl e Chl ori ne
Hypochl ori tes, i norgani c, n.o.s. 140 3212
3,3' -Imi nodi propyl ami ne 153 2269
Infectious substance, affecting 158 2900
ani mal s onl y
Infectious substance, affecting 158 2814
humans
Ink, pri nter s, fl ammabl e 129 1210
Insecticide gas, flammable, n.o.s. 115 1954
Insecticide gas, flammable, n.o.s. 115 3354
Insecti ci de gas, n.o.s. 126 1968
Insecti ci de gas, poi sonous, 119 3355
fl ammabl e, n.o.s.
fl ammabl e, n.o.s.
fl ammabl e, n.o.s.
fl ammabl e, n.o.s.
fl ammabl e, n.o.s.
n.o.s.
Insecti ci de gas, toxi c, fl ammabl e, 119 3355
n. o. s.
n. o. s.
n. o. s.
n. o. s.
n. o. s.
I nsect i ci de gas, t oxi c, n. o. s. 123 1967
Iodine monochloride 157 1792
Iodine pentafluoride 144 2495
2-Iodobutane 129 2390
Iodomethylpropanes 129 2391
Iodopropanes 129 2392
IPDI 156 2290
Iron oxi de, spent 135 1376
Iron pentacarbonyl 131 1994
Iron sponge, spent 135 1376
Isobutane 115 1075
Isobutane 115 1969
Isobutane mixture 115 1075
Isobutane mixture 115 1969
Isobutanol 129 1212
Isobutyl acetate 129 1213
Isobutyl acryl ate 130P 2527
Isobutyl acryl ate, i nhi bi ted 130P 2527
Isobutyl acryl ate, stabi l i zed 130P 2527
Isobutyl al cohol 129 1212
Isobutyl al dehyde 130 2045
No. No.
No. No.
Page 128
Isobutyl ami ne 132 1214
Isobutyl chloroformate 155 2742
Isobutyl ene 115 1055
Isobutyl ene 115 1075
Isobutyl formate 129 2393
Isobutyl i sobutyrate 130 2528
Isobutyl i socyanate 155 2486
Isobutyl methacryl ate 130P 2283
Isobutyl methacryl ate, i nhi bi ted 130P 2283
Isobutyl methacryl ate, stabi l i zed 130P 2283
Isobutyl propionate 129 2394
Isobutyral dehyde 130 2045
Isobutyri c aci d 132 2529
Isobutyri c anhydri de 132 2530
Isobutyronitrile 131 2284
Isobutyryl chl ori de 132 2395
Isocyanate sol uti on, fl ammabl e, 155 2478
poi sonous, n.o.s.
Isocyanate sol uti on, fl ammabl e, 155 2478
t oxi c, n. o. s.
Isocyanate sol uti on, poi sonous, 155 3080
fl ammabl e, n.o.s.
Isocyanate sol uti on, poi sonous, 155 2206
n.o.s.
Isocyanate sol uti on, toxi c, 155 3080
fl ammabl e, n.o.s.
Isocyanate sol uti on, toxi c, n.o.s. 155 2206
Isocyanate sol uti ons, n.o.s. 155 2206
Isocyanates, fl ammabl e, 155 2478
poi sonous, n.o.s.
Isocyanates, fl ammabl e, toxi c, 155 2478
n.o.s.
I socyanat es, n. o. s. 155 2206
Isocyanates, poi sonous, 155 3080
fl ammabl e, n.o.s.
Isocyanates, poi sonous, n.o.s. 155 2206
Isocyanates, toxi c, fl ammabl e, 155 3080
n.o.s.
I socyanat es, t oxi c, n. o. s. 155 2206
Isocyanatobenzotrifluorides 156 2285
Isoheptenes 128 2287
Isohexenes 128 2288
Isooctane 128 1262
Isooctenes 128 1216
Isopentane 128 1265
Isopentenes 128 2371
Isophoronediamine 153 2289
Isophorone di i socyanate 156 2290
Isoprene, inhibited 130P 1218
Isoprene, stabi l i zed 130P 1218
Isopropanol 129 1219
Isopropenyl acetate 129P 2403
Isopropenylbenzene 128 2303
Isopropyl acetate 129 1220
Isopropyl aci d phosphate 153 1793
Isopropyl al cohol 129 1219
Isopropyl ami ne 132 1221
Isopropylbenzene 130 1918
Isopropyl butyrate 129 2405
Isopropyl chl oroacetate 155 2947
Isopropyl chl oroformate 155 2407
Isopropyl 2-chloropropionate 129 2934
Isopropyl i sobutyrate 127 2406
Isopropyl i socyanate 155 2483
No. No.
No. No.
Page 129
Isopropyl nitrate 130 1222
Isopropyl propionate 129 2409
Isosorbide dinitrate mixture 133 2907
Isosorbide-5-mononitrate 133 3251
Kerosene 128 1223
Ketones, l i qui d, n.o.s. 127 1224
Krypton 121 1056
Krypton, compressed 121 1056
Krypton, refrigerated liquid 120 1970
L (Lewi si te) 153 2810
Lead acetate 151 1616
Lead arsenates 151 1617
Lead arsenites 151 1618
Lead compound, sol ubl e, n.o.s. 151 2291
Lead cyani de 151 1620
Lead di oxi de 141 1872
Lead nitrate 141 1469
Lead perchlorate 141 1470
Lead perchlorate, solid 141 1470
Lead perchlorate, solution 141 1470
Lead perchlorate, solution 141 3408
Lead phosphite, dibasic 133 2989
Lead sul fate, wi th more than 3% 154 1794
free acid
Lead sul phate, wi th more than 154 1794
3% f ree aci d
Lewisite 153 2810
Li fe-savi ng appl i ances, not sel f- 171 3072
inflating
Li fe-savi ng appl i ances, sel f- 171 2990
inflating
Lighter refills (cigarettes) 115 1057
(flammable gas)
Lighters (cigarettes) 115 1057
(flammable gas)
Lighters for cigars, cigarettes 128 1226
(flammable liquid)
Liquefied gas (nonflammable) 120 1058
Li quefi ed gas, fl ammabl e, n.o.s. 115 1954
Li quefi ed gas, fl ammabl e, n.o.s. 115 3161
Liquefied gas, flammable, 119 1953
poi sonous, n.o.s.
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
Li quefi ed gas, fl ammabl e, toxi c, 119 1953
n.o.s.
Zone A)
Zone B)
Zone C)
Zone D)
Li quefi ed gas, n.o.s. 126 1956
Li quefi ed gas, n.o.s. 126 3163
Li quefi ed gas, oxi di zi ng, n.o.s. 122 3157
No. No.
No. No.
Page 130
Liquefied gas, poisonous, 123 3308
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
fl ammabl e, n.o.s.
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
Li quefi ed gas, poi sonous, n.o.s. 123 1955
No. No.
No. No.
Page 131
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
Li quefi ed gas, toxi c, corrosi ve, 123 3308
n.o.s.
Zone A)
Zone B)
Zone C)
Zone D)
Li quefi ed gas, toxi c, fl ammabl e, 119 3309
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
n.o.s.
Zone A)
Zone B)
Zone C)
Zone D)
Li quefi ed gas, toxi c, n.o.s. 123 1955
Li quefi ed gas, toxi c, oxi di zi ng, 124 3310
Hazard Zone A)
No. No.
No. No.
Page 132
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
n.o.s.
Zone A)
Zone B)
Zone C)
Zone D)
Liquefied gases, non-flammable, 120 1058
charged wi th Ni trogen,
Carbon di oxi de or Ai r
Li quefi ed natural gas (cryogeni c 115 1972
liquid)
Liquefied petroleum gas 115 1075
Lithium 138 1415
Li thi um al kyl s 135 2445
Li thi um al kyl s, l i qui d 135 2445
Li thi um al kyl s, sol i d 135 3433
Li thi um al umi num hydri de 138 1410
Li thi um al umi num hydri de, 138 1411
ethereal
Lithium amide 139 1412
Lithium batteries 138 3090
Li thi um batteri es, l i qui d or sol i d 138 3090
cathode
Lithium batteries contained in 138 3091
equipment
Lithium batteries packed with 138 3091
equipment
Lithium borohydride 138 1413
Lithium ferrosilicon 139 2830
Li thi um hydri de 138 1414
Li thi um hydri de, fused sol i d 138 2805
Li thi um hydroxi de 154 2680
Li thi um hydroxi de, monohydrate 154 2680
Li thi um hydroxi de, sol i d 154 2680
Li thi um hydroxi de, sol uti on 154 2679
Li thi um hypochl ori te, dry 140 1471
Li thi um hypochl ori te mi xture 140 1471
Li thi um hypochl ori te mi xtures, 140 1471
dr y
Lithium nitrate 140 2722
Lithium nitride 138 2806
Lithium peroxide 143 1472
Li thi um si l i con 138 1417
LNG (cryogeni c l i qui d) 115 1972
London purple 151 1621
LPG 115 1075
Magnesium 138 1869
Magnesi um, i n pel l ets, turni ngs 138 1869
or ribbons
Magnesi um al kyl s 135 3053
Magnesi um al l oys, wi th more 138 1869
than 50% Magnesi um, i n
pellets, turnings or ribbons
Magnesi um al l oys powder 138 1418
Magnesium aluminum phosphide 139 1419
Magnesium arsenate 151 1622
No. No.
No. No.
Page 133
Magnesium bromate 140 1473
Magnesium chlorate 140 2723
Magnesi um chl ori de and 140 1459
Chl orate mi xture
Chl orate mi xture, sol i d
Chl orate mi xture, sol uti on
Magnesium diamide 135 2004
Magnesi um di phenyl 135 2005
Magnesium fluorosilicate 151 2853
Magnesium granules, coated 138 2950
Magnesi um hydri de 138 2010
Magnesium nitrate 140 1474
Magnesium perchlorate 140 1475
Magnesi um peroxi de 140 1476
Magnesium phosphide 139 2011
Magnesi um powder 138 1418
Magnesi um si l i ci de 138 2624
Magnesi um si l i cofl uori de 151 2853
Magnetized material 171 2807
Mal ei c aci d 156 2215
Mal ei c anhydri de 156 2215
Mal ei c anhydri de, mol ten 156 2215
Malononitrile 153 2647
Maneb 135 2210
Maneb, stabi l i zed 135 2968
Maneb preparation, stabilized 135 2968
Maneb preparati on, wi th not l ess 135 2210
t han 60% Maneb
Manganese nitrate 140 2724
Manganese resinate 133 1330
Matches, fusee 133 2254
Matches, safety 133 1944
Mat ches, st ri ke anywhere 133 1331
Mat ches, wax vest a 133 1945
MD 152 1556
Medi cal wast e, n. o. s. 158 3291
Medi ci ne, l i qui d, fl ammabl e, 131 3248
poi sonous, n.o.s.
Medi ci ne, l i qui d, fl ammabl e, 131 3248
t oxi c, n. o. s.
Medi ci ne, l i qui d, poi sonous, 151 1851
n.o.s.
Medi ci ne, l i qui d, t oxi c, n. o. s. 151 1851
Medi ci ne, sol i d, poi sonous, 151 3249
n.o.s.
Medi ci ne, sol i d, t oxi c, n. o. s. 151 3249
Medi ci nes, corrosi ve, l i qui d, 154 1760
n.o.s.
Medi ci nes, corrosi ve, sol i d, 154 1759
n.o.s.
Medi ci nes, fl ammabl e, l i qui d, 128 1993
n.o.s.
Medi ci nes, fl ammabl e, sol i d, 133 1325
n.o.s.
Medi ci nes, oxi di zi ng 140 1479
substances, sol i d, n.o.s.
Mercaptan mi xture, l i qui d, 130 3336
fl ammabl e, n.o.s.
fl ammabl e, poi sonous, n.o.s.
fl ammabl e, toxi c, n.o.s.
Mercaptan mi xture, l i qui d, toxi c, 131 3071
fl ammabl e, n.o.s.
Mercaptan mi xtures, l i qui d, 131 1228
n.o.s.
No. No.
No. No.
Page 134
Mercaptan mi xtures, l i qui d, 131 3071
n.o.s.
Mercaptans, l i qui d, fl ammabl e, 130 3336
n.o.s.
poi sonous, n.o.s.
t oxi c, n. o. s.
Mercaptans, l i qui d, n.o.s. 131 3071
Mercaptans, l i qui d, poi sonous, 131 3071
fl ammabl e, n.o.s.
Mercaptans, l i qui d, toxi c, 131 3071
fl ammabl e, n.o.s.
Mercuri c arsenate 151 1623
Mercuri c bromi de 154 1634
Mercuri c chl ori de 154 1624
Mercuri c cyani de 154 1636
Mercuric nitrate 141 1625
Mercuri c oxycyani de 151 1642
Mercuri c potassi um cyani de 157 1626
Mercuric sulfate 151 1645
Mercuri c sul phate 151 1645
Mercurous bromi de 154 1634
Mercurous nitrate 141 1627
Mercury 172 2809
Mercury acetate 151 1629
Mercury ammoni um chl ori de 151 1630
Mercury based pesti ci de, l i qui d, 131 2778
fl ammabl e, toxi c
poisonous
t oxi c
toxi c, fl ammabl e
Mercury based pesti ci de, sol i d, 151 2777
poisonous
Mercury based pesti ci de, sol i d, 151 2777
t oxi c
Mercury benzoate 154 1631
Mercury bromi des 154 1634
Mercury compound, l i qui d, n.o.s. 151 2024
Mercury compound, sol i d, n. o. s. 151 2025
Mercury cyani de 154 1636
Mercury gl uconate 151 1637
Mercury i odi de 151 1638
Mercury metal 172 2809
Mercury nucl eate 151 1639
Mercury ol eate 151 1640
Mercury oxi de 151 1641
Mer cur y oxycyani de, 151 1642
desensitized
Mercury potassi um i odi de 151 1643
Mercury sal i cyl at e 151 1644
Mercury sul fate 151 1645
Mercury sul phate 151 1645
Mercury thi ocyanate 151 1646
Mesi t yl oxi de 129 1229
Metal al kyl , sol uti on, n.o.s. 135 9195
Met al al kyl hal i des, n. o. s. 138 3049
Metal al kyl hal i des, water- 138 3049
reacti ve, n.o.s.
Met al al kyl hydri des, n. o. s. 138 3050
Metal al kyl hydri des, water- 138 3050
reacti ve, n.o.s.
Met al al kyl s, n. o. s. 135 2003
No. No.
No. No.
Page 135
Metal al kyl s, water-reacti ve, 135 2003
n.o.s.
Metal aryl hal i des, n.o.s. 138 3049
Metal aryl hal i des, water- 138 3049
reacti ve, n.o.s.
Met al aryl hydri des, n. o. s. 138 3050
Metal aryl hydri des, water- 138 3050
reacti ve, n.o.s.
Met al aryl s, n. o. s 135 2003
Metal aryl s, water-reacti ve, 135 2003
n.o.s.
Metal carbonyl s, l i qui d, n.o.s. 151 3281
Met al carbonyl s, n. o. s. 151 3281
Met al carbonyl s, sol i d, n. o. s. 151 3466
Met al cat al yst , dry 135 2881
Metal catal yst, wetted 170 1378
Metal dehyde 133 1332
Metal hydrides, flammable, n.o.s. 170 3182
Metal hydri des, water-reacti ve, 138 1409
n.o.s.
Metal l i c substance, water- 138 3208
reacti ve, n.o.s.
Metal l i c substance, water- 138 3209
reacti ve, sel f-heati ng, n.o.s.
Metal powder, fl ammabl e, n.o.s. 170 3089
Metal powder, self-heating, n.o.s. 135 3189
Metal sal ts of organi c 133 3181
compounds, fl ammabl e, n.o.s.
Methacryl al dehyde 131P 2396
Methacryl al dehyde, i nhi bi ted 131P 2396
Methacryl al dehyde, stabi l i zed 131P 2396
Methacryl i c aci d, i nhi bi ted 153P 2531
Methacryl i c aci d, stabi l i zed 153P 2531
Methacrylonitrile, inhibited 131P 3079
Methacryl oni tri l e, stabi l i zed 131P 3079
Methal l yl al cohol 129 2614
Methane 115 1971
Methane, compressed 115 1971
Methane, refrigerated liquid 115 1972
Methane and Hydrogen mi xture, 115 2034
compressed
Methanesul fonyl chl ori de 156 3246
Methanesulphonyl chloride 156 3246
Methanol 131 1230
Met hoxymet hyl i socyanat e 155 2605
4-Methoxy-4-methyl - 128 2293
pentan-2-one
1-Methoxy-2-propanol 129 3092
Methyl acetate 129 1231
Methyl acetyl ene and 116P 1060
Propadi ene mi xture,
stabilized
Methyl acryl ate, i nhi bi ted 129P 1919
Methyl acryl ate, stabi l i zed 129P 1919
Methyl al 127 1234
Methyl al cohol 131 1230
Methyl al l yl chl ori de 130P 2554
Methyl ami ne, anhydrous 118 1061
Methyl ami ne, aqueous sol uti on 132 1235
Methyl amyl acetate 130 1233
Methyl amyl al cohol 129 2053
Methyl amyl ketone 127 1110
N-Methyl ani l i ne 153 2294
Methyl benzoate 152 2938
al pha-Methyl benzyl al cohol 153 2937
al pha-Methyl benzyl al cohol , 153 2937
liquid
al pha-Methyl benzyl al cohol , 153 3438
sol i d
No. No.
No. No.
Page 136
Methyl benzyl al cohol (al pha) 153 2937
Methyl bromi de 123 1062
Methyl bromi de and Chl oropi cri n 123 1581
mixture
Methyl bromi de and Ethyl ene 151 1647
di bromi de mi xture, l i qui d
Methyl bromoacetate 155 2643
2-Methylbutanal 129 3371
3-Methylbutan-2-one 127 2397
2-Methyl-1-butene 128 2459
N-Methyl butyl ami ne 132 2945
Methyl tert-butyl ether 127 2398
Methyl butyrate 129 1237
Methyl chl ori de 115 1063
Methyl chl ori de and Chl oropi cri n 119 1582
mixture
Methyl chl ori de and Methyl ene 115 1912
chloride mixture
Methyl chl oroacetate 155 2295
Methyl chl oroformate 155 1238
Methyl chl oromethyl ether 131 1239
Methyl 2-chloropropionate 129 2933
Methyl chl orosi l ane 119 2534
Met hyl cyani de 127 1648
Met hyl cycl ohexane 128 2296
Met hyl cycl ohexanol s 129 2617
Methyl cycl ohexanone 128 2297
Methyl cycl opentane 128 2298
Methyl di chl oroacetate 155 2299
Methyl di chl oroarsi ne 152 1556
Methyl di chl orosi l ane 139 1242
Methyl ene chl ori de 160 1593
Methyl ene chl ori de and Methyl 115 1912
chloride mixture
Methyl ethyl ether 115 1039
Methyl ethyl ketone 127 1193
2-Methyl -5-ethyl pyri di ne 153 2300
Methyl fl uori de 115 2454
Methyl formate 129 1243
2-Methylfuran 128 2301
2-Methyl-2-hepthanethiol 131 3023
5-Methyl hexan-2-one 127 2302
Methyl hydrazi ne 131 1244
Methyl i odi de 151 2644
Methyl i sobutyl carbi nol 129 2053
Methyl i sobutyl ketone 127 1245
Methyl i socyanate 155 2480
Methyl i sopropenyl ketone, 127P 1246
inhibited
Methyl i sopropenyl ketone, 127P 1246
stabilized
Methyl i sothi ocyanate 131 2477
Methyl i soval erate 130 2400
Methyl magnesi um bromi de i n 135 1928
Ethyl ether
Methyl mercaptan 117 1064
Methyl methacryl ate monomer, 129P 1247
inhibited
Methyl methacryl ate monomer, 129P 1247
stabilized
4-Methylmorpholine 132 2535
N-Methyl morphol i ne 132 2535
Methylmorpholine 132 2535
Methyl ni tri te 116 2455
Methyl orthosi l i cate 155 2606
Methyl parathi on, l i qui d 152 3018
No. No.
No. No.
Page 137
Methyl parathi on, sol i d 152 2783
Methylpentadiene 128 2461
2-Methylpentan-2-ol 129 2560
Methyl phenyl di chl orosi l ane 156 2437
Methyl phosphoni c di chl ori de 137 9206
Methyl phosphonous di chl ori de 135 2845
1-Methylpiperidine 132 2399
Methyl propionate 129 1248
Methyl propyl ether 127 2612
Methyl propyl ketone 127 1249
Methyltetrahydrofuran 127 2536
Methyl trichloroacetate 156 2533
Methyl tri chl orosi l ane 155 1250
al pha-Methyl val eral dehyde 130 2367
Methyl val eral dehyde (al pha) 130 2367
Met hyl vi nyl ket one 131P 1251
Methyl vi nyl ketone, stabi l i zed 131P 1251
M. I . B. C. 129 2053
Mol ybdenum pentachl ori de 156 2508
Monoethanolamine 153 2491
Mononitrotoluidines 153 2660
Monopropyl ami ne 132 1277
Morpholine 132 2054
Motor fuel anti -knock mi xture 131 1649
Motor spi ri t 128 1203
Muri ati c aci d 157 1789
Musk xyl ene 149 2956
Mustard 153 2810
Mustard Lewi si te 153 2810
Naphthalene, crude 133 1334
Naphthalene, molten 133 2304
Naphthalene, refined 133 1334
alpha-Naphthylamine 153 2077
Naphthyl ami ne (al pha) 153 2077
beta-Naphthylamine 153 1650
beta-Naphthylamine, solid 153 1650
beta-Naphthylamine, solution 153 3411
Naphthylamine (beta) 153 1650
Naphthyl ami ne (beta), sol i d 153 1650
Naphthyl ami ne (beta), sol uti on 153 3411
Naphthylthiourea 153 1651
Naphthyl urea 153 1652
Natural gas, compressed 115 1971
Natural gas, refrigerated liquid 115 1972
Neohexane 128 1208
Neon 121 1065
Neon, compressed 121 1065
Neon, refrigerated liquid 120 1913
Ni ckel carbonyl 131 1259
Ni ckel cat al yst , dry 135 2881
Ni ckel cyani de 151 1653
Ni ckel ni trate 140 2725
Ni ckel ni tri te 140 2726
Nicotine 151 1654
Ni coti ne compound, l i qui d, 151 3144
n.o.s.
Ni coti ne compound, sol i d, n.o.s. 151 1655
Ni coti ne hydrochl ori de 151 1656
Ni coti ne hydrochl ori de, l i qui d 151 1656
Ni coti ne hydrochl ori de, sol i d 151 1656
Ni coti ne hydrochl ori de, sol i d 151 3444
Ni coti ne hydrochl ori de, sol uti on 151 1656
Ni coti ne preparati on, l i qui d, 151 3144
n.o.s.
No. No.
No. No.
Page 138
Ni coti ne preparati on, sol i d, 151 1655
n.o.s.
Ni coti ne sal i cyl ate 151 1657
Ni coti ne sul fate, sol i d 151 1658
Ni coti ne sul fate, sol i d 151 3445
Nicotine sulfate, solution 151 1658
Ni coti ne sul phate, sol i d 151 1658
Ni coti ne sul phate, sol i d 151 3445
Nicotine sulphate, solution 151 1658
Nicotine tartrate 151 1659
Ni trates, i norgani c, aqueous 140 3218
sol uti on, n.o.s.
Ni trates, i norgani c, n.o.s. 140 1477
Ni trati ng aci d mi xture 157 1796
Ni trati ng aci d mi xture, spent 157 1826
Ni tri c aci d, fumi ng 157 2032
Ni tri c aci d, other than red fumi ng 157 2031
Ni tri c aci d, red fumi ng 157 2032
Ni t ri c oxi de 124 1660
Ni tri c oxi de, compressed 124 1660
Ni tri c oxi de and Di ni trogen 124 1975
tetroxi de mi xture
Ni tri c oxi de and Ni trogen di oxi de 124 1975
mixture
Ni tri c oxi de and Ni trogen 124 1975
tetroxi de mi xture
Ni tri l es, fl ammabl e, poi sonous, 131 3273
n.o.s.
Ni t ri l es, f l ammabl e, t oxi c, n. o. s. 131 3273
Ni tri l es, poi sonous, fl ammabl e, 131 3275
n.o.s.
Ni tri l es, poi sonous, l i qui d, n.o.s. 151 3276
Ni tri l es, poi sonous, n.o.s. 151 3276
Ni tri l es, poi sonous, sol i d, n.o.s. 151 3439
Ni t ri l es, t oxi c, f l ammabl e, n. o. s. 131 3275
Ni t ri l es, t oxi c, l i qui d, n. o. s. 151 3276
Ni t ri l es, t oxi c, n. o. s. 151 3276
Ni t ri l es, t oxi c, sol i d, n. o. s. 151 3439
Ni tri tes, i norgani c, aqueous 140 3219
sol uti on, n.o.s.
Ni tri tes, i norgani c, n.o.s. 140 2627
Nitroanilines 153 1661
Ni troani sol es 152 2730
Ni troani sol es, l i qui d 152 2730
Ni troani sol es, sol i d 152 2730
Ni troani sol es, sol i d 152 3458
Nitrobenzene 152 1662
Nitrobenzenesulfonic acid 153 2305
Nitrobenzenesulphonic acid 153 2305
Nitrobenzotrifluorides 152 2306
Nitrobenzotrifluorides, liquid 152 2306
Nitrobenzotrifluorides, solid 152 3431
Nitrobromobenzenes 152 2732
Nitrobromobenzenes, liquid 152 2732
Nitrobromobenzenes, solid 152 2732
Nitrobromobenzenes, solid 152 3459
Ni trocel l ul ose, sol uti on, 127 2059
flammable
Ni trocel l ul ose, sol uti on, i n a 127 2059
flammable liquid
Nitrocellulose membrane filters 133 3270
Ni trocel l ul ose mi xture, wi thout 133 2557
plasticizer, without pigment
Ni trocel l ul ose mi xture, wi thout 133 2557
pl asti ci zer, wi th pi gment
Ni trocel l ul ose mi xture, wi th 133 2557
plasticizer, without pigment
Ni trocel l ul ose mi xture, wi th 133 2557
pl asti ci zer, wi th pi gment
Ni trocel l ul ose wi th al cohol 113 2556
No. No.
No. No.
Page 139
Ni trocel l ul ose wi th not l ess than 113 2556
25% al cohol
Ni trocel l ul ose wi th pl asti ci zi ng 133 2557
substance
Ni trocel l ul ose wi th water, not 113 2555
3-Nitro-4-chlorobenzotrifluoride 152 2307
Ni trocresol s 153 2446
Ni trocresol s, l i qui d 153 3434
Ni trocresol s, sol i d 153 2446
Nitroethane 129 2842
Nitrogen 121 1066
Ni trogen, compressed 121 1066
Nitrogen, refrigerated liquid 120 1977
Ni trogen and Rare gases mi xture 121 1981
Ni trogen and Rare gases 121 1981
Ni trogen di oxi de 124 1067
Ni trogen di oxi de, l i quefi ed 124 1067
Ni trogen di oxi de and Ni tri c oxi de 124 1975
mixture
Ni trogen tetroxi de and Ni tri c 124 1975
oxi de mi xture
Nitrogen trifluoride 122 2451
Nitrogen trifluoride, compressed 122 2451
Ni trogen tri oxi de 124 2421
Ni trogl yceri n, sol uti on i n 127 3064
al cohol , wi th more than 1%
but not more than 5%
Ni trogl yceri n
Ni trogl yceri n, sol uti on i n 127 1204
al cohol , wi th not more than
1% Ni t rogl yceri n
Ni trogl yceri n mi xture, 113 3343
desensi ti zed, l i qui d, fl ammabl e,
n.o.s., wi th not more than 30%
Ni trogl yceri n
desensi ti zed, l i qui d, n.o.s.,
Ni trogl yceri n
desensi ti zed, sol i d, n.o.s.,
wi th more than 2% but not more
than 10% Ni trogl yceri n
Ni trogl yceri n mi xture wi th more 113 3319
than 2% but not more than 10%
Ni trogl yceri n, desensi ti zed
Ni troguani di ne (Pi cri te), wetted 113 1336
wi th not l ess than 20% water
Ni troguani di ne, wetted wi th not 113 1336
Ni trohydrochl ori c aci d 157 1798
Nitromethane 129 1261
Nitronaphthalene 133 2538
Nitrophenols 153 1663
4-Ni trophenyl hydrazi ne, wi th not 113 3376
Nitropropanes 129 2608
p-Nitrosodimethylaniline 135 1369
Ni trostarch, wetted wi th not l ess 113 1337
t han 20% wat er
Ni trostarch, wetted wi th not l ess 113 1337
than 30% sol vent
Ni trosyl chl ori de 125 1069
Ni trosyl sul furi c aci d 157 2308
Ni trosyl sul furi c aci d, l i qui d 157 2308
Ni trosyl sul furi c aci d, sol i d 157 2308
Ni trosyl sul furi c aci d, sol i d 157 3456
Ni trosyl sul phuri c aci d 157 2308
No. No.
No. No.
Page 140
Ni trosyl sul phuri c aci d, l i qui d 157 2308
Ni trosyl sul phuri c aci d, sol i d 157 2308
Ni trosyl sul phuri c aci d, sol i d 157 3456
Nitrotoluenes 152 1664
Nitrotoluenes, liquid 152 1664
Ni trotol uenes, sol i d 152 1664
Ni trotol uenes, sol i d 152 3446
Nitrotoluidines (mono) 153 2660
Ni trous oxi de 122 1070
Ni trous oxi de, compressed 122 1070
Ni trous oxi de, refri gerated l i qui d 122 2201
Ni trous oxi de and Carbon 126 1015
di oxi de mi xture
Ni t roxyl enes 152 1665
Ni troxyl enes, l i qui d 152 1665
Ni t roxyl enes, sol i d 152 1665
Ni t roxyl enes, sol i d 152 3447
Nonanes 128 1920
Nonyl tri chl orosi l ane 156 1799
2,5-Norbornadiene 128P 2251
2,5-Norbornadiene, inhibited 128P 2251
2,5-Norbornadiene, stabilized 128P 2251
Octadecyl tri chl orosi l ane 156 1800
Octadiene 128P 2309
Octafluorobut-2-ene 126 2422
Octafluorocyclobutane 126 1976
Octafluoropropane 126 2424
Octanes 128 1262
Oct yl al dehydes 129 1191
tert-Octyl mercaptan 131 3023
Octyl tri chl orosi l ane 156 1801
Oi l , petrol eum 128 1270
Oi l gas 119 1071
Oi l gas, compressed 119 1071
Organi c peroxi de type B, l i qui d 146 3101
Organi c peroxi de type B, l i qui d, 148 3111
Organi c peroxi de type B, sol i d 146 3102
Organi c peroxi de type B, sol i d, 148 3112
Organi c peroxi de type C, l i qui d 146 3103
Organi c peroxi de type C, l i qui d, 148 3113
Organi c peroxi de type C, sol i d 146 3104
Organi c peroxi de t ype C, sol i d, 148 3114
Organi c peroxi de type D, l i qui d 145 3105
Organi c peroxi de type D, l i qui d, 148 3115
Organi c peroxi de type D, sol i d 145 3106
Organi c peroxi de type D, sol i d, 148 3116
Organi c peroxi de type E, l i qui d 145 3107
Organi c peroxi de type E, l i qui d, 148 3117
Organi c peroxi de type E, sol i d 145 3108
Organi c peroxi de type E, sol i d, 148 3118
Organi c peroxi de type F, l i qui d 145 3109
Organi c peroxi de type F, l i qui d, 148 3119
Organi c peroxi de type F, sol i d 145 3110
Organi c peroxi de type F, sol i d, 148 3120
Organic phosphate compound 123 1955
Organi c phosphate mi xed wi th 123 1955
compressed gas
No. No.
No. No.
Page 141
Organic phosphorus compound 123 1955
Organic pigments, self-heating 135 3313
Organoarsenic compound, 151 3280
l i qui d, n.o.s.
Organoarseni c compound, n.o.s. 151 3280
Organoarsenic compound, 151 3465
sol i d, n. o. s.
Organochl ori ne pesti ci de, l i qui d, 131 2762
fl ammabl e, toxi c
poisonous
t oxi c
toxi c, fl ammabl e
Organochl ori ne pesti ci de, sol i d, 151 2761
poisonous
Organochl ori ne pesti ci de, sol i d, 151 2761
t oxi c
Organometallic compound, 151 3282
poi sonous, l i qui d, n.o.s.
poi sonous, n.o.s.
Organometal l i c compound, sol i d 138 3372
water-reactive, flammable, n.o.s.
t oxi c, n. o. s.
water-reactive, flammable, n.o.s.
Organometallic compound 138 3207
di spersi on, water-reacti ve,
fl ammabl e, n.o.s.
Organometallic compound 138 3207
sol uti on, water-reacti ve,
fl ammabl e, n.o.s.
Organometallic substance, 135 3392
l i qui d, pyrophoric
l i qui d, pyrophoric,
water-reacti ve
l i qui d, water-reacti ve
l i qui d, water-reacti ve,
flammable
sol i d, pyrophoric
sol i d, pyrophoric,
water-reacti ve
solid, self-heating
sol i d, water-reacti ve
sol i d, water-reacti ve,
flammable
sol i d, water-reacti ve,
self-heating
Organophosphorus compound, 131 3279
poi sonous, l i qui d, n.o.s.
poi sonous, n.o.s.
No. No.
No. No.
Page 142
toxi c, fl ammabl e, n.o.s.
t oxi c, n. o. s.
Organophosphorus pesticide, 131 2784
liquid, poisonous
l i qui d, toxi c
solid, poisonous
sol i d, t oxi c
Organotin compound, liquid, 153 2788
n.o.s.
Organotin compound, solid, 153 3146
n.o.s.
Organoti n pesti ci de, l i qui d, 131 2787
fl ammabl e, toxi c
poisonous
Organoti n pesti ci de, l i qui d, toxi c 153 3020
toxi c, fl ammabl e
Organoti n pesti ci de, sol i d, 153 2786
poisonous
Organoti n pesti ci de, sol i d, toxi c 153 2786
Osmi um tetroxi de 154 2471
Other regulated substances, 171 3082
l i qui d, n.o.s.
Other regulated substances, 171 3077
sol i d, n. o. s.
Oxi di zi ng l i qui d, corrosi ve, 140 3098
n.o.s.
Oxi di zi ng l i qui d, n. o. s. 140 3139
Oxidizing liquid, poisonous, n.o.s. 142 3099
Oxi di zi ng l i qui d, t oxi c, n. o. s. 142 3099
Oxidizing solid, corrosive, n.o.s. 140 3085
Oxi di zi ng sol i d, fl ammabl e, 140 3137
n.o.s.
Oxi di zi ng sol i d, n. o. s. 140 1479
Oxi di zi ng sol i d, poi sonous, 141 3087
n.o.s.
Oxi di zi ng sol i d, sel f-heati ng, 135 3100
n.o.s.
Oxi di zi ng sol i d, t oxi c, n. o. s. 141 3087
Oxi di zi ng sol i d, water-reacti ve, 144 3121
n.o.s.
Oxi di zi ng substances, l i qui d, 140 3098
n.o.s.
poi sonous, n.o.s.
t oxi c, n. o. s.
Oxi di zi ng substances, sel f- 135 3100
heati ng, n.o.s.
No. No.
No. No.
Page 143
Oxi di zi ng substances, sol i d, 140 3085
fl ammabl e, n.o.s.
n.o.s.
poi sonous, n.o.s.
sel f-heati ng, n.o.s.
t oxi c, n. o. s.
whi ch i n contact wi th water
emi t fl ammabl e gases, n.o.s.
Oxygen 122 1072
Oxygen, compressed 122 1072
Oxygen, refri gerated l i qui d 122 1073
Oxygen and Carbon di oxi de 122 1014
mixture
Oxygen and Carbon di oxi de 122 1014
Oxygen and Rare gases mi xture 121 1980
Oxygen and Rare gases mi xture, 121 1980
compressed
Oxygen di fl uori de 124 2190
Oxygen di fl uori de, compressed 124 2190
Oxygen generator, chemi cal 140 3356
Oxygen generator, chemi cal , 140 3356
spent
Pai nt (corrosi ve) 153 3066
Paint (flammable) 128 1263
Paint related material 153 3066
(corrosi ve)
Paint related material 128 1263
(flammable)
Paper, unsaturated oil treated 133 1379
Paraformaldehyde 133 2213
Paral dehyde 129 1264
Parathion 152 2783
Parathi on and compressed gas 123 1967
mixture
PCB 171 2315
PD 152 1556
Pentaborane 135 1380
Pentachloroethane 151 1669
Pentachlorophenol 154 3155
Pentaerythrite tetranitrate 113 3344
mi xture,desensi ti zed, sol i d,
n. o. s. , wi t h more t han 10%
but not more than 20% PETN
Pentafluoroethane 126 3220
Pentafluoroethane and Ethylene 126 3298
Pentamethylheptane 128 2286
Pentan-2,4-dione 131 2310
n-Pentane 128 1265
2,4-Pentanedione 131 2310
Pentane-2,4-dione 131 2310
Pentanes 128 1265
Pentanols 129 1105
1-Pentene 128 1108
1-Pentol 153P 2705
Percarbonates, i norgani c, n.o.s. 140 3217
Perchl orates, i norgani c, 140 3211
aqueous sol uti on, n.o.s.
Perchl orates, i norgani c, n.o.s. 140 1481
Perchl ori c aci d, wi th more than 143 1873
acid
No. No.
No. No.
Page 144
Perchl ori c aci d, wi th not more 140 1802
than 50% aci d
Perchloroethylene 160 1897
Perchloromethyl mercaptan 157 1670
Perchl oryl fl uori de 124 3083
Perfl uoroethyl vi nyl ether 115 3154
Perfl uoro(ethyl vi nyl ether) 115 3154
Perfl uoromethyl vi nyl ether 115 3153
Perfl uoro(methyl vi nyl ether) 115 3153
Perfumery products, wi th 127 1266
flammable solvents
Permanganates, inorganic, 140 3214
Permanganates, inorganic, 140 1482
n.o.s.
Peroxi des, i norgani c, n.o.s. 140 1483
Persul fates, i norgani c, aqueous 140 3216
sol uti on, n.o.s.
Persul fates, i norgani c, n.o.s. 140 3215
Persul phates, i norgani c, 140 3216
Persul phates, i norgani c, n.o.s. 140 3215
Pesti ci de, l i qui d, fl ammabl e, 131 3021
poi sonous, n.o.s.
Pesti ci de, l i qui d, fl ammabl e, 131 3021
t oxi c, n. o. s.
Pesti ci de, l i qui d, poi sonous, 131 2903
fl ammabl e, n.o.s.
Pesti ci de, l i qui d, poi sonous, 151 2902
n.o.s.
Pesti ci de, l i qui d, toxi c, 131 2903
fl ammabl e, n.o.s.
Pest i ci de, l i qui d, t oxi c, n. o. s. 151 2902
Pesti ci de, sol i d, poi sonous 151 2588
Pesti ci de, sol i d, poi sonous, 151 2588
n.o.s.
Pest i ci de, sol i d, t oxi c, n. o. s. 151 2588
Petrol 128 1203
Petrol eum crude oi l 128 1267
Petrol eum di sti l l ates, n.o.s. 128 1268
Petroleum gases, liquefied 115 1075
Petrol eum oi l 128 1270
Petrol eum products, n.o.s. 128 1268
Phenacyl bromi de 153 2645
Phenetidines 153 2311
Phenol , mol ten 153 2312
Phenol , sol i d 153 1671
Phenol solution 153 2821
Phenolates, liquid 154 2904
Phenolates, solid 154 2905
Phenol sul foni c aci d, l i qui d 153 1803
Phenol sul phoni c aci d, l i qui d 153 1803
Phenoxyaceti c aci d deri vati ve 131 3346
poisonous
t oxi c
pesti ci de, l i qui d, poi sonous
pesti ci de, l i qui d, poi sonous,
flammable
pesti ci de, l i qui d, toxi c
pesti ci de, l i qui d, toxi c,
flammable
pesti ci de, sol i d, toxi c
No. No.
No. No.
Page 145
Phenoxy pesti ci de, l i qui d, 131 2766
fl ammabl e, toxi c
poisonous
Phenoxy pesti ci de, l i qui d, toxi c 152 3000
Phenoxy pest i ci de, l i qui d, t oxi c, 131 2999
flammable
Phenoxy pesti ci de, sol i d, 152 2765
poisonous
Phenoxy pest i ci de, sol i d, t oxi c 152 2765
Phenylacetonitrile, liquid 152 2470
Phenyl acetyl chl ori de 156 2577
Phenyl carbyl ami ne chl ori de 151 1672
Phenyl chloroformate 156 2746
Phenylenediamines 153 1673
Phenyl hydrazi ne 153 2572
Phenyl i socyanate 155 2487
Phenyl mercaptan 131 2337
Phenyl mercuri c acetate 151 1674
Phenyl mercuri c compound, 151 2026
n.o.s.
Phenyl mercuri c hydroxi de 151 1894
Phenyl mercuri c ni trate 151 1895
Phenylphosphorus dichloride 137 2798
Phenylphosphorus 137 2799
thiodichloride
Phenyl tri chl orosi l ane 156 1804
Phenyl urea pesti ci de, l i qui d, 131 2768
fl ammabl e, toxi c
poisonous
t oxi c
toxi c, fl ammabl e
Phenyl urea pesti ci de, sol i d, 151 2767
poisonous
Phenyl urea pesti ci de, sol i d, 151 2767
t oxi c
Phosgene 125 1076
9-Phosphabi cycl ononanes 135 2940
Phosphine 119 2199
Phosphori c aci d 154 1805
Phosphori c aci d, l i qui d 154 1805
Phosphori c aci d, sol i d 154 1805
Phosphori c aci d, sol i d 154 3453
Phosphori c aci d, sol uti on 154 1805
Phosphorous acid 154 2834
Phosphorous aci d, ortho 154 2834
Phosphorus, amorphous 133 1338
Phosphorus, amorphous, red 133 1338
Phosphorus, whi te, dry or under 136 1381
Phosphorus, whi te, mol ten 136 2447
Phosphorus, yel l ow, dry or under 136 1381
Phosphorus heptasulfide, free 139 1339
from yel l ow and whi te
Phosphorus
Phosphorus heptasulphide, free 139 1339
Phosphorus
Phosphorus oxybromi de 137 1939
No. No.
No. No.
Page 146
Phosphorus oxybromi de, mol ten 137 2576
Phosphorus oxybromi de, sol i d 137 1939
Phosphorus oxychl ori de 137 1810
Phosphorus pentabromide 137 2691
Phosphorus pentachloride 137 1806
Phosphorus pentafluoride 125 2198
Phosphorus pentafluoride, 125 2198
compressed
Phosphorus pentasulfide, free 139 1340
Phosphorus
Phosphorus pentasulphide, free 139 1340
Phosphorus
Phosphorus pentoxide 137 1807
Phosphorus sesqui sul fi de, free 139 1341
Phosphorus
Phosphorus sesquisulphide, 139 1341
free from yel l ow and whi te
Phosphorus
Phosphorus tribromide 137 1808
Phosphorus trichloride 137 1809
Phosphorus tri oxi de 157 2578
Phosphorus trisulfide, free from 139 1343
yel l ow and whi te Phosphorus
Phosphorus trisulphide, free 139 1343
Phosphorus
Phthal i c anhydri de 156 2214
Phthal i mi de deri vati ve 131 2774
poisonous
t oxi c
flammable
flammable
Pi col i nes 129 2313
Pi cri c aci d, wet , wi t h not l ess 113 1344
t han 10% wat er
Pi cri c aci d, wetted wi th not l ess 113 3364
t han 10% wat er
Pi cri te, wetted 113 1336
Pi cryl chl ori de, wetted wi th not 113 3365
alpha-Pinene 128 2368
Pinene (alpha) 128 2368
Pi ne oi l 129 1272
Piperazine 153 2579
Piperidine 132 2401
Pl asti c mol di ng compound 171 3314
Pl asti c, ni trocel l ul ose-based, 135 2006
spontaneously combustible,
n.o.s.
Pl asti cs moul di ng compound 171 3314
Pl asti cs, ni trocel l ul ose-based, 135 2006
sel f-heati ng, n.o.s.
Poi son B, l i qui d, n. o. s. 153 2810
Poi sonous by i nhal ati on l i qui d, 154 3389
Hazard Zone A)
No. No.
No. No.
Page 147
Hazard Zone B)
Hazard Zone A)
Hazard Zone B)
Zone A)
Zone B)
Hazard Zone A)
Hazard Zone B)
Poi sonous l i qui d, corrosi ve, 154 3289
i norgani c, n.o.s.
i norgani c, n.o.s. (Inhal ati on
Hazard Zone A)
Hazard Zone B)
n.o.s.
Zone A)
Zone B)
Poi sonous l i qui d, fl ammabl e, 131 2929
n.o.s.
Zone A)
Zone B)
organi c, n.o.s.
organi c, n.o.s. (Inhal ati on
Hazard Zone A)
organi c, n.o.s. (Inhal ati on
Hazard Zone B)
Poi sonous l i qui d, i norgani c, 151 3287
n.o.s.
Zone A)
Zone B)
Poi sonous l i qui d, n.o.s. 153 2810
Poi sonous l i qui d, organi c, n.o.s. 153 2810
Poi sonous l i qui d, oxi di zi ng, 142 3122
n.o.s.
No. No.
No. No.
Page 148
Zone A)
Zone B)
Poi sonous l i qui d, water- 139 3123
reacti ve, n.o.s.
Hazard Zone A)
Hazard Zone B)
Poi sonous l i qui d, whi ch i n 139 3123
Poi sonous sol i d, corrosi ve, 154 3290
i norgani c, n.o.s.
Poi sonous sol i d, corrosi ve, 154 2928
n.o.s.
Poi sonous sol i d, fl ammabl e, 134 2930
n.o.s.
Poi sonous sol i d, fl ammabl e, 134 2930
organi c, n.o.s.
Poi sonous sol i d, i norgani c, 151 3288
n.o.s.
Poi sonous sol i d, organi c, n.o.s. 154 2811
Poi sonous sol i d, oxi di zi ng, 141 3086
n.o.s.
Poi sonous sol i d, sel f-heati ng, 136 3124
n.o.s.
Poi sonous sol i d, water-reacti ve, 139 3125
n.o.s.
Poi sonous sol i d, whi ch i n 139 3125
Pol yal kyl ami nes, n. o. s. 132 2733
Pol yami nes, fl ammabl e, 132 2733
Pol yami nes, l i qui d, corrosi ve, 132 2734
fl ammabl e, n.o.s.
Pol yami nes, l i qui d, corrosi ve, 153 2735
n.o.s.
Pol yami nes, sol i d, corrosi ve, 154 3259
n.o.s.
Pol ychl ori nated bi phenyl s 171 2315
Pol ychl ori nated bi phenyl s, l i qui d 171 2315
Pol ychl ori nated bi phenyl s, sol i d 171 2315
Pol ychl ori nated bi phenyl s, sol i d 171 3432
Pol yester resi n ki t 128 3269
Pol yhal ogenated bi phenyl s, 171 3151
liquid
Pol yhal ogenated bi phenyl s, 171 3152
sol i d
Pol yhal ogenated terphenyl s, 171 3151
liquid
Pol yhal ogenated terphenyl s, 171 3152
sol i d
Pol ymeri c beads, expandabl e 133 2211
Pol ystyrene beads, expandabl e 133 2211
Potassium 138 2257
Potassi um, metal 138 2257
Potassi um, metal al l oys 138 1420
Potassi um, metal al l oys, l i qui d 138 1420
Potassi um, metal al l oys, sol i d 138 3403
No. No.
No. No.
Page 149
Potassium arsenate 151 1677
Potassium arsenite 154 1678
Potassi um borohydri de 138 1870
Potassium bromate 140 1484
Potassium chlorate 140 1485
Potassium chlorate, aqueous 140 2427
solution
Potassium chlorate, solution 140 2427
Potassi um cuprocyani de 157 1679
Potassi um cyani de 157 1680
Potassi um cyani de, sol i d 157 1680
Potassi um cyani de, sol uti on 157 3413
Potassium dithionite 135 1929
Potassium fluoride 154 1812
Potassi um fl uori de, sol i d 154 1812
Potassium fluoride, solution 154 3422
Potassium fluoroacetate 151 2628
Potassium fluorosilicate 151 2655
Potassium hydrogendifluoride 154 1811
Potassi um hydrogen di fl uori de, 154 1811
sol i d
Potassi um hydrogen di fl uori de, 154 3421
solution
Potassium hydrogen sulfate 154 2509
Potassi um hydrogen sul phate 154 2509
Potassi um hydrosul fi te 135 1929
Potassi um hydrosul phi te 135 1929
Pot assi um hydroxi de, dry, sol i d 154 1813
Potassi um hydroxi de, fl ake 154 1813
Potassi um hydroxi de, sol i d 154 1813
Potassi um hydroxi de, sol uti on 154 1814
Potassium metavanadate 151 2864
Potassi um monoxi de 154 2033
Potassium nitrate 140 1486
Potassi um ni trate and Sodi um 140 1499
nitrate mixture
Potassi um ni trate and Sodi um 140 1487
ni tri te mi xture
Potassium nitrite 140 1488
Potassium perchlorate 140 1489
Potassium permanganate 140 1490
Potassi um peroxi de 144 1491
Potassium persulfate 140 1492
Potassium persulphate 140 1492
Potassium phosphide 139 2012
Potassi um si l i cofl uori de 151 2655
Potassi um sodi um al l oys 138 1422
Potassi um sodi um al l oys, l i qui d 138 1422
Potassi um sodi um al l oys, sol i d 138 3404
Potassi um sul fi de, anhydrous 135 1382
Potassi um sul fi de, hydrated, 153 1847
of crystal l i zati on
Potassi um sul fi de, hydrated, 153 1847
of hydration
Potassi um sul fi de, wi th l ess than 135 1382
30% water of crystal l i zati on
Potassi um sul fi de, wi th l ess than 135 1382
30% water of hydrati on
Potassi um sul phi de, anhydrous 135 1382
Potassi um sul phi de, hydrated, 153 1847
of crystal l i zati on
Potassi um sul phi de, hydrated, 153 1847
of hydration
Potassi um sul phi de, wi th l ess 135 1382
than 30% water of
crystal l i zati on
No. No.
No. No.
Page 150
Potassi um sul phi de, wi th l ess 135 1382
than 30% water of hydrati on
Potassi um superoxi de 143 2466
Pri nti ng i nk, fl ammabl e 129 1210
Printing ink related material 129 1210
Propadiene, inhibited 116P 2200
Propadiene, stabilized 116P 2200
Propadiene and 116P 1060
Methyl acetyl ene mi xture,
stabilized
Propane 115 1075
Propane 115 1978
Propane-Ethane mi xture, 115 1961
refrigerated liquid
Propane mi xture 115 1075
Propane mi xture 115 1978
Propanethiols 130 2402
n-Propanol 129 1274
Propargyl al cohol 131 1986
Propi onal dehyde 129 1275
Propi oni c aci d 132 1848
Propi oni c anhydri de 156 2496
Propionitrile 131 2404
Propi onyl chl ori de 132 1815
n-Propyl acetate 129 1276
normal Propyl al cohol 129 1274
Propyl al cohol , normal 129 1274
Propyl ami ne 132 1277
n-Propyl benzene 128 2364
Propyl chl ori de 129 1278
n-Propyl chl oroformate 155 2740
Propyl ene 115 1075
Propyl ene 115 1077
Propyl ene, Ethyl ene and 115 3138
Acetyl ene i n mi xture,
not more than 22.5%
6% Pr opyl ene
Propyl ene chl orohydri n 131 2611
1,2-Propylenediamine 132 2258
1,3-Propylenediamine 132 2258
Propyl ene di chl ori de 130 1279
Propyleneimine, inhibited 131P 1921
Propyl enei mi ne, stabi l i zed 131P 1921
Propyl ene oxi de 127P 1280
Propyl ene oxi de and Ethyl ene 129P 2983
Propylene tetramer 128 2850
Propyl formates 129 1281
n-Propyl i socyanate 155 2482
n-Propyl nitrate 131 1865
Propyl tri chl orosi l ane 155 1816
Pyrethroi d pesti ci de, l i qui d, 131 3350
fl ammabl e, toxi c
poisonous
Pyrethroid pesticide, liquid, toxic 151 3352
Pyrethroid pesticide, liquid, toxic, 131 3351
flammable
Pyrethroi d pesti ci de, sol i d, 151 3349
poisonous
Pyrethroi d pesti ci de, sol i d, toxi c 151 3349
Pyri di ne 129 1282
No. No.
No. No.
Page 151
Pyrophori c al l oy, n. o. s. 135 1383
Pyrophori c l i qui d, i norgani c, 135 3194
n.o.s.
Pyrophori c l i qui d, n.o.s. 135 2845
Pyrophori c l i qui d, organi c, n.o.s. 135 2845
Pyrophori c metal , n.o.s. 135 1383
Pyrophoric organometallic 135 3203
compound, n.o.s.
Pyrophoric organometallic 135 3203
compound, water-reacti ve,
n.o.s.
Pyrophori c sol i d, i norgani c, 135 3200
n.o.s.
Pyrophori c sol i d, n. o. s. 135 2846
Pyrophori c sol i d, organi c, n.o.s. 135 2846
Pyrosul furyl chl ori de 137 1817
Pyrosul phuryl chl ori de 137 1817
Pyrrol i di ne 132 1922
Quinoline 154 2656
Radi oacti ve materi al , arti cl es 161 2909
manufactured from depleted
Uranium
Thorium
Uranium
Radi oacti ve materi al , empty 161 2908
packages
Radi oacti ve materi al , excepted 161 2909
from depleted Uranium
from depleted Uranium
from natural Uranium
from natural Uranium
package, empty packagi ng
package, empty packagi ng
articles
articles
package, l i mi ted quanti ty of
material
Radi oacti ve materi al , fi ssi l e, 165 2918
n.o.s.
Radi oacti ve materi al , 161 2911
i nstruments or arti cl es
Radi oacti ve materi al , l i mi ted 161 2910
quanti ty, n.o.s.
Radi oacti ve materi al , l ow 162 2912
speci f i c act i vi t y (LSA), n. o. s.
speci fi c acti vi ty (LSA-I)
speci f i c act i vi t y (LSA-I I )
No. No.
No. No.
Page 152
speci f i c act i vi t y (LSA-I I ),
fissile
speci f i c act i vi t y (LSA-I I I )
speci f i c act i vi t y (LSA-I I I ),
fissile
Radi oacti ve materi al , n.o.s. 163 2982
Radi oacti ve materi al , speci al 164 2974
form, n.o.s.
Radi oacti ve materi al , surface 162 2913
contami nated obj ects (SCO)
contami nated obj ects (SCO-I)
contaminated objects
(SCO-I), fi ssi l e
contami nated obj ects (SCO-II)
contaminated objects
(SCO-I I ), f i ssi l e
Radioactive material, transported 163 2919
under special arrangement
Radioactive material, transported 165 3331
under special arrangement,
fissile
Radi oacti ve materi al , Type A 163 2915
package
package, fi ssi l e
package, speci al form
package, speci al form, fi ssi l e
Radi oacti ve materi al , Type B(M) 163 2917
package
Radi oacti ve materi al , Type B(M) 165 3329
package, fi ssi l e
Radi oacti ve materi al , Type B(U) 163 2916
package
Radi oacti ve materi al , Type B(U) 165 3328
package, fi ssi l e
Radi oacti ve materi al , Type C 163 3323
package
Radi oacti ve materi al , Type C 165 3330
package, fi ssi l e
Radi oacti ve materi al , Urani um 166 2977
hexafl uori de, fi ssi l e
hexafluoride
hexafl uori de, non-fi ssi l e or
fissile-excepted
Rags, oi l y 133 1856
Rare gases and Ni trogen mi xture 121 1981
Rare gases and Ni trogen 121 1981
Rare gases and Oxygen mi xture 121 1980
Rare gases and Oxygen mi xture, 121 1980
compressed
Rare gases mi xture 121 1979
Rare gases mi xture, compressed 121 1979
Receptacl es, smal l , contai ni ng 115 2037
gas
Red phosphorus 133 1338
Red phosphorus, amorphous 133 1338
Refri gerant gas, n.o.s. 126 1078
Refri gerant gas, n.o.s. 115 1954
(flammable)
Refrigerant gas R-12 126 1028
Refrigerant gas R-12 and 126 2602
Refrigerant gas R-152a
azeotropi c mi xture wi th 74%
Refrigerant gas R-12
No. No.
No. No.
Page 153
Refrigerant gas R-12B1 126 1974
Refrigerant gas R-13B1 126 1009
Refrigerant gas R-14, 126 1982
compressed
Refrigerant gas R-116, 126 2193
compressed
Refrigerant gas R-133a 126 1983
Refrigerant gas R-142b 115 2517
Refrigerant gas R-152a and 126 2602
Refrigerant gas R-404A 126 3337
Refrigerant gas R-407A 126 3338
Refrigerant gas R-407B 126 3339
Refri gerant gas R-407C 126 3340
(azeotropi c mi xture of
Refrigerant gas R-12 and
Refrigerant gas R-152a with
Refrigerant gas R-12)
(azeotropi c mi xture of
Refrigerant gas R-13 and
Refrigerant gas R-23 with
Refrigerant gas R-13)
Refrigerant gas R-1132a 116P 1959
Refri gerant gas RC-318 126 1976
Refrigerating machine 128 1993
Refrigerating machines, 126 2857
(UN2073)
(UN2672)
containing flammable,
non-poisonous, non-
corrosi ve, l i quefi ed gas
Refrigerating machines, containing 115 3358
flammable, non-toxic, liquefied
gas
No. No.
No. No.
Page 154
containing non-flammable,
liquefied gas
non-poisonous gases
non-poisonous, liquefied gas
non-poi sonous, non-corrosi ve,
liquefied gas
non-toxi c gases
non-toxi c, l i quefi ed gas
non-toxi c, non-corrosi ve,
liquefied gas
Regul ated medi cal waste, n.o.s. 158 3291
Regul ated medi cal waste 158 9275
Resin solution 127 1866
Resorcinol 153 2876
Rosi n oi l 127 1286
Rubber scrap, powdered or 133 1345
granulated
Rubber shoddy, powdered or 133 1345
granulated
Rubber solution 127 1287
Rubidium 138 1423
Rubi di um hydroxi de 154 2678
Rubi di um hydroxi de, sol i d 154 2678
Rubi di um hydroxi de, sol uti on 154 2677
Rubidium metal 138 1423
SA 119 2188
Sari n 153 2810
Seat-belt modules 171 3268
Seat-belt pre-tensioners 171 3268
Seat-belt pre-tensioners, 126 3353
compressed gas
Seat-belt pre-tensioners, 171 3268
pyrotechni c
Seed cake, wi t h more t han 1. 5% 135 1386
oi l and not more than 11%
moisture
Seed cake, wi th not more than 135 2217
1.5% oi l and not more than
11% moi sture
Selenates 151 2630
Sel eni c aci d 154 1905
Selenites 151 2630
Sel eni um compound, l i qui d, 151 3440
n.o.s.
Sel eni um compound, n.o.s. 151 3283
Sel eni um compound, sol i d, 151 3283
n.o.s.
Selenium disulfide 153 2657
Selenium disulphide 153 2657
Selenium hexafluoride 125 2194
Sel eni um oxi de 154 2811
Sel eni um oxychl ori de 157 2879
Sel eni um powder 152 2658
Sel f-defense spray, non- 171 3334
pressurized
Sel f-heati ng l i qui d, corrosi ve, 136 3188
i norgani c, n.o.s.
Sel f-heati ng l i qui d, corrosi ve, 136 3185
organi c, n.o.s.
Self-heating liquid, inorganic, 135 3186
n.o.s.
No. No.
No. No.
Page 155
Self-heating liquid, organic, 135 3183
n.o.s.
Self-heating liquid, poisonous, 136 3187
i norgani c, n.o.s.
Self-heating liquid, poisonous, 136 3184
organi c, n.o.s.
Sel f-heati ng l i qui d, toxi c, 136 3187
i norgani c, n.o.s.
Sel f-heati ng l i qui d, toxi c, 136 3184
organi c, n.o.s.
Self-heating metal powders, 135 3189
n.o.s.
Sel f-heati ng sol i d, corrosi ve, 136 3192
i norgani c, n.o.s.
Sel f-heati ng sol i d, corrosi ve, 136 3126
organi c, n.o.s.
Sel f-heati ng sol i d, i norgani c, 135 3190
n.o.s.
poi sonous, n.o.s.
t oxi c, n. o. s.
Sel f-heati ng sol i d, organi c, 135 3088
n.o.s.
poi sonous, n.o.s.
t oxi c, n. o. s.
Sel f-heati ng sol i d, oxi di zi ng, 135 3127
n.o.s.
Sel f-heati ng sol i d, poi sonous, 136 3191
i norgani c, n.o.s.
Sel f-heati ng sol i d, poi sonous, 136 3128
organi c, n.o.s.
Sel f-heati ng sol i d, toxi c, 136 3191
i norgani c, n.o.s.
Sel f-heati ng sol i d, toxi c, 136 3128
organi c, n.o.s.
Sel f-heati ng substance, sol i d, 136 3126
Sel f-heati ng substances, sol i d, 135 3088
n.o.s.
poi sonous, n.o.s.
t oxi c, n. o. s.
Sel f-reacti ve l i qui d type B 149 3221
Sel f-reacti ve l i qui d type B, 150 3231
Sel f-reacti ve l i qui d type C 149 3223
Sel f-reacti ve l i qui d type C, 150 3233
Sel f-reacti ve l i qui d type D 149 3225
Sel f-reacti ve l i qui d type D, 150 3235
Sel f-reacti ve l i qui d type E 149 3227
Sel f-reacti ve l i qui d type E, 150 3237
Sel f-reacti ve l i qui d type F 149 3229
Sel f-reacti ve l i qui d type F, 150 3239
Sel f-reacti ve sol i d type B 149 3222
Sel f-reacti ve sol i d type B, 150 3232
Sel f-reacti ve sol i d type C 149 3224
Sel f-reacti ve sol i d type C, 150 3234
Sel f-reacti ve sol i d type D 149 3226
Sel f-reacti ve sol i d type D, 150 3236
Sel f-reacti ve sol i d type E 149 3228
Sel f-reacti ve sol i d type E, 150 3238
No. No.
No. No.
Page 156
Sel f-reacti ve sol i d type F 149 3230
Sel f-reacti ve sol i d type F, 150 3240
Shal e oi l 128 1288
Silane 116 2203
Si l i cofl uori des, n.o.s. 151 2856
Si l ane, compressed 116 2203
Si l i con powder, amorphous 170 1346
Silicon tetrachloride 157 1818
Silicon tetrafluoride 125 1859
Silicon tetrafluoride, 125 1859
compressed
Si l ver arseni te 151 1683
Si l ver cyani de 151 1684
Si l ver ni trate 140 1493
Si l ver pi crate, wetted wi th not 113 1347
Sl udge aci d 153 1906
Smokel ess powder for smal l 133 3178
arms
Soda l i me, wi th more than 4% 154 1907
Sodi um hydroxi de
Sodium 138 1428
Sodi um al umi nate, sol i d 154 2812
Sodium aluminate, solution 154 1819
Sodi um al umi num hydri de 138 2835
Sodi um ammoni um vanadate 154 2863
Sodium arsanilate 154 2473
Sodium arsenate 151 1685
Sodi um arseni te, aqueous 154 1686
solution
Sodi um arseni te, sol i d 151 2027
Sodi um azi de 153 1687
Sodium bisulfate, solution 154 2837
Sodium bisulphate, solution 154 2837
Sodi um borohydri de 138 1426
Sodi um borohydri de and Sodi um 157 3320
hydroxi de sol uti on, wi th not
more than 12% Sodi um
borohydri de and not more
than 40% Sodi um hydroxi de
Sodium bromate 141 1494
Sodi um cacodyl ate 152 1688
Sodi um carbonate peroxyhydrate 140 3378
Sodi um chl orate 140 1495
Sodi um chl orate, aqueous 140 2428
solution
Sodi um chl ori te 143 1496
Sodi um chl ori te, sol uti on, wi th 154 1908
more than 5% avai l abl e
Chlorine
Sodium chloroacetate 151 2659
Sodi um cuprocyani de, sol i d 157 2316
Sodi um cuprocyani de, sol uti on 157 2317
Sodi um cyani de 157 1689
Sodi um cyani de, sol i d 157 1689
Sodi um cyani de, sol uti on 157 3414
Sodium dichloroisocyanurate 140 2465
Sodium dichloro-s-triazinetrione 140 2465
Sodium dinitro-o-cresolate, 113 3369
water
Sodium dinitro-o-cresolate, 113 1348
water
Sodium dinitro-ortho-cresolate, 113 1348
wetted
Sodium dithionite 135 1384
Sodium fluoride 154 1690
Sodi um fl uori de, sol i d 154 1690
No. No.
No. No.
Page 157
Sodium fluoride, solution 154 3415
Sodium fluoroacetate 151 2629
Sodium fluorosilicate 154 2674
Sodi um hydri de 138 1427
Sodium hydrogendifluoride 154 2439
Sodi um hydrogen sul fate, 154 2837
solution
Sodi um hydrogen sul phate, 154 2837
solution
Sodi um hydrosul fi de, sol i d, 135 2318
wi th l ess than 25% water of
crystal l i zati on
Sodi um hydrosul fi de, sol uti on 154 2922
Sodi um hydrosul fi de, wi th l ess 135 2318
than 25% water of
crystal l i zati on
Sodi um hydrosul fi de, wi th not 154 2949
crystal l i zati on
Sodi um hydrosul fi te 135 1384
Sodi um hydrosul phi de, sol i d, 135 2318
wi th l ess than 25% water of
crystal l i zati on
Sodi um hydrosul phi de, sol uti on 154 2922
Sodi um hydrosul phi de, wi th l ess 135 2318
than 25% water of
crystal l i zati on
Sodi um hydrosul phi de, wi th not 154 2949
crystal l i zati on
Sodi um hydrosul phi te 135 1384
Sodi um hydroxi de, bead 154 1823
Sodi um hydroxi de, dry 154 1823
Sodi um hydroxi de, fl ake 154 1823
Sodi um hydroxi de, granul ar 154 1823
Sodi um hydroxi de, sol i d 154 1823
Sodi um hydroxi de, sol uti on 154 1824
Sodium methylate 138 1431
Sodi um methyl ate, dry 138 1431
Sodi um methyl ate, sol uti on i n 132 1289
alcohol
Sodi um monoxi de 157 1825
Sodium nitrate 140 1498
Sodi um ni trate and Potassi um 140 1499
nitrate mixture
Sodium nitrite 140 1500
Sodi um ni tri te and Potassi um 140 1487
nitrate mixture
Sodium pentachlorophenate 154 2567
Sodium perborate 140 3377
monohydrate
Sodium percarbonates 140 2467
Sodium perchlorate 140 1502
Sodium permanganate 140 1503
Sodi um peroxi de 144 1504
Sodi um peroxoborate, 140 3247
anhydrous
Sodium persulfate 140 1505
Sodium persulphate 140 1505
Sodium phosphide 139 1432
Sodi um pi cramate, wetted wi th 113 1349
Sodi um potassi um al l oys 138 1422
Sodi um potassi um al l oys, l i qui d 138 1422
Sodi um potassi um al l oys, sol i d 138 3404
Sodi um sel eni te 151 2630
Sodium silicofluoride 154 2674
Sodi um sul fi de, anhydrous 135 1385
Sodi um sul fi de, hydrated, wi th 153 1849
No. No.
No. No.
Page 158
Sodi um sul fi de, wi th l ess than 135 1385
Sodi um sul phi de, anhydrous 135 1385
Sodi um sul phi de, hydrated, wi th 153 1849
Sodi um sul phi de, wi th l ess than 135 1385
Sodi um superoxi de 143 2547
Sol i ds contai ni ng corrosi ve 154 3244
l i qui d, n.o.s.
Solids containing flammable 133 3175
l i qui d, n.o.s.
Solids containing poisonous 151 3243
l i qui d, n.o.s.
Sol i ds contai ni ng toxi c l i qui d, 151 3243
n.o.s.
Soman 153 2810
Stanni c chl ori de, anhydrous 137 1827
Stannic chloride, pentahydrate 154 2440
Stannic phosphides 139 1433
Stibine 119 2676
St raw, wet , damp or 133 1327
contaminated with oil
Strontium arsenite 151 1691
Strontium chlorate 143 1506
Strontium chlorate, solid 143 1506
Strontium chlorate, solution 143 1506
Strontium nitrate 140 1507
Strontium perchlorate 140 1508
Strontium peroxide 143 1509
Strontium phosphide 139 2013
Strychni ne 151 1692
Strychni ne sal ts 151 1692
Styrene monomer, inhibited 128P 2055
Styrene monomer, stabi l i zed 128P 2055
Substances, whi ch i n contact 138 3129
gases, l i qui d, corrosi ve, n. o. s.
gases, l i qui d, n.o.s.
gases, l i qui d, poi sonous,
n.o.s.
gases, l i qui d, t oxi c, n. o. s.
gases, sol i d, corrosi ve, n. o. s.
gases, sol i d, fl ammabl e, n.o.s.
gases, sol i d, n. o. s.
gases, sol i d, oxi di zi ng, n. o. s.
gases, sol i d, poi sonous,
n.o.s.
gases, sol i d, sel f-heati ng,
n.o.s.
gases, sol i d, t oxi c, n. o. s.
Substituted nitrophenol 131 2780
poisonous
No. No.
No. No.
Page 159
t oxi c
flammable
flammable
Sul fami c aci d 154 2967
Sulfur 133 1350
Sul fur, mol ten 133 2448
Sulfur chlorides 137 1828
Sul fur di oxi de 125 1079
Sul fur di oxi de, l i quefi ed 125 1079
Sulfur hexafluoride 126 1080
Sul furi c aci d 137 1830
Sul furi c aci d, fumi ng 137 1831
Sul furi c aci d, fumi ng, wi th l ess 137 1831
than 30% free Sul fur tri oxi de
Sul furi c aci d, fumi ng, wi th not 137 1831
l ess than 30% free Sul fur
trioxide
Sul furi c aci d, spent 137 1832
Sul furi c aci d, wi th more than 137 1830
51% aci d
Sul furi c aci d, wi th not more than 157 2796
51% aci d
Sul furi c aci d and Hydrofl uori c 157 1786
aci d mi xture
Sul furous aci d 154 1833
Sulfur tetrafluoride 125 2418
Sul fur tri oxi de 137 1829
Sul fur tri oxi de, i nhi bi ted 137 1829
Sul fur tri oxi de, stabi l i zed 137 1829
Sulfur trioxide, uninhibited 137 1829
Sul fur tri oxi de and 137 1754
Chl orosul foni c aci d mi xture
Sul furyl chl ori de 137 1834
Sulfuryl fluoride 123 2191
Sul phami c aci d 154 2967
Sulphur 133 1350
Sul phur, mol ten 133 2448
Sulphur chlorides 137 1828
Sul phur di oxi de 125 1079
Sul phur di oxi de, l i quefi ed 125 1079
Sulphur hexafluoride 126 1080
Sul phuri c aci d 137 1830
Sul phuri c aci d, fumi ng 137 1831
Sul phuri c aci d, fumi ng, wi th l ess 137 1831
than 30% free Sul phur tri oxi de
Sul phuri c aci d, fumi ng, wi th not 137 1831
l ess than 30% free Sul phur
trioxide
Sul phuri c aci d, spent 137 1832
Sul phuri c aci d, wi th more than 137 1830
51% aci d
Sul phuri c aci d, wi th not more 157 2796
than 51% aci d
Sul phuri c aci d and Hydrofl uori c 157 1786
aci d mi xture
Sul phurous aci d 154 1833
Sulphur tetrafluoride 125 2418
No. No.
No. No.
Page 160
Sul phur tri oxi de 137 1829
Sul phur tri oxi de, i nhi bi ted 137 1829
Sul phur tri oxi de, stabi l i zed 137 1829
Sulphur trioxide, uninhibited 137 1829
Sul phur tri oxi de and 137 1754
Chl orosul phoni c aci d mi xture
Sul phuryl chl ori de 137 1834
Sul phuryl fl uori de 123 2191
Tabun 153 2810
Tars, liquid 130 1999
Tear gas candles 159 1700
Tear gas devi ces 159 1693
Tear gas grenades 159 1700
Tear gas substance, l i qui d, 159 1693
n.o.s.
Tear gas substance, sol i d, n.o.s. 159 1693
Tear gas substance, sol i d, n.o.s. 159 3448
Tel l uri um compound, n.o.s. 151 3284
Tellurium hexafluoride 125 2195
Terpene hydrocarbons, n.o.s. 128 2319
Terpinolene 128 2541
Tetrabromoethane 159 2504
1,1,2,2-Tetrachloroethane 151 1702
Tetrachloroethane 151 1702
Tetrachloroethylene 160 1897
Tetraethyl dithiopyrophosphate 153 1704
Tetraethyl dithiopyrophosphate, 153 1704
mi xture, dry or l i qui d
Tetraethylenepentamine 153 2320
Tetraethyl lead, liquid 131 1649
Tetraethyl pyrophosphate, liquid 152 3018
Tetraethyl pyrophosphate, solid 152 2783
Tetraethyl silicate 129 1292
1,1,1,2-Tetrafluoroethane 126 3159
Tetrafluoroethane and Ethylene 126 3299
Tetrafluoroethylene, inhibited 116P 1081
Tetrafluoroethylene, stabilized 116P 1081
Tetrafluoromethane 126 1982
Tetrafluoromethane, 126 1982
compressed
1,2,3,6-Tetrahydro- 129 2498
benzaldehyde
Tetrahydrofuran 127 2056
Tetrahydrofurfurylamine 129 2943
Tetrahydrophthalic anhydrides 156 2698
1,2,3,6-Tetrahydropyridine 129 2410
1,2,5,6-Tetrahydropyridine 129 2410
Tetrahydrothiophene 130 2412
Tetramethylammonium 153 1835
hydroxi de
hydroxi de, sol i d
hydroxi de, sol uti on
Tetramethylsilane 130 2749
Tetranitromethane 143 1510
Tetrapropyl orthotitanate 128 2413
Texti l e waste, wet 133 1857
Thallium chlorate 141 2573
Thal l i um compound, n.o.s. 151 1707
Thallium nitrate 141 2727
Thallium sulfate, solid 151 1707
Thallium sulphate, solid 151 1707
4-Thiapentanal 152 2785
Thia-4-pentanal 152 2785
Thi ckened GD 153 2810
Thioacetic acid 129 2436
No. No.
No. No.
Page 161
Thiocarbamate pesticide, liquid, 131 2772
fl ammabl e, toxi c
poisonous
t oxi c
toxi c, fl ammabl e
Thiocarbamate pesticide, solid, 151 2771
poisonous
Thiocarbamate pesticide, solid, 151 2771
t oxi c
Thioglycol 153 2966
Thi ogl ycol i c aci d 153 1940
Thiolactic acid 153 2936
Thionyl chloride 137 1836
Thiophene 130 2414
Thiophosgene 157 2474
Thiophosphoryl chloride 157 1837
Thiourea dioxide 135 3341
Thorium metal, pyrophoric 162 2975
Thorium nitrate, solid 162 2976
Tinctures, medicinal 127 1293
Tin tetrachloride 137 1827
Tin tetrachloride, pentahydrate 154 2440
Titanium disulfide 135 3174
Titanium disulphide 135 3174
Titanium hydride 170 1871
Ti tani um powder, dry 135 2546
Ti tani um powder, wetted wi th 170 1352
Titanium sponge granules 170 2878
Titanium sponge powders 170 2878
Titanium sulfate, solution 154 1760
Titanium sulphate, solution 154 1760
Titanium tetrachloride 137 1838
Titanium trichloride, pyrophoric 135 2441
Titanium trichloride mixture 157 2869
Titanium trichloride mixture, 135 2441
pyrophori c
TNT, wetted wi th not l ess than 113 3366
10% wat er
TNT, wetted wi th not l ess than 113 1356
30% wat er
Toe puffs, nitrocellulose base 133 1353
Toluene 130 1294
2,4-Toluenediamine 151 1709
Toluene diisocyanate 156 2078
Tol uene sul foni c aci d, l i qui d, 153 2584
Sul furi c aci d
Tol uene sul foni c aci d, l i qui d, 153 2586
Sul furi c aci d
Tol uene sul foni c aci d, sol i d, wi th 153 2583
acid
Tol uene sul foni c aci d, sol i d, wi th 153 2585
acid
Tol uene sul phoni c aci d, l i qui d, 153 2584
Sul phuri c aci d
Tol uene sul phoni c aci d, l i qui d, 153 2586
Sul phuri c aci d
No. No.
No. No.
Page 162
Tol uene sul phoni c aci d, sol i d, 153 2583
Sul phuri c aci d
Tol uene sul phoni c aci d, sol i d, 153 2585
Sul phuri c aci d
Toluidines 153 1708
Toluidines, liquid 153 1708
Toluidines, solid 153 1708
Toluidines, solid 153 3451
2,4-Toluylenediamine 151 1709
2,4-Toluylenediamine, solid 151 1709
2,4-Toluylenediamine, solution 151 3418
Toxi c by i nhal ati on l i qui d, 154 3389
Hazard Zone A)
Hazard Zone B)
Hazard Zone A)
Hazard Zone B)
Zone A)
Zone B)
Hazard Zone A)
Hazard Zone B)
Toxi c l i qui d, corrosi ve, 154 3289
i norgani c, n.o.s.
Hazard Zone A)
Hazard Zone B)
Toxi c l i qui d, corrosi ve, organi c, 154 2927
n.o.s.
Zone A)
Zone B)
Toxi c l i qui d, fl ammabl e, n.o.s. 131 2929
Toxi c l i qui d, fl ammabl e, organi c, 131 2929
n.o.s.
Zone A)
Zone B)
Toxi c l i qui d, i norgani c, n.o.s. 151 3287
No. No.
No. No.
Page 163
Toxi c l i qui d, n.o.s. 153 2810
Toxi c l i qui d, n.o.s. (Inhal ati on 153 2810
Hazard Zone A)
Toxi c l i qui d, n.o.s. (Inhal ati on 153 2810
Hazard Zone B)
Toxi c l i qui d, organi c, n.o.s. 153 2810
Toxi c l i qui d, oxi di zi ng, n. o. s. 142 3122
Toxi c l i qui d, water-reacti ve, 139 3123
n.o.s.
Zone A)
Zone B)
Toxi c l i qui d, whi ch i n contact 139 3123
gases, n. o. s.
Hazard Zone A)
Hazard Zone B)
Toxi c sol i d, corrosi ve, i norgani c, 154 3290
n.o.s.
Toxi c sol i d, corrosi ve, organi c, 154 2928
n.o.s.
Toxi c sol i d, fl ammabl e, n.o.s. 134 2930
Toxi c sol i d, fl ammabl e, organi c, 134 2930
n.o.s.
Toxi c sol i d, i norgani c, n.o.s. 151 3288
Toxi c sol i d, organi c, n.o.s. 154 2811
Toxi c sol i d, oxi di zi ng, n. o. s. 141 3086
Toxi c sol i d, sel f-heati ng, n.o.s. 136 3124
Toxi c sol i d, water-reacti ve, 139 3125
n.o.s.
Toxi c sol i d, whi ch i n contact wi th 139 3125
water emi ts fl ammabl e gases,
n.o.s.
Toxins 153
Toxi ns, extracted from l i vi ng 153 3172
sources, l i qui d, n.o.s.
sources, n. o. s.
Triallylamine 132 2610
Tri al l yl borate 156 2609
Triazine pesticide, liquid, 131 2764
fl ammabl e, toxi c
poisonous
Tri azi ne pesti ci de, l i qui d, toxi c 151 2998
Tri azi ne pesti ci de, l i qui d, toxi c, 131 2997
flammable
No. No.
No. No.
Page 164
Tri azi ne pesti ci de, sol i d, 151 2763
poisonous
Tri azi ne pesti ci de, sol i d, toxi c 151 2763
Tri-(1-aziridinyl)phosphine 152 2501
oxi de, sol uti on
Tributylamine 153 2542
Tributylphosphane 135 3254
Tributylphosphine 135 3254
Trichloroacetic acid 153 1839
Trichloroacetic acid, solution 153 2564
Tri chl oroacetyl chl ori de 156 2442
Trichlorobenzenes, liquid 153 2321
Trichlorobutene 152 2322
1,1,1-Trichloroethane 160 2831
Trichloroethylene 160 1710
Tri chl oroi socyanuri c aci d, dry 140 2468
Trichlorosilane 139 1295
(mono)-(Trichloro)-tetra- 140 2468
(monopotassium dichloro)-
penta-s-triazinetrione, dry
Tricresyl phosphate 151 2574
Triethylamine 132 1296
Triethylenetetramine 153 2259
Triethyl phosphite 130 2323
Trifluoroacetic acid 154 2699
Trifluoroacetyl chloride 125 3057
Trifluorochloroethylene 119P 1082
Trifluorochloroethylene, 119P 1082
inhibited
Trifluorochloroethylene, 119P 1082
stabilized
1,1,1-Trifluoroethane 115 2035
Trifluoroethane, compressed 115 2035
Trifluoromethane 126 1984
Trifluoromethane, refrigerated 120 3136
liquid
Trifluoromethane and 126 2599
Chlorotrifluoromethane
Chlorotrifluoromethane
2-Trifluoromethylaniline 153 2942
3-Trifluoromethylaniline 153 2948
Triisobutylene 128 2324
Triisopropyl borate 129 2616
Trimethoxysilane 132 9269
Tri methyl acetyl chl ori de 132 2438
Trimethylamine, anhydrous 118 1083
Trimethylamine, aqueous 132 1297
solution
1,3,5-Trimethylbenzene 129 2325
Trimethyl borate 129 2416
Trimethylchlorosilane 155 1298
Tri methyl cycl ohexyl ami ne 153 2326
Tri met hyl hexamet hyl enedi ami nes 153 2327
Tri methyl hexamethyl ene 156 2328
di i socyanate
Trimethyl phosphite 130 2329
Trinitrobenzene, wetted with not 113 3367
Trinitrobenzene, wetted with not 113 1354
Tri ni trobenzoi c aci d, wetted wi th 113 3368
Tri ni trobenzoi c aci d, wetted wi th 113 1355
Trinitrochlorobenzene, wetted 113 3365
Trinitrophenol, wetted with not 113 3364
No. No.
No. No.
Page 165
Trinitrophenol, wetted with not 113 1344
Trinitrotoluene, wetted with not 113 3366
Trinitrotoluene, wetted with not 113 1356
Tripropylamine 132 2260
Tripropylene 128 2057
Tris-(1-aziridinyl)phosphine 152 2501
oxi de, sol uti on
Tungsten hexafluoride 125 2196
Turpentine 128 1299
Turpentine substitute 128 1300
Undecane 128 2330
Urani um hexafl uori de 166 2978
Urani um hexafl uori de, fi ssi l e 166 2977
contai ni ng more than 1%
Uranium-235
Urani um hexafl uori de, fi ssi l e- 166 2978
excepted
Urani um hexafl uori de, l ow 166 2978
speci fi c acti vi ty
Urani um hexafl uori de, non- 166 2978
fissile
Urani um metal , pyrophori c 162 2979
Urani um ni trate, hexahydrate, 162 2980
solution
Uranyl ni trate, hexahydrate, 162 2980
solution
Uranyl ni trate, sol i d 162 2981
Urea hydrogen peroxi de 140 1511
Urea ni trate, wetted wi th not l ess 113 3370
t han 10% wat er
Urea ni trate, wetted wi th not l ess 113 1357
t han 20% wat er
Val eral dehyde 129 2058
Val eryl chl ori de 132 2502
Vanadi um compound, n.o.s. 151 3285
Vanadi um oxytri chl ori de 137 2443
Vanadium pentoxide 151 2862
Vanadium tetrachloride 137 2444
Vanadium trichloride 157 2475
Vanadyl sul fate 151 2931
Vanadyl sul phate 151 2931
Vehi cl e, fl ammabl e gas powered 128 3166
Vehi cl e, fl ammabl e l i qui d 128 3166
powered
Vi nyl acetate 129P 1301
Vi nyl acetate, i nhi bi ted 129P 1301
Vi nyl acetate, stabi l i zed 129P 1301
Vi nyl bromi de, i nhi bi ted 116P 1085
Vi nyl bromi de, stabi l i zed 116P 1085
Vi nyl butyrate, i nhi bi ted 129P 2838
Vi nyl butyrate, stabi l i zed 129P 2838
Vi nyl chl ori de, i nhi bi ted 116P 1086
Vi nyl chl ori de, stabi l i zed 116P 1086
Vi nyl chl oroacetate 155 2589
Vi nyl ethyl ether 127P 1302
Vi nyl ethyl ether, i nhi bi ted 127P 1302
Vi nyl ethyl ether, stabi l i zed 127P 1302
Vi nyl fl uori de, i nhi bi ted 116P 1860
Vi nyl fl uori de, stabi l i zed 116P 1860
Vi nyl i dene chl ori de, i nhi bi ted 130P 1303
Vi nyl i dene chl ori de, stabi l i zed 130P 1303
Vi nyl i sobutyl ether 127P 1304
Vi nyl i sobutyl ether, i nhi bi ted 127P 1304
Vi nyl i sobutyl ether, stabi l i zed 127P 1304
Vi nyl methyl ether 116P 1087
Vi nyl methyl ether, i nhi bi ted 116P 1087
No. No.
No. No.
Page 166
Vi nyl methyl ether, stabi l i zed 116P 1087
Vi nyl pyri di nes, i nhi bi ted 131P 3073
Vi nyl pyri di nes, stabi l i zed 131P 3073
Vi nyl tol uenes, i nhi bi ted 130P 2618
Vi nyl tol uenes, stabi l i zed 130P 2618
Vi nyl tri chl orosi l ane 155P 1305
Vi nyl tri chl orosi l ane, i nhi bi ted 155P 1305
Vi nyl tri chl orosi l ane, stabi l i zed 155P 1305
VX 153 2810
Water-reacti ve l i qui d, corrosi ve, 138 3129
n.o.s.
Water-reacti ve l i qui d, n.o.s. 138 3148
Water-reacti ve l i qui d, 139 3130
poi sonous, n.o.s.
Water-reacti ve l i qui d, toxi c, 139 3130
n.o.s.
Water-reacti ve sol i d, corrosi ve, 138 3131
n.o.s.
Water-reacti ve sol i d, fl ammabl e, 138 3132
n.o.s.
Water-reacti ve sol i d, n.o.s. 138 2813
Water-reacti ve sol i d, oxi di zi ng, 138 3133
n.o.s.
Water-reacti ve sol i d, poi sonous, 139 3134
n.o.s.
Water-reacti ve sol i d, sel f- 138 3135
heati ng, n.o.s.
Water-reacti ve sol i d, toxi c, n.o.s. 139 3134
Water-reactive substances, 138 3129
l i qui d, corrosi ve, n.o.s.
l i qui d, n.o.s.
l i qui d, poi sonous, n.o.s.
l i qui d, t oxi c, n. o. s.
sol i d, corrosi ve, n. o. s.
sol i d, fl ammabl e, n.o.s.
sol i d, n. o. s.
sol i d, oxi di zi ng, n. o. s.
sol i d, poi sonous, n.o.s.
sol i d, sel f-heati ng, n.o.s.
sol i d, t oxi c, n. o. s.
Wheel chai r, el ectri c, wi th 154 3171
batteries
White asbestos 171 2590
Whi te phosphorus, dry 136 1381
White phosphorus, in solution 136 1381
White phosphorus, molten 136 2447
Whi te phosphorus, under water 136 1381
Wood preservati ves, l i qui d 129 1306
Wool wast e, wet 133 1387
Xanthates 135 3342
Xenon 121 2036
Xenon, compressed 121 2036
Xenon, refrigerated liquid 120 2591
Xyl enes 130 1307
Xyl enol s 153 2261
Xyl enol s, l i qui d 153 3430
Xyl enol s, sol i d 153 2261
Xyl i di nes 153 1711
Xyl i di nes, l i qui d 153 1711
Xyl i di nes, sol i d 153 1711
No. No.
No. No.
Page 167
Xyl i di nes, sol i d 153 3452
Xyl yl bromi de 152 1701
Xyl yl bromi de, l i qui d 152 1701
Xyl yl bromi de, sol i d 152 3417
Yel l ow phosphorus, dry 136 1381
Yel l ow phosphorus, i n sol uti on 136 1381
Yel l ow phosphorus, mol ten 136 2447
Yel l ow phosphorus, under water 136 1381
Zinc ammonium nitrite 140 1512
Zinc arsenate 151 1712
Zinc arsenate and Zinc arsenite 151 1712
mixture
Zinc arsenite 151 1712
Zinc arsenite and Zinc arsenate 151 1712
mixture
Zinc ashes 138 1435
Zinc bromate 140 2469
Zinc chlorate 140 1513
Zi nc chl ori de, anhydrous 154 2331
Zi nc chl ori de, sol uti on 154 1840
Zi nc cyani de 151 1713
Zinc dithionite 171 1931
Zinc dross 138 1435
Zinc dust 138 1436
Zinc fluorosilicate 151 2855
Zinc hydrosulfite 171 1931
Zinc hydrosulphite 171 1931
Zinc nitrate 140 1514
Zinc permanganate 140 1515
Zi nc peroxi de 143 1516
Zinc phosphide 139 1714
Zi nc powder 138 1436
Zinc residue 138 1435
Zinc resinate 133 2714
Zinc silicofluoride 151 2855
Zi nc ski mmi ngs 138 1435
Zi rconi um, dry, coi l ed wi re, 170 2858
fi ni shed metal sheets or stri ps
Zi rconi um, dry, fi ni shed sheets, 135 2009
stri ps or coi l ed wi re
Zirconium hydride 138 1437
Zirconium metal, liquid 170 1308
suspension
Zi rconi um metal , powder, wet 170 1358
Zirconium nitrate 140 2728
Zirconium picramate, wetted 113 1517
Zi rconi um powder, dry 135 2008
Zi rconi um powder, wetted wi th 170 1358
Zi rconi um scrap 135 1932
Zirconium sulfate 171 9163
Zirconium sulphate 171 9163
Zi rconi um suspended i n a 170 1308
flammable liquid
Zi rconi um suspended i n a l i qui d 170 1308
(flammable)
Zirconium tetrachloride 137 2503
NOTES
E EE EER RR RRG GG GG2004 2004 2004 2004 2004
G GG GGU UU UUI II IID DD DDE EE EE
Page 169
GUI DES GUI DES
GUI DES GUI DES GUI DES
G GG GGU UU UUI II II D DD DDE EE EE
Page 170
MIXED LOAD/UNIDENTIFIED CARGO
POTENTIAL HAZARDS
FIRE OR EXPLOSION
May expl ode f r om heat , shock, f r i ct i on or cont ami nat i on.
May r eact vi ol ent l y or expl osi vel y on cont act wi t h ai r , wat er or f oam.
May be i gni t ed by heat , spar ks or f l ames.
Vapor s may t r avel t o sour ce of i gni t i on and f l ash back.
Cont ai ner s may expl ode when heat ed.
Rupt ur ed cyl i nder s may r ocket .
HEALTH
I nhal at i on, i ngest i on or cont act wi t h subst ance may cause sever e i nj ur y, i nf ect i on,
di sease or deat h.
Hi gh concent r at i on of gas may cause asphyxi at i on wi t hout war ni ng.
Cont act may cause bur ns t o ski n and eyes.
Fi r e or cont act wi t h wat er may pr oduce i r r i t at i ng, t oxi c and/ or cor r osi ve gases.
Runof f f rom f i re cont rol may cause pol l ut i on.
PUBLIC SAFETY
CALL Emer gency Response Tel ephone Number on Shi ppi ng Paper f i r st . I f
Shi ppi ng Paper not avai l abl e or no answer , r ef er t o appr opr i at e t el ephone
number l i st ed on t he i nsi de back cover .
As an i mmedi at e pr ecaut i onar y measur e, i sol at e spi l l or l eak ar ea f or at l east 100 met er s
(330 f eet ) i n al l di rect i ons.
Keep unaut hor i zed per sonnel away.
St ay upwi nd.
Keep out of l ow ar eas.
PROTECTIVE CLOTHING
Wear posi t i ve pressure sel f -cont ai ned breat hi ng apparat us (SCBA).
St ruct ural f i ref i ght ers' prot ect i ve cl ot hi ng provi des l i mi t ed prot ect i on i n f i re si t uat i ons
ONLY; i t may not be ef f ect i ve i n spi l l si t uat i ons.
EVACUATION
Fi r e
I f t ank, r ai l car or t ank t r uck i s i nvol ved i n a f i r e, I SOLATE f or 800 met er s ( 1/ 2 mi l e) i n al l
di rect i ons; al so, consi der i ni t i al evacuat i on f or 800 met ers (1/ 2 mi l e) i n al l di rect i ons.
111
Page 171
MIXED LOAD/UNIDENTIFIED CARGO
EMERGENCY RESPONSE
FIRE
CAUTI ON: Mat eri al may react wi t h ext i ngui shi ng agent .
Smal l Fi r es
Dr y chemi cal , CO
2
, wat er spr ay or r egul ar f oam.
Lar ge Fi r es
Wat er spr ay, f og or r egul ar f oam.
Move cont ai ner s f r om f i r e ar ea i f you can do i t wi t hout r i sk.
Fi r e i nvol vi ng Tanks
Cool cont ai ners wi t h f l oodi ng quant i t i es of wat er unt i l wel l af t er f i re i s out .
Do not get wat er i nsi de cont ai ners.
Wi t hdr aw i mmedi at el y i n case of r i si ng sound f r om vent i ng saf et y devi ces or
di scol orat i on of t ank.
ALWAYS st ay away f r om t anks engul f ed i n f i r e.
SPILL OR LEAK
Do not t ouch or wal k t hrough spi l l ed mat eri al .
ELI MI NATE al l i gni t i on sour ces ( no smoki ng, f l ar es, spar ks or f l ames i n i mmedi at e ar ea) .
Al l equi pment used when handl i ng t he product must be grounded.
Keep combust i bl es ( wood, paper , oi l , et c. ) away f r om spi l l ed mat er i al .
Use wat er spr ay t o r educe vapor s or di ver t vapor cl oud dr i f t . Avoi d al l owi ng water runoff
t o cont act spi l l ed mat eri al .
Pr event ent r y i nt o wat er ways, sewer s, basement s or conf i ned ar eas.
Smal l Spi l l s Take up wi t h sand or ot her non- combust i bl e absor bent mat er i al and pl ace
i nt o cont ai ners f or l at er di sposal .
Large Spi l l s Di ke f ar ahead of l i qui d spi l l f or l at er di sposal .
FIRST AID
Move vi ct i m t o f r esh ai r . Cal l 911 or emer gency medi cal ser vi ce.
Gi ve art i f i ci al respi rat i on i f vi ct i m i s not breat hi ng.
Do not use mout h- t o- mout h met hod i f vi ct i m i ngest ed or i nhal ed t he subst ance;
gi ve ar t i f i ci al r espi r at i on wi t h t he ai d of a pocket mask equi pped wi t h a one- way
val ve or ot her pr oper r espi r at or y medi cal devi ce.
Admi ni st er oxygen i f breat hi ng i s di f f i cul t .
Remove and i sol at e cont ami nat ed cl ot hi ng and shoes.
I n case of cont act wi t h subst ance, i mmedi at el y f l ush ski n or eyes wi t h r unni ng wat er f or
at l east 20 mi nut es.
Shower and wash wi t h soap and wat er .
Keep vi ct i m war m and qui et .
Ef f ect s of exposur e ( i nhal at i on, i ngest i on or ski n cont act ) t o subst ance may be del ayed.
Ensur e t hat medi cal per sonnel ar e awar e of t he mat er i al ( s) i nvol ved and t ake
precaut i ons t o prot ect t hemsel ves.
111
Page 172
EXPLOSIVES* - DIVISION 1.1, 1.2, 1.3, 1.5 OR
1.6; CLASS A OR B
POTENTIAL HAZARDS
FIRE OR EXPLOSION
MAY EXPLODE AND THROW FRAGMENTS 1600 met ers ( 1 MI LE) OR MORE I F FI RE
REACHES CARGO.
For i nformati on on Compati bi l i ty Group l etters, refer to Gl ossary secti on.
HEALTH
Fi re may produce i rri t at i ng, corrosi ve and/ or t oxi c gases.
PUBLI C SAFETY
CALL Emergency Response Tel ephone Number on Shi ppi ng Paper fi rst. I f Shi ppi ng
Paper not avai l abl e or no answer, refer to appropri ate tel ephone number l i sted on the
i nsi de back cover.
I sol at e spi l l or l eak area i mmedi at el y f or at l east 500 met ers (1/ 3 mi l e) i n al l di rect i ons.
Move peopl e out of l i ne of si ght of t he scene and away f rom wi ndows.
Keep unauthori zed personnel away.
Stay upwi nd.
Venti l ate cl osed spaces before enteri ng.
PROTECTI VE CLOTHI NG
Wear posi ti ve pressure sel f-contai ned breathi ng apparatus (SCBA).
Structural fi refi ghters protecti ve cl othi ng wi l l onl y provi de l i mi ted protecti on.
EVACUATION
Large Spi l l
Consi der i ni ti al evacuati on for 800 meters (1/ 2 mi l e) i n al l di recti ons.
Fire
I f rai l car or t rai l er i s i nvol ved i n a f i re and heavi l y encased expl osi ves such as bombs or
art i l l ery proj ect i l es are suspect ed, I SOLATE f or 1600 m (1 mi l e) i n al l di rect i ons; al so,
i ni t i at e evacuat i on i ncl udi ng emergency responders f or 1600 m (1 mi l e) i n al l di rect i ons.
When heavi l y encased expl osi ves are not i nvol ved, evacuat e t he area f or 800 met ers
(1/ 2 mi l e) i n al l di rect i ons.
112
* For i nformati on on "Compati bi l i ty Group" l etters, refer to the Gl ossary secti on.
Page 173
EXPLOSIVES* - DIVISION 1.1, 1.2, 1.3, 1.5 OR
1.6; CLASS A OR B
EMERGENCY RESPONSE
FIRE
CARGO Fi res
DO NOT f i ght f i re when f i re reaches cargo! Cargo may EXPLODE!
St op al l t raf f i c and cl ear t he area f or at l east 1600 met ers (1 mi l e) i n al l di rect i ons and l et
burn.
Do not move cargo or vehi cl e i f cargo has been exposed t o heat .
TI RE or VEHI CLE Fi res
Use pl enty of water - FLOOD i t! I f water i s not avai l abl e, use CO
2
, dry chemi cal or di rt.
I f possi bl e, and WI THOUT RI SK, use unmanned hose hol ders or moni t or nozzl es f rom
maxi mum di st ance t o prevent f i re f rom spreadi ng t o cargo area.
Pay speci al at t ent i on t o t i re f i res as re-i gni t i on may occur. St and by wi t h ext i ngui sher ready.
SPI LL OR LEAK
ELI MI NATE al l i gni t i on sources (no smoki ng, f l ares, sparks or f l ames i n i mmedi at e area).
DO NOT OPERATE RADI O TRANSMI TTERS WI THI N 100 met ers (330 f eet ) OF ELECTRI C
DETONATORS.
DO NOT CLEAN-UP OR DI SPOSE OF, EXCEPT UNDER SUPERVI SI ON OF A
SPECI ALI ST.
FI RST AI D
112
Page 174
FLAMMABLE SOLIDS - TOXIC
(WET/DESENSITIZED EXPLOSIVE)
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Fl ammabl e/ combust i bl e mat eri al .
DRI ED OUT mat er i al may expl ode i f exposed t o heat , f l ame, f r i ct i on or shock;
Treat as an expl osi ve ( GUI DE 112) .
Keep mat eri al wet wi t h wat er or t reat as an expl osi ve ( GUI DE 112) .
Runof f t o sewer may cr eat e f i r e or expl osi on hazar d.
HEALTH
Some ar e t oxi c and may be f at al i f i nhal ed, swal l owed or absor bed t hr ough ski n.
Fi r e may pr oduce i r r i t at i ng, cor r osi ve and/ or t oxi c gases.
Runof f f rom f i re cont rol or di l ut i on wat er may cause pol l ut i on.
PUBLIC SAFETY
I sol at e spi l l or l eak area i mmedi at el y f or at l east 100 met ers (330 f eet ) i n al l di rect i ons.
St ay upwi nd.
Vent i l at e cl osed spaces bef ore ent eri ng.
PROTECTIVE CLOTHING
St ruct ural f i ref i ght ers prot ect i ve cl ot hi ng wi l l onl y provi de l i mi t ed prot ect i on.
EVACUATION
Lar ge Spi l l
Consi der i ni t i al evacuat i on f or 500 met er s ( 1/ 3 mi l e) i n al l di r ect i ons.
Fi r e
113
Page 175
FLAMMABLE SOLIDS - TOXIC
(WET/DESENSITIZED EXPLOSIVE)
EMERGENCY RESPONSE
FI RE
CARGO Fi res
St op al l t raf f i c and cl ear t he area f or at l east 800 met ers (1/ 2 mi l e) i n al l di rect i ons and l et
burn.
Do not move cargo or vehi cl e i f cargo has been exposed to heat.
2
SPI LL OR LEAK
Smal l Spi l l s
Fl ush area wi t h f l oodi ng quant i t i es of wat er.
Large Spi l l s
Wet down wi t h wat er and di ke f or l at er di sposal .
KEEP WETTED PRODUCT WET BY SLOWLY ADDI NG FLOODI NG QUANTI TI ES OF
WATER.
FI RST AI D
113
Page 176
POTENTIAL HAZARDS
FIRE OR EXPLOSION
MAY EXPLODE AND THROW FRAGMENTS 500 met ers ( 1/ 3 MI LE) OR MORE I F FI RE
REACHES CARGO.
For i nformati on on Compati bi l i ty Group l etters, refer to Gl ossary secti on.
HEALTH
PUBLI C SAFETY
I sol at e spi l l or l eak area i mmedi at el y f or at l east 100 met ers (330 f eet ) i n al l di rect i ons.
Move peopl e out of l i ne of si ght of t he scene and away f rom wi ndows.
Keep unauthori zed personnel away.
Stay upwi nd.
Venti l ate cl osed spaces before enteri ng.
Structural fi refi ghters protecti ve cl othi ng wi l l onl y provi de l i mi ted protecti on.
EVACUATION
Large Spi l l
Consi der i ni ti al evacuati on for 250 meters (800 feet) i n al l di recti ons.
Fire
I f rai l car or t rai l er i s i nvol ved i n a f i re, I SOLATE f or 500 met ers (1/ 3 mi l e) i n al l di rect i ons;
al so i ni t i at e evacuat i on i ncl udi ng emergency responders f or 500 met ers (1/ 3 mi l e) i n al l
di recti ons.
EXPLOSIVES* - DIVISION 1.4; CLASS C
114
Page 177
EMERGENCY RESPONSE
FIRE
CARGO Fi res
St op al l t raf f i c and cl ear t he area f or at l east 500 met ers (1/ 3 mi l e) i n al l di rect i ons and l et
burn.
Do not move cargo or vehi cl e i f cargo has been exposed to heat.
2
SPI LL OR LEAK
DO NOT OPERATE RADI O TRANSMI TTERS WI THI N 100 met ers (330 f eet ) OF ELECTRI C
DETONATORS.
SPECI ALI ST.
FI RST AI D
SUPPLEMENTAL INFORMATION
Packages beari ng t he 1. 4S l abel or packages cont ai ni ng mat eri al cl assi f i ed as 1. 4S are
desi gned or packaged i n such a manner t hat when i nvol ved i n a f i re, may burn vi gorousl y
wi th l ocal i zed detonati ons and proj ecti on of fragments.
Ef f ect s are usual l y conf i ned t o i mmedi at e vi ci ni t y of packages.
I f f i re t hreat ens cargo area cont ai ni ng packages beari ng t he 1. 4S l abel or packages
cont ai ni ng mat eri al cl assi f i ed as 1. 4S, consi der i sol at i ng at l east 15 met ers (50 feet) in all
di rect i ons. Fi ght f i re wi t h normal precaut i ons f rom a reasonabl e di st ance.
EXPLOSIVES* - DIVISION 1.4; CLASS C
114
Page 178
POTENTIAL HAZARDS
FI RE OR EXPLOSI ON
EXTREMELY FLAMMABLE.
Wi l l be easi l y i gni t ed by heat , spar ks or f l ames.
Wi l l f or m expl osi ve mi xt ur es wi t h ai r .
Vapors f rom l i quef i ed gas are i ni t i al l y heavi er t han ai r and spread al ong ground.
CAUTI ON: Hydrogen ( UN1049) , Deut eri um ( UN1957) and Met hane ( UN1971) are
l i ght er t han ai r and wi l l r i se. Hydr ogen and Deut er i um f i r es ar e di f f i cul t t o
det ect si nce t hey bur n wi t h an i nvi si bl e f l ame. Use an al t er nat e met hod of
det ect i on ( t her mal camer a, br oom handl e, et c. )
Cyl i nder s exposed t o f i r e may vent and r el ease f l ammabl e gas t hr ough pr essur e r el i ef
devi ces.
HEALTH
Vapor s may cause di zzi ness or asphyxi at i on wi t hout war ni ng.
Some may be i rri t at i ng i f i nhal ed at hi gh concent rat i ons.
Cont act wi t h gas or l i quef i ed gas may cause bur ns, sever e i nj ur y and/ or f r ost bi t e.
Fi r e may pr oduce i r r i t at i ng and/ or t oxi c gases.
PUBLIC SAFETY
St ay upwi nd.
Many gases ar e heavi er t han ai r and wi l l spr ead al ong gr ound and col l ect i n l ow or
conf i ned ar eas ( sewer s, basement s, t anks) .
PROTECTIVE CLOTHING
Al ways wear t her mal pr ot ect i ve cl ot hi ng when handl i ng r ef r i ger at ed/ cr yogeni c l i qui ds.
EVACUATION
Lar ge Spi l l
Consi der i ni t i al downwi nd evacuat i on f or at l east 800 met er s ( 1/ 2 mi l e) .
Fi r e
I f t ank, r ai l car or t ank t r uck i s i nvol ved i n a f i r e, I SOLATE f or 1600 met er s ( 1 mi l e) i n al l
di r ect i ons; al so, consi der i ni t i al evacuat i on f or 1600 met er s ( 1 mi l e) i n al l di r ect i ons.
GASES - FLAMMABLE
(INCLUDING REFRIGERATED LIQUIDS)
115
Page 179
EMERGENCY RESPONSE
FIRE
DO NOT EXTI NGUI SH A LEAKI NG GAS FI RE UNLESS LEAK CAN BE STOPPED.
CAUTI ON: Hydr ogen ( UN1049) and Deut er i um ( UN1957) bur n wi t h an i nvi si bl e
f l ame.
Smal l Fi r es
Dr y chemi cal or CO
2
.
Lar ge Fi r es
Wat er spr ay or f og.
Fi ght f i r e f r om maxi mum di st ance or use unmanned hose hol der s or moni t or nozzl es.
Do not di r ect wat er at sour ce of l eak or saf et y devi ces; i ci ng may occur .
For massi ve f i r e, use unmanned hose hol der s or moni t or nozzl es; i f t hi s i s i mpossi bl e,
wi t hdraw f rom area and l et f i re burn.
SPI LL OR LEAK
St op l eak i f you can do i t wi t hout ri sk.
I f possi bl e, t urn l eaki ng cont ai ners so t hat gas escapes rat her t han l i qui d.
Use wat er spray t o reduce vapors or di vert vapor cl oud dri f t . Avoid allowing water runoff t o
contact spi l l ed materi al .
Do not di rect wat er at spi l l or source of l eak.
Prevent spreadi ng of vapors t hrough sewers, vent i l at i on syst ems and conf i ned areas.
I sol at e area unt i l gas has di spersed.
CAUTI ON: When i n contact wi th refri gerated/ cryogeni c l i qui ds, many materi al s become
bri ttl e and are l i kel y to break wi thout warni ng.
FI RST AI D
Cl ot hi ng f rozen t o t he ski n shoul d be t hawed bef ore bei ng removed.
I n case of cont act wi t h l i quef i ed gas, t haw f r ost ed par t s wi t h l ukewar m wat er .
I n case of bur ns, i mmedi at el y cool af f ect ed ski n f or as l ong as possi bl e wi t h col d wat er .
Do not remove cl ot hi ng i f adheri ng t o ski n. Keep vi ct i m war m and qui et .
GASES - FLAMMABLE
115
Page 180
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Wi l l be easi l y i gni t ed by heat , spar ks or f l ames.
Wi l l f or m expl osi ve mi xt ur es wi t h ai r .
Si l ane wi l l i gni t e spont aneousl y i n ai r .
Those subst ances desi gnat ed wi t h a "P" may pol ymer i ze expl osi vel y when heat ed or
i nvol ved i n a f i re.
devi ces.
HEALTH
Some may be t oxi c i f i nhal ed at hi gh concent r at i ons.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
GASES - FLAMMABLE (UNSTABLE)
116
Page 181
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
.
Lar ge Fi r es
SPI LL OR LEAK
Prevent ent ry i nt o wat erways, sewers, basement s or conf i ned areas.
FI RST AI D
Do not remove cl ot hi ng i f adheri ng t o ski n.
GASES - FLAMMABLE (UNSTABLE)
116
Page 182
POTENTIAL HAZARDS
HEALTH
TOXI C; Ext remel y Hazardous.
May be f at al i f i nhal ed or absor bed t hr ough ski n.
I ni t i al odor may be i r r i t at i ng or f oul and may deaden your sense of smel l .
Fi r e wi l l pr oduce i r r i t at i ng, cor r osi ve and/ or t oxi c gases.
FIRE OR EXPLOSION
These mat er i al s ar e ext r emel y f l ammabl e.
May f or m expl osi ve mi xt ur es wi t h ai r .
Runof f may cr eat e f i r e or expl osi on hazar d.
Cyl i nder s exposed t o f i r e may vent and r el ease t oxi c and f l ammabl e gas t hr ough
pr essur e r el i ef devi ces.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
Wear chemi cal pr ot ect i ve cl ot hi ng t hat i s speci f i cal l y r ecommended by t he manuf act ur er .
I t may provi de l i t t l e or no t hermal prot ect i on.
ONLY; i t i s not ef f ect i ve i n spi l l si t uat i ons wher e di r ect cont act wi t h t he subst ance i s
possi bl e.
EVACUATION
Spi l l
See t he Tabl e of I ni t i al I sol at i on and Prot ect i ve Act i on Di st ances.
Fi r e
GASES - TOXIC - FLAMMABLE (EXTREME HAZARD)
117
Page 183
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
Damaged cyl i nder s shoul d be handl ed onl y by speci al i st s.
di scol or at i on of t ank.
SPILL OR LEAK
Ful l y encapsul at i ng, vapor pr ot ect i ve cl ot hi ng shoul d be wor n f or spi l l s and l eaks wi t h
no f i r e. Do not t ouch or wal k t hr ough spi l l ed mat er i al .
St op l eak i f you can do i t wi t hout r i sk.
t o cont act spi l l ed mat eri al . Do not di r ect wat er at spi l l or sour ce of l eak.
Consi der i gni t i ng spi l l or l eak t o el i mi nat e t oxi c gas concer ns.
FIRST AID
Keep vi ct i m war m and qui et . Keep vi ct i m under obser vat i on.
Ef f ect s of cont act or i nhal at i on may be del ayed.
GASES - TOXIC - FLAMMABLE (EXTREME HAZARD)
117
Page 184
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Some of t hese mat er i al s may r eact vi ol ent l y wi t h wat er .
devi ces.
HEALTH
May cause t oxi c ef f ect s i f i nhal ed.
Vapor s ar e ext r emel y i r r i t at i ng.
PUBLIC SAFETY
St ay upwi nd.
Keep out of l ow ar eas. Vent i l at e cl osed spaces bef ore ent eri ng.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
GASES - FLAMMABLE - CORROSIVE
118
Page 185
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
.
Lar ge Fi r es
SPILL OR LEAK
Ful l y encapsul at i ng, vapor pr ot ect i ve cl ot hi ng shoul d be wor n f or spi l l s and
l eaks wi t h no f i re.
Do not di r ect wat er at spi l l or sour ce of l eak.
FIRST AID
GASES - FLAMMABLE - CORROSIVE
118
Page 186
POTENTIAL HAZARDS
HEALTH
TOXI C; may be f at al i f i nhal ed or absor bed t hr ough ski n.
Runof f f r om f i r e cont r ol may cause pol l ut i on.
FIRE OR EXPLOSION
Fl ammabl e; may be i gni t ed by heat , spar ks or f l ames.
i nvol ved i n a f i r e.
Vapor s f r om l i quef i ed gas ar e i ni t i al l y heavi er t han ai r and spr ead al ong gr ound.
Cyl i nder s exposed t o f i r e may vent and r el ease t oxi c and f l ammabl e gas t hr ough
PUBLIC SAFETY
( 330 f eet ) i n al l di r ect i ons.
Keep unaut hor i zed per sonnel away. St ay upwi nd.
Keep out of l ow ar eas. Vent i l at e cl osed spaces bef or e ent er i ng.
PROTECTIVE CLOTHING
Wear posi t i ve pr essur e sel f - cont ai ned br eat hi ng appar at us ( SCBA) .
I t may pr ovi de l i t t l e or no t her mal pr ot ect i on.
possi bl e.
EVACUATION
Spi l l
See t he Tabl e of I ni t i al I sol at i on and Prot ect i ve Act i on Di st ances f or hi ghl i ght ed
subst ances. For non- hi ghl i ght ed subst ances, i ncr ease, i n t he downwi nd di r ect i on, as
necessar y, t he i sol at i on di st ance shown under PUBLI C SAFETY .
Fi r e
GASES - TOXIC - FLAMMABLE
119
Page 187
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
, wat er spr ay or al cohol - r esi st ant f oam.
Lar ge Fi r es
Wat er spray, f og or al cohol -resi st ant f oam.
FOR CHLOROSI LANES, DO NOT USE WATER; use AFFF al cohol - r esi st ant medi um
expansi on f oam. Move cont ai ner s f r om f i r e ar ea i f you can do i t wi t hout r i sk.
di scol or at i on of t ank. ALWAYS st ay away f r om t anks engul f ed i n f i r e.
SPILL OR LEAK
Ful l y encapsul ati ng, vapor protecti ve cl othi ng shoul d be worn for spi l l s and l eaks wi th no fi re.
FOR CHLOROSI LANES, use AFFF al cohol - r esi st ant medi um expansi on f oam t o r educe
vapor s.
FIRST AID
GASES - TOXIC - FLAMMABLE
119
Page 188
POTENTIAL HAZARDS
HEALTH
FIRE OR EXPLOSION
Non- f l ammabl e gases.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
Al ways wear t her mal pr ot ect i ve cl ot hi ng when handl i ng r ef r i ger at ed/ cr yogeni c l i qui ds or
sol i ds.
EVACUATION
Lar ge Spi l l
Consi der i ni t i al downwi nd evacuat i on f or at l east 100 met er s ( 330 f eet ) .
Fi r e
di r ect i ons; al so, consi der i ni t i al evacuat i on f or 800 met er s ( 1/ 2 mi l e) i n al l di r ect i ons.
GASES - INERT
120
Page 189
EMERGENCY RESPONSE
FIRE
Use ext i ngui shi ng agent sui t abl e f or t ype of surroundi ng f i re.
SPILL OR LEAK
Al l ow subst ance t o evapor at e.
Vent i l at e t he area.
CAUTI ON: When i n cont act wi t h r ef r i ger at ed/ cr yogeni c l i qui ds, many mat er i al s
become br i t t l e and ar e l i kel y t o br eak wi t hout war ni ng.
FIRST AID
GASES - INERT
120
Page 190
POTENTIAL HAZARDS
HEALTH
FIRE OR EXPLOSION
Non- f l ammabl e gases.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
GASES - INERT
121
Page 191
EMERGENCY RESPONSE
FIRE
SPILL OR LEAK
FIRST AID
GASES - INERT
121
Page 192
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Subst ance does not burn but wi l l support combust i on.
Some may r eact expl osi vel y wi t h f uel s.
May i gni t e combust i bl es ( wood, paper , oi l , cl ot hi ng, et c. ) .
HEALTH
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
GASES - OXIDIZING
122
Page 193
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
.
Lar ge Fi r es
SPI LL OR LEAK
Keep combust i bl es (wood, paper, oi l , et c. ) away f rom spi l l ed mat eri al .
Al l ow substance to evaporate.
CAUTI ON: When i n contact wi th refri gerated/ cryogeni c l i qui ds, many materi al s become
bri ttl e and are l i kel y to break wi thout warni ng.
FI RST AI D
Move vi ct i m t o f resh ai r. Cal l 911 or emergency medi cal servi ce.
GASES - OXIDIZING
122
Page 194
POTENTIAL HAZARDS
HEALTH
Vapor s may be i r r i t at i ng.
FIRE OR EXPLOSION
Some may bur n, but none i gni t e r eadi l y.
Cyl i nder s exposed t o f i r e may vent and r el ease t oxi c and/ or cor r osi ve gas t hr ough
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
GASES - TOXIC AND/OR CORROSIVE
123
Page 195
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
.
Lar ge Fi r es
SPILL OR LEAK
FI RST AI D
GASES - TOXIC AND/OR CORROSIVE
123
Page 196
POTENTIAL HAZARDS
HEALTH
FIRE OR EXPLOSION
These ar e st r ong oxi di zer s and wi l l r eact vi gor ousl y or expl osi vel y wi t h many mat er i al s
i ncl udi ng fuel s.
May i gni t e combust i bl es (wood, paper, oi l , cl ot hi ng, et c. ).
Some wi l l r eact vi ol ent l y wi t h ai r , moi st ai r and/ or wat er .
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
GASES - TOXIC AND/OR CORROSIVE - OXIDIZING
124
Page 197
EMERGENCY RESPONSE
FIRE
Smal l Fi r es: Wat er onl y; no dr y chemi cal , CO
2
or Hal on
.
Cont ai n f i r e and l et bur n. I f f i r e must be f ought , wat er spr ay or f og i s r ecommended.
SPI LL OR LEAK
Ful l y encapsul at i ng, vapor prot ect i ve cl ot hi ng shoul d be worn f or spi l l s and l eaks wi t h no
f i re.
Venti l ate the area.
FI RST AI D
GASES - TOXIC AND/OR CORROSIVE - OXIDIZING
124
Page 198
POTENTIAL HAZARDS
HEALTH
TOXI C; may be f at al i f i nhal ed, i ngest ed or absor bed t hr ough ski n.
Vapor s ar e ext r emel y i r r i t at i ng and cor r osi ve.
FIRE OR EXPLOSION
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
GASES - CORROSIVE
125
Page 199
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
.
Lar ge Fi r es
di scol orat i on of t ank. ALWAYS st ay away f r om t anks engul f ed i n f i r e.
SPILL OR LEAK
cont act spi l l ed mat eri al . I sol at e ar ea unt i l gas has di sper sed.
FIRST AID
I n case of cont act wi t h Hydrogen f l uori de, anhydrous ( UN1052) , f l ush ski n and
eyes wi t h wat er f or 5 mi nut es; t hen, f or ski n exposur es r ub on a cal ci um/ j el l y
combi nat i on; f or eyes f l ush wi t h a wat er / cal ci um sol ut i on f or 15 mi nut es.
GASES - CORROSIVE
125
Page 200
POTENTIAL HAZARDS
FIRE OR EXPLOSION
HEALTH
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
GASES - COMPRESSED OR LIQUEFIED
(INCLUDING REFRIGERANT GASES)
126
Page 201
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
.
Lar ge Fi r es
Some of t hese mat er i al s, i f spi l l ed, may evapor at e l eavi ng a f l ammabl e r esi due.
SPILL OR LEAK
FIRST AID
GASES - COMPRESSED OR LIQUEFIED
(INCLUDING REFRIGERANT GASES)
126
Page 202
POTENTIAL HAZARDS
FIRE OR EXPLOSION
HI GHLY FLAMMABLE: Wi l l be easi l y i gni t ed by heat , spar ks or f l ames.
Vapor s may f or m expl osi ve mi xt ur es wi t h ai r .
Most vapor s ar e heavi er t han ai r . They wi l l spr ead al ong gr ound and col l ect i n l ow or
confi ned areas (sewers, basements, tanks).
Vapor expl osi on hazard i ndoors, out doors or i n sewers.
Those subst ances desi gnat ed wi t h a "P" may pol ymeri ze expl osi vel y when heat ed or
Runof f t o sewer may creat e f i re or expl osi on hazard.
Contai ners may expl ode when heated.
Many l i qui ds are l i ght er t han wat er.
HEALTH
I nhal at i on or cont act wi t h mat eri al may i rri t at e or burn ski n and eyes.
Vapors may cause di zzi ness or suf f ocat i on.
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Consi der i ni t i al downwi nd evacuat i on f or at l east 300 met ers (1000 f eet ).
Fi r e
FLAMMABLE LIQUIDS
(POLAR/WATER-MISCIBLE)
127
Page 203
EMERGENCY RESPONSE
FIRE
CAUTI ON: Al l t hese product s have a very l ow f l ash poi nt : Use of wat er spray when
fi ghti ng fi re may be i neffi ci ent.
Smal l Fi res
Dry chemi cal , CO
2
, wat er spray or al cohol -resi st ant f oam.
Large Fi res
Water spray, fog or al cohol -resi stant foam.
Use wat er spray or f og; do not use st rai ght st reams.
Move cont ai ners f rom f i re area i f you can do i t wi t hout ri sk.
Fi re i nvol vi ng Tanks or Car/ Trai l er Loads
Fi ght f i re f rom maxi mum di st ance or use unmanned hose hol ders or moni t or nozzl es.
Wi t hdraw i mmedi at el y i n case of ri si ng sound f rom vent i ng saf et y devi ces or
di scol orati on of tank.
ALWAYS st ay away f rom t anks engul f ed i n f i re.
For massi ve f i re, use unmanned hose hol ders or moni t or nozzl es; i f t hi s i s i mpossi bl e,
SPI LL OR LEAK
A vapor suppressi ng f oam may be used t o reduce vapors.
Absorb or cover wi t h dry eart h, sand or ot her non-combust i bl e mat eri al and
transfer to contai ners.
Use cl ean non-sparki ng t ool s t o col l ect absorbed mat eri al .
Large Spi l l s
Di ke f ar ahead of l i qui d spi l l f or l at er di sposal .
Wat er spray may reduce vapor; but may not prevent i gni t i on i n cl osed spaces.
FI RST AI D
at l east 20 mi nut es. Wash ski n wi t h soap and wat er .
FLAMMABLE LIQUIDS
(POLAR/WATER-MISCIBLE)
127
Page 204
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Subst ance may be t ransport ed hot .
I f mol t en al umi num i s i nvol ved, r ef er t o GUI DE 169.
HEALTH
I nhal at i on or cont act wi t h mat er i al may i r r i t at e or bur n ski n and eyes.
Vapor s may cause di zzi ness or suf f ocat i on.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
FLAMMABLE LIQUIDS
(NON-POLAR/WATER-IMMISCIBLE)
128
Page 205
EMERGENCY RESPONSE
FIRE
f i ght i ng f i r e may be i nef f i ci ent .
CAUTI ON: For mi xt ur es cont ai ni ng a hi gh per cent age of an al cohol or pol ar
sol vent , al cohol - resi st ant f oam may be more ef f ect i ve.
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
Use wat er spr ay or f og; do not use st r ai ght st r eams.
Fi r e i nvol vi ng Tanks or Car / Tr ai l er Loads
SPI LL OR LEAK
Do not t ouch or wal k t hrough spi l l ed mat eri al . St op l eak i f you can do i t wi t hout r i sk.
A vapor suppr essi ng f oam may be used t o r educe vapor s.
Absor b or cover wi t h dr y ear t h, sand or ot her non- combust i bl e mat er i al and
t ransf er t o cont ai ners. Use cl ean non- spar ki ng t ool s t o col l ect absor bed mat er i al .
Lar ge Spi l l s
Wat er spr ay may r educe vapor ; but may not pr event i gni t i on i n cl osed spaces.
FIRST AID
Wash ski n wi t h soap and wat er . Keep vi ct i m war m and qui et .
FLAMMABLE LIQUIDS
(NON-POLAR/WATER-IMMISCIBLE)
128
Page 206
POTENTIAL HAZARDS
FIRE OR EXPLOSION
HEALTH
May cause t oxi c ef f ect s i f i nhal ed or absorbed t hrough ski n.
Fi re wi l l produce i rri t at i ng, corrosi ve and/ or t oxi c gases.
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
FLAMMABLE LIQUIDS
(POLAR/WATER-MISCIBLE/NOXIOUS)
129
Page 207
EMERGENCY RESPONSE
FIRE
Smal l Fi res Dry chemi cal , CO
2
Do not use dry chemi cal exti ngui shers to control fi res i nvol vi ng ni tromethane or
nitroethane.
Large Fi res
Do not use strai ght streams.
SPI LL OR LEAK
FIRST AID
FLAMMABLE LIQUIDS
(POLAR/WATER-MISCIBLE/NOXIOUS)
129
Page 208
POTENTIAL HAZARDS
FIRE OR EXPLOSION
HEALTH
May cause t oxi c ef f ect s i f i nhal ed or absorbed t hrough ski n.
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
FLAMMABLE LIQUIDS
(NON-POLAR/WATER-IMMISCIBLE/NOXIOUS)
130
Page 209
EMERGENCY RESPONSE
FIRE
Smal l Fi res
Dry chemi cal , CO
2
, wat er spray or regul ar f oam.
Large Fi res
Wat er spray, f og or regul ar f oam.
Do not use strai ght streams.
SPI LL OR LEAK
FI RST AI D
Do not remove cl ot hi ng i f adheri ng t o ski n
FLAMMABLE LIQUIDS
(NON-POLAR/WATER-IMMISCIBLE/NOXIOUS)
130
Page 210
POTENTIAL HAZARDS
HEALTH
TOXI C; may be f at al i f i nhal ed, i ngest ed or absor bed t hr ough ski n.
I nhal at i on or cont act wi t h some of t hese mat er i al s wi l l i r r i t at e or bur n ski n and eyes.
FIRE OR EXPLOSION
Vapor expl osi on and poi son hazard i ndoors, out doors or i n sewers.
PUBLI C SAFETY
St ay upwi nd. Keep out of l ow ar eas.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
necessar y, t he i sol at i on di st ance shown under "PUBLI C SAFETY".
Fi r e
FLAMMABLE LIQUIDS - TOXIC
131
Page 211
EMERGENCY RESPONSE
FIRE
Smal l Fi res Dry chemi cal , CO
2
Large Fi res
Di ke f i re cont rol wat er f or l at er di sposal ; do not scat t er t he mat eri al .
SPI LL OR LEAK
f i re.
Smal l Spi l l s Absor b wi t h ear t h, sand or ot her non- combust i bl e mat er i al and
t ransf er t o cont ai ners f or l at er di sposal .
FIRST AID
FLAMMABLE LIQUIDS - TOXIC
131
Page 212
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Fl ammabl e/ combust i bl e mat er i al s.
Vapor expl osi on hazar d i ndoor s, out door s or i n sewer s.
Runof f t o sewer may cr eat e f i r e or expl osi on hazar d.
Many l i qui ds ar e l i ght er t han wat er .
HEALTH
May cause t oxi c ef f ect s i f i nhal ed or i ngest ed/ swal l owed.
Cont act wi t h subst ance may cause sever e bur ns t o ski n and eyes.
Runof f f r om f i r e cont r ol or di l ut i on wat er may cause pol l ut i on.
PUBLIC SAFETY
( 150 f eet ) i n al l di r ect i ons.
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
FLAMMABLE LIQUIDS - CORROSIVE
132
Page 213
EMERGENCY RESPONSE
FIRE
Some of t hese mat eri al s may react vi ol ent l y wi t h wat er.
Smal l Fi res Dr y chemi cal , CO
2
Large Fi res Wat er spr ay, f og or al cohol - r esi st ant f oam.
SPI LL OR LEAK
f i re.
Absorb wi t h eart h, sand or ot her non-combust i bl e mat eri al and t ransf er t o
contai ners (except for Hydrazi ne).
FI RST AI D
FLAMMABLE LIQUIDS - CORROSIVE
132
Page 214
POTENTIAL HAZARDS
FIRE OR EXPLOSION
May be i gni t ed by f r i ct i on, heat , spar ks or f l ames.
Some may bur n r api dl y wi t h f l ar e bur ni ng ef f ect .
Powder s, dust s, shavi ngs, bor i ngs, t ur ni ngs or cut t i ngs may expl ode or bur n wi t h
expl osi ve vi ol ence.
Subst ance may be t r anspor t ed i n a mol t en f or m at a t emper at ur e t hat may be above i t s
f l ash poi nt .
May re-i gni t e af t er f i re i s ext i ngui shed.
HEALTH
Cont act wi t h mol t en subst ance may cause sever e bur ns t o ski n and eyes.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
FLAMMABLE SOLIDS
133
Page 215
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
, sand, ear t h, wat er spr ay or r egul ar f oam.
Lar ge Fi r es
SPI LL OR LEAK
Smal l Dry Spi l l s
Wi t h cl ean shovel pl ace mat eri al i nt o cl ean, dry cont ai ner and cover l oosel y; move
cont ai ners f rom spi l l area.
Large Spi l l s
FI RST AI D
Removal of sol i di f i ed mol t en mat er i al f r om ski n r equi r es medi cal assi st ance.
FLAMMABLE SOLIDS
133
Page 216
POTENTIAL HAZARDS
FIRE OR EXPLOSION
When heat ed, vapor s may f or m expl osi ve mi xt ur es wi t h ai r : i ndoor s, out door s and
sewer s expl osi on hazar ds.
Cont act wi t h met al s may evol ve f l ammabl e hydr ogen gas.
HEALTH
TOXI C; i nhal at i on, i ngest i on or ski n cont act wi t h mat er i al may cause sever e i nj ur y or
deat h.
Runof f f r om f i r e cont r ol or di l ut i on wat er may be cor r osi ve and/ or t oxi c and cause
pol l uti on.
PUBLIC SAFETY
St ay upwi nd.
Vent i l at e encl osed areas.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
FLAMMABLE SOLIDS - TOXIC AND/OR CORROSIVE
134
Page 217
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
SPILL OR LEAK
Do not t ouch damaged cont ai ners or spi l l ed mat eri al unl ess weari ng
appropri ate protecti ve cl othi ng.
Use cl ean non-sparki ng t ool s t o col l ect mat eri al and pl ace i t i nt o l oosel y covered pl ast i c
contai ners for l ater di sposal .
FI RST AI D
For mi nor ski n cont act , avoi d spr eadi ng mat er i al on unaf f ect ed ski n.
FLAMMABLE SOLIDS - TOXIC AND/OR CORROSIVE
134
Page 218
POTENTIAL HAZARDS
FIRE OR EXPLOSION
May i gni t e on cont act wi t h moi st ai r or moi st ur e.
May bur n r api dl y wi t h f l ar e- bur ni ng ef f ect .
Some r eact vi gor ousl y or expl osi vel y on cont act wi t h wat er .
Some may decompose expl osi vel y when heat ed or i nvol ved i n a f i r e.
HEALTH
I nhal at i on of decomposi t i on pr oduct s may cause sever e i nj ur y or deat h.
PUBLIC SAFETY
As an i mmedi at e pr ecaut i onar y measur e, i sol at e spi l l or l eak ar ea i n al l di r ect i ons f or at
l east 50 met ers (150 f eet ) f or l i qui ds and at l east 25 met ers (75 f eet ) f or sol i ds.
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Spi l l
Fi r e
SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE
135
Page 219
EMERGENCY RESPONSE
FIRE
DO NOT USE WATER, CO
2
OR FOAM ON MATERI AL I TSELF.
EXCEPTI ON: For Xant hat es, UN3342 and f or Di t hi oni t e ( Hydr osul f i t e/
Hydrosul phi t e) UN1384, UN1923 and UN1929, USE FLOODI NG AMOUNTS OF
WATER f or SMALL AND LARGE f i r es t o st op t he r eact i on. Smot her i ng wi l l not
wor k f or t hese mat er i al s, t hey do not need ai r t o bur n.
Smal l Fi r es
Dr y chemi cal , soda ash, l i me or DRY sand, EXCEPT f or UN1384, UN1923 and UN1929.
Lar ge Fi r es
DRY sand, dr y chemi cal , soda ash or l i me, EXCEPT f or UN1384, UN1923 and UN1929,
or wi t hdr aw f r om ar ea and l et f i r e bur n.
Do not get wat er i nsi de cont ai ner s or i n cont act wi t h subst ance.
SPILL OR LEAK
Ful l y encapsul ati ng, vapor protecti ve cl othi ng shoul d be worn for spi l l s and l eak wi th no fi re.
Smal l Spi l l s
EXCEPTI ON: For spi l l s of Xant hat es, UN3342 and f or Di t hi oni t e ( Hydr osul f i t e/
Hydrosul phi t e) , UN1384, UN1923 and UN1929, di ssol ve i n 5 part s wat er and
col l ect f or pr oper di sposal .
Cover wi t h DRY ear t h, DRY sand or ot her non- combust i bl e mat er i al fol l owed wi th pl asti c
sheet t o mi ni mi ze spreadi ng or cont act wi t h rai n.
Use cl ean non-sparki ng t ool s t o col l ect mat eri al and pl ace i t i nt o l oosel y covered pl ast i c
FI RST AI D
at l east 20 mi nut es. Keep vi ct i m war m and qui et .
SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE
135
Page 220
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Ext r emel y f l ammabl e; wi l l i gni t e i t sel f i f exposed t o ai r .
Bur ns r api dl y, r el easi ng dense, whi t e, i r r i t at i ng f umes.
Subst ance may be t r anspor t ed i n a mol t en f or m.
Cor r osi ve subst ances i n cont act wi t h met al s may pr oduce f l ammabl e hydr ogen gas.
HEALTH
TOXI C; i ngest i on of subst ance or i nhal at i on of decomposi t i on pr oduct s wi l l cause sever e
i nj ury or death.
Cont act wi t h subst ance may cause severe burns t o ski n and eyes.
Some ef f ect s may be experi enced due t o ski n absorpt i on.
Runof f f rom f i re cont rol may be corrosi ve and/ or t oxi c and cause pol l ut i on.
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
For Phosphor us ( UN1381) : Speci al al umi ni zed pr ot ect i ve cl ot hi ng shoul d be
worn when di rect cont act wi t h t he subst ance i s possi bl e.
EVACUATION
Spi l l
Fi r e
SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE -
TOXIC AND/OR CORROSIVE (AIR-REACTIVE)
136
Page 221
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Wat er spr ay, wet sand or wet ear t h.
Lar ge Fi r es
Do not scat t er spi l l ed mat er i al wi t h hi gh pr essur e wat er st r eams.
SPILL OR LEAK
Do not t ouch damaged cont ai ners or spi l l ed mat eri al unl ess weari ng appropri at e
prot ect i ve cl ot hi ng.
Smal l Spi l l s
Cover wi t h wat er , sand or ear t h. Shovel i nt o met al cont ai ner and keep mat er i al under
wat er .
Lar ge Spi l l s
Di ke f or l at er di sposal and cover wi t h wet sand or ear t h.
FIRST AID
I n case of cont act wi t h subst ance, keep exposed ski n ar eas i mmer sed i n wat er or
cover ed wi t h wet bandages unt i l medi cal at t ent i on i s r ecei ved.
Remove and i sol at e cont ami nat ed cl ot hi ng and shoes at t he si t e and pl ace i n met al
cont ai ner f i l l ed wi t h wat er . Fi r e hazar d i f al l owed t o dr y.
SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE -
TOXIC AND/OR CORROSIVE (AIR-REACTIVE)
136
Page 222
POTENTIAL HAZARDS
HEALTH
CORROSI VE and/ or TOXI C; i nhal at i on, i ngest i on or cont act ( ski n, eyes) wi t h vapor s,
dust s or subst ance may cause sever e i nj ur y, bur ns or deat h.
React i on wi t h wat er may gener at e much heat whi ch wi l l i ncr ease t he concent r at i on of
f umes i n t he ai r .
FIRE OR EXPLOSION
EXCEPT FOR ACETI C ANHYDRI DE (UN1715), THAT I S FLAMMABLE, some of t hese
mat er i al s may bur n, but none i gni t e r eadi l y.
Subst ance wi l l r eact wi t h wat er ( some vi ol ent l y) , r el easi ng cor r osi ve and/ or t oxi c
gases.
Fl ammabl e/ t oxi c gases may accumul at e i n conf i ned ar eas ( basement , t anks, hopper /
t ank car s et c. )
Cont ai ner s may expl ode when heat ed or i f cont ami nat ed wi t h wat er .
PUBLIC SAFETY
St ay upwi nd. Keep out of l ow ar eas. Vent i l at e encl osed areas.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
SUBSTANCES - WATER-REACTIVE - CORROSIVE
137
Page 223
EMERGENCY RESPONSE
FIRE
When mat er i al i s not i nvol ved i n f i r e: do not use wat er on mat er i al i t sel f .
Smal l Fi r es
2
.
Lar ge Fi r es
Fl ood f i r e ar ea wi t h l ar ge quant i t i es of wat er , whi l e knocki ng down vapor s wi t h wat er
f og. I f i nsuf f i ci ent wat er suppl y: knock down vapor s onl y.
SPILL OR LEAK
Use wat er spr ay t o r educe vapor s; do not put wat er di r ect l y on l eak, spi l l ar ea or i nsi de
contai ner.
Smal l Spi l l s Cover wi t h DRY eart h, DRY sand or ot her non-combust i bl e mat eri al
f ol l owed wi t h pl ast i c sheet t o mi ni mi ze spr eadi ng or cont act wi t h r ai n.
Use cl ean non- spar ki ng t ool s t o col l ect mat er i al and pl ace i t i nt o l oosel y cover ed pl ast i c
FI RST AI D
SUBSTANCES - WATER-REACTIVE - CORROSIVE
137
Page 224
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Pr oduce f l ammabl e gases on cont act wi t h wat er .
May i gni t e on cont act wi t h wat er or moi st ai r .
Some are t ransport ed i n hi ghl y f l ammabl e l i qui ds.
HEALTH
I nhal at i on or cont act wi t h vapor s, subst ance or decomposi t i on pr oduct s may cause
sever e i nj ur y or deat h.
May pr oduce cor r osi ve sol ut i ons on cont act wi t h wat er .
PUBLIC SAFETY
St ay upwi nd.
Vent i l at e t he area bef ore ent ry.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
SUBSTANCES - WATER-REACTIVE
(EMITTING FLAMMABLE GASES)
138
Page 225
EMERGENCY RESPONSE
FIRE
DO NOT USE WATER OR FOAM.
Smal l Fi r es
Dr y chemi cal , soda ash, l i me or sand.
Lar ge Fi r es
DRY sand, dr y chemi cal , soda ash or l i me or wi t hdr aw f r om ar ea and l et f i r e bur n.
Magnesi um Fi r es
DRY sand, sodi um chl or i de powder , gr aphi t e powder or Met - L- X
powder .
Li t hi um Fi r es
DRY sand, sodi um chl or i de powder , gr aphi t e powder , copper powder or Li t h- X
powder .
SPILL OR LEAK
DO NOT GET WATER on spi l l ed subst ance or i nsi de cont ai ners.
Di ke f or l at er di sposal ; do not appl y wat er unl ess di r ect ed t o do so.
Powder Spi l l s Cover powder spi l l wi t h pl ast i c sheet or t ar p t o mi ni mi ze
spreadi ng and keep powder dry.
SPECI ALI ST.
FI RST AI D
I n case of cont act wi t h subst ance, wi pe f r om ski n i mmedi at el y; f l ush ski n or eyes wi t h
runni ng wat er f or at l east 20 mi nut es.
(EMITTING FLAMMABLE GASES)
138
Page 226
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Pr oduce f l ammabl e and t oxi c gases on cont act wi t h wat er .
May i gni t e on cont act wi t h wat er or moi st ai r .
Some are t ransport ed i n hi ghl y f l ammabl e l i qui ds.
HEALTH
Hi ghl y t oxi c: cont act wi t h wat er pr oduces t oxi c gas, may be f at al i f i nhal ed.
May pr oduce cor r osi ve sol ut i ons on cont act wi t h wat er .
PUBLIC SAFETY
St ay upwi nd.
Vent i l at e t he area bef ore ent ry.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
(EMITTING FLAMMABLE AND TOXIC GASES)
139
Page 227
EMERGENCY RESPONSE
FIRE
DO NOT USE WATER OR FOAM. (FOAM MAY BE USED FOR CHLOROSILANES, SEE BELOW)
Smal l Fi r es
Lar ge Fi r es
expansi on f oam; DO NOT USE dr y chemi cal s, soda ash or l i me on chl or osi l ane f i r es
( l ar ge or smal l ) as t hey may r el ease l ar ge quant i t i es of hydr ogen gas t hat may expl ode.
SPILL OR LEAK
FOR CHLOROSILANES, use AFFF al cohol -resi stant medi um expansi on foam to reduce
vapors.
Di ke f or l at er di sposal ; do not appl y wat er unl ess di r ect ed t o do so.
Powder Spi l l s Cover powder spi l l wi t h pl ast i c sheet or t ar p t o mi ni mi ze
spreadi ng and keep powder dry.
DO NOT CLEAN-UP OR DI SPOSE OF, EXCEPT UNDER SUPERVI SI ON OF A SPECI ALI ST.
FI RST AI D
Ensur e t hat medi cal per sonnel ar e awar e of t he mat er i al ( s) i nvol ved and t ake pr ecaut i ons
t o pr ot ect t hemsel ves.
(EMITTING FLAMMABLE AND TOXIC GASES)
139
Page 228
POTENTIAL HAZARDS
FIRE OR EXPLOSION
These subst ances wi l l accel er at e bur ni ng when i nvol ved i n a f i r e.
Some may decompose expl osi vel y when heat ed or i nvol ved i n a f i r e.
May expl ode f rom heat or cont ami nat i on.
Some wi l l r eact expl osi vel y wi t h hydr ocar bons ( f uel s) .
HEALTH
I nhal at i on, i ngest i on or cont act ( ski n, eyes) wi t h vapor s or subst ance may cause sever e
i nj ur y, bur ns or deat h.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
OXIDIZERS
140
Page 229
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Use wat er . Do not use dr y chemi cal s or f oams. CO
2
or Hal on
may pr ovi de l i mi t ed
cont rol .
Lar ge Fi r es
Fl ood f i r e ar ea wi t h wat er f r om a di st ance.
Do not move car go or vehi cl e i f car go has been exposed t o heat .
SPI LL OR LEAK
Smal l Li qui d Spi l l s
Use a non- combust i bl e mat er i al l i ke ver mi cul i t e or sand t o soak up t he pr oduct and pl ace
i nt o a cont ai ner f or l at er di sposal .
Lar ge Spi l l s
Fol l owi ng pr oduct r ecover y, f l ush ar ea wi t h wat er .
FIRST AID
Cont ami nat ed cl ot hi ng may be a f i r e r i sk when dr y.
OXIDIZERS
140
Page 230
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Some may bur n r api dl y.
HEALTH
Toxi c by i ngest i on.
I nhal at i on of dust i s t oxi c.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
OXIDIZERS - TOXIC
141
Page 231
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
or Hal on
cont rol .
Lar ge Fi r es
SPI LL OR LEAK
Large Spi l l s
Di ke f ar ahead of spi l l f or l at er di sposal .
FI RST AI D
OXIDIZERS - TOXIC
141
Page 232
POTENTIAL HAZARDS
FIRE OR EXPLOSION
HEALTH
TOXI C; i nhal at i on, i ngest i on or cont act ( ski n, eyes) wi t h vapor s or subst ance may
cause sever e i nj ur y, bur ns or deat h.
Toxi c/ f l ammabl e f umes may accumul at e i n conf i ned ar eas ( basement , t anks, t ank car s,
et c. ) .
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
OXIDIZERS - TOXIC (LIQUID)
142
Page 233
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
or Hal on
cont rol .
Lar ge Fi r es
SPI LL OR LEAK
Ful l y encapsul at i ng, vapor prot ect i ve cl ot hi ng shoul d be worn f or spi l l s and
Use wat er spray t o reduce vapors or di vert vapor cl oud dri f t .
Use a non- combust i bl e mat er i al l i ke ver mi cul i t e or sand t o soak up t he pr oduct and pl ace
i nt o a cont ai ner f or l at er di sposal .
Lar ge Spi l l s
FIRST AID
OXIDIZERS - TOXIC (LIQUID)
142
Page 234
POTENTIAL HAZARDS
FIRE OR EXPLOSION
May expl ode f r om f r i ct i on, heat or cont ami nat i on.
HEALTH
TOXI C; i nhal at i on, i ngest i on or cont act ( ski n, eyes) wi t h vapor s, dust s or subst ance
may cause sever e i nj ur y, bur ns or deat h.
Toxi c f umes or dust may accumul at e i n conf i ned ar eas ( basement , t anks, hopper / t ank
car s, et c. ) .
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
OXIDIZERS (UNSTABLE)
143
Page 235
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
2
or Hal on
cont rol .
Lar ge Fi r es
Do not get wat er i nsi de cont ai ner s: a vi ol ent r eact i on may occur .
Di ke f i re-cont rol wat er f or l at er di sposal .
SPI LL OR LEAK
Use wat er spray t o reduce vapors or di vert vapor cl oud dri f t .
Smal l Spi l l s
Fl ush area wi t h f l oodi ng quant i t i es of wat er.
Large Spi l l s
FI RST AI D
OXIDIZERS (UNSTABLE)
143
Page 236
POTENTIAL HAZARDS
FIRE OR EXPLOSION
React vi gor ousl y and/ or expl osi vel y wi t h wat er .
Pr oduce t oxi c and/ or cor r osi ve subst ances on cont act wi t h wat er .
Fl ammabl e/ t oxi c gases may accumul at e i n t anks and hopper car s.
Some may pr oduce f l ammabl e hydr ogen gas upon cont act wi t h met al s.
HEALTH
TOXI C; i nhal at i on or cont act wi t h vapor , subst ance, or decomposi t i on pr oduct s may
cause sever e i nj ur y or deat h.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
OXIDIZERS (WATER-REACTIVE)
144
Page 237
EMERGENCY RESPONSE
FIRE
DO NOT USE WATER OR FOAM.
Smal l Fi r es
Dr y chemi cal , soda ash or l i me.
Lar ge Fi r es
SPILL OR LEAK
appropri at e prot ect i ve cl ot hi ng.
Smal l Spi l l s
Cover wi t h DRY ear t h, DRY sand or ot her non- combust i bl e mat er i al fol l owed wi th pl asti c
sheet t o mi ni mi ze spreadi ng or cont act wi t h rai n.
Large Spi l l s
FI RST AI D
OXIDIZERS (WATER-REACTIVE)
144
Page 238
POTENTIAL HAZARDS
FIRE OR EXPLOSION
HEALTH
I ngest i on or cont act ( ski n, eyes) wi t h subst ance may cause sever e i nj ur y or bur ns.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Consi der i ni t i al evacuat i on f or at l east 250 met ers (800 f eet ).
Fi r e
ORGANIC PEROXIDES
(HEAT AND CONTAMINATION SENSITIVE)
145
Page 239
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Wat er spr ay or f og i s pr ef er r ed; i f wat er not avai l abl e use dr y chemi cal , CO
2
or r egul ar
f oam.
Lar ge Fi r es
SPI LL OR LEAK
Keep subst ance wet usi ng wat er spray.
Smal l Spi l l s
Take up wi t h i ner t , damp, non- combust i bl e mat er i al usi ng cl ean non- spar ki ng t ool s and
pl ace i nt o l oosel y cover ed pl ast i c cont ai ner s f or l at er di sposal .
Lar ge Spi l l s
DO NOT CLEAN- UP OR DI SPOSE OF, EXCEPT UNDER SUPERVI SI ON OF A
SPECI ALI ST.
FI RST AI D
Remove mat er i al f r om ski n i mmedi at el y.
ORGANIC PEROXIDES
(HEAT AND CONTAMINATION SENSITIVE)
145
Page 240
POTENTIAL HAZARDS
FIRE OR EXPLOSION
May expl ode f r om heat , shock, f r i ct i on or cont ami nat i on.
HEALTH
I ngest i on or cont act ( ski n, eyes) wi t h subst ance may cause sever e i nj ur y or bur ns.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
ORGANIC PEROXIDES (HEAT, CONTAMINATION
AND FRICTION SENSITIVE)
146
Page 241
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Wat er spr ay or f og i s pr ef er r ed; i f wat er not avai l abl e use dr y chemi cal , CO
2
or r egul ar
f oam.
Lar ge Fi r es
SPI LL OR LEAK
Keep subst ance wet usi ng wat er spray.
Smal l Spi l l s
Lar ge Spi l l s
SPECI ALI ST.
FI RST AI D
ORGANIC PEROXIDES (HEAT, CONTAMINATION AND
FRICTION SENSITIVE)
146
Page 242
147
Page Intentionally Left Blank
Page 243
147
Page Intentionally Left Blank
Page 244
POTENTIAL HAZARDS
FIRE OR EXPLOSION
May expl ode f rom heat , cont ami nat i on or l oss of t emperat ure cont rol .
These mat er i al s ar e par t i cul ar l y sensi t i ve t o t emper at ur e r i ses. Above a gi ven Cont r ol
Temperature they decompose vi ol entl y and catch fi re.
May i gni t e spont aneousl y i f exposed t o ai r.
May be i gni t ed by heat , sparks or f l ames.
May burn rapi dl y wi th fl are-burni ng effect.
Runof f may creat e f i re or expl osi on hazard.
HEALTH
I ngest i on or cont act (ski n, eyes) wi t h subst ance may cause severe i nj ury or burns.
PUBLI C SAFETY
St ay upwi nd.
DO NOT al l ow t he subst ance t o war m up. Obt ai n l i qui d ni t r ogen, dr y i ce or i ce f or
cool i ng. I f none can be obtai ned, evacuate the area i mmedi atel y.
EVACUATION
Lar ge Spi l l
Fi r e
ORGANIC PEROXIDES (HEAT AND CONTAMINATION
SENSITIVE/TEMPERATURE CONTROLLED)
148
Page 245
EMERGENCY RESPONSE
FIRE
The t emper at ur e of t he subst ance must be mai nt ai ned at or bel ow t he Cont r ol
Temperature at al l ti mes.
Smal l Fi res
Wat er spray or f og i s pref erred; i f wat er not avai l abl e use dry chemi cal , CO
2
or regul ar f oam.
Large Fi res
Fl ood f i re area wi t h wat er f rom a di st ance.
Do not move cargo or vehi cl e i f cargo has been exposed t o heat .
BEWARE OF POSSI BLE CONTAI NER EXPLOSI ON.
SPI LL OR LEAK
Smal l Spi l l s
Lar ge Spi l l s
SPECI ALI ST.
FI RST AI D
ORGANIC PEROXIDES (HEAT AND CONTAMINATION
SENSITIVE/TEMPERATURE CONTROLLED)
148
Page 246
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Sel f - decomposi t i on or sel f - i gni t i on may be t r i gger ed by heat , chemi cal r eact i on,
fri cti on or i mpact.
Some may decompose expl osi vel y when heat ed or i nvol ved i n a f i re.
May burn vi ol ent l y. Decomposi t i on may be sel f -accel erat i ng and produce
l arge amounts of gases.
Vapors or dust may f orm expl osi ve mi xt ures wi t h ai r.
HEALTH
May pr oduce i r r i t at i ng, t oxi c and/ or cor r osi ve gases.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
SUBSTANCES (SELF-REACTIVE)
149
Page 247
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
SPILL OR LEAK
Smal l Spi l l s
FIRST AID
SUBSTANCES (SELF-REACTIVE)
149
Page 248
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Sel f - decomposi t i on or sel f - i gni t i on may be t r i gger ed by heat , chemi cal r eact i on,
fri cti on or i mpact.
Sel f -accel erat i ng decomposi t i on may occur i f t he speci f i c cont rol t emperat ure i s not
mai ntai ned.
These mat eri al s are part i cul arl y sensi t i ve t o t emperat ure ri ses. Above a gi ven Cont rol
Temperature they decompose vi ol entl y and catch fi re.
Some may decompose expl osi vel y when heat ed or i nvol ved i n a f i re.
May burn vi ol ent l y. Decomposi t i on may be sel f -accel erat i ng and produce
l arge amounts of gases.
Vapors or dust may f orm expl osi ve mi xt ures wi t h ai r.
HEALTH
severe i nj ury or death.
May produce i rri tati ng, toxi c and/or corrosi ve gases.
PUBLI C SAFETY
St ay upwi nd.
DO NOT al l ow t he subst ance t o war m up. Obt ai n l i qui d ni t r ogen, dr y i ce or i ce f or
cool i ng. I f none can be obtai ned, evacuate the area i mmedi atel y.
EVACUATION
Lar ge Spi l l
Fi r e
SUBSTANCES (SELF-REACTIVE/
TEMPERATURE CONTROLLED)
150
Page 249
EMERGENCY RESPONSE
FI RE
The t emper at ur e of t he subst ance must be mai nt ai ned at or bel ow t he Cont r ol
Temperature at al l ti mes.
Smal l Fi res
Dry chemi cal , CO
2
Large Fi res
Fl ood f i re area wi t h wat er f rom a di st ance.
SPI LL OR LEAK
Smal l Spi l l s
SPECI ALI ST.
FI RST AI D
SUBSTANCES (SELF-REACTIVE/
TEMPERATURE CONTROLLED)
150
Page 250
POTENTIAL HAZARDS
HEALTH
Hi ghl y t oxi c, may be f at al i f i nhal ed, swal l owed or absor bed t hr ough ski n.
Avoi d any ski n cont act .
pol l uti on.
FIRE OR EXPLOSION
Non-combust i bl e, subst ance i t sel f does not burn but may decompose upon heat i ng t o
produce corrosi ve and/or toxi c fumes.
Runoff may pol l ute waterways.
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
SUBSTANCES - TOXIC (NON-COMBUSTIBLE)
151
Page 251
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
or wat er spr ay.
Lar ge Fi r es
SPI LL OR LEAK
Cover wi t h pl ast i c sheet t o prevent spreadi ng.
DO NOT GET WATER I NSI DE CONTAI NERS.
FI RST AI D
SUBSTANCES - TOXIC (NON-COMBUSTIBLE)
151
Page 252
POTENTIAL HAZARDS
HEALTH
Hi ghl y t oxi c, may be f at al i f i nhal ed, swal l owed or absor bed t hr ough ski n.
pol l uti on.
FIRE OR EXPLOSION
Combust i bl e mat er i al : may bur n but does not i gni t e r eadi l y.
Runof f may pol l ut e wat er ways.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
SUBSTANCES - TOXIC (COMBUSTIBLE)
152
Page 253
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
or wat er spr ay.
Lar ge Fi r es
SPI LL OR LEAK
Cover wi t h pl ast i c sheet t o pr event spr eadi ng.
FI RST AI D
SUBSTANCES - TOXIC (COMBUSTIBLE)
152
Page 254
POTENTIAL HAZARDS
HEALTH
deat h.
pol l uti on.
FIRE OR EXPLOSION
Cont act wi t h met al s may evol ve f l ammabl e hydrogen gas.
Subst ance may be t ransport ed i n a mol t en f orm.
PUBLI C SAFETY
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
SUBSTANCES - TOXIC AND/OR CORROSIVE
(COMBUSTIBLE)
153
Page 255
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
or wat er spr ay.
Lar ge Fi r es
Dr y chemi cal , CO
2
, al cohol - r esi st ant f oam or wat er spr ay.
SPILL OR LEAK
FI RST AI D
(COMBUSTIBLE)
153
Page 256
POTENTIAL HAZARDS
HEALTH
deat h.
pol l uti on.
FIRE OR EXPLOSION
Some are oxi di zers and may i gni t e combust i bl es (wood, paper, oi l , cl ot hi ng, et c. ).
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
(NON-COMBUSTIBLE)
154
Page 257
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
or wat er spr ay.
Lar ge Fi r es
Dr y chemi cal , CO
2
SPILL OR LEAK
FI RST AI D
(NON-COMBUSTIBLE)
154
Page 258
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Vapors f orm expl osi ve mi xt ures wi t h ai r: i ndoors, out doors and sewers expl osi on hazards.
Those subst ances desi gnat ed wi t h a " P" may pol ymer i ze expl osi vel y when heat ed or
Subst ance wi l l r eact wi t h wat er ( some vi ol ent l y) r el easi ng f l ammabl e, t oxi c or cor r osi ve
gases and r unof f .
HEALTH
Br omoacet at es and chl or oacet at es ar e ext r emel y i r r i t at i ng/ l achr ymat or s.
React i on wi t h wat er or moi st ai r wi l l r el ease t oxi c, cor r osi ve or f l ammabl e gases.
Runoff from fi re control or di l uti on water may be corrosi ve and/or toxi c and cause pol l uti on.
PUBLIC SAFETY
l east 50 met er s ( 150 f eet ) f or l i qui ds and at l east 25 met er s ( 75 f eet ) f or sol i ds.
St ay upwi nd. Keep out of l ow ar eas. Vent i l at e encl osed ar eas.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
(FLAMMABLE/WATER-SENSITIVE)
155
Page 259
EMERGENCY RESPONSE
FIRE
Not e: Most f oams wi l l r eact wi t h t he mat er i al and r el ease cor r osi ve/ t oxi c gases.
CAUTI ON: For Acet yl chl or i de ( UN1717) , use CO
2
or dr y chemi cal onl y.
Smal l Fi r es CO
2
, dr y chemi cal , dr y sand, al cohol - r esi st ant f oam.
Lar ge Fi r es
Wat er spr ay, f og or al cohol - r esi st ant f oam.
expansi on f oam.
Do not get wat er i nsi de cont ai ner s.
Cool cont ai ner s wi t h f l oodi ng quant i t i es of wat er unt i l wel l af t er f i r e i s out .
di scol or at i on of t ank.
SPILL OR LEAK
Al l equi pment used when handl i ng t he pr oduct must be gr ounded.
Do not t ouch damaged cont ai ner s or spi l l ed mat er i al unl ess wear i ng
FOR CHLOROSI LANES, use AFFF al cohol - r esi st ant medi um expansi on f oam t o
r educe vapor s.
DO NOT GET WATER on spi l l ed subst ance or i nsi de cont ai ner s.
Use wat er spr ay t o r educe vapor s or di ver t vapor cl oud dr i f t . Avoi d al l owi ng wat er runof f
t o cont act spi l l ed mat er i al .
Smal l Spi l l s Cover wi t h DRY ear t h, DRY sand or ot her non- combust i bl e mat er i al
cont ai ner s f or l at er di sposal .
FIRST AID
Gi ve ar t i f i ci al r espi r at i on i f vi ct i m i s not br eat hi ng.
Admi ni st er oxygen i f br eat hi ng i s di f f i cul t .
pr ecaut i ons t o pr ot ect t hemsel ves.
(FLAMMABLE/WATER-SENSITIVE)
155
Page 260
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Subst ance wi l l r eact wi t h wat er ( some vi ol ent l y) r el easi ng f l ammabl e, t oxi c or cor r osi ve
gases and runoff.
Vapors may t ravel t o source of i gni t i on and f l ash back.
Cont ai ners may expl ode when heat ed or i f cont ami nat ed wi t h wat er.
HEALTH
f umes i n t he ai r.
Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
PUBLI C SAFETY
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
(COMBUSTIBLE/WATER-SENSITIVE)
156
Page 261
EMERGENCY RESPONSE
FIRE
Smal l Fi res CO
2
, dr y chemi cal , dr y sand, al cohol - r esi st ant f oam.
Lar ge Fi r es
expansi on foam.
SPI LL OR LEAK
FOR CHLOROSI LANES, use AFFF al cohol -resi st ant medi um expansi on f oam t o
reduce vapors.
DO NOT GET WATER on spi l l ed substance or i nsi de contai ners.
FI RST AI D
(COMBUSTIBLE/WATER-SENSITIVE)
156
Page 262
POTENTIAL HAZARDS
HEALTH
React i on wi t h wat er may gener at e much heat t hat wi l l i ncr ease t he concent r at i on of
Runoff from fi re control or di l uti on water may be corrosi ve and/or toxi c and cause pol l uti on.
FIRE OR EXPLOSION
Vapors may accumul at e i n conf i ned areas (basement , t anks, hopper/ t ank cars et c. ).
Subst ance wi l l r eact wi t h wat er ( some vi ol ent l y) , r el easi ng cor r osi ve and/ or t oxi c
gases.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
(NON-COMBUSTIBLE/WATER-SENSITIVE)
157
Page 263
EMERGENCY RESPONSE
FIRE
Smal l Fi res CO
2
( except f or Cyani des) , dr y chemi cal , dr y sand, al cohol - r esi st ant f oam.
Lar ge Fi r es
SPILL OR LEAK
FI RST AI D
(NON-COMBUSTIBLE/WATER-SENSITIVE)
157
Page 264
POTENTIAL HAZARDS
HEALTH
I nhal at i on or cont act wi t h subst ance may cause i nf ect i on, di sease or deat h.
Not e: Damaged packages cont ai ni ng sol i d CO
2
as a r ef r i ger ant may pr oduce
wat er or f r ost f r om condensat i on of ai r . Do not t ouch t hi s l i qui d as i t coul d be
cont ami nat ed by t he cont ent s of t he parcel .
FIRE OR EXPLOSION
Some of t hese mat er i al s may bur n, but none i gni t e r eadi l y.
Some may be t r anspor t ed i n f l ammabl e l i qui ds.
PUBLIC SAFETY
St ay upwi nd.
Obt ai n i dent i t y of subst ance i nvol ved.
PROTECTIVE CLOTHING
INFECTIOUS SUBSTANCES
158
Page 265
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Lar ge Fi r es
Do not scat t er spi l l ed mat eri al wi t h hi gh pressure wat er st reams.
SPILL OR LEAK
Absorb wi t h eart h, sand or ot her non-combust i bl e mat eri al .
Cover damaged package or spi l l ed mat er i al wi t h damp t owel or r ag and keep
wet wi t h l i qui d bl each or ot her di si nf ect ant .
SPECI ALI ST.
FI RST AI D
Move vi ct i m t o a saf e i sol at ed area.
CAUTI ON: Vi cti m may be a source of contami nati on.
Cal l 911 or emergency medi cal servi ce.
I n case of cont act wi t h subst ance, i mmedi at el y f l ush ski n or eyes wi t h runni ng wat er f or at
l east 20 mi nut es.
Ef f ect s of exposure (i nhal at i on, i ngest i on or ski n cont act ) t o subst ance may be del ayed.
For further assi stance, contact your l ocal Poi son Control Center.
INFECTIOUS SUBSTANCES
158
Page 266
POTENTIAL HAZARDS
HEALTH
I nhal at i on of vapor s or dust i s ext r emel y i r r i t at i ng.
May cause bur ni ng of eyes and f l ow of t ear s.
May cause coughi ng, di f f i cul t breat hi ng and nausea.
Br i ef exposur e ef f ect s l ast onl y a f ew mi nut es.
Exposur e i n an encl osed ar ea may be ver y har mf ul .
FIRE OR EXPLOSION
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
SUBSTANCES (IRRITATING)
159
Page 267
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
SPI LL OR LEAK
Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.
Smal l Spi l l s
Take up wi t h sand or ot her non-combust i bl e absorbent mat eri al and pl ace i nt o
cont ai ners f or l at er di sposal .
Lar ge Spi l l s
FIRST AID
Ef f ect s shoul d di sappear af t er i ndi vi dual has been exposed t o f resh ai r f or
approxi matel y 10 mi nutes.
SUBSTANCES (IRRITATING)
159
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POTENTIAL HAZARDS
HEALTH
Toxi c by i ngest i on.
Exposur e i n an encl osed ar ea may be ver y har mf ul .
Cont act may i r r i t at e or bur n ski n and eyes.
FIRE OR EXPLOSION
Most vapor s ar e heavi er t han ai r .
Ai r / vapor mi xt ur es may expl ode when i gni t ed.
Cont ai ner may expl ode i n heat of f i r e.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
HALOGENATED SOLVENTS
160
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EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
or wat er spr ay.
Lar ge Fi r es
Dr y chemi cal , CO
2
SPILL OR LEAK
Take up wi t h sand, eart h or ot her non-combust i bl e absorbent mat eri al .
Lar ge Spi l l s
FIRST AID
Wash ski n wi t h soap and wat er .
HALOGENATED SOLVENTS
160
Page 270
POTENTIAL HAZARDS
HEALTH
Radi at i on pr esent s mi ni mal r i sk t o t r anspor t wor ker s, emer gency r esponse per sonnel
and t he publ i c duri ng t ransport at i on acci dent s. Packagi ng durabi l i t y i ncreases as
pot ent i al hazard of radi oact i ve cont ent i ncreases.
Ver y l ow l evel s of cont ai ned r adi oact i ve mat er i al s and l ow r adi at i on l evel s out si de
packages r esul t i n l ow r i sks t o peopl e. Damaged packages may r el ease measur abl e
amount s of r adi oact i ve mat er i al , but t he r esul t i ng r i sks ar e expect ed t o be l ow.
Some r adi oact i ve mat er i al s cannot be det ect ed by commonl y avai l abl e i nst r ument s.
Packages do not have RADI OACTI VE I , I I , or I I I l abel s. Some may have EMPTY l abel s or
may have t he word Radi oact i ve i n t he package marki ng.
FI RE OR EXPLOSI ON
Some of t hese mat eri al s may burn, but most do not i gni t e readi l y.
Many have cardboard out er packagi ng; cont ent (physi cal l y l arge or smal l ) can be of many
di fferent physi cal forms.
Radi oact i vi t y does not change f l ammabi l i t y or ot her propert i es of mat eri al s.
PUBLI C SAFETY
Pr i or i t i es f or r escue, l i f e- savi ng, f i r st ai d, f i r e cont r ol and ot her hazar ds ar e
hi gher t han t he pr i or i t y f or measur i ng r adi at i on l evel s.
Radi at i on Aut hori t y must be not i f i ed of acci dent condi t i ons. Radi at i on Aut hori t y i s usual l y
responsi bl e f or deci si ons about radi ol ogi cal consequences and cl osure of emergenci es.
St ay upwi nd.
Det ai n or i sol at e uni nj ured persons or equi pment suspect ed t o be cont ami nat ed; del ay
decontami nati on and cl eanup unti l i nstructi ons are recei ved from Radi ati on Authori ty.
Posi ti ve pressure sel f-contai ned breathi ng apparatus (SCBA) and structural fi refi ghters
protecti ve cl othi ng wi l l provi de adequate protecti on.
EVACUATION
Large Spi l l
Fire
When a l arge quant i t y of t hi s mat eri al i s i nvol ved i n a maj or f i re, consi der an i ni t i al
evacuat i on di st ance of 300 met ers (1000 f eet ) i n al l di rect i ons.
RADIOACTIVE MATERIALS
(LOW LEVEL RADIATION)
161
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EMERGENCY RESPONSE
FIRE
Presence of radi oact i ve mat eri al wi l l not i nf l uence t he f i re cont rol processes and shoul d
not i nf l uence sel ect i on of t echni ques.
Do not move damaged packages; move undamaged packages out of f i r e zone.
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
Wat er spray, f og (f l oodi ng amount s).
SPILL OR LEAK
Do not t ouch damaged packages or spi l l ed mat eri al .
Cover l i qui d spi l l wi t h sand, eart h or ot her non-combust i bl e absorbent mat eri al .
Cover powder spi l l wi t h pl ast i c sheet or t ar p t o mi ni mi ze spr eadi ng.
FIRST AID
Medi cal pr obl ems t ake pr i or i t y over r adi ol ogi cal concer ns.
Use f i rst ai d t reat ment accordi ng t o t he nat ure of t he i nj ury.
Do not del ay car e and t r anspor t of a ser i ousl y i nj ur ed per son.
I nj ured persons cont ami nat ed by cont act wi t h rel eased mat eri al are not a seri ous hazard
t o heal t h care personnel , equi pment or f aci l i t i es.
Ensur e t hat medi cal per sonnel ar e awar e of t he mat er i al ( s) i nvol ved, t ake pr ecaut i ons t o
protect themsel ves and prevent spread of contami nati on.
(LOW LEVEL RADIATION)
161
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POTENTIAL HAZARDS
HEALTH
Radi at i on pr esent s mi ni mal r i sk t o t r anspor t wor ker s, emer gency r esponse per sonnel
and t he publ i c duri ng t ransport at i on acci dent s. Packagi ng durabi l i t y i ncreases as
pot ent i al hazard of radi oact i ve cont ent i ncreases.
Undamaged packages are safe. Contents of damaged packages may cause hi gher external
radiation exposure, or both external and internal radiation exposure if contents are released.
Low radi ati on hazard when materi al i s i nsi de contai ner. If materi al i s rel eased from package or
bul k contai ner, hazard wi l l vary from l ow to moderate. Level of hazard wi l l depend on the
type and amount of radi oacti vi ty, the ki nd of materi al i t i s i n, and/or the surfaces i t i s on.
Some mat er i al may be r el eased f r om packages dur i ng acci dent s of moder at e sever i t y but
ri sks t o peopl e are not great .
Rel eased radi oact i ve mat eri al s or cont ami nat ed obj ect s usual l y wi l l be vi si bl e i f packagi ng f ai l s.
Some exclusive use shipments of bulk and packaged materials will not have RADIOACTIVE
l abel s. Pl acards, marki ngs and shi ppi ng papers provi de i denti fi cati on.
Some packages may have a RADI OACTI VE l abel and a second hazar d l abel . The
second hazar d i s usual l y gr eat er t han t he r adi at i on hazar d; so f ol l ow t hi s GUI DE as wel l
as t he r esponse GUI DE f or t he second hazar d cl ass l abel .
Some r adi oact i ve mat er i al s cannot be det ect ed by commonl y avai l abl e i nst r ument s.
Runof f f r om cont r ol of car go f i r e may cause l ow- l evel pol l ut i on.
FIRE OR EXPLOSION
Some of t hese mat er i al s may bur n, but most do not i gni t e r eadi l y.
Ur ani um and Thor i um met al cut t i ngs may i gni t e spont aneousl y i f exposed t o ai r ( see
GUI DE 136).
Ni t r at es ar e oxi di zer s and may i gni t e ot her combust i bl es ( see GUI DE 141) .
PUBLIC SAFETY
( 75 f eet ) i n al l di r ect i ons. St ay upwi nd. Keep unaut hor i zed per sonnel away.
decontami nati on and cl eanup unti l i nstructi ons are recei ved from Radi ati on Authori ty.
Posi ti ve pressure sel f-contai ned breathi ng apparatus (SCBA) and structural fi refi ghters
protecti ve cl othi ng wi l l provi de adequate protecti on.
EVACUATION
Large Spi l l
Fire
When a l arge quant i t y of t hi s mat eri al i s i nvol ved i n a maj or f i re, consi der an i ni t i al
evacuat i on di st ance of 300 met ers (1000 f eet ) i n al l di rect i ons.
(LOW TO MODERATE LEVEL RADIATION)
162
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EMERGENCY RESPONSE
FIRE
Presence of radi oact i ve mat eri al wi l l not i nf l uence t he f i re cont rol processes and shoul d
Do not move damaged packages; move undamaged packages out of f i r e zone.
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
SPILL OR LEAK
Cover l i qui d spi l l wi t h sand, eart h or ot her non-combust i bl e absorbent mat eri al .
Di ke t o col l ect l ar ge l i qui d spi l l s.
Cover powder spi l l wi t h pl ast i c sheet or t ar p t o mi ni mi ze spr eadi ng.
FIRST AID
Medi cal pr obl ems t ake pr i or i t y over r adi ol ogi cal concer ns.
Do not del ay car e and t r anspor t of a ser i ousl y i nj ur ed per son.
I nj ured persons cont ami nat ed by cont act wi t h rel eased mat eri al are not a seri ous hazard t o
heal th care personnel , equi pment or faci l i ti es.
Ensure t hat medi cal personnel are aware of t he mat eri al (s) i nvol ved, t ake precaut i ons t o
(LOW TO MODERATE LEVEL RADIATION)
162
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POTENTIAL HAZARDS
HEALTH
Radi ati on presents mi ni mal ri sk to transport workers, emergency response personnel and the publ i c
duri ng t ransport at i on acci dent s. Packagi ng durabi l i t y i ncreases as pot ent i al hazard of radi oact i ve
cont ent i ncreases.
Undamaged packages are safe. Contents of damaged packages may cause higher external radiation exposure,
or both external and internal radiation exposure if contents are released.
Type A packages (cartons, boxes, drums, articles, etc.) identified as Type A by marking on packages or
by shipping papers contain non-life endangering amounts. Partial releases might be expected if Type A
packages are damaged in moderately severe accidents.
Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain the
most hazardous amounts. They can be identified by package markings or by shipping papers. Life threatening
condi t i ons may exi st onl y i f cont ent s are rel eased or package shi el di ng f ai l s. Because of desi gn,
eval uati on and testi ng of packages, these condi ti ons woul d be expected onl y for acci dents of utmost
sever i t y.
The rarely occurring "Special Arrangement" shipments may be of Type A, Type B or Type C packages. Package
type will be marked on packages, and shipment details will be on shipping papers.
Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are very
low (less than 0.005 mSv/h (0.5 mrem/h)).
Radioactive Yellow-II and Yellow-III labeled packages have higher radiation levels. The transport index
(TI) on the label identifies the maximum radiation level in mrem/h one meter from a single, isolated, undamaged
package.
Some radioactive materials cannot be detected by commonly available instruments.
Water from cargo fire control may cause pollution.
FI RE OR EXPLOSI ON
Some of t hese mat eri al s may burn, but most do not i gni t e readi l y.
Type B packages are desi gned and eval uat ed t o wi t hst and t ot al engul f ment i n f l ames at
t emperat ures of 800C (1475F) f or a peri od of 30 mi nut es.
PUBLI C SAFETY
CALL Emergency Response Tel ephone Number on Shi ppi ng Paper fi rst. I f Shi ppi ng Paper
not avai l abl e or no answer, refer to appropri ate tel ephone number l i sted on the i nsi de back
cover.
decont ami nat i on and cl eanup unt i l i nst ruct i ons are recei ved f rom Radi at i on Aut hori t y.
Posi t i ve pressure sel f -cont ai ned breat hi ng apparat us (SCBA) and st ruct ural f i ref i ght ers
prot ect i ve cl ot hi ng wi l l provi de adequat e prot ect i on agai nst i nt ernal radi at i on exposure, but not
ext ernal radi at i on exposure.
EVACUATION
Large Spi l l
Fi re
When a l arge quant i t y of t hi s mat eri al i s i nvol ved i n a maj or f i re, consi der an i ni t i al evacuat i on
di st ance of 300 met er s ( 1000 f eet ) i n al l di r ect i ons.
(LOW TO HIGH LEVEL RADIATION)
163
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EMERGENCY RESPONSE
FIRE
Pr esence of r adi oact i ve mat er i al wi l l not i nf l uence t he f i r e cont r ol pr ocesses and shoul d
Do not move damaged packages; move undamaged packages out of f i re zone.
Smal l Fi res
Dry chemi cal , CO
2
Large Fi res
SPI LL OR LEAK
Damp surf aces on undamaged or sl i ght l y damaged packages are sel dom an i ndi cat i on of
packagi ng f ai l ure. Most packagi ng f or l i qui d cont ent have i nner cont ai ners and/ or i nner
absorbent mat eri al s.
Cover l i qui d spi l l wi t h sand, ear t h or ot her non- combust i bl e absor bent mat er i al .
FI RST AI D
Medi cal probl ems t ake pri ori t y over radi ol ogi cal concerns.
Do not del ay care and t ransport of a seri ousl y i nj ured person.
I n case of cont act wi t h subst ance, i mmedi at el y f l ush ski n or eyes wi t h runni ng water for at l east 20
mi nut es.
I nj ured persons cont ami nat ed by cont act wi t h rel eased mat eri al are not a serious hazard t o heal t h
care personnel , equi pment or f aci l i t i es.
Ensure t hat medi cal personnel are aware of t he mat eri al (s) i nvol ved, take precautions to prot ect
t hemsel ves and prevent spread of cont ami nat i on.
(LOW TO HIGH LEVEL RADIATION)
163
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POTENTIAL HAZARDS
HEALTH
Radi at i on present s mi ni mal ri sk t o t ransport workers, emergency response personnel and t he
publ i c duri ng t ransport at i on acci dent s. Packagi ng durabi l i t y i ncreases as pot ent i al hazard of
radi oact i ve cont ent i ncreases.
Undamaged packages are safe; contents of damaged packages may cause external radiation
exposure, and much higher external exposure if contents (source capsules) are released.
Contamination and internal radiation hazards are not expected, but not impossible.
Type A packages (cartons, boxes, drums, articles, etc.) identified as Type A by marking on packages
or by shipping papers contain non-life endangering amounts. Radioactive sources may be released if
Type A packages are damaged in moderately severe accidents.
Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain
the most hazardous amounts. They can be identified by package markings or by shipping papers. Life
threatening conditions may exist only if contents are released or package shielding fails. Because of
desi gn, eval uat i on and t est i ng of packages, t hese condi t i ons woul d be expect ed onl y f or
acci dent s of ut most severi t y.
Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are
very low (less than 0.005 mSv/h (0.5 mrem/h)).
Radioactive Yellow-II and Yellow-III labeled packages have higher radiation levels. The transport
index (TI) on the label identifies the maximum radiation level in mrem/h one meter from a single,
isolated, undamaged package.
Radiation from the package contents, usually in durable metal capsules, can be detected by most
radiation instruments.
Water from cargo fire control is not expected to cause pollution.
FI RE OR EXPLOSI ON
Packagings can burn completely without risk of content loss from sealed source capsule.
Radioactivity does not change flammability or other properties of materials.
Radioactive source capsules and Type B packages are designed and evaluated to withstand total
engulfment in flames at temperatures of 800C (1475F).
PUBLI C SAFETY
CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not
available or no answer, refer to appropriate telephone number listed on the inside back cover.
Pri ori ti es for rescue, l i fe-savi ng, fi rst ai d, fi re control and other hazards are hi gher
than the pri ori ty for measuri ng radi ati on l evel s.
Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible
for decisions about radiological consequences and closure of emergencies.
As an i mmedi at e precaut i onary measure, i sol at e spi l l or l eak area f or at l east 25 met ers (75
f eet ) i n al l di rect i ons.
Stay upwind. Keep unauthorized personnel away.
Delay final cleanup until instructions or advice is received from Radiation Authority.
Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters protective
clothing will provide adequate protection against internal radiation exposure, but not external radiation
exposure.
EVACUATION
Large Spill
Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire
When a large quantity of this material is involved in a major fire, consider an initial evacuation distance
of 300 met ers (1000 f eet ) i n al l di rect i ons.
RADIOACTIVE MATERIALS (SPECIAL FORM / LOW TO
HIGH LEVEL EXTERNAL RADIATION)
164
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EMERGENCY RESPONSE
FIRE
Smal l Fi res
Dry chemi cal , CO
2
Large Fi res
SPI LL OR LEAK
packagi ng f ai l ure. Cont ent s are sel dom l i qui d. Cont ent i s usual l y a met al capsul e, easi l y seen i f
rel eased f rom package.
I f source capsul e i s i dent i f i ed as bei ng out of package, DO NOT TOUCH. St ay away and awai t
advi ce f rom Radi at i on Aut hori t y.
FI RST AI D
Persons exposed t o speci al f orm sources are not l i kel y t o be cont ami nat ed wi t h radi oact i ve
mat eri al .
heal t h care personnel , equi pment or f aci l i t i es.
Ensure t hat medi cal personnel are aware of t he mat eri al (s) i nvol ved, t ake precaut i ons t o prot ect
t hemsel ves and prevent spread of cont ami nat i on.
RADIOACTIVE MATERIALS (SPECIAL FORM/LOW TO
HIGH LEVEL EXTERNAL RADIATION)
164
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POTENTIAL HAZARDS
HEALTH
Radi at i on present s mi ni mal ri sk t o t ransport workers, emergency response personnel and t he
publ i c duri ng t ransport at i on acci dent s. Packagi ng durabi l i t y i ncreases as pot ent i al radi at i on
and cri t i cal i t y hazards of t he cont ent i ncrease.
Undamaged packages are safe. Contents of damaged packages may cause higher external radiation
exposure, or both external and internal radiation exposure if contents are released.
Type AF or IF packages, identified by package markings, do not contain life-threatening amounts of
mat eri al . Ext ernal radi at i on l evel s are l ow and packages are desi gned, eval uat ed and t est ed
t o cont rol rel eases and t o prevent a f i ssi on chai n react i on under severe t ransport condi t i ons.
Type B(U)F, B(M)F and CF packages (identified by markings on packages or shipping papers) contain
pot ent i al l y l i f e endangeri ng amount s. Because of desi gn, eval uat i on and t est i ng of packages,
f i ssi on chai n react i ons are prevent ed and rel eases are not expect ed t o be l i f e endangeri ng f or
al l acci dent s except t hose of ut most severi t y.
The rarely occurring "Special Arrangement" shipments may be of Type AF, BF or CF packages.
Package type will be marked on packages, and shipment details will be on shipping papers.
The t ransport i ndex (TI ) shown on l abel s or a shi ppi ng paper mi ght not i ndi cat e t he radi at i on
l evel at one met er f rom a si ngl e, i sol at ed, undamaged package; i nst ead, i t mi ght rel at e t o
cont rol s needed duri ng t ransport because of t he f i ssi l e propert i es of t he mat eri al s.
Al t ernat i vel y, t he f i ssi l e nat ure of t he cont ent s may be i ndi cat ed by a cri t i cal i t y saf et y i ndex
(CSI ) on a speci al FI SSI LE l abel or on t he shi ppi ng paper.
Some radi oact i ve mat eri al s cannot be det ect ed by commonl y avai l abl e i nst rument s.
Water from cargo fire control is not expected to cause pollution.
FI RE OR EXPLOSI ON
These mat eri al s are sel dom f l ammabl e. Packages are desi gned t o wi t hst and f i res wi t hout
damage t o cont ent s.
Type AF, I F, B(U)F, B(M)F and CF packages are desi gned and eval uat ed t o wi t hst and t ot al
engul f ment i n f l ames at t emperat ures of 800C (1475F) f or a peri od of 30 mi nut es.
PUBLI C SAFETY
CALL Emergency Response Tel ephone Number on Shi ppi ng Paper fi rst. I f Shi ppi ng Paper
not avai l abl e or no answer, refer to appropri ate tel ephone number l i sted on the i nsi de back
cover.
decont ami nat i on and cl eanup unt i l i nst ruct i ons are recei ved f rom Radi at i on Aut hori t y.
Posi t i ve pr essur e sel f - cont ai ned br eat hi ng appar at us ( SCBA) and st r uct ur al f i r ef i ght er s
prot ect i ve cl ot hi ng wi l l provi de adequat e prot ect i on agai nst i nt ernal radi at i on exposure, but not
ext ernal radi at i on exposure.
EVACUATION
Large Spi l l
F i r e
When a l ar ge quant i t y of t hi s mat er i al i s i nvol ved i n a maj or f i r e, consi der an i ni t i al
evacuat i on di st ance of 300 met er s ( 1000 f eet ) i n al l di r ect i ons.
(FISSILE/LOW TO HIGH LEVEL RADIATION)
165
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EMERGENCY RESPONSE
FIRE
Smal l Fi res
Dry chemi cal , CO
2
Large Fi res
SPI LL OR LEAK
packagi ng f ai l ure. Most packagi ng f or l i qui d cont ent have i nner cont ai ners and/ or i nner
absorbent mat eri al s.
Li qui d Spi l l s
Package cont ent s are sel dom l i qui d. I f any radi oact i ve cont ami nat i on resul t i ng f rom a l i qui d
rel ease i s present , i t probabl y wi l l be l ow-l evel .
FI RST AI D
I n case of cont act wi t h subst ance, i mmedi at el y f l ush ski n or eyes wi t h runni ng wat er f or at l east
20 mi nut es.
heal t h care personnel , equi pment or f aci l i t i es.
Ensure t hat medi cal personnel are aware of t he mat eri al (s) i nvol ved, t ake precaut i ons t o prot ect
t hemsel ves and pr event spr ead of cont ami nat i on.
(FISSILE/LOW TO HIGH LEVEL RADIATION)
165
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POTENTIAL HAZARDS
HEALTH
Radi ati on presents mi ni mal ri sk to transport workers, emergency response personnel and the
publ i c duri ng transportati on acci dents. Packagi ng durabi l i ty i ncreases as potenti al radi ati on
and cri ti cal i ty hazards of the content i ncrease.
Chemi cal hazard greatl y exceeds radi ati on hazard.
Subst ance react s wi t h wat er and wat er vapor i n ai r t o f orm t oxi c and corrosi ve hydrogen
fl uori de gas and an extremel y i rri tati ng and corrosi ve, whi te-col ored, water-sol ubl e resi due.
If i nhal ed, may be fatal .
Di rect contact causes burns to ski n, eyes, and respi ratory tract.
Low-l evel radi oact i ve mat eri al ; very l ow radi at i on hazard t o peopl e.
Runoff from control of cargo fi re may cause l ow-l evel pol l uti on.
FIRE OR EXPLOSION
Subst ance does not bur n. The mat er i al may r eact vi ol ent l y wi t h f uel s.
Cont ai ner s i n pr ot ect i ve over packs ( hor i zont al cyl i ndr i cal shape wi t h shor t l egs f or t i e-
downs) , ar e i dent i f i ed wi t h " AF" , " B( U) F" or " H( U) " on shi ppi ng paper s or by mar ki ngs on
t he over packs. They ar e desi gned and eval uat ed t o wi t hst and sever e condi t i ons
i ncl udi ng t ot al engul f ment i n f l ames at t emper at ur es of 800C ( 1475F) .
Bar e f i l l ed cyl i nder s, i dent i f i ed wi t h UN2978 as par t of t he mar ki ng ( may al so be mar ked
H( U) or H( M) ) , may r upt ur e i n heat of engul f i ng f i r e; bar e empt y ( except f or r esi due)
cyl i nder s wi l l not r upt ur e i n f i r es.
Radi oact i vi t y does not change f l ammabi l i t y or ot her pr oper t i es of mat er i al s.
PUBLIC SAFETY
Radi at i on Aut hor i t y must be not i f i ed of acci dent condi t i ons. Radi at i on Aut hor i t y i s usual l y
r esponsi bl e f or deci si ons about r adi ol ogi cal consequences and cl osur e of emer genci es.
Det ai n or i sol at e uni nj ur ed per sons or equi pment suspect ed t o be cont ami nat ed; del ay
decont ami nat i on and cl eanup unt i l i nst r uct i ons ar e r ecei ved f r om Radi at i on Aut hor i t y.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Lar ge Spi l l
Fi r e
When a l ar ge quant i t y of t hi s mat er i al i s i nvol ved i n a maj or f i r e, consi der an i ni t i al
evacuat i on di st ance of 300 met er s ( 1000 f eet ) i n al l di r ect i ons.
RADIOACTIVE MATERIALS - CORROSIVE
(URANIUM HEXAFLUORIDE/WATER-SENSITIVE)
166
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EMERGENCY RESPONSE
FIRE
DO NOT USE WATER OR FOAM ON MATERI AL I TSELF.
Smal l Fi r es
2
.
Lar ge Fi r es
I f t hi s i s i mpossi bl e, wi t hdr aw f r om ar ea and l et f i r e bur n.
SPILL OR LEAK
Wi t hout f i r e or smoke, l eak wi l l be evi dent by vi si bl e and i r r i t at i ng vapor s and r esi due
f ormi ng at t he poi nt of rel ease.
Use f i ne wat er spray t o reduce vapors; do not put wat er di rect l y on poi nt of mat eri al rel ease
from contai ner.
Resi due bui l dup may sel f -seal smal l l eaks.
Di ke f ar ahead of spi l l t o col l ect runof f wat er.
FI RST AI D
I nj ured persons cont ami nat ed by cont act wi t h rel eased mat eri al are not a seri ous hazard
t o heal t h care personnel , equi pment or f aci l i t i es.
Ensur e t hat medi cal per sonnel ar e awar e of t he mat er i al ( s) i nvol ved, t ake pr ecaut i ons t o
RADIOACTIVE MATERIALS - CORROSIVE
(URANIUM HEXAFLUORIDE/WATER-SENSITIVE)
166
Page 282
POTENTIAL HAZARDS
HEALTH
TOXI C; may be f at al i f i nhal ed.
Vapor s ar e ext r emel y i r r i t at i ng.
Cont act wi t h gas or l i quef i ed gas wi l l cause bur ns, sever e i nj ur y and/ or f r ost bi t e.
FIRE OR EXPLOSION
Thi s i s a st r ong oxi di zer and wi l l r eact vi gor ousl y or expl osi vel y wi t h many mat er i al s
i ncl udi ng fuel s.
Vapor expl osi on and poi son hazard i ndoors, out doors or i n sewers.
Rupt ured cyl i nders may rocket .
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
di rect i ons; al so, consi der i ni t i al evacuat i on f or 1600 met ers (1 mi l e) i n al l di rect i ons.
FLUORINE (REFRIGERATED LIQUID)
167
Page 283
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Lar ge Fi r es
SPI LL OR LEAK
I f you have not donned speci al prot ect i ve cl ot hi ng approved f or t hi s mat eri al , do not expose
yoursel f t o any ri sk of t hi s mat eri al t ouchi ng you.
Do not di rect water at spi l l or source of l eak.
A f i ne wat er spray remot el y di rect ed t o t he edge of t he spi l l pool can be used t o di rect and
mai nt ai n a hot f l are f i re whi ch wi l l burn t he spi l l ed mat eri al i n a cont rol l ed manner.
Venti l ate the area.
FI RST AI D
FLUORINE (REFRIGERATED LIQUID)
167
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POTENTIAL HAZARDS
HEALTH
TOXI C; Ext remel y Hazardous.
I nhal at i on ext r emel y danger ous; may be f at al .
Odor l ess, wi l l not be det ect ed by sense of smel l .
FIRE OR EXPLOSION
Fl ame may be i nvi si bl e.
Vapor expl osi on and poi son hazar d i ndoor s, out door s or i n sewer s.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
possi bl e.
EVACUATION
Spi l l
Fi r e
CARBON MONOXIDE (REFRIGERATED LIQUID)
168
Page 285
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
or wat er spr ay.
Lar ge Fi r es
SPILL OR LEAK
Ful l y encapsul at i ng, vapor pr ot ect i ve cl ot hi ng shoul d be wor n f or spi l l s and l eaks wi t h
no f i r e.
FIRST AID
CARBON MONOXIDE (REFRIGERATED LIQUID)
168
Page 286
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Subst ance i s t ransport ed i n mol t en f orm at a t emperat ure above 705C (1300F).
Vi ol ent r eact i on wi t h wat er ; cont act may cause an expl osi on or may pr oduce a
f l ammabl e gas.
Wi l l i gni t e combust i bl e mat er i al s ( wood, paper , oi l , debr i s, et c. ) .
Cont act wi t h ni t r at es or ot her oxi di zer s may cause an expl osi on.
Cont act wi t h cont ai ner s or ot her mat er i al s, i ncl udi ng col d, wet or di r t y t ool s, may cause
an expl osi on.
Cont act wi t h concr et e wi l l cause spal l i ng and smal l pops.
HEALTH
Cont act causes sever e bur ns t o ski n and eyes.
PUBLIC SAFETY
PROTECTIVE CLOTHING
Wear f l ame ret ardant st ruct ural f i ref i ght ers prot ect i ve cl ot hi ng, i ncl udi ng f aceshi el d,
hel met and gl oves, t hi s wi l l pr ovi de l i mi t ed t her mal pr ot ect i on.
ALUMINUM (MOLTEN)
169
Page 287
EMERGENCY RESPONSE
FIRE
Do Not Use Wat er , except i n l i f e t hr eat eni ng si t uat i ons and t hen onl y i n a f i ne
spr ay.
Do not use hal ogenat ed ext i ngui shi ng agent s or f oam.
Move combust i bl es out of pat h of advanci ng pool i f you can do so wi t hout r i sk.
Ext i ngui sh f i res st art ed by mol t en mat eri al by usi ng appropri at e met hod f or t he burni ng
mat eri al ; keep wat er, hal ogenat ed ext i ngui shi ng agent s and f oam away f rom t he mol t en
materi al .
SPI LL OR LEAK
Do not at t empt t o st op l eak, due t o danger of expl osi on.
Subst ance i s very f l ui d, spreads qui ckl y, and may spl ash. Do not t ry t o st op i t wi t h
shovel s or other obj ects.
Di ke f ar ahead of spi l l ; use dry sand t o cont ai n t he f l ow of mat eri al .
Where possi bl e al l ow mol t en mat eri al t o sol i di f y nat ural l y.
Avoi d cont act even af t er mat eri al sol i di f i es. Mol t en, heat ed and col d al umi num
l ook al i ke; do not t ouch unl ess you know i t i s col d.
Cl ean up under t he supervi si on of an expert af t er mat eri al has sol i di f i ed.
FI RST AI D
For sever e bur ns, i mmedi at e medi cal at t ent i on i s r equi r ed.
ALUMINUM (MOLTEN)
169
Page 288
POTENTIAL HAZARDS
FIRE OR EXPLOSION
May r eact vi ol ent l y or expl osi vel y on cont act wi t h wat er .
Some are t ransport ed i n f l ammabl e l i qui ds.
May be i gni t ed by f r i ct i on, heat , spar ks or f l ames.
Some of t hese mat er i al s wi l l bur n wi t h i nt ense heat .
Dust s or f umes may f or m expl osi ve mi xt ur es i n ai r .
HEALTH
Oxi des f r om met al l i c f i r es ar e a sever e heal t h hazar d.
I nhal at i on or cont act wi t h subst ance or decomposi t i on pr oduct s may cause
severe i nj ury or death.
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
METALS (POWDERS, DUSTS, SHAVINGS, BORINGS,
TURNINGS, OR CUTTINGS, ETC.)
170
Page 289
EMERGENCY RESPONSE
FIRE
DO NOT USE WATER, FOAM OR CO
2
.
Dousi ng met al l i c f i r es wi t h wat er may gener at e hydr ogen gas, an ext r emel y danger ous
expl osi on hazard, part i cul arl y i f f i re i s i n a conf i ned envi ronment (i . e. , bui l di ng, cargo hol d,
etc.).
Use DRY sand, graphi t e powder, dry sodi um chl ori de based ext i ngui shers,
G-1
or Met-L-X
powder.
Confi ni ng and smotheri ng metal fi res i s preferabl e rather than appl yi ng water.
I f i mpossi bl e t o ext i ngui sh, prot ect surroundi ngs and al l ow f i re t o burn i t sel f out .
SPI LL OR LEAK
FI RST AI D
METALS (POWDERS, DUSTS, SHAVINGS, BORINGS,
TURNINGS, OR CUTTINGS, ETC.)
170
Page 290
POTENTIAL HAZARDS
FIRE OR EXPLOSION
Some may bur n but none i gni t e r eadi l y.
Some may be t ransport ed hot .
HEALTH
I nhal at i on of mat eri al may be harmf ul .
I nhal at i on of Asbest os dust may have a damagi ng ef f ect on t he l ungs.
Some l i qui ds pr oduce vapor s t hat may cause di zzi ness or suf f ocat i on.
PUBLIC SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Spi l l
Fi r e
SUBSTANCES (LOW TO MODERATE HAZARD)
171
Page 291
EMERGENCY RESPONSE
FIRE
Smal l Fi r es
Dr y chemi cal , CO
2
Lar ge Fi r es
Do not scat t er spi l l ed mat eri al wi t h hi gh pressure wat er st reams.
SPILL OR LEAK
Pr event dust cl oud.
Avoi d i nhal at i on of asbest os dust .
Smal l Dr y Spi l l s
Wi t h cl ean shovel pl ace mat er i al i nt o cl ean, dr y cont ai ner and cover l oosel y; move
Smal l Spi l l s
Take up wi t h sand or ot her non-combust i bl e absorbent mat eri al and pl ace
i nto contai ners for l ater di sposal .
Large Spi l l s
Cover powder spi l l wi t h pl ast i c sheet or t arp t o mi ni mi ze spreadi ng.
FI RST AI D
SUBSTANCES (LOW TO MODERATE HAZARD)
171
Page 292
POTENTIAL HAZARDS
HEALTH
I nhal at i on of vapors or cont act wi t h subst ance wi l l resul t i n cont ami nat i on and pot ent i al
harmful effects.
FI RE OR EXPLOSI ON
Non-combust i bl e, subst ance i t sel f does not burn but may react upon heat i ng t o produce
corrosi ve and/ or t oxi c f umes.
PUBLI C SAFETY
St ay upwi nd.
PROTECTIVE CLOTHING
EVACUATION
Lar ge Spi l l
Fi r e
When any l ar ge cont ai ner i s i nvol ved i n a f i r e, consi der i ni t i al evacuat i on f or 500 met er s
( 1/ 3 mi l e) i n al l di r ect i ons.
GALLIUM AND MERCURY
172
Page 293
GALLIUM AND MERCURY
172
EMERGENCY RESPONSE
FIRE
Do not di rect wat er at t he heat ed met al .
SPILL OR LEAK
Do not use st eel or al umi num t ool s or equi pment .
Cover wi t h ear t h, sand or ot her non- combust i bl e mat er i al f ol l owed wi t h pl ast i c sheet t o
mi ni mi ze spreadi ng or cont act wi t h rai n.
For mercury, use a mercury spi l l ki t .
Mercury spi l l areas may be subsequent l y t reat ed wi t h cal ci um sul phi de/ cal ci um sul f i de or
wi t h sodi um t hi osul phat e/ sodi um t hi osul f at e wash t o neut ral i ze any resi dual mercury.
FI RST AI D
Page 294
NOTES
Page 295
INTRODUCTION TO THE TABLE OF INITIAL ISOLATION
AND PROTECTIVE ACTION DISTANCES
The Table of Initial Isolation and Protective Action Distances suggests distances useful to protect
people from vapors resulting from spills involving dangerous goods which are considered toxic
by inhalation (TIH), including certain chemical warfare agents, or which produce toxic gases
upon contact with water. The Table provides first responders with initial guidance until technically
qualified emergency response personnel are available. Distances show areas likely to be
affected during the first 30 minutes after materials are spilled and could increase
with time.
The Initial Isolation Zone defines an area SURROUNDING the incident in which persons
may be exposed to dangerous (upwind) and life threatening (downwind) concentrations of
material. The Protective Action Zone defines an area DOWNWIND from the incident in
which persons may become incapacitated and unable to take protective action and/or incur
serious or irreversible health effects. The Table provides specific guidance for small and
large spills occurring day or night.
Adjusting distances for a specific incident involves many interdependent variables and should
be made only by personnel technically qualified to make such adjustments. For this reason,
no precise guidance can be provided in this document to aid in adjusting the table distances;
however, general guidance follows.
Factors That May Change the Protective Action Distances
The guide for a material (orange-bordered pages) clearly indicates under the section
EVACUATION Fire, the evacuation distance required to protect against fragmentation hazard
of a large container. If the material becomes involved in a FIRE, the toxic hazard may become
less important than the fire or explosion hazard.
If more than one tank car, cargo tank, portable tank, or large cylinder involved in the incident is
leaking, LARGE SPILL distances may need to be increased.
For a material with a protective action distance of 11.0+ km (7.0+ miles), the actual distance can
be larger in certain atmospheric conditions. If the dangerous goods vapor plume is channeled
in a valley or between many tall buildings, distances may be larger than shown in the Table due
to less mixing of the plume with the atmosphere. Daytime spills in regions with known strong
inversions or snow cover, or occurring near sunset, accompanied by a steady wind, may
require an increase in protective action distance. When these conditions are present, airborne
contaminants mix and disperse more slowly and may travel much farther downwind. In addition,
protective action distances may be larger for liquid spills when either the material or outdoor
temperature exceeds 30C (86F).
Materials which react with water to produce large amounts of toxic gases are included in the
Table of Initial Isolation and Protective Action Distances. Note that some water-reactive materials
Page 296
(WRM) which are also TIH (e.g., Bromine trifluoride (1746), Thionyl chloride (1836), etc.)
produce additional TIH materials when spilled in water. For these materials, two entries are
provided in the Table of Initial Isolation and Protective Action Distances (i.e., for spills on land
and for spills in water). If it is not clear whether the spill is on land or in water, or in cases where
the spill occurs both on land and in water, choose the larger Protective Action Distance. Following
the Table of Initial Isolation and Protective Action Distances is a table that lists the materials which,
when spilled in water, produce toxic gases. The toxic gases that these water-reactive materials
(WRM) produce are also included in the Table.
When a water-reactive TIH producing material is spilled into a river or stream, the source of the
toxic gas may move with the current and stretch from the spill point downstream for a substantial
distance.
Certain chemical warfare agents have been added to the Table of Initial Isolation and Protective
Action Distances. The distances shown were calculated using worst case scenarios for these
agents when used as a weapon.
Initial isolation and protective action distances in this guidebook are derived from historical data
on transportation incidents and the use of statistical models. For worst case scenarios involving
the instantaneous release of the entire contents of a package (e.g., as a result of terrorism,
sabotage or catastrophic accident) the distances may increase. The increase can be estimated
by multiplying the distances by a factor of two (2).
Page 297
PROTECTIVE ACTION DECISION FACTORS TO CONSIDER
The choice of protective actions for a given situation depends on a number of factors. For some
cases, evacuation may be the best option; in others, sheltering in-place may be the best course.
Sometimes, these two actions may be used in combination. In any emergency, officials need to
quickly give the public instructions. The public will need continuing information and instructions
while being evacuated or sheltered in-place.
Proper evaluation of the factors listed below will determine the effectiveness of evacuation or in-
place protection. The importance of these factors can vary with emergency conditions. In
specific emergencies, other factors may need to be identified and considered as well. This list
indicates what kind of information may be needed to make the initial decision.
The Dangerous Goods
Degree of health hazard
Chemical and physical properties
Amount involved
Containment/control of release
Rate of vapor movement
The Population Threatened
Location
Number of people
Time available to evacuate or shelter in-place
Ability to control evacuation or shelter in-place
Building types and availability
Special institutions or populations, e.g., nursing homes, hospitals,
prisons
Weather Conditions
Effect on vapor and cloud movement
Potential for change
Effect on evacuation or protection in-place
Page 298
PROTECTIVE ACTIONS
Protective Actions are those steps taken to preserve the health and safety of emergency
responders and the public during an incident involving releases of dangerous goods. The
Table of Initial Isolation and Protective Action Distances (green-bordered pages) predicts
the size of downwind areas which could be affected by a cloud of toxic gas. People in this
area should be evacuated and/or sheltered in-place inside buildings.
Isolate Hazard Area and Deny Entry means keep everybody away from the area if they
are not directly involved in emergency response operations. Unprotected emergency re-
sponders should not be allowed to enter the isolation zone. This isolation task is done first
to establish control over the area of operations. This is the first step for any protective
actions that may follow. See the Table of Isolation and Protective Action Distances (green-
bordered pages) for more detailed information on specific materials.
Evacuate means move all people from a threatened area to a safer place. To perform an
evacuation, there must be enough time for people to be warned, to get ready, and to leave
an area. If there is enough time, evacuation is the best protective action. Begin evacuating
people nearby and those outdoors in direct view of the scene. When additional help ar-
rives, expand the area to be evacuated downwind and crosswind to at least the extent
recommended in this guidebook. Even after people move to the distances recommended,
they may not be completely safe from harm. They should not be permitted to congregate at
such distances. Send evacuees to a definite place, by a specific route, far enough away so
they will not have to be moved again if the wind shifts.
Shelter In-Place means people should seek shelter inside a building and remain inside
until the danger passes. Sheltering in-place is used when evacuating the public would
cause greater risk than staying where they are, or when an evacuation cannot be
performed. Direct the people inside to close all doors and windows and to shut off all
ventilating, heating and cooling systems. In-place protection may not be the best op-
tion if (a) the vapors are flammable; (b) if it will take a long time for the gas to clear the area;
or (c) if buildings cannot be closed tightly. Vehicles can offer some protection for a short
period if the windows are closed and the ventilating systems are shut off. Vehicles are not
as effective as buildings for in-place protection.
It is vital to maintain communications with competent persons inside the building so
that they are advised about changing conditions. Persons protected-in-place should be
warned to stay far from windows because of the danger from glass and projected metal
fragments in a fire and/or explosion.
Every dangerous goods incident is different. Each will have special problems and con-
cerns. Action to protect the public must be selected carefully. These pages can help with
initial decisions on how to protect the public. Officials must continue to gather information
and monitor the situation until the threat is removed.
Page 299
BACKGROUND ON THE INITIAL ISOLATION
AND PROTECTIVE ACTION DISTANCE TABLE
Initial Isolation and Protective Action Distances in this guidebook were determined for small
and large spills occurring during day or night. The overall analysis was statistical in nature
and utilized state-of-the-art emission rate and dispersion models; statistical release data
from the U.S. DOT HMIS (Hazardous Materials Incident Reporting System) database; 5
years of meteorological observations from over 120 locations in United States, Canada and
Mexico; and the most current toxicological exposure guidelines.
For each chemical, thousands of hypothetical releases were modeled to account for the
statistical variation in both release amount and atmospheric conditions. Based on this statistical
sample, the 90% percentile Protective Action Distance for each chemical and category was
selected to appear in the Table. A brief description of the analysis is provided below. A
detailed report outlining the methodology and data used in the generation of the Initial Isolation
and Protective Action Distances may be obtained from the U.S. Department of Transportation,
Research and Special Programs Administration.
Release amounts and emission rates into the atmosphere were statistically modeled based on
(1) data from the U.S. DOT HMIS database; (2) container types and sizes authorized for transport
as specified in 49 CFR 172.101 and Part 173; (3) physical properties of the materials involved, and
(4) atmospheric data from a historical database. The emission model calculated the release of
vapor due to evaporation of pools on the ground, direct release of vapors from the container, or a
combination of both, as would occur for liquefied gases which can flash to form both a vapor/
aerosol mixture and an evaporating pool. In addition, the emission model also calculated the
emission of toxic vapor by-products generated from spilling water-reactive chemicals in water. Spills
that involve releases of approximately 200 liters or less are considered Small Spills, while spills that
involve quantities greater than 200 liters are considered Large Spills.
Downwind dispersion of the vapor was estimated for each case modeled. Atmospheric
parameters affecting the dispersion, and the emission rate, were selected in a statistical
fashion from a database containing hourly meteorological data from 120 cities in United
States, Canada and Mexico. The dispersion calculation accounted for the time dependent
emission rate from the source as well as the density of the vapor plume (i.e., heavy gas
effects). Since atmospheric mixing is less effective at dispersing vapor plumes during
nighttime, day and night were separated in the analysis. In the Table, Day refers to time
periods after sunrise and before sunset, while Night includes all hours between sunset and
sunrise.
Toxicological short-term exposure guidelines for the chemicals were applied to determine
the downwind distance to which persons may become incapacitated and unable to take
protective action or may incur serious health effects. Toxicological exposure guidelines were
chosen from (1) emergency response guidelines, (2) occupational health guidelines, or (3)
lethal concentrations determined from animal studies, as recommended by an independent
panel of toxicological experts from industry and academia.
Page 300
HOW TO USE THE TABLE OF INITIAL ISOLATION AND
PROTECTIVE ACTION DISTANCES
(1) The responder should already have:
Identified the material by its ID Number and Name; (if an ID Number cannot be
found, use the Name of Material index in the blue-bordered pages to locate that
number.)
Found the three-digit guide for that material in order to consult the emergency
actions recommended jointly with this table;
Noted the wind direction.
(2) Look in this Table (the green-bordered pages) for the ID Number and Name of the
Material involved in the incident. Some ID Numbers have more than one shipping
name listedlook for the specific name of the material. (If the shipping name is not
known and the Table lists more than one name for the same ID Number, use the entry
with the largest protective action distances.)
(3) Determine if the incident involves a SMALL or LARGE spill and if DAY or NIGHT.
Generally, a SMALL SPILL is one which involves a single, small package (e.g., a drum
containing up to approximately 200 liters), a small cylinder, or a small leak from a large
package. A LARGE SPILL is one which involves a spill from a large package, or
multiple spills from many small packages. DAY is any time after sunrise and before
sunset. NIGHT is any time between sunset and sunrise.
(4) Look up the initial ISOLATION distance.
Direct all persons to move, in a crosswind
direction, away from the spill to the
distance specifiedin meters and feet.
(5) Look up the initial PROTECTIVE ACTION DISTANCE shown in the Table. For a given
material, spill size, and whether day or night, the Table gives the downwind distancein
kilometers and miles for which protective actions should be considered. For practical
purposes, the Protective Action Zone (i.e., the area in which people are at risk of harmful
exposure) is a square, whose length and width are the same as the downwind distance
shown in the Table.
Initial Isolation
Zone
Initial Isolation
Distance
Spill
Page 301
(6) Initiate Protective Actions to the extent possible, beginning with those closest to the
spill site and working away from the site in the downwind direction. When a water-
reactive TIH producing material is spilled into a river or stream, the source of the toxic
gas may move with the current or stretch from the spill point downstream for a substantial
distance.
The shape of the area in which protective actions should be taken (the Protective
Action Zone) is shown in this figure. The spill is located at the center of the small
circle. The larger circle represents the INITIAL ISOLATION zone around the spill.
NOTE: See Introduction To The Table Of Initial Isolation And Protective Action
Distances for factors which may increase or decrease Protective Action
Distances.
Call the emergency response telephone number listed on the shipping paper, or the
appropriate response agency as soon as possible for additional information on the material,
safety precautions, and mitigation procedures.
Protective
Action Zone
Initial
Isolation
Zone
1/2 Downwind
Distance
Wind Direction
1/2 Downwind
Distance
Spill
Downwind Distance
P
a
g
e

3
0
2
TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES
SMALL SPILLS LARGE SPILLS
(From a large package or from many small packages) (From a small package or small leak from a large package)
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
persons Downwind during-
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1005 Ammonia, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)
1005 Ammonia, anhydrous, liquefied
1005 Ammonia, solution, with more
than 50% Ammonia
1005 Anhydrous ammonia
1005 Anhydrous ammonia, liquefied
1008 Boron trifluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.8 km (1.1 mi) 4.8 km (3.0 mi)
1008 Boron trifluoride, compressed
1016 Carbon monoxide 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi)
1016 Carbon monoxide, compressed
1017 Chlorine 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 7.4 km (4.6 mi)
1023 Coal gas 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)
1023 Coal gas, compressed
1026 Cyanogen 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 120 m (400 ft) 1.1 km (0.7 mi) 4.3 km (2.7 mi)
1026 Cyanogen, liquefied
1026 Cyanogen gas
1040 Ethylene oxide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)
1040 Ethylene oxide with Nitrogen
1045 Fluorine 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi)
1045 Fluorine, compressed
1048 Hydrogen bromide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.7 km (3.6 mi)
1050 Hydrogen chloride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 360 m (1200 ft) 3.6 km (2.2 mi) 10.4 km (6.5 mi)
1051 AC (when used as a weapon) 60 m (200 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 500 m (1500 ft) 1.7 km (1.0 mi) 3.9 km (2.4 mi)
"+" means distance can be larger in certain atmospheric conditions
P
a
g
e

3
0
3
1051 Hydrocyanic acid, aqueous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.7 km (2.3 mi)
solutions, with more than 20%
Hydrogen cyanide
1051 Hydrocyanic acid, liquefied
1051 Hydrogen cyanide, anhydrous,
stabilized
1051 Hydrogen cyanide, stabilized
1052 Hydrogen fluoride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 210 m (700 ft) 1.9 km (1.2 mi) 4.3 km (2.7 mi)
1053 Hydrogen sulfide 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 210 m (700 ft) 2.1 km (1.3 mi) 6.2 km (3.9 mi)
1053 Hydrogen sulfide, liquefied
1053 Hydrogen sulphide
1053 Hydrogen sulphide, liquefied
1062 Methyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.2 km (1.4 mi)
1064 Methyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 150 m (500 ft) 1.3 km (0.8 mi) 4.5 km (2.8 mi)
1067 Dinitrogen tetroxide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.6 km (1.0 mi) 4.1 km (2.5 mi)
1067 Dinitrogen tetroxide, liquefied
1067 Nitrogen dioxide
1067 Nitrogen dioxide, liquefied
1069 Nitrosyl chloride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 450 m (1500 ft) 4.3 km (2.7 mi) 11.0 km (6.9 mi)
1071 Oil gas 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)
1071 Oil gas, compressed
1076 CG (when used as a weapon) 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.0 mi) 800 m (2500 ft) 7.3 km (4.5 mi) 11.0+ km (7.0+ mi)
1076 Diphosgene 90 m (300 ft) 0.9 km (0.6 mi) 4.1 km (2.6 mi) 800 m (2500 ft) 6.6 km (4.1 mi) 11.0+ km (7.0+ mi)
1076 DP (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 180 m (600 ft) 1.7 km (1.0 mi) 4.6 km (2.8 mi)
1076 Phosgene 90 m (300 ft) 0.9 km (0.6 mi) 4.1 km (2.6 mi) 800 m (2500 ft) 6.6 km (4.1 mi) 11.0+ km (7.0+ mi)
1079 Sulfur dioxide 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 210 m (700 ft) 2.0 km (1.3 mi) 6.3 km (3.9 mi)
1079 Sulfur dioxide, liquefied
1079 Sulphur dioxide
1079 Sulphur dioxide, liquefied
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First
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in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1082 Trifluorochloroethylene 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)
1082 Trifluorochloroethylene, inhibited
1082 Trifluorochloroethylene, stabilized
1092 Acrolein, inhibited 60 m (200 ft) 0.5 km (0.3 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.8 km (3.0 mi) 10.2 km (6.3 mi)
1092 Acrolein, stabilized
1098 Allyl alcohol 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi)
1135 Ethylene chlorohydrin 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.5 km (1.0 mi)
1143 Crotonaldehyde, inhibited 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)
1143 Crotonaldehyde, stabilized
1162 Dimethyldichlorosilane 30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 7.9 km (4.9 mi)
(when spilled in water)
1163 1,1-Dimethylhydrazine 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.2 km (0.8 mi)
1163 Dimethylhydrazine, unsymmetrical
1182 Ethyl chloroformate 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.8 km (1.1 mi)
1185 Ethyleneimine, inhibited 30 m (100 ft) 0.2 km (0.2 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.2 mi) 4.0 km (2.5 mi)
1185 Ethyleneimine, stabilized
1196 Ethyltrichlorosilane 30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 7.9 km (4.9 mi)
1238 Methyl chloroformate 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 180 m (600 ft) 1.8 km (1.1 mi) 3.9 km (2.4 mi)
1239 Methyl chloromethyl ether 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
1242 Methyldichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.8 km (3.0 mi)
1244 Methylhydrazine 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.4 km (0.9 mi) 2.9 km (1.8 mi)
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1250 Methyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 4.0 km (2.5 mi)
1251 Methyl vinyl ketone 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
1251 Methyl vinyl ketone, stabilized
1259 Nickel carbonyl 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 9.8 km (6.1 mi)
1295 Trichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 6.5 km (4.1 mi)
1298 Trimethylchlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi)
1305 Vinyltrichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.0 km (3.1 mi)
1305 Vinyltrichlorosilane, inhibited
1305 Vinyltrichlorosilane, stabilized
1340 Phosphorus pentasulfide, free 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.0 km (0.6 mi) 3.9 km (2.4 mi)
from yellow or white Phosphorus
1340 Phosphorus pentasulphide, free
from yellow or white Phosphorus
1360 Calcium phosphide 60 m (200 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 6.3 km (3.9 mi) 11.0+ km (7.0+ mi)
1380 Pentaborane 90 m (300 ft) 0.9 km (0.6 mi) 3.3 km (2.1 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)
1384 Sodium dithionite 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
1384 Sodium hydrosulfite
1384 Sodium hydrosulphite
1397 Aluminum phosphide 90 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+ km (7.0+ mi)
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First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1412 Lithium amide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.6 km (1.0 mi)
1419 Magnesium aluminum phosphide 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi) 1000 m (3000 ft) 7.9 km (4.9 mi) 11.0+ km (7.0+ mi)
1432 Sodium phosphide 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 11.0+ km (7.0+ mi)
1510 Tetranitromethane 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)
1541 Acetone cyanohydrin, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 240 m (800 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi)
1556 MD (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.1 km (0.7 mi)
1556 Methyldichloroarsine 30 m (100 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 120 m (400 ft) 1.3 km (0.8 mi) 3.6 km (2.2 mi)
1556 PD (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi)
1560 Arsenic chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.8 km (1.1 mi)
1560 Arsenic trichloride
1569 Bromoacetone 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.3 km (1.5 mi)
1580 Chloropicrin 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi)
1581 Chloropicrin and Methyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 210 m (700 ft) 2.1 km (1.3 mi) 5.9 km (3.7 mi)
mixture
1581 Methyl bromide and Chloropicrin
mixture
1582 Chloropicrin and Methyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi)
mixture
1582 Methyl chloride and Chloropicrin
mixture
1583 Chloropicrin mixture, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi)
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1589 CK (when used as a weapon) 60 m (200 ft) 0.7 km (0.4 mi) 2.5 km (1.5 mi) 420 m (1300 ft) 4.1 km (2.5 mi) 8.1 km (5.0 mi)
1589 Cyanogen chloride, inhibited 60 m (200 ft) 0.6 km (0.4 mi) 2.8 km (1.8 mi) 450 m (1400 ft) 4.3 km (2.7 mi) 10.1 km (6.3 mi)
1589 Cyanogen chloride, stabilized
1595 Dimethyl sulfate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)
1595 Dimethyl sulphate
1605 Ethylene dibromide 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi)
1612 Hexaethyl tetraphosphate and 90 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.1 km (5.1 mi)
compressed gas mixture
1613 Hydrocyanic acid, aqueous 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 120 m (400 ft) 0.5 km (0.3 mi) 1.3 km (0.8 mi)
solution, with not more than
20% Hydrogen cyanide
1613 Hydrogen cyanide, aqueous
solution, with not more than
1614 Hydrogen cyanide, anhydrous, 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.7 km (1.1 mi)
stabilized (absorbed)
1614 Hydrogen cyanide, stabilized
(absorbed)
1647 Ethylene dibromide and Methyl 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi)
bromide mixture, liquid
1647 Methyl bromide and Ethylene
dibromide mixture, liquid
1660 Nitric oxide 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi)
1660 Nitric oxide, compressed
1670 Perchloromethyl mercaptan 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.2 km (0.8 mi)
1680 Potassium cyanide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 300 m (1000 ft) 1.0 km (0.6 mi) 3.9 km (2.4 mi)
1680 Potassium cyanide, solid
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First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1689 Sodium cyanide 60 m (200 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 390 m (1300 ft) 1.3 km (0.8 mi) 4.9 km (3.0 mi)
1689 Sodium cyanide, solid
1694 CA (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.7 km (1.0 mi) 4.2 km (2.6 mi)
1695 Chloroacetone, stabilized 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi)
1697 CN (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.2 km (0.7 mi) 3.3 km (2.0 mi)
1698 Adamsite (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 180 m (600 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi)
1698 DM (when used as a weapon)
1699 DA (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 180 m (600 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi)
1716 Acetyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.3 km (1.4 mi)
1717 Acetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 3.5 km (2.2 mi)
1722 Allyl chlorocarbonate 30 m (100 ft) 0.4 km (0.2 mi) 0.8 km (0.5 mi) 210 m (700 ft) 2.0 km (1.2 mi) 3.8 km (2.4 mi)
1722 Allyl chloroformate
1724 Allyltrichlorosilane, stabilized 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.2 mi) 5.4 km (3.4 mi)
1725 Aluminum bromide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.6 km (1.6 mi)
1726 Aluminum chloride, anhydrous 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 120 m (400 ft) 1.2 km (0.7 mi) 4.5 km (2.8 mi)
1728 Amyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi)
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1732 Antimony pentafluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 180 m (600 ft) 1.9 km (1.2 mi) 5.4 km (3.4 mi)
1741 Boron trichloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.7 km (1.1 mi)
1744 Bromine 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
1744 Bromine, solution
1745 Bromine pentafluoride 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)
(when spilled on land)
1745 Bromine pentafluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 240 m (800 ft) 2.2 km (1.4 mi) 6.6 km (4.1 mi)
1746 Bromine trifluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.8 km (1.1 mi) 4.8 km (3.0 mi)
1746 Bromine trifluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 210 m (700 ft) 1.9 km (1.2 mi) 5.8 km (3.6 mi)
1747 Butyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)
1749 Chlorine trifluoride 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 300 m (1000 ft) 2.8 km (1.8 mi) 8.1 km (5.1 mi)
1752 Chloroacetyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 2.6 km (1.6 mi)
1752 Chloroacetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.5 km (1.0 mi)
1754 Chlorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)
1754 Chlorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)
1754 Chlorosulfonic acid and Sulfur 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)
trioxide mixture
1754 Chlorosulfonic acid and Sulfur 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)
trioxide mixture
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First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1754 Chlorosulphonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)
1754 Chlorosulphonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)
1754 Chlorosulphonic acid and 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)
Sulphur trioxide mixture
1754 Chlorosulphonic acid and 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)
Sulphur trioxide mixture
1754 Sulfur trioxide and Chlorosulfonic 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)
acid mixture (when spilled on land)
1754 Sulfur trioxide and Chlorosulfonic 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)
acid mixture (when spilled in water)
1754 Sulphur trioxide and 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)
Chlorosulphonic acid mixture
1754 Sulphur trioxide and 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)
Chlorosulphonic acid mixture
1758 Chromium oxychloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)
1763 Cyclohexyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi)
1766 Dichlorophenyltrichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 210 m (700 ft) 2.1 km (1.3 mi) 5.7 km (3.6 mi)
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1767 Diethlydichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
1769 Diphenyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi)
1771 Dodecyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.2 mi)
1777 Fluorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.0 km (0.6 mi) 3.4 km (2.1 mi)
1777 Fluorosulphonic acid
1784 Hexyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.0 km (0.7 mi) 3.8 km (2.4 mi)
1799 Nonyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi)
1800 Octadecyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi)
1801 Octyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi)
1804 Phenyltrichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 240 m (800 ft) 2.2 km (1.4 mi) 6.4 km (4.0 mi)
1806 Phosphorus pentachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.1 km (1.9 mi)
1809 Phosphorus trichloride 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.5 km (1.0 mi) 3.5 km (2.2 mi)
1809 Phosphorus trichloride 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.8 km (3.0 mi)
1810 Phosphorus oxychloride 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.0 km (0.7 mi) 2.2 km (1.4 mi)
1810 Phosphorus oxychloride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 240 m (800 ft) 2.3 km (1.5 mi) 6.3 km (3.9 mi)
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First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1816 Propyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)
1818 Silicon tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.5 km (1.0 mi) 4.6 km (2.9 mi)
1828 Sulfur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.7 km (1.1 mi)
1828 Sulfur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 4.9 km (3.0 mi)
1828 Sulphur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.7 km (1.1 mi)
1828 Sulphur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 4.9 km (3.0 mi)
1829 Sulfur trioxide 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)
1829 Sulfur trioxide, inhibited
1829 Sulfur trioxide, stabilized
1829 Sulfur trioxide, uninhibited
1829 Sulphur trioxide
1829 Sulphur trioxide, inhibited
1829 Sulphur trioxide, stabilized
1829 Sulphur trioxide, uninhibited
1831 Sulfuric acid, fuming 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)
1831 Sulfuric acid, fuming, with not
less than 30% free Sulfur trioxide
1831 Sulphuric acid, fuming
1831 Sulphuric acid, fuming, with not
less than 30% free Sulphur trioxide
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1834 Sulfuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi)
1834 Sulfuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi)
1834 Sulphuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi)
1834 Sulphuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi)
1836 Thionyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 90 m (300 ft) 1.0 km (0.6 mi) 2.2 km (1.4 mi)
1836 Thionyl chloride 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 450 m (1500 ft) 4.5 km (2.8 mi) 10.5 km (6.5 mi)
1838 Titanium tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)
1838 Titanium tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 3.7 km (2.3 mi)
1859 Silicon tetrafluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)
1859 Silicon tetrafluoride, compressed
1892 ED (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 120 m (400 ft) 1.3 km (0.8 mi) 2.6 km (1.6 mi)
1892 Ethyldichloroarsine 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)
1898 Acetyl iodide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.8 km (1.1 mi)
1911 Diborane 60 m (200 ft) 0.4 km (0.2 mi) 1.6 km (1.0 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.4 km (3.4 mi)
1911 Diborane, compressed
1923 Calcium dithionite 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
1923 Calcium hydrosulfite
1923 Calcium hydrosulphite
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First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1931 Zinc dithionite 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
1931 Zinc hydrosulfite
1931 Zinc hydrosulphite
1953 Compressed gas, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
poisonous, n.o.s. (Inhalation
Hazard Zone A)
1953 Compressed gas, flammable, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
1953 Compressed gas, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
toxic, n.o.s. (Inhalation
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
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Hazard Zone D)
1953 Compressed gas, poisonous, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
flammable, n.o.s.
1953 Compressed gas, poisonous,
flammable, n.o.s. (Inhalation
Hazard Zone A)
1953 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
1953 Compressed gas, toxic, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
flammable, n.o.s.
1953 Compressed gas, toxic,
Hazard Zone A)
1953 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
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First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1953 Liquefied gas, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
poisonous, n.o.s.
1953 Liquefied gas, flammable,
Hazard Zone A)
1953 Liquefied gas, flammable, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
1953 Liquefied gas, flammable, toxic, n.o.s. 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
1953 Liquefied gas, flammable, toxic, n.o.s.
(Inhalation Hazard Zone A)
1953 Liquefied gas, flammable, toxic, n.o.s. 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
(Inhalation Hazard Zone B)
(Inhalation Hazard Zone C)
(Inhalation Hazard Zone D)
1955 Compressed gas, poisonous, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
1955 Compressed gas, poisonous, n.o.s.
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1955 Compressed gas, poisonous, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
1955 Compressed gas, poisonous, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)
1955 Compressed gas, poisonous, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)
1955 Compressed gas, toxic, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
1955 Compressed gas, toxic, n.o.s.
1955 Compressed gas, toxic, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
1955 Compressed gas, toxic, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)
1955 Compressed gas, toxic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)
1955 Liquefied gas, poisonous, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
1955 Liquefied gas, poisonous, n.o.s.
1955 Liquefied gas, poisonous, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
1955 Liquefied gas, poisonous, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)
1955 Liquefied gas, toxic, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
1955 Liquefied gas, toxic, n.o.s.
1955 Liquefied gas, toxic, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
P
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3
1
8
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
1955 Liquefied gas, toxic, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)
1955 Organic phosphate compound 120 m (400 ft) 1.0 km (0.7 mi) 3.4 km (2.1 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.6 km (6.0 mi)
mixed with compressed gas
1955 Organic phosphate mixed with
compressed gas
1955 Organic phosphorus compound
mixed with compressed gas
1967 Insecticide gas, poisonous, n.o.s. 120 m (400 ft) 1.0 km (0.7 mi) 3.4 km (2.1 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.6 km (6.0 mi)
1967 Insecticide gas, toxic, n.o.s.
1967 Parathion and compressed gas
mixture
1975 Dinitrogen tetroxide and Nitric 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi)
oxide mixture
1975 Nitric oxide and Dinitrogen
tetroxide mixture
1975 Nitric oxide and Nitrogen dioxide
mixture
1975 Nitric oxide and Nitrogen
tetroxide mixture
1975 Nitrogen dioxide and Nitric oxide
mixture
1975 Nitrogen tetroxide and Nitric
oxide mixture
1994 Iron pentacarbonyl 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 3.0 km (1.9 mi)
2004 Magnesium diamide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.9 km (1.8 mi)
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2011 Magnesium phosphide 60 m (200 ft) 0.5 km (0.4 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 7.5 km (4.7 mi) 11.0+ km (7.0+ mi)
2012 Potassium phosphide 60 m (200 ft) 0.4 km (0.3 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 11.0+ km (7.0+ mi)
2013 Strontium phosphide 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.6 km (2.9 mi) 11.0+ km (7.0+ mi)
2032 Nitric acid, fuming 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.2 km (0.8 mi)
2032 Nitric acid, red fuming
2186 Hydrogen chloride, refrigerated liquid 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 360 m (1200 ft) 3.6 km (2.2 mi) 10.4 km (6.5 mi)
2188 Arsine 60 m (200 ft) 0.6 km (0.4 mi) 3.0 km (1.9 mi) 420 m (1400 ft) 4.1 km (2.6 mi) 9.5 km (5.9 mi)
2188 SA (when used as a weapon) 60 m (200 ft) 0.9 km (0.5 mi) 2.5 km (1.5 mi) 420 m (1300 ft) 4.1 km (2.5 mi) 8.1 km (5.0 mi)
2189 Dichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
2190 Oxygen difluoride 600 m (2000ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2190 Oxygen difluoride, compressed
2191 Sulfuryl fluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)
2191 Sulphuryl fluoride
2192 Germane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi)
2194 Selenium hexafluoride 90 m (300 ft) 0.7 km (0.5 mi) 3.2 km (2.0 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.0 km (5.6 mi)
2195 Tellurium hexafluoride 90 m (300 ft) 1.0 km (0.6 mi) 4.0 km (2.5 mi) 600 m (2000 ft) 6.0 km (3.7 mi) 11.0+ km (7.0+ mi)
2196 Tungsten hexafluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.1 km (0.7 mi) 120 m (400 ft) 1.0 km (0.6 mi) 3.7 km (2.3 mi)
2197 Hydrogen iodide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 120 m (400 ft) 1.3 km (0.8 mi) 3.7 km (2.3 mi)
2198 Phosphorus pentafluoride 30 m (100 ft) 0.3 km (0.2 mi) 1.6 km (1.0 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.6 km (2.9 mi)
2198 Phosphorus pentafluoride,
compressed
2199 Phosphine 60 m (200 ft) 0.7 km (0.4 mi) 3.1 km (1.9 mi) 450 m (1400 ft) 4.3 km (2.7 mi) 9.6 km (6.0 mi)
2202 Hydrogen selenide, anhydrous 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
P
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3
2
0
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
2204 Carbonyl sulfide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 8.1 km (5.0 mi)
2204 Carbonyl sulphide
2232 Chloroacetaldehyde 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)
2232 2-Chloroethanal
2334 Allylamine 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 2.5 km (1.5 mi)
2337 Phenyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi)
2382 1,2-Dimethylhydrazine 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.2 km (0.8 mi)
2382 Dimethylhydrazine, symmetrical
2407 Isopropyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi)
2417 Carbonyl fluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.1 km (0.7 mi) 90 m (300 ft) 1.0 km (0.6 mi) 3.6 km (2.3 mi)
2417 Carbonyl fluoride, compressed
2418 Sulfur tetrafluoride 60 m (200 ft) 0.7 km (0.4 mi) 3.2 km (2.0 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 10.6 km (6.6 mi)
2418 Sulphur tetrafluoride
2420 Hexafluoroacetone 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)
2421 Nitrogen trioxide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.9 km (1.2 mi)
2437 Methylphenyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi)
2438 Trimethylacetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)
2442 Trichloroacetyl chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.8 km (0.5 mi) 120 m (400 ft) 1.2 km (0.8 mi) 2.2 km (1.4 mi)
2474 Thiophosgene 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 360 m (1200 ft) 3.6 km (2.3 mi) 6.8 km (4.2 mi)
2477 Methyl isothiocyanate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.0 km (0.7 mi)
2480 Methyl isocyanate 60 m (200 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi) 600 m (1800 ft) 5.4 km (3.3 mi) 11.0+ km (7.0+ mi)
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2481 Ethyl isocyanate 60 m (200 ft) 0.6 km (0.4 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)
2482 n-Propyl isocyanate 120 m (400 ft) 1.0 km (0.7 mi) 2.5 km (1.6 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+ km (7.0+ mi)
2483 Isopropyl isocyanate 120 m (400 ft) 1.1 km (0.7 mi) 2.8 km (1.8 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2484 tert-Butyl isocyanate 90 m (300 ft) 1.0 km (0.6 mi) 2.4 km (1.5 mi) 1000 m (3000 ft) 8.4 km (5.2 mi) 11.0+ km (7.0+ mi)
2485 n-Butyl isocyanate 90 m (300 ft) 0.7 km (0.5 mi) 1.6 km (1.0 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 8.0 km (5.0 mi)
2486 Isobutyl isocyanate 90 m (300 ft) 0.7 km (0.5 mi) 1.6 km (1.0 mi) 500 m (1600 ft) 4.7 km (3.0 mi) 7.8 km (4.8 mi)
2487 Phenyl isocyanate 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.9 km (1.8 mi)
2488 Cyclohexyl isocyanate 30 m (100 ft) 0.2 km (0.2 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.6 km (1.0 mi)
2495 Iodine pentafluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 210 m (700 ft) 1.9 km (1.2 mi) 5.7 km (3.6 mi)
2521 Diketene, inhibited 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
2521 Diketene, stabilized
2534 Methylchlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)
2548 Chlorine pentafluoride 30 m (100 ft) 0.3 km (0.2 mi) 1.7 km (1.1 mi) 240 m (800 ft) 2.4 km (1.5 mi) 7.4 km (4.6 mi)
2600 Carbon monoxide and Hydrogen 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi)
mixture
2600 Carbon monoxide and Hydrogen
mixture, compressed
2600 Hydrogen and Carbon monoxide
mixture
2600 Hydrogen and Carbon monoxide
mixture, compressed
2605 Methoxymethyl isocyanate 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.6 km (1.6 mi)
2606 Methyl orthosilicate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.7 km (0.4 mi)
2644 Methyl iodide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi)
2646 Hexachlorocyclopentadiene 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.5 km (0.3 mi)
2668 Chloroacetonitrile 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
P
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3
2
2
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
2676 Stibine 60 m (200 ft) 0.4 km (0.3 mi) 2.2 km (1.4 mi) 270 m (900 ft) 2.8 km (1.7 mi) 7.5 km (4.7 mi)
2691 Phosphorus pentabromide 30 m (100 ft) 0.1 km (0.1 mi) 0.7 km (0.4 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.8 km (1.7 mi)
2692 Boron tribromide 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.3 km (0.8 mi)
2692 Boron tribromide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.6 km (1.6 mi)
2740 n-Propyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi)
2742 sec-Butyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.6 km (0.4 mi)
2742 Isobutyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
2743 n-Butyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)
2806 Lithium nitride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.6 km (1.6 mi)
2810 Buzz (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.5 km (0.3 mi) 2.0 km (1.2 mi)
2810 BZ (when used as a weapon)
2810 CS (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 240 m (800 ft) 2.6 km (1.6 mi) 5.7 km (3.5 mi)
2810 DC (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.5 mi) 240 m (800 ft) 2.3 km (1.4 mi) 5.4 km (3.3 mi)
2810 GA (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.7 km (1.0 mi) 3.1 km (1.9 mi)
2810 GB (when used as a weapon) 150 m (500 ft) 1.7 km (1.0 mi) 3.4 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2810 GD (when used as a weapon) 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi)
2810 GF (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 240 m (800 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi)
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2810 H (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.2 km (0.7 mi)
2810 HD (when used as a weapon)
2810 HL (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi)
2810 HN-1 (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.3 km (0.8 mi)
2810 L (Lewisite) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi)
(when used as a weapon)
2810 Lewisite (when used as a weapon)
2810 Mustard (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi)
2810 Mustard Lewisite 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi)
2810 Poisonous liquid, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2810 Poisonous liquid, n.o.s.
2810 Poisonous liquid, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
2810 Poisonous liquid, organic, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2810 Poisonous liquid, organic, n.o.s.
2810 Poisonous liquid, organic, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
2810 Sarin (when used as a weapon) 150 m (500 ft) 1.7 km (1.0 mi) 3.4 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2810 Soman (when used as a weapon) 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi)
2810 Tabun (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.7 km (1.0 mi) 3.1 km (1.9 mi)
2810 Thickened GD 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi)
P
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3
2
4
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
2810 Toxic liquid, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2810 Toxic liquid, n.o.s. (Inhalation
Hazard Zone A)
2810 Toxic liquid, n.o.s. (Inhalation 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
Hazard Zone B)
2810 Toxic liquid, organic, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2810 Toxic liquid, organic, n.o.s.
2810 Toxic liquid, organic, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
2810 VX (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.0 km (0.6 mi)
2811 CX (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 1.0 km (0.6 mi) 3.1 km (1.9 mi)
2826 Ethyl chlorothioformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.0 km (0.6 mi)
2845 Ethyl phosphonous dichloride, 30 m (100 ft) 0.4 km (0.2 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi)
anhydrous
2845 Methyl phosphonous dichloride 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi)
2901 Bromine chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.9 km (0.6 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.3 km (3.9 mi)
2927 Ethyl phosphonothioic 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi)
dichloride, anhydrous
2927 Ethyl phosphorodichloridate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.2 mi)
2927 Poisonous liquid, corrosive, 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)
n.o.s.
2927 Poisonous liquid, corrosive, n.o.s.
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2927 Poisonous liquid, corrosive, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
2927 Toxic liquid, corrosive, organic, 60 m (200 ft) 0.6 km (0.4 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)
n.o.s.
2927 Toxic liquid, corrosive, organic,
n.o.s. (Inhalation Hazard Zone A)
2927 Toxic liquid, corrosive, organic, 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.9 km (1.8 mi)
n.o.s. (Inhalation Hazard Zone B)
2929 Poisonous liquid, flammable, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
n.o.s.
2929 Poisonous liquid, flammable, n.o.s.
2929 Poisonous liquid, flammable, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
2929 Poisonous liquid, flammable, 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
organic, n.o.s.
2929 Poisonous liquid, flammable,
organic, n.o.s. (Inhalation
Hazard Zone A)
2929 Poisonous liquid, flammable, 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
organic, n.o.s. (Inhalation
Hazard Zone B)
2929 Toxic liquid, flammable, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2929 Toxic liquid, flammable, n.o.s.
2929 Toxic liquid, flammable, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
2929 Toxic liquid, flammable, organic, 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
n.o.s.
2929 Toxic liquid, flammable, organic,
P
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3
2
6
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
2929 Toxic liquid, flammable, organic, 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
2977 Radioactive material, Uranium 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 3.3 km (2.1 mi)
hexafluoride, fissile
2977 Uranium hexafluoride, fissile
containing more than 1%
Uranium-235
2978 Radioactive material, Uranium 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 3.3 km (2.1 mi)
hexafluoride
2978 Radioactive material, Uranium
hexafluoride, non-fissile or
fissile-excepted
2978 Uranium hexafluoride
2978 Uranium hexafluoride, fissile-excepted
2978 Uranium hexafluoride, low
specific activity
2978 Uranium hexafluoride, non-fissile
2985 Chlorosilanes, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)
corrosive, n.o.s.
2985 Chlorosilanes, n.o.s.
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7
2986 Chlorosilanes, corrosive, 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)
flammable, n.o.s.
2987 Chlorosilanes, corrosive, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)
2988 Chlorosilanes, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)
2988 Chlorosilanes, water-reactive,
flammable, corrosive, n.o.s.
3023 2-Methyl-2-hepthanethiol 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)
3023 tert-Octyl mercaptan
3048 Aluminum phosphide pesticide 90 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+ km (7.0+ mi)
3049 Metal alkyl halides, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)
3049 Metal alkyl halides, water-reactive,
n.o.s. (when spilled in water)
3049 Metal aryl halides, n.o.s.
3049 Metal aryl halides, water-reactive,
n.o.s. (when spilled in water)
3052 Aluminum alkyl halides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)
3052 Aluminum alkyl halides, liquid
3052 Aluminum alkyl halides, solid
3057 Trifluoroacetyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
P
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3
2
8
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
3079 Methacrylonitrile, inhibited 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (02 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)
3079 Methacrylonitrile, stabilized
3083 Perchloryl fluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)
3122 Poisonous liquid, oxidizing, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
n.o.s.
3122 Poisonous liquid, oxidizing, n.o.s.
3122 Poisonous liquid, oxidizing, n.o.s. 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)
3122 Toxic liquid, oxidizing, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
3122 Toxic liquid, oxidizing, n.o.s.
3122 Toxic liquid, oxidizing, n.o.s. 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)
3123 Poisonous liquid, water-reactive, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
n.o.s.
3123 Poisonous liquid, water-reactive,
3123 Poisonous liquid, water-reactive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
3123 Poisonous liquid, which in 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
contact with water emits
flammable gases, n.o.s.
3123 Poisonous liquid, which in contact
with water emits flammable gases,
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3
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9
3123 Poisonous liquid, which in contact 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
with water emits flammable gases,
3123 Toxic liquid, water-reactive, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
n.o.s.
3123 Toxic liquid, water-reactive,
3123 Toxic liquid, water-reactive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
3123 Toxic liquid, which in contact 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
with water emits flammable
gases, n.o.s.
3123 Toxic liquid, which in contact with
water emits flammable gases,
3123 Toxic liquid, which in contact with 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
water emits flammable gases,
3160 Liquefied gas, poisonous, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
flammable, n.o.s.
3160 Liquefied gas, poisonous,
Hazard Zone A)
3160 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
P
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3
3
0
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
3160 Liquefied gas, toxic, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
n.o.s.
3160 Liquefied gas, toxic, flammable,
3160 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
n.o.s. (Inhalation Hazard Zone C)
3160 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)
n.o.s. (Inhalation Hazard Zone D)
3162 Liquefied gas, poisonous, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
3162 Liquefied gas, poisonous, n.o.s.
3162 Liquefied gas, poisonous, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
3162 Liquefied gas, toxic, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
3162 Liquefied gas, toxic, n.o.s.
3162 Liquefied gas, toxic, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
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3246 Methanesulfonyl chloride 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 2.6 km (1.6 mi)
3246 Methanesulphonyl chloride
3275 Nitriles, poisonous, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)
n.o.s.
3275 Nitriles, toxic, flammable, n.o.s.
3276 Nitriles, poisonous, liquid, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)
3276 Nitriles, poisonous, n.o.s.
3276 Nitriles, toxic, liquid, n.o.s.
3276 Nitriles, toxic, n.o.s.
3278 Organophosphorus compound, 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi)
poisonous, liquid, n.o.s.
3278 Organophosphorus compound,
poisonous, n.o.s.
toxic, liquid, n.o.s.
toxic, n.o.s.
3279 Organophosphorus compound, 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi)
poisonous, flammable, n.o.s.
toxic, flammable, n.o.s.
3280 Organoarsenic compound, liquid, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 210 m (700 ft) 2.1 km (1.3 mi) 5.1 km (3.2 mi)
3280 Organoarsenic compound, n.o.s.
3281 Metal carbonyls, liquid, n.o.s. 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 9.8 km (6.1 mi)
3281 Metal carbonyls, n.o.s.
3287 Poisonous liquid, inorganic, 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)
n.o.s.
3287 Poisonous liquid, inorganic,
3287 Poisonous liquid, inorganic, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
P
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2
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
3287 Toxic liquid, inorganic, n.o.s. 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)
3287 Toxic liquid, inorganic, n.o.s.
3287 Toxic liquid, inorganic, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
3289 Poisonous liquid, corrosive, 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)
inorganic, n.o.s.
3289 Poisonous liquid, corrosive,
inorganic, n.o.s. (Inhalation
Hazard Zone A)
3289 Poisonous liquid, corrosive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
Hazard Zone B)
3289 Toxic liquid, corrosive, 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)
inorganic, n.o.s.
3289 Toxic liquid, corrosive,
Hazard Zone A)
3289 Toxic liquid, corrosive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
Hazard Zone B)
3294 Hydrogen cyanide, solution in 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 210 m (700 ft) 0.7 km (0.4 mi) 2.1 km (1.3 mi)
alcohol, with not more than
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3300 Carbon dioxide and Ethylene 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)
oxide mixture, with more than
87% Ethylene oxide
3300 Ethylene oxide and Carbon
dioxide mixture, with more
than 87% Ethylene oxide
3303 Compressed gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
oxidizing, n.o.s.
oxidizing, n.o.s. (Inhalation
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
3303 Compressed gas, toxic, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
oxidizing, n.o.s.
Hazard Zone A)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
P
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3
3
4
First
ISOLATE
in all Directions
Meters (Feet)
Then
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NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
corrosive, n.o.s.
corrosive, n.o.s. (Inhalation
Hazard Zone A)
3304 Compressed gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
corrosive, n.o.s.
Hazard Zone A)
3304 Compressed gas, toxic, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
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oxidizing, corrosive, n.o.s.
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6
First
ISOLATE
in all Directions
Meters (Feet)
Then
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NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
3307 Liquefied gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
oxidizing, n.o.s.
Hazard Zone A)
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Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
3307 Liquefied gas, toxic, oxidizing, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
n.o.s.
3307 Liquefied gas, toxic, oxidizing,
3307 Liquefied gas, toxic, oxidizing, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)
corrosive, n.o.s.
Hazard Zone A)
3308 Liquefied gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)
Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
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8
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
3308 Liquefied gas, toxic, corrosive, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
3308 Liquefied gas, toxic, corrosive,
3308 Liquefied gas, toxic, corrosive, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)
3308 Liquefied gas, toxic, corrosive, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)
3308 Liquefied gas, toxic, corrosive, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)
3309 Liquefied gas, toxic, flammable, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
corrosive, n.o.s.
3309 Liquefied gas, toxic, flammable,
Hazard Zone A)
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Hazard Zone B)
Hazard Zone C)
Hazard Zone D)
3310 Liquefied gas, toxic, oxidizing, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
corrosive, n.o.s.
3310 Liquefied gas, toxic, oxidizing,
Hazard Zone A)
Hazard Zone B)
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First
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in all Directions
Meters (Feet)
Then
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NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
Hazard Zone C)
Hazard Zone D)
3318 Ammonia solution, with more 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)
than 50% Ammonia
3355 Insecticide gas, poisonous, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
flammable, n.o.s
3355 Insecticide gas, poisonous,
flammable, n.o.s.
3355 Insecticide gas, poisonous, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
3355 Insecticide gas, toxic, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
flammable, n.o.s
3355 Insecticide gas, toxic,
flammable, n.o.s.
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3355 Insecticide gas, toxic, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
3381 Poisonous by inhalation liquid, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
3381 Toxic by inhalation liquid, n.o.s.
3382 Poisonous by inhalation liquid, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)
3382 Toxic by inhalation liquid, n.o.s.
3383 Poisonous by inhalation liquid, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
flammable, n.o.s.
3383 Toxic by inhalation liquid,
flammable, n.o.s.
3384 Poisonous by inhalation liquid, 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)
flammable, n.o.s.
flammable, n.o.s.
water-reactive, n.o.s.
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First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
NIGHT
Kilometers (Miles)
DAY
Kilometers (Miles)
NAME OF MATERIAL
First
ISOLATE
in all Directions
Meters (Feet)
Then
PROTECT
DAY
Kilometers (Miles)
NIGHT
Kilometers (Miles)
ID
No.
oxidizing, n.o.s.
oxidizing, n.o.s.
3388 Poisonous by inhalation liquid, 30 m (100 ft) 0.4 km (0.2mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)
oxidizing, n.o.s.
oxidizing, n.o.s.
3389 Poisonous by inhalation liquid, 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)
corrosive, n.o.s.
corrosive, n.o.s.
corrosive, n.o.s.
corrosive, n.o.s.
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See Next Page for Table of Water-Reactive Materials Which Produce Toxic Gases
3461 Aluminum alkyl halides, solid 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)
9191 Chlorine dioxide, hydrate, frozen 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi)
9192 Fluorine, refrigerated liquid 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi)
(cryogenic liquid)
9202 Carbon monoxide, refrigerated 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi)
liquid (cryogenic liquid)
9206 Methyl phosphonic dichloride 30 m (100 ft) 0.1km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi)
9263 Chloropivaloyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
9264 3,5-Dichloro-2,4,6- 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)
trifluoropyridine
9269 Trimethoxysilane 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 2.2 km (1.4 mi)
Chemi cal Symbol s f or TI H Gases:
Br
2
Br omi ne
Cl
2
Chl or i ne
HBr Hydr ogen br omi de
HCl Hydr ogen chl or i de
HCN Hydr ogen cyani de
HF Hydr ogen f l uor i de
HI Hydr ogen i odi de
H
2
S Hydr ogen sul f i de
H
2
S Hydr ogen sul phi de
NH
3
Ammoni a
PH
3
Phosphi ne
SO
2
Sul f ur di oxi de
SO
2
Sul phur di oxi de
SO
3
Sul f ur t r i oxi de
SO
3
Sul phur t r i oxi de
I D Guide TI H Gas(es)
No. No. Name of Materi al Produced
Materi al s Whi ch Produce Large Amounts of Toxi c-by-I nhal ati on (TI H) Gas(es)
When Spi l l ed i n Water
TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES
Us e t h i s l i s t o n l y wh en mat er i al i s s p i l l ed i n wat er .
Page 344
1162 155 Dimethyldichlorosilane HCl
1196 155 Ethyltrichlorosilane HCl
1242 139 Methyldichlorosilane HCl
1250 155 Methyltrichlorosilane HCl
1295 139 Trichlorosilane HCl
1298 155 Trimethylchlorosilane HCl
1305 155P Vinyltrichlorosilane HCl
1305 155P Vinyltrichlorosilane, inhibited HCl
1305 155P Vinyltrichlorosilane, stabilized HCl
1340 139 Phosphorus pentasulfide, free from yellow and white Phosphorus H
2
S
1340 139 Phosphorus pentasulphide, free from yellow and white Phosphorus H
2
S
1360 139 Calcium phosphide PH
3
1384 135 Sodium dithionite H
2
S SO
2
1384 135 Sodium hydrosulfite H
2
S SO
2
1384 135 Sodium hydrosulphite H
2
S SO
2
1397 139 Aluminum phosphide PH
3
1412 139 Lithium amide NH
3
1419 139 Magnesium aluminum phosphide PH
3
1432 139 Sodium phosphide PH
3
1541 155 Acetone cyanohydrin, stabilized HCN
1680 157 Potassium cyanide HCN
1680 157 Potassium cyanide, solid HCN
1689 157 Sodium cyanide HCN
1689 157 Sodium cyanide, solid HCN
Br
2
Br omi ne
Cl
2
Chl or i ne
H
2
H
2
NH
3
Ammoni a
PH
3
Phosphi ne
SO
2
Sul f ur di oxi de
SO
2
Sul phur di oxi de
SO
3
SO
3
Page 345
1716 156 Acetyl bromide HBr
1717 155 Acetyl chloride HCl
1724 155 Allyltrichlorosilane, stabilized HCl
1725 137 Aluminum bromide, anhydrous HBr
1726 137 Aluminum chloride, anhydrous HCl
1728 155 Amyltrichlorosilane HCl
1732 157 Antimony pentafluoride HF
1745 144 Bromine pentafluoride HF Br
2
1746 144 Bromine trifluoride HF Br
2
1747 155 Butyltrichlorosilane HCl
1752 156 Chloroacetyl chloride HCl
1754 137 Chlorosulfonic acid HCl
1754 137 Chlorosulfonic acid and Sulfur trioxide mixture HCl
1754 137 Chlorosulphonic acid HCl
1754 137 Chlorosulphonic acid and Sulphur trioxide mixture HCl
1754 137 Sulfur trioxide and Chlorosulfonic acid HCl
1754 137 Sulphur trioxide and Chlorosulphonic acid HCl
1758 137 Chromium oxychloride HCl
1763 156 Cyclohexyltrichlorosilane HCl
1766 156 Dichlorophenyltrichlorosilane HCl
1767 155 Diethyldichlorosilane HCl
1769 156 Diphenyldichlorosilane HCl
1771 156 Dodecyltrichlorosilane HCl
1777 137 Fluorosulfonic acid HF
Br
2
Br omi ne
Cl
2
Chl or i ne
H
2
H
2
NH
3
Ammoni a
PH
3
Phosphi ne
SO
2
Sul f ur di oxi de
SO
2
Sul phur di oxi de
SO
3
SO
3
Page 346
1777 137 Fluorosulphonic acid HF
1784 156 Hexyltrichlorosilane HCl
1799 156 Nonyltrichlorosilane HCl
1800 156 Octadecyltrichlorosilane HCl
1801 156 Octyltrichlorosilane HCl
1804 156 Phenyltrichlorosilane HCl
1806 137 Phosphorus pentachloride HCl
1809 137 Phosphorus trichloride HCl
1810 137 Phosphorus oxychloride HCl
1816 155 Propyltrichlorosilane HCl
1818 157 Silicon tetrachloride HCl
1828 137 Sulfur chlorides HCl SO
2
H
2
S
1828 137 Sulphur chlorides HCl SO
2
H
2
S
1834 137 Sulfuryl chloride HCl SO
3
1834 137 Sulphuryl chloride HCl SO
3
1836 137 Thionyl chloride HCl SO
2
1838 137 Titanium tetrachloride HCl
1898 156 Acetyl iodide HI
1923 135 Calcium dithionite H
2
S SO
2
1923 135 Calcium hydrosulfite H
2
S SO
2
1923 135 Calcium hydrosulphite H
2
S SO
2
1931 171 Zinc dithionite H
2
S SO
2
1931 171 Zinc hydrosulfite H
2
S SO
2
1931 171 Zinc hydrosulphite H
2
S SO
2
Br
2
Br omi ne
Cl
2
Chl or i ne
H
2
H
2
NH
3
Ammoni a
PH
3
Phosphi ne
SO
2
Sul f ur di oxi de
SO
2
Sul phur di oxi de
SO
3
SO
3
Page 347
2004 135 Magnesium diamide NH
3
2011 139 Magnesium phosphide PH
3
2012 139 Potassium phosphide PH
3
2013 139 Strontium phosphide PH
3
2437 156 Methylphenyldichlorosilane HCI
2495 144 Iodine pentafluoride HF
2691 137 Phosphorus pentabromide HBr
2692 157 Boron tribromide HBr
2806 138 Lithium nitride NH
3
2977 166 Radioactive material, Uranium hexafluoride, fissile HF
2977 166 Uranium hexafluoride, fissile containing more than 1% HF
Uranium-235
2978 166 Radioactive material, Uranium hexafluoride HF
2978 166 Radioactive material, Uranium hexafluoride, non-fissile or HF
fissile-excepted
2978 166 Uranium hexafluoride HF
2978 166 Uranium hexafluoride, fissile-excepted HF
2978 166 Uranium hexafluoride, low specific activity HF
2978 166 Uranium hexafluoride, non-fissile HF
2985 155 Chlorosilanes, flammable, corrosive, n.o.s. HCl
2985 155 Chlorosilanes, n.o.s. HCl
2986 155 Chlorosilanes, corrosive, flammable, n.o.s. HCl
2987 156 Chlorosilanes, corrosive, n.o.s. HCl
Br
2
Br omi ne
Cl
2
Chl or i ne
H
2
H
2
NH
3
Ammoni a
PH
3
Phosphi ne
SO
2
Sul f ur di oxi de
SO
2
Sul phur di oxi de
SO
3
SO
3
Page 348
2988 139 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. HCl
3048 157 Aluminum phosphide pesticide PH
3
3049 138 Metal alkyl halides, n.o.s. HCl
3049 138 Metal alkyl halides, water-reactive, n.o.s. HCl
3049 138 Metal aryl halides, n.o.s. HCl
3049 138 Metal aryl halides, water-reactive, n.o.s. HCl
3052 135 Aluminum alkyl halides HCl
3052 135 Aluminum alkyl halides, liquid HCl
3052 135 Aluminum alkyl halides, solid HCl
3461 135 Aluminum alkyl halides, solid HCl
9191 143 Chlorine dioxide, hydrate, frozen Cl
2
Br
2
Br omi ne
Cl
2
Chl or i ne
H
2
H
2
NH
3
Ammoni a
PH
3
Phosphi ne
SO
2
Sul f ur di oxi de
SO
2
Sul phur di oxi de
SO
3
SO
3
Page 349
P PP PPage I nt ent i onal l y Lef t Bl ank age I nt ent i onal l y Lef t Bl ank age I nt ent i onal l y Lef t Bl ank age I nt ent i onal l y Lef t Bl ank age I nt ent i onal l y Lef t Bl ank
Page 350
PROTECTIVE CLOTHING
Street Clothing and Work Uniforms. These garments, such as uniforms worn by police and
emergency medical services personnel, provide almost no protection from the harmful effects of
dangerous goods.
Structural Fire Fighters Protective Clothing (SFPC). This category of clothing, often
called turnout or bunker gear, means the protective clothing normally worn by fire fighters
during structural fire fighting operations. It includes a helmet, coat, pants, boots, gloves and
a hood to cover parts of the head not protected by the helmet and facepiece. This clothing
must be used with full-facepiece positive pressure self-contained breathing apparatus (SCBA).
This protective clothing should, at a minimum, meet the OSHA Fire Brigades Standard (29
CFR 1910.156). Structural fire fighters protective clothing provides limited protection from
heat and cold, but may not provide adequate protection from the harmful vapors or liquids
that are encountered during dangerous goods incidents. Each guide includes a statement
about the use of SFPC in incidents involving those materials referenced by that guide. Some
guides state that SFPC provides limited protection. In those cases, the responder wearing
SFPC and SCBA may be able to perform an expedient, that is quick in-and-out, operation.
However, this type of operation can place the responder at risk of exposure, injury or death.
The incident commander makes the decision to perform this operation only if an overriding
benefit can be gained (i.e., perform an immediate rescue, turn off a valve to control a leak,
etc.). The coverall-type protective clothing customarily worn to fight fires in forests or wildlands
is not SFPC and is not recommended nor referred to elsewhere in this guidebook.
Positive Pressure Self-Contained Breathing Apparatus (SCBA). This apparatus provides
a constant, positive pressure flow of air within the facepiece, even if one inhales deeply while
doing heavy work. Use apparatus certified by NIOSH and the Department of Labor/Mine
Safety and Health Administration in accordance with 42 CFR Part 84. Use it in accordance
with the requirements for respiratory protection specified in OSHA 29 CFR 1910.134
(Respiratory Protection) and/or 29 CFR 1910.156 (f) (Fire Brigades Standard). Chemical-
cartridge respirators or other filtering masks are not acceptable substitutes for positive pressure
self-contained breathing apparatus. Demand-type SCBA does not meet the OSHA 29 CFR
1910.156 (f)(1)(i) of the Fire Brigades Standard.
Chemical Protective Clothing and Equipment. Safe use of this type of protective clothing
and equipment requires specific skills developed through training and experience. It is
generally not available to, or used by, first responders. This type of special clothing may
protect against one chemical, yet be readily permeated by chemicals for which it was not
designed. Therefore, protective clothing should not be used unless it is compatible with the
released material. This type of special clothing offers little or no protection against heat and/
or cold. Examples of this type of equipment have been described as (1) Vapor Protective Suits
(NFPA 1991), also known as Totally-Encapsulating Chemical Protective (TECP) Suits or Level
A* protection (OSHA 29 CFR 1910.120, Appendix A & B), and (2) Liquid-Splash Protective Suits
(NFPA 1992 & 1993), also known as Level B* or C* protection (OSHA 29 CFR 1910.120,
Page 351
Appendix A & B) or suits for chemical/biological terrorism incidents (NFPA 1994), class 1, 2 or 3
Ensembles. No single protective clothing material will protect you from all dangerous goods. Do
not assume any protective clothing is resistant to cold and/or heat or flame exposure unless it is
so certified by the manufacturer. (NFPA 1991 5-3 Flammability Resistance Test and 5-6 Cold
Temperature Performance Test)
* Consult glossary for additional protection levels under the heading Protective Clothing.
Page 352
FIRE AND SPILL CONTROL
FIRE CONTROL
Water is the most common and generally most available fire extinguishing agent. Exercise
caution in selecting a fire extinguishing method since there are many factors to be considered
in an incident. Water may be ineffective in fighting fires involving some materials; its
effectiveness depends greatly on the method of application.
Spill fires involving flammable liquids are generally controlled by applying a fire fighting foam
to the surface of the burning material. Fighting flammable liquid fires requires foam concentrate
which is chemically compatible with the burning material, correct mixing of the foam concentrate
with water and air, and careful application and maintenance of the foam blanket. There are
two general types of fire fighting foam: regular and alcohol-resistant. Examples of regular
foam are protein-base, fluoroprotein, and aqueous film forming foam (AFFF). Some flammable
liquids, including many petroleum products, can be controlled by applying regular foam.
Other flammable liquids, including polar solvents (flammable liquids which are water soluble)
such as alcohols and ketones, have different chemical properties. A fire involving these
materials cannot be easily controlled with regular foam and requires application of
alcohol-resistant foam. Polar-solvent fires may be difficult to control and require a higher
foam application rate than other flammable liquid fires (see NFPA/ANSI Standards 11 and
11A for further information). Refer to the appropriate guide to determine which type of foam
is recommended. Although it is impossible to make specific recommendations for flammable
liquids which have subsidiary corrosive or toxic hazards, alcohol-resistant foam may be
effective for many of these materials. The emergency response telephone number on the
shipping document, or the appropriate emergency response agency, should be contacted as
soon as possible for guidance on the proper fire extinguishing agent to use. The final selection
of the agent and method depends on many factors such as incident location, exposure hazards,
size of the fire, environmental concerns, as well as the availability of extinguishing agents
and equipment at the scene.
WATER REACTIVE MATERIALS
Water is sometimes used to flush spills and to reduce or direct vapors in spill situations.
Some of the materials covered by the guidebook can react violently or even explosively with
water. In these cases, consider letting the fire burn or leaving the spill alone (except to
prevent its spreading by diking) until additional technical advice can be obtained. The
applicable guides clearly warn you of these potentially dangerous reactions. These materials
require technical advice since
(1) water getting inside a ruptured or leaking container may cause an explosion;
(2) water may be needed to cool adjoining containers to prevent their rupturing
(exploding) or further spread of the fires;
(3) water may be effective in mitigating an incident involving a water-reactive material
only if it can be applied at a sufficient flooding rate for an extended period; and
Page 353
(4) the products from the reaction with water may be more toxic, corrosive, or
otherwise more undesirable than the product of the fire without water applied.
When responding to an incident involving water-reactive chemicals, take into account the
existing conditions such as wind, precipitation, location and accessibility to the incident, as
well as the availability of the agents to control the fire or spill. Because there are variables to
consider, the decision to use water on fires or spills involving water-reactive materials should
be based on information from an authoritative source; for example, a producer of the material,
who can be contacted through the emergency response telephone number or the appropriate
emergency response agency.
VAPOR CONTROL
Limiting the amount of vapor released from a pool of flammable or corrosive liquids is an
operational concern. It requires the use of proper protective clothing, specialized equipment,
appropriate chemical agents, and skilled personnel. Before engaging in vapor control, get
advice from an authoritative source as to the proper tactics.
There are several ways to minimize the amount of vapors escaping from pools of spilled
liquids, such as special foams, adsorbing agents, absorbing agents, and neutralizing agents.
To be effective, these vapor control methods must be selected for the specific material involved
and performed in a manner that will mitigate, not worsen, the incident.
Where specific materials are known, such as at manufacturing or storage facilities, it is
desirable for the dangerous goods response team to prearrange with the facility operators to
select and stockpile these control agents in advance of a spill. In the field, first responders
may not have the most effective vapor control agent for the material available. They are
likely to have only water and only one type of fire fighting foam on their vehicles. If the
available foam is inappropriate for use, they are likely to use water spray. Because the water
is being used to form a vapor seal, care must be taken not to churn or further spread the spill
during application. Vapors that do not react with water may be directed away from the site
using the air currents surrounding the water spray. Before using water spray or other methods
to safely control vapor emission or to suppress ignition, obtain technical advice, based on
specific chemical name identification.
Page 354
CRIMINAL/TERRORIST USE OF CHEMICAL/BIOLOGICAL/RADIOLOGICAL AGENTS
The following is intended to supply information to first responders for use in making a preliminary
assessment of a situation that they suspect involves criminal/terrorist use of chemical, biological
(CB) agents and/or radioactive materials. To aid in the assessment, a list of observable indicators
of the use and/or presence of a CB agent or radioactive material is provided in the following
paragraphs.
DIFFERENCES BETWEEN A CHEMICAL, BIOLOGICAL AND RADIOLOGICAL AGENT
Chemical and biological agents as well as radioactive materials can be dispersed in the air we
breathe, the water we drink, or on surfaces we physically contact. Dispersion methods may be
as simple as opening a container, using conventional (garden) spray devices, or as elaborate as
detonating an improvised explosive device.
Chemical Incidents are characterized by the rapid onset of medical symptoms (minutes to
hours) and easily observed signatures (colored residue, dead foliage, pungent odor, dead
insects and animals).
Biological Incidents are characterized by the onset of symptoms in hours to days. Typically,
there will be no characteristic signatures because biological agents are usually odorless and
colorless. Because of the delayed onset of symptoms in a biological incident, the area
affected may be greater due to the movement of infected individuals.
Radiological Incidents are characterized by the onset of symptoms, if any, in days to weeks or
longer. Typically, there will be no characteristic signatures because radioactive materials are
usually odorless and colorless. Specialized equipment is required to determine the size of the
affected area, and whether the level of radioactivity presents an immediate or long-term health
hazard. Because radioactivity is not detectable without special equipment, the affected area may
be greater due to the migration of contaminated individuals.
At the levels created by most probable sources, not enough radiation would be generated to kill
people or cause severe illness. In a radiological incident generated by a dirty bomb, or
Radiological Dispersal Device (RDD), in which a conventional explosive is detonated to spread
radioactive contamination, the primary hazard is from the explosion. However, certain radioactive
materials dispersed in the air could contaminate up to several city blocks, creating fear and
possibly panic, and requiring potentially costly cleanup.
INDICATORS OF A POSSIBLE CHEMICAL INCIDENT
Dead animals/birds/fish Not just an occasional road kill, but numerous animals (wild
and domestic, small and large), birds, and fish in the same
area.
Page 355
INDICATORS OF A POSSIBLE CHEMICAL INCIDENT (Continued)
Lack of insect life If normal insect activity (ground, air, and/or water) is missing,
check the ground/water surface/shore line for dead insects.
If near water, check for dead fish/aquatic birds.
Unexplained odors Smells may range from fruity to flowery to sharp/pungent to
garlic/ horseradish-like to bitter almonds/peach kernels to
new mown hay. It is important to note that the particular odor
is completely out of character with its surroundings.
Unusual numbers of dying or Health problems including nausea, disorientation, difficulty
sick people (mass casualties) in breathing, convulsions, localized sweating, conjunctivitis
(reddening of eyes/nerve agent symptoms), erythema
(reddening of skin/vesicant symptoms) and death.
Pattern of casualties Casualties will likely be distributed downwind, or if indoors,
by the air ventilation system.
Blisters/rashes Numerous individuals experiencing unexplained water-like
blisters, weals (like bee stings), and/or rashes.
Illness in confined area Different casualty rates for people working indoors versus
outdoors dependent on where the agent was released.
Unusual liquid droplets Numerous surfaces exhibit oily droplets/film; numerous water
surfaces have an oily film. (No recent rain.)
Different looking areas Not just a patch of dead weeds, but trees, shrubs, bushes,
food crops, and/or lawns that are dead, discolored, or
withered. (No current drought.)
Low-lying clouds Low-lying cloud/fog-like condition that is not consistent with
its surroundings.
Unusual metal debris Unexplained bomb/munitions-like material, especially if it
contains a liquid.
INDICATORS OF A POSSIBLE BIOLOGICAL INCIDENT
Unusual numbers of sick or Any number of symptoms may occur. Casualties may
dying people or animals occur hours to days after an incident has occurred. The
time required before symptoms are observed is dependent
on the agent used.
Unscheduled and unusual Especially if outdoors during periods of darkness.
spray being disseminated
Abandoned spray devices Devices may not have distinct odors.
Page 356
INDICATORS OF A POSSIBLE RADIOLOGICAL INCIDENT
Radiation Symbols Containers may display a propeller radiation symbol.
Unusual metal debris Unexplained bomb/munitions-like material.
Heat-emitting material Material that is hot or seems to emit heat without any sign of
an external heat source.
Glowing material Strongly radioactive material may emit or cause
radioluminescence.
Sick people/animals In very improbable scenarios there may be unusual numbers
of sick or dying people or animals. Casualties may occur
hours to days or weeks after an incident has occurred. The
time required before symptoms are observed is dependent
on the radioactive material used, and the dose received.
Possible symptoms include skin reddening or vomiting.
PERSONAL SAFETY CONSIDERATIONS
When approaching a scene that may involve CB agents or radioactive materials, the most critical
consideration is the safety of oneself and other responders. Protective clothing and respiratory
protection of appropriate level of safety must be used. Be aware that the presence and identification
of CB or radioactive materials may not be verifiable, especially in the case of biological or
radiological agents. The following actions/measures to be considered are applicable to either a
chemical, biological or radiological incident. The guidance is general in nature, not all
encompassing, and its applicability should be evaluated on a case-by-case basis.
Approach and response strategies. Protect yourself and use a safe approach (minimize any
exposure time, maximize the distance between you and the item that is likely to harm you, use
cover as protection and wear appropriate personal protective equipment and respiratory
protection). Identify and estimate the hazard by using indicators as provided above. Isolate the
area and secure the scene; potentially contaminated people should be isolated and decontaminated
as soon as possible. To the extent possible, take measures to limit the spread of contamination.
In the event of a chemical incident, the fading of chemical odors is not necessarily an indication of
reduced vapor concentrations. Some chemicals deaden the senses giving the false perception
that the chemical is no longer present.
If there is any indication that an area may be contaminated with radioactive materials, including the
site of any non-accidental explosion, responder personnel should be equipped with radiation
detection equipment that would alert them if they are entering a radiologically compromised
environment, and should have received adequate training in its use. This equipment should be
designed in such a way that it can also alert the responders when an unacceptable ambient dose
rate or ambient dose has been reached.
Page 357
Decontamination measures. Emergency responders should follow standard decontamination
procedures (flush-strip-flush). Mass casualty decontamination should begin as soon as possible
by stripping (all clothing) and flushing (soap and water). If biological agents are involved or
suspected, careful washing and use of a brush are more effective. If chemical agents are
suspected, the most important and effective decontamination will be that done within the first one or
two minutes. If possible, further decontamination should be performed using a 0.5% hypochlorite
solution (1 part household bleach mixed with 9 parts water). If biological agents are suspected,
a contact time of 10 to 15 minutes should be allowed before rinsing. The solution can be used on
soft tissue wounds, but must not be used in eyes or open wounds of the abdomen, chest, brain,
or spine. For further information contact the agencies listed in this guidebook.
For persons contaminated with radioactive material, remove them to a low radiation area if
necessary. Remove their clothing and place it in a clearly marked sealed receptacle, such as a
plastic bag, for later testing. Use decontamination methods described above, but avoid breaking
the skin, e.g., from shaving, or overly vigorous brushing. External radiological contamination on
intact skin surface rarely causes a high enough dose to be a hazard to either the contaminated
person or the first responders. For this reason, except in very unusual circumstances, an injured
person who is also radiologically contaminated should be medically stabilized, taking care to
minimize the spread of the contamination to the extent possible, before decontamination measures
are initiated.
NOTE: The above information was developed in part by the Department of National Defence
(Canada) and the U.S. Department of the Army, Edgewood Arsenal.
Page 358
Glossary
Alcohol resistant foam A foam that is resistant to polar chemicals such as ketones and
esters which may break down other types of foam.
Biological agents Living organisms that cause disease, sickness and mortality in
humans. Anthrax and Ebola are examples of biological agents.
Refer to GUIDE 158.
Blister agents (vesicants) Substances that cause blistering of the skin. Exposure is through
liquid or vapor contact with any exposed tissue (eyes, skin, lungs).
Mustard (H), Distilled Mustard (HD), Nitrogen Mustard (HN) and
Lewisite (L) are blister agents.
Symptoms: Red eyes, skin irritation, burning of skin, blisters,
upper respiratory damage, cough, hoarseness.
Blood agents Substances that injure a person by interfering with cell respiration
(the exchange of oxygen and carbon dioxide between blood and
tissues). Hydrogen cyanide (AC) and Cyanogen chloride (CK)
are blood agents.
Symptoms: Respiratory distress, headache, unresponsiveness,
seizures, coma.
Burn Refers to either a chemical or thermal burn, the former may be
caused by corrosive substances and the latter by liquefied
cryogenic gases, hot molten substances, or flames.
Choking agents Substances that cause physical injury to the lungs. Exposure is
through inhalation. In extreme cases, membranes swell and lungs
become filled with liquid (pulmonary edema). Death results from
lack of oxygen; hence, the victim is choked. Phosgene (CG) is
a choking agent.
Symptoms: irritation to eyes/nose/throat, respiratory distress,
nausea and vomiting, burning of exposed skin.
CO
2
Carbon dioxide gas.
Cold zone Area where the command post and support functions that are
necessary to control the incident are located. This is also referred
to as the clean zone, green zone or support zone in other documents.
(EPA Standard Operating Safety Guidelines, OSHA 29 CFR
1910.120, NFPA 472)
Page 359
Glossary
Combustible liquid Liquids which have a flash point greater than 60.5
o
C (141
o
F) and
below 93
o
C (200
o
F). U.S. regulations permit a flammable liquid
with a flash point between 38
o
C (100
o
F) and 60.5
o
C (141
o
F) to be
reclassed as a combustible liquid.
Compatibility Group Letters identify explosives that are deemed to be compatible. Class
1 materials are considered to be compatible if they can be
transported together without significantly increasing either the
probability of an incident or, for a given quantity, the magnitude
of the effects of such an incident.
A Substances which are expected to mass detonate very
soon after fire reaches them.
B Articles which are expected to mass detonate very soon
after fire reaches them.
C Substances or articles which may be readily ignited and
burn violently without necessarily exploding.
D Substances or articles which may mass detonate (with
blast and/or fragment hazard) when exposed to fire.
E&F Articles which may mass detonate in a fire.
G Substances and articles which may mass explode and
give off smoke or toxic gases.
H Articles which in a fire may eject hazardous projectiles and
dense white smoke.
J Articles which may mass explode.
K Articles which in a fire may eject hazardous projectiles and
toxic gases.
L Substances and articles which present a special risk and
could be activated by exposure to air or water.
N Articles which contain only extremely insensitive
detonating substances and demonstrate a negligible
probability of accidental ignition or propagation.
S Packaged substances or articles which, if accidentally
initiated, produce effects that are usually confined to the
immediate vicinity.
Page 360
Glossary
Control zones Designated areas at dangerous goods incidents, based on safety
and the degree of hazard. Many terms are used to describe control
zones; however, in this guidebook, these zones are defined as the
hot/exclusion/restricted zone, warm/contamination reduction/limited
access zone, and cold/support/clean zone. (EPA Standard
Operating Safety Guidelines, OSHA 29 CFR 1910.120, NFPA 472)
Cryogenic liquid A refrigerated, liquefied gas that has a boiling point colder than
-90
o
C (-130
o
F) at atmospheric pressure.
Dangerous Water Produces significant toxic gas when it comes in contact with water.
Reactive Material
Decomposition products Products of a chemical or thermal break-down of a substance.
Decontamination The removal of dangerous goods from personnel and equipment to
the extent necessary to prevent potential adverse health effects.
Always avoid direct or indirect contact with dangerous goods;
however, if contact occurs, personnel should be decontaminated as
soon as possible. Since the methods used to decontaminate personnel
and equipment differ from one chemical to another, contact the
chemical manufacturer, through the agencies listed on the inside
back cover, to determine the appropriate procedure. Contaminated
clothing and equipment should be removed after use and stored in
a controlled area (warm/contamination reduction/limited access zone)
until cleanup procedures can be initiated. In some cases, protective
clothing and equipment cannot be decontaminated and must be
disposed of in a proper manner.
Dry chemical A preparation designed for fighting fires involving flammable liquids,
pyrophoric substances and electrical equipment. Common types
contain sodium bicarbonate or potassium bicarbonate.
Edema The accumulation of an excessive amount of watery fluid in cells and
tissues. Pulmonary edema is an excessive buildup of water in the
lungs, for instance, after inhalation of a gas that is corrosive to lung
tissue.
ERPG(s) Emergency Response Planning Guideline(s). Values intended
to provide estimates of concentration ranges above which one
could reasonably anticipate observing adverse health effects;
see ERPG-1, ERPG-2 and ERPG-3.
Page 361
Glossary
ERPG-1 The maximum airborne concentration below which it is believed
nearly all individuals could be exposed for up to 1 hour without
experiencing more than mild, transient adverse health effects or
without perceiving a clearly defined objectionable odor.
experiencing or developing irreversible or other serious health
effects or symptoms that could impair an individuals ability to take
protective action.
experiencing or developing life-threatening health effects.
Flammable liquid A liquid that has a flash point of 60.5
o
C (141
o
F) or lower.
Flash point Lowest temperature at which a liquid or solid gives off vapor in such
a concentration that, when the vapor combines with air near the
surface of the liquid or solid, a flammable mixture is formed. Hence,
the lower the flash point, the more flammable the material.
Hazard zones (Inhalation HAZARD ZONE A: Gases: LC50 of less than or equal to 200
Hazard Zones) ppm,
Liquids: V equal to or greater than 500
LC50 and LC50 less than or equal to 200
ppm,
HAZARD ZONE B: Gases: LC50 greater than 200 ppm and
less than or equal to 1000 ppm,
Liquids: V equal to or greater than 10
LC50; LC50 less than or equal to 1000 ppm
and criteria for Hazard Zone A are not met.
HAZARD ZONE C: LC50 greater than 1000 ppm and less than or
equal to 3000 ppm,
HAZARD ZONE D: LC50 greater than 3000 ppm and less than or
equal to 5000 ppm.
Hot zone Area immediately surrounding a dangerous goods incident which
extends far enough to prevent adverse effects from released
dangerous goods to personnel outside the zone. This zone is also
referred to as exclusion zone, red zone or restricted zone in other
documents. (EPA Standard Operating Safety Guidelines, OSHA 29
CFR 1910.120, NFPA 472)
Page 362
Glossary
Immiscible In this guidebook, means that a material does not mix readily with water.
LC50 Lethal concentration 50. The concentration of a material administered
by inhalation that is expected to cause the death of 50% of an
experimental animal population within a specified time.
(Concentration is reported in either ppm or mg/m
3
)
Mass explosion Explosion which affects almost the entire load virtually
instantaneously.
mg/m
3
Milligrams of a material per cubic meter of air.
Miscible In this guidebook, means that a material mixes readily with water.
mL/m
3
Milliliters of a material per cubic meter of air. (1 mL/m
3
equals 1
ppm)
Nerve agents Substances that interfere with the central nervous system. Exposure
is primarily through contact with the liquid (via skin and eyes) and
secondarily through inhalation of the vapor. Tabun (GA), Sarin
(GB), Soman (GD) and VX are nerve agents.
Symptoms: Pinpoint pupils, extreme headache, severe tightness in
the chest, dyspnea, runny nose, coughing, salivation, unresponsiveness,
seizures.
Non-polar See Immiscible.
n.o.s. These letters refer to not otherwise specified. The entries which use
this description are generic names such as Corrosive liquid, n.o.s.
This means that the actual chemical name for that corrosive liquid is
not listed in the regulations; therefore, a generic name must be used
to describe it on shipping papers.
Noxious In this guidebook, means that a material may be harmful or injurious
to health or physical well-being.
Oxidizer A chemical which supplies its own oxygen and which helps other
combustible material burn more readily.
Page 363
P The letter P following a guide number in the yellow-bordered and
blue-bordered pages identifies a material which may polymerize
violently under high temperature conditions or contamination with
other products. This polymerization will produce heat and high
pressure buildup in containers which may explode or rupture. (See
polymerization below.)
pH pH is a value that represents the acidity or alkalinity of a water solution.
Pure water has a pH of 7. A pH value below 7 indicates an acid solution
(a pH of 1 is extremely acidic). A pH above 7 indicates an alkaline
solution (a pH of 14 is extremely alkaline). Acids and alkalies (bases)
are commonly referred to as corrosive materials.
PIH Poison Inhalation Hazard. Term used to describe gases and volatile
liquids that are toxic when inhaled. (Same as TIH)
Polar See Miscible.
Polymerization This term describes a chemical reaction which is generally associated
with the production of plastic substances. Basically, the individual
molecules of the chemical (liquid or gas) react with each other to
produce what can be described as a long chain. These chains can
be formed in many useful applications. A well known example is the
styrofoam (polystyrene) coffee cup which is formed when liquid
molecules of styrene react with each other or polymerize forming a
solid, therefore changing the name from styrene to polystyrene
(poly means many).
ppm Parts per million. (1 ppm equals 1 mL/m
3
)
Protective clothing Includes both respiratory and physical protection. One cannot assign
a level of protection to clothing or respiratory devices separately.
These levels were accepted and defined by response organizations
such as U.S. Coast Guard, NIOSH, and U.S. EPA.
Level A: SCBA plus totally encapsulating chemical resistant clothing
(permeation resistant).
Level B: SCBA plus hooded chemical resistant clothing (splash suit).
Level C: Full or half-face respirator plus hooded chemical resistant
clothing (splash suit).
Level D: Coverall with no respiratory protection.
Pyrophoric A material which ignites spontaneously upon exposure to air (or oxygen).
Glossary
Page 364
Glossary
Radioactivity The property of some substances to emit invisible and potentially
harmful radiation.
Radiation Authority As referred to in GUIDES 161 through 166 for radioactive materials,
the Radiation Authority is either a Federal, state/provincial agency
or state/province designated official. The responsibilities of this
authority include evaluating radiological hazard conditions during
normal operations and during emergencies. If the identity and
telephone number of the authority are not known by emergency
responders, or included in the local response plan, the information
can be obtained from the agencies listed on the inside back cover.
They maintain a periodically updated list of radiation authorities.
Refrigerated liquid See Cryogenic liquid.
Straight (solid) stream Method used to apply or distribute water from the end of a hose.
The water is delivered under pressure for penetration. In an efficient
straight (solid) stream, approximately 90% of the water passes
through an imaginary circle 38 cm (15 inches) in diameter at the
breaking point. Hose (solid or straight) streams are frequently used
to cool tanks and other equipment exposed to flammable liquid fires,
or for washing burning spills away from danger points. However,
straight streams will cause a spill fire to spread if improperly used or
when directed into open containers of flammable and combustible
liquids.
TIH Toxic Inhalation Hazard. Term used to describe gases and volatile
liquids that are toxic when inhaled. (Same as PIH)
V Saturated vapor concentration in air of a material in mL/m
3
(volatility)
at 20
o
C and standard atmospheric pressure.
Vapor density Weight of a volume of pure vapor or gas (with no air present)
compared to the weight of an equal volume of dry air at the same
temperature and pressure. A vapor density less than 1 (one) indicates
that the vapor is lighter than air and will tend to rise. A vapor density
greater than 1 (one) indicates that the vapor is heavier than air and
may travel along the ground.
Vapor pressure Pressure at which a liquid and its vapor are in equilibrium at a given
temperature. Liquids with high vapor pressures evaporate rapidly.
Page 365
Glossary
Viscosity Measure of a liquids internal resistance to flow. This property is
important because it indicates how fast a material will leak out through
holes in containers or tanks.
Warm zone Area between Hot and Cold zones where personnel and equipment
decontamination and hot zone support take place. It includes control
points for the access corridor and thus assists in reducing the spread
of contamination. Also referred to as the contamination reduction
corridor (CRC), contamination reduction zone (CRZ), yellow zone
or limited access zone in other documents. (EPA Standard Operating
Safety Guidelines, OSHA 29 CFR 1910.120, NFPA 472)
Water-sensitive Substances which may produce flammable and/or toxic
decomposition products upon contact with water.
Water spray (fog) Method or way to apply or distribute water. The water is finely
divided to provide for high heat absorption. Water spray patterns
can range from about 10 to 90 degrees. Water spray streams
can be used to extinguish or control the burning of a fire or to
provide exposure protection for personnel, equipment, buildings,
etc. (This method can be used to absorb vapors, knock-
down vapors or disperse vapors. Direct a water spray (fog),
rather than a straight (solid) stream, into the vapor cloud to
accomplish any of the above).
Water spray is particularly effective on fires of flammable liquids and
volatile solids having flash points above 37.8
o
C (100
o
F).
Regardless of the above, water spray can be used successfully on
flammable liquids with low flash points. The effectiveness depends
particularly on the method of application. With proper nozzles, even
gasoline spill fires of some types have been extinguished when
coordinated hose lines were used to sweep the flames off the surface
of the liquid. Furthermore, water spray carefully applied has frequently
been used with success in extinguishing fires involving flammable
liquids with high flash points (or any viscous liquids) by causing frothing
to occur only on the surface, and this foaming action blankets and
extinguishes the fire.
Page 366
PUBLICATION DATA
The 2004 Emergency Response Guidebook (ERG2004) was prepared by the staff of Transport
Canada, the U.S. Department of Transportation, and the Secretariat of Communications and
Transport of Mexico with the assistance of many interested parties from government and industry
including the collaboration of CIQUIME of Argentina. The principal authors of the ERG since its
inception have been Transport Canada's Michel Cloutier and U.S. DOT's George Cushmac.
ERG2004 is based on earlier Transport Canada, U.S. DOT, and Secretariat of Communications
and Transport emergency response guidebooks. ERG2004 is published in three languages:
English, French and Spanish. The Emergency Response Guidebook has been translated and
printed in other languages, including Chinese, German, Hebrew, Japanese, Portuguese, Korean,
Hungarian, Polish, Turkish and Thai.
We encourage countries that wish to participate in future editions of the Guidebook to provide their
emergency response center information for inclusion. Please contact any of the websites or
telephone numbers in the paragraph below.
DISTRIBUTION OF THIS GUIDEBOOK
The primary objective is to place one copy of the ERG2004 in each emergency service vehicle
through distribution to Federal, state, provincial and local public safety authorities. The distribution
of this guidebook is being accomplished through the voluntary cooperation of a network of key
agencies. Emergency service organizations that have not yet received copies of ERG2004
should contact the respective distribution center in their country, state or province. In the U.S.,
information about the distribution center for your location may be obtained from the Office of
Hazardous Materials Safety web site at http://hazmat.dot.gov or call 202-366-4900. In Canada,
contact CANUTEC at 613-992-4624 or via the web site at http://www.canutec.gc.ca for information.
In Mexico, call SCT at 52-555-684-1275 or 684-0188 or via email at iflores@sct.gob.mx. In
Argentina, call CIQUIME at 011-4613-1100, or via the web site at http://www.ciquime.org.ar, or
via email at erg2004@ciquime.org.ar
REPRODUCTION and RESALE
Copies of this document which are provided free of charge to fire, police and other emergency
services may not be resold. ERG2004 (RSPA P 5800.9) may be reproduced without further
permission subject to the following:
The names and the seals of the participating governments may not be
reproduced on a copy of this document unless that copy accurately reproduces
the entire content (text, format, and coloration) of this document without
modification. In addition, the publishers full name and address must be
displayed on the outside back cover of each copy, replacing the wording
placed on the center of the back cover.
Page 367
Constructive comments concerning ERG2004 are solicited; in particular, comments concerning its
use in handling incidents involving dangerous goods. Comments should be addressed to:
In Canada:
Director, CANUTEC
Transport Dangerous Goods
Transport Canada
Ottawa, Ontario
Canada K1A 0N5
Phone: 613-992-4624 (information)
FAX: 613-954-5101
Email: canutec@tc.gc.ca
In the U.S.:
U. S. Department of Transportation
Office of Hazardous Materials Initiatives and Training (DHM-50)
Washington, DC 20590-0001
Phone: 202-366-4900
FAX: 202-366-7342
Email: welisten@rspa.dot.gov
In Mexico:
Secretariat for Communications and Transport
Land Transport Directorate
Hazardous Materials and Wastes Directorate
Calz. de las Bombas No. 411-9 piso
Col. San Bartolo Coapa
Coyoacan 04800, D.F.
Mexico
Phone and FAX: 52-555-684-1275 and 684-0188
In Argentina:
Information Center for Chemical Emergencies (CIQUIME)
Juan Bautista Alberdi 2986
C1406GSS Buenos Aires, Argentina
Tel. (011) 4613-1100 Fax (011) 4613-3707
Email: erg2004@ciquime.org.ar
Page 368
NOTES
Page 369
The Emergency Response Guidebook is normally revised and reissued every four years.
However, in the event of a significant mistake, omission or change in the state of knowledge,
special instructions to change the guidebook (in pen-and-ink, with paste-over stickers, or
with a supplement) may be issued.
Users of this guidebook should check periodically (about every 6 months) to make sure their
version is current. Changes should be annotated below. Contact:
DOT/RSPA
http://hazmat.dot.gov/gydebook.htm
TRANSPORT CANADA
http://www.tc.gc.ca/canutec/en/guide/guide.htm
CIQUIME
http://www.ciquime.org.ar
This guidebook incorporates changes dated:
Page 370
EMERGENCY RESPONSE TELEPHONE NUMBERS
MEXICO
1. SETIQ
5559-1588
011-52-555-559-1588
2. CENACOM
5550-1496, 5550-1552. 5550-1485 or 5550-4885
011-52-555-550-1496, or 011-52-555-550-1552
011-52-555-550-1485, or 011-52-555-550-4885
ARGENTINA
1. CIQUIME
0-800-222-2933 in the Republic of Argentina
+54-11-4613-1100
BRAZIL
1. PR-QUMICA
0-800-118270
(Toll-free in Brazil)
+55-11-232-1144
(Collect calls are accepted)
COLOMBIA
1. CISPROQUIM
01-800-091-6012 in Colombia
For calls originating in Bogot, Colombia call
288-6012
For calls originating elsewhere call
011-57-1-288-6012
For additional details see the section entiitled "WHO TO CALL FOR ASSISTANCE."
EMERGENCY CONTACT
1-000-000-0000
NO. & TYPE
OF PACKAGES
QUANTITY
DESCRIPTION OF
ARTICLES
1 TANK TRUCK ISOPROPANOL 3 UN1219 II 3,000 LITERS
EXAMPLE OF EMERGENCY
RESPONSE TELEPHONE NUMBER
HAZARD CLASS
OR DIVISION NO.
SHIPPING NAME ID NUMBER PACKING GROUP
SHIPPING DOCUMENTS (PAPERS)*
The shipping document provides vital information when responding to a
hazardous materials/dangerous goods** incident. The shipping document
contains information needed to identify the materials involved. Use this
information to initiate protective actions for your own safety and the safety
of the public. The shipping document contains the proper shipping name
(see blue-bordered pages), the hazard class or division of the material(s),
ID number (see yellow-bordered pages), and, where appropriate, the
Packing Group. In addition, there must be information available that
describes the hazards of the material which can be used in the mitigation
of an incident. The information must be entered on or be with the shipping
document. This requirement may be satisfied by attaching a guide from the
ERG2004 to the shipping document, or by having the entire guidebook
available for ready reference. Shipping documents are required for most
dangerous goods in transportation. Shipping documents are kept in
the cab of the motor vehicle,
the possession of the train crew member,
a holder on the bridge of a vessel, or
an aircraft pilots possession.
The 4-digit ID Number may be shown on the diamond-shaped placard or on
an adjacent orange panel displayed on the ends and sides of a cargo tank,
vehicle or rail car.
* For the purposes of this book, the terms shipping document/shipping paper are synonymous.
** For the purposes of this book, the terms hazardous materials/dangerous goods are synonymous.
EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER
or A Numbered
Placard
A Placard
and an
Orange Panel
1219
1219
FLAMMABLE
EnglishCover2004.qxd 9/8/2004 8:51 AM Page 2
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G
U
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B
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Secretariat of Transport and Communications
Transport Transports
Canada Canada
Safety and Security
THIS DOCUMENT SHOULD NOT BE USED TO
DETERMINE COMPLIANCE WITH THE
DANGEROUS GOODS REGULATIONS
OR
TO CREATE WORKER SAFETY DOCUMENTS
FOR SPECIFIC CHEMICALS
U.S. Department of Transportation
N O T F O R S A L E
This document is distributed free of charge to Public Safety Organizations
and may not be resold.
2004
A GUIDEBOOK FOR
FIRST RESPONDERS
DURING THE INITIAL PHASE
OF A DANGEROUS GOODS/
HAZARDOUS MATERIALS
INCIDENT
Emergency
Response
Guidebook

Erg 2004

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, a 24-hour emergency response communication service, can be reached as follows:

, CHEM-TEL, INC., INFOTRAC

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