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Unit - 11
1.
s
.
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t
s
e
i
d
u
t
y
a
d
m
o
.c
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2.
3.
4.
(ix)
C6H5OC3H7
(x)
CH3CH2OCH2CH2CH2Cl
m
o
.c
Write the structures of the compounds whose names are given below :
y
a
d
(i)
3, 5-dimethoxyhexane-1, 3, 5-triol
(ii)
cyclohexylmethanol
(i)
(ii)
(iii)
Williamson synthesis
(iv)
Reimer-Tiemann reaction.
(v)
Kolbes reaction
(vi)
to
s
(iii) 2-ethoxy-3-methylpentane e
i
d
(iv) 3-chloromethylpentan-2-ol
u
t
s
(v) p-nitroanisole .
w reactions with example :
w
Describe the following
w
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s
.
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ww
t
s
e
i
d
u
t
y
a
d
m
o
.c
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5.
(ii)
m
o
.c
(iii) cumene is oxidised in the presence of air and the product formed
is treated with dilute acid.
6.
y
a
d
(iv)
(v)
t
s
e
i
d
u
t
(i)
propene to propan-l-ol.
(ii)
anisole to phenol
(iii)
butan-2-one to butan-2-ol
(iv)
ethanal to ethanol
(v)
phenol to ethoxybenzene
(vi)
1-phenylethene to 1-phenylethanol
(vii)
formaldehyde to cyclohexylmethanol
s
.
w
ww
(x)
(xi)
(xii)
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7.
8.
y
a
d
m
o
.c
s
.
w
ww
10.
t
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e
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d
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t
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(ii)
CH3 CH2 OH
443 K
CH2 = CH2
(iii)
CH3CH2OCH2CH3
413 K
2CH3CH2OH
11.
(iv)
CH3OH + CH3I
CH3OCH3 + HI
(v)
CH3OH + (CH3)3 CI
(CH3)3C O CH3 + HI
(ii)
(iii)
(iv)
(v)
(vii)
(a)
(b)
s
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y
a
d
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(x)
(ix)
(x)
(xi)
(xii)
m
o
(xiv) phenols do not give protonation reaction.c
readily.
y
afactional distillation of ethanol
(xvi) absolute ethanol can not be obtaineddby
and water mixture.
to
s
Arrange the following in the increasing
ie order of property shown :
d
(i)
methanol, ethanol, tdiethylether,
ethyleneglycol. (Boiling points)
u
s
. m-nitrophenol, p-nitrophenol. (Acid strength)
(ii)
phenol, o-nitrophenol,
w
(iii) dimethylether,
w ethanol, phenol. (Solubility in water)
w
(iv) n-butanol, 2-methylpropan-1-ol, 2-methylpropan-2-ol. (Acid strength)
(xiii) alcohols can act as weak base as well as weak acids.
12.
13.
(ii)
(iii)
(iv)
(v)
(vi)
*14. Which of the following compounds gives fastest reaction with HBr and
why?
(i)
(CH3)3COH
(ii) FROM
CHWWW.STUDIESTODAY.COM
DOWNLOADED
3CH2CH2OH
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*15. What is the function of ZnCl2 (anhyd) in Lucas test for distinction between
1, 2 and 3 alcohols.
16.
[A] : (CH3)2CHCH2OH
[B] : CH3CH(CH3)COOH
o : (CH ) C OH
t[D]
s
e molecular formula C H O gives a
An organic compound A having
i
d
characteristic colour with aqueous FeCl . When A is treated with NaOH
upressure, compound B is obtained. Compound
t
and CO at 400 K under
s
. compound C which reacts with acetyl chloride to
B on acidification gives
w
form D which isw
a popular pain killer. Deduce the structure of A, B, C and
w
D. What is the common name of Drug D?
[C] : (CH3)2C = CH2
*17.
y
a
d
m
o
.c
3 3
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[Ans. : (A)
20.
(B)
CH3CH2OH
(C)
CH3CHOHCH3
(D)
CH3COOH
(E)
CH3COCH3
Phenol, C6H5OH when it first reacts with concentrated sulphuric acid, forms
Y.Y is reacted with concentrated nitric acid to form Z. Identify Y and Z and
explain why phenol is not converted commercially to Z by reacting it with
conc. HNO3.
[Ans. :
s
.
w
y
a
d
t
s
e
i
d
u
t
m
o
.c
Phenol is not reacted directly with conc. HNO3 because the yield of picric
acid is very poor]
ww
21.
22.
Ethoxybenzene
(b)
2methoxy2methylpropane
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