Assumptions 1) Steady state therefore 2) Well mixed therefore r A is the same throughout the reactor
Rearranging the generation
In terms of conversion
Reactors in Series Given -r A as a function of conversion, , -r A = f(X), one can also design any sequence of reactors in series provided there are no side streams by defining the overall conversion at any point.
Mole Balance on Reactor 1
Mole Balance on Reactor 2
Given -r A = f(X) the Levenspiel Plot can be used to find the reactor volume
For a PFR between two CSTRs
Reactor 2 Reactor 1 Reactor 3 Effect of Step Change in Input Concentration to the Concentration of Solute in Stirred Tank Reactors in Series. When a step change of solute concentration is introduced at the feed of tank 1, the tank in series will experience a transient behavior as a Figure 7 below. The response will be dependent on the residence time of each reactor in series.
Concentration Concentration
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Time Time
Figure 1a: Step change input Figure 1b: Transient response of tank in series to the step input.
Effect of Pulse in Input Concentration to the Concentration of Solute in Stirred Tank in Series. When a pulse input of solute concentration is introduced at the feed of tank 1, the transient behavior will be different than the step change input due to the diminishing concentration from the input after pulsing as described in Figure 2.
Time Time
Figure 2a: Pulse input Figure 2b: Transient response of tank in series to the pulse input Reactor 1 Reactor 2 Reactor 3 C o n c e n t r a t i o n
C o n c e n t r a t i o n
PROCEDURES
Experiment 1: The Effect of Step Change Input
In this experiment a step-change input would be introduced and the progression of the tracer will be monitored via the conductivity measurements in all the three reactors. Tank 1 and tank 2 was filled up with 20L feeds deionised water. 300g of Sodium Chloride was dissolved in tank 1until the salts dissolve entirely and the solution is homogenous. Three way valve (V3) was set to position 2 so that deionised water from tank 2 will flow into reactor 1. Pump 2 was switched on to fill up all three reactors with deionised water. The flow rate (Fl1) was set to 150 ml/min by adjusting the needles valve (V4). Do not use too high flow rate to avoid the over flow and make sure no air bubbles trapped in the piping. The stirrers 1, 2 and 3 were switched on. The deionised water was continued pumped for about 10 minute until the conductivity readings for all three reactors were stable at low values. The values of conductivity were recorded at t 0 . The pump 2 was switched off after 5 minutes. The valve (V3) was switched to position 1 and the pump 1 was switched on. The timer was started. The conductivity values for each reactor were recorded every three minutes. Record the conductivity values were continued until reading for reactor 3 closed to reactor 1. Pump 2 was switched off and the valve (V4) was closed. All liquids in reactors were drained by opening valves V5 and V6.