Professional Documents
Culture Documents
CHEMISTRY
CHEMISTRY
ACTIVITY
ACTIVITY RESOURCES
RESOURCES
Teacher’s Edition
OH SING SENG
GOH SIAH CHING
N RAZIMI HJ MUDA
ROSLENA HJ MUNEL
SRI YANI HEPNIE
1
Contents Page
INTRODUCTION TO CHEMISTRY 3
CHEMICAL FORMULA 9
EXPERIMENTAL CHEMISTRY 30 – 33
SALTS 39 – 46
QUALITATIVE ANALYSIS 47 – 55
ELECTROLYSIS 71 – 76
SPEED OF REACTIONS 77 – 83
REVERSIBLE REACTIONS 84 – 86
REDOX 87 – 88
ORGANIC CHEMISTRY 90 – 99
REFERENCES 100
2
Activity 1.4
INTRODUCTION TO CHEMISTRY
Aim: Use mnemonics to familiarize with name and symbol of first row of common transition
metals.
Example:
Use mnemonics to memorise the first row of the common transition metals.
Scandium, Titanium, Vanadium, Chromium, Manganese, Iron, Cobalt, Nickel, Copper, and Zinc
Scary - Scandium
Tim - Titanium
Very - Vanadium
Crooked - Chromium
Man - Manganese
I - Iron
Call - Cobalt
Nick - Nickel
Corporal - Copper
Zee - Zinc
3
Activity 2.2
Procedure:
1. A group of students (6- 9), stand at the front of the room acting as atoms.
2. Standing next to each other in 2 or 3 rows with arms linked they represent a solid- particles
closed together, moving slightly (vibrating) at their fixed position.
3. As heat energy is applied the students move further away from each other and eventually the
links break.
4. Allowing students to move randomly passing each other but still remain close together.
5. Further heating the students move freely away from each other at high speed.
4
Activity 2.3
Apparatus:
Thermometer Conical flask
Retort stand Bunsen burner
Boiling tube Stopwatch
Materials:
Solid naphthalene
Procedure:
1. Clamp boiling tube on retort stand.
2. Add 3 spatulas of powdered naphthalene into a boiling tube and insert a thermometer.
3. Heat the naphthalene until all has melted (about 85 C ).
4. Then, leave it to cool in a conical flask.
5. Record the temperature for every 20 seconds until it falls to about 60 C .
6. Record the results in a table.
5
Results:
Cooling of naphthalene
Analysis of data:
6
Activity 2.4
Apparatus:
Thermometer Tripod stand
Beaker 250 cm 3 Wire gauze
Retort stand Bunsen burner
Boiling tube Stopwatch
Stirrer or glass rod Porcelain chip
Materials:
Water
Ethanol sample (Caution: ethanol is flammable)
Procedure:
1. Quarter fill the boiling tube with your ethanol sample.
2. Add a porcelain chip to the boiling tube to ensure it does not ‘froth up’ too much on boiling.
3. Set up apparatus as shown below.
7
4. Heat the water gently and stir continuously to ensure an even temperature around the boiling
tube.
5. Continue heating until the ethanol boil. This is when the bubbles start to appear from the
porcelain chip.
Results:
Questions:
1. The boiling point of ethanol is 78 C . Is your ethanol sample pure?
………………………………………………………………………………………………………………
2. What effect does an impurity have on the boiling point of a substance?
………………………………………………………………………………………………………………
3. Why must we heat the ethanol in a water bath and not heat it directly with a Bunsen flame?
………………………………………………………………………………………………………………
8
Activity 5.1
CHEMICAL FORMULA
Aim: To work out the formula of ionic compound using card games.
Materials:
A set of cards representing common anions and cations. Each card has the symbol of the ion
written on it.
Procedure:
1. Group the students (2 to 3 students in a group).
2. Give each group a set of cards.
3. To get a correct formula, join the shapes to form a rectangle.
4. The formula can then be read or copied from the card.
For example, to find the formula of copper(II) chloride, a complete rectangle is formed by joining
one copper(II) ion card and two chloride ion cards (see below). Hence the formula of copper(II)
chloride is CuCl 2 .
Questions:
Now use the card to work out the chemical formulae of the following ionic compounds
9
Activity 6.2
Apparatus:
Test tubes with rack White tile
Pair of forceps Water trough (for sodium only)
Knife or scalpel
Materials:
Sodium (store in oil) – teacher’s demonstration
Calcium Copper
Magnesium Distilled water
Iron
Procedure:
1. Place distilled water in four test tubes to a depth of 5 cm.
2. Drop a piece of calcium into a test tube filled with water.
3. Observe the reaction carefully and answer the following questions:
(a) Does the metal float or sink in water?
(b) Does the metal react vigorously?
4. Test the gas given out using lighted splint
5. Dip a piece of red litmus to the solution in the test tube. Is there a colour change?
6. Repeat step 1, 2, 3, and 4 for the other metals.
7. Record all your observations in a table provided under the Results section.
10
Results:
Observations
Effect on red
Element Vigorous or Lighted splint test
Float or Sink litmus paper
Not vigorous
Magnesium
Copper
Calcium
Sodium
Iron
From the results arranged the five metals in the order of decreasing reactivity.
Questions:
1. Which group of the Periodic Table does sodium belong?
……………………………………………………………………………………………………….....
2. What is the common name for this group of metals?
………………………………………………………………………………………………………….
3. Name the alkali formed when sodium reacts with water.
………………………………………………………………………………………………………….
4. Name the gas produced when sodium reacts with water.
……………………………………………………………………………….....................................
5. Which other metals (listed above) will produce similar reaction with cold water?
………………………………………………………………………………………………………….
6. Name this type of reaction.
………………………………………………………………………………………………………….
7. Write a balanced equation for the above reaction.
………………………………………………………………………………………………………….
11
Activity 6.3
Apparatus:
Test tubes with rack
Chemicals:
Zinc foil Iron wire
Magnesium ribbon Dilute hydrochloric acid solution
Copper foil
Procedure:
1. Place dilute hydrochloric acid in a test tube to a depth of 2 cm.
2. Drop a piece of zinc into the test tube.
3. Test the gas given out using a lighted splint.
4. Repeat step 1, 2 and 3 for magnesium, copper and iron.
5. Record all your observations in a table provided in the Results section.
12
Results:
Metals Observations Lighted splint test
Copper
Zinc
Magnesium
Iron
From the results arranged the four metals in the order of decreasing reactivity.
Questions:
1. Write the chemical formula for hydrochloric acid.
.…………………………………………………………………………………………………………
2. Name the gas given out when dilute acid reacts with a metal.
.................................................................................................................................................
3. Name the metals (listed above) other than zinc that produces similar reaction with acid.
………………………………………………………………………………………………………….
4. What would you expect the reaction to be if potassium is used instead of zinc in the above
reaction?
………………………………………………………………………………………………………….
5. Although copper is a metal, it does not react with dilute hydrochloric acid. Why?
………………………………………………………………………………………………………….
6. Name the salt formed when zinc reacts with dilute hydrochloric acid.
………………………………………………………………………………………………………….
7. Name this type of reaction
………………………………………………………………………………………………………….
8. Write a balanced equation for the above reaction.
………………………………………………………………………………………………………….
13
Activity 6.4
Apparatus:
Test tube with rack Delivery tube (or plastic syringe)
Boiling tube Spatula
Chemicals:
Calcium carbonate powder
Copper(II) carbonate powder
Dilute hydrochloric acid solution
Limewater
Procedure:
1. The test tube is filled with dilute hydrochloric acid to a depth of 3 cm.
2. One spatula of powdered calcium carbonate is added to the dilute hydrochloric acid.
3. Pass the gas given out into limewater.
4. Repeat step 1 and 3 for powdered copper(II) carbonate.
5. Record all your observations in the table provided.
Boiling tube
14
Results:
Observations Limewater test
Calcium carbonate
Copper(II) carbonate
Questions:
Calcium carbonate
1. Name the gas given out in the reaction.
………………………………………………………………………………………………………….
2. Is calcium carbonate soluble in water?
………………………………………………………………………………………………………….
3. Name the salt formed when calcium carbonate reacts with dilute hydrochloric acid?
………………………………………………………………………………………………………….
4. Is this salt soluble in water?
………………………………………………………………………………………………………….
5. Name this type of reaction.
………………………………………………………………………………………………………….
6. Write a balanced equation for the above reaction.
………………………………………………………………………………………………………….
Copper(II) carbonate
1. What is the colour of copper(II) carbonate?
……………………………………………………………………………………………………........
2. Is copper(II) carbonate soluble in water?
………………………………………………………………………………………………………….
3. Name the gas given out in the above reaction.
………………………………………………………………………………………………………….
4. Write a balanced chemical reaction for the above reaction.
………………………………………………………………………………………………………….
15
Activity 6.5
Apparatus:
Test tubes
Materials:
Potassium iodide solution Sodium sulphate solution
Lead(II) nitrate solution Barium chloride solution
Silver nitrate solution Dilute hydrochloric acid solution
Procedure:
1. Pour potassium iodide solution into a test tube (about 2 cm depth) and add an equal volume of
lead(II) nitrate solution and observe.
2. Leave the mixture to stand for a few minutes and observe.
3. Repeat step 1 and 2 for:
(a) silver nitrate and dilute hydrochloric acid solutions
(b) Sodium sulphate and barium chloride solutions
Results:
Reaction Initial observations When left to stand
16
Questions:
1. Name the precipitate formed in experiment (a), (b) and (c).
Experiment (a): …………………………………..
Experiment (b): …………………………………..
Experiment (c): …………………………………..
2. Write the balanced chemical equations for experiment (a), (b) and (c).
Experiment (a): …………………………………………………………………………………………...
Experiment (b): …………………………………………………………………………………………...
Experiment (c): ……………………………………………………………………………………………
17
Activity 6.6
Apparatus:
Beaker 50 cm3 Sand paper
Measuring cylinder
Materials:
Magnesium ribbon Silver nitrate solution
Lead(II) nitrate solution Magnesium chloride solution
Zinc foil Copper foil
Copper(II) sulphate solution
Procedure:
1. Clean a strip of magnesium ribbon with a sand paper.
18
Results:
Reaction Observations Conclusion
Magnesium
+
lead(II) nitrate solution
Zinc
+
copper(II) sulphate solution
Magnesium
+
silver nitrate solution
Copper
+
Magnesium chloride solution
19
Activity 6.7
Apparatus:
Test tubes
Materials:
Chlorine water Potassium iodide solution
Bromine water Iodine
Sodium bromide solution Sodium chloride solution
Procedure:
1. Pour potassium iodide solution into a test tube (about 2 cm depth).
2. Add an equal volume of chlorine water and observe.
3. Record your observations in the table provided.
4. Repeat the experiment for the following reaction:
(i) Chlorine water and sodium bromide solution,
(ii) Bromine water and sodium chloride solution,
(iii) Bromine water and potassium iodide solution,
(iv) Iodine and sodium chloride solution,
(v) Iodine and sodium bromide solution.
20
Results:
Halides
Halogen
NaCl (aq) NaBr (aq) KI (aq)
Chlorine
Bromine
Iodine
Questions:
1. From the results, arrange the three halogens in the order of decreasing reactivity.
………………………………………………………………………………………………………..
………………………………………………………………………………………………………..
………………………………………………………………………………………………………..
21
Activity 6.8
Apparatus:
Pyrex glass test tube Delivery tube (or plastic syringe)
Test tube with rack Bunsen burner
Test tube holder
Materials:
Copper(II) carbonate powder Limewater
Ammonium carbonate powder Zinc carbonate powder
Procedure:
1. Put some powdered copper(II) carbonate into a Pyrex test tube and heat it strongly.
2. Pass the gas given out through limewater and observe.
3. Record your observations in the table provided.
4. Repeat the experiment with ammonium carbonate and zinc carbonate.
22
Results:
Reaction Observations Limewater test
Questions:
1. What is the colour of the residue in experiment (a)?
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
23
Activity 6.9
Apparatus:
Crucible Tong
Pipeclay triangle Spatula
Tripod stand Bunsen burner
Materials:
Iron filings
Sulphur powder
Procedure:
1. Mix one spatula full sulphur powder with an equal amount of iron filing in a crucible.
2. Heat the mixture strongly and observe.
Results:
Observation: …………………………………………………………………………………………………...
Questions:
1. Name the product of the reaction.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
24
Part 2: Heating sulphur with air (oxygen)
Apparatus:
Crucible Tong
Pipeclay triangle Spatula
Tripod stand Bunsen burner
Materials:
Sulphur powder Strip filter paper
Blue litmus paper Acidified potassium dichromate(VI)
Procedure:
1. Add one spatula full sulphur powder into a crucible.
2. Then, heat strongly and observe.
3. Test the gas given out using moist blue litmus paper and acidified potassium dichromate(VI)
paper.
4. Record your observations in the table
Results:
Test Observations
Questions:
1. Name the product of the reaction.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
25
Activity 7.1
Part 1:
Preparation of 0.1 mol dm 3 copper(II) sulphate solution
Apparatus:
Volumetric flask 250 cm3 Glass rod
Beaker
Balance
Materials:
Distilled water
Copper(II) sulphate crystals
Procedure:
1 Use the balance to weigh _______ g of copper(II) sulphate pentahydrate crystals.
2 Dissolve the copper(II) sulphate in distilled water inside a beaker.
Results:
The solution prepared is 0.1 mol dm 3 copper(II) sulphate solution.
26
Part 2:
Preparation of 0.01 mol dm 3 copper(II) sulphate solution from 0.1 mol dm 3 copper(II) sulphate
solution.
Procedure:
1 Pipette 25 cm3 of copper(II) sulphate solution from Part 1.
Results:
The solution prepared is 0.01 mol dm 3 copper(II) sulphate solution.
Questions:
………………… X
27
Activity 7.2
Apparatus:
Bunsen burner with matches Pipeclay triangle
Tripod stand Tongs
Crucible Spatula
Materials:
Sample of impure sodium carbonate (sodium carbonate mixed with ammonium carbonate)
Procedure:
1. Weigh the mass of the crucible.
2. Then add in sample of impure sodium carbonate and weigh.
3. Place the crucible on the tripod stand, and heat it strongly for five minutes.
4. Leave the crucible to cool and weigh the content again.
28
Results:
(a) Mass of the empty crucible = ……………….. g
Questions:
Calculate the percentage purity of sodium carbonate.
29
Activity 8.1
EXPERIMENTAL CHEMISTRY
Aim: To obtain copper(II) sulphate crystals from a mixture of copper(II) sulphate and sand.
Apparatus:
250 cm3 beaker Stirring rod
Evaporating dish
250 cm3 conical flask Bunsen burner
Filter paper Tripod stand
Filter funnel
Materials:
A mixture of copper(II) sulphate with sand
Procedure:
1. Put the mixture in a beaker
2. Add water to the mixture
3. Stir with a glass rod to make sure that copper(II) sulphate dissolved.
4. Filter the mixture; collect the filtrate in a conical flask.
5. Wash the residue on the filter paper with water.
6. Evaporate the filtrate until saturated, and leave it to crystallize.
30
Results:
1. The residue is …………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
3. Give an example of a mixture of two other substances that can be separated by this method.
………………………………………………………………………………………………………………
31
Activity 8.5
EXPERIMENTAL CHEMISTRY
Aim: To separate various dyes in food colouring and measure the R f values.
Apparatus:
Boiling tube Pair of scissors
Filter paper Distilled water
Ruler
Materials:
Mixture of food colouring
Procedure:
1. Cut a strip of filter paper such that it can fit neatly into a boiling tube. It should also be slightly
longer than the boiling tube.
2. Draw a baseline with a pencil, about 2 cm away from the bottom tip.
3. Mark a tiny spot on the middle of the baseline with food colouring.
4. Put about 1cm depth of distilled water into the boiling tube.
5. Mount the filter paper strip in the boiling tube.
6. Leave the apparatus to stand for a short while.
7. Observe the solvent front as the water travels up the paper.
8. Remove the piece of filter paper when the solvent front reaches just below (1cm) the top of the
paper. [DO NOT let the solvent front go beyond the top of the paper]
9. Allow the paper to dry.
spot
baseline
32
Results:
Attach your chromatogram in the space below.
Questions:
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
33
Activity 9.1
Apparatus:
Materials:
Solution P is dilute hydrochloric acid of unknown concentration
Solution Q is 0.1 mol dm3 sodium hydroxide solution
Methyl orange or screened methyl orange indicator.
Procedure:
1. Fill the burette with solution P until 0 mark. Make sure that no air bubbles are trapped at the tip
of the burette.
2. Pipette a 25.0 cm3 portion of Q into a conical flask. Add a few drops of either screened methyl
orange or methyl orange indicator.
3. Titrate the solution Q with the solution P from the burette and record the results in the table,
repeating the titration as many times as you consider necessary to achieve consistent results.
34
Results:
Titration number 1 2 3
Summary:
Tick () the best titration results.
Using these results, the average volume of P required was …………………………. cm3 .
Questions:
1. Calculate the number of moles of sodium hydroxide used in the titration.
3. How many moles of HCl would be used in neutralising NaOH in the titration?
4. Having known the number of moles of hydrochloric acid from (3) and also the volume of the
acid used in the titration, calculate the concentration in mol dm3 of the hydrochloric acid.
35
Activity 9.2
Materials:
Solution P is 0.2 mol dm3 hydrochloric acid
Solution Q is made by dissolving 28 g of a mixture of sodium chloride and sodium carbonate in
water and made up to 1 dm3 solution.
Procedure:
You are required to find the percentage purity of sodium carbonate in the mixture.
Results:
Titration number 1 2 3
Summary:
In the above titration …………… cm3 of solution P is required to exactly neutralise
…………... cm3 of solution Q.
36
Questions:
1. Write a chemical equation to show the reaction involved in the titration.
2. From the titration, calculate the concentration of sodium carbonate in solution Q in mol dm3 .
3. Given that the molecular mass of sodium carbonate, Na 2 CO 3 is 106, calculate the
concentration of sodium carbonate in solution Q in g dm 3 .
4. Calculate the percentage purity by mass of sodium carbonate in the original mixture used in
the preparation of solution Q.
37
Activity 9.3
Apparatus:
Test tube with rack Bunsen burner
Test tube holder Spatula
Materials:
Sodium hydroxide solution
Solid ammonium chloride
Litmus paper
Procedure:
1. Put one spatula full solid ammonium chloride into a test tube and slowly pour in sodium
hydroxide solution. Smell the gas.
2. Warm the mixture gently by using a small Bunsen flame.
3. Test the gas by using moist red and blue litmus paper.
Results:
1. When aqueous sodium hydroxide is added to solid ammonium chloride and warmed gently a
gas is formed. Describe the smell of the gas.
………………………………………………………………………………………………………………
2. Test the gas with moist blue litmus paper. Describe your observation.
………………………………………………………………………………………………………………
3. Test the gas with moist red litmus paper. Describe your observation.
………………………………………………………………………………………………………………
Conclusion:
1. When an ammonium salt reacts with an alkali …………………… gas is formed, which turn
moist ………….. litmus paper ………………. .
2. Write an equation for the reaction between sodium hydroxide and ammonium chloride.
………………………………………………………………………………………………………………
38
Activity 10.1
SALTS
Aim: To prepare copper(II) sulphate crystals by reacting sulphuric acid with
copper(II) oxide or copper(II) carbonate
Apparatus:
Beaker Filter paper
Conical flask Evaporating basin
Stirrer Spatula
Filter funnel
Materials:
Dilute sulphuric acid
Copper(II) oxide or copper(II) carbonate
Procedure:
1. Put about 100 cm3 of dilute sulphuric acid in a beaker and heat it gently.
2. Add copper(II) oxide or copper(II) carbonate to the hot sulphuric acid, a little at a time until in
excess.
3. Filter out the excess copper(II) oxide or copper(II) carbonate by using filter funnel and filter
paper.
4. Collect the filtrate in an evaporating basin and evaporate the filtrate until saturated.
5. Leave the saturated filtrate to cool and crystallise.
39
Questions:
1. Name the base or carbonate used in this reaction?
………………………………………………………………………………………………………………
2. What is the formula of this compound?
………………………………………………………………………………………………………………
3. Is this compound soluble or insoluble?
………………………………………………………………………………………………………………
4. Name the above reaction.
………………………………………………………………………………………………………………
5. Write chemical equation for the above reaction.
………………………………………………………………………………………………………………
6. Name the salt formed from the above reaction.
………………………………………………………………………………………………………………
7. Name the filtrate.
………………………………………………………………………………………………………………
8. What is the residue left on the filter paper?
………………………………………………………………………………………………………………
9. Why must the copper(II) oxide be added in excess?
………………………………………………………………………………………………………………
10. Can the above reaction be carried out using titration method? Why?
………………………………………………………………………………………………………………
40
Activity 10.2
SALTS
Aim: To prepare insoluble salts
Apparatus:
Test tubes with rack
Materials:
Silver nitrate solution Dilute hydrochloric acid solution
Potassium iodide solution Dilute nitric acid solution
Procedure:
Carry out the following tests and record your observations in the table.
Test
Test observations
no.
41
Questions:
1. Name the above reaction.
………………………………………………………………………………………………………………
2. Write the symbol and ionic equations for the reactions between silver nitrate and hydrochloric
acid.
(a) Symbol equation
………………………………………………………………………………………………………..
(b) Ionic equation
………………………………………………………………………………………………………..
3. Write the symbol and ionic equations for the reactions between potassium iodide and lead(II)
nitrate.
(a) Symbol equation
………………………………………………………………………………………………………..
(b) Ionic equation
………………………………………………………………………………………………………..
42
Activity 10.3
SALTS
Aim: To investigate solubility of salts in water
Apparatus:
Test tubes with rack
Stoppers
Spatula
Materials:
Distilled Water
Solid salts:
Silver chloride Lead(II) sulphate
Sodium chloride Sodium carbonate
Lead(II) chloride Calcium carbonate
Barium sulphate Potassium nitrate
Copper(II) sulphate Silver nitrate
Procedure:
1. Add half a spatula of a salt to a test tube.
2. Half-fill the test tube with distilled water. Then stopper the tube and shake well.
3. Record your observation in the table provided.
Results:
Solubility
Salt
(soluble or insoluble)
Silver chloride
Sodium chloride
Lead(II) chloride
Barium sulphate
Copper(II) sulphate
Lead(II) sulphate
Sodium carbonate
Calcium carbonate
Potassium nitrate
Silver nitrate
43
Questions:
State whether you think the following substances are soluble or insoluble in water:
(a) Zinc nitrate ……………………………
44
Activity 10.4
SALTS
Aim: To determine the solubility of salts in g cm 3 .
Apparatus:
Beakers Filter funnel
Glass rod Filter paper
Spatula Measuring cylinder
Balance
Materials:
Water
Solid salts: sodium chloride and copper(II) sulphate
Procedure:
1. Label each beaker with the name of the salts. Measure 100 cm3 water into each beaker.
2. Record the mass of these beakers containing water.
3. Add a spatula of sodium chloride salt and stir till dissolved.
4. Repeat step 3 until no more salt can dissolve in the 100 cm3 of water.
5. Filter this salt solution and collect the filtrate.
6. Record the mass of this salt solution (filtrate).
7. Subtract this new mass with the previous mass.
45
Results:
Solubility in g dm 3
Conclusion:
46
Activity 11.1
QUALITATIVE ANALYSIS
Aim: To identify the following cations: Al3 , NH 4 , Ca 2 , Cu 2 , Fe 2 , Fe 3 and Zn 2
Apparatus:
Test tubes with rack
Test tube holder
Bunsen burner
Materials:
Aqueous sodium hydroxide solution
Aqueous ammonia solution
Procedure:
A, B, C, D, E, F and G are unknown solutions containing different cations. Carry out the following
test and record your observations in the table. You should test and name, where possible, any
gases evolved.
Test
Test Observations
no.
47
Test
Test Observations
no.
48
Test
Test Observations
no.
49
Questions:
Give the names and formulae of the cations present in:
Name Formula
Solution A
Solution B
Solution C
Solution D
Solution E
Solution F
Solution G
50
Activity 11.2
QUALITATIVE ANALYSIS
Aim: To identify the following anions: CO 23 , Cl , I , NO 3 and SO 24
Apparatus:
Test tubes with rack
Test tube holder
Bunsen burner
Materials:
Aqueous solution of the anions above:
Sodium carbonate – A Aqueous barium chloride
Sodium chloride – B Aqueous lead(II) nitrate
Potassium iodide – C Aqueous sodium hydroxide
Silver nitrate – D Aluminum foil
Sodium sulphate - E Dilute nitric acid
Students are required to carry out tests to identify the anions in solutions A, B, C, D and E.
State either positive ( ) or negative ( X ) for each test using the reagents below
Solution NaOH + Al
Dilute nitric acid AgNO 3 (aq) BaCl 2 (aq) Pb(NO 3 ) 2 (aq)
and heat
51
Write the positive test for the anions A, B, C, D and E in the spaces provided
Reagent giving Anion
Solution Procedure Observations
positive test present
52
C
E
Activity 11.3
QUALITATIVE ANALYSIS
Aim: To test for gases
Apparatus:
Bunsen burner Test tube holder
Litmus paper Plastic syringe
Spatula Test tubes with rack
Filter paper Wooden splint
Materials:
Acidified potassium dichromate (VI) Dilute hydrochloric acid
Distilled water Solid calcium hydroxide
Ammonium chloride solution Manganese(IV) oxide
Hydrogen peroxide solution Sodium sulphite
Bleach solution Calcium carbonate
Limewater Magnesium ribbon
Procedure:
1. Generate the gas as described in the table.
2. Note its colour and odour and record your observations in the table
3. Carry out specific tests described in column 3 and record your observations.
Note: Use a test tube holder when heating anything in a test tube.
53
Test
Gas observations Specific Test and observations
No.
Then add 2 – 3 cm 3 of
dilute hydrochloric acid into
the test tube.
54
Test
Gas observations Specific Test and observations
No.
55
Activity 12.1
Apparatus:
Test tubes with rack
Sandpaper
Spatula
Materials:
Magnesium ribbon 1 mol dm3 Zinc sulphate solution
Zinc foils
Iron fillings 1 mol dm3 Iron (II) sulphate solution
Copper foils 1 mol dm3 Copper (II) sulphate solution
3
1 mol dm Magnesium sulphate solution
Procedure:
1. Clean a strip of magnesium ribbon with sandpaper.
2. Half fill a test tube with zinc sulphate solution.
3. Immerse the magnesium ribbon in the zinc sulphate solution.
4. Leave the mixture aside for a few minutes, and observe.
5. Repeat the experiment above using the materials stated in the table.
56
Results:
Observations with
Magnesium Zinc Iron Copper
Magnesium
sulphate solution
Zinc sulphate
solution
Iron(II) sulphate
solution
Copper(II) sulphate
solution
Questions:
1. From your results arrange the four metals in order of decreasing reactivity.
Most reactive Least reactive
................................... , ................................... , ................................... , ................................... .
2. Complete these displacement equations:
3. Aluminium is more reactive than zinc but less reactive than magnesium. Will aluminium
displace iron from a solution of iron (II) salt? Explain.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
57
Activity 12.2
Apparatus:
Sand bath
Paper cone made from filter paper
Spatula
Materials:
Iron(III) oxide Magnesium ribbon
Aluminium powder Barium peroxide (or potassium chlorate)
Magnesium powder
Procedure:
1. Mix a few grams of iron(III) oxide powder with an equal amount of aluminium powder and put
the mixture in a paper cone mounted on a sand bath as shown in the diagram.
2. Mix a little barium peroxide or potassium chlorate with magnesium powder and pour the
mixture into the paper cone containing the mixture of iron(II) oxide and aluminium powder. This
mixture is to set off a preliminary reaction.
3. Using a long piece of clean magnesium ribbon as a fuse, stick one end into the base of the
paper cone and burn the other end.
[Caution: Immediately move far away from the burning magnesium ribbon.]
Magnesium ribbon
Mixture of barium peroxide and as fuse
magnesium powder
Paper cone
Mixture of
iron(III) oxide and
aluminium powder
Sand bath
58
Results:
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
2. Write the equation to show the reaction between iron(III) oxide and aluminium.
……………………………………………………………………………………………………………...
59
Activity 12.3
Apparatus:
Test tubes with rack Bunsen burner
Test tube holders Plastic syringe (or delivery tube)
Materials:
Zinc carbonate
Copper(II) carbonate
Lime water
Procedure:
1. Put some powdered zinc carbonate into a test-tube and heat it strongly.
2. Pass the gas given out through lime water and observe for the formation of a new substance.
3. Repeat the experiment using copper(II) carbonate and observe for the colour change and the
formation of a new substance.
Results:
(a) Zinc carbonate is …………………… (colour). When strongly heated zinc carbonate gives out a
…………………… (colour) gas which turns lime water ……………………
(b) The residue is …………………… (colour) when hot and ……………………(colour) when cold.
(c) The gas is …………………… and the residue is ……………………
(d) Write word equation for the above reaction.
………………………………………………………………………………………………………………
(e) Write symbol equation for the above reaction.
………………………………………………………………………………………………………………
(f) Copper(II) carbonate is ……………………(colour). When strongly heated copper(II) carbonate
gives out a ……………………(colour) gas which turns lime water ……………………
(g) The residue is ……………………(colour)
(h) The gas is …………………… and the residue is ……………………
(i) Write word equation for the above reaction.
………………………………………………………………………………………………………………
(j) Write symbol equation for the above reaction.
………………………………………………………………………………………………………………
60
Activity 12.4
Apparatus:
Boiling tubes
Test tube rack
Materials:
Iron nails Cooking oil
Boiled water Tap water
Procedure:
1. Prepare four boiling tubes in a rack, labelled them as A, B, C and D.
2. Into each boiling tube place a clean iron nail.
3. Pour water from the tap into boiling tube A until the nail is fully submerged.
4. Pour some hot water into boiling tube B until the nail is fully submerged and pour a layer of
cooking oil to cover the surface of the water.
5. Place a little anhydrous cobalt chloride into boiling tube C and cork the mouth of the boiling
tube with a rubber bung.
6. Pour some cooking oil into boiling tube D until the nail is fully submerged.
7. Leave the four boiling tubes in the rack for a few days and then observe.
Results:
(a) Does the tap water in boiling tube A contain air? Why?
………………………………………………………………………………………………………………
(b) Does the water in boiling tube B contain air? Why?
………………………………………………………………………………………………………………
(c) Does the air in the boiling tube C contain water? Why?
………………………………………………………………………………………………………………
(d) Does boiling tube D contain any air or water?
………………………………………………………………………………………………………………
(e) Which iron nail becomes rusty?
………………………………………………………………………………………………………………
(f) Why does the iron nail become rusty?
………………………………………………………………………………………………………………
61
Activity 12.5
Materials:
Salt solution
Iron nails
Magnesium ribbon
Copper foil
Procedure:
1. Fill the three Petri dishes with some salt solution and then make a cushion of cotton wool and
place it in each Petri dish so that it is soaked in the salt solution.
2. Label the Petri dishes as A, B, and C.
3. In Petri dish A, place a clean iron nail on the cushion of cotton wool. In Petri dish B, place a
clean iron nail wound with magnesium ribbon and in Petri dish C, place a clean iron nail wound
with copper strip.
4. Leave the three Petri dishes for a few days and then observe.
A B C
Magnesium ribbon Copper foil
62
Results:
1. What happen to the iron nail in A?
……………………………………………………………………………………………………………...
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
63
Activity 12.6
Apparatus:
Bunsen burner
Blow pipe
Materials:
Lead(II) oxide
Carbon block
Procedure:
1. Wet the middle of carbon block using tap water.
2. Place a little amount of lead(II) oxide on a carbon block.
3. Heat and blow air using blow pipe over the oxide.
4. Observe any changes on the carbon block.
lead(II) oxide
carbon block
blow pipe
Bunsen burner
Observations:
…………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………...
64
Activity 13.1
Materials:
Lithium Litmus paper
Potassium Phenolphthalein
Sodium
Procedure:
1. Put a few drops of phenolphthalein in a 250 cm3 beaker containing water.
2. Cut a very small piece of lithium and drop it in water, and observe.
3. Repeat the above experiment with the following metals: sodium and potassium.
4. Record your observations in the table.
Lithium or sodium
or potassium
White tile
Lumps of lithium
or sodium or
potassium
Results:
Effect on
Effect of solution on
Metal Observations phenolphthalein
red litmus paper
indicator
Lithium
Sodium
Potassium
65
Questions:
From the results, it shows that when a metal reacts with water, the solution formed is
2. Write a balanced chemical equation for the reaction between lithium and water.
………………………………………………………………………………………………………………
3. Write a balanced chemical equation for the reaction between sodium and water.
………………………………………………………………………………………………………………
4. Write a balanced chemical equation for the reaction between potassium and water.
………………………………………………………………………………………………………………
66
Activity 14.1
Apparatus:
Two 100 cm3 measuring cylinders Thermometer
Plastic cup
250 cm3 beakers
Materials:
0.1 mol dm3 HCl – solution Q
0.1 mol dm3 NaOH – solution P
Procedure:
In this question you are required to determine the heat of neutralisation between a strong acid HY
and a strong alkali MOH.
You are provided with the following.
67
Results:
Initial temperature of the acid Q = …………...... (a)
Questions:
1. Write an equation to show the neutralisation between P and Q.
………………………………………………………………………………………………………………
2. Write an ionic equation for the above reaction.
………………………………………………………………………………………………………………
3. Ignoring the heat lost to the plastic container and the beaker, calculate the heat given out by
the reaction. (The specific heat of solution is 4.2 J g °C).
[Hint: Use the formula H = m x c x θ]
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
4. Calculate the number of mole of the acid HY or the alkali MOH involved in the reaction.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
5. Calculate the heat of neutralisation, H, between MOH and HY.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
68
Activity 14.2
Apparatus:
Plastic cup
Thermometer
Spatula
Materials:
Sodium hydroxide
Ammonium chloride
Procedure:
1. Measure out 50 cm3 of water in a measuring cylinder and pour it into a plastic cup.
2. Measure the initial temperature of the water.
3. Add a spatula full of solid sodium hydroxide into the water in the cup.
4. Stir to dissolve the solid.
5. Record the highest temperature obtained.
6. Repeat step 1- 4 with ammonium chloride and for step 5 record the lowest temperature
obtained.
[Repeat with other salts; nitrates, sulphates, carbonates etc.]
Result:
Exothermic
Initial Final Change in
Reaction or
temperature/ C temperature/ C temperature/ C
Endothermic
Sodium hydroxide +
water
Ammonium chloride +
water
Conclusion:
69
Activity 14.3
Apparatus:
Beaker
Voltmeter
Materials:
Copper plate 1.0 mol dm3 copper(II) sulphate solution
Zinc plate
Voltmeter
1.0 mol dm3 zinc sulphate solution Connecting wires
Procedure:
1. Set up copper metal as the positive terminal and zinc metal as the negative terminal.
2. Immerse the zinc metal in zinc sulphate solution and the copper metal in copper(II) sulphate
solution.
3. Connect the two solutions using a salt bridge as shown.
salt bridge
voltmeter
zinc
Results:
The electrode potential of Daniel cell is ………………. V
70
Activity 15.1
ELECTROLYSIS
Aim: To demonstrate electrolysis of molten lead(II) bromide.
Apparatus:
Crucible Crocodile clips
Spatula Tripod stand
Graphite electrodes Clay pipe triangle
Power pack Bunsen burner
Materials:
Lead(II) bromide
Procedure:
1. A crucible is half filled with lead(II) bromide solid.
2. The solid lead(II) bromide is heated until it melts to a molten state.
3. Two carbon electrodes are dipped in the molten lead(II) bromide and are then connected to
power pack using crocodile clips.
4. Electric current is allowed to flow through for 15 minutes and the changes that occur at the
cathode and anode are recorded.
Results:
Observations Inference
At the anode
At the cathode
71
Activity 15.2
ELECTROLYSIS
Aim: To demonstrate electrolysis of dilute sodium chloride solution.
Apparatus:
Power pack 100 cm3 beaker
Carbon electrodes
Crocodile clips
Materials:
Aqueous 0.5 mol dm3 sodium chloride solution
Procedure:
1. Aqueous sodium chloride is put into a beaker
2. Insert two carbon electrodes into the aqueous sodium chloride and connect them to the power
pack.
3. The switch is turned on and electric current is allowed to flow for 15 minutes and observe.
4. Collect the gas and test.
5. Record your observations in the table.
carbon electrodes
aqueous sodium chloride
Results:
Electrolyte Observations Test for the gas
At the cathode: Splint test
Dilute sodium
chloride solution At the anode: Splint test
72
Activity 15.3
ELECTROLYSIS
Title: To Demonstrate electrolysis of concentrated sodium chloride solution.
Apparatus:
Power pack 100 cm3 beaker
Carbon electrodes
Crocodile clips
Materials:
Concentrated sodium chloride solution (1 mol dm 3 )
Procedure:
1. Concentrated sodium chloride is put into a beaker.
2. Insert two carbon electrodes into the concentrated sodium chloride solution and connect them
to the power pack.
3. The switch is turned on and electric current is allowed to flow for 15 minutes and observe.
4. Collect the gas and test.
5. Record your observations in the table.
carbon electrodes
concentrated sodium
chloride solution
Results:
Electrolyte Observations Test for the gas
At the cathode: Splint test
concentrated sodium
chloride solution At the anode: Litmus test
73
Activity 15.4
ELECTROLYSIS
Aim: To demonstrate electrolysis of copper(II) sulphate using carbon electrodes.
Apparatus:
Power pack 100 cm3 beaker
Carbon electrodes
Crocodile clips
Materials:
Aqueous 0.5 mol dm3 copper(II) sulphate solution
Procedure:
1. Copper(II) sulphate solution is put into a beaker.
2. Insert two carbon electrodes into the copper(II) sulphate solution and connect them to the
power pack.
3. The switch is turned on and electric current is allowed to flow for 15 minutes and observe.
4. Record your observations in the table.
Results:
Electrolyte Observations
At the cathode:
Copper(II) sulphate
solution At the anode:
Questions:
1. What would you expect the colour of the copper(II) sulphate solution to be if the electrolysis is
carried out for a long period? Why?
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
74
Activity 15.5
ELECTROLYSIS
Aim: To demonstrate electrolysis of copper(II) sulphate using copper electrodes.
Apparatus:
Power pack 100 cm3 beaker
Copper electrodes
Crocodile clips
Materials:
Aqueous 1.0 mol dm3 copper(II) sulphate solution
Procedure:
1. Copper(II) sulphate solution is put into a beaker.
2. Insert copper electrodes into the copper(II) sulphate solution and connect them to the power
pack.
3. The switch is turned on and electric current is allowed to flow for 15 minutes and observe.
4. Record your observations in the table.
Results:
Electrode Observations
At the cathode:
Copper(II) sulphate
solution At the anode:
Questions:
1. What would you expect the colour of the copper(II) sulphate solution to be if the electrolysis is
carried out for a long period? Why?
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
75
Activity 15.6
ELECTROLYSIS
Aim: To demonstrate electroplating of spatula with copper.
Apparatus:
Power pack 1.0 mol dm3 copper(II) sulphate
3
Beaker 250 cm Copper plate
Crocodile clips Metal spatula
Materials:
1.0 mol dm3 copper(II) sulphate
Procedure:
1. Pour about 200 cm3 of 1.0 mol dm3 copper(II) sulphate solution into a beaker.
2. A piece of copper plate is connected to the positive terminal. This plate act as the anode.
3. The metal spatula is connected to the negative terminal. This metal spatula acts as the
cathode.
4. Immerse both the metal spatula and the copper plate in the copper(II) sulphate solution. (Make
sure that they do not come into contact)
5. The solution is electrolysed for 30 minutes using a small current (0.5 A ).
Results:
Observations Half-equations
At the cathode: At the cathode:
76
Activity 16.1
SPEED OF REACTIONS
Aim: To show the effect of concentration on the speed of reaction.
Apparatus:
Beaker Filter paper marked “X”
Stop-watch Measuring cylinders
Materials:
2.0 mol dm3 hydrochloric acid
0.25 mol dm3 sodium thiosulphate, Na 2 S 2 O 3 solution
Distilled water
Procedure
1. Measure 5 cm3 of sodium thiosulphate solution into a 250 cm3 beaker and add 45 cm3 of
distilled water.
2. Place the beaker over the filter paper marked “X”.
3. By using a separate measuring cylinder, add 10 cm3 of 2.0 mol dm3 HCl and at once start the
stop-watch.
4. Swirl the beaker a few times and then put the beaker back on the paper over the mark “X”.
5. Observe the mark “X” from above through the solution mixture in the beaker.
6. As more precipitate is formed the mark “X” will eventually disappears from sight.
7. Stop the stop-watch when the mark “X” just disappears from sight. Record the time taken in the
table below.
8. Repeat the experiment by changing the volume of sodium thiosulphate and distilled water.
9. Record the time taken in the table provided.
77
Results:
Volume of sodium Volume of distilled Volume of
thiosulphate solution, water hydrochloric acid Reaction time
s
cm3 cm3 cm3
10
15
20
25
Draw the graph of volume of sodium thiosulphate in cm3 against time in seconds.
Conclusion:
As the concentration of sodium thiosulphate increases …………………………………………………..
………………………………………………………………………………………………………………...…
…………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………...
78
Activity 16.2
SPEED OF REACTIONS
Aim: To show the effect of temperature on the speed of reaction.
Apparatus:
Beaker Measuring cylinder
Stop-watch Thermometer
Filter paper marked “X”
Materials:
2.0 mol dm3 hydrochloric acid
Distilled water
0.25 mol dm3 sodium thiosulphate, Na 2 S 2 O 3 solution
Procedure:
1. Measure 20 cm3 of sodium thiosulphate solution into a beaker and add 60 cm3 of distilled
water. Record the temperature of the solution mixture.
2. Place the beaker over the filter paper marked “X”.
3. Add 20 cm3 of 2.0 mol dm3 HCl and at once start the stop-watch.
4. Swirl the beaker a few times and put the beaker back on the filter paper over the mark “X”.
5. Observe the mark “X” through the solution mixture.
6. Stop the stop-watch when the mark “X” just disappears from sight. Record the time taken in the
table provided.
7. Repeat the experiment at different temperatures by heating the mixtures of 20 cm3 of sodium
thiosulphate and 60 cm3 of distilled water to 40°C, 50°C, 60°C and 70°C.
79
Results:
Room temperature
40°C
50°C
60°C
70°C
Conclusion:
As the temperature increases ………………………………………………………………………………..
………………………………………………………………………………………………………………...…
…………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………...
80
Activity 16.3
SPEED OF REACTIONS
Aim: To show the effect of particle size using calcium carbonate (lump and powder) with
hydrochloric acid.
Apparatus:
Conical flask connected to gas syringe
Stop-clock
Electronic balance
Measuring cylinder 50 cm3
Materials:
Hydrochloric acid 0.25 mol dm3
Calcium carbonate (powder and lump forms)
Procedure:
1. Use an electronic balance to weigh exactly 0.5 g of marble chips and put them in a conical
flask connected to a gas syringe.
2. Use a measuring cylinder to measure exactly 30.0 cm3 of 0.25 mol dm3 hydrochloric acid and
pour into the conical flask containing the marble chips.
3. Immediately cork the conical flask to the gas syringe and at the same time start the stop-clock.
4. Read the volume of the carbon dioxide collected in the gas syringe for every 10 seconds until
the reaction stops.
5. Create your own table to tabulate the readings.
6. Repeat the above experiment by using marble chips of (a) smaller size and (b) powdered
calcium carbonate.
7. Draw on the same graph paper the volume of carbon dioxide gas against time for the three
experiments.
Result:
Conclusion:
As the particle size increases ………………………………………………………………………………..
………………………………………………………………………………………………………………...…
81
Activity 16.4
SPEED OF REACTIONS
Aim: To show the decomposition of hydrogen peroxide using manganese(IV) oxide.
Apparatus:
50 cm3 measuring cylinder Delivery tube
Clock Rubber bung
Spatula Rubber tubing connector
Conical flask Retort stand and clamp
Gas syringe
Materials:
0.2 mol dm3 or ‘2 volume’ hydrogen peroxide (20 volume diluted 10 x)
Powdered manganese(IV) oxide
Procedure:
1. Set up the apparatus shown in the diagram.
hydrogen peroxide
solution
manganese(IV) oxide
82
Results:
Time/min 0 1 2 3 4 5 6 7 8 9 10
Volume
of gas
/cm3
Conclusion:
83
Activity 17.1
REVERSIBLE REACTIONS
Aim: To show reversible reactions.
Apparatus:
Test tubes with rack
Materials:
Potassium chromate(VI) solution
Aqueous sodium hydroxide
Aqueous copper (II) sulphate
Concentrated hydrochloric acid
Concentrated ammonium hydroxide
Dilute sulphuric acid
Procedure:
1. (a) Pour potassium chromate(VI) solution in a test-tube until it is about one-fifth full and
slowly adds dilute sulphuric acid until a change is seen.
Observation:
………………………………………………………………………………………………………
………………………………………………………………………………………………………
Write ionic equation for the reaction in (a).
………………………………………………………………………………………………………
(b) To the mixture from (a) slowly add dilute sodium hydroxide solution and observe the
change.
Observation:
………………………………………………………………………………………………………..
.……………………………………………………………………………………………………….
Explain in terms of reversibility the observation in the experiment (b).
…………………………………………………………………………………………………………
…………………………………………………………………………………………………………
84
2. (a) Pour copper (II) sulphate solution into a test-tube until it is about one-fifth full and slowly
add concentrated hydrochloric acid until a change is seen.
Observation:
…………………….………………………………………………………………………………….
..………………………………………………………………………………………………………
Write the ionic equation for the reaction in (a).
………………………………………………………………………………………………………..
(b) To the mixture from (a) add concentrated ammonia solution a little at a time until a change
is seen.
Observation:
………………………………………………………………………………………………………
………………………………………………………………………………………………………
85
Activity 17.2
REVERSIBLE REACTIONS
Aim: To prepare fertilizer using nitric acid (The manufacture of fertilizer from ammonia).
Apparatus:
Burette Evaporating dish
Pipette Bunsen burner
Pipette filler Tripod stand and wire gauze
2 conical flasks White tile
Retort stand
Materials:
Dilute nitric acid
Aqueous ammonium hydroxide
Methyl orange indicator
Procedure:
1. Place nitric acid in burette.
2. Pipette 25.0 cm3 of aqueous ammonium hydroxide into a conical flask. Add a few drops of the
indicator.
3. Titrate the acid with the alkali until neutralise.
4. Repeat titration, this time without the indicator.
5. Heat the mixture (ammonium nitrate solution) until it is saturated.
6. Transfer some mixture into an evaporating dish and leave to crystallise.
Conclusion:
86
Activity 18.1
REDOX
Aim: To show the colour change in oxidizing agents - acidified potassium manganate(VII) and
acidified potassium dichromate(VI) solution.
Apparatus:
Measuring cylinder Test-tube
Beaker Burette
Conical flask
Material:
Potassium manganate(VII) solution Dilute sulphuric acid
Potassium dichromate(VI) solution Sodium sulphite solution
Procedure:
1. Measure 20 cm3 of potassium manganate(VII) solution into a conical flask and add about 5
Observations:
(a) Potassium manganate (VII) solution is …………………… (colour) due to the presence of
…………………… ions.
(b) As sodium sulphite solution is added, the colour changes to …………………… (colour) due to
the formation of …………………… ion.
(c) Potassium dichromate(VI) solution is …………………… (colour) due to the presence of
…………………… ions.
(d) As sodium sulphite solution is added the colour changes to …………………… (colour) due to
the formation of …………………… ion.
Conclusion:
Potassium manganate(VII) and potassium dichromate(VI) are oxidizing agents. They are
…………………… by the reducing agent, sodium sulphite.
87
Activity 18.2
REDOX
Aim: To show the colour change of iodide ion in redox reaction.
Apparatus:
Boiling tube
Test tube
Materials:
Hydrogen peroxide ‘20-volume’,
1.0 mol dm3 potassium iodide solution
Starch solution
Procedure:
1. Pour about 5 cm3 of potassium iodide solution into a boiling tube and slowly add equal volume
of ‘20-volume’ hydrogen peroxide, and observe.
2. Leave the mixture for a few minutes and observe for the formation of any solid substance.
3. Transfer some solution from the boiling tube into a test tube and add a few drops of starch
solution.
Results:
(a) Potassium iodide solution changed from ……………………………. (colour) to
……………………………. (colour) when added with hydrogen peroxide.
(b) When left to stand for a few minutes a ……………………………. (colour) solid substance was
seen at the bottom of the boiling tube.
(c) When starch was added, the solution turned ……………………………. (colour) showing that
……………………………. was formed.
Questions:
1. Write an ionic equation to show oxidation of iodide ion.
………………………………………………………………………………………………………………
2. Write an ionic equation for the reduction of hydrogen peroxide.
………………………………………………………………………………………………………………
3. Write ionic equation to show redox reaction between potassium iodide and hydrogen peroxide.
………………………………………………………………………………………………………………
88
Activity 19.2
Apparatus:
500 cm3 beakers
Spatula
Materials:
Sample of muddy water
Alum
Procedure:
1. Fill two beakers with muddy water until three quarter full.
2. Add a spoonful of alum in one but not the other.
3. Leave the two beakers for about 10 minutes and compare the appearance of the water in the
two beakers.
alum
muddy water
Observations:
…………………………………………………………………………………………………………………...
…………………………………………………………………………………………………………………...
89
Activity 20.1
ORGANIC CHEMISTRY
Aim: To show incomplete combustion of hydrocarbon.
Apparatus:
Bunsen burner Evaporating dish
Wooden splint
Materials:
Benzene
Toluene
Kerosene
Procedure:
1. Place a little of each hydrocarbon into an evaporating dish.
2. Burn the hydrocarbon with a lighted wooden splint and observe for the products. (Note:
Burning should be carried out outside the lab as its burning will produce dense smoke and
carbon monoxide).
3. Observe the colour of the flame and record it in the table below
Lighted
wooden splint
Evaporating dish
Benzene
Results:
90
Questions:
1. Do you think these hydrocarbons make good fuel? Explain.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
2. Which of the three hydrocarbons produces the least smoke? Relate your observations in terms
of percentage of carbon in the compound.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
91
Activity 20.3
ORGANIC CHEMISTRY
Aim: To test for alkenes with bromine
Apparatus:
Test tube
Materials:
Liquid bromine
Hexene
Procedure:
1. Add about 2 cm 3 of liquid bromine in a test tube.
Results:
1. The brown colour of liquid bromine is ……………………………...
………………………………………………………………………………………………………………
92
Activity 20.4
ORGANIC CHEMISTRY
Aim: To compare the flammability and the colour of the flame produced by different alcohols and
to show the variation of physical properties of the first four alcohols.
Apparatus:
Evaporating dishes Bunsen burner
Wooden splint
Materials:
Methanol Butanol
Ethanol Cobalt(II) chloride paper
Propanol
Procedure:
1. Pour a little of each of the following alcohols (methanol, ethanol, propanol and butanol) into
four different evaporating dishes.
2. Burn the alcohols with the lighted wooden splint.
3. Compare the colour of the flame and the ease of it burning.
4. Observe what is left on the evaporating dishes. Test it with blue cobalt(II) chloride paper.
Lighted Lighted
wooden splint wooden splint
Methanol Ethanol
Lighted Lighted
wooden splint wooden splint
Propanol Butanol
93
Questions:
1. Note the differences of the colour of the flames from the burning of methanol to butanol.
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
94
Activity 20.5
ORGANIC CHEMISTRY
Aim: To compare fluidity of the alcohols.
Apparatus:
Test tubes with rack
Materials:
Methanol Propanol
Ethanol Butanol
Procedure:
1. Half fill the four test tubes with four different alcohols and compare their fluidity.
2. Place the order of fluidity among the four alcohols.
Results:
most fluid least fluid
1 2 3 4
Questions:
As the molecular mass increases the alcohols become ………………………………. fluid.
95
Activity 20.6
ORGANIC CHEMISTRY
Aim: To show oxidation of ethanol to ethanoic acid.
Apparatus:
Bunsen burner Retort stand with clamp
Boiling tube Beaker
Test tube Delivery tube
Materials:
Ethanol Cold water
Potassium dichromate(VI) solution Blue litmus paper
Dilute sulphuric acid
Procedure:
1. The boiling tube is filled with approximately 5 cm3 of potassium dichromate(VI) solution.
2. About 5 cm3 of dilute sulphuric acid is added to the potassium dichromate(VI) solution.
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Results:
Test on the distillate Observations
Colour
Smell
Action on blue litmus paper
Questions:
1. When ethanol is boiled with acidified potassium dichromate(VI) solution, it is oxidised to
ethanoic acid which has the smell of ……………………………..
2. The colour of acidified potassium dichromate changes from ……………………………. to
………………………………..
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Activity 20.7
ORGANIC CHEMISTRY
Aim: To show acidic properties of carboxylic acid.
Apparatus:
Evaporating dish Wooden splints
Tripod stand Test tubes
Bunsen burner Glass rod
Spatula Delivery tube
Materials:
Ethanoic acid Magnesium ribbon
Aqueous sodium hydroxide Limewater
Sodium carbonate powder Red litmus paper
Procedure:
Observations:
Describe the product left behind the evaporating dish after the solution mixture is evaporated to
dryness.
…………………………………………………………………………………………………………………...
.............................................................................................................................................................
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(b) Reaction between ethanoic acid with magnesium ribbon
1. The test tube is filled with about 5 cm3 of ethanoic acid.
2. A piece of magnesium ribbon (about 3 cm long) is added to ethanoic acid.
3. Test the gas given off with the lighted wooden splint.
Observations:
…………………………………………………………………………………………………………………...
Observations:
…………………………………………………………………………………………………………………...
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REFERENCES:
1. T.Y. Toon, L.W. Leng & T.O Tin. Success Chemistry SPM. Selangor Darul Ehsan: Oxford
Fajar Sdn. Bhd, 2007.
2. Practical Chemsitry For ‘O’ Level. Singapore: Dyna Publisher Pte. Ltd.
3. C.N. Prescott. Chemistry A Course for ‘O’ Level. Practical Workbook. Volume 1. Singapore:
Federal Publications (S) Pte Ltd, 1994.
4. C.N. Prescott. Chemistry A Course for ‘O’ Level. Practical Workbook. Volume 2. Singapore:
Federal Publications (S) Pte Ltd, 1994.
5. L.J. Rasanayagam. Practical Chemistry. A course for ‘O’ Level. Volume 1. Singapore: Federal
Publications (S) Pte Ltd, 1981.
6. L.J. Rasanayagam. Practical Chemistry. A course for ‘O’ Level. Volume 2. Singapore: Federal
Publications (S) Pte Ltd, 1981.
7. J.G.R. Briggs. Chemistry ‘O’ Level Practical. Volume 1 (2nd Ed.). Singapore: Pearson
Education Asia Pte Ltd, 1998.
8. J.G.R. Briggs. Chemistry ‘O’ Level Practical. Volume 2 (2nd Ed.). Singapore: Pearson
Education Asia Pte Ltd, 1998.
9. T.Y. Toon & C.L. Kwong. Chemistry Matters for GCE ‘O’ Level. Practical Workbook.
Singapore: Times Media Private Limited, 2002.
10. L.J. Rasanayagam & R.M. Kok. GCE ‘O’ Level Chemistry Matters. Practical Book. Singapore:
Marshall Cavendish Education, 2007.
11. R.M. Heyworth & J.G.R. Briggs. Chemistry Insights ‘O’ Level (2nd Ed.) Practical Workbook.
Singapore: Pearson Education South Asia Pte Ltd, 2007.
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