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1. Calculate the vapour densities (kg/m3) of pure carbon dioxide, propane and butane at 25C
and atmospheric pressure. Assume ideal gas behaviour!
Jawab:
Diketahui:
Patm = 101325 N/m2
R = 8,31431 J/K.mol
Ditanya:
Penyelesaian:
Hukum gas ideal:
2. Assuming ideal gas behaviour, what will the final volume be if 1 m3 of air is heated from
20C to 700C at constant pressure?
Jawab:
Diketahui: T1=20 = 293,17 K
T2=700 = 973,17 K
P1 = P2
V1 = 1 m3
Ditanya: V2 = .....?
Penyelesaian:
Hukum gas ideal:
Untuk tekanan yang sama (Hukum Charles) persamaan dapat diubah menjadi:
3. Calculate the vapour pressure of the following pure liquids at 0C: (a) n-octane; (b)
methanol; (c) acetone.
Jawab:
Diketahui : T = 0 C = 273,17 K
Ditanya:
Penyelesaian:
(
(a).n-octane
(
(b).methanol
(c).acetone
4. Calculate the vapour pressures of n-hexane and n-decane above a mixture at 25C
containing 2% n-C6H14 + 98% n-C10H22, by volume. Assume that the densities of pure nhexane and n-decane are 660 and 730 kg/m3 respectively and that the liquids behave ideally.
Jawab:
Diketahui: T=25 = 298,17 K
Diketahui:
Penyelesaian:
)
(
.
(
5. Calculate the vapour pressures of iso-octane and n-dodecane above a mixture at 20C
containing 5% i-C8H18 and 95% n-C12H26, by volume. The densities of the pure liquids are
692 and 749 kg/m3 respectively. Assume ideal behaviour.
Jawab:
Diketahui:
Penyelesaian:
ni- C8H18 =
=
= 0,303508774 mol
nn- C12H26 =
xi- C8H18 =
xi- C12H26 =
= 4,185588235 mol
=
=
= xn-C8H18 x Pn-C8H18
= 0,067610205 x 36,6124945
P-C8H18
= 2,475378259 mm Hg
= 0,205511966 mm Hg
Pn-C12H26
6. Work out the enthalpy of formation of propane at 25C (298 K) from Equation (1.20)
using data contained in Tables 1.13 and 1.14
Jawab:
Diketahui: T=25 = 298,17 K
Ditanya:
Penyelesaian:
7. Given that the stoichiometric reaction for the oxidation of n-pentane is:
calculate
Jawab:
Diketahui:
Ditanya :
Penyelesaian:
8. Calculate the enthalpy change (20C) in the oxidation of n-pentane to carbon monoxide
and water, i.e.
Jawab:
Dik :
C5H12 = -3259 kJ/mol
C0 = -283 kJ/mol
Dit
Penyelesaian :
n-C5H12 + 8 O2
5 CO2 + 6 H2O
n-C5H12 + 5 O2
5 CO + 6 H2O
5 CO + O2
= -3259 5 (-283)
5 CO2
5 CO + 6 H2O
= -1844 kJ/mol
Jadi,
9. The products of the partial combustion of n-pentane were found to contain CO2 and CO in
the ratio of 4: 1. What is the actual heat released per mole of n-pentane burnt if the only other
product is H2O?
Jawab:
Diketahui:
Ditanya:
Penyelesaian:
10. Express the result of problem 9 in terms of heat released (a) per gram of n-pentane burnt;
(b) per gram of air consumed.
Jawab:
Diketahui :
Ditanya:
Penyelesaian:
(a)
(b)
11. Calculate the masses of air required to burn completely 1 g each of propane (C3H8),
pentane ( C5H12) decane (C10H22).
Jawab:
Diketahui :
Penyelesaian:
Propana:
Jadi
Pentana:
Jadi
Decana:
Jadi
12. Calculate the adiabatic flame temperatures for the following mixtures initially at 25C
assuming that dissociation does not occur:
(a) stoichiometric n -pentane/oxygen mixture;
(b) stoichiometric n -pentane/air mixture;
(c) 1.5% n-pentane in air (lower flammability limit, see Chapter 3).
Jawab:
Diketahui
:
T = 25 0C
Ditanya:
Penyelesaian :
a) C5H12 + 8 O2
5 CO2 + 6 H2O
Cp
(J/mol.K)
n.Cp (J/K)
CO2
54,3
271,5
H2O
41,2
247,2
518,7
Tf = 25 +
b) C5H12 + 8 O2 + 6 (3,76) N2
Species
n.Cp (J/K)
CO2
54,3
271,5
H2O
41,2
247,2
N2
30,08
32,7
983,616
1502,316
Tf = 25 +
= 2194,317241 0C