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CCS
Devil in
the detail
Cost is not the only barrier to the
widespread use of carbon capture and
storage, say Tim Fowler and colleagues
CAREERS
CCS tce
CH3NH2
Mono-methylamine
X
Alkyl radical
intermediate
.
.
.
X = OH , NO3
.
CH3N H
.
CH2NH2
Amino radical
intermediate
NO
Other product
NO2
CH3NHNO
CH3NHNO2
Methylnitrosamine
Methylnitramine
All species and reactions are only in the gas phase (subscript g omitted)
Harald Pettersen/Statoil
Figure 1: Formation of nitrosamines and nitramines by free radical oxidation (MMA example)
photochemistry
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tce
CCS
CH3NHNO2
CH3NH2 a
kA1
k14
kA3
CH3NHNO2 a
kA4
k3 NO2
kA2
k1OH
CH3NH2
k10NO3
k6hv
.
CH3N H
k2NO
k4NO2
k5O2
k11OH
CH3NHNO
kA5
kA6
CH3NHNO a
k13
Other product
k12NO3
Chemical reaction
Mass transfer between gas and aqueous phase
All species are in the gas phase unless shown as aqueous (a)
Figure 2: Summary of significant chemical and partition processes modelled (MMA example)
Pollutants deposited to
ground can, amongst other
processes, adhere to soils
or other materials, can be
transported and diluted by
water flow, can volatilise back
into the atmosphere, can
chemically react, or can be
metabolised by flora, fauna or
microbial activity.
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deposition processes
Air pollutants can be transferred to the
ground by dry and wet deposition processes.
Dry deposition occurs by adsorption of
pollutants onto vegetation and other surfaces.
Wet deposition occurs when precipitation
falls through the pollutant plume and
pollutants transfer to the droplets as they fall.
At Mongstad, wet deposition dominates over
dry deposition.
model implementation
The Calpuff modelling system4 is an open
source modified Gaussian puff air dispersion
and deposition model. We used this model
as the starting point and developed a
bespoke chemical and physical processes
model to represent all the processes shown
other inputs
Air quality models also require meteorological
input data, data to describe local significant
buildings, local ground cover, topography and
land use. Local data for Mongstad were used.
main results
The model developed above was used to
help evaluate the performance of several
CO2 capture process options. While we cant
provide full details here due to commercial
confidentiality we can, however, share some
important high-level results.
First and foremost, the analysis shows that
some CO2 capture processes can comfortably
satisfy the proposed environmental quality
criteria for impacts to air and to water.
Second, the detailed design of the CO2
absorber and the use of emission-reducing
technologies have a highly significant effect
on the emissions of amines released to the
atmosphere.
Third, different process release conditions,
such as stack height, tall buildings, released
gas temperature and velocity could
significantly affect dispersion performance.
Fourth, at Mongstad, water quality impacts
were more significant than air quality issues.
This observation may be due to the greater
uncertainty in the deposition parameters
used in the model. It also suggests that
greater CO2 capture process flexibility may be
possible in localities where surface water is
not used as a source of drinking water, though
in this case a groundwater quality assessment
may be necessary.
Fifth, environmental and health impacts
can be assessed in a variety of ways. Each
way has both strengths and weaknesses.
We describe a model where chemical
transformation and dispersion processes are
represented together. The concentrations we
predict are significantly lower compared to
simpler dispersion only models. In effect, we
have shown that the location of the maximum
CAREERS
CCS tce
Helge Hansen
conclusions
It has been shown that representing relevant
physical and chemical processes results in
lower estimates of environmental impacts of
nitrosamines and nitramines from aminebased CO2 capture processes compared to
results from less sophisticated dispersiononly models. In turn, this allows greater
process design flexibility and possible lower
process costs, perhaps by reducing the
required stack height, reducing the gas exit
velocity or reducing the gas exit temperature.
Balanced against this is the need to
estimate a large number of physio-chemical
parameters.
In conclusion, this work has shown how
dispersion models can incorporate amine
chemistry and be used to evaluate the health
The Mongstad refinery site where the carboncapture plant was to be constructed. Water
from lakes in the area is used for potable water
supplies
the future
In October 2013 the Norwegian government
withdrew financial support to the Mongstad
CCS project, citing delays and cost overruns6. Norway, however, remains committed
to developing a full-scale CCS process before
2020. A strategy for how to achieve this goal is
under development. tce
further reading
1. www.gassnova.no/en
2. bit.ly/1ctTuew
3. Nielsen, CJ et al, Atmospheric chemistry
and environmental impact of the use of
amines in carbon capture and storage,
Chemical Society Review, 2012, 121, DOI
10.1039/c2cs35059a
4. www.src.com/calpuff/calpuff1.htm
5. bit.ly/1gQYJBQ
6. The Chemical Engineer, November 2013, p13
Energy
Lines 2, 15, 24
Water
Lines 12, 17
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