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Basic Competence
Indicator
principle of LCAO
To distinguish the orbital bonding, non bonding, and antibonding
To write electron configurations in the molecular orbitals
To determine the energy level and frequency of electronic
transitions using the method of Huckel
To describe the current developments of molecular orbital
theory.
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WORKSHEET 009
Repeat this case by putting the electron in different locations, i.e. on the right location,
on the left location, or in location between of the two protons.
Describe where the location of electron so that their interactions caused both hydrogen
atom cores or protons move closer with each other.
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Summarize the position of electron density distribution in chemical bonding.
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4. a. Draw a chemical bonding model of hydrogen molecular ion with two thick black dots
mark each hydrogen nucleus A and B which is connected by the line R. Electron
positioned at the location between the two hydrogen nuclei which connected to point A
with rA line and to point B with rB line.
When a force drown from point A to the electron and also from point B towards the
electron, then explain what the point A (the core of the first hydrogen atom) and point B
(the core of the second hydrogen atom) will toward each other or away from each other.
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b. Write down in detail the Schrodinger equation to solve the case on the model 4.a.
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c. Explain why the equation resulting in 4.b. is difficult to be solved.
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d. Explain what Born-Oppenheimer assumed to resolve cases 4.a. which can be formulated
in the 4.b.
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e. What is the formulation of equation developed by Born-Oppenheimer as a result of the
simplification of the Schrodinger equation obtained from section 4.b.
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