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xi
0.05
0.07
0.16
0.24
0.26
0.12
0.08
0.02
wi
0.02
0.04
0.11
0.20
0.27
0.16
0.12
0.05
Solution
(a) From the tabulated data, we are asked to compute M n , the number-average molecular weight. This is carried
out below.
Molecular wt.
Range
Mean Mi
xi
xiMi
15,000-30,000
22,500
0.05
1125
30,000-45,000
37,500
0.07
2625
45,000-60,000
52,500
0.16
8400
60,000-75,000
67,500
0.24
16,200
75,000-90,000
82,500
0.26
21,450
90,000-105,000
97,500
0.12
11,700
105,000-120,000
112,500
0.08
9000
120,000-135,000
127,500
0.02
2250
_________________________
M n = xi M i = 72,750 g/mol
(b) From the tabulated data, we are asked to compute M w , the weight-average molecular weight. This
determination is performed as follows:
Molecular wt.
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MANE/ENGR 2220
Mean Mi
wi
wiMi
15,000-30,000
22,500
0.02
450
30,000-45,000
37,500
0.04
1500
45,000-60,000
52,500
0.11
5775
60,000-75,000
67,500
0.20
13,500
75,000-90,000
82,500
0.27
22,275
90,000-105,000
97,500
0.16
15,600
105,000-120,000
112,500
0.12
13,500
120,000-135,000
127,500
0.05
6375
_________________________
M w = wi M i = 78,975 g/mol
(c) We are now asked if the degree of polymerization is 1165, which of the polymers in Table 14.3 is this material?
It is necessary to compute m in Equation 14.6 as
m=
Mn
72,750 g/mol
=
= 62.45 g/mol
DP
1165
The repeat unit molecular weights of the polymers listed in Table 14.3 are as follows:
Polyethylene--28.05 g/mol
Poly(vinyl chloride)--62.49 g/mol
Polytetrafluoroethylene--100.02 g/mol
Polypropylene--42.08 g/mol
Polystyrene--104.14 g/mol
Poly(methyl methacrylate)--100.11 g/mol
Phenol-formaldehyde--133.16 g/mol
Nylon 6,6--226.32 g/mol
PET--192.16 g/mol
Polycarbonate--254.27 g/mol
Therefore, Poly(vinyl chloride) is the material since its repeat unit molecular weight is closest to that calculated above.
2. The density and associated percent crystallinity for two polymer materials are as follows:
(g/cm3)
1.132
crystallinity (%)
51.3
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MANE/ENGR 2220
64.2
(a) Compute the densities of totally crystalline and totally amorphous polymer.
(b) Determine the density of a specimen having 53.8% crystallinity.
Solution
(a) We are asked to compute the densities of totally crystalline and totally amorphous polymer (c and a from
Equation 14.8). From Equation 14.8 let C =
% crystallinity
, such that
100
C =
c ( s a )
s (c a )
c (C s s ) + ca C sa = 0
in which c and a are the variables for which solutions are to be found. Since two values of s and C are specified in the
c (C1 s1 s1) c a C1 s1 a 0
c (C2 s2 s2 ) ca C2 s2a 0
In which s1 = 1.132 g/cm3, s2 = 1.215 g/cm3, C1 = 0.513, and C2 = 0.642. Solving the above two equations for a and
c leads to
(C C2 )
a s1 s2 1
C1 s1 C2 s2
And
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MANE/ENGR 2220
s1 s2 (C 2 C1)
s2 (C 2 1) s1(C1 1)
(b) Now we are asked to determine the density of a specimen having 53.8% crystallinity. Solving for s from
Equation 14.8 and substitution for a and c which were computed in part (a) yields
s =
c a
C (c a ) c
3. The tensile strength and number-average molecular weight for two poly(methyl methacrylate)
materials are as follows:
Tensile Strength
(MPa)
Number-Average
Molecular Weight (g/mol)
107
30,000
170
60,000
Estimate the number-average molecular weight that is required to give a tensile strength of 185 MPa.
Solution
This problem gives us the tensile strengths and associated number-average molecular weights for two poly(methyl
methacrylate) materials.
Equation 15.3 cites the dependence of the tensile strength on M n . Thus, using the data
provided in the problem statement, we may set up two simultaneous equations from which it is possible to solve for the two
constants TS and A. These equations are as follows:
170 MPa = TS
A
30,000 g / mol
A
60,000 g / mol
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MANE/ENGR 2220
185 =TS
= 233 MPa
Mn
A
g / mol
4. In a continuous and aligned fiber-reinforced composite, the fibers are to carry 84% of a load
Aramid fiber
Polycarbonate
Modulus of Elasticity
[GPa (psi)]
Tensile
Strength
[MPa (psi)]
3600 (520,000)
65 (9425)
Ff
Fm
Ef Vf
EmVm
Ef Vf
Em (1 V f
Ff
Fm
0.84
= 5.25
0.16
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MANE/ENGR 2220
Ff
= 5.25 =
Fm
(131GPa )V f
( 2.4 GPa )(1V f )
+ f V f
= (45 MPa)(1
0.087) + (3600 MPa)(0.087)
= 354.285 MPa
since values for
(3600 MPa) and 'm (45 MPa) are given in the problem statement.
5. Compute
the volume fraction of fibers of an aligned glass fiber-epoxy matrix in which the average
are 1.2 10-2 mm and 1 mm, respectively and longitudinal tensile strength is
fiber diameter and length
750 MPa. Assume that (1) the fiber fracture strength is 5000 MPa; (2) the fiber-matrix bond strength is
25 MPa; and (3) the matrix stress at fiber failure is 10 MPa.
Solution
It is first necessary to compute the value of the critical fiber length using Equation 16.3. If the fiber length is much
greater than lc, then we may determine Vf using Equation 16.17, otherwise, use of either Equation 16.18 or Equation 16.19
is necessary. Thus,
lc =
f d
2 c
Inasmuch as l < lc (1.0 mm < 1.20 mm), then use of Equation 16.19 is required. Therefore,
=
cd'
750 MPa =
l c
d
V f + m' (1 V f )
(V f )
+ (10 MPa)(1 V f )
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MANE/ENGR 2220
6. A continuous and aligned fiber-reinforced composite having a cross sectional area of 940 mm 2 is
subjected to an external tensile load. If the volume fraction of fibers is 0.37, determine the moduli of
elasticity of fiber and matrix phases. The moduli of elasticity in the longitudinal and transverse
directions are 19.7 and 3.66 GPa, respectively.
Solution
This problem asks for us to compute the elastic moduli of fiber and matrix phases for a continuous and aligned
fiber-reinforced composite. We can write expressions for the longitudinal and transverse elastic moduli using Equations
16.10b and 16.16, as
Ecl = Em (1 V f
+ Ef Vf
And
Ect =
3.66
GPa =
(1
EmE f
V f ) E f V f Em
Em E f
(1 0.37 ) E f 0.37 E m
E m = 6.4 GPa
E f = 42.34 GPa
7. Using the definitions for total chain molecule length, L, ( L = Nd sin , where d is the bond
2
length between chain atoms, N is the total number of bonds in the molecule and is the angle between
adjacent backbone chain atoms) and average chain end-to-end distance r, ( r = d N ), for a linear
polyethylene determine:
(a) the number-average molecular weight for L = 1500 nm;
(b) the number-average molecular weight for r = 15 nm.
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MANE/ENGR 2220
N =
L
d sin
2
1500 nm
=
= 11,964
(0.154 nm) sin 109
2
Since there are two CC bonds per polyethylene repeat unit, there is an average of N/2 or 11,964/2 = 5982 repeat units per
chain, which is also the degree of polymerization, DP. In order to compute the value of M n using Equation 14.6, we must
first determine m for polyethylene. Each polyethylene repeat unit consists of two carbon and four hydrogen atoms, thus
m = 2(AC) + 4(AH)
(b) Next, we are to determine the number-average molecular weight for r = 15 nm. Solving for N from Equation
14.12 leads to
N=
r2
(15 nm) 2
=
= 9487
d 2 (0.154 nm) 2
which is the total number of bonds per average molecule. Since there are two CC bonds per repeat unit, then DP = N/2 =
9487/2 = 4743. Now, from Equation 14.6
8. Compute repeat unit molecular weights for the following: (a) polystyrene, (b) poly(ethylene
terephthalate), (c) polycarbonate, and (d) polydimethylsiloxane, (e) polypropylene.
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MANE/ENGR 2220
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